CN105369389B - Collagen fiber and its production process - Google Patents
Collagen fiber and its production process Download PDFInfo
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- CN105369389B CN105369389B CN201510431030.2A CN201510431030A CN105369389B CN 105369389 B CN105369389 B CN 105369389B CN 201510431030 A CN201510431030 A CN 201510431030A CN 105369389 B CN105369389 B CN 105369389B
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- 102000008186 Collagen Human genes 0.000 title claims abstract description 138
- 108010035532 Collagen Proteins 0.000 title claims abstract description 138
- 229920001436 collagen Polymers 0.000 title claims abstract description 138
- 239000000835 fiber Substances 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000002994 raw material Substances 0.000 claims abstract description 51
- 238000000034 method Methods 0.000 claims abstract description 31
- 238000009987 spinning Methods 0.000 claims abstract description 17
- 238000004332 deodorization Methods 0.000 claims abstract description 3
- 238000002166 wet spinning Methods 0.000 claims abstract description 3
- 239000004744 fabric Substances 0.000 claims description 52
- 238000012545 processing Methods 0.000 claims description 24
- 241000251468 Actinopterygii Species 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 7
- 239000004627 regenerated cellulose Substances 0.000 claims description 7
- -1 acryl Chemical group 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 229910001385 heavy metal Inorganic materials 0.000 claims description 3
- 239000006166 lysate Substances 0.000 claims description 3
- 235000020995 raw meat Nutrition 0.000 claims description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 2
- 230000006378 damage Effects 0.000 claims description 2
- 239000003456 ion exchange resin Substances 0.000 claims description 2
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims 1
- 238000009738 saturating Methods 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000003020 moisturizing effect Effects 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 53
- 230000000052 comparative effect Effects 0.000 description 15
- 239000000463 material Substances 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 229920002678 cellulose Polymers 0.000 description 8
- 235000010980 cellulose Nutrition 0.000 description 8
- 241001427556 Anoplura Species 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 230000001877 deodorizing effect Effects 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical class CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
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- 210000000245 forearm Anatomy 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000013102 re-test Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A collagen fiber and its preparation method are provided. The process of the collagen fiber comprises: step A: a fiber raw material solution containing a fiber raw material is prepared. And B: a collagen solution containing collagen is prepared. The collagen is 5-10 parts by weight based on 100 parts by weight of the fiber raw material. And C: mixing the fiber raw material solution and the collagen solution to form a spinning solution, and preparing the spinning solution into collagen fibers by a wet spinning method. The process has the advantage of difficult yarn breakage during spinning into fibers, and the collagen fibers with good deodorization function and skin moisturizing function can be manufactured by using a small amount of collagen.
Description
Technical field
The present invention relates to a kind of fiber, the processing procedure and collagen obtained more particularly to a kind of collagen fabric are fine
Dimension.
Background technology
There are many different functional fibers, with the difference of functional kinds of fibers, different functional fibers on the market
Can have the function of that such as moisture absorption, warming, antibacterial and deodorizing etc. are different, wherein, collagen fabric has good smelly eliminating work(
Energy and moisture-retention function of skin, and collagen is the ingredient originally having in human body, thus skin-friendly is good.Since collagen fabric has
There is the advantages of aforementioned, so how to provide a kind of can produce the processing procedure of collagen fabric, and make the collagen produced
Fiber have good deodorizing function and moisture-retention function of skin, be one be worth solve the problems, such as.
Invention content
The first object of the present invention is to provide a kind of processing procedure of collagen fabric, can be in spinning smoothly
Collagen fabric is produced, and obtained collagen fabric has good deodorizing function and moisture-retention function of skin.
The processing procedure of collagen fabric of the present invention includes step A：It is molten to prepare a fibrous raw material for including fibrous raw material
Liquid, step B：Prepare a collagen solution for including collagen, in step B, with the fiber of 100 parts by weight
On the basis of raw material, which is 5~10 parts by weight, and the processing procedure of the collagen fabric also includes one after step B
Step C, in step C, mixing the fibrous raw material solution and the collagen solution becomes a kind of spinning solution, and with wet type
Collagen fabric is made in the spinning solution by spin processes.
