CN105010372A - Weeding composition containing stabilizer - Google Patents
Weeding composition containing stabilizer Download PDFInfo
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- CN105010372A CN105010372A CN201410182611.2A CN201410182611A CN105010372A CN 105010372 A CN105010372 A CN 105010372A CN 201410182611 A CN201410182611 A CN 201410182611A CN 105010372 A CN105010372 A CN 105010372A
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- nicosulfuron
- stabilizing agent
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- fatty acid
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Abstract
The invention relates to a weeding composition, in particular to a weeding composition containing a stabilizer. The composition comprises an active component, the stabilizer, a surfactant and a carrier. The weeding composition comprises, by weight percentage, 1-70% of active components, 0.1-20% of stabilizer, 1-30% of surfactant and 1-90% of carrier, wherein the active component is icosulfuron or the combination of nicosulfuron and one or several substances that have herbicidal activity. The herbicidal activity of the composition is not reduced, and the composition is good in safety and stable in physical and chemical properties and can improve thermal stability of nicosulfuron.
Description
Technical field
The present invention relates to Herbicidal combinations, specifically a kind of Herbicidal combinations containing stabilizing agent.
Background technology
Nicosulfuron (chemical name 2-(4,6-dimethoxy-2-pyrimidinyl-amino formamido group sulfonyl)-N, N-dimethyl nicotinamide) is a kind of systemic herbicide.Inventor carries out dispersibling in the preparation series further investigation process of oil-suspending agent and oil-suspending agent containing nicosulfuron, find that the phenomenon of decomposing may appear in nicosulfuron in the process of processing, preparation heat storage resolution ratio (54 ± 2 DEG C, 14d) simultaneously after its processing is higher than 5%.The formulation stabilizer agent screening test containing nicosulfuron single dose and mixture is inventors performed for above produced problem.And Chinese invention patent and document have no this stabilizing agent relevant report.
Summary of the invention
The object of the present invention is to provide the Herbicidal combinations containing stabilizing agent that a kind of herbicidal effect and stability are all good.
For achieving the above object, the present invention adopts technical scheme to be:
Containing a Herbicidal combinations for stabilizing agent, said composition comprises active component, stabilizing agent, surfactant and carrier; Each composition weight percentage composition is as follows: active component 1-70%, stabilizing agent 0.1-20%, surfactant 1-30%, carrier 1-90%;
Wherein, active component be nicosulfuron or nicosulfuron and one or more there is the combination of the material of activity of weeding.
Composition and the weight percentage of each component of preferred described Herbicidal combinations are as follows: active component 1-70%, stabilizing agent 0.1-15%, surfactant 1-25%, carrier 1-90%.Active component be nicosulfuron and one or more there is the combination of the material of activity of weeding.
More preferably the composition of each component of Herbicidal combinations and weight percentage as follows: active component 1-50%, stabilizing agent 0.1-15%, surfactant 1-25%, carrier 20-90%.
The described material with activity of weeding includes but not limited to one or more in Brominal, bromoxynil octanoate, atrazine, sulphur humulone, mesotrione, fluroxypyr, the different monooctyl ester of fluroxypyr, 2.4D butyl ester, 2.4D acid, 2.4D ammonium salt, 2.4D sodium salt, the different monooctyl ester of 2.4D, fluthiacet, prometryn, 2 first 4 chlorine, 2 first 4 chlorine sodium salts, Acetochlor, the third careless amine, butachlor, propisochlor etc.
Described stabilizing agent is selected from methyl alcohol, ethanol, normal propyl alcohol, propane diols, glycerine, isopropyl alcohol, n-butanol, isobutanol, n-amyl alcohol, isoamyl alcohol, lauryl alcohol, polyethylene glycol, sorbierite, xylitol, cellulose, cyclodextrin, mannitol, urea, phosphoamide, percarbamide, Carbamaid peroxide, malonamide, oleamide, coconut oleoyl amine, triethanolamine, ethylenediamine, diisopropylamine etc.Stabilizing agent can be used alone, and two or more also can selecting wherein combinationally use; When combinationally using, adding of they can be selected arbitrarily than row.
Described surfactant is selected from non-ionic surface active agent, is selected from such as fatty alcohol polyethenoxy ether class, alkylphenol polyoxyethylene class, polyoxyethylene nonylphenol ether class, aliphatic amine polyoxyethylene ether class, vegetable and animals oils polyethenoxy ether class, sorbitan monooleate, polyoxyethylene sorbitan fatty acid ester, Crodaret, dioctyl sulphonyl calcium succinate etc.Above-mentioned surfactant can be used alone or as a mixture.
