CN104812362A - Oil-based liquid cleansing composition - Google Patents
Oil-based liquid cleansing composition Download PDFInfo
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- CN104812362A CN104812362A CN201380060335.6A CN201380060335A CN104812362A CN 104812362 A CN104812362 A CN 104812362A CN 201380060335 A CN201380060335 A CN 201380060335A CN 104812362 A CN104812362 A CN 104812362A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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Abstract
The present invention addresses the problem of providing a cleansing agent that is effective in removing eye makeup cosmetic preparations of the emulsion/emulsion resin composite type, eye makeup cosmetic preparations of the oil-based solvent type, and keratotic plugs of the skin. The problem is solved with an oil-based liquid cleansing composition prepared by compounding caprylyl caprylate and/or caprylyl caprate with an oil agent and a polyglycerin fatty acid ester.
Description
Technical field
The present invention relates to oil-based liquid skin cleansing composition.
Background technology
To wash off for the purpose of the dirt of skin, oiliness color make-up cosmetic preparation, gone on the market oil-based liquid skin cleansing composition.Compared with the cream shape of oil-based liquid skin cleansing composition and oil-in-water type, the clean skin composition of emulsion form or the clean skin composition of the aqueous gel of aqueous, clean skin excellent effect.
But, develop the various color make-up cosmetic preparations that cosmetic retentivity is good compared with cosmetics in the past in recent years, thus expect the oil-based liquid skin cleansing composition adapted with it.
Especially eye color make-up cosmetic preparation has developed that a large amount of cosmetic retentivity is good, excellent preparation.Wherein, roughly divide and there is the different preparation of two kinds of characteristics.
One type is the preparation being called as " oil-based solvent type ", and it is by resin dispersion strong for tack or the preparation being dissolved in volatility oil preparation, and waterproof effect is strong.
As having of " oil-based solvent type " eye color make-up cosmetic preparation: the eye color make-up cosmetic preparation (patent documentation 1: Japanese Unexamined Patent Publication 7-196449 publication) containing trimethylsiloxysilicate, acrylic acid-silicone based graft copolymer, low boiling organic silicone oil; Oil eyelashe containing rosin esterification compound, oil-soluble resin, volatility oil preparation cosmetic preparation (patent documentation 2: Japanese Unexamined Patent Publication 2009-114099 publication) etc.
Another kind of type be coordinated as " the emulsion resin type " of the water system emulsion polymer of tunicle forming agent and emulsion and emulsion resin also with the preparation being called as " emulsion emulsion resin is compound " of type.
As having of " emulsion emulsion resin is compound " eye color make-up cosmetic preparation: the oil-in-water type cosmetic for sticking to keratin fiber (patent documentation 3: Japanese Unexamined Patent Publication 2010-77042 publication) etc. containing alkylol acrylamide acid esters vinyl acetate copolymer emulsion, alkylol acrylamide acid ester copolymer emulsion, carbon black, polyhydric alcohol, water solublity peel-forming agent.
The preparation of this two type is called as cosmetic retentivity the most general good dosage form (non-patent literature 1).In order to remove the former " oil-based solvent type " eye color make-up cosmetic preparation, if do not coordinate the oil preparation high with this cosmetic preparation intermiscibility in a large number, then removal effect can not be obtained.The eye color make-up cosmetic preparation of " emulsion resin type " and " emulsion emulsion resin is compound " is commercially referred to as " film type " on the other hand, and available hot water, water solubility scour are removed.
Be somebody's turn to do " emulsion resin type " and " emulsion emulsion resin is compound " although the cleaning of available hot water, water solubility scour is removed, with regard to oil-based liquid skin detergents, solidification can be produced and become the problem being difficult to wash off on the contrary.Therefore, the oil-based liquid skin cleansing composition of the removal excellence of " emulsion resin type " and " emulsion emulsion resin is compound " eye color make-up cosmetic preparation is expected.If such oil-based liquid skin detergents, then can be used as the makeup removing of all eye cosmetics and oiliness color make-up cosmetic preparation.But preparation desirable so is not yet provided.
Prior art document
Patent documentation
Patent documentation 1 Japanese Unexamined Patent Publication 07-196449 publication
Patent documentation 2 Japanese Unexamined Patent Publication 2009-114099 publication
Patent documentation 3 Japanese Unexamined Patent Publication 2010-077042 publication
Non-patent literature
Non-patent literature 1 functional cosmetics IV (Japanese original name: Machine energy property cosmetics IV), 114 ~ 115 pages, Co., Ltd. C MC publishes, the 1st printing distribution on June 30th, 2006
Summary of the invention
Problem of the present invention is to provide a kind of oil-based liquid skin cleansing composition, and it plays a role to emulsion emulsion resin compound eye color make-up cosmetic preparation and oil-based solvent type eye color make-up cosmetic preparation.
Main composition of the present invention is as follows.
(1) an oil-based liquid skin cleansing composition, is characterized in that, containing octyl octanoate and/or octyl.
(2) the oil-based liquid skin cleansing composition Gen Ju (1), is characterized in that, the content of octyl octanoate and/or octyl is 2 ~ 50 quality %.
(3) according to (1) or the oil-based liquid skin cleansing composition described in (2), it is characterized in that, comprise octyl octanoate and/or octyl, oil preparation and surfactant.
(4) the oil-based liquid skin cleansing composition Gen Ju (3), is characterized in that, oil preparation is aqueous or pasty state at 25 DEG C.
(5) the oil-based liquid skin cleansing composition Gen Ju (3), it is characterized in that, surfactant contains polyglyceryl fatty acid ester.