The processing procedure of collagen fabric of the present invention, in step B, the weight of the collagen accounts for the collagen egg
The 25%~35% of white solution gross weight.
The processing procedure of collagen fabric of the present invention, molecular weight are point of the collagen of 655~1791dalton
Son accounts for whole collagen ratio more than 50%.
The processing procedure of collagen fabric of the present invention, the average molecular weight of the collagen is 1000dalton.
The processing procedure of collagen fabric of the present invention, the fibrous raw material of the fibrous raw material solution for regenerated cellulose or
Acryl.
The second object of the present invention is to provide a kind of collagen fabric have good deodorizing function and skin moisture-keeping
Function.
Collagen fabric of the present invention, the collagen fabric are that manner described above is made.
Fibrous raw material of the present invention can be the regenerated cellulose for rayon (rayon) to be made, and also can be for making
Make acryl (acryl) material of staple fibre.Meeting natural, environmentally friendly demand, the fibrous raw material is preferably using regeneration
Cellulose.Collagen fabric as that must prepare long fine kenel, which is preferably acryl material.Prepare the fiber
The method of material solution is for example first to collect suitable natural cellulose with regenerated cellulose, and the cellulose
Can for paper products, timber, linen-cotton or above-mentioned material the natural material from the Nature such as any combination, then by the cellulose
It is dissolved in a solvent, stirs at room temperature, the cellulose solution that fibrous raw material is regenerated cellulose can be made.The solvent
Can be sodium hydroxide solution, N-methylmorpholine-N- oxides (N-methylmorpholineN-oxide, NMMO), tertiary amine oxygen
Compound, cyclic annular amine oxide, ethyl alcohol, carbon disulfide, dimethylformamide, diformazan sulfurous or above-mentioned material any combination.
On implementing other than voluntarily preparing the fibrous raw material solution, it can also come in fact in buying ready-made fibrous raw material solution finished product on the market
Apply the present invention.
The source of collagen of the present invention need not be particularly limited to, as being made with animal materials such as ox and pigs.Compared with
Goodly, in order to avoid the propagation of the common disease of people and animals, which can be made with fish of raw material.More preferably, using fish scale as original
The collagen of no fish stink can be more made in material.The method for preparing the collagen solution washes with water collected first
Fish scale, to wash away the impurity of such as silt etc..Then clean the fish scale with acid solution again, with remove nonprotein other into
Part, and obtain transparent flap.The flap is poured into the water-bath added with ferment, by the fish scale after heating stirring
Yellowish lysate is made in piece hydrolysis.After obtaining the lysate, the activity to destroy ferment is heated, and add in active carbon adsorption
Impurity and removal agent of raw meat smell deodorization, later filtering can obtain the transparent liquid of limpid and similary micro- Huang.Again on demand with ion exchange resin
Filtering absorption heavy metal or concentration, can be made the collagen solution.
When implementing the present invention, the concentration of the collagen solution should limit.When concentration is too high, caking gelation is had
The problem of not easy to be processed, and when the concentration is too low, after being mixed with the fibrous raw material solution, it can cause the concentration of the collagen
It crosses dilute, the collagen can not be made fully to be combined with the fibrous raw material.It is thus preferable to the weight of the collagen is to account for this
The 25%~35% of the gross weight of collagen solution.More preferably, the weight of the collagen is account for the collagen solution total
The 35% of weight.In addition, using the gross weight of the fibrous raw material contained by fibrous raw material solution prepared in step A as 100 parts by weight,
Collagen contained by the collagen solution is preferably 5~10 parts by weight.When the weight of the collagen exceeds in 10 weights
When measuring part, the effect that the collagen that more adds can increase is not obvious, and in step C, can reduce spinnability, also
It is to say that higher wire broken rate can be generated in spinning process.When collagen is when weighing less than 5 parts by weight, obtained collagen
The functionals such as the smelly eliminating of azelon and moisturizing can be bad, therefore the parts by weight of the collagen are preferably 5~10 parts by weight, more
Good ground can be 10 parts by weight.
