Nothing Special   »   [go: up one dir, main page]

CN105348902A - Method for removing wall painting advertisements - Google Patents

Method for removing wall painting advertisements Download PDF

Info

Publication number
CN105348902A
CN105348902A CN201510997532.1A CN201510997532A CN105348902A CN 105348902 A CN105348902 A CN 105348902A CN 201510997532 A CN201510997532 A CN 201510997532A CN 105348902 A CN105348902 A CN 105348902A
Authority
CN
China
Prior art keywords
mass concentration
reagent
wall
container
glacial acetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201510997532.1A
Other languages
Chinese (zh)
Inventor
高玉梅
张帆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changzhou Yahuan Environmental Protection Technology Co Ltd
Original Assignee
Changzhou Yahuan Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changzhou Yahuan Environmental Protection Technology Co Ltd filed Critical Changzhou Yahuan Environmental Protection Technology Co Ltd
Priority to CN201510997532.1A priority Critical patent/CN105348902A/en
Publication of CN105348902A publication Critical patent/CN105348902A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • C09D9/005Chemical paint or ink removers containing organic solvents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a method for removing wall painting advertisements and belongs to the technical field of dirt cleaning. Tetrabutyl titanate, sodium hypochlorite, absolute ethyl alcohol, glacial acetic acid, concentrated nitric acid, hydrogen peroxide and hydrochloric acid are taken as raw materials and react, and a liquid reagent A is prepared; waste newspaper, deionized water, sodium chlorite, glacial acetic acid, potassium hydroxide, nickel oxide and concentrated nitric acid react, and a viscous reagent B is prepared; the reagent A and the reagent B are sprayed to the wall painting advertisements repeatedly, and the wall is washed with clear water after sunlight exposure, so that the wall painting advertisements are effectively removed. Examples prove that the method is simple and easy to implement and low in cost, the removal effect is remarkable, the removal rate is up to 95% or higher, the reagents used in the removal process don't have any pungent smell, and no injury is caused to a human body if the reagents are used for a long time.

