CN105235302A - Bi-stable fusion carbon fiber enhanced composite material - Google Patents
Bi-stable fusion carbon fiber enhanced composite material Download PDFInfo
- Publication number
- CN105235302A CN105235302A CN201510752263.2A CN201510752263A CN105235302A CN 105235302 A CN105235302 A CN 105235302A CN 201510752263 A CN201510752263 A CN 201510752263A CN 105235302 A CN105235302 A CN 105235302A
- Authority
- CN
- China
- Prior art keywords
- ratio
- composite
- state
- carbon fiber
- under
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 60
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 45
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 45
- 230000004927 fusion Effects 0.000 title abstract description 3
- 239000000463 material Substances 0.000 claims abstract description 61
- 239000000835 fiber Substances 0.000 claims abstract description 41
- 239000003365 glass fiber Substances 0.000 claims abstract description 40
- 239000004743 Polypropylene Substances 0.000 claims abstract description 18
- -1 Polypropylene Polymers 0.000 claims abstract description 14
- 229920001155 polypropylene Polymers 0.000 claims abstract description 14
- 239000004744 fabric Substances 0.000 claims abstract description 13
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 12
- 230000008569 process Effects 0.000 claims abstract description 10
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 238000009940 knitting Methods 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims description 28
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 229920001903 high density polyethylene Polymers 0.000 claims description 6
- 239000004700 high-density polyethylene Substances 0.000 claims description 6
- 239000011159 matrix material Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002360 explosive Substances 0.000 claims description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 3
- 229920000914 Metallic fiber Polymers 0.000 claims description 3
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 3
- 239000004695 Polyether sulfone Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004760 aramid Substances 0.000 claims description 3
- 229920003235 aromatic polyamide Polymers 0.000 claims description 3
- 230000007423 decrease Effects 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 229920006351 engineering plastic Polymers 0.000 claims description 3
- 229920003247 engineering thermoplastic Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920006393 polyether sulfone Polymers 0.000 claims description 3
- 229920002530 polyetherether ketone Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 238000003860 storage Methods 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000007943 implant Substances 0.000 description 2
- 238000005381 potential energy Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002305 electric material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 210000003041 ligament Anatomy 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/12—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Moulding By Coating Moulds (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention provides a bi-stable fusion carbon fiber enhanced composite material. The material is formed by carbon fibers and glass fibers which are arranged alternatively, two states are achieved, that is to say, carbon fiber yarn and glass fiber yarn are regularly and alternatively arranged in a same plane according to the ratio of one to one or three to one and knitted into knitted fabric through a knitting machine, the carbon fiber yarn and the glass fiber yarn are regularly knitted into a layer of knitted fabric again in the other plane with a fiber thickness distance from the plane according to the ratio of one to one or three to one, and meanwhile it is guaranteed that the carbon fibers and the glass fibers which are in the same plane are mutually parallel, the carbon fibers and the glass fibers which are in two planes are mutually perpendicular, and therefore a bi-stable special structure form is formed. A preparation method comprises the steps that the well arranged two layers of knitted fabric are evenly spread to make a composite material by adopting a thermoplastic prefabricated technology; a curing process is conducted for one minute at 167 DEG C, and curing formation is achieved after the temperature is decreased; adopted resin is propylene PP (Polypropylene, Polypropene) 147 curing agents, and the mass ratio is 100 to 28.
Description
Technical field
The invention provides a kind of bistable state and merge carbon fibre reinforced composite, belong to carbon fibre composite field.
Background technology
In composite extended familys, fibre reinforced materials is the focus that people pay close attention to always.Since the fiberglass of glass fibre and organic resin compound comes out, the composite that carbon fiber, ceramic fibre and boron fibre strengthen is succeeded in developing in succession, and performance is constantly improved, and makes its field of compound material present one vitality.
Carbon fiber can be processed into fabric, felt, seat, band, paper and other materials.During tradition uses, carbon fiber is except being used as heat-insulating material, is not generally used alone, how joins in the materials such as resin, metal, pottery, concrete as reinforcing material, forms composite.Carbon fiber reinforced composite can be used as aircraft construction material, electromagnetic shielding except the health such as electric material, artificial ligament substitute material and for the manufacture of rocket envelope, power ship, industrial robot, leaf springs of car and driving shaft etc.
