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CN105548070A - Apple soluble solid near-infrared detection part compensation method and system - Google Patents

Apple soluble solid near-infrared detection part compensation method and system Download PDF

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Publication number
CN105548070A
CN105548070A CN201511031809.1A CN201511031809A CN105548070A CN 105548070 A CN105548070 A CN 105548070A CN 201511031809 A CN201511031809 A CN 201511031809A CN 105548070 A CN105548070 A CN 105548070A
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apple
soluble solid
predetermined patterns
near infrared
spectrum
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CN105548070B (en
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黄文倩
樊书祥
王庆艳
李江波
张保华
王超鹏
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Beijing Research Center of Intelligent Equipment for Agriculture
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Beijing Research Center of Intelligent Equipment for Agriculture
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/359Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using near infrared light
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3563Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing solids; Preparation of samples therefor

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  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
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Abstract

The invention provides an apple soluble solid near-infrared detection part compensation method and system. The method includes the steps an absorbancy spectrum of the preset portion of an apple is obtained; the soluble solid content of the preset portion of the apple is obtained; according to the absorbancy spectrum and the soluble solid content, a characteristic wavelength screening algorithm is applied to select characteristic wavelengths related to the apple soluble solid content in a full-wave band spectral range, and an apple soluble solid near-infrared detection model is set up. Spectral information of multiple portions of the apple is fused, the characteristic wavelength screening algorithm is combined, the apple soluble solid near-infrared detection model is set up, the influence on the apple soluble solid near-infrared detection model by changes of spectrum detection is overcome, the stability of the model is improved, and a theoretical basis is laid for portable detection and online detection of apple soluble solid in practical production.

Description

A kind of apple soluble solid near infrared detection position compensation method and system
Technical field
The present invention relates to fruit quality detection field, particularly relate to a kind of apple soluble solid near infrared detection position compensation method and system.
Background technology
Soluble solid refers to all general names being dissolved in the compound of water in liquid or fluid food, comprises sugar, acid, vitamin, mineral matter etc.The soluble solid content of apple is the important indicator of measuring apple internal quality, is also the determinative affecting consumer's purchase intention.
At present, near-infrared spectrum technique is widely applied in apple soluble solid context of detection with the advantage of its quick nondestructive.But the stability of model is often subject to the temperature variation of apple, the impact of the factors such as the place of production, kind, seasonal variation.In addition, the soluble solid content skewness of apple surface, its distribution trend raises along carpopodium gradually to calyx direction, therefore, may cause there are differences between the spectrum of different parts.
In prior art, mostly the research detected about apple soluble solid near infrared spectrum is for position, equator, by gathering the spectral information at position, apple equator, sets up apple soluble solid near infrared spectrum detection model.Therefore, when the soluble solid content going to prediction other positions of apple as carpopodium with this model, its precision of prediction will be affected.
Summary of the invention
For defect of the prior art, the invention provides a kind of apple soluble solid near infrared detection position compensation method and system, by merging the spectral information at the multiple position of apple, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model, the change overcoming spectral detection position, on the impact of apple soluble solid near infrared spectrum detection model, improves the stability of model.
First aspect, the invention provides a kind of apple soluble solid near infrared detection position compensation method, described method comprises:
Obtain the absorbance spectrum of the predetermined patterns of apple;
Obtain the soluble solid content of the predetermined patterns of described apple;
According to described absorbance spectrum and described soluble solid content, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model;
Wherein, described apple predetermined patterns comprises the carpopodium of apple, equator and calyx.
Preferably, the absorption spectrum degree of the predetermined patterns of described acquisition apple, comprising:
By integrating sphere diffuse reflection methodology, obtain the absorbance spectrum of the predetermined patterns of the described apple preset in wave band interval.
Preferably, the absorbance spectrum of the predetermined patterns of described acquisition apple, comprising:
Gather the absorbance spectrum of the predetermined patterns of multiple apple;
Second derivative process is carried out to the absorbance spectrum of the predetermined patterns of described multiple apple, obtains the absorbance spectrum after multiple process.