(6) according to the oil-based liquid skin cleansing composition according to any one of (3) ~ (5), it is characterized in that, polyglyceryl fatty acid ester is selected from the different pelargonate of polyglycereol-20 eight, the different pelargonate of polyglycereol-20 six, the different pelargonate of polyglycereol-20 seven, polyglycereol-20 six caprylate, polyglycereol-20 eight caprylate, polyglycereol-20 ten caprylate, polyglycereol-20 15 caprylate, polyglycereol-20 six decanoin, polyglycereol-20 eight decanoin, Natrulon H-10 diisopstearate, Natrulon H-10 isostearate, Natrulon H-10 three isostearate, Natrulon H-10 decanoin, polyglycereol-5 laurate, polyglycereol-2 decanoin, polyglycereol-6 caprylate, Natrulon H-10 caprylate, more than a kind in polyglycereol-2 caprylate.
(7) according to the oil-based liquid skin cleansing composition according to any one of (3) ~ (6), it is characterized in that, the content of polyglyceryl fatty acid ester is 1 ~ 40 quality %.
(8) according to oil-based liquid skin cleansing composition according to any one of (3) ~ (7), it is characterized in that, also comprise the diester oil that unitary branched chain fatty acid and dihydroxylic alcohols are formed.
(9) the oil-based liquid skin cleansing composition Gen Ju (8), is characterized in that, the diester oil that unitary branched chain fatty acid and dihydroxylic alcohols are formed is two different n-nonanoic acid butanediol esters.
Can provide a kind of skin cleansing composition according to the present invention, it has stronger cleansing power to both emulsion emulsion resin compound eye color make-up cosmetic preparation and oil-based solvent type eye color make-up cosmetic preparation.
Further, the pore dirt of compositions of the present invention removes that excellent, the available wet hands of property uses, washability is excellent, and have both through time storage stability.
Accompanying drawing explanation
Fig. 1 is the chart of the clearance of the compound eye cosmetic of emulsion emulsion resin representing the oil-based liquid skin cleansing composition adopting embodiment 1, comparative example 1 ~ 16.
Fig. 2 is the chart of the clearance of the oil-based solvent type eye cosmetic representing the oil-based liquid skin cleansing composition adopting embodiment 1, comparative example 1 ~ 16.
Fig. 3 is the chart of the measurement result of the particle size distribution of the O/W emulsifying particle diameter represented when to add large water gaging in the skin cleansing composition of embodiment 2.
Fig. 4 is the chart of the measurement result of the particle size distribution of the O/W emulsifying particle diameter represented when to add large water gaging in the skin cleansing composition of comparative example 17.
Fig. 5 is the chart of the result of the keratotic plug dissolution rate representing mensuration embodiment 2, comparative example 18,19.
Fig. 6 is the chart of the result of the skin water loss amount representing mensuration embodiment 2, comparative example 18,19.
Detailed description of the invention
Oil-based liquid clean skin oil is using aqueous oil preparation as main component, and wherein a small amount of matching surface activating agent etc. thus make skin dirt, cosmetic preparation is easy to the preparation that cleans and rinse.
Present inventor finds, as oil-based liquid clean skin oil composition composition, the compositions comprising octyl octanoate and/or octyl is not only excellent to the removal of oiliness color make-up cosmetic preparation, and also excellent to the removal of emulsion resin type, emulsion emulsion resin compound eye color make-up cosmetic preparation.
The octyl octanoate used in the present invention, octyl are known material as ester oil, are used as the oiliness improver of cosmetics.This compound can be used alone or use both mixture.Octyl octanoate is sold with trade name Cetiol 88 by BASF JAPAN company, can use these commodity.The miscella of octyl octanoate, octyl is marked as (caprylic/capric) monooctyl ester.(caprylic/capric) monooctyl ester is also sold with trade name Cetiol RLF by BASFJAPAN company.
The use level of octyl octanoate and/or octyl is preferably 2 ~ 50 quality % in the clean skin oil of oil-based liquid.When being less than 2 quality %, there is the situation of the removal capacity difference of color make-up cosmetic preparation.
In the clean skin oil of oil-based liquid of the present invention, as long as the oil preparation coordinated in the clean skin oil of routine all can use.Be preferably used in the oil preparation for aqueous or pasty state at 25 DEG C.As being oil preparation that is aqueous or pasty state at 25 DEG C, such as ester oil, organic silicone oil, vegetable and animals oils, hydrocarbon ils, higher fatty acids, higher alcohol etc. can be enumerated.
In addition, owing to coordinating organic silicone oil can improve cleansing power, so preferably as the oil preparation of synthesis.Polydimethylsiloxane, diphenyl silicon oxygen base phenyl trimethicone, caprylyl methicone etc. can be enumerated as organic silicone oil.
Olive oil, jojoba wet goods can be enumerated as vegetable and animals oils, can liquid paraffin, squalane etc. be enumerated as hydrocarbon ils, can isostearic acid, oleic acid etc. be enumerated as higher fatty acids, can octyldodecanol, oleyl alcohol etc. be enumerated as higher alcohol.
What the present invention used be aqueous or the oil preparation of pasty state and the total use level of octyl octanoate and/or octyl at 25 DEG C, relative to the total amount of oil-based liquid skin cleansing composition, and preferably 40 ~ 95 quality %.During lower than 40 quality %, lack the effect that color make-up cosmetic preparation is appeared in one's mind from skin; When being greater than 95 quality %, be difficult to rinse after color make-up cosmetic preparation is merged.