Description

A kind of wall sprays paint the minimizing technology of advertisement
Technical field
The invention discloses a kind of wall to spray paint the minimizing technology of advertisement, belong to pollution clean-up technology field.
Background technology
Along with improving constantly of standard of living, the level of consumption of people constantly promotes, and various different industries is constantly risen as emerged rapidly in large numbersBamboo shoots after a spring rain.A lot of businessman is in order to solicit customers or business, can publicize on a large scale shop, great majority are advertising, leaflet publicity, popularization on TV etc., some pedlars then in order to save promotion expense, ignore environmental pollution, advertisement that the wall in each road, community, park sprays paint, these advertisements are generally all made up of paint, coating, therefore, this is also the most headache of current sanitation worker, is also the most unmanageable one " rubbish ".
Wall sprays paint advertisement not only contaminate environment, and affects the attractive in appearance of wall, so must thoroughly eliminate.The paint remover cleaning that the minimizing technology that the normal wall used sprays paint advertisement at present has mechanical removal method, caustic dip method and some markets to sell.
(1) mechanical paint removal method, mainly adopt artificial method to utilize some machine tools to carry out polishing to the used paint layer of wall surface and old glue-line and remove, this needs a large amount of manual labor, and production efficiency is low, easily causes the scuffing of body material;
(2) alkali lye paint removal method, is placed on thing to be removed in alkali lye exactly and carries out immersion paint removal, and soak time at 8 ~ 10 hours, then removes surface residue, complex operation through the artificial hairbrush that uses;
(3) paint remover paint removal method, the enamelled coating of effects on surface breakage can be removed, but paint stripping rate is slow, and removing general paint film needs several tens minutes, the even longer time, is unfavorable for production application.
Except above-mentioned three kinds of methods, also have solvent method and dry ice method, the shortcoming of solvent method is exactly that moiety comprises some harmful materials, can distribute the smell that some stimulate; Although and dry ice thoroughly can be removed wall and to spray paint advertisement and harmless, this technology is owing to being external introduction, and cost compare is high.
Therefore, find a kind of cost low, have no irritating odor, and the high wall of clearance sprays paint, advertisement minimizing technology is necessary.
Summary of the invention
The technical problem that the present invention mainly solves: spray paint in the process of advertisement removal to wall for utilizing traditional method at present, although finally can remove wall advertisement of spraying paint, but ubiquity cost is high, clearance rate is low, complex operation and scavenging process be always with pungency toxic odor, human body is had to the present situation of certain infringement, providing one utilizes solid, liquid two kinds of reagent repeatedly to spray, and economic benefits and social benefits remove the method for advertisement of spraying paint.The method using tetrabutyl titanate, clorox, dehydrated alcohol, Glacial acetic acid, concentrated nitric acid, hydrogen peroxide and hydrochloric acid as raw material, through the obtained liquid reagent A of reaction, again by waste newspaper, deionized water, Textone, Glacial acetic acid, potassium hydroxide, nickel oxide and concentrated nitric acid, thickness reagent B is made through reaction, afterwards A, B reagent is sprayed repeatedly to wall advertisement of spraying paint, and clear water rinses after solar exposure, thus wall advertisement of spraying paint effectively is removed.Not only operation is simple for the method, and cost is low, and elimination effect is remarkable, the reagent used in the process of removing without any irritating smell, life-time service to human body also without endangering.
In order to solve the problems of the technologies described above, the technical solution adopted in the present invention is:
(1) at normal temperatures, get 10 ~ 15mL mass concentration be 28% tetrabutyl titanate solution and 8 ~ 12mL mass concentration be the chlorine bleach liquor of 32%, with magnetic stirring apparatus strong stirring 5 ~ 8min, mix, fast with dripping of 2 ~ 3mL/min, slowly be added drop-wise to and 50 ~ 60mL dehydrated alcohol be housed and 35 ~ 55mL mass concentration is in the container of the Glacial acetic acid of 98%, control to dropwise in 10 ~ 15min, wait to dropwise, continue stirring 10 ~ 12min, 50 ~ 55 DEG C are warming up to the rate program of 5 ~ 8 DEG C/min in the process stirred, and by 20 ~ 25mL mass concentration be 65% concentrated nitric acid and 30 ~ 35mL mass concentration be 30% hydrogen peroxide pour into successively wherein, after vigorous reaction 18 ~ 23min, instilling 5 ~ 8 mass concentrations is more wherein the hydrochloric acid soln of 3.5%, adjust ph is 2.8 ~ 3.0, leave standstill 30 ~ 35min, be cooled to room temperature voluntarily, obtain mixing solutions, be designated as A reagent,
(2) 85 ~ 100g waste newspaper is got, after putting into 200 ~ 300mL deionized water immersion, 1 ~ 2h, take out, move in hollander and smash, obtain paper pulp and be placed in container, take 10 ~ 15g Textone subsequently, when temperature is 55 ~ 60 DEG C with 30 ~ 35mL mass concentration be 25% Glacial acetic acid mix, to be cooled put room temperature after, with deionized water wash to neutral, pour into and be equipped with in the container of paper pulp, take 5 ~ 8g potassium hydroxide and 2 ~ 3g nickel oxide again, when temperature is 38 ~ 50 DEG C with 20 ~ 30mL mass concentration be 65% concentrated nitric acid vigorous stirring even, to be cooledly put room temperature, instillation 2 ~ 3mL mass concentration is the hydrochloric acid soln of 3.2%, adjust ph is after 2.6 ~ 3.2, pour into equally and be equipped with in the container of paper pulp, treat all to pour into complete, with the rotating speed of 300 ~ 320r/min, stirring 20 ~ 25min is carried out to the container that mixture and paper pulp are housed, obtain viscous mixture, be designated as B reagent,
(3) centered by advertisement of spraying paint, radius is on the wall of 10 ~ 15cm scope, even sprinkling one deck clear water, the B reagent that uniform application above-mentioned steps (2) is obtained in the scope of spraying clear water subsequently, after all having smeared in specialized range, has dried 30 ~ 45min naturally, afterwards on the metope dried, with the A reagent that spray gun obtains with the speed even application above-mentioned steps (1) of 3 ~ 5m3/h, end to be sprayed, be exposed to the sun under the wall after spraying is appointed sunlight 12h;
(4) end of being exposed to the sun is waited, reuse the B reagent that above-mentioned steps (2) is obtained, the wall after shining is smeared, repeatedly smears 1 ~ 3 time, do not stay any space, after 15 ~ 18min, continue the A reagent that specialized range wall spray gun is obtained with the speed even application above-mentioned steps (1) of 3 ~ 5m3/h, treat all to spray end, be exposed to the sun the wall after painting 16h in the sun, and repeatedly rinse with clear water, until A, B reagent all drops voluntarily.
In described step (1) in A reagent each material further desirable 12 ~ 14mL mass concentration be 28% tetrabutyl titanate solution, 10 ~ 11mL mass concentration be 32% chlorine bleach liquor, 55 ~ 58mL dehydrated alcohol, the 45 ~ 50mL mass concentration Glacial acetic acid that is 98%, the 22 ~ 24mL mass concentration concentrated nitric acid that is 65%, 32 ~ 34mL mass concentration be 30% hydrogen peroxide and 6 ~ 7 mass concentrations be the hydrochloric acid soln of 3.5%.
In described step (2) in B reagent each material further desirable 90 ~ 95g waste newspaper, 250 ~ 280mL deionized water, 12 ~ 14g Textone, 32 ~ 34mL mass concentration be 25% Glacial acetic acid, 6 ~ 7g potassium hydroxide, 2.3 ~ 2.8g nickel oxide and 25 ~ 35mL mass concentration be the concentrated nitric acid of 65%.
The invention has the beneficial effects as follows:
(1) the present invention sprays paint in the process of advertisement removal to wall, the reagent environmental protection of use, health, and without any irritating smell, life-time service is also safe from harm to human body;
(2) the present invention is utilized to remove wall advertisement of spraying paint, without any residual, and the solid colour of the wall color removed after advertisement of spraying paint and other wall, visually without any difference;
(3) elimination effect is remarkable, and clearance rate is up to more than 95%.
Embodiment
