CN104663668A - Insecticidal and acaricidal composition containing acetyl coenzyme A inhibitor insecticide - Google Patents
Insecticidal and acaricidal composition containing acetyl coenzyme A inhibitor insecticide Download PDFInfo
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- CN104663668A CN104663668A CN201310608663.7A CN201310608663A CN104663668A CN 104663668 A CN104663668 A CN 104663668A CN 201310608663 A CN201310608663 A CN 201310608663A CN 104663668 A CN104663668 A CN 104663668A
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- 239000004208 shellac Substances 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of insecticides, and relates to an insecticidal and acaricidal composition containing an acetyl coenzyme A inhibitor insecticide. The composition contains an active component A and an active component B, a weight part ratio of the component A to the component B is 1:99-99:1, the active component A is a compound I represented by a structural formula shown in the invention, and the active component B is selected from acetyl coenzyme A carboxylase inhibitor insecticides/acaricides. The composition has the advantages of obvious synergy and resistance delaying, and can be used for controlling various insects.
Description
Technical field
The invention belongs to field of pesticides, relate to a kind of insecticide acaricide composition containing acetyl coenzyme A inhibitor insecticides.
Background technology
Insecticide has obvious effect in control agriculture and forestry injurious insect or urban health insect.
Chinese invention patent CN101875633 discloses a kind of pyrazolyl acrylonitrile compound and controls the purposes of insect pest and mite evil, wherein compound 5(is hereinafter referred to as chemical compounds I) can be used for preventing and treating various pests, evil mite, especially to evil mite, there is outstanding control efficiency.
Insecticide containing single-activity component, control of insect uses continuously, easily makes insect develop immunity to drugs.By the insecticide of two kinds of active components by a certain percentage mixture become blending ingredients, often can improve preventive effect, reduce the consumption of active ingredient, cost-saving, the generation of pest resistance to insecticide can be delayed simultaneously.
Although disclose chemical compounds I general in prior art or its homologue can produce additional advantage and effect with other Mixture Use of Insecticides, the technical scheme of the binary pesticide composition containing chemical compounds I has no concrete open.
Summary of the invention
The object of the invention is to develop a kind of insecticide acaricide composition containing acetyl coenzyme A inhibitor insecticides, to meet the demand that agricultural and pest control aspect, urban health field day by day improve insecticide effect and kind is constantly updated.
For achieving the above object, the technical solution used in the present invention is:
An insecticide acaricide composition containing acetyl coenzyme A inhibitor insecticides, composition contains A, B two kinds of active components, and the ratio of weight and number between component A and B component two component is 1:99-99:1; Active component A is selected from following structural formula
Shown chemical compounds I, active component B is selected from acetyl-CoA carboxylase inhibitor class desinsection/mite agent;
Described active component A structure is as follows,
Described acetyl-CoA carboxylase inhibitor class class desinsection (mite) agent is selected from spiral shell mite ester (Spirodiclofen), spiral shell worm ester (Spiromesifen) or spiral shell worm ethyl ester (Spirotetramat) etc.
In composition of the present invention, active component B is preferably spiral shell mite ester.
In composition of the present invention, the ratio of weight and number of two kinds of active components is 1:99-99:1, is preferably 1:20-20:1.
Synergistic effect composition of the present invention can provide in finished product preparation form.Therefore, the present invention also comprises a kind of insecticides of dosage form.Take composition as active component, make missible oil, suspending agent, water-dispersible granules, aqueous emulsion, soluble concentrate, wetting powder, water dispersible oil suspending agent etc. as required.In preparation, the cumulative amount of the active component of composition is between 0.5% ~ 95%, and preferred cumulative amount is between 1%-85%.In composition of the present invention, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and synergistic effect degree.The optimum range of active component content is different according to the preparation type of composition.
The preparation of composition finished product preparation of the present invention can be prepared by common processing method, after mixing with liquid-carrier (solvent) or solid carrier by active substance, add one or more surfactants as emulsifier, dispersant, wetting agent, adhesive, stabilizing agent and defoamer etc.Containing at least one carrier and at least one surfactant in usual composition.In all cases, should guarantee that present composition active component is uniformly distributed.
