CN104673042A - Flame-retardant steel surface coating material and preparation method thereof - Google Patents
Flame-retardant steel surface coating material and preparation method thereof Download PDFInfo
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- CN104673042A CN104673042A CN201510056136.9A CN201510056136A CN104673042A CN 104673042 A CN104673042 A CN 104673042A CN 201510056136 A CN201510056136 A CN 201510056136A CN 104673042 A CN104673042 A CN 104673042A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
- C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3445—Five-membered rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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Abstract
The invention discloses a flame-retardant steel surface coating material and a preparation method thereof. The flame-retardant steel surface coating material is prepared from the following components in parts by weight: 35-48 parts of polyacrylamide, 5-9 parts of zinc oxide, 0.05-0.2 part of ammonium polyphosphate, 0.05-0.1 part of dibutyltin maleate, 0.03-0.1 part of diazolidinyl urea, 0.02-0.04 part of silane coupling agents, 0.01-0.2 part of antioxidants and 15-20 parts of 1,2-pentanediol. The invention also provides the preparation method of the flame-retardant steel surface coating material. The flame-retardant steel surface coating material prepared through the method disclosed by the invention not only has good flame-retardant property, but also has good scraping resistant property and antibacterial property. The flame-retardant steel surface coating material prepared through the method disclosed by the invention can be widely applied to the surfaces of a household appliance, an instrument, a meter, air purifying equipment and water purifying equipment.
Description
Technical field
The invention belongs to coated material field, particularly fire-retardant steel coating material of one and preparation method thereof.
Background technology
Steel top coat is for steel material surface, for changing the coated material of the characteristic of steel surface.Steel coating material can play the effect on good protection steel surface, and by adding mill base material, can change color, play decorative effect.Meanwhile, the coated material on steel surface can improve steel surface tension, play the effect of isolated air, and the oxidation rate on steel surface is reduced, the effect of the growth in work-ing life of material.
A kind of preparation method of UV cured flame-retardant coated material is disclosed in Chinese patent CN102585574A, mainly through preparation function colloidal sol, wherein function colloidal sol is the colloidal sol that silane coupler modified Nano sol or alkoxide and silane coupling agent cohydrolysis are produced, and add UV cured resin, nanometer antimony oxide, glass microballon and initiator, flow agent, the high hard abrasion resistant fire blocking coated material of the UV solidification obtained.This material can stop the transmission of heat from source, reach the object improved Working environment, reduce energy consumption.But this collosol coating material, its surperficial scraping and wiping resistance performance is not good, affects its work-ing life.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of fire-retardant steel coating material and preparation method thereof, this fire-retardant steel coating material not only has good flame retardant properties, and has good scrape resistant and anti-microbial property.The fire-retardant steel coating material that the present invention obtains can be widely used in household electrical appliance, instrument, air-purification unit, water correction plant surface.
Object of the present invention can be achieved through the following technical solutions:
A kind of fire-retardant steel coating material, be made up of the component comprising following weight part:
Polyacrylamide 35-48 part,
Zinc oxide 5-9 part,
Ammonium polyphosphate 0.05-0.2 part,
Dibutyitin maleate 0.05-0.1 part,
Two Imidurea 0.03-0.1 part,
Silane coupling agent 0.02-0.04 part,
Oxidation inhibitor 0.01-0.2 part,
1,2-pentanediol 15-20 part.
Described silane coupling agent is KH550.
Described oxidation inhibitor is selected from 2,6-tri-grades of butyl-4-methylphenols, two (3,5-tri-grades of butyl-4-hydroxy phenyls) mixing of one or more in thioether, four (β-(3,5-, tri-grades of butyl-4-hydroxy phenyls) propionic acid) pentaerythritol ester, two Lauryl Alcohol ester and two ten four carbon alcohols esters and two octadecanol ester.
A preparation method for fire-retardant steel coating material, the method comprises the following steps:
(1) take zinc oxide 5-9 part, dibutyitin maleate 0.05-0.1 part, add in shredder, grinding 5-15 minute, obtains 300-400 order powder;
(2) in the powder of step 1, add 1,2-pentanediol 15-20 part, polyacrylamide 35-48 part, ammonium polyphosphate 0.05-0.2 part successively, stir at 65-70 DEG C;
(3) heat up, add two Imidurea 0.03-0.1 part, silane coupling agent 0.02-0.04 part and oxidation inhibitor 0.01-0.2 part successively, stir 10-20 minute, obtain fire-retardant steel coating material.
The temperature heated up described in step 3 is 85-95 DEG C.
Described shredder is ball mill.
compared with prior art, its beneficial effect is in the present invention:
(1) the fire-retardant steel top coat material that the present invention obtains is major ingredient with polyacrylamide, adds polyphosphoric acid, meanwhile, present invention adds dibutyitin maleate and make it have good resistance to elevated temperatures and mechanical strength.
(2) the fire-retardant steel coating material that obtains of the present invention is by adding two Imidurea and zinc oxide, makes it have good tack, scratch resistance and anti-microbial property, can play the effect on isolated air conservation steel surface.
(3) fire-retardant steel coating material of the present invention, can use for a long time, and surface can be kept for a long time intact in the environment of outdoor or uviolizing.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) take zinc oxide 5kg, dibutyitin maleate 0.1kg, add in ball mill, grind 5 minutes, obtain 400 order powder;
(2) in the powder of step 1, add 1,2-pentanediol 15kg, polyacrylamide 48kg, ammonium polyphosphate 0.05kg successively, stir at 65 DEG C;
(3) be warming up to 85 DEG C, add two Imidurea 0.03kg, 0.02kg Silane coupling agent KH550 and 2,6-, tri-grades of butyl-4-methylphenol 0.01kg successively, stir 10 minutes, obtain fire-retardant steel coating material.
The performance test results of obtained fire-retardant steel coating material is as shown in table 1.
Embodiment 2
(1) take zinc oxide 5kg, dibutyitin maleate 0.1kg, add in ball mill, grind 15 minutes, obtain 300 order powder;
(2) in the powder of step 1, add 1,2-pentanediol 20kg, polyacrylamide 48kg, ammonium polyphosphate 0.05kg successively, stir at 65 DEG C;
(3) be warming up to 85 DEG C, add two Imidurea 0.03kg, 0.04kg Silane coupling agent KH550 and 2,6-, tri-grades of butyl-4-methylphenol 0.01kg successively, stir 10 minutes, obtain fire-retardant steel coating material.
The performance test results of obtained fire-retardant steel coating material is as shown in table 1.
Embodiment 3
(1) take zinc oxide 9kg, dibutyitin maleate 0.05kg, add in ball mill, grind 15 minutes, obtain 300 order powder;
(2) in the powder of step 1, add 1,2-pentanediol 20kg, polyacrylamide 35kg, ammonium polyphosphate 0.2kg successively, stir at 70 DEG C;
(3) be warming up to 95 DEG C, add two Imidurea 0.1kg, 0.04kg Silane coupling agent KH550s and two octadecanol ester 0.2kg successively, stir 20 minutes, obtain fire-retardant steel coating material.
The performance test results of obtained fire-retardant steel coating material is as shown in table 1.
Embodiment 4
(1) take zinc oxide 9kg, dibutyitin maleate 0.1kg, add in ball mill, grind 15 minutes, obtain 300 order powder;
(2) in the powder of step 1, add 1,2-pentanediol 20kg, polyacrylamide 40kg, ammonium polyphosphate 0.1kg successively, stir at 70 DEG C;
(3) 90 DEG C are warming up to, add two Imidurea 0.08kg, 0.03kg Silane coupling agent KH550 and four (β-(3 successively, 5-tri-grades of butyl-4-hydroxy phenyls) propionic acid) pentaerythritol ester 0.1kg, stirs 15 minutes, obtains fire-retardant steel coating material.
The performance test results of obtained fire-retardant steel coating material is as shown in table 1.
Embodiment 5
(1) take zinc oxide 7kg, dibutyitin maleate 0.08kg, add in ball mill, grind 10 minutes, obtain 300 order powder;
(2) in the powder of step 1, add 1,2-pentanediol 18kg, polyacrylamide 42kg, ammonium polyphosphate 0.15kg successively, stir at 68 DEG C;
(3) be warming up to 90 DEG C, add two Imidurea 0.08kg, 0.03kg Silane coupling agent KH550s and two Lauryl Alcohol ester 0.1kg successively, stir 15 minutes, obtain fire-retardant steel coating material.
The performance test results of obtained fire-retardant steel coating material is as shown in table 1.
Comparative example
Take polyacrylamide 50kg, zinc oxide 7kg, nanometer antimony oxide 0.2kg, dibutyitin maleate 0.1kg, glass microballon 0.1kg and 0.03kg Silane coupling agent KH550, add in ball mill, grind 10 minutes, at 90 DEG C, stir 15 minutes, obtain steel coating material.
Table 1
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example |
| The resistance to combustion time | 35min | 38min | 25min | 26min | 32min | 5min |
| Pencil hardness (level) | 2H | 2H | H | H | 2H | B |
The invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (6)
1. a fire-retardant steel coating material, is characterized in that, is made up of the component comprising following weight part:
Polyacrylamide 35-48 part,
Zinc oxide 5-9 part,
Ammonium polyphosphate 0.05-0.2 part,
Dibutyitin maleate 0.05-0.1 part,
Two Imidurea 0.03-0.1 part,
Silane coupling agent 0.02-0.04 part,
Oxidation inhibitor 0.01-0.2 part,
1,2-pentanediol 15-20 part.
2. fire-retardant steel coating material according to claim 1, is characterized in that, described silane coupling agent is KH550.
3. fire-retardant steel coating material according to claim 1, it is characterized in that, described oxidation inhibitor is selected from 2,6-tri-grades of butyl-4-methylphenols, two (3,5-tri-grades of butyl-4-hydroxy phenyls) mixing of one or more in thioether, four (β-(3,5-, tri-grades of butyl-4-hydroxy phenyls) propionic acid) pentaerythritol ester, two Lauryl Alcohol ester and two ten four carbon alcohols esters and two octadecanol ester.
4. a preparation method for fire-retardant steel coating material, it is characterized in that, the method comprises the following steps:
(1) take zinc oxide 5-9 part, dibutyitin maleate 0.05-0.1 part, add in shredder, grinding 5-15 minute, obtains 300-400 order powder;
(2) in the powder of step 1, add 1,2-pentanediol 15-20 part, polyacrylamide 35-48 part, ammonium polyphosphate 0.05-0.2 part successively, stir at 65-70 DEG C;
(3) heat up, add two Imidurea 0.03-0.1 part, silane coupling agent 0.02-0.04 part and oxidation inhibitor 0.01-0.2 part successively, stir 10-20 minute, obtain fire-retardant steel coating material.
5. the preparation method of fire-retardant steel coating material according to claim 4, is characterized in that, the temperature heated up described in step 3 is 85-95 DEG C.
6. the preparation method of fire-retardant steel coating material according to claim 4, is characterized in that, described shredder is ball mill.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877563A (en) * | 2015-06-11 | 2015-09-02 | 张家港市五湖新材料技术开发有限公司 | Three-proofing lacquer for circuit board preventing electromagnetic interference |
| CN105086719A (en) * | 2015-07-11 | 2015-11-25 | 合肥正浩机械科技有限公司 | Surface treating agent for sliding mechanical parts and preparation method therefor |
| CN105215266A (en) * | 2015-09-21 | 2016-01-06 | 蚌埠冠宜型材科技有限公司 | A kind of casting Wooden Pattern Making method of high stability |
| CN105860730A (en) * | 2016-05-04 | 2016-08-17 | 黄炜强 | Wall-mounting-type cabinet |
| CN105877222A (en) * | 2016-05-26 | 2016-08-24 | 程南南 | Flame-retardant wall-mounted cupboard with fire extinguishing apparatus |
| CN105901972A (en) * | 2016-05-04 | 2016-08-31 | 黄炜强 | Wall-mounted cupboard |
| CN106118284A (en) * | 2016-07-19 | 2016-11-16 | 芜湖昊轩环保新材料有限公司 | Water nano composite coating and preparation method thereof |
| CN107151504A (en) * | 2017-06-26 | 2017-09-12 | 苏昭缄 | A kind of high temperature abrasion material and preparation method thereof |
| ITUA20162167A1 (en) * | 2016-03-31 | 2017-10-01 | Bio Eco Active S R L | Manufactured product comprising an antioxidant agent and a bacteriostatic action agent and related production process. |
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| CN103351723A (en) * | 2013-06-29 | 2013-10-16 | 青岛国强环保科技有限公司 | Architectural sound-insulation paint |
| CN104231805A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Water-based ultra-thin fire-retardant coating for steel structures and preparation method of fire-retardant coating |
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| CN103351723A (en) * | 2013-06-29 | 2013-10-16 | 青岛国强环保科技有限公司 | Architectural sound-insulation paint |
| CN104231805A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Water-based ultra-thin fire-retardant coating for steel structures and preparation method of fire-retardant coating |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877563A (en) * | 2015-06-11 | 2015-09-02 | 张家港市五湖新材料技术开发有限公司 | Three-proofing lacquer for circuit board preventing electromagnetic interference |
| CN105086719A (en) * | 2015-07-11 | 2015-11-25 | 合肥正浩机械科技有限公司 | Surface treating agent for sliding mechanical parts and preparation method therefor |
| CN105215266A (en) * | 2015-09-21 | 2016-01-06 | 蚌埠冠宜型材科技有限公司 | A kind of casting Wooden Pattern Making method of high stability |
| ITUA20162167A1 (en) * | 2016-03-31 | 2017-10-01 | Bio Eco Active S R L | Manufactured product comprising an antioxidant agent and a bacteriostatic action agent and related production process. |
| KR102391639B1 (en) | 2016-03-31 | 2022-04-27 | 벤빅 에스에이에스 | Articles comprising antioxidants and bacteriostatic agents and processes for their manufacture |
| US11178874B2 (en) | 2016-03-31 | 2021-11-23 | Benvic Sas | Articles comprising antioxidizing agents and bacteriostatic agents, and production processes thereof |
| KR20180132738A (en) * | 2016-03-31 | 2018-12-12 | 바이오 에코 액티브 에스.알.엘. | Articles containing antioxidants and bacteriostats and processes for their production |
| WO2017168357A1 (en) * | 2016-03-31 | 2017-10-05 | Bio Eco Active S.R.L. | Article comprising an antioxidizing agent and a bacteriostatic agent and a production process thereof |
| CN105860730A (en) * | 2016-05-04 | 2016-08-17 | 黄炜强 | Wall-mounting-type cabinet |
| CN105901972A (en) * | 2016-05-04 | 2016-08-31 | 黄炜强 | Wall-mounted cupboard |
| CN105877222A (en) * | 2016-05-26 | 2016-08-24 | 程南南 | Flame-retardant wall-mounted cupboard with fire extinguishing apparatus |
| CN106118284A (en) * | 2016-07-19 | 2016-11-16 | 芜湖昊轩环保新材料有限公司 | Water nano composite coating and preparation method thereof |
| CN107151504A (en) * | 2017-06-26 | 2017-09-12 | 苏昭缄 | A kind of high temperature abrasion material and preparation method thereof |
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Application publication date: 20150603 |