Summary of the invention
For the problems referred to above, the invention provides a kind of bistable state and merge carbon fibre reinforced composite, it has two special form stable, has huge application prospect for fields such as military affairs, Aero-Space, ground observations.
The technology path that the present invention adopts is:
A kind of bistable state merges carbon fibre reinforced composite, the material spool line of state (i.e. the first stable state) is put for lateral shaft in material scroll with composite, with the tubular axis line of composite extended state (i.e. the second stable state) in a tubular form for longitudinal axis, comprise: the first manufactures form, the horizontal carbon fiber of 1:1 ratio, the horizontal glass fibre of 1:1 ratio, the longitudinal carbon fiber of 1:1 ratio, the longitudinal glass fibre of 1:1 ratio, needs other host materials added under 1:1 ratio, the second manufactures form, the horizontal carbon fiber of 3:1 ratio, the horizontal glass fibre of 3:1 ratio, the longitudinal carbon fiber of 3:1 ratio, the longitudinal glass fibre of 3:1 ratio, other host materials added are needed under 3:1 ratio, it is characterized in that: under 1:1 ratio manufacturing mode, the horizontal carbon fiber 1 of 1:1 ratio and the horizontal glass fibre of 1:1 ratio are alternately arranged in proportion in same plane, and keep being parallel to each other, another plane of the longitudinal carbon fiber of 1:1 ratio and the longitudinal glass fibre of 1:1 ratio plane fiber thickness in distance is alternately arranged in proportion, and keep being parallel to each other, the filament serrated vertical between two planes must be ensured simultaneously, under the bottom adds 1:1 ratio, need other host materials added simultaneously, above-mentioned three layers of composition 1:1 ratio manufacturing cell, under 3:1 ratio manufacturing mode, the horizontal carbon fiber of 3:1 ratio and the horizontal glass fibre of 3:1 ratio are alternately arranged in proportion in same plane, and keep being parallel to each other, another plane of the longitudinal carbon fiber of 3:1 ratio and the longitudinal glass fibre of 3:1 ratio plane fiber thickness in distance is alternately arranged in proportion, and keep being parallel to each other, the filament serrated vertical between two planes must be ensured simultaneously, under the bottom adds 3:1 ratio, need other host materials added, above-mentioned three layers of composition 3:1 ratio manufacturing cell simultaneously,
Further, for realizing the needs of material manufacturing property, need other host materials added to be use thermoplastic matrix material and add to comprise the fortifying fibre of fragrant adoption fiber, metallic fiber, high density polyethylene (HDPE) series fiber and polymer under needing other host materials of adding and 3:1 ratio under described 1:1 ratio, comprise the thermoplastic matrix material of polypropylene fibre, polyester, polyethersulfone resin, polyether-ether-ketone, aramid, polyethylene-based, engineering plastics and thermoplastic carbamate;
Further, for producing the material body that proper strength requires, described composite is formed by stacking by several 1:1 ratio manufacturing cells or 3:1 ratio manufacturing cell.
A kind of bistable state merges carbon fibre reinforced composite, its manufacturing process is: by carbon fiber yarn and glass fiber yarn proportionally, adopt different radicals of entrying, warp knitting machine is made into knitted fabric, remains on carbon fiber yarn in knitted fabric consistent with the width of glass fiber yarn simultaneously; By uniform for the above-mentioned two-layer knitted fabric of having arranged, adopt thermoplastic precasting process to make composite, curing process be 167 degrees Celsius lower 1 minute, temperature decline Post RDBMS is shaped, and the resin of employing is polypropylene PP (Polypropylene; Polypropene) 147 curing agent, quality proportioning is 100:28.
