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CN105176415A - Adhesive with strong cohesiveness - Google Patents

Adhesive with strong cohesiveness Download PDF

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Publication number
CN105176415A
CN105176415A CN201510601088.7A CN201510601088A CN105176415A CN 105176415 A CN105176415 A CN 105176415A CN 201510601088 A CN201510601088 A CN 201510601088A CN 105176415 A CN105176415 A CN 105176415A
Authority
CN
China
Prior art keywords
parts
polyolefin resin
burning
following weight
tackifying resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510601088.7A
Other languages
Chinese (zh)
Inventor
杨传长
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Chuangye Mechanical & Electrical Equipment Co Ltd
Original Assignee
Anhui Chuangye Mechanical & Electrical Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Chuangye Mechanical & Electrical Equipment Co Ltd filed Critical Anhui Chuangye Mechanical & Electrical Equipment Co Ltd
Priority to CN201510601088.7A priority Critical patent/CN105176415A/en
Publication of CN105176415A publication Critical patent/CN105176415A/en
Pending legal-status Critical Current

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Abstract

The invention relates to the technical field of adhesives, in particular to an adhesive with the strong cohesiveness. The adhesive is characterized by comprising, by weight, 40-50 parts of acrylic acid methyl ester, 20-25 parts of chloroprene rubber, 15-25 parts of modified polyolefin resin, 2-3 parts of a 4010 anti-aging agent, 1-2 parts of an antioxidant, 5-10 parts of tackifying resin, 12-17 parts of cyclopropanone and 2-4 parts of a cross-linking agent. According to the modified polyolefin resin, aggregation force of molecules in a glue solution can be enhanced, the glue solution can be easily bonded with the rubber and metal, the intermolecular acting force is enhanced, and therefore the adhesive has the excellent anti-pull function and cohesiveness.

Description

One has strong close-burning tackiness agent
Technical field:
The present invention relates to field of adhesive technology, relate to one in particular and there is strong close-burning tackiness agent.
Background technology:
In the manufacture of hardware & tools; frequent meeting is at the outer gluing one deck elastomeric material of metal handle; handle is made to have certain anti-skid; also feel can be promoted in addition; but often can obscission be there is in this handle; namely rubber and metal separation come, and this throw such as special screwdriver, is especially easily separated.
Summary of the invention:
Technical problem to be solved by this invention is that overcoming existing technological deficiency provides one to have strong close-burning tackiness agent.
Technical problem to be solved by this invention adopts following technical scheme to realize:
One has strong close-burning tackiness agent, it is characterized in that being made up of the raw material of following weight part: 40-50 part methyl acrylate, 20-25 part chloroprene rubber, 15-25 part modified polyolefin resin, 2-3 part 4010 anti-aging agent, 1-2 part antioxidant, 5-10 part tackifying resin, 12-17 part cyclopropanone, 2-4 part linking agent.
Further, described tackifying resin comprises the component of following weight part: 15-20 part tackifying resin RA-65,5-10 part tackifying resin RA, 2-4 part tackifying resin A, by multiple synergy can make the mobility of glue and viscosity better.
Further, described linking agent comprises the component of following weight part: 50-60 part dicumyl peroxide, 2-7 part diphenylmethanediisocyanate, 15-20 part tolylene diisocyanate, 30-35 part isophorone diisocyanate.
Further, described modified polyolefin resin is made up of the raw material of following weight part: 70-80 part polyolefin resin, 2-5 part sodium sulfate, 10-15 part vegetable-protein liquid, 5-8 part diatomite, 1-2 part nitrophenols.
Further, described modified polyolefin resin preparation method is: add alkaline pH adjusting agent after being mixed with vegetable-protein liquid by polyolefin resin, adjust ph is after 8-10, stir 5-10 minute, add acidic ph modifier again, add remaining raw material, adjust ph is after 4-6 simultaneously, stirs 5-10 minute and get final product.
The modified polyolefin resin that the present invention uses can strengthen the cohesion of interior molecules in glue, makes more to be easy to cohere with rubber and metal, intermolecular reactive force is strengthened, thus makes tackiness agent have excellent tensile property and agglutinating value(of coal).
Embodiment:
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1: one has strong close-burning tackiness agent, is characterized in that being made up of the raw material of following weight part: 40 parts of methyl acrylates, 20 parts of chloroprene rubbers, 15 parts of modified polyolefin resins, 2 part of 4010 anti-aging agent, 1 part of antioxidant, 5 parts of tackifying resins, 12 parts of cyclopropanones, 2 parts of linking agents.
Tackifying resin comprises the component of following weight part: 15 parts of tackifying resin RA-65,5 parts of tackifying resin RA, 2 parts of tackifying resin A.
Linking agent comprises the component of following weight part: 50 parts of dicumyl peroxides, 2 parts of diphenylmethanediisocyanates, 15 parts of tolylene diisocyanates, 30 parts of isophorone diisocyanate.
Modified polyolefin resin is made up of the raw material of following weight part: 70 parts of polyolefin resines, 2 parts of sodium sulfate, 10 parts of vegetable-protein liquid, 5 parts of diatomite, 1 part of nitrophenols.
Modified polyolefin resin preparation method is: add alkaline pH adjusting agent after being mixed with vegetable-protein liquid by polyolefin resin, and adjust ph is after 8, stirs 5 minutes, add acidic ph modifier again, add remaining raw material, adjust ph is after 4, stirs 5 minutes and get final product simultaneously.
Embodiment 2: one has strong close-burning tackiness agent, is characterized in that being made up of the raw material of following weight part: 50 parts of methyl acrylates, 25 parts of chloroprene rubbers, 25 parts of modified polyolefin resins, 3 part of 4010 anti-aging agent, 2 parts of antioxidants, 10 parts of tackifying resins, 17 parts of cyclopropanones, 4 parts of linking agents.
Tackifying resin comprises the component of following weight part: 20 parts of tackifying resin RA-65,10 parts of tackifying resin RA, 4 parts of tackifying resin A, by multiple synergy can make the mobility of glue and viscosity better.
Linking agent comprises the component of following weight part: 60 parts of dicumyl peroxides, 7 parts of diphenylmethanediisocyanates, 20 parts of tolylene diisocyanates, 35 parts of isophorone diisocyanate.
Modified polyolefin resin is made up of the raw material of following weight part: 80 parts of polyolefin resines, 5 parts of sodium sulfate, 15 parts of vegetable-protein liquid, 8 parts of diatomite, 2 parts of nitrophenolss.
Modified polyolefin resin preparation method is: add alkaline pH adjusting agent after being mixed with vegetable-protein liquid by polyolefin resin, and adjust ph is after 10, stirs 10 minutes, add acidic ph modifier again, add remaining raw material, adjust ph is after 6, stirs 10 minutes and get final product simultaneously.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.