Preferably, described according to described absorbance spectrum and described soluble solid content, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model, comprising:
In conjunction with characteristic wavelength filtering algorithm, from all band absorbance spectrum of described predetermined patterns, select the characteristic wavelength relevant to apple soluble solid;
According to the soluble solid content of the absorbance spectrum under the characteristic wavelength of described predetermined number apple predetermined patterns and correspondence thereof, partial least squares algorithm is adopted to set up apple soluble solid near infrared spectrum detection model.
Preferably, described apple soluble solid near infrared spectrum detection model, is specially:
Y=∑A kλ k+B;
Wherein, Y is the estimated value of apple soluble solid content, and k is the characteristic wavelength selected, λ kfor the absorbance spectrum under k wavelength, A kfor λ kregression coefficient, B is constant.
Preferably, it is characterized in that, described method also comprises:
Described apple soluble solid near infrared spectrum detection model is tested.
Preferably, described described apple soluble solid near infrared spectrum detection model to be tested, comprising:
Obtain the inspection absorbance log spectrum of apple and the measured value of soluble solid content;
According to the absorbance log spectrum under the characteristic wavelength of described inspection apple, utilize described apple soluble solid near infrared spectrum detection model, obtain the estimated value of soluble solid content;
The estimated value of the measured value of described soluble solid content and described soluble solid content is compared, obtain checking and appraising index, described checking and appraising index is for judging the estimated performance of described apple soluble solid near infrared spectrum detection model.
Second aspect, the invention provides a kind of apple soluble solid near infrared detection position bucking-out system, described system comprises:
First acquiring unit, for obtaining the absorbance spectrum of the predetermined patterns of apple;
Second acquisition unit, for obtaining the soluble solid content of the predetermined patterns of described apple;
Modeling unit, the soluble solid content that the absorbance spectrum obtained according to described first acquiring unit and described second acquisition unit obtain, in conjunction with characteristic wavelength filtering algorithm, sets up apple soluble solid near infrared spectrum detection model;
Wherein, described apple predetermined patterns comprises the carpopodium of apple, equator and calyx.
Preferably, described first acquiring unit, specifically for,
Gather the absorbance spectrum of the predetermined patterns of multiple apple;
Second derivative process is carried out to the absorbance spectrum of the predetermined patterns of described multiple apple, obtains the absorbance spectrum after multiple process.
Preferably, described modeling unit, specifically for,
In conjunction with characteristic wavelength filtering algorithm, from all band absorbance spectrum of described predetermined patterns, select the characteristic wavelength relevant to apple soluble solid;
According to the soluble solid content of the absorbance spectrum under the characteristic wavelength of described predetermined number apple predetermined patterns and correspondence thereof, partial least squares algorithm is adopted to set up apple soluble solid near infrared spectrum detection model.
As shown from the above technical solution, the invention provides a kind of apple soluble solid near infrared detection position compensation method and system, by merging the spectral information of the multiple position of apple as carpopodium, equator and calyx, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model, overcome the change at spectral detection position to the impact of apple soluble solid near infrared spectrum detection model, improve the stability of model, for the portable detection of apple soluble solid content in actual production and on-line checkingi have established theoretical foundation.
Accompanying drawing explanation
In order to be illustrated more clearly in disclosure embodiment or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, accompanying drawing in the following describes is only embodiments more of the present disclosure, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these figure.
The schematic flow sheet of a kind of apple soluble solid near infrared detection position compensation method that Fig. 1 provides for one embodiment of the invention;
The schematic flow sheet of a kind of apple soluble solid near infrared detection position compensation method that Fig. 2 provides for another embodiment of the present invention;
The structure intention of a kind of apple soluble solid near infrared detection position compensation method that Fig. 3 provides for one embodiment of the invention;
The apple spectra collection position schematic diagram that Fig. 4 provides for one embodiment of the invention;
The scatter diagram of the forecast set sample predictions result that Fig. 5 provides for one embodiment of the invention.