A kind of bistable state merges carbon fibre reinforced composite, two kinds of stable states can be reached: one is composite is that material scroll puts state (i.e. the first stable state) after manufacture, two kinds are composite extended state (i.e. the second stable state) in a tubular form, and connect nature transition between two kinds of stable states; And, composite puts the certain energy of stable storage in state (i.e. the first stable state) in material scroll, composite extended state (i.e. the second stable state) in a tubular form can be automatically changeb under the effect of storing energy after composite is launched, and the release of this process storing energy is mild, can not produce explosive fault offset; Simultaneously, under composite in a tubular form extended state (i.e. the second stable state), material can be crushed, and being wound into composite in expecting that scroll puts state (i.e. the first stable state), storing energy puts state (i.e. the first stable state) inside at composite in material scroll stably simultaneously.The present invention has the following advantages:
1, element or the following shortcoming of product and danger that similar technique scheme produces is overcome
(1), when tubular-type, do not possess thicker, more powerful prestressing force.
(2), the potential energy that is stored in bending apparatus is huge, danger of blasting.
(3), normally use, when it discharges from curved, this element also danger close, it may return tubulose with explosive speed.
2, the element in material forms a base layer structure, and this mechanism is full of elasticity, in this case, and the very thin hollow form of element and be reversible by situation about compressing.
3, generation potential energy can be resisted under this compression environment, even should eliminate it.Because under this energy can not only make strong element be stored securely in bending environment, all right these elements of safe release, form the form of elongated hollow.
4, under the form of elongated hollow, enough hard of material supports oneself.Therefore, element promptly can extend to the length of requirement from compression stroke, extension illustrates structuring hardness, really accomplishes abundant fusion that is flexible and hardness.
5, material itself implant fiber be wrapped covering, both safe and reliable, increase service life, save again space, use replace easy, to long distance construction application and miniature precision equipment significant.
Accompanying drawing explanation
Fig. 1 is the structural representation under 1:1 ratio modeling of the present invention.
Fig. 2 is the structural representation under 3:1 ratio manufacturing mode of the present invention.
Fig. 3 is two kinds of stable state schematic diagrames of material of the present invention.
Drawing reference numeral: the horizontal carbon fiber of 1-1:1 ratio; The horizontal glass fibre of 2-1:1 ratio; The longitudinal carbon fiber of 3-1:1 ratio; The longitudinal glass fibre of 4-1:1 ratio; Other host materials added are needed under 5-1:1 ratio; The horizontal carbon fiber of 6-3:1 ratio; The horizontal glass fibre of 7-3:1 ratio; The longitudinal carbon fiber of 8-3:1 ratio; The longitudinal glass fibre of 9-3:1 ratio; Other host materials added are needed under 10-3:1 ratio; 11-composite puts state (i.e. the first stable state) in material scroll; 12-composite is extended state (i.e. the second stable state) in a tubular form.
Detailed description of the invention
As shown in Figure 1 to Figure 3, a kind of bistable state merges carbon fibre reinforced composite, the material spool line of state (i.e. the first stable state) 11 is put for lateral shaft in material scroll with composite, with the tubular axis line of composite extended state (i.e. the second stable state) 12 in a tubular form for longitudinal axis, comprise: the first manufactures form, the horizontal carbon fiber 1 of 1:1 ratio, the horizontal glass fibre 2 of 1:1 ratio, the longitudinal carbon fiber 3 of 1:1 ratio, other host materials 5 added are needed under longitudinal glass fibre 4, the 1:1 ratio of 1:1 ratio, the second manufactures form, the horizontal carbon fiber 6 of 3:1 ratio, the horizontal glass fibre 7 of 3:1 ratio, the longitudinal carbon fiber 8 of 3:1 ratio, the longitudinal glass fibre 9 of 3:1 ratio, other host materials 10 added are needed under 3:1 ratio, it is characterized in that: under 1:1 ratio manufacturing mode, the horizontal carbon fiber 1 of 1:1 ratio and the horizontal glass fibre 2 of 1:1 ratio are alternately arranged in proportion in same plane, and keep being parallel to each other, another plane of the longitudinal carbon fiber 3 of 1:1 ratio and the longitudinal glass fibre 4 of 1:1 ratio plane fiber thickness in distance is alternately arranged in proportion, and keep being parallel to each other, the filament serrated vertical between two planes must be ensured simultaneously, under the bottom adds 1:1 ratio, need other host materials 5 added simultaneously, above-mentioned three layers of composition 1:1 ratio manufacturing cell, under 3:1 ratio manufacturing mode, the horizontal carbon fiber 6 of 3:1 ratio and the horizontal glass fibre 7 of 3:1 ratio are alternately arranged in proportion in same plane, and keep being parallel to each other, another plane of the longitudinal carbon fiber 8 of 3:1 ratio and the longitudinal glass fibre 9 of 3:1 ratio plane fiber thickness in distance is alternately arranged in proportion, and keep being parallel to each other, the filament serrated vertical between two planes must be ensured simultaneously, under the bottom adds 3:1 ratio, need other host materials 10 added, above-mentioned three layers of composition 3:1 ratio manufacturing cell simultaneously,
Further, for realizing the needs of material manufacturing property, need other host materials 10 added to be use thermoplastic matrix material and add to comprise the fortifying fibre of fragrant adoption fiber, metallic fiber, high density polyethylene (HDPE) series fiber and polymer under needing other host materials 5 of adding and 3:1 ratio under described 1:1 ratio, comprise the thermoplastic matrix material of polypropylene fibre, polyester, polyethersulfone resin, polyether-ether-ketone, aramid, polyethylene-based, engineering plastics and thermoplastic carbamate;
Further, for producing the material body that proper strength requires, described composite is formed by stacking by several 1:1 ratio manufacturing cells or 3:1 ratio manufacturing cell.