Missible oil contains the active component of 10 ~ 50% usually, 2 ~ 20% emulsifier, other additive such as stabilizing agent, the bleeding agent etc. of 0 ~ 20%, and solvent (if desired also containing cosolvent).
Suspending agent needs sand milling usually, to obtain stable non-deposited flowable product.Usually containing 5 ~ 75% active components in suspending agent, 5 ~ 15% dispersants, 4 ~ 10% antifreezing agents, other additive of 0 ~ 10% is as defoamer, preservative, stabilizing agent, bleeding agent and thickener, and liquid-carrier surplus.
Water-dispersible granules makes 10 ~ 100 international standard sieve mesh (1.676 ~ 0.152mm) particles usually, can by extruding, dipping or Spray granulation method preparation.Usual water-dispersible granules contains the active component of 0.5 ~ 75% and surfactant such as stabilizing agent, wetting dispersing agent, disintegrant and the adhesive of 5 ~ 20%, and inert carrier surplus.
Wetting powder contains the active component of 10 ~ 85% usually, except solid inert carrier, usually contains the dispersant of 3 ~ 10%, can also contain stabilizing agent and (or) other additive of 0 ~ 10%, such as bleeding agent or sticker.
Aqueous emulsion is that former medicine, organic solvent, surfactant mixing are formed oil phase; Water, antifreezing agent are mixed, becomes transparent and homogeneous aqueous phase.With high-shear emulsion machine high speed shear oil phase, slowly aqueous phase is added oil phase, usual active ingredient 1 ~ 60%, surfactant 5 ~ 20%, antifreezing agent 2 ~ 10%, water surplus simultaneously.
Microemulsion is mixed former medicine, organic solvent, surfactant, water, becomes transparent and homogeneous aqueous phase.Usual active ingredient 1 ~ 50%, surfactant 10 ~ 40%, antifreezing agent 2 ~ 10%, water surplus.
Soluble liquid is mixed active component, organic solvent, surfactant, becomes transparent and homogeneous liquid.Usual active ingredient 1 ~ 50%, surfactant 6 ~ 20%, organic solvent surplus.
Water dispersible oil suspending agent is that active component, surfactant, oil based vehicle are added sand milling in sand mill, until particle diameter is qualified, and usual active ingredient 2 ~ 60%, surfactant 6 ~ 20%, oil based vehicle surplus.
Moisture dispersion liquid and emulsion (composition that missible oil as of the present invention in dilute with water, wetting powder or concentrate obtain) are also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have dense thick paste-like consistency.
The preparation of composition finished product preparation of the present invention can adopt known (liquid or solid) carrier of those skilled in the art and various auxiliary agent.Such as include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., as one or more in toluene, dimethylbenzene, acetone, cyclohexanone, acetonitrile, benzene, cyclohexane, isopropyl alcohol, ethylene glycol, sorbierite, methyl alcohol, ethanol, butanols, dimethyl formamide, dimethyl sulfoxide (DMSO), N-methyl-pyrrolidon, tributyl phosphate, methyl iso-butyl ketone (MIBK), naphthalane, machine oil, benzinum, methyl oleate, methylated soya oil or the molten fiber of methyl etc.The mixture of different liquids is often applicable.
Suitable solid carrier comprises clay that is natural or synthesis and silicate, and the solid carrier being applicable to pulvis comprises the mineral matter (as microdispersed silicic acid or aluminium oxide) ground of the White Carbon black of natural formation, rock dust, chalk, quartz, clay, imvite, sodium sulphate, white carbon, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, attapulgite, precipitated calcium carbonate, potter's clay and synthesis.The particulate vector be applicable to comprises the broken synthesis particle made with natural rock such as calcite, marble, float stone, sepiolite and dolomite of classification and by the powder of organic matter and inorganic matter.