Embodiment
Below in conjunction with drawings and Examples, the specific embodiment of the present invention is described in further detail.Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Fig. 1 shows the schematic flow sheet of a kind of apple soluble solid near infrared detection position compensation method that one embodiment of the invention provides, as shown in Figure 1, a kind of apple soluble solid near infrared detection position compensation method of the present embodiment, described method comprises:
The absorbance spectrum of the predetermined patterns of S11, acquisition apple.
Be understandable that, described apple predetermined patterns comprises the carpopodium of apple, equator and calyx.
Specifically, by AntarisII ft-nir spectrometer, adopt InGaAs detecting device, obtain the absorbance spectrum of the carpopodium of apple, equator and calyx.
S12, obtain the soluble solid content of the predetermined patterns of described apple.
Be understandable that, the mensuration of apple soluble solid content is with reference to adopting the semi-automatic Abbe refractometer (ReichertInc., USA) of Arias500 type.
Specifically, after spectra collection completes, and then utilize traditional destructive test to adopt part from the carpopodium of apple, equator and calyx successively and cut band arillate top layer pulp, be placed on gauze for filtering, extrude juice 1 ~ 2, measure the soluble solid content of apple.
S13, according to described absorbance spectrum and described soluble solid content, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model.
The present embodiment is by merging the spectral information at the multiple position of apple, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model, overcome the change at spectral detection position to the impact of apple soluble solid near infrared spectrum detection model, improve the stability of model, for the portable detection of apple soluble solid content in actual production and on-line checkingi have established theoretical foundation.
Fig. 2 shows the schematic flow sheet of a kind of apple soluble solid near infrared detection position compensation method that another embodiment of the present invention provides, as shown in Figure 2, a kind of apple soluble solid near infrared detection position compensation method of the present embodiment, described method comprises:
The absorbance spectrum of the predetermined patterns of S21, acquisition apple.
Be understandable that, by integrating sphere diffuse reflection methodology, obtain the absorbance spectrum of the predetermined patterns of the described apple preset in wave band interval.Wherein, scanning times is 32 times, and resolution is 4cm -1, described default wave band interval is 10000-4000cm -1.
Above-mentioned step S21 can be following not shown step S211-S212:
S211, gather the absorbance spectrum of the predetermined patterns of multiple apple.
Being understandable that, in order to improve the accuracy of modeling, the sample of multiple apple as modeling should being chosen.
S212, second derivative process is carried out to the absorbance spectrum of the predetermined patterns of described multiple apple, obtain the absorbance spectrum after multiple process.
Be understandable that, the absorbance spectrum collected, the random noise often containing instrument, in addition, the spuious introducing of the information such as to penetrate of baseline wander, light, also can affect the corresponding relation between near infrared spectrum and soluble solid content, cause the reliability and stability of institute's established model to reduce.
Specifically, in the present embodiment, by carrying out second derivative process to the absorbance spectrum of acquired original, applying and leading the spectroscopic data after process through second order and carry out follow-up modeling analysis.
S22, obtain the soluble solid content of the predetermined patterns of described apple.
Be understandable that, the mensuration of apple soluble solid content is with reference to adopting the semi-automatic Abbe refractometer (ReichertInc., USA) of Arias500 type.
Specifically, after spectra collection completes, and then utilize traditional destructive test to adopt part from the carpopodium of apple, equator and calyx successively and cut band arillate top layer pulp, be placed on gauze for filtering, extrude juice 1 ~ 2, measure the soluble solid content of apple.
S23, according to described absorbance spectrum and described soluble solid content, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model.
Above-mentioned step S23 can be following not shown step S231-S232:
S231, in conjunction with characteristic wavelength filtering algorithm, from all band absorbance spectrum of described predetermined patterns, select the characteristic wavelength relevant to apple soluble solid.
Be understandable that between spectral variables, to there is a large amount of redundancies and colinearity information, larger interference is created to the extraction of spectral effective information, cause the problems such as model is complicated, calculated amount is large.