In step C, when mixing the fibrous raw material solution with the collagen solution, it should be noted that the collagen solution
The distribution of the molecular size range and molecular weight of contained collagen.Since collagen is one kind for belonging to high molecular material,
And since the molecular weight of high molecular material has no centainly, and the physics of molecular weight effects material and engineering properties are very big, therefore the glue
The molecular weight of former albumen should limit.When the average molecular weight of the collagen is too big, then collagen is not easy and fibrous raw material
Uniformly mixing can make the poor quality of collagen fabric finished product obtained, if the average molecular weight of the collagen is too small,
It represents collagen and is almost cracked into Amino acid, collagen possessed functional in itself can be lost.In addition, if collagen
The molecular weight distribution of albumen is excessively wide, as intermolecular otherness is excessive so that and the interregional otherness of finished product is big, and
Therefore cause that the finished product easy stress in stress is uneven and damages.Therefore preferably, molecular weight is 655~1791dalton's
The molecule of collagen accounts for the ratio of whole collagen more than 50%, and the average molecular weight of the collagen is
1000dalton。
It is to pour into the spinning solution in spinning tank in step C, and passes through spinning-drawing machine and spun with wet-spinning, then put
Enter one containing sulfuric acid, sodium sulphate and zinc sulfate solidification liquid in, solidified forming collagen fabric and obtain finished product.
The beneficial effects of the present invention are：By controlling the ratio of the fibrous raw material and the collagen, can take into account
In the case of spinnability, the collagen fabric with good deodorizing function and moisture-retention function of skin is made.
Description of the drawings
Nothing.
Specific embodiment
The embodiment 1 of the processing procedure of collagen fabric of the present invention and collagen fabric obtained, comprising：
Step A：Prepare the fibrous raw material solution for including fibrous raw material.It is first collected for example during making：Paper products, linen-cotton etc.
Fiber base material containing cellulose, and the base material and sodium hydrate aqueous solution are acted on forming alkalinized celluloses.The hydrogen
The concentration of aqueous solution of sodium oxide, preferably 5~20 weight %.More preferably, the present embodiment is with the sodium hydroxide of 18 weight %
Solution is handled.Obtain it is experienced after after (matured) and weight percent account for about 30~40% alkalinized celluloses, add
Carbon disulfide reacts, and is dissolved with the sodium hydrate aqueous solution of 5 weight %, after filtering and deaeration, and fibrous raw material, which can be made, is
The fibrous raw material solution of regenerated cellulose.On the implementation, the fibrous raw material solution also can be purchased from existing products on the market,
The step of equally also completing to prepare the fibrous raw material solution.
Step B：Prepare the collagen solution of an including collagen.Anoplura fish scale, and high pressure washing institute are collected first
Anoplura fish scale is stated to wash away impurity.The Anoplura fish scale of 5000g is taken, and adds in 0.6 centinormal 1 15 liters of stirrings of aqueous hydrochloric acid solution
After one day, 0.3 centinormal 1 15 liters of aqueous hydrochloric acid solution is put into coarse net filtering Anoplura squama again, stirs 10 minutes and filters.Then
It pickling 1 time and washes 6 times again, the Anoplura fish scale of the common 3800g of weight in wet base can be obtained.The Anoplura fish scale is put into 10 liters of reaction
In pot, then add after the water of 5000g when being heated up to 50 DEG C, add in the ferment of 4g, the pH value of solution is about 3.2 at this time.Continuous heating
After three hours, fish scale meeting almost all is dissolved, and the pH value of solution increases to 4.0 or so.Removal agent of raw meat smell, the 20g of 40g is added in later
Activated carbon, and increase temperature up to 90 DEG C maintain 40 minutes after be filtered to get limpid yellowish transparent liquid.It will be transparent
Liquid is cooled to 40 DEG C hereinafter, the transparent liquid is made to flow through anion-cation exchange resin, after removing heavy metal, can obtain about 8000 milliliters
Unconcentrated collagen solution.Using vacuum decker, the content which is concentrated into collagen accounts for always
The 35% of weight, that is to say, that collagen nearly weighs 1155g, and water nearly weighs 2145g, which always weighs about 3300g.
