CN104998163A - Antibacterial wet tissue paper and manufacturing method thereof - Google Patents
Antibacterial wet tissue paper and manufacturing method thereof Download PDFInfo
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Abstract
The invention relates to antibacterial wet tissue paper and a manufacturing method thereof. The antibacterial wet tissue paper comprises wetting liquid and non-woven materials soaked in the wetting liquid; the non-woven materials are wet tissue paper base paper prepared by papermaking pulp composed of, by weight of fibers, 25-28% of polylactic acid fibers, 4-6% of linen fibers, 3-5% of silk fibers and the balance wood pulp fibers; the wetting liquid is fermentation liquor obtained by performing fermentation cultivation after an appropriate amount of bacillus subtilis is inoculated into the raw materials including, by weight, 5-10 parts of corn stigmas, 15-20 parts of fructus cnidii, 8-10 parts of angelica sinensis, 10-15 parts of radix angelicae, 10-12 parts of radix stemonae, 20-30 parts of folium artemisiae argyi, 5-10 parts of bunge pricklyash leaves, 5-10 parts of rhizoma kaempferiae, 20-30 parts of lespedeza pilosa, 15-20 parts of folium isatidis, 3-5 parts of citric acid, 10-15 parts of coconut oil, 15-20 parts of flavedo and 400-500 parts of water. According to the antibacterial wet tissue paper, the dispersing performance is good, biodegradation can be performed, and multiple bacteria can be inhibited.
Description
Technical field
The present invention relates to a kind of non-woven material, particularly a kind of antibacterial wet tissue paper and manufacture method thereof.
Background technology
Two decades years in the past, nonwovens industry high speed development, technology is maked rapid progress, and nonwovens industry goods enter huge numbers of families, the European and American developed countries that particularly level of consumption is high.With dry, the wet tissue that non-weaving cloth is made, feminine napkin, child's diaper etc., because of cheap, convenient and practical, clean hygiene enters daily life.But the wet tissue used under current used nonwoven product, particularly hygrometric state situation, if be discarded in water closet, can block water closet bottom outlet, household drain pipe and urban sewage pipe system, the inconvenience to city management band.
In order to meet the demand that people live to high-quality, occurred in recent years breaking up type wet tissue, this product softness, moisture content are high, and during use, cleannes are good, can directly drop in lavatory.The definition of breaking up property/type lavatory wet tissue is: refer under the expection service condition of product, can keep the unimpeded of water closet and sewerage system; With System compatible such as existing sewage transport, process, recycling and disposal; Within the rational time, garbage becomes not identifiable design, and environmentally friendly.
Most the broken up type wet tissue washed away can wash away because of its small size in the market.They can move along drainage or soil pipe, but not easily disperse, and therefore may cause the problem of blocking pipeline or filter.
Summary of the invention
The invention provides the antibacterial wet tissue paper that a kind of dispersive property is good, biodegradable, can suppress various bacteria.
The present invention also provides the manufacture method of described antibacterial wet tissue paper.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of antibacterial wet tissue paper, it comprises fountain solution and is immersed in the non-woven material in fountain solution, described non-woven material is by the acid fiber by polylactic of fibre weight 25-28%, the flax fiber of 4-6%, the silk fiber of 3-5%, surplus is the moisture paper tissue papers body paper that the paper making pulp of wood pulp cellulose composition is made, this antibacterial wet tissue paper is not containing the binding agent added and wet strength agent, described fountain solution accesses by the raw material of following weight portion the fermentation liquid obtained after appropriate bacillus subtilis carries out fermentation culture: 5 ~ 10 parts of Stigma Maydis, 15 ~ 20 parts of Fructus Cnidiis, 8 ~ 10 parts of Radix Angelicae Sinensis, 10 ~ 15 parts of Radixs Angelicae Dahuricae, 10 ~ 12 parts of Radixs Stemonae, 20 ~ 30 portions of Folium Artemisiae Argyis, 5 ~ 10 parts of Folium Zanthoxyli Bungeanis, 5 ~ 10 parts of Rhizoma Kaempferiaes, 20 ~ 30 parts of Herba lespedezae pilosaes, 15 ~ 20 portions of Folium Isatidiss, 3 ~ 5 parts of citric acids, 10 ~ 15 portions of Oleum Cocois, 15 ~ 20 parts of Pericarpium Citri junoriss, 400 ~ 500 parts of water.The present invention adds more acid fiber by polylactic in the paper pulp raw material of moisture paper tissue papers body paper, and appropriate flax fiber, improves the tensile strength of moisture paper tissue papers, makes its not cracky in use.