First at normal temperatures, get 10 ~ 15mL mass concentration be 28% tetrabutyl titanate solution and 8 ~ 12mL mass concentration be the chlorine bleach liquor of 32%, with magnetic stirring apparatus strong stirring 5 ~ 8min, mix, fast with dripping of 2 ~ 3mL/min, slowly be added drop-wise to and 50 ~ 60mL dehydrated alcohol be housed and 35 ~ 55mL mass concentration is in the container of the Glacial acetic acid of 98%, control to dropwise in 10 ~ 15min, wait to dropwise, continue stirring 10 ~ 12min, 50 ~ 55 DEG C are warming up to the rate program of 5 ~ 8 DEG C/min in the process stirred, and by 20 ~ 25mL mass concentration be 65% concentrated nitric acid and 30 ~ 35mL mass concentration be 30% hydrogen peroxide pour into successively wherein, after vigorous reaction 18 ~ 23min, instilling 5 ~ 8 mass concentrations is more wherein the hydrochloric acid soln of 3.5%, adjust ph is 2.8 ~ 3.0, leave standstill 30 ~ 35min, be cooled to room temperature voluntarily, obtain mixing solutions, be designated as A reagent, then 85 ~ 100g waste newspaper is got, after putting into 200 ~ 300mL deionized water immersion, 1 ~ 2h, take out, move in hollander and smash, obtain paper pulp and be placed in container, take 10 ~ 15g Textone subsequently, when temperature is 55 ~ 60 DEG C with 30 ~ 35mL mass concentration be 25% Glacial acetic acid mix, to be cooled put room temperature after, with deionized water wash to neutral, pour into and be equipped with in the container of paper pulp, take 5 ~ 8g potassium hydroxide and 2 ~ 3g nickel oxide again, when temperature is 38 ~ 50 DEG C with 20 ~ 30mL mass concentration be 65% concentrated nitric acid vigorous stirring even, to be cooledly put room temperature, instillation 2 ~ 3mL mass concentration is the hydrochloric acid soln of 3.2%, adjust ph is after 2.6 ~ 3.2, pour into equally and be equipped with in the container of paper pulp, treat all to pour into complete, with the rotating speed of 300 ~ 320r/min, stirring 20 ~ 25min is carried out to the container that mixture and paper pulp are housed, obtain viscous mixture, be designated as B reagent, next centered by advertisement of spraying paint, radius is on the wall of 10 ~ 15cm scope, even sprinkling one deck clear water, the above-mentioned obtained B reagent of uniform application in the scope of spraying clear water, after all having smeared in specialized range, has dried 30 ~ 45min naturally subsequently, afterwards on the metope dried, with spray gun with the above-mentioned obtained A reagent of the speed even application of 3 ~ 5m3/h, end to be sprayed, be exposed to the sun under the wall after spraying is appointed sunlight 12h, finally wait end of being exposed to the sun, reuse above-mentioned obtained B reagent, the wall after shining is smeared, repeatedly smears 1 ~ 3 time, do not stay any space, after 15 ~ 18min, to continue specialized range wall spray gun, with the above-mentioned obtained A reagent of the speed even application of 3 ~ 5m3/h, to treat all to spray end, be exposed to the sun the wall after painting 16h in the sun, and repeatedly rinse with clear water, until A, B reagent all drops voluntarily.
Further, in described A reagent each material further desirable 12 ~ 14mL mass concentration be 28% tetrabutyl titanate solution, 10 ~ 11mL mass concentration be 32% chlorine bleach liquor, 55 ~ 58mL dehydrated alcohol, the 45 ~ 50mL mass concentration Glacial acetic acid that is 98%, the 22 ~ 24mL mass concentration concentrated nitric acid that is 65%, 32 ~ 34mL mass concentration be 30% hydrogen peroxide and 6 ~ 7 mass concentrations be the hydrochloric acid soln of 3.5%.
Further, in described B reagent each material further desirable 90 ~ 95g waste newspaper, 250 ~ 280mL deionized water, 12 ~ 14g Textone, 32 ~ 34mL mass concentration be 25% Glacial acetic acid, 6 ~ 7g potassium hydroxide, 2.3 ~ 2.8g nickel oxide and 25 ~ 35mL mass concentration be the concentrated nitric acid of 65%.
Example 1
First at normal temperatures, get 10mL mass concentration be 28% tetrabutyl titanate solution and 8mL mass concentration be the chlorine bleach liquor of 32%, with magnetic stirring apparatus strong stirring 5min, mix, fast with dripping of 2mL/min, slowly be added drop-wise to and 50mL dehydrated alcohol be housed and 35mL mass concentration is in the container of the Glacial acetic acid of 98%, dropwise in control 10min, wait to dropwise, continue to stir 10min, 50 DEG C are warming up to the rate program of 5 DEG C/min in the process stirred, and by 20mL mass concentration be 65% concentrated nitric acid and 30mL mass concentration be 30% hydrogen peroxide pour into successively