A kind of bistable state merges carbon fibre reinforced composite, its manufacturing process is: by carbon fiber yarn and glass fiber yarn proportionally, adopt different radicals of entrying, warp knitting machine is made into knitted fabric, remains on carbon fiber yarn in knitted fabric consistent with the width of glass fiber yarn simultaneously; By uniform for the above-mentioned two-layer knitted fabric of having arranged, adopt thermoplastic precasting process to make composite, curing process be 167 degrees Celsius lower 1 minute, temperature decline Post RDBMS is shaped, and the resin of employing is polypropylene PP (Polypropylene; Polypropene) 147 curing agent, quality proportioning is 100:28.
A kind of bistable state merges carbon fibre reinforced composite, two kinds of stable states can be reached: one is composite is that material scroll puts state (i.e. the first stable state) 11 after manufacture, two kinds are composite extended state (i.e. the second stable state) 12 in a tubular form, and connect nature transition between two kinds of stable states; And, composite puts the certain energy of stable storage in state (i.e. the first stable state) 11 in material scroll, composite extended state (i.e. the second stable state) 12 in a tubular form can be automatically changeb under the effect of storing energy after composite is launched, and the release of this process storing energy is mild, can not produce explosive fault offset; Simultaneously, in composite extended state (i.e. the second stable state) 12 times in a tubular form, material can be crushed, and being wound into composite in expecting that scroll puts state (i.e. the first stable state) 11, storing energy puts state (i.e. the first stable state) 11 inside at composite in material scroll stably simultaneously.
This materials application:
1, the design of integration
This material can represent with a kind of material steel structure simultaneously, has flintiness and flexibility concurrently, thus makes wholely to become a sturdy firmly workbench by rolling parts; And one can be formed while not using any additional components by fast and stable, expansion and compression, stable and shaping problem can be solved, directly can change another work kenel into from a kind of kenel.Such as: antenna equipment is implanted ATS, communication wire bar can directly as antenna, and it carries, safeguard and at once become fast and simple with using.
2, many materials combine
This material can with optical fiber, cable, the various material such as antenna and chemical fibre combines, and implants after in product and can increase various functions, realizes different attribute superposition.This technology can enable the built-in control circuit of robot arm, accurately completes far-end and precisely controls, there is not circuit partitioning problem, also do not need other installation.If access visual fiber, then can realize data transmission, accurately judge environment around, without the need to additionally connecting up and significantly can promote visual range after extension.
3, high-performance special fiber
This material working range not temperature influence from the Sahara to the Arctic Circle, can be embedded in the space environment of concrete, anaerobic, high radiation, even if be also applicable to the outer space---in the liquid environment of danger, and also response lag, and very environmental protection.ATS very fastly can produce the physical space for receiving, or is extended into various body of unrestricted length.There are significant anisotropy, softness, very light based on its profile, are easy to carry out welding according to the scheme of engineers design, the technique such as bonding performs.As antifatigue, corrosion-resistant, rub resistance material, more can be applied in oil and gas pipes, be completed by sensing and detect monitoring task.