Fountain solution provided by the invention is complete natural herb preparation, and nontoxic to human body, environment, Stigma Maydis contains saponin, alkaloid, fatty wet goods plurality of active ingredients, and its water extract has excellent bactericidal effect, and Stigma Maydis fairly, cheap; Fructus Cnidii, Radix Angelicae Sinensis, the Radix Angelicae Dahuricae, the Radix Stemonae, Folium Artemisiae Argyi, Rhizoma Kaempferiae, Herba lespedezae pilosae, the mutual coordinated of several Chinese medicine of Folium Isatidis, can effectively kill the various pathogenic microorganisms such as staphylococcus aureus, Candida albicans, Pseudomonas aeruginosa, escherichia coli, mycete, bactericidal effect is good, and nontoxic to human body, environment; Citric acid, to adjust fountain solution pH for faintly acid, strengthens the bactericidal effect of fountain solution of the present invention greatly; Folium Zanthoxyli Bungeani is the leaf of Chinese pricklyash, and Pericarpium Zanthoxyli is hot in nature, has pain relieving, insecticidal action.Oleum Cocois is added in the present invention, oils and fats containing a large amount of medium-chain fatty acid composition in Oleum Cocois, medium-chain fatty acid has natural comprehensive antibacterial ability, disinfection effect of the present invention can be improved, the most important thing is, Oleum Cocois has moisturizing, neutralization, can greatly reduce the zest to sensitive skin and wound of the present invention, improve comfort, and Oleum Cocois can also improve stability of the present invention and permeance property; Pericarpium Citri junoris not only has bactericidal action, but also containing abundant natural perfume material, absorption affinity and resistance to oxidation by force, can effectively neutralize and remove the abnormal flavour of skin surface.The subtilin produced in bacillus subtilis thalli growth process, polymyxin, nystatin, Gramicidin isoreactivity material, the conditioned pathogen of these active substances to pathogenic bacterium or autogenous infection has obvious inhibitory action.The present invention is by the mutual Synergistic between each component, and have sterilization, anti-inflammation detumescence, deodouring effect concurrently, cost is low, good stability, nonirritant, to human temperature and, thus make human comfort better, papery softness is durable, not cracky.
Further, the length of described acid fiber by polylactic is 5-12mm, and the length of flax fiber is 8-12mm.
Further, pulverize after Stigma Maydis, Fructus Cnidii, Radix Angelicae Sinensis, the Radix Angelicae Dahuricae, the Radix Stemonae, Folium Artemisiae Argyi, Folium Zanthoxyli Bungeani, Rhizoma Kaempferiae, Herba lespedezae pilosae, Folium Isatidis, Pericarpium Citri junoris mixing according to proportioning, 1 ~ 2h is soaked in ground product, then access bacillus subtilis and carry out shaking table cultivation at 30-37 DEG C, fermentation time is 5-8 hour, gets fermentation liquid and filter after having fermented, and adds citric acid and Oleum Cocois in filtrate, stir, obtain fountain solution.It is the Metabolites Concentration controlling bacillus subtilis that the present invention controls fermentation time object.
A manufacture method for described antibacterial wet tissue paper, by air-flow dry-laying after the mixing of acid fiber by polylactic, flax fiber, silk fiber and wood pulp cellulose, then oven dry, clot, forms non-weaving cloth; Prepare fountain solution by weight, non-weaving cloth is cut, fold, put into plastic bag after soaking completely in fountain solution and seal.
The fibrous web weight that described air-flow dry-laying is formed is 50-100GSM.
Polylactic acid forms with the L-type lactic acid polymerizes of starch, carbohydrate fermentation, acid fiber by polylactic is a kind of synthetic fibers of fully biodegradable, all agricultural product such as Semen Maydis etc., even common plant all can extract Starch Production polylactic acid, in order to break away from the in short supply of petroleum resources, can be analyzed to carbon dioxide and water after its goods are discarded in soil or sea water through microbial action, during burning, can not distribute poison, can not pollute, be a kind of ecological fiber of sustainable development.
Flax fiber is a kind of environment-protection fiber, and flax fiber textile has good health care.It has unique anti-bacteria effect.The hidden savoury herb of linum, can distribute a kind of indistinct fragrance.Expert thinks that this abnormal smells from the patient can kill many antibacterials, and can suppress multiple parasitic growth.Prove with the scientific experiments that contact method is done: lingerie has significant bacteriostasis, to bacillus pyocyaneus, the bacteriostasis rate of the international standard bacterial strains such as Candida albicans can reach more than 65%, exceeds more than 90% to the bacteriostasis rate of escherichia coli and gold-coloured staphylococci pearl.The present invention adds appropriate flax fiber in moisture paper tissue papers body paper, effectively can improve the bactericidal and bacteriostatic effect of product, turn avoid the sense of discomfort that too much flax fiber brings, the addition of flax fiber needs very accurate, many then harsh feeling is strong, has lacked and has not then reached the antibacterial function of Synergistic sterilizing.