wherein, after vigorous reaction 18min, instilling 5 mass concentrations wherein is again the hydrochloric acid soln of 3.5%, adjust ph is 2.8, leave standstill 30min, be cooled to room temperature voluntarily, obtain mixing solutions, be designated as A reagent, then 85g waste newspaper is got, put into after 200mL deionized water soaks 1h, take out, move in hollander and smash, obtain paper pulp and be placed in container, take 10g Textone subsequently, when temperature is 55 DEG C with 30mL mass concentration be 25% Glacial acetic acid mix, to be cooled put room temperature after, with deionized water wash to neutral, pour into and be equipped with in the container of paper pulp, take 5g potassium hydroxide and 2g nickel oxide again, when temperature is 38 DEG C with 20mL mass concentration be 65% concentrated nitric acid vigorous stirring even, to be cooledly put room temperature, instillation 2mL mass concentration is the hydrochloric acid soln of 3.2%, adjust ph is after 2.6, pour into equally and be equipped with in the container of paper pulp, treat all to pour into complete, with the rotating speed of 300r/min, stirring 20min is carried out to the container that mixture and paper pulp are housed, obtain viscous mixture, be designated as B reagent, next centered by advertisement of spraying paint, radius is on the wall of 10cm scope, even sprinkling one deck clear water, the above-mentioned obtained B reagent of uniform application in the scope of spraying clear water, after all having smeared in specialized range, has dried 30min naturally subsequently, afterwards on the metope dried, with spray gun with the above-mentioned obtained A reagent of the speed even application of 3m3/h, end to be sprayed, be exposed to the sun under the wall after spraying is appointed sunlight 12h, finally wait end of being exposed to the sun, reuse above-mentioned obtained B reagent, the wall after shining is smeared, repeatedly smears 1 time, do not stay any space, after 15min, to continue specialized range wall spray gun, with the above-mentioned obtained A reagent of the speed even application of 3m3/h, to treat all to spray end, be exposed to the sun the wall after painting 16h in the sun, and repeatedly rinse with clear water, until A, B reagent all drops voluntarily.
This case method is unique novel, and not only running cost is low, and using method is simple, and the reagent used in the process removed is without any irritating smell, and life-time service also without harm, finally makes clearance rate reach 95% to human body.
Example 2
First at normal temperatures, get 13mL mass concentration be 28% tetrabutyl titanate solution and 10mL mass concentration be the chlorine bleach liquor of 32%, with magnetic stirring apparatus strong stirring 7min, mix, fast with dripping of 2.5mL/min, slowly be added drop-wise to and 55mL dehydrated alcohol be housed and 45mL mass concentration is in the container of the Glacial acetic acid of 98%, dropwise in control 13min, wait to dropwise, continue to stir 11min, 53 DEG C are warming up to the rate program of 7 DEG C/min in the process stirred, and by 23mL mass concentration be 65% concentrated nitric acid and 33mL mass concentration be 30% hydrogen peroxide pour into successively wherein, after vigorous reaction 20min, instilling 7 mass concentrations wherein is again the hydrochloric acid soln of 3.5%, adjust ph is 2.9, leave standstill 33min, be cooled to room temperature voluntarily, obtain mixing solutions, be designated as A reagent, then 95g waste newspaper is got, put into after 250mL deionized water soaks 1.5h, take out, move in hollander and smash, obtain paper pulp and be placed in container, take 13g Textone subsequently, when temperature is 58 DEG C with 33mL mass concentration be 25% Glacial acetic acid mix, to be cooled put room temperature after, with deionized water wash to neutral, pour into and be equipped with in the container of paper pulp, take 7g potassium hydroxide and 2.5g nickel oxide again, when temperature is 45 DEG C with 25mL mass concentration be 65% concentrated nitric acid vigorous stirring even, to be cooledly put room temperature, instillation 2.5mL mass concentration is the hydrochloric acid soln of 3.2%, adjust ph is after 2.8, pour into equally and be equipped with in the container of paper pulp, treat all to pour into complete, with the rotating speed of 310r/min, stirring 23min is carried out to the container that mixture and paper pulp are housed, obtain viscous mixture, be designated as B reagent, next