Preferably, in the present embodiment, based on the spectroscopic data at above-mentioned multiple detection position, the heavy weighting algorithm of competitive self-adaptation is adopted, from all band 10000-4000cm -1pick out the characteristic wavelength of apple soluble solid content, for setting up apple soluble solid near infrared spectrum detection model.
S232, soluble solid content according to the absorbance spectrum under the characteristic wavelength of described predetermined number apple predetermined patterns and correspondence thereof, adopt partial least squares algorithm to set up apple soluble solid near infrared spectrum detection model.
Specifically, described apple soluble solid near infrared spectrum detection model is:
Y=∑A kλ k+B;
Wherein, Y is the estimated value of apple soluble solid content, and k is the characteristic wavelength selected, λ kfor the absorbance spectrum under k wavelength, A kfor λ kregression coefficient, B is constant.
S24, described apple soluble solid near infrared spectrum detection model to be tested.
Above-mentioned step S24 can be following not shown step S241-S243:
S241, the acquisition inspection absorbance log spectrum of apple and the measured value of soluble solid content.
Be understandable that, in order to verify precision of prediction and the stability of above-mentioned institute Modling model, modeling apple used and new apple can be chosen respectively as inspection apple, obtain the absorbance log spectrum of inspection apple, and utilize the method for step S22 to obtain the measured value of the soluble solid content of its correspondence.
S242, absorbance log spectrum according to described inspection apple, utilize described apple soluble solid near infrared spectrum detection model, obtains the estimated value of soluble solid content.
Be understandable that, according to the absorbance log spectrum of described inspection apple, utilize model Y=∑ A kλ k+ B, obtains the estimated value of soluble solid content.
S243, the estimated value of the measured value of described soluble solid content and described soluble solid content to be compared, obtain checking and appraising index, described checking and appraising index is for judging the estimated performance of described apple soluble solid near infrared spectrum detection model.
Be understandable that, checking and appraising index comprises related coefficient and root-mean-square error.
The present embodiment is by merging the spectral information at the multiple position of apple, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model, overcome the change at spectral detection position to the impact of apple soluble solid near infrared spectrum detection model, improve the stability of model, for the portable detection of apple soluble solid content in actual production and on-line checkingi have established theoretical foundation.
Fig. 3 shows the structural representation of a kind of apple soluble solid near infrared detection position bucking-out system that another embodiment of the present invention provides, and as shown in Figure 3, a kind of apple soluble solid near infrared detection position bucking-out system 30 of the present embodiment, comprising:
First acquiring unit 31, for obtaining the absorbance spectrum of the predetermined patterns of apple;
Second acquisition unit 32, for obtaining the soluble solid content of the predetermined patterns of described apple;
Modeling unit 33, the soluble solid content that the absorbance spectrum obtained according to described first acquiring unit 31 and described second acquisition unit 32 obtain, in conjunction with characteristic wavelength filtering algorithm, sets up apple soluble solid near infrared spectrum detection model;
Wherein, described apple predetermined patterns comprises the carpopodium of apple, equator and calyx.
In a kind of apple soluble solid near infrared detection position bucking-out system that another embodiment of the present invention provides,
Described first acquiring unit 31, specifically for,
Gather the absorbance spectrum of the predetermined patterns of multiple apple;
Second derivative process is carried out to the absorbance spectrum of the predetermined patterns of described multiple apple, obtains the absorbance spectrum after multiple process.
Described modeling unit 33, specifically for,
In conjunction with characteristic wavelength filtering algorithm, from all band absorbance spectrum of described predetermined patterns, select the characteristic wavelength relevant to apple soluble solid;
According to the soluble solid content of the absorbance spectrum under the characteristic wavelength of described predetermined number apple predetermined patterns and correspondence thereof, partial least squares algorithm is adopted to set up apple soluble solid near infrared spectrum detection model.
The present embodiment is by merging the spectral information at the multiple position of apple, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model, overcome the change at spectral detection position to the impact of apple soluble solid near infrared spectrum detection model, improve the stability of model, for the portable detection of apple soluble solid content in actual production and on-line checkingi have established theoretical foundation.