Add a small amount of silk fiber, this product can be made more soft durable.
The invention has the beneficial effects as follows: antibacterial wet tissue paper of the present invention, has papery softness durable, not the advantage such as cracky.Through conventional microorganism detection, after this product scrape skin, sterilizing rate can reach more than 98%, all has bactericidal and bacteriostatic effect to common various microorganisms.
Detailed description of the invention
Below by specific embodiment, technical scheme of the present invention is described in further detail.Should be appreciated that enforcement of the present invention is not limited to the following examples, any pro forma accommodation make the present invention and/or change all will fall into scope.
In the present invention, if not refer in particular to, all parts, percentage ratio are unit of weight, and the equipment adopted and raw material etc. all can be buied from market or this area is conventional.Method in following embodiment, if no special instructions, is the conventional method of this area.
The acid fiber by polylactic that the present invention adopts is the ultrashort acid fiber by polylactic of paper grade (stock), and fibre length is 5-12mm; The length of flax fiber and silk fiber is 8-12mm.
Wood pulp, 100% pure Canadian softwood pulp;
Bacillus subtilis, Bai Fude bio tech ltd, Wuxi.
Embodiment 1:
Raw material: the acid fiber by polylactic of 25%, the flax fiber of 5%, 5% silk fiber, the wood pulp cellulose of 65%;
Non-woven production: by air-flow dry-laying after the mixing of acid fiber by polylactic, flax fiber and wood pulp cellulose, then oven dry, clot, forms non-weaving cloth, i.e. antibacterial wet tissue paper body paper; Prepare fountain solution by weight proportion, non-weaving cloth is cut, fold, put into plastic bag after soaking completely in fountain solution and seal.
Fountain solution formula: 10g Stigma Maydis, 20g Fructus Cnidii, 10g Radix Angelicae Sinensis, the 15g Radix Angelicae Dahuricae, the 12g Radix Stemonae, 30g Folium Artemisiae Argyi, 10g Folium Zanthoxyli Bungeani, 10g Rhizoma Kaempferiae, 30g Herba lespedezae pilosae, 20g Folium Isatidis, 5g citric acid, 15g Oleum Cocois, 20g Pericarpium Citri junoris, 500g water.
The preparation method of described fountain solution is as follows: pulverize after Stigma Maydis, Fructus Cnidii, Radix Angelicae Sinensis, the Radix Angelicae Dahuricae, the Radix Stemonae, Folium Artemisiae Argyi, Folium Zanthoxyli Bungeani, Rhizoma Kaempferiae, Herba lespedezae pilosae, Folium Isatidis, Pericarpium Citri junoris mixing according to proportioning, 2h is soaked in ground product, then access bacillus subtilis and carry out shaker fermentation cultivation at 30-37 DEG C, inoculum concentration is 2%, fermentation time is 5 hours, gets fermentation liquid and filter after having fermented, and adds citric acid and Oleum Cocois in filtrate, stir, obtain fountain solution.
Bacillus subtilis carries out fermentation culture again after seed culture medium is cultivated, and seed culture based formulas is: Carnis Bovis seu Bubali cream 3g, peptone 10g, sodium chloride 5g, water 1000ml, pH value about 7.0, inoculum concentration is 2%, seed liquor condition of culture, temperature 37 DEG C, shaking table is cultivated, fermentation time 10-12 hour.
Embodiment 2:
Raw material: the acid fiber by polylactic of 28%, the flax fiber of 6%, 4% silk fiber, the wood pulp cellulose of 62%;
Non-woven production: by air-flow dry-laying after the mixing of acid fiber by polylactic, flax fiber and wood pulp cellulose, then oven dry, clot, forms non-weaving cloth; Prepare fountain solution by weight proportion, non-weaving cloth is cut, fold, put into plastic bag after soaking completely in fountain solution and seal.
Fountain solution formula: 8g Stigma Maydis, 18g Fructus Cnidii, 8g Radix Angelicae Sinensis, the 10g Radix Angelicae Dahuricae, the 12g Radix Stemonae, 28g Folium Artemisiae Argyi, 8g Folium Zanthoxyli Bungeani, 6g Rhizoma Kaempferiae, 25g Herba lespedezae pilosae, 16g Folium Isatidis, 3g citric acid, 10g Oleum Cocois, 15g Pericarpium Citri junoris, 500g water.