centered by advertisement of spraying paint, radius is on the wall of 13cm scope, even sprinkling one deck clear water, the above-mentioned obtained B reagent of uniform application in the scope of spraying clear water, after all having smeared in specialized range, has dried 35min naturally subsequently, afterwards on the metope dried, with spray gun with the above-mentioned obtained A reagent of the speed even application of 4m3/h, end to be sprayed, be exposed to the sun under the wall after spraying is appointed sunlight 12h, finally wait end of being exposed to the sun, reuse above-mentioned obtained B reagent, the wall after shining is smeared, repeatedly smears 2 times, do not stay any space, after 16min, to continue specialized range wall spray gun, with the above-mentioned obtained A reagent of the speed even application of 4m3/h, to treat all to spray end, be exposed to the sun the wall after painting 16h in the sun, and repeatedly rinse with clear water, until A, B reagent all drops voluntarily.
This case method is unique novel, and not only running cost is low, and using method is simple, and the reagent used in the process removed is without any irritating smell, and life-time service also without harm, finally makes clearance rate reach 96% to human body.
Example 3
First at normal temperatures, get 15mL mass concentration be 28% tetrabutyl titanate solution and 12mL mass concentration be the chlorine bleach liquor of 32%, with magnetic stirring apparatus strong stirring 8min, mix, fast with dripping of 3mL/min, slowly be added drop-wise to and 60mL dehydrated alcohol be housed and 55mL mass concentration is in the container of the Glacial acetic acid of 98%, dropwise in control 15min, wait to dropwise, continue to stir 12min, 55 DEG C are warming up to the rate program of 8 DEG C/min in the process stirred, and by 25mL mass concentration be 65% concentrated nitric acid and 35mL mass concentration be 30% hydrogen peroxide pour into successively wherein, after vigorous reaction 23min, instilling 8 mass concentrations wherein is again the hydrochloric acid soln of 3.5%, adjust ph is 3.0, leave standstill 35min, be cooled to room temperature voluntarily, obtain mixing solutions, be designated as A reagent, then 100g waste newspaper is got, put into after 300mL deionized water soaks 2h, take out, move in hollander and smash, obtain paper pulp and be placed in container, take 15g Textone subsequently, when temperature is 60 DEG C with 35mL mass concentration be 25% Glacial acetic acid mix, to be cooled put room temperature after, with deionized water wash to neutral, pour into and be equipped with in the container of paper pulp, take 8g potassium hydroxide and 3g nickel oxide again, when temperature is 50 DEG C with 30mL mass concentration be 65% concentrated nitric acid vigorous stirring even, to be cooledly put room temperature, instillation 3mL mass concentration is the hydrochloric acid soln of 3.2%, adjust ph is after 3.2, pour into equally and be equipped with in the container of paper pulp, treat all to pour into complete, with the rotating speed of 320r/min, stirring 25min is carried out to the container that mixture and paper pulp are housed, obtain viscous mixture, be designated as B reagent, next centered by advertisement of spraying paint, radius is on the wall of 15cm scope, even sprinkling one deck clear water, the above-mentioned obtained B reagent of uniform application in the scope of spraying clear water, after all having smeared in specialized range, has dried 45min naturally subsequently, afterwards on the metope dried, with spray gun with the above-mentioned obtained A reagent of the speed even application of 5m3/h, end to be sprayed, be exposed to the sun under the wall after spraying is appointed sunlight 12h, finally wait end of being exposed to the sun, reuse above-mentioned obtained B reagent, the wall after shining is smeared, repeatedly smears 3 times, do not stay any space, after 18min, to continue specialized range wall spray gun, with the above-mentioned obtained A reagent of the speed even application of 5m3/h, to treat all to spray end, be exposed to the sun the wall after painting 16h in the sun, and repeatedly rinse with clear water, until A, B reagent all drops voluntarily.
This case method is unique novel, and not only running cost is low, and using method is simple, and the reagent used in the process removed is without any irritating smell, and life-time service also without harm, finally makes clearance rate reach 97% to human body.