Described carrier is mainly liquid-carrier.Described liquid-carrier is mainly selected from one or more the material mixing in soybean oil, epoxidized soybean oil, butyl oleate, methyl oleate, methylated vegetable oils.Specifically selecting of carrier can be determined according to the active component of associativity weed killer herbicide.
Obtain Herbicidal combinations of the present invention by said components mixing, can be prepared into as required and dispersible oil-suspending agent and oil-suspending agent.Herbicidal combinations of the present invention can by by each component of ormal weight with random order or mix simultaneously, the preparation needed for obtaining with processing method well-known to those skilled in the art.
Herbicidal combinations of the present invention has the following advantages: 1. the former drug stabilisation in composition; 2. the stabilizer function in Herbicidal combinations obviously, improve the stability of active component.3. Herbicidal combinations of the present invention is when conbined usage, does not need to use tank-mix adjuvants.
Embodiment
Following examples are used for the present invention is described in further detail, but are not construed as limiting the invention, and composition of the present invention is only limitted to absolutely not these embodiments.Each raw material involved in formulation Example all has commercially available.Nicosulfuron content 85-99%, rolls over hundred post doses and adds.Each material is measured all by weight and is added.
Formulation Example
Embodiment 14% nicosulfuron dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Urea | 1％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 14% nicosulfuron dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Embodiment 24% nicosulfuron dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Isopropyl alcohol | 5％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 24% nicosulfuron dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Embodiment 34% nicosulfuron dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Isopropyl alcohol | 5％ |
| Urea | 1％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 34% nicosulfuron dispersibles oil-suspending agent (identical with contrast 2)
| The former medicine of nicosulfuron (97%) | 4％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Embodiment 420% nicosulfuron bromoxynil octanoate dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Urea | 1％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 420% nicosulfuron bromoxynil octanoate dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Embodiment 520% nicosulfuron bromoxynil octanoate dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Isopropyl alcohol | 5％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 520% nicosulfuron bromoxynil octanoate dispersibles oil-suspending agent (identical with contrast 4)
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Embodiment 620% nicosulfuron bromoxynil octanoate dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Urea | 1％ |
| Isopropyl alcohol | 5％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 620% nicosulfuron bromoxynil octanoate dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Embodiment 730% nicosulfuron bromoxynil octanoate 24D butyl ester dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| 2.4D butyl ester | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Urea | 1％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 730% nicosulfuron bromoxynil octanoate 2.4D butyl ester dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| 2.4D butyl ester | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Embodiment 830% nicosulfuron bromoxynil octanoate 2.4D butyl ester dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| 2.4D butyl ester | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Isopropyl alcohol | 5％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 830% nicosulfuron bromoxynil octanoate 2.4D butyl ester dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| 2.4D butyl ester | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Embodiment 930% nicosulfuron bromoxynil octanoate 2.4D butyl ester dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| 2.4D butyl ester | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Urea | 1％ |
| Isopropyl alcohol | 5％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 930% nicosulfuron bromoxynil octanoate 2.4D butyl ester dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 4％ |
| Bromoxynil octanoate | 16％ |
| 2.4D butyl ester | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
The different monooctyl ester of embodiment 1030% nicosulfuron bromoxynil octanoate fluroxypyr dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 5％ |
| Bromoxynil octanoate | 15％ |
| The different monooctyl ester of fluroxypyr | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Urea | 1％ |
| Methylated vegetable oils | Polishing to 100% |
The different monooctyl ester of reference examples 1030% nicosulfuron bromoxynil octanoate fluroxypyr dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 5％ |
| Bromoxynil octanoate | 15％ |
| The different monooctyl ester of fluroxypyr | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Embodiment 1130% nicosulfuron bromoxynil octanoate 2.4D butyl ester dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 5％ |
| Bromoxynil octanoate | 15％ |
| The different monooctyl ester of fluroxypyr | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Isopropyl alcohol | 5％ |
| Methylated vegetable oils | Polishing to 100% |
Reference examples 1130% nicosulfuron bromoxynil octanoate 2.4D butyl ester dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 5％ |
| Bromoxynil octanoate | 15％ |
| The different monooctyl ester of fluroxypyr | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
The different monooctyl ester of embodiment 1230% nicosulfuron bromoxynil octanoate fluroxypyr dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 5％ |
| Bromoxynil octanoate | 15％ |
| The different monooctyl ester of fluroxypyr | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Urea | 1％ |
| Isopropyl alcohol | 5％ |
| Methylated vegetable oils | Polishing to 100% |
The different monooctyl ester of reference examples 1230% nicosulfuron bromoxynil octanoate fluroxypyr dispersibles oil-suspending agent
| The former medicine of nicosulfuron (97%) | 5％ |
| Bromoxynil octanoate | 15％ |
| The different monooctyl ester of fluroxypyr | 10％ |
| Sorbitan fatty acid ester | 6％ |
| Polyoxyethylene sorbitan fatty acid ester | 3％ |
| Methylated vegetable oils | Polishing to 100% |
Processing method is sketched: by recipe requirements, first adds in high shear machine roughly grind after former medicine, surfactant, carrier metering, and then injecting sand mill, to be finely ground to material qualified, and discharging is packed.