Polyglyceryl fatty acid ester is used in the present invention.As polyglyceryl fatty acid ester, the different pelargonate of polyglycereol-20 eight can be enumerated, the different pelargonate of polyglycereol-20 six, the different pelargonate of polyglycereol-20 seven, polyglycereol-20 six caprylate, polyglycereol-20 eight caprylate, polyglycereol-20 ten caprylate, polyglycereol-20 15 caprylate, polyglycereol-20 six decanoin, polyglycereol-20 eight decanoin, Natrulon H-10 diisopstearate, Natrulon H-10 isostearate, Natrulon H-10 three isostearate, Natrulon H-10 decanoin, polyglycereol-5 laurate, polyglycereol-2 decanoin, polyglycereol-6 caprylate, Natrulon H-10 caprylate, polyglycereol-2 caprylate etc.
The use level of polyglyceryl fatty acid ester that the present invention uses, relative to whole compositions of oil-based liquid skin cleansing composition of the present invention, preferably in 1 ~ 40 quality %, range fit particularly preferably in 5 ~ 25 quality %.
During lower than 1 quality %, cleaning, the washing property of compositions are insufficient; When being greater than 40 quality %, occur sometimes to produce the problems such as stimulation to skin when can not keep oil-based liquid, use because mobility is deteriorated.
In oil-based liquid skin cleansing composition of the present invention, the non-ionic surface active agent except polyglyceryl fatty acid ester can be coordinated.Such as polyoxyethylene alkyl ether class, isostearic acid polyoxyethylene (10) ether, octyl dodecanol polyoxyethylene (10) ether etc. can be coordinated; As fatty acid esters of sorbitan class, sorbitan isostearate, sorbitan laurate, anhydro sorbitol coconut oil fat acid esters etc. can be coordinated; As cithrol class, Polyethylene Glycol (8) isostearate, Polyethylene Glycol (10) oleate etc. can be coordinated; As polyoxyethylene castor oil class, Polyethylene Glycol (30) hydrogenated castor wet goods can be coordinated; As polyoxyethylene sorbitan fatty acid ester class, Polyethylene Glycol (20) anhydro sorbitol coconut oil fat acid esters etc. can be coordinated; As polyoxyethylene glycerol ether fatty acid ester, isostearic acid Polyethylene Glycol (40) glyceride, three isostearic acid Polyethylene Glycol (30) glyceride etc. can be coordinated.
In addition, in oil-based liquid skin cleansing composition of the present invention, except nonionic surfactant, anionic surfactant, cationic surfactant, amphoteric surfactant can also be coordinated in the scope not hindering effect of the present invention.
In oil-based liquid skin cleansing composition of the present invention, oiliness viscosifier can be coordinated.As oiliness viscosifier, stearic acid inulin, behenic acid/eicosane diacid glyceride, dextrin cetylate, dextrin (cetylate/caprylate) etc. can be enumerated.
In oil-based liquid skin cleansing composition of the present invention, if the diester that use unary fatty acid and dihydroxylic alcohols are formed is as ester oil, then improve with the intermiscibility of color make-up cosmetic preparation, thus play excellent cleaning performance, improve flushing performance simultaneously.As unary fatty acid, 2 ethyl hexanoic acid, different n-nonanoic acid, caproic acid, sad, capric acid etc. can be enumerated.In unary fatty acid, the cleansing power of the diester oil that the branched chain fatty acid such as 2 ethyl hexanoic acid, different n-nonanoic acid and dihydroxylic alcohols are formed is more excellent, and in addition, the performance used with wet hands is more excellent.Ethylene glycol, propylene glycol, 1,3 butylene glycol, dipropylene glycol, neopentyl glycol, 1,2-pentanediol etc. can be enumerated as dihydroxylic alcohols.In dihydroxylic alcohols, because propylene glycol, 1,3 butylene glycol, dipropylene glycol can obtain higher cleansing power, so preferably.
As the diester oil that unitary branched chain fatty acid and dihydroxylic alcohols are formed, specifically can enumerate two 2 ethyl hexanoic acid glycol esters, two 2 ethyl hexanoic acid propylene glycol esters, two 2 ethyl hexanoic acids 1,3-butanediol ester, two 2 ethyl hexanoic acid dipropylene glycol esters, two 2 ethyl hexanoic acid DOPCP, two 2 ethyl hexanoic acids 1,2-pentadiol ester, two different n-nonanoic acid glycol esters, two different n-nonanoic acid propylene glycol esters, two different n-nonanoic acids 1,3-butanediol ester (indicating title: two different n-nonanoic acid BG), two different n-nonanoic acid dipropylene glycol esters, two different n-nonanoic acid DOPCP, two different n-nonanoic acid 1,2-pentadiol esters etc.
In addition, in the scope not damaging effect of the present invention, various raw materials conventional in cosmetics can be coordinated, such as, polyalcohols, polyalkylene glycols, saccharide, lower alcohols, high score subclass, organic and inorganic powdery type and the functional component such as antiseptic, antioxidant.
In addition, also can hydrous water in oil-based liquid skin cleansing composition of the present invention.If but a large amount of hydrous water, water can not completely in wrap in oil phase, can O/W emulsion composition be formed.During hydrous water, preferably coordinate and become below 20 quality %.
Embodiment
Below illustrate that embodiment, comparative example and test example are described in detail the present invention and action effect thereof.