Claims (3)

1. wall sprays paint a minimizing technology for advertisement, it is characterized in that concrete operation step is:
(1) at normal temperatures, get 10 ~ 15mL mass concentration be 28% tetrabutyl titanate solution and 8 ~ 12mL mass concentration be the chlorine bleach liquor of 32%, with magnetic stirring apparatus strong stirring 5 ~ 8min, mix, fast with dripping of 2 ~ 3mL/min, slowly be added drop-wise to and 50 ~ 60mL dehydrated alcohol be housed and 35 ~ 55mL mass concentration is in the container of the Glacial acetic acid of 98%, control to dropwise in 10 ~ 15min, wait to dropwise, continue stirring 10 ~ 12min, 50 ~ 55 DEG C are warming up to the rate program of 5 ~ 8 DEG C/min in the process stirred, and by 20 ~ 25mL mass concentration be 65% concentrated nitric acid and 30 ~ 35mL mass concentration be 30% hydrogen peroxide pour into successively wherein, after vigorous reaction 18 ~ 23min, instilling 5 ~ 8 mass concentrations is more wherein the hydrochloric acid soln of 3.5%, adjust ph is 2.8 ~ 3.0, leave standstill 30 ~ 35min, be cooled to room temperature voluntarily, obtain mixing solutions, be designated as A reagent,
(2) 85 ~ 100g waste newspaper is got, after putting into 200 ~ 300mL deionized water immersion, 1 ~ 2h, take out, move in hollander and smash, obtain paper pulp and be placed in container, take 10 ~ 15g Textone subsequently, when temperature is 55 ~ 60 DEG C with 30 ~ 35mL mass concentration be 25% Glacial acetic acid mix, to be cooled put room temperature after, with deionized water wash to neutral, pour into and be equipped with in the container of paper pulp, take 5 ~ 8g potassium hydroxide and 2 ~ 3g nickel oxide again, when temperature is 38 ~ 50 DEG C with 20 ~ 30mL mass concentration be 65% concentrated nitric acid vigorous stirring even, to be cooledly put room temperature, instillation 2 ~ 3mL mass concentration is the hydrochloric acid soln of 3.2%, adjust ph is after 2.6 ~ 3.2, pour into equally and be equipped with in the container of paper pulp, treat all to pour into complete, with the rotating speed of 300 ~ 320r/min, stirring 20 ~ 25min is carried out to the container that mixture and paper pulp are housed, obtain viscous mixture, be designated as B reagent,
(3) centered by advertisement of spraying paint, radius is on the wall of 10 ~ 15cm scope, even sprinkling one deck clear water, the B reagent that uniform application above-mentioned steps (2) is obtained in the scope of spraying clear water subsequently, after all having smeared in specialized range, has dried 30 ~ 45min naturally, afterwards on the metope dried, with the A reagent that spray gun obtains with the speed even application above-mentioned steps (1) of 3 ~ 5m3/h, end to be sprayed, be exposed to the sun under the wall after spraying is appointed sunlight 12h;
(4) end of being exposed to the sun is waited, reuse the B reagent that above-mentioned steps (2) is obtained, the wall after shining is smeared, repeatedly smears 1 ~ 3 time, do not stay any space, after 15 ~ 18min, continue the A reagent that specialized range wall spray gun is obtained with the speed even application above-mentioned steps (1) of 3 ~ 5m3/h, treat all to spray end, be exposed to the sun the wall after painting 16h in the sun, and repeatedly rinse with clear water, until A, B reagent all drops voluntarily.
2. a kind of wall according to claim 1 sprays paint the minimizing technology of advertisement, it is characterized in that: in described step (1) in A reagent each material further desirable 12 ~ 14mL mass concentration be 28% tetrabutyl titanate solution, 10 ~ 11mL mass concentration be 32% chlorine bleach liquor, 55 ~ 58mL dehydrated alcohol, the 45 ~ 50mL mass concentration Glacial acetic acid that is 98%, the 22 ~ 24mL mass concentration concentrated nitric acid that is 65%, 32 ~ 34mL mass concentration be 30% hydrogen peroxide and 6 ~ 7 mass concentrations be the hydrochloric acid soln of 3.5%.
3. a kind of wall according to claim 1 sprays paint the minimizing technology of advertisement, it is characterized in that: in described step (2) in B reagent each material further desirable 90 ~ 95g waste newspaper, 250 ~ 280mL deionized water, 12 ~ 14g Textone, 32 ~ 34mL mass concentration be 25% Glacial acetic acid, 6 ~ 7g potassium hydroxide, 2.3 ~ 2.8g nickel oxide and 25 ~ 35mL mass concentration be the concentrated nitric acid of 65%.
CN201510997532.1A 2015-12-28 2015-12-28 Method for removing wall painting advertisements Withdrawn CN105348902A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510997532.1A CN105348902A (en) 2015-12-28 2015-12-28 Method for removing wall painting advertisements