Also can add white carbon as required in the weed killer herbicide of each formulation of the various embodiments described above preparation, be conducive to the physical stability improving preparation, the such as effect such as thickening or deflocculation.
Physical property and efficacy testing
The stability of test the various embodiments described above preparation, carries out the test of two control samples (being commercially available) simultaneously.Test condition is: store 14 days in 54 ± 2 DEG C of constant temperature ovens.Content after being stored by liquid-phase chromatographic analysis, utilizes following formulae discovery to obtain the resolution ratio of active constituent:
Computing formula: active constituent resolution ratio X is calculated as follows:
In formula:
M
0percentage composition before the storage of ┄ sample heat, %;
M
1percentage composition after the storage of ┄ sample heat, %.
The results are shown in table 1.
Table 1 embodiment and reference examples stability test contrast
As can be seen from the table the former medicine of nicosulfuron dispersible oil-suspending agent nicosulfuron chemical stability under the effect of stabilizing agent well can effectively solve reference examples heat storage resolution problem and reach standard-required at 54 ± 2 DEG C, under 14 days storage requirements, resolution ratio is within 5%.
The activity of weeding of stabilizing agent in addition in the present invention to preparation does not have reducing effect, and show as consistent in the raw survey in indoor and field result, the correction data of such as embodiment and reference examples, this result is not limited to again these data.
Reagent agent was to after the activity test result treatment of piemarker 14 days
Reagent agent was to after the activity test result treatment of barnyard grass 21 days
Claims (7)
1., containing the Herbicidal combinations stablizing component, it is characterized in that: said composition comprises active component, stabilizing agent, surfactant and carrier; Each composition weight percentage composition is as follows: active component 1-70%, stabilizing agent 0.1-20%, surfactant 1-30%, carrier 1-90%;
Wherein, active component be nicosulfuron or nicosulfuron and one or more there is the combination of the material of activity of weeding.
2., by the Herbicidal combinations containing stabilizing agent according to claim 1, it is characterized in that: composition and the weight percentage of each component of described associativity weed killer herbicide are as follows: active component 1-70%, stabilizing agent 0.1-15%, surfactant 1-25%, carrier 1-90%.
3., by the Herbicidal combinations containing stabilizing agent according to claim 1, it is characterized in that:
Described there is activity of weeding material Brominal, bromoxynil octanoate, atrazine, sulphur humulone, mesotrione, fluroxypyr, the different monooctyl ester of fluroxypyr, 2.4D butyl ester, 2.4D acid, 2.4D ammonium salt, 2.4D sodium salt, the different monooctyl ester of 2.4D, fluthiacet, prometryn, 2 first 4 chlorine, 2 first 4 chlorine sodium salts, Acetochlor, the third careless amine, butachlor, one or more in propisochlor.
4., by the Herbicidal combinations containing stabilizing agent described in claim 1 or 2, it is characterized in that: described stabilizing agent is selected from one or more in methyl alcohol, ethanol, normal propyl alcohol, propane diols, glycerine, isopropyl alcohol, n-butanol, isobutanol, n-amyl alcohol, isoamyl alcohol, lauryl alcohol, polyethylene glycol, sorbierite, xylitol, cellulose, cyclodextrin, mannitol, urea, phosphoamide, percarbamide, Carbamaid peroxide, malonamide, oleamide, coconut oleoyl amine, triethanolamine, ethylenediamine, diisopropylamine.