1. embodiment 1
The preparation of oil-based liquid skin cleansing composition
In advance, make the standard prescription of skin cleansing composition, and it can be used as basic prescription, it take oil preparation as main component, confirms the cleaning performance had for oiliness lipstick etc., and not for the cleaning performance of the compound mascara of emulsion emulsion resin.
[table 1]
Clean skin oil composition
The various oil preparationes shown in table 2 are added in this basic prescription, thus the oil-based liquid skin cleansing composition of preparation embodiment 1, comparative example 1 ~ comparative example 16.
[table 2]
The oil preparation guide look added
| Indicate title | |
| Embodiment 1 | (caprylic/capric) monooctyl ester |
| Comparative example 1 | Thylhexoic acid spermaceti alcohol ester |
| Comparative example 2 | Two different n-nonanoic acid BG |
| Comparative example 3 | Sad Propylheptyl |
| Comparative example 4 | Two (caprylic capric) propylene glycol ester |
| Comparative example 5 | Succinic acid ethylhexyl |
| Comparative example 6 | Different n-nonanoic acid isotridecanol |
| Comparative example 7 | IPIS |
| Comparative example 8 | Isostearyl isostearate ester |
| Comparative example 9 | Thylhexoic acid alkyl (14,16,18) ester |
| Comparative example 10 | Dicaprylyl carbonate |
| Comparative example 11 | Diphenyl silicon oxygen base phenyl trimethicone |
| Comparative example 12 | Caprylyl methicone |
| Comparative example 13 | Polydimethylsiloxane |
| Comparative example 14 | Hydrogenated polydecene |
| Comparative example 15 | Hydrogenation gathers (C6-12 alkene) |
| Comparative example 16 | Parleam |
Oil components, activating agent are heated to 80 DEG C, is uniformly mixed with disperser, is cooled to room temperature, to prepare oil-based liquid skin cleansing composition.
< evaluation test 1> is to the effect of water-emulsifiable liquid emulsion resin compound eye color make-up cosmetic preparation
Buy the eyeliner (Eye Liner) of commercially available representative R Inc., for test.R Products is representative " emulsion emulsion resin is compound " eye color make-up cosmetic preparation, and for having coordinated the O/W preparation of acrylic acid (ester) the analog copolymer ammonium as peel-forming agent.
Clean skin ability is measured according to following test sequence.
(1) sticking two-faced adhesive tape in resin test piece, then the ivory white dermatine (" soft semi lina " (Japanese original name: ソ Off ト セ ミ リ mono-Na)) pasting 30 × 60mm.
(2) colour examining (angle of light 45 degree, mensuration 0 degree, angle) (being designated as L* (2), a* (2), b* (2)) is carried out by the L*a*b* value of spectrophotometric color measurement instrument to dermatine.
(3) weight of having pasted the resin test piece of dermatine is measured.
(4) on dermatine, paste the plastics adhesive tape manufacturing (TEPRA Tape) being drilled with 10mm φ hole.
(5) the R Inc. eyeliner that even spread is commercially available in the hole of TEPRA Tape.
(6) TEPRA Tape is peeled off.
(7) measure the weight of test piece, from the coating eyeliner that measures (3) before the difference of weight try to achieve the weight of eyeliner, be that the test piece of 0.001g is used for testing by the weight of eyeliner.
(8) eyeliner is made at 25 DEG C dry 1 hour.
(9) colour examining (angle of light 45 degree, mensuration 0 degree, angle) (being designated as L* (9), a* (9), b* (9)) is carried out by the L*a*b* value of spectrophotometric color measurement instrument to the dermatine after coating eyeliner.
(10) on the pedestal of JamesHHeal Inc. of Britain Martindale (Martindale) testing machine (MiniMartindale), paste dermatine beyond test piece (material be pasted onto in resin test piece identical), immediately below the guide rod by pressurizing resin test piece, drip each oil-based liquid skin cleansing composition of 0.1mL.
(11) use guide rod with 15g/cm
2load by test piece by being pressed on the dermatine of pedestal, come and go 50 times (6cm come and go about 2 minutes) with speed change pattern 0.5 speed.
(12) take off test piece, wipe the dirt of the dermatine of pedestal with ethanol.
(13) on the dermatine of the pedestal cleaned up, 0.2mL pure water is dripped.
(14) use guide rod with 15g/cm
2load by test piece by being pressed on the dermatine of pedestal, with speed change pattern 0.5 speed come and go 10 times.
(15) take off test piece, will dirt washer bottle residual on the dermatine of test piece be affixed on distilled water flushing.
(16) dermatine is peeled and natural drying from test piece, carry out colour examining (angle of light 45 degree, mensuration 0 degree, angle) (being designated as L* (16), a* (16), b* (16)) by the L*a*b* value of spectrophotometric color measurement instrument to the part being coated with eyeliner.
(17) measured color value L* (2), a* (2), the b* (2) before the eyeliner coating of (2) is used, (9) measured color value L* (9), a* (9), b* (9) after eyeliner coating, measured color value L* (16), a* (16) after the eyeliner removal of (16), b* (16) calculate the clearance of eyeliner by following formula.And clearance is tried to achieve by the meansigma methods that three times measure.
Be coated with the aberration (R1) of the dermatine after eyeliner and the dermatine before coating eyeliner
R1＝[(L*(9)-L*(2))
2+(a*(9)-a*(2))
2+(b*(9)-b*(2))
2]1/2
The aberration (R2) of dermatine after dermatine after cleaning and coating eyeliner
R2＝[(L*(16)-L*(9))
2+(a*(16)-a*(9))
2+(b*(16)-b*(9))
2]1/2
Clearance=(R2/R1) * 100 (%) of eyeliner
The clearance of the compound eyeliner of emulsion emulsion resin of the oil-based liquid skin cleansing composition of embodiment 1, comparative example 1 ~ 16 is as shown in table 3, Fig. 1.
