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CN105214482A - A kind of domestic briquet stove flue gas purifying method - Google Patents

A kind of domestic briquet stove flue gas purifying method Download PDF

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Publication number
CN105214482A
CN105214482A CN201510778984.0A CN201510778984A CN105214482A CN 105214482 A CN105214482 A CN 105214482A CN 201510778984 A CN201510778984 A CN 201510778984A CN 105214482 A CN105214482 A CN 105214482A
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CN
China
Prior art keywords
flue gas
adsorption element
briquet stove
domestic briquet
purifying method
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Pending
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CN201510778984.0A
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Chinese (zh)
Inventor
华玉叶
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Individual
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Individual
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Priority to CN201510778984.0A priority Critical patent/CN105214482A/en
Publication of CN105214482A publication Critical patent/CN105214482A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The invention discloses a kind of domestic briquet stove flue gas purifying method, it is placed with the first adsorption element, catalytic member and the second adsorption element at the exhaust end of domestic briquet stove according to the direction order of flow of flue gas.CO, SO in the domestic briquet stove flue gas of purification xand NO xconcentration all lower than 0.5mg/m 3, greatly reduce the pollution of domestic briquet stove to atmospheric environment.

Description

A kind of domestic briquet stove flue gas purifying method
Technical field
The present invention relates to technical field of air purification, be specifically related to a kind of domestic briquet stove flue gas purifying method.
Background technology
Research shows, in north of China region, winter, haze belonged to multiple season, and its pollution level and haze number of days will far away higher than spring and autumns.
Haze weather is a kind of atmosphere pollution state, haze is the general statement to suspended particulate substance content overproof various in air, and especially PM2.5 (equivalent aerodynamic diameter is less than or equal to the particle of 2.5 microns) is considered to " arch-criminal " that cause haze weather.Sulfur dioxide, nitrogen oxide and pellet are the main compositions of haze.
In early or mid November, 2015, the city being representative with Shenyang and other places, its haze PM2.5 index reaches surprising 1140, belongs to serious pollution.Under this kind of environment, pollutant not only injures the respiratory system of people, and the organs such as eyes also can be caused to produce burning sensation, the health of damage eyes.
Causing in numerous reasons that winter, haze number of days increased, fire coal is a key factor.For main equipments such as coal-burning boilers, because the requirement of discharging standards, generally gas cleaning can be carried out.But for resident's heating, the coal furnace used of cooking, due to its small scale, service time is irregular, be difficult to process on a large scale, so there is no corresponding cleaning equipment and method, its flue gas produced directly enters air, pollute environment, increase the weight of the degree of haze.
Summary of the invention
The object of the invention is to the flue gas purifying method proposing a kind of applicable domestic briquet stove, it adopts specific filter course, Catalytic Layer and adsorption layer, comes dust, oxysulfide, nitrogen oxide and oxycarbide in the flue gas of purifying domestic household coal stove generation.
For reaching this object, the present invention by the following technical solutions:
A kind of domestic briquet stove flue gas purifying method, it is placed with the first adsorption element, catalytic member and the second adsorption element at the exhaust end of domestic briquet stove according to the direction order of flow of flue gas.
Described first adsorption element is provided with asbestos fibre filter course.
Described catalytic member is provided with catalyst layer, and described catalyst comprises following component,
A) the titanium base iron cerium molybdenum vanadium oxides composite of 8%, the mol ratio Ti:Fe:Ce:Mo:V of its each component is 1:0.05:0.05:0.05:0.05;
B) 7% zirconium doping ferric vandate, the mol ratio of Zr:FeVO4 is 0.1:1;
C) the SAPO-34 molecular sieve of surplus.
Described second adsorption element is provided with activated carbon adsorption layer.
Method operation principle of the present invention is as follows:
Fire coal burns in domestic briquet stove, and produce flue gas, flue gas mainly comprises dust, CO, CO 2, SO x, NO x.Described flue gas enters exhaust end, and due to the restriction of radiating rate, the temperature of the exhaust end flue gas of domestic briquet stove still belongs to higher temperature, and its temperature is between 50-400 DEG C.
First described flue gas enters the first adsorption element, and described first adsorption element parts are provided with asbestos fibre filter course.Because asbestos belong to exotic material, therefore it can be applicable to described high-temperature flue gas.The materials such as the dust in flue gas, coal ash are under the filtration of asbestos fibre, and be accumulated in the side of asbestos fibre, along with the accumulation of dust, coal ash, it is natural subsidence under gravity, enters the ash discharging hole below the first adsorption element.The material such as dust, coal ash from external opening, can be discharged flue by ash discharging hole.
Air after filtering enters catalytic member subsequently, in catalytic member, under the catalytic action of catalyst, and CO, SO of air state at a middle or low price xand NO xwith the O in flue gas 2at high temperature be oxidized to CO 2, SO 2and NO 2deng high price form.
Air after catalysis, enters the second adsorption element.SO in charcoal absorption flue gas in second adsorption element 2and NO 2, after certain interval of time, described second adsorption element is taken out and washes, then eliminate the SO in active carbon 2and NO 2, thus achieve the regeneration of active carbon.
First adsorption element of the present invention, catalytic member and the second adsorption element all can make the shape adapted to chimney size, and exist with the form of grid superimposed layer.In use, directly described first adsorption element, catalytic member and the second adsorption element are placed in the flue of coal stove, after using a period of time, take out cleaning, continue to use.
Method of the present invention, utilizes easy first adsorption element, catalytic member and the second adsorption element to be placed in the flue of domestic briquet stove, greatly reduces the content of pollutant in flue gas, through measuring, and CO, SO in the domestic briquet stove flue gas of purification xand NO xconcentration all lower than 0.5mg/m 3.Greatly reduce the pollution of domestic briquet stove to atmospheric environment.
Detailed description of the invention
The present invention is described breathing mask of the present invention by following embodiment.
Embodiment 1
A kind of domestic briquet stove flue gas purifying method, it is placed with the first adsorption element, catalytic member and the second adsorption element at the exhaust end of domestic briquet stove according to the direction order of flow of flue gas.
Described first adsorption element is provided with asbestos fibre filter course.
Described catalytic member is provided with catalyst layer, and described catalyst comprises following component,
A) the titanium base iron cerium molybdenum vanadium oxides composite of 8%, the mol ratio Ti:Fe:Ce:Mo:V of its each component is 1:0.05:0.05:0.05:0.05;
B) 7% zirconium doping ferric vandate, the mol ratio of Zr:FeVO4 is 0.1:1;
C) the SAPO-34 molecular sieve of surplus.
Described second adsorption element is provided with activated carbon adsorption layer.
Light domestic briquet stove, the fire coal that coal stove adopts is commercial fire coal, for testing its purification function, after fire coal takes fire 5 minutes, tests the flue gas through purification, after testing, and CO, SO in flue gas xand NO xconcentration all lower than 0.5mg/m 3.
Comparative example 1
Component A content 15%, not containing B component, all the other conditions are constant, CO, SO in flue gas xand NO xconcentration all higher than 2mg/m 3.
Comparative example 2
B component content 15%, not containing component A, all the other conditions are constant, CO, SO in flue gas xand NO xconcentration all higher than 2mg/m 3.
Comparative example 3
The SAPO-34 molecular sieve of component C is replaced with alundum (Al2O3), and all the other conditions are constant, CO, SO in flue gas xand NO xconcentration all higher than 2mg/m 3.
Above-described embodiment and comparative example illustrate, there is specific contact between catalyst carrier of the present invention, omit or replace wherein one or more, all can not reach the certain effects of the application, prove to which create cooperative effect.
Applicant states, the present invention illustrates the catalyst of breathing mask of the present invention and employing by above-described embodiment, but the present invention is not limited to above-mentioned catalyst, does not namely mean that the present invention must rely on above-mentioned detailed catalysts and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.