In one particular embodiment of the present invention, as described below:
Choose 95 apples as calibration set, for Modling model; Choose 35 apples as forecast set, for the inspection of institute's established model.
At room temperature, as shown in Figure 4, to all 130 apples, absorbance spectrum is gathered from the carpopodium of each apple, equator and calyx 3 parts successively.
After spectra collection completes, and then utilize traditional destructive test to adopt part from the carpopodium of apple sample, equator and calyx successively and cut band arillate top layer pulp, measure the soluble solid content of apple.
Second derivative process is carried out to the absorbance spectrum gathered, applies the spectroscopic data after second derivative process and carry out follow-up modeling analysis.
In conjunction with characteristic wavelength filtering algorithm, in full band range, select the characteristic wavelength relevant to apple soluble solid, especially, in this example, adopt the heavy weighting algorithm of competitive self-adaptation, from all band 10000-4000cm -1pick out the characteristic wavelength of 66 apple soluble solids, adopt partial least squares algorithm foundation based on the apple soluble solid near infrared spectrum detection model of selected characteristic wavelength.
Model expression is as follows:
Y=-56525.898λ 4078.7-22856.338λ 4182.8-36943.720λ 4269.6+56956.642λ 4271.5+154815.334λ 4313.9+113330.183λ 4398.8+129408.255λ 4504.8-117514.829λ 4539.6-121295.514λ 4541.5-121564.421λ 4545.3-84672.852λ 4636.0-90901.481λ 4637.9-82541.703λ 4703.5-89625.552λ 4707.3-104470.820λ 4738.2-105405.841λ 4769.0-106029.872λ 4786.4-108989.175λ 4788.3-107924.008λ 4796. 0-104129.292λ 4988.9-103529.299λ 4990.8-111549.708λ 5085.3-115909.981λ 5490.3-106618.822λ 5496.1-116337.682λ 5498.0+106438.398λ 5688.9+96029.676λ 5810.4+115032.826λ 5814.3+107935.301λ 5957.0-91748.438λ 5958.9-88456.837λ 5960.8-95833.780λ 5962.8+199904.1549λ 5966.6+189393.5788λ 5968.6+160175.552λ 6190.3+142319.686λ 6196.1+126593.009λ 6198.0+116570.457λ 713 5.3+122100.435λ 7225.9+207595.089λ 7239.4-83566.187λ 7241.3-67547.235λ 7291.5-63108.673λ 7 293.4-70816.081λ 7320.4-89420.384λ 7322.3+171940.532λ 7357.1+175047.273λ 7359.0-60733.900λ 7362.8-91592.019λ 7364.8-85493.596λ 7386.0-177139.329λ 7387.9-206453.142λ 7391.8-115512.261λ 8342.5-129283.029λ 8572.0-153976.382λ 8573.9-150740.715λ 8575.8-117422.490λ 8629.8-114922.986λ 8631.8-127950.490λ 8633.7+54391.231λ 8755.2-105707.858λ 8757.1+242191.880λ 8826.5+147387.742λ 9513.1+80160.282λ 9601.8-159513.138λ 9605.6-220245.358λ 9744.5+7.124;
Wherein, Y is the estimated value of apple soluble solid content, and unit is a ° Brix.λ 4078.7for wave number is 4078.7cm -1corresponding leads the spectral value after process through second order, and 56525.898 is λ 4078.7regression coefficient, 7.124 is constant.
In order to verify precision of prediction and the stability of above-mentioned institute established model, utilize above-mentioned model to calibration set, and the soluble solid content of the forecast set sample including 3 different parts spectral informations detecting, and result is evaluated.Evaluation index lieutenant colonel positive correlation coefficient (r c), prediction related coefficient (r p) larger, correction root-mean-square error (RMSEC), predicted root mean square error more (RMSEP) are little, illustrate that model prediction performance is better.Predict the outcome as shown in table 1 below:
Table 1
Related coefficient between the predicted value of calibration set and forecast set and measured value is all greater than 0.95, and root-mean-square error is all less than 0.5 ° of Brix, obtains satisfied precision of prediction.Meanwhile, the forecast set of 3 groups of different parts is all achieved and predicts the outcome preferably, illustrate that this model is insensitive for the change at spectral detection position.