[table 3]
The clearance of the compound eyeliner of emulsion emulsion resin
| Clearance (%) | σ (deviation) | |
| Embodiment 1 | 36.51 | 5.35 |
| Comparative example 1 | 15.42 | 5.36 |
| Comparative example 2 | 20.21 | 4.25 |
| Comparative example 3 | 16.78 | 2.68 |
| Comparative example 4 | 18.80 | 3.62 |
| Comparative example 5 | 14.01 | 2.92 |
| Comparative example 6 | 13.44 | 6.82 |
| Comparative example 7 | 10.94 | 3.11 |
| Comparative example 8 | 19.33 | 3.38 |
| Comparative example 9 | 13.81 | 2.14 |
| Comparative example 10 | 17.01 | 6.42 |
| Comparative example 11 | 17.38 | 3.66 |
| Comparative example 12 | 10.74 | 5.34 |
| Comparative example 13 | 22.84 | 5.84 |
| Comparative example 14 | 9.29 | 4.48 |
| Comparative example 15 | 13.89 | 5.17 |
| Comparative example 16 | 12.31 | 5.35 |
Eyeliner clearance when using the clean skin of oil-based liquid of the cooperation of embodiment 1 (caprylic/capric) monooctyl ester oily is 36.5%.On the other hand, specify that compared with being the removal effect of 9.3% ~ 22.8% with the clearance of eyeliner during skin fluid composition clean as the oil-based liquid employing comparative example 1 ~ 16, high 2 ~ 4 times.
The removal effect of < evaluation test 2> oil-based solvent type eye color make-up cosmetic preparation (mascara)
Buy commercially available representative S Inc. mascara, for test.S Products is representative " oil-based solvent type " eye color make-up cosmetic preparation, for containing the trimethylsiloxysilicate as the strong resin of tack, and containing the oil-based solvent type preparation as the Fancol ID of volatility oil preparation.
According to the clean skin ability of the sequential determination same with evaluation test 1.
The clearance of the oil-based solvent type mascara of the oil-based liquid skin cleansing composition of embodiment 1, comparative example 1 ~ 16 is as shown in table 4, Fig. 2.
[table 4]
The clearance of oil-based solvent type mascara
| Clearance (%) | σ (deviation) | |
| Embodiment 1 | 71.36 | 5.99 |
| Comparative example 1 | 58.89 | 8.72 |
| Comparative example 2 | 64.76 | 6.77 |
| Comparative example 3 | 47.20 | 18.42 |
| Comparative example 4 | 68.63 | 2.02 |
| Comparative example 5 | 45.93 | 8.09 |
| Comparative example 6 | 53.57 | 10.22 |
| Comparative example 7 | 61.56 | 10.20 |
| Comparative example 8 | 48.41 | 13.12 |
| Comparative example 9 | 54.37 | 14.80 |
| Comparative example 10 | 60.57 | 18.50 |
| Comparative example 11 | 51.39 | 6.48 |
| Comparative example 12 | 48.73 | 6.96 |
| Comparative example 13 | 54.47 | 5.65 |
| Comparative example 14 | 65.42 | 11.25 |
| Comparative example 15 | 57.02 | 15.04 |
| Comparative example 16 | 58.69 | 6.93 |
When using the cooperation of the embodiment 1 oil-based liquid skin cleansing composition of (caprylic/capric) monooctyl ester, the removal effect of S Inc. mascara is best.Although the compositions of comparative example is poorer than embodiment, also there is the removal effect of solvent-borne type mascara.
From the result of above evaluation test 1, evaluation test 2, compositions of the present invention all has stronger clean skin ability for any one in water miscible eyeliner, solvent type mascara.
The < evaluation test 3> usability evaluation of wet hands
Implement the evaluation that can use with wet hands evaluated as the usability of skin detergents.Respectively take 3.5g embodiment 1, the oil-based liquid skin cleansing composition of comparative example 1 ~ 16 is placed in test tube, add 0.105g water, visual assessment transparency.If transparent, then water-soluble enter in oil-based liquid skin cleansing composition, thus become the index that can play clean skin function.
Its evaluation of result is: embodiment 1, comparative example 1 ~ 16 all do not produce nebulousurine, all has the function that available wet hands uses.
The evaluation of " smoothening " characteristic of < evaluation test 4> skin cleansing composition
As the performance of skin detergents, " smoothening " when skin is coated with is important assessment item.The amalgamation smoothening excellent skin detergents and skin is good, and the removal effect of dirt might as well.
Used the oil-based liquid skin cleansing composition of embodiment 1, comparative example 1 ~ 16 by 10 professional judging panels, and with comparative example 1 for standard, be designated as 2 points when " smoothening " is excellent, time identical with comparative example 1 " smoothening ", be designated as 1 point, during " smoothening " difference, be designated as 0 point.
Calculate its average mark, " smoothen " Optimality according to following standard evaluation.
◎: " smoothening " Optimality be equally divided into more than 1.5 points
Zero: the average mark of " smoothening " Optimality, more than 0.5 point, is less than 1.5 points
×: " smoothening " Optimality be equally divided into less than 0.5 point
Result is as shown in table 5.