Collagen solution made from method described above, the average molecular weight of collagen is 1000, and molecular weight is
The molecule of the collagen of 655~1791dalton accounts for whole collagen ratio more than 50%, the molecule of the collagen
Distribution record is measured in table 1.
Table 1
When taking collagen solution made from this step, it should be noted that with the weight of the fibrous raw material of the fibrous raw material solution
It measures as 100 parts by weight, which is 5 parts by weight.For example, as the usage amount of the fibrous raw material solution be 100g when,
According to the fibrous raw material that should contain about 21g for the ratio of step A.Therefore, the collagen content of the collagen solution should be
1.05g, that is to say, that the usage amount of the collagen solution is 3g.
Step C：Mixing the fibrous raw material solution and the collagen solution becomes a spinning solution, and the spinning solution is wet by one
Formula spinning-drawing machine is spun with the speed of 60m/min, and the solidified forming in a solidification liquid, after forming again after washing oils etc.
Processing can obtain collagen fabric.Every liter of the solidification liquid contains 120 grams of 98% concentrated sulfuric acid, 280 grams of sodium sulphate
And 15 grams of zinc sulfate, and pH value is between 2~3.The fiber bodies of obtained collagen fabric can contain regenerated cellulose
The fibrous raw material and the collagen.The smelly eliminating ability of collagen fabric obtained by last re-test the present embodiment and
Skin moisture-keeping sexuality, and result is reported in Table 2 below.
The embodiment 2 of the processing procedure of collagen fabric of the present invention and collagen fabric obtained is similar with the embodiment 1,
Different places are：The usage amount of the collagen is increased into 10 parts by weight.Glue obtained by similary test the present embodiment
The smelly eliminating ability of former azelon and skin moisture-keeping sexuality, and result is reported in Table 2 below.
The comparative example 1 of the processing procedure of collagen fabric of the present invention and collagen fabric obtained is similar with the embodiment 1,
Different places is in step B, using the weight of the fibrous raw material of the fibrous raw material solution as 100 parts by weight, the collagen
The weight of albumen is 1 parts by weight.The smelly eliminating ability and skin moisture-keeping of collagen fabric obtained by similary test the present embodiment
Sexuality, and result is reported in Table 2 below.
The comparative example 2 of the processing procedure of collagen fabric of the present invention and collagen fabric obtained is similar with the embodiment 1,
Different places is in step B, using the weight of the fibrous raw material of the fibrous raw material solution as 100 parts by weight, the collagen
The weight of albumen is 11 parts by weight.Though due to this comparative example still can spinned fiber because wire broken rate is high, do not meet economic effect
Rate, therefore omit the test of smelly eliminating ability and skin moisture-keeping sexuality.
The comparative example 3 of the processing procedure of collagen fabric of the present invention and collagen fabric obtained is similar with the embodiment 1,
Different places is in step B, using the weight of the fibrous raw material of the fibrous raw material solution as 100 parts by weight, the collagen
The parts by weight of albumen are 15 parts by weight.Since this comparative example is not easy spinned fiber, therefore smelly eliminating ability and skin guarantor can not be carried out
The test of moist ability.
Table 2
(1) smelly eliminating is tested：It is tested using equipment analysis detection tube method and equipment analysis GC methods.