Claims (1)

1. a domestic briquet stove flue gas purifying method, it is placed with the first adsorption element, catalytic member and the second adsorption element at the exhaust end of domestic briquet stove according to the direction order of flow of flue gas.
Described first adsorption element is provided with asbestos fibre filter course.
Described catalytic member is provided with catalyst layer, and described catalyst comprises following component,
A) the titanium base iron cerium molybdenum vanadium oxides composite of 8%, the mol ratio Ti:Fe:Ce:Mo:V of its each component is 1:0.05:0.05:0.05:0.05;
B) 7% zirconium doping ferric vandate, the mol ratio of Zr:FeVO4 is 0.1:1;
C) the SAPO-34 molecular sieve of surplus.
Described second adsorption element is provided with activated carbon adsorption layer.
CN201510778984.0A 2015-11-14 2015-11-14 A kind of domestic briquet stove flue gas purifying method Pending CN105214482A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510778984.0A CN105214482A (en) 2015-11-14 2015-11-14 A kind of domestic briquet stove flue gas purifying method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510778984.0A CN105214482A (en) 2015-11-14 2015-11-14 A kind of domestic briquet stove flue gas purifying method

Publications (1)

Publication Number Publication Date
CN105214482A true CN105214482A (en) 2016-01-06

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CN201510778984.0A Pending CN105214482A (en) 2015-11-14 2015-11-14 A kind of domestic briquet stove flue gas purifying method

Country Status (1)

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CN (1) CN105214482A (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1256354A (en) * 1998-12-04 2000-06-14 杜成林 Motor vehicle purifier to eliminate smoke, reduce noise, prevent fire and dedust
CN201361519Y (en) * 2008-12-09 2009-12-16 抚顺凯特利机电化工有限公司 Hydrocarbon removing air purifier
CN102421505A (en) * 2009-04-23 2012-04-18 特莱巴赫工业有限公司 Catalyst composition for selective catalytic reduction of exhaust gases
CN102764643A (en) * 2012-07-16 2012-11-07 中国科学院生态环境研究中心 Vanadium-titanium oxide catalyst, and preparation method and application thereof
CN102974340A (en) * 2012-11-22 2013-03-20 中节能六合天融环保科技有限公司 Preparation method of cellular V-Ti low-temperature smoke denitration catalyst
WO2013099253A1 (en) * 2011-12-27 2013-07-04 日揮触媒化成株式会社 Titanium-containing granular powder and method for production thereof, and exhaust gas treatment catalyst using same and method for production thereof
CN204627714U (en) * 2015-05-19 2015-09-09 合肥工业大学 A kind of automobile exhaust gas processing apparatus
CN105032395A (en) * 2015-05-29 2015-11-11 上海大学 Zirconium doped cerium vanadate denitration catalyst, preparation method and application

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1256354A (en) * 1998-12-04 2000-06-14 杜成林 Motor vehicle purifier to eliminate smoke, reduce noise, prevent fire and dedust
CN201361519Y (en) * 2008-12-09 2009-12-16 抚顺凯特利机电化工有限公司 Hydrocarbon removing air purifier
CN102421505A (en) * 2009-04-23 2012-04-18 特莱巴赫工业有限公司 Catalyst composition for selective catalytic reduction of exhaust gases
WO2013099253A1 (en) * 2011-12-27 2013-07-04 日揮触媒化成株式会社 Titanium-containing granular powder and method for production thereof, and exhaust gas treatment catalyst using same and method for production thereof
CN102764643A (en) * 2012-07-16 2012-11-07 中国科学院生态环境研究中心 Vanadium-titanium oxide catalyst, and preparation method and application thereof
CN102974340A (en) * 2012-11-22 2013-03-20 中节能六合天融环保科技有限公司 Preparation method of cellular V-Ti low-temperature smoke denitration catalyst
CN204627714U (en) * 2015-05-19 2015-09-09 合肥工业大学 A kind of automobile exhaust gas processing apparatus
CN105032395A (en) * 2015-05-29 2015-11-11 上海大学 Zirconium doped cerium vanadate denitration catalyst, preparation method and application

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