[table 5]
" smoothening " evaluation result of skin cleansing composition
| Oil-based liquid skin cleansing composition | Smoothen |
| Embodiment 1 | ◎ |
| Comparative example 1 | Standard |
| Comparative example 2 | ◎ |
| Comparative example 3 | ◎ |
| Comparative example 4 | ◎ |
| Comparative example 5 | ○ |
| Comparative example 6 | ◎ |
| Comparative example 7 | × |
| Comparative example 8 | × |
| Comparative example 9 | ○ |
| Comparative example 10 | ◎ |
| Comparative example 11 | ○ |
| Comparative example 12 | ○ |
| Comparative example 13 | × |
| Comparative example 14 | × |
| Comparative example 15 | × |
| Comparative example 16 | × |
The compositions of embodiment 1 shows clean skin characteristic necessary good " smoothening ".
The storage stability test of < evaluation test 5> skin cleansing composition
At 25 DEG C, the compositions 3 months of keeping embodiment 1, comparative example 1 ~ 16, observes solution state.Appearance uniform be evaluated as "○", produce be separated, precipitation be evaluated as "×".
Result is as shown in table 6.
[table 6]
The storage stability evaluation result of 25 DEG C
| Oil-based liquid skin cleansing composition | Stability |
| Embodiment 1 | ○ |
| Comparative example 1 | ○ |
| Comparative example 2 | ○ |
| Comparative example 3 | ○ |
| Comparative example 4 | × |
| Comparative example 5 | × |
| Comparative example 6 | ○ |
| Comparative example 7 | ○ |
| Comparative example 8 | ○ |
| Comparative example 9 | ○ |
| Comparative example 10 | ○ |
| Comparative example 11 | ○ |
| Comparative example 12 | ○ |
| Comparative example 13 | ○ |
| Comparative example 14 | ○ |
| Comparative example 15 | ○ |
| Comparative example 16 | × |
Can confirm that the compositions of embodiment 1 is stable at 25 DEG C.
From evaluation test 3,4,5, the compositions of embodiment 1, except clean skin ability, also has as the necessary key property of skin detergents, namely with characteristic, the Optimality of " smoothening ", ageing stability that wet hands uses.
2. embodiment 2
The oil-based liquid skin cleansing composition of preparation embodiment 2, said composition with the addition of the two different n-nonanoic acid 1,3 butylene glycol esters (indicating title: two different n-nonanoic acid BG) of the diester oil formed as unitary branched chain fatty acid and dihydroxylic alcohols.In addition in order to the effect of the compositions of Evaluation operation example 2, the thylhexoic acid spermaceti alcohol ester of preparation isodose replaces the compositions (comparative example 17) of two different n-nonanoic acid BG, and evaluation effect.
[table 7]
| Composition name (sign title) | Embodiment 2 | Comparative example 17 |
| Thylhexoic acid spermaceti alcohol ester | 50 | 70 |
| Two different n-nonanoic acid BG | 20 | - |
| Diphenyl silicon oxygen base phenyl trimethicone | 3 | 3 |
| Polydimethylsiloxane | 2 | 2 |
| (caprylic/capric) monooctyl ester | 5 | 5 |
| Dicaprylyl carbonate | - | - |
| Natrulon H-10 diisopstearate | 10 | 10 |
| The different pelargonate of polyglycereol-20 eight | 5 | 5 |
| Polyglycereol-20 six caprylate | 5 | 5 |
The mensuration of < evaluation test 6>O/W emulsifying particle diameter
In order to evaluate easy washability, to the oil-based liquid skin cleansing composition of embodiment 2 and comparative example 17, measure O/W emulsifying particle diameter when adding large water gaging.Assay method is as follows.
(1) in 0.5g oil-based liquid skin cleansing composition, add the pure water of 50mL, and stir.
(2) the emulsifying particle diameter of the mixed liquor of (1) is measured with laser diffraction formula particle size distribution device (Britain Malvern Instruments Ltd. Mastersizer 2000).
As shown in Figure 3, the particle size distribution of the particle of the compositions formation of comparative example 17 as shown in Figure 4 for the particle size distribution of the particle of the compositions formation of embodiment 2.Following evaluation can be done by this result.
Volume averaging emulsifying particle diameter when A. rinsing the oil-based liquid skin cleansing composition of comparative example 17 is 9.841 μm, in contrast, volume averaging emulsifying particle diameter when rinsing the oil-based liquid skin cleansing composition of embodiment 2 is 1.410 μm.The compositions of embodiment 2 and the compositions of comparative example 17 are in a ratio of significantly fine particle.
B. in addition, as shown in Figure 3, the narrow distribution of emulsifying particle diameter when adding large water gaging in the compositions of embodiment 2.
C. because the oil-based liquid skin cleansing composition of the embodiment 2 of diester oil formed containing unitary branched chain fatty acid and dihydroxylic alcohols is scattered in a large amount of water immediately, so can easily rinse, therefore known washability is excellent.
< evaluation test 7> irrigation tests
Used the oil-based liquid skin cleansing composition of embodiment 2, comparative example 17 by 10 professional judging panels, by the single blind trial of judging panel evaluate which compositions do not clean after oil residues soapy feeling.
Its result all judging panels be all evaluated as: the compositions of embodiment 2 does not have oil residues soapy feeling.The result sensory test of evaluation test 6 is also confirmed.
The dissolubility test of the artificial keratotic plug of < evaluation test 8>
The keratotic plug solute effect of the oil-based liquid skin cleansing composition of test example 2.
Test method is as follows.
(1) cool after the composition mixing shown in table 8, to prepare artificial keratotic plug at 70 DEG C.