Claims (5)
1. a bistable state merges carbon fibre reinforced composite, the material spool line of state (i.e. the first stable state) (11) is put for lateral shaft in material scroll with composite, with the tubular axis line of composite extended state (i.e. the second stable state) (12) in a tubular form for longitudinal axis, comprise: the first manufactures form, the horizontal carbon fiber (1) of 1:1 ratio, the horizontal glass fibre (2) of 1:1 ratio, the longitudinal carbon fiber (3) of 1:1 ratio, the longitudinal glass fibre (4) of 1:1 ratio, needs other host materials (5) added under 1:1 ratio, the second manufactures form, the horizontal carbon fiber (6) of 3:1 ratio, the horizontal glass fibre (7) of 3:1 ratio, the longitudinal carbon fiber (8) of 3:1 ratio, the longitudinal glass fibre (9) of 3:1 ratio, other host materials (10) added are needed under 3:1 ratio, it is characterized in that: under 1:1 ratio manufacturing mode, the horizontal carbon fiber (1) of 1:1 ratio and the horizontal glass fibre (2) of 1:1 ratio are alternately arranged in proportion in same plane, and keep being parallel to each other, another plane of the longitudinal carbon fiber (3) of 1:1 ratio and the longitudinal glass fibre (4) of 1:1 ratio plane fiber thickness in distance is alternately arranged in proportion, and keep being parallel to each other, the filament serrated vertical between two planes must be ensured simultaneously, under the bottom adds 1:1 ratio, need other host materials (5) added simultaneously, above-mentioned three layers of composition 1:1 ratio manufacturing cell, under 3:1 ratio manufacturing mode, the horizontal carbon fiber (6) of 3:1 ratio and the horizontal glass fibre (7) of 3:1 ratio are alternately arranged in proportion in same plane, and keep being parallel to each other, another plane of the longitudinal carbon fiber (8) of 3:1 ratio and the longitudinal glass fibre (9) of 3:1 ratio plane fiber thickness in distance is alternately arranged in proportion, and keep being parallel to each other, the filament serrated vertical between two planes must be ensured simultaneously, under the bottom adds 3:1 ratio, need other host materials (10) added simultaneously, above-mentioned three layers of composition 3:1 ratio manufacturing cell.
2. a kind of bistable state as claimed in claim 1 merges carbon fibre reinforced composite, it is characterized in that: under needing other host materials (5) of interpolation and 3:1 ratio under described 1:1 ratio, need other host materials (10) added to be use thermoplastic matrix material and interpolation to comprise fragrant adoption fiber, metallic fiber, the fortifying fibre of high density polyethylene (HDPE) series fiber and polymer, comprise polypropylene fibre, polyester, polyethersulfone resin, polyether-ether-ketone, aramid, polyethylene-based, engineering plastics and thermoplastic carbamate are interior thermoplastic matrix material.
3. a kind of bistable state as claimed in claim 1 merges carbon fibre reinforced composite, it is characterized in that: described composite is formed by stacking by several 1:1 ratio manufacturing cells or 3:1 ratio manufacturing cell.
4. a bistable state merges carbon fibre reinforced composite, its manufacturing process is: by carbon fiber yarn and glass fiber yarn proportionally, adopt different radicals of entrying, warp knitting machine is made into knitted fabric, remains on carbon fiber yarn in knitted fabric consistent with the width of glass fiber yarn simultaneously; By uniform for the above-mentioned two-layer knitted fabric of having arranged, adopt thermoplastic precasting process to make composite, curing process be 167 degrees Celsius lower 1 minute, temperature decline Post RDBMS is shaped, and the resin of employing is polypropylene PP (Polypropylene; Polypropene) 147 curing agent, quality proportioning is 100:28.