The preparation method of described fountain solution is as follows: pulverize after Stigma Maydis, Fructus Cnidii, Radix Angelicae Sinensis, the Radix Angelicae Dahuricae, the Radix Stemonae, Folium Artemisiae Argyi, Folium Zanthoxyli Bungeani, Rhizoma Kaempferiae, Herba lespedezae pilosae, Folium Isatidis, Pericarpium Citri junoris mixing according to proportioning, 2h is soaked in ground product, then access bacillus subtilis and carry out shaker fermentation cultivation at 30-33 DEG C, inoculum concentration is 2%, fermentation time is 8 hours, gets fermentation liquid and filter after having fermented, and adds citric acid and Oleum Cocois in filtrate, stir, obtain fountain solution.
Bacillus subtilis carries out fermentation culture again after seed culture medium is cultivated, and seed culture based formulas is: Carnis Bovis seu Bubali cream 3g, peptone 10g, sodium chloride 5g, water 1000ml, pH value about 7.0, inoculum concentration is 2%, seed liquor condition of culture, temperature 37 DEG C, shaking table is cultivated, fermentation time 10-12 hour.
Embodiment 3:
Raw material: the acid fiber by polylactic of 26%, the flax fiber of 4%, 3% silk fiber, the wood pulp cellulose of 67%;
Non-woven production: by air-flow dry-laying after the mixing of acid fiber by polylactic, flax fiber and wood pulp cellulose, then oven dry, clot, forms non-weaving cloth; Prepare fountain solution by weight proportion, non-weaving cloth is cut, fold, put into plastic bag after soaking completely in fountain solution and seal.
Fountain solution formula: 5g Stigma Maydis, 15g Fructus Cnidii, 8g Radix Angelicae Sinensis, the 10g Radix Angelicae Dahuricae, the 10g Radix Stemonae, 20g Folium Artemisiae Argyi, 5g Folium Zanthoxyli Bungeani, 5g Rhizoma Kaempferiae, 20g Herba lespedezae pilosae, 15g Folium Isatidis, 3g citric acid, 10g Oleum Cocois, 15g Pericarpium Citri junoris, 500g water.The preparation method of described fountain solution is as follows: pulverize after Stigma Maydis, Fructus Cnidii, Radix Angelicae Sinensis, the Radix Angelicae Dahuricae, the Radix Stemonae, Folium Artemisiae Argyi, Folium Zanthoxyli Bungeani, Rhizoma Kaempferiae, Herba lespedezae pilosae, Folium Isatidis, Pericarpium Citri junoris mixing according to proportioning, 2h is soaked in ground product, then access bacillus subtilis and carry out shaker fermentation cultivation at 30-37 DEG C, inoculum concentration is 2%, fermentation time is 6 hours, gets fermentation liquid and filter after having fermented, and adds citric acid and Oleum Cocois in filtrate, stir, obtain fountain solution.
Bacillus subtilis carries out fermentation culture again after seed culture medium is cultivated, and seed culture based formulas is: Carnis Bovis seu Bubali cream 3g, peptone 10g, sodium chloride 5g, water 1000ml, pH value about 7.0, inoculum concentration is 2%, seed liquor condition of culture, temperature 37 DEG C, shaking table is cultivated, fermentation time 10-12 hour.
Comparative example 1:
Raw material: the acid fiber by polylactic of 26%, the flax fiber of 4%, the wood pulp cellulose of 70%;
Non-woven production: by air-flow dry-laying after the mixing of acid fiber by polylactic, flax fiber and wood pulp cellulose, then oven dry, clot, forms non-weaving cloth; Preparation fountain solution, cuts non-weaving cloth, folds, put into plastic bag and seal in fountain solution after soaking completely.
Fountain solution formula: main component is Herba Menthae, Aloe, propylene glycol, second alcohol and water.
Comparative example 2:
Certain brand moisture paper tissue papers commercially available.
The product of Example 1-3 and comparative example 1 and 2 carries out performance test, the results are shown in Table 1.
Table 1
According to the analysis of trier's experience data, moisture paper tissue papers fragrance of the present invention is lastingly soft, and during wiping, flexible body sense is refrigerant comfortable, nonirritant, and moisture paper tissue papers enters water and easily decomposes.
Dry wet strength test: according to GB/T24328.4-2009 toilet paper and goods thereof, the regulation of the 4th part tensile strength measures.
Water absorption rate: measure according to the regulation of FZ/T64012.2-2001.