As shown in Figure 5, sample, near being distributed in regression straight line both sides, has good linear prediction effect.The method of the above results application the present embodiment can reduce the change at spectral detection position to the impact of apple soluble solid near infrared spectrum detection model.
In order to verify by the validity of characteristic wavelength selected in the spectral information of multiple collection positions acquisition, with the spectrum at position, equator for calibration set, set up the apple soluble solid calibration model based on selected characteristic wavelength, still verified by the prediction the set pair analysis model containing 3 different parts spectral informations.Modeling and predict the outcome as shown in table 2 below.Meanwhile, in order to the validity of characterization wavelength, in table 2, give the result of the model based on position, equator all band establishment of spectrum.
Table 2
Contrast above-mentioned two models, can find out, based on the apple soluble solid near infrared spectrum detection model that position, all band equator is set up, when soluble solid content for detecting with its different parts as calyx position, fairly obvious error can be produced.And based on the model that 66 characteristic wavelengths are set up, while the precision of prediction of model is improved, all larger predicated error is not occurred to 3 forecast sets.Therefore, by 66 validity feature wavelength of screening, the impact of spectral detection change in location on the model set up as the spectral information in equator based on single position can be reduced.
One of ordinary skill in the art will appreciate that: above each embodiment, only in order to technical scheme of the present invention to be described, is not intended to limit; Although with reference to foregoing embodiments to invention has been detailed description, those of ordinary skill in the art is to be understood that: it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein some or all of technical characteristic; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the scope of the claims in the present invention.

Claims (10)

1. an apple soluble solid near infrared detection position compensation method, is characterized in that, described method comprises:
Obtain the absorbance spectrum of the predetermined patterns of apple;
Obtain the soluble solid content of the predetermined patterns of described apple;
According to described absorbance spectrum and described soluble solid content, in conjunction with characteristic wavelength filtering algorithm, set up apple soluble solid near infrared spectrum detection model;
Wherein, described apple predetermined patterns comprises the carpopodium of apple, equator and calyx.
2. method according to claim 1, is characterized in that, the absorption spectrum degree of the predetermined patterns of described acquisition apple, comprising:
By integrating sphere diffuse reflection methodology, obtain the absorbance spectrum of the predetermined patterns of the described apple preset in wave band interval.
3. method according to claim 1, is characterized in that, the absorbance spectrum of the predetermined patterns of described acquisition apple, comprising:
Gather the absorbance spectrum of the predetermined patterns of multiple apple;
Second derivative process is carried out to the absorbance spectrum of the predetermined patterns of described multiple apple, obtains the absorbance spectrum after multiple process.
4. method according to claim 3, is characterized in that, described according to described absorbance spectrum and described soluble solid content, in conjunction with characteristic wavelength filtering algorithm, sets up apple soluble solid near infrared spectrum detection model, comprising:
In conjunction with characteristic wavelength filtering algorithm, from all band absorbance spectrum of described predetermined patterns, select the characteristic wavelength relevant to apple soluble solid;
According to the soluble solid content of the absorbance spectrum under the characteristic wavelength of described predetermined number apple predetermined patterns and correspondence thereof, partial least squares algorithm is adopted to set up apple soluble solid near infrared spectrum detection model.
5. method according to claim 4, is characterized in that, described apple soluble solid near infrared spectrum detection model, is specially:
Y=∑A kλ k+B;
Wherein, Y is the estimated value of apple soluble solid content, and k is the characteristic wavelength selected, λ kfor the absorbance spectrum under k wavelength, A kfor λ kregression coefficient, B is constant.