Claims (5)

1. there is a strong close-burning tackiness agent, it is characterized in that being made up of the raw material of following weight part: 40-50 part methyl acrylate, 20-25 part chloroprene rubber, 15-25 part modified polyolefin resin, 2-3 part 4010 anti-aging agent, 1-2 part antioxidant, 5-10 part tackifying resin, 12-17 part cyclopropanone, 2-4 part linking agent.
2. one according to claim 1 has strong close-burning tackiness agent, it is characterized in that described tackifying resin comprises the component of following weight part: 15-20 part tackifying resin RA-65,5-10 part tackifying resin RA, 2-4 part tackifying resin A.
3. one according to claim 1 has strong close-burning tackiness agent, it is characterized in that described linking agent comprises the component of following weight part: 50-60 part dicumyl peroxide, 2-7 part diphenylmethanediisocyanate, 15-20 part tolylene diisocyanate, 30-35 part isophorone diisocyanate.
4. one according to claim 1 has strong close-burning tackiness agent, it is characterized in that described modified polyolefin resin is made up of the raw material of following weight part: 70-80 part polyolefin resin, 2-5 part sodium sulfate, 10-15 part vegetable-protein liquid, 5-8 part diatomite, 1-2 part nitrophenols.
5. one according to claim 1 has strong close-burning tackiness agent, it is characterized in that described modified polyolefin resin preparation method is: after being mixed with vegetable-protein liquid by polyolefin resin, add alkaline pH adjusting agent, adjust ph is after 8-10, stir 5-10 minute, add acidic ph modifier again, add remaining raw material, adjust ph is after 4-6 simultaneously, stirs 5-10 minute and get final product.
CN201510601088.7A 2015-09-18 2015-09-18 Adhesive with strong cohesiveness Pending CN105176415A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510601088.7A CN105176415A (en) 2015-09-18 2015-09-18 Adhesive with strong cohesiveness

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510601088.7A CN105176415A (en) 2015-09-18 2015-09-18 Adhesive with strong cohesiveness

Publications (1)

Publication Number Publication Date
CN105176415A true CN105176415A (en) 2015-12-23

Family

ID=54898873

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510601088.7A Pending CN105176415A (en) 2015-09-18 2015-09-18 Adhesive with strong cohesiveness

Country Status (1)

Country Link
CN (1) CN105176415A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103834307A (en) * 2012-11-23 2014-06-04 湖北回天胶业股份有限公司 High peel strength acrylate adhesive
CN104449418A (en) * 2014-12-08 2015-03-25 北京天山新材料技术有限公司 Ultrahigh-strength acrylate structural adhesive with wide adhesion and preparation method of ultrahigh-strength acrylate structural adhesive
CN104603222A (en) * 2012-08-16 2015-05-06 罗曼有限合资公司 Adhesive agent having adhesive blend of acrylate and styrene block copolymer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104603222A (en) * 2012-08-16 2015-05-06 罗曼有限合资公司 Adhesive agent having adhesive blend of acrylate and styrene block copolymer
CN103834307A (en) * 2012-11-23 2014-06-04 湖北回天胶业股份有限公司 High peel strength acrylate adhesive
CN104449418A (en) * 2014-12-08 2015-03-25 北京天山新材料技术有限公司 Ultrahigh-strength acrylate structural adhesive with wide adhesion and preparation method of ultrahigh-strength acrylate structural adhesive

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Application publication date: 20151223