(2) skin moisture-keeping test condition is as follows：Environment temperature is 20 ± 1 DEG C, and ambient humidity is 65 ± 4%, test pair
It is 30 minutes during covering the test of sample as being 10 minutes during for 30 years old women, not covering the adaptation of sample, measurement sites
For forearm, posture is sitting posture during measurement, and measuring instrument is Evaporimeter EP2, and moisturizing benchmark is pure cotton material.
(3) above-mentioned test is that collagen fabric is made knitted fabric to test, and the composition of knitted fabric is 50%
Collagen fabric, 48% cotton and 2% spandex.
(4) the spinnability evaluation criterion described in is as follows：" excellent " represents in spinning process in 3 hours not fracture of wire, " good " generation
Fracture of wire 1~2 time in 3 hours in table spinning process, "available" represents in spinning process fracture of wire in 3 hours, and, more than 5 times, " poor " represent is spun
It is not easy to form silk during silk, that is to say, that silk intensity difference.
Before embodiment described in comparison and the comparative example is started, first to illustrate, due to most in industrial implementation
Using 5 parts by weight as exploiting entity, therefore 2 parts by weight are omitted to the comparative example between 4 parts by weight and 6 parts by weight between 9 parts by weight
Comparative example.The difference of implementation result of the present invention is not only involved additionally, due to spinnability, more involves whether the present invention is able to reality
The emphasis applied, therefore in this specification between 10 to 15 parts by weight, also in addition test the comparative example 2 of 11 parts by weight.
It is learnt by the embodiment 1 and the experimental result of the comparative example 1, which removes for acetic acid and valeric acid (lucky grass
Acid) smelly eliminating ability be substantially better than outside the comparative example 1, skin moisture-keeping is also significantly promoted to 16% by 2%.By the implementation
Example 2 and the experimental result of the comparative example 2 and the comparative example 3 are learnt, although the embodiment 2 meeting fracture of wire, wire broken rate Shang Neng hold
Perhaps range, but the wire broken rate of the comparative example 2 is excessive, and which is then almost difficult to that fiber is made.In addition, observe the embodiment
1st, the embodiment 2 and the comparative example 3, we can have found, when collagen is increased to 5 parts by weight by 1 parts by weight, skin is protected
Moist effect rises to 8 times, and when the collagen is increased to 10 parts by weight by 5 parts by weight, skin moisture-keeping effect is to carry
A height of 1.25 times, therefore we can know that, when the weight of collagen is more than 10 parts by weight, the production cost of input with into
The increased functional of product will be disproportionate, does not have economic benefit.
On the implementation, which can also replace with the fibrous raw material solution using acryl as fibrous raw material, and
The collagen fabric of the present invention is mixed and is made with the collagen solution.Due to the fibrous raw material solution of acryl fiber
It is all conventional art to prepare and how to be spun into fiber, therefore is no longer illustrated.As long as control the weight of the collagen solution
Part and concentration are in the range of as previously described.
In conclusion the processing procedure of collagen fabric of the present invention, by the parts by weight and the fiber that control the collagen
The ratio of the parts by weight of raw material so that while this processing procedure takes into account preferable spinning rate, can produce with good deodorizing function
And the collagen fabric of moisture-retention function of skin, therefore the purpose of the present invention can be reached really.
Claims (5)
1. a kind of processing procedure of collagen fabric, includes step A：Prepare the fibrous raw material solution for including fibrous raw material,
Step B：Prepare a collagen solution for including collagen；It is characterized in that：The collagen be using flap as
Raw material, and fish scale is poured into the water added with ferment, the flap is dissolved into a lysate after heating stirring, then lead to
After crossing heating destruction yeast activity, after adding in activated carbon adsorption dye matter and removal agent of raw meat smell deodorization, the saturating of limpid and micro- Huang is obtained by filtration
Bright liquid, then the object with ion exchange resin absorption heavy metal gained, while the collagen that molecular weight is 655~1791dalton
Molecule accounts for whole collagen ratio more than 50%,
In step B, on the basis of the fibrous raw material of 100 parts by weight, which is 5~10 parts by weight, should
Comprising the step C after step B one, in step C, it is molten also to mix the fibrous raw material for the processing procedure of collagen fabric
Liquid and the collagen solution become a kind of spinning solution, and the spinning solution is made collagen fabric with wet-spinning.