(2) artificial keratotic plug is enclosed in the hole of the diameter 5mm φ that acrylic panel bores out, then extrudes 5mm with aluminium bar, then cut with scraper.The keratotic plug cut is about 100mg.
(3) bottom surface (disc) of columniform keratotic plug is bonded on microscope slide with Instant cement.
(4) microscope slide is placed in assigned position, uses microscope photographing photo.
(5) with line, microscope slide and Tokyo physics and chemistry apparatus oscillator MULTI SHAKERMMS are linked together, be configured to the form that microscope slide shakes up and down, and the artificial keratotic plug bonding portion of microscope slide is immersed in oil-based liquid skin cleansing composition.Make oscillator with the speed operation 30 minutes of the amplitude of about 2cm, 200rpm, thus the artificial keratotic plug on microscope slide is shaken in oil-based liquid skin cleansing composition.
(6) microscope slide is placed in the position of regulation, uses microscope photographing photo.
(7) image analysis is passed through, try to achieve the height of artificial keratotic plug after the concussion of the height of artificial keratotic plug before the concussion of (4) and the aggregate value of body diameter and (6) and the aggregate value of body diameter, to shake the reduction of the difference after front and concussion as keratotic plug.This numerical value becomes the deliquescent index of keratotic plug.The reduction of keratotic plug measures 3 times and asks its meansigma methods in addition.
[table 8]
The composition of artificial keratotic plug
In addition, preparation does not contain the compositions (with reference to table 9) of the comparative example 18,19 of octyl octanoate or octyl, with comparing contrast.
[table 9]
| Composition name (sign title) | Comparative example 18 | Comparative example 19 |
| Thylhexoic acid spermaceti alcohol ester | 55 | 50 |
| Two different n-nonanoic acid BG | 20 | 20 |
| Diphenyl silicon oxygen base phenyl trimethicone | 3 | 3 |
| Polydimethylsiloxane | 2 | 2 |
| (caprylic/capric) monooctyl ester | - | - |
| Dicaprylyl carbonate | - | 5 |
| Natrulon H-10 diisopstearate | 10 | 10 |
| The different pelargonate of polyglycereol-20 eight | 5 | 5 |
| Polyglycereol-20 six caprylate | 5 | 5 |
The reduction of keratotic plug as shown in Figure 5.
Coordinate the keratotic plug dissolubility of the embodiment 2 of (caprylic/capric) monooctyl ester, improve 24% compared with not containing the comparative example 18 of (caprylic/capric) monooctyl ester, improve 13% compared with the comparative example 19 having coordinated dicaprylyl carbonate.
Can confirm that the oil-based liquid skin cleansing composition of embodiment 2 is compared with reference substance, the removal effect of pore dirt is excellent.In addition, the oil-based liquid skin cleansing composition of embodiment 2 can be confirmed to be actually used in Irrigation, and when observing the pore dirt state before and after cleaning with magnifier, there is excellent pore dirt removal effect.
< evaluation test 9> is to the effect appraise of skin barrier function
Skin detergents due to keratotic plug dissolubility excellence likely can be removed the sebum of more than necessary amount and the barrier function of skin is declined, so in order to the compositions of Evaluation operation example 2 is on the impact of skin, thus has carried out the mensuration of moisture flow vector.
The moisture flow vector of the forearm before clean skin is measured with water loss tester AS ?TW (Japanese ASAHIBIOMED Inc.), and embrocate 40 after washings wipe moisture away again at dropping skin detergents, measure the moisture flow vector after 5 minutes, thus try to achieve the difference of the moisture flow vector before and after clean skin.
Moisture flow vector before and after clean skin is also measured similarly to Example 2 for comparative example 18, comparative example 19, and tries to achieve the difference (rising value) of moisture flow vector.Measurement result as shown in Figure 6.
The difference (rising value) of the moisture flow vector before and after the clean skin of embodiment 2 and comparative example 18 is 0.3 μ g/cm
2, the difference (rising value) of the moisture flow vector before and after the clean skin of comparative example 19 is 0.95 μ g/cm
2.
Can confirm that the oil-based liquid skin cleansing composition of embodiment 2 does not remove the sebum of more than necessary amount.
From above evaluation test 6 ~ 9, the necessary excellent of clean skin such as compositions washability of the present invention, the dissolubility of keratotic plug, the protection of skin barrier.
Below enumerate the prescription example of oil-based liquid skin detergents.
Prescription example 1
Prescription example 2
Prescription example 3
Prescription example 4
Prescription example 5
Claims (9)
1. an oil-based liquid skin cleansing composition, is characterized in that, containing octyl octanoate and/or octyl.
2. oil-based liquid skin cleansing composition according to claim 1, is characterized in that, the content of octyl octanoate and/or octyl is 2 ~ 50 quality %.
3. according to oil-based liquid skin cleansing composition according to claim 1 or claim 2, it is characterized in that, comprise octyl octanoate and/or octyl, oil preparation and surfactant.
4. oil-based liquid skin cleansing composition according to claim 3, is characterized in that, oil preparation is aqueous or pasty state at 25 DEG C.
5. oil-based liquid skin cleansing composition according to claim 3, it is characterized in that, surfactant contains polyglyceryl fatty acid ester.