Breaking up property: measure according to mentioning water-disintegrable non-woven fabrics detecting step in JISP8135-1998, specific as follows:
(1) sample of 100mm × 100mm is cut, dropping into is equipped with in the beaker of 300mL deionized water, magnetic agitation instrument is utilized to stir, rotor speed is 600r/min, timing visual method observes the dispersity of non-weaving cloth, measures the time required when this non-weaving cloth reaches dispersion accordingly.
(2) if the time reaching dispersion at below 150s, be then considered as water and dispersible.Preferred value is below 100s.
For convenience of evaluation of result, according to jitter time with stir after the integrity of cloth cover be classified as 0,1,2,3,4,5 totally 6 ranks.
0 grade---do not disperse after 150s, cloth cover is complete.
1 grade---do not disperse after 100s, after 150s, cloth cover edge is disperseed, but overall cloth cover is complete.
2 grades---start dispersion after 100s, small part dispersion after 150s, a small amount of hole of cloth cover.
3 grades---start dispersion after 100s, major part dispersion after 150s, a large amount of hole of cloth cover.
4 grades---100s rear section disperses, and after 150s, cloth specimen is dispersed into strip.
5 grades---in 100s, cloth specimen is dispersed into bulk completely.
Above-described embodiment is one of the present invention preferably scheme, not does any pro forma restriction to the present invention, also has other variant and remodeling under the prerequisite not exceeding the technical scheme described in claim.
Claims (5)
1. an antibacterial wet tissue paper, it comprises fountain solution and is immersed in the non-woven material in fountain solution, it is characterized in that: described non-woven material is by the acid fiber by polylactic of fibre weight 25-28%, the flax fiber of 4-6%, the silk fiber of 3-5%, surplus is the moisture paper tissue papers body paper that the paper making pulp of wood pulp cellulose composition is made, this antibacterial wet tissue paper is not containing the binding agent added and wet strength agent, described fountain solution accesses by the raw material of following weight portion the fermentation liquid obtained after appropriate bacillus subtilis carries out fermentation culture: 5 ~ 10 parts of Stigma Maydis, 15 ~ 20 parts of Fructus Cnidiis, 8 ~ 10 parts of Radix Angelicae Sinensis, 10 ~ 15 parts of Radixs Angelicae Dahuricae, 10 ~ 12 parts of Radixs Stemonae, 20 ~ 30 portions of Folium Artemisiae Argyis, 5 ~ 10 parts of Folium Zanthoxyli Bungeanis, 5 ~ 10 parts of Rhizoma Kaempferiaes, 20 ~ 30 parts of Herba lespedezae pilosaes, 15 ~ 20 portions of Folium Isatidiss, 3 ~ 5 parts of citric acids, 10 ~ 15 portions of Oleum Cocois, 15 ~ 20 parts of Pericarpium Citri junoriss, 400 ~ 500 parts of water.
2. antibacterial wet tissue paper according to claim 1, is characterized in that: the length of described acid fiber by polylactic is 5-12mm, and the length of flax fiber and silk fiber is 8-12mm.
3. antibacterial wet tissue paper according to claim 1, it is characterized in that the preparation method of described fountain solution is as follows: pulverize after Stigma Maydis, Fructus Cnidii, Radix Angelicae Sinensis, the Radix Angelicae Dahuricae, the Radix Stemonae, Folium Artemisiae Argyi, Folium Zanthoxyli Bungeani, Rhizoma Kaempferiae, Herba lespedezae pilosae, Folium Isatidis, Pericarpium Citri junoris mixing according to proportioning, 1 ~ 2h is soaked in ground product, then access bacillus subtilis and carry out shaking table cultivation at 30-37 DEG C, fermentation time is 5-8 hour, get fermentation liquid after having fermented to filter, citric acid and Oleum Cocois is added in filtrate, stir, obtain fountain solution.
4. a manufacture method for antibacterial wet tissue paper according to claim 1, is characterized in that: by air-flow dry-laying after the mixing of acid fiber by polylactic, flax fiber, silk fiber and wood pulp cellulose, and then oven dry, clot, forms non-weaving cloth; Prepare fountain solution by weight, non-weaving cloth is cut, fold, put into plastic bag after soaking completely in fountain solution and seal.
5. manufacture method according to claim 4, is characterized in that: the fibrous web weight that described air-flow dry-laying is formed is 50-100GSM.
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CN106214042A (en) * | 2016-08-24 | 2016-12-14 | 旌德县万方日用品有限公司 | A kind of Chinese medicine formula of health sterilizing napkin |
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