5. a bistable state merges carbon fibre reinforced composite, two kinds of stable states can be reached: one is composite is that material scroll puts state (i.e. the first stable state) (11) after manufacture, two kinds are composite extended state (i.e. the second stable state) (12) in a tubular form, and connect nature transition between two kinds of stable states; And, composite puts the certain energy of stable storage in state (i.e. the first stable state) (11) in material scroll, composite extended state (i.e. the second stable state) (12) in a tubular form can be automatically changeb under the effect of storing energy after composite is launched, and the release of this process storing energy is mild, can not produce explosive fault offset; Simultaneously, under composite in a tubular form extended state (i.e. the second stable state) (12), material can be crushed, and being wound into composite in expecting that scroll puts state (i.e. the first stable state) (11), storing energy puts state (i.e. the first stable state) (11) inside at composite in material scroll stably simultaneously.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510752263.2A CN105235302B (en) | 2015-11-06 | 2015-11-06 | A kind of bistable state merges carbon fibre reinforced composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510752263.2A CN105235302B (en) | 2015-11-06 | 2015-11-06 | A kind of bistable state merges carbon fibre reinforced composite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105235302A true CN105235302A (en) | 2016-01-13 |
| CN105235302B CN105235302B (en) | 2018-05-25 |
Family
ID=55033239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510752263.2A Active CN105235302B (en) | 2015-11-06 | 2015-11-06 | A kind of bistable state merges carbon fibre reinforced composite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105235302B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106189234A (en) * | 2016-07-13 | 2016-12-07 | 温州雏鹰科技有限公司 | A kind of high intensity unmanned plane propeller and preparation technology thereof |
| CN108125731A (en) * | 2017-12-26 | 2018-06-08 | 复旦大学附属华山医院 | Ankle-joint artificial ligament |
| CN109968749A (en) * | 2019-04-08 | 2019-07-05 | 浙江大学 | A kind of prestressing force bistable state multiple layer combination material and the preparation method and application thereof |
| CN110165362A (en) * | 2019-05-24 | 2019-08-23 | 北京遥测技术研究所 | A kind of portable composite material shortwave whip antenna device |
| WO2020068187A3 (en) * | 2018-06-07 | 2020-06-04 | Honeywell International Inc. | Hybrid fiber multi-axial prepreg |
| CN116113539A (en) * | 2020-11-03 | 2023-05-12 | 叶片动力学有限公司 | Hybrid pultruded panels for spar caps of wind turbine blades |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4728851A (en) * | 1982-01-08 | 1988-03-01 | Ford Motor Company | Field emitter device with gated memory |
| CN101396871A (en) * | 2008-10-28 | 2009-04-01 | 清华大学 | Preparation method of foldable structure based on composite material and performance characterization |
| CN104065303A (en) * | 2014-05-28 | 2014-09-24 | 哈尔滨工业大学 | Piezoelectric bi-stable state energy collector |
-
2015
- 2015-11-06 CN CN201510752263.2A patent/CN105235302B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4728851A (en) * | 1982-01-08 | 1988-03-01 | Ford Motor Company | Field emitter device with gated memory |
| CN101396871A (en) * | 2008-10-28 | 2009-04-01 | 清华大学 | Preparation method of foldable structure based on composite material and performance characterization |
| CN104065303A (en) * | 2014-05-28 | 2014-09-24 | 哈尔滨工业大学 | Piezoelectric bi-stable state energy collector |
Non-Patent Citations (1)
| Title |
|---|
| 张征等: "正交铺设碳纤维复合材料结构的双稳态特性研究", 《功能材料》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106189234A (en) * | 2016-07-13 | 2016-12-07 | 温州雏鹰科技有限公司 | A kind of high intensity unmanned plane propeller and preparation technology thereof |
| CN108125731A (en) * | 2017-12-26 | 2018-06-08 | 复旦大学附属华山医院 | Ankle-joint artificial ligament |
| WO2020068187A3 (en) * | 2018-06-07 | 2020-06-04 | Honeywell International Inc. | Hybrid fiber multi-axial prepreg |
| US11440287B2 (en) | 2018-06-07 | 2022-09-13 | Honeywell International Inc. | Hybrid fiber multi-axial prepreg |
| CN109968749A (en) * | 2019-04-08 | 2019-07-05 | 浙江大学 | A kind of prestressing force bistable state multiple layer combination material and the preparation method and application thereof |