6. the oil-based liquid skin cleansing composition according to any one of claim 3 ~ claim 5, it is characterized in that, polyglyceryl fatty acid ester is selected from the different pelargonate of polyglycereol-20 eight, the different pelargonate of polyglycereol-20 six, the different pelargonate of polyglycereol-20 seven, polyglycereol-20 six caprylate, polyglycereol-20 eight caprylate, polyglycereol-20 ten caprylate, polyglycereol-20 15 caprylate, polyglycereol-20 six decanoin, polyglycereol-20 eight decanoin, Natrulon H-10 diisopstearate, Natrulon H-10 isostearate, Natrulon H-10 three isostearate, Natrulon H-10 decanoin, polyglycereol-5 laurate, polyglycereol-2 decanoin, polyglycereol-6 caprylate, Natrulon H-10 caprylate, more than a kind in polyglycereol-2 caprylate.
7. the oil-based liquid skin cleansing composition according to any one of claim 3 ~ claim 6, is characterized in that, the content of polyglyceryl fatty acid ester is 1 ~ 40 quality %.
8. the oil-based liquid skin cleansing composition according to any one of claim 3 ~ claim 7, is characterized in that, also comprises the diester oil that unitary branched chain fatty acid and dihydroxylic alcohols are formed.
9. oil-based liquid skin cleansing composition according to claim 8, is characterized in that, the diester oil that unitary branched chain fatty acid and dihydroxylic alcohols are formed is two different n-nonanoic acid butanediol esters.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013017340A JP5453556B1 (en) | 2013-01-31 | 2013-01-31 | Oily liquid cleansing composition |
| JP2013-017340 | 2013-01-31 | ||
| PCT/JP2013/075076 WO2014119039A1 (en) | 2013-01-31 | 2013-09-18 | Oil-based liquid cleansing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104812362A true CN104812362A (en) | 2015-07-29 |
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| CN201380060335.6A Pending CN104812362A (en) | 2013-01-31 | 2013-09-18 | Oil-based liquid cleansing composition |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5453556B1 (en) |
| CN (1) | CN104812362A (en) |
| HK (1) | HK1209352A1 (en) |
| WO (1) | WO2014119039A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108096061A (en) * | 2016-11-25 | 2018-06-01 | 株式会社芳珂 | Cosmetic preparation composition |
| CN108324677A (en) * | 2018-05-16 | 2018-07-27 | 浙江艳庄化妆品有限公司 | A kind of vanishing cream for being suitable for sensitive skin crowd and using |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6433165B2 (en) * | 2014-06-10 | 2018-12-05 | 太陽化学株式会社 | Cosmetic composition |
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| JP2009242253A (en) * | 2008-03-28 | 2009-10-22 | Fancl Corp | Oil-based liquid cleansing composition |
| CN101744745A (en) * | 2008-11-27 | 2010-06-23 | 株式会社芳珂 | Composition for oil-based liquid cleansing |
| CN102812115A (en) * | 2010-03-23 | 2012-12-05 | 考格尼斯知识产权管理有限责任公司 | Use of cleaning agents containing microemulsions that contain wax |
| JP2013001698A (en) * | 2011-06-21 | 2013-01-07 | Fancl Corp | Oily gel cleansing composition |
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| GB9716273D0 (en) * | 1997-07-31 | 1997-10-08 | Kimberly Clark Ltd | Hand cleanser |
| DE102008052520A1 (en) * | 2008-10-21 | 2010-04-22 | Cognis Ip Management Gmbh | Cosmetic and / or pharmaceutical preparations |
| JP5550873B2 (en) * | 2008-11-27 | 2014-07-16 | 株式会社ファンケル | Oily liquid cleansing composition. |
| CN103648468B (en) * | 2011-07-08 | 2017-01-18 | 考格尼斯知识产权管理有限责任公司 | Use of microemulsions in cosmetic cleaning compositions |
| WO2013136616A1 (en) * | 2012-03-13 | 2013-09-19 | 株式会社 資生堂 | Water-in-oil emulsion composition having high internal water phase content |
-
2013
- 2013-01-31 JP JP2013017340A patent/JP5453556B1/en active Active
- 2013-09-18 WO PCT/JP2013/075076 patent/WO2014119039A1/en active Application Filing
- 2013-09-18 CN CN201380060335.6A patent/CN104812362A/en active Pending
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2015
- 2015-10-15 HK HK15110152.6A patent/HK1209352A1/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009242253A (en) * | 2008-03-28 | 2009-10-22 | Fancl Corp | Oil-based liquid cleansing composition |
| CN101744745A (en) * | 2008-11-27 | 2010-06-23 | 株式会社芳珂 | Composition for oil-based liquid cleansing |
| CN102812115A (en) * | 2010-03-23 | 2012-12-05 | 考格尼斯知识产权管理有限责任公司 | Use of cleaning agents containing microemulsions that contain wax |
| JP2013001698A (en) * | 2011-06-21 | 2013-01-07 | Fancl Corp | Oily gel cleansing composition |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108096061A (en) * | 2016-11-25 | 2018-06-01 | 株式会社芳珂 | Cosmetic preparation composition |
| CN108096061B (en) * | 2016-11-25 | 2022-04-08 | 株式会社芳珂 | Cosmetic composition |
| CN108324677A (en) * | 2018-05-16 | 2018-07-27 | 浙江艳庄化妆品有限公司 | A kind of vanishing cream for being suitable for sensitive skin crowd and using |
| CN108324677B (en) * | 2018-05-16 | 2019-09-10 | 浙江艳庄化妆品有限公司 | A kind of vanishing cream used suitable for sensitive skin crowd |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5453556B1 (en) | 2014-03-26 |
| WO2014119039A1 (en) | 2014-08-07 |
| JP2014148476A (en) | 2014-08-21 |
| HK1209352A1 (en) | 2016-04-01 |
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