2. the processing procedure of the collagen fabric as described in claim 1, it is characterised in that：In step B, the collagen
Weight account for the 25%~35% of the collagen solution gross weight.
3. the processing procedure of the collagen fabric as described in claim 2, it is characterised in that：The average molecular weight of the collagen
For 1000dalton.
4. the processing procedure of the collagen fabric as described in claim 1, it is characterised in that：The fiber of the fibrous raw material solution is former
Expect for regenerated cellulose or acryl.
5. a kind of collagen fabric, it is characterised in that：The collagen fabric is with right any in claim 1 to 4
It is required that the processing procedure is made.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW103127053 | 2014-08-07 | ||
| TW103127053A TWI565483B (en) | 2014-08-07 | 2014-08-07 | The preparation of collagen fibers and the collagen fibers obtained |
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| Publication Number | Publication Date |
|---|---|
| CN105369389A CN105369389A (en) | 2016-03-02 |
| CN105369389B true CN105369389B (en) | 2018-06-08 |
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| CN201510431030.2A Active CN105369389B (en) | 2014-08-07 | 2015-07-22 | Collagen fiber and its production process |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108096054A (en) * | 2017-12-08 | 2018-06-01 | 厦门医学院 | The purposes of milkfish fish scale collagen |
| CN110878439A (en) * | 2018-09-05 | 2020-03-13 | 东莞盛翔新材料技术有限公司 | Fulispun silk collagen peptide titanium amino acid fiber cloth |
| CN115323517A (en) * | 2022-09-01 | 2022-11-11 | 广州迈菲科技有限公司 | Preparation method of collagen fiber, collagen fiber and application |
| CN115748249B (en) * | 2022-11-23 | 2024-06-25 | 浙江诸暨聚源生物技术有限公司 | Recombinant collagen hydrogel fiber and preparation method thereof |
Citations (5)
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| CN101008110A (en) * | 2007-01-12 | 2007-08-01 | 四川大学 | Method for preparing collagen/ polyvinyl alcohol composite fiber using dialdehyde as cross-linking agent |
| CN101215733A (en) * | 2008-01-14 | 2008-07-09 | 四川大学 | Collagen-base PEG composite fibre and spinning technique thereof |
| CN101597817A (en) * | 2008-07-01 | 2009-12-09 | 河南瑞贝卡发制品股份有限公司 | A kind of preparation method of collagen fiber for artificial hair |
| CN101660215A (en) * | 2009-09-23 | 2010-03-03 | 陈福库 | Protein and cellulose composite fiber and manufacturing method thereof |
| CN102181959A (en) * | 2011-04-07 | 2011-09-14 | 北京服装学院 | Fish collagen composite fibers and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101008110A (en) * | 2007-01-12 | 2007-08-01 | 四川大学 | Method for preparing collagen/ polyvinyl alcohol composite fiber using dialdehyde as cross-linking agent |
| CN101215733A (en) * | 2008-01-14 | 2008-07-09 | 四川大学 | Collagen-base PEG composite fibre and spinning technique thereof |
| CN101597817A (en) * | 2008-07-01 | 2009-12-09 | 河南瑞贝卡发制品股份有限公司 | A kind of preparation method of collagen fiber for artificial hair |
| CN101660215A (en) * | 2009-09-23 | 2010-03-03 | 陈福库 | Protein and cellulose composite fiber and manufacturing method thereof |
| CN102181959A (en) * | 2011-04-07 | 2011-09-14 | 北京服装学院 | Fish collagen composite fibers and preparation method thereof |
Also Published As
| Publication number | Publication date |
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| TW201605495A (en) | 2016-02-16 |
| TWI565483B (en) | 2017-01-11 |
| CN105369389A (en) | 2016-03-02 |
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