Suitable co-solvents is one or more in methyl alcohol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, dimethyl formamide, dimethyl sulfoxide (DMSO), N-methyl-pyrrolidon, methyl oleate, methyl iso-butyl ketone (MIBK), the molten fiber of methyl etc.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n
20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, castor oil polyoxyethylene ether, alkyl vinyl aryl phenyl ether (YUS-SC3), diphenyl phenolic group polyoxyethylene (n
18) ether formaldehyde condensation products, the different thionic acid calcium of oleic acid, agriculture breast AEO-3, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast T-85, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#, agriculture breast OX-2681, agriculture breast OX-8686, agriculture breast 2201#, agriculture breast NP-7, agriculture breast OX-635, agriculture breast OX-653, agriculture breast YUS-D935, agriculture breast YUS-D3020, agriculture breast NP-10, agriculture breast NP-15 etc.
Suitable dispersant can be sodium lignin sulfonate, calcium lignosulfonate, the sodium salt of alkyl naphthalene sulfonic acid condensation polymer, polycarboxylate salt dispersant GY-D800, polycarboxylate salt dispersant GY-D04, polycarboxylate salt dispersant GY-D02, naphthalenesulfonic acid-formaldehyde condensate, naphtholsulfonic acid formaldehyde condensation products sodium salt, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, alkyl-diethylene glycol ether-sodium sulfonate, detergent LS, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, dispersant SP-28F, dispersant SP-SC3, reach profit dispersant D909S, alkylaryl APEO, alkylpolyoxyethylene phosphate, polyaryl phenol polyethenoxy ether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, alkylnaphthalene sulfonate formaldehyde condensation products (NNO), ethylene oxide-propylene oxide block copolymer alkylphenol polyoxyethylene formaldehyde condensation products, N-methyl-oleoyl-sodium taurocholate, N-methyl-fatty acyl group-sodium taurocholate, alkylphenol polyoxyethylene formaldehyde condensation products, nekal (Nekal BX), dibutyl naphthalenesulfonic acid formaldehyde condensation products, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy based phosphates etc.
Suitable wetting agent can be lauryl sodium sulfate, sodium sulphate, Morwet EFW, wetting agent SP-SC3266, isopropyl naphthalene sulfonate, alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, sldium lauryl sulfate, neopelex, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc.
Suitable thickener can be synthesis (as carbonyl methylol, polyvinyl alcohol, polyvinyl acetate) or natural water-soluble polymer (as xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, PEG 8000, phenolic resins, shellac, methylcellulose, soluble starch, carboxymethyl cellulose and sodium alginate etc.), adds in preparation with powder, particle or latex form.Suitable defoamer is bubble enemy, silicone, C8-10 fatty alcohol, phosphoric acid ester, C10-20 saturated fat acids (as capric acid) and acid amides etc.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sodium alginate etc.
Aerosol can be made during for preventing and treating city insect, need to add propellant wherein, also bait formulation composition be can make, except containing except active component, also the foodstuff of insect's food-taking, optional attractant and optional wetting agent are suitable for containing one or more.
The present invention also comprises the present composition and is prepared into the purposes that Insecticiding-miticiding preparation controls agriculture and forestry injurious insect or urban health insect.Specifically be suitable for preventing and treating multiple important pest, as aphid, leafhopper, aleyrodid, thrips, pear sucker, scale insect, panonychus citri, phyllocoptruta oleivora, apple tetranychus, Tetranychus urticae, goitre mite, flour mite etc., city insect is as termite, blattaria, ant, fly class, mosquito class etc.For fruit tree as apple, pears, citrus, lichee etc., Cereal is as wheat, paddy rice etc., and beans is as soybean, Kidney bean etc., and cotton, vegetables are as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum and flowers etc.
The present invention also comprises a kind of method controlling insect pest, the present composition can be imposed on the medium of insect or its growth needing to control with effective dose.The comparatively suitable effective dose of usual selection is per hectare 10 grams to 500 grams, and preferred effective dose is per hectare 15 grams to 100 grams.
Separately, demonstrate composition of the present invention through indoor biological determination of activity and there is synergistic effect.Such as, chemical compounds I and spiral shell mite ester show certain synergistic effect to Tetranychus cinnabarinus within the scope of 1:20-20:1.
Tool of the present invention has the following advantages:
1. composition of the present invention shows obvious synergistic effect in certain ratio range, improves the control efficiency of this compound to insect.