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510997532.1A CN105348902A (en) 2015-12-28 2015-12-28 Method for removing wall painting advertisements

Publications (1)

Publication Number Publication Date
CN105348902A true CN105348902A (en) 2016-02-24

Family

ID=55324975

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510997532.1A Withdrawn CN105348902A (en) 2015-12-28 2015-12-28 Method for removing wall painting advertisements

Country Status (1)

Country Link
CN (1) CN105348902A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106391517A (en) * 2016-09-22 2017-02-15 重庆中渝市政环卫有限责任公司解放碑分公司 Method for removing ink smudges of stone wall space floor tiles and reagent
CN106519782A (en) * 2016-11-08 2017-03-22 嘉善弘欣化工厂(普通合伙) Paint scavenger and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106391517A (en) * 2016-09-22 2017-02-15 重庆中渝市政环卫有限责任公司解放碑分公司 Method for removing ink smudges of stone wall space floor tiles and reagent
CN106519782A (en) * 2016-11-08 2017-03-22 嘉善弘欣化工厂(普通合伙) Paint scavenger and preparation method thereof

Similar Documents

Publication Publication Date Title
CN106398374B (en) The preparation method of the de-inking method of glass pieces and used aqueous deinking agent and the aqueous deinking agent
CA2803389C (en) Carboxy ester ketal removal compositions, methods of manufacture, and uses thereof
CN105199877A (en) Adhesive removing agent as well as preparation and using methods thereof
CN102850841A (en) Paint stripping and cleaning agent
CN101067058B (en) Advertisement picture detergent
WO1994015727A1 (en) Method of activating n-methyl-2-pyrrolidone (nmp) varnish and paint remover solvents for removal of organic coatings
CN109692797A (en) A kind of preparation method of aluminum veneer
CN104403851A (en) Adhesive sticker cleaner based on normal temperature water
CN105348902A (en) Method for removing wall painting advertisements
WO2011041837A1 (en) Graffiti removal composition and method
CN107937168A (en) A kind of production method of environment-friendly type degreasing cleaning agent
CN103421616A (en) Cleaning agent
CN105647680A (en) Glass detergent and preparation method thereof
CN102786832B (en) Printing ink cleaning agent and preparation method thereof
CN102719331A (en) Adhesive sticker paste remover and preparation method thereof
CN1492007A (en) Paint remover and preparing method
CN103031060B (en) Novel paint preparation method and application thereof
CN109266090A (en) A kind of environment-friendly type film removal material and preparation method thereof for municipal maintenance project
CN106519783A (en) Environmentally friendly aqueous coating remover and preparation method thereof
CN102504963A (en) Component formula for liquid glass detergent
CN104450231A (en) Electronic part washing agent and preparation method thereof
CN103387763A (en) Efficient environment-friendly paint remover
CN103773621A (en) Dirt removal composition for glass
US20160362637A1 (en) Compositions and methods for the removal of paints, varnishes, stains or graffiti
CN108948854A (en) Preparation with function of cleaning coating

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20160224

WW01 Invention patent application withdrawn after publication