| CN110165362A (en) * | 2019-05-24 | 2019-08-23 | 北京遥测技术研究所 | A kind of portable composite material shortwave whip antenna device |
| CN116113539A (en) * | 2020-11-03 | 2023-05-12 | 叶片动力学有限公司 | Hybrid pultruded panels for spar caps of wind turbine blades |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105235302B (en) | 2018-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105235302A (en) | Bi-stable fusion carbon fiber enhanced composite material | |
| Hasan et al. | Potential fabric-reinforced composites: a comprehensive review | |
| Ge et al. | A finite element analysis of a 3D auxetic textile structure for composite reinforcement | |
| US10576670B2 (en) | Methods to increase structural performance, strength and durability of fabric-reinforced composite materials by pre-stressing | |
| US11754205B2 (en) | Method and apparatus of making pipes and panels using a treated fiber thread to weave, braid or spin products | |
| CN104421536B (en) | The hot Wrapping formed manometer tube of composite winding belt and forming method | |
| CN102234934A (en) | Laid fabric composite coil and manufacturing method thereof | |
| CN105451973B (en) | Method for manufacturing composite molding part and composite molding part | |
| Ishmael et al. | Textile technologies for the manufacture of three-dimensional textile preforms | |
| MX342504B (en) | Preform and method for reinforcing woven fiber nodes. | |
| CN201731184U (en) | Fiber-enhanced antistatic plastic pipe for resisting high temperature | |
| JP2007046197A (en) | Multiaxial nonwoven fabric sheet for fiber-reinforced plastic and method for producing the same | |
| CN106605079A (en) | Energy-absorbing member | |
| RU2013122083A (en) | LONG-DIMENSIONAL POWER STRUCTURAL ELEMENT OF TYPE OF BUILDING BEAM FROM POLYMERIC COMPOSITE MATERIAL | |
| US11913592B2 (en) | Thermally insulating pipes | |
| Gao et al. | Integrated design for manufacturing of braided preforms for advanced composites part II: 3D braiding | |
| CN202215862U (en) | Reinforced composite heat-insulation ultra-high molecular weight polyethylene pipe | |
| CN203453652U (en) | Pressure pipe formed by hot winding of composite winding strips | |
| Chen et al. | 3D woven preforms and properties for textile composites | |
| CN104611820A (en) | Basalt fiber woven fabric and manufacturing method thereof | |
| CN101885244A (en) | Method for manufacturing fiber reinforced high-temperature-resistant antistatic plastic pipe | |
| CN214197633U (en) | High-impact-resistance reinforced fiber composite woven winding pultrusion pipe | |
| CN107757020A (en) | It is a kind of with noctilucence and to be compounded with the non-woven fabrics of carbon fiber | |
| CN110524970B (en) | Bionic scale foot snail composite material structure and forming method | |
| KR101830014B1 (en) | Method for producing a composite structural part, composite structural part and wind power plant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160815 Address after: 266000 Shandong Province, Qingdao city Nanping Road No. 1 Applicant after: Qingdao genuine Intellectual Property Agency Co., Ltd. Address before: Donghai West Road 266000 Shandong city of Qingdao province C 7 floor No. 43 households Applicant before: QINGDAO ASIDUN ENGINEERING TECHNOLOGY TRANSFER CO., LTD. |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170109 Address after: 266000 Shandong Province, Qingdao city Nanping Road No. 1 Applicant after: QINGDAO ASIDUN ENGINEERING TECHNOLOGY TRANSFER CO., LTD. Address before: 266000 Shandong Province, Qingdao city Nanping Road No. 1 Applicant before: Qingdao genuine Intellectual Property Agency Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20171225 Address after: B District 266000 Shandong city of Qingdao province Ningxia City Road 288 No. 5 Qingdao Software Park Building 5 layer Applicant after: Qiu Gang Applicant after: Qiu Wenkun Address before: 266000 Shandong Province, Qingdao city Nanping Road No. 1 Applicant before: QINGDAO ASIDUN ENGINEERING TECHNOLOGY TRANSFER CO., LTD. |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180416 Address after: 266000 Shandong Province, Qingdao city Nanping Road No. 1 Applicant after: QINGDAO ASIDUN ENGINEERING TECHNOLOGY TRANSFER CO., LTD. Address before: B District 266000 Shandong city of Qingdao province Ningxia City Road 288 No. 5 Qingdao Software Park Building 5 layer Applicant before: Qiu Gang Applicant before: Qiu Wenkun |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |