CN104738048A - Composite insecticidal composition containing pyridalyl and cyantraniliprole and application thereof - Google Patents
Composite insecticidal composition containing pyridalyl and cyantraniliprole and application thereof Download PDFInfo
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- CN104738048A CN104738048A CN201310726625.1A CN201310726625A CN104738048A CN 104738048 A CN104738048 A CN 104738048A CN 201310726625 A CN201310726625 A CN 201310726625A CN 104738048 A CN104738048 A CN 104738048A
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- insect amide
- cyanogen insect
- fluoroform pyrrole
- pyrrole ether
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- 0 CC(C1OCCCOCC2=CC(*)C*(C)=C2)=CC(*CC=C(*)N)=CC1O Chemical compound CC(C1OCCCOCC2=CC(*)C*(C)=C2)=CC(*CC=C(*)N)=CC1O 0.000 description 1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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Abstract
The invention discloses a composite insecticidal composition containing pyridalyl and cyantraniliprole and application thereof. The insecticidal composition employs active components of pyridalyl and cyantraniliprole in the weight ratio of 0.1-80:0.5-80. The insecticidal composition can produce high synergetic effects, overcomes and delays the insect resistance, and has high insecticidal speed, long effective period, reduced cost of medication and control effect obvious higher than that of a single dose. The invention can control lepidoptera pests of crops, especially can be used for the control of cotton bollworm and snout moth's larva, and the effect is obviously higher than that of the single dose.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of be principle active component Pesticidal combination and the application thereof of fluoroform pyrrole ether and cyanogen insect amide.
Background technology
Fluoroform pyrrole ether (Pyridalyl), chemical name: 2-{3-[2.3-bis-chloro-4-(3,3-bis-chloro-2-acrylic oxygen base) phenoxy group] propoxyl group }-5-(trifluoromethyl) pyrimidine, structural formula:
Fluoroform pyrrole ether, also known as pyridalyl, is to be developed by SUMITOMO CHEMICAL chemical company and the novel pyrimidines developed is efficient, low toxic pesticide, has remarkable preventive effect, with existing lepidopteran insecticidal agent without cross resistance to lepidoptera pest.It has the effect of tagging with stomach toxicity, is mainly used in the lepidoptera pest larva preventing and treating damage to crops, also has good preventive effect in addition to thrips thrips, diptera leaf miner.
Cyanogen insect amide (Cyantraniliprole), chemical name: 4'-table-methylamino-4'-deoxidation abamectin benzoate.Structural formula is:
Cyanogen insect amide is also bromine cyanogen insect amide (cyantraniliprole), it is E.I.Du Pont Company's second generation ryanodine receptor inhibitor insecticides that success is developed after chlorantraniliprole, cyanogen insect amide is formed by the various polar groups changed on phenyl ring, have more efficient, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
But the insect such as cotton bollworm, snout moth's larva is under the condition of current long-term prescription, resistance increases gradually, and the effect of agricultural chemicals single dose to control of insect declines gradually.Inventor finds after deliberation, and the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures improving preventive effect, not yet finds the Pesticidal combination about fluoroform pyrrole ether and cyanogen insect amide up to now.
Summary of the invention
The object of this invention is to provide a kind of compound pesticide compositions containing fluoroform pyrrole ether and cyanogen insect amide, this Pesticidal combination is the multifunctional insecticide composition of control lepidoptera pest.
Another object of the present invention is to provide this Pesticidal combination and is preparing the application prevented and treated on the insecticidal materials of resistance lepidoptera pest, the application particularly on the insecticidal materials preparing control cotton bollworm or snout moth's larva.
The object of the invention is to be achieved through the following technical solutions:
Containing a compound pesticide compositions for fluoroform pyrrole ether and cyanogen insect amide, this compound pesticide compositions is with fluoroform pyrrole ether and cyanogen insect amide for principle active component, and wherein, the weight ratio of fluoroform pyrrole ether and cyanogen insect amide is 0.1 ~ 80:0.5 ~ 80.
In this compound pesticide compositions, the weight ratio of fluoroform pyrrole ether and cyanogen insect amide is preferably 1 ~ 50:1 ~ 50, more preferably 1 ~ 10:1 ~ 10, most preferably is 1 ~ 10:1.
This compound pesticide compositions can only containing active component fluoroform pyrrole ether and cyanogen insect amide, and also can add other components when using or prepare in active component, the effective ingredient in this Pesticidal combination can also be present in composition by enhancing effective amount.
In compound pesticide compositions of the present invention, both fluoroform pyrrole ether and the cyanogen insect amide weight percentage in this compound pesticide compositions is 3% ~ 80%.Be preferably 5% ~ 55%, further preferably 20% ~ 55%, most preferably 20% ~ 30%.
Compound pesticide compositions of the present invention with fluoroform pyrrole ether and cyanogen insect amide for active component or principle active component, any one formulation that agricultural chemicals allows is become, the preferred missible oil of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion or water dispersion granule with insecticides adjuvant and excipient.
Aforementionedly can be applicable to the not special restriction of insecticides adjuvant of the present invention, include, but are not limited to calcium dodecyl benzene sulfonate, agriculture breast 600
#, the rare block compound of polyoxyethylene polyoxy third is (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., aforementionedly can be applicable to excipient of the present invention and be also not particularly limited, include, but are not limited to solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can be alone or and use.
Compound pesticide compositions of the present invention has good preventive effect to the lepidoptera pest that cotton bollworm and snout moth's larva etc. easily produce resistance; And suppress insect to produce the pesticide resistance of unitary agent (fluoroform pyrrole ether or cyanogen insect amide arbitrary).
Compound pesticide compositions of the present invention is preparing the application prevented and treated on resistance lepidoptera pest insecticidal materials, and the effect especially on preparation control cotton bollworm or snout moth's larva insecticidal materials is remarkable.Described snout moth's larva is preferably rice-stem borer.
Compared with prior art beneficial effect of the present invention: (1) is compared with single dose, said composition antagonism lepidoptera pest is obvious synergistic function as cotton bollworm, snout moth's larva etc. have, and overcomes and has delayed pest resistance to insecticide, and expanding prevention is composed, desinsection speed is fast, significantly improves control efficiency; (2) control recruitment, drug cost is reduced; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) with fluoroform pyrrole ether compared with cyanogen insect amide single dose, produce and use cost reduction; (6) suppress lepidoptera pest to strengthen the resistance of agricultural chemicals, its successful uses higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but do not limit the present invention in any way.
Embodiment 1:
Take fluoroform pyrrole ether and cyanogen insect amide altogether 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, vegetable oil to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and is mixed with the fluoroform pyrrole ether cyanogen insect amide missible oil that principle active component weight percentage is 30%.Wherein the concrete ratio of fluoroform pyrrole ether and cyanogen insect amide is in table 1 and 2.
Adopt feed to add malicious method and carry out indoor synergy biologicall test, selection resistant bollworm is target pest, and often process repetition 3 times, every concentration process 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism cotton bollworm by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 1:
Table 1 fluoroform pyrrole ether and cyanogen insect amide is composite and the toxicity test of single dose antagonism cotton bollworm
As shown in Table 1, fluoroform pyrrole ether and cyanogen insect amide composite, co-toxicity coefficient is all greater than 120, shows good synergistic function.
Adopt feed to add malicious method and carry out indoor synergy biologicall test, selection rice-stem borer is target pest, often processes repetition 3 times, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method
50, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, the results are shown in Table 2:
Table 2 fluoroform pyrrole ether and cyanogen insect amide is composite and single dose to the toxicity test of striped rice borer
Table 2 is known, fluoroform pyrrole ether and cyanogen insect amide composite, co-toxicity coefficient is all greater than 120, shows good synergistic function.
Embodiment 2:
Take 5g fluoroform pyrrole ether, 50g cyanogen insect amide, phenethyl phenol polyoxyethylene polyoxypropylene ether 3g, agriculture breast 33
#2g, 600#1g, solvent naphtha 13g, adds water to 100g.The method above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, forms the fluoroform pyrrole ether cyanogen insect amide aqueous emulsion that principle active component weight percentage is 55%.
Embodiment 3:
Take 2g fluoroform pyrrole ether, 18g cyanogen insect amide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyoxyethylene polyoxypropylene ether 3g, agriculture breast 33
#2g, agriculture breast 600
#1g, cyclohexanone 10g, adds water to 100g.The method above raw material being prepared routinely microemulsion drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether cyanogen insect amide microemulsion that principle active component weight percentage is 20%.
Carry out the control cotton bollworm test of pesticide effectiveness to embodiment 3, contrast medicament is 10% cyanogen insect amide OF and 100g/l fluoroform pyrrole ether EC, and dilute according to the extension rate of form 3 li, look into 3 days after medicine, 7 days, the result of 14 days, result is in table 3:
Table 3: the field test results of the composite antagonism cotton bollworm of fluoroform pyrrole ether-cyanogen insect amide
Field efficacy result shows, fluoroform pyrrole ether cyanogen insect amide composition antagonism cotton bollworm has excellent control efficiency, and control efficiency is all better than the direct acting effect of single dose kind.
Carry out water prevention chilo suppressalis field medicine effect test to embodiment 3, contrast medicament is 10% cyanogen insect amide OF and 100g/L fluoroform pyrrole ether EC, and dilute according to the extension rate of form 3 li, look into 3 days after medicine, 7 days, the result of 14 days, result is in table 4:
Table 4: the composite field test results to rice-stem borer of fluoroform pyrrole ether-cyanogen insect amide
Field efficacy result shows, fluoroform pyrrole ether cyanogen insect amide composition has excellent control efficiency to rice-stem borer, and control efficiency is all better than the direct acting effect of single dose kind.
Embodiment 4:
Take 1g fluoroform pyrrole ether, 5g cyanogen insect amide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether cyanogen insect amide missible oil that principle active component weight percentage is 6%.
Embodiment 5:
Take 50g fluoroform pyrrole ether, 20g cyanogen insect amide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether cyanogen insect amide missible oil that principle active component weight percentage is 70%.
Embodiment 6:
Take 2g fluoroform pyrrole ether, 40g cyanogen insect amide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether cyanogen insect amide missible oil that principle active component weight percentage is 42%.
Embodiment 7:
Take 0.2g fluoroform pyrrole ether, 50g cyanogen insect amide, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether cyanogen insect amide missible oil that principle active component weight percentage is 50.2%.
Embodiment 8:
Take 5g fluoroform pyrrole ether, 0.5g cyanogen insect amide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether cyanogen insect amide missible oil that principle active component weight percentage is 5.5%.
Embodiment 9:
Take 5g fluoroform pyrrole ether, 30g cyanogen insect amide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether cyanogen insect amide missible oil that principle active component weight percentage processed is 35%.
Embodiment 10:
Take 20g fluoroform pyrrole ether, 5g cyanogen insect amide, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the fluoroform pyrrole ether cyanogen insect amide missible oil that preparation principle active component weight percentage is 25%.
Embodiment 11:
Take 30g fluoroform pyrrole ether, 12g cyanogen insect amide, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether 4g, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, the weight percentage forming principle active component under the effect of sand mill is the fluoroform pyrrole ether cyanogen insect amide suspending agent of 42%.
Embodiment 12:
Take 2g fluoroform pyrrole ether, 5g cyanogen insect amide, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite adds to 100g, is the fluoroform pyrrole ether cyanogen insect amide water dispersion granule of 7% by above raw material by the weight percentage of water dispersible granular agent method formation principle active component.
Embodiment 13:
Take 50g fluoroform pyrrole ether, 3g cyanogen insect amide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and the weight percentage forming principle active component is the fluoroform pyrrole ether cyanogen insect amide missible oil of 53%.
Embodiment 14:
Take 2g fluoroform pyrrole ether, 18g cyanogen insect amide, lignin 10g, Negel 2g, add to 100g with diatomite, mixed in micronizer by above raw material, the weight percentage forming principle active component is the fluoroform pyrrole ether cyanogen insect amide wetting powder of 20%.
Embodiment 15:
Take 7g fluoroform pyrrole ether, 70g cyanogen insect amide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and the weight percentage forming principle active component is the fluoroform pyrrole ether cyanogen insect amide missible oil of 77%.
Embodiment 16:
Take 60g fluoroform pyrrole ether, 5g cyanogen insect amide, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, above raw material is the fluoroform pyrrole ether cyanogen insect amide water dispersible granules of 65% by the weight percentage of water dispersible granular agent method formation principle active component by kaolin 13g.
Claims (10)
1., containing a compound pesticide compositions for fluoroform pyrrole ether and cyanogen insect amide, it is characterized in that this compound pesticide compositions with fluoroform pyrrole ether and cyanogen insect amide for active insecticidal components, wherein, the weight ratio of fluoroform pyrrole ether and cyanogen insect amide is 0.1 ~ 80:0.5 ~ 80.
2. the compound pesticide compositions containing fluoroform pyrrole ether and cyanogen insect amide according to claim 1, is characterized in that the weight ratio of described fluoroform pyrrole ether and cyanogen insect amide is 1 ~ 50:1 ~ 50.
3. the compound pesticide compositions containing fluoroform pyrrole ether and cyanogen insect amide according to claim 2, is characterized in that the weight ratio of described fluoroform pyrrole ether and cyanogen insect amide is 1 ~ 10:1 ~ 10.
4. the compound pesticide compositions containing fluoroform pyrrole ether and cyanogen insect amide according to claim 3, is characterized in that the weight ratio of described fluoroform pyrrole ether and cyanogen insect amide is 1 ~ 10:1.
5. the compound pesticide compositions containing fluoroform pyrrole ether and cyanogen insect amide according to claim 1, is characterized in that both fluoroform pyrrole ether and the cyanogen insect amide weight percentage in this compound pesticide compositions is 3% ~ 80%.
6. the compound pesticide compositions containing fluoroform pyrrole ether and cyanogen insect amide according to claim 5, is characterized in that both fluoroform pyrrole ether and the cyanogen insect amide weight percentage in this compound pesticide compositions is 5% ~ 55%.
7. the compound pesticide compositions containing fluoroform pyrrole ether and cyanogen insect amide according to claim 1, is characterized in that this compound pesticide compositions with fluoroform pyrrole ether and cyanogen insect amide for active insecticidal components and insecticides adjuvant are mixed with the formulation that agricultural chemicals allows.
8. the compound pesticide compositions containing fluoroform pyrrole ether and cyanogen insect amide according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions containing fluoroform pyrrole ether and cyanogen insect amide according to claim 1 is preparing the application prevented and treated on the insecticidal materials of resistance lepidoptera pest.
10. application according to claim 9, is characterized in that described resistance lepidoptera pest is cotton bollworm or snout moth's larva.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310726625.1A CN104738048A (en) | 2013-12-25 | 2013-12-25 | Composite insecticidal composition containing pyridalyl and cyantraniliprole and application thereof |
| PCT/CN2014/076320 WO2015096331A1 (en) | 2013-12-25 | 2014-04-28 | Insecticidal compound composition containing pyridalyl and cyantraniliprole and use thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310726625.1A CN104738048A (en) | 2013-12-25 | 2013-12-25 | Composite insecticidal composition containing pyridalyl and cyantraniliprole and application thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104738048A true CN104738048A (en) | 2015-07-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310726625.1A Pending CN104738048A (en) | 2013-12-25 | 2013-12-25 | Composite insecticidal composition containing pyridalyl and cyantraniliprole and application thereof |
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| WO (1) | WO2015096331A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112715554A (en) * | 2019-10-14 | 2021-04-30 | 江苏功成生物科技有限公司 | Pesticide composition containing pyridalyl and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996011909A1 (en) * | 1994-10-14 | 1996-04-25 | Sumitomo Chemical Company, Limited | Dihalopropene compounds, insecticidal/acaricidal agents containing same, and intermediates for their production |
| CN102388059A (en) * | 2009-02-11 | 2012-03-21 | 陶氏益农公司 | Pesticidal compositions |
| CN103355306A (en) * | 2012-03-27 | 2013-10-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing pyridalyl and amide |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY140912A (en) * | 2004-07-26 | 2010-01-29 | Du Pont | Mixtures of anthranilamide invertebrate pest control agents |
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2013
- 2013-12-25 CN CN201310726625.1A patent/CN104738048A/en active Pending
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- 2014-04-28 WO PCT/CN2014/076320 patent/WO2015096331A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996011909A1 (en) * | 1994-10-14 | 1996-04-25 | Sumitomo Chemical Company, Limited | Dihalopropene compounds, insecticidal/acaricidal agents containing same, and intermediates for their production |
| CN102388059A (en) * | 2009-02-11 | 2012-03-21 | 陶氏益农公司 | Pesticidal compositions |
| CN103355306A (en) * | 2012-03-27 | 2013-10-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing pyridalyl and amide |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112715554A (en) * | 2019-10-14 | 2021-04-30 | 江苏功成生物科技有限公司 | Pesticide composition containing pyridalyl and application thereof |
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| WO2015096331A1 (en) | 2015-07-02 |
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Application publication date: 20150701 |