6. the method according to any one of claim 1-5, is characterized in that, described method also comprises:
Described apple soluble solid near infrared spectrum detection model is tested.
7. method according to claim 6, is characterized in that, describedly tests to described apple soluble solid near infrared spectrum detection model, comprising:
Obtain the inspection absorbance log spectrum of apple and the measured value of soluble solid content;
According to the absorbance log spectrum under the characteristic wavelength of described inspection apple, utilize described apple soluble solid near infrared spectrum detection model, obtain the estimated value of soluble solid content;
The estimated value of the measured value of described soluble solid content and described soluble solid content is compared, obtain checking and appraising index, described checking and appraising index is for judging the estimated performance of described apple soluble solid near infrared spectrum detection model.
8. an apple soluble solid near infrared detection position bucking-out system, is characterized in that, described system comprises:
First acquiring unit, for obtaining the absorbance spectrum of the predetermined patterns of apple;
Second acquisition unit, for obtaining the soluble solid content of the predetermined patterns of described apple;
Modeling unit, the soluble solid content that the absorbance spectrum obtained according to described first acquiring unit and described second acquisition unit obtain, in conjunction with characteristic wavelength filtering algorithm, sets up apple soluble solid near infrared spectrum detection model;
Wherein, described apple predetermined patterns comprises the carpopodium of apple, equator and calyx.
9. system according to claim 8, is characterized in that, described first acquiring unit, specifically for,
Gather the absorbance spectrum of the predetermined patterns of multiple apple;
Second derivative process is carried out to the absorbance spectrum of the predetermined patterns of described multiple apple, obtains the absorbance spectrum after multiple process.
10. system according to claim 8, is characterized in that, described modeling unit, specifically for,
In conjunction with characteristic wavelength filtering algorithm, from all band absorbance spectrum of described predetermined patterns, select the characteristic wavelength relevant to apple soluble solid;
According to the soluble solid content of the absorbance spectrum under the characteristic wavelength of described predetermined number apple predetermined patterns and correspondence thereof, partial least squares algorithm is adopted to set up apple soluble solid near infrared spectrum detection model.
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CN106124447A (en) * 2016-06-08 2016-11-16 沈阳农业大学 A kind of based on the method for soluble solid content in near-infrared spectral analysis technology detection Fructus Fragariae Ananssae
CN107462533A (en) * 2017-08-11 2017-12-12 宜宾金铁红林业科技有限公司 Oily camphor tree fruit based on spectral technique adopts instrument
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CN111693487A (en) * 2020-05-28 2020-09-22 济南大学 Fruit sugar degree detection method and system based on genetic algorithm and extreme learning machine

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Publication number Priority date Publication date Assignee Title
CN106124447A (en) * 2016-06-08 2016-11-16 沈阳农业大学 A kind of based on the method for soluble solid content in near-infrared spectral analysis technology detection Fructus Fragariae Ananssae
CN107462533A (en) * 2017-08-11 2017-12-12 宜宾金铁红林业科技有限公司 Oily camphor tree fruit based on spectral technique adopts instrument
CN108333139A (en) * 2018-01-15 2018-07-27 深圳市芭田生态工程股份有限公司 A kind of apple soluble solid rapid detection method
CN109238973A (en) * 2018-07-18 2019-01-18 中科谱光科技(天津)有限公司 A method of detection apple soluble solid content and water content
CN109946246A (en) * 2019-02-27 2019-06-28 北京农业智能装备技术研究中心 A kind of detection method and device of apple soluble solid
CN109946246B (en) * 2019-02-27 2023-03-14 北京农业智能装备技术研究中心 Detection method and device for soluble solid of apple
CN110991469A (en) * 2019-12-30 2020-04-10 西南大学 Fruit soluble solid online detection method and system
CN110991469B (en) * 2019-12-30 2022-08-12 西南大学 Fruit soluble solid online detection method and system
CN111693487A (en) * 2020-05-28 2020-09-22 济南大学 Fruit sugar degree detection method and system based on genetic algorithm and extreme learning machine

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