5., by the Herbicidal combinations containing stabilizing agent according to claim 1, it is characterized in that: described surfactant is selected from non-ionic surface active agent.
6., by the Herbicidal combinations containing stabilizing agent according to claim 5, it is characterized in that: described non-ionic surface active agent is selected from one or more in fatty alcohol polyethenoxy ether class, alkylphenol polyoxyethylene class, polyoxyethylene nonylphenol ether class, aliphatic amine polyoxyethylene ether class, vegetable and animals oils polyethenoxy ether class, sorbitan monooleate, polyoxyethylene sorbitan fatty acid ester, Crodaret, dioctyl sulphonyl calcium succinate.
7., by the Herbicidal combinations containing stabilizing agent according to claim 1, it is characterized in that: described carrier is liquid-carrier.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105439718A (en) * | 2015-12-15 | 2016-03-30 | 中山市骏业佳特农业科技有限公司 | Liquid silicon fertilizer and production technology thereof |
| CN106106446A (en) * | 2016-06-20 | 2016-11-16 | 河南中天恒信生物化学科技有限公司 | A kind of plant source high effective additives and synthetic method thereof |
| CN106332895A (en) * | 2016-08-25 | 2017-01-18 | 上海贯发海洋生物科技有限公司 | Iodine oligosaccharide acid-containing synergistic weeding composition and applications thereof |
| CN110063330A (en) * | 2019-06-03 | 2019-07-30 | 江苏省苏科农化有限责任公司 | One kind containing span 80 and the environmentally protective emulsifier of aliphatic amine polymer |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1846499A (en) * | 2005-04-14 | 2006-10-18 | 山东侨昌化学有限公司 | Corn field herbicide |
| WO2007018060A1 (en) * | 2005-08-10 | 2007-02-15 | Ishihara Sangyo Kaisha, Ltd. | Water-based herbicidal suspension of sulfonylurea |
| CN102939980A (en) * | 2012-10-30 | 2013-02-27 | 吉林省八达农药有限公司 | Herbicide composition containing dicamba, nicosulfuron and atrazine, and preparation method thereof |
| CN102972422A (en) * | 2012-10-30 | 2013-03-20 | 辽宁海佳农化有限公司 | Herbicide containing fluroxypyr, nicosulfuron and atrazine and preparation method thereof |
| CN103719129A (en) * | 2014-01-08 | 2014-04-16 | 赵明天 | Herbicide compounded from nicosulfuron, bromoxynil octanoate and fluroxypyr |
-
2014
- 2014-04-30 CN CN201410182611.2A patent/CN105010372A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1846499A (en) * | 2005-04-14 | 2006-10-18 | 山东侨昌化学有限公司 | Corn field herbicide |
| WO2007018060A1 (en) * | 2005-08-10 | 2007-02-15 | Ishihara Sangyo Kaisha, Ltd. | Water-based herbicidal suspension of sulfonylurea |
| CN102939980A (en) * | 2012-10-30 | 2013-02-27 | 吉林省八达农药有限公司 | Herbicide composition containing dicamba, nicosulfuron and atrazine, and preparation method thereof |
| CN102972422A (en) * | 2012-10-30 | 2013-03-20 | 辽宁海佳农化有限公司 | Herbicide containing fluroxypyr, nicosulfuron and atrazine and preparation method thereof |
| CN103719129A (en) * | 2014-01-08 | 2014-04-16 | 赵明天 | Herbicide compounded from nicosulfuron, bromoxynil octanoate and fluroxypyr |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105439718A (en) * | 2015-12-15 | 2016-03-30 | 中山市骏业佳特农业科技有限公司 | Liquid silicon fertilizer and production technology thereof |
| CN106106446A (en) * | 2016-06-20 | 2016-11-16 | 河南中天恒信生物化学科技有限公司 | A kind of plant source high effective additives and synthetic method thereof |
| CN106332895A (en) * | 2016-08-25 | 2017-01-18 | 上海贯发海洋生物科技有限公司 | Iodine oligosaccharide acid-containing synergistic weeding composition and applications thereof |
| CN110063330A (en) * | 2019-06-03 | 2019-07-30 | 江苏省苏科农化有限责任公司 | One kind containing span 80 and the environmentally protective emulsifier of aliphatic amine polymer |
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