2. the present composition reduces the using dosage of compound in the application, thus reduces use cost, reduces environmental pollution.
3. in the present composition, the mechanism of action of each active ingredient is different, there is not the problem of cross resistance, can delay the generation of pest resistance to insecticide with its pest control, and improve the control efficiency of antagonism population.
Embodiment
Following specific embodiment is for further describing the present invention, but the present invention is only limitted to absolutely not these examples.In embodiment, each component percentages or proportioning are all by weight.Active component in each formula calculates with effective content, and in composition, each material all can prepare in a conventional manner simultaneously.
Formulation Example
The preparation of embodiment 1,21% spiral shell mite ester compounds I missible oil
By recipe requirements, add 1 part of spiral shell mite ester respectively, 20 parts of chemical compounds Is, 8 parts of agriculture breast OX-2681,3 parts of agriculture breast OX-8686,2 parts of agriculture breast 1601#, 8 parts of dimethyl formamides, 6 parts of methyl alcohol, dimethylbenzene complement to 100% and add in mixing kettle, be uniformly mixed, use hot bath heating for dissolving if desired, 21% spiral shell mite ester compounds I missible oil can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell mite ester alternative costs specification, new 21% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I missible oil can also be formed.
The preparation of embodiment 2,42% spiral shell mite ester compounds I wetting powder
By recipe requirements, 40 parts of spiral shell mite esters, 2 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 5 parts of methanonaphthalene sodium sulfonates, 4 parts of naphtholsulfonic acid formaldehyde condensation products sodium salts, 4 parts of oleic acid methylaminoethyl sodium sulfonates, 5 parts of White Carbon blacks, bentonites are complemented to 100% and fully mix, after ultra-fine pulverizer disintegrating, 42% spiral shell mite ester compounds I wetting powder can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell mite ester alternative costs specification, new 42% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I wetting powder can also be formed.
The preparation (1:1) of embodiment 3,12% spiral shell worm ethyl ester compound I wetting powder
By recipe requirements; 2 parts of spiral shell worm ethyl esters, 10 parts of chemical compounds Is, 2 parts of Morwet EFW, 5 parts of polycarboxylate salt dispersant GY-D800,6 parts of N-methyl-oleoyl-sodium taurocholates, 2 parts of detergent LS, 5 parts of White Carbon blacks, precipitated calcium carbonates are complemented to 100% and fully mix; after ultra-fine pulverizer disintegrating, 12% spiral shell worm ethyl ester compound I wetting powder can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell worm ethyl ester alternative costs specification, new 12% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I wetting powder can also be formed.
The preparation of embodiment 4,22% spiral shell mite ester compounds I aqueous emulsion
By recipe requirements, by 20 parts of spiral shell mite esters, 2 parts of chemical compounds Is, 8 parts of triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, 2 parts of Nongru-700 #, 5 parts of agriculture breast YUS-D935,10 parts of dimethyl formamides, 5 parts of tributyl phosphates, 5 parts of dimethylbenzene add in mixing kettle, be uniformly mixed, make to be dissolved into homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is joined oil phase, 22% spiral shell mite ester compounds I aqueous emulsion of favorable dispersibility can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell mite ester alternative costs specification, new 22% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I aqueous emulsion can also be formed.
The preparation (1:1) of embodiment 5,40% spiral shell mite ester compounds I aqueous emulsion
By recipe requirements, by 20 parts of spiral shell mite esters, 20 parts of chemical compounds Is, 5 parts of polyoxyethylene (n
20) phenethyl phenol ether through reaction oleate, 5 parts of YUS-D935,6 parts of agriculture breast 507#, 8 parts of cyclohexanone, 8 parts of dimethyl sulfoxide (DMSO)s, 10 parts of dimethylbenzene add in mixing kettle, be uniformly mixed, make to be dissolved into homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is joined oil phase, 40% spiral shell mite ester compounds I aqueous emulsion of favorable dispersibility can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell mite ester alternative costs specification, new 40% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I aqueous emulsion can also be formed.
Embodiment 6,60% spiral shell mite ester compounds I water-dispersible granules (1:1)
By recipe requirements; by 30 parts of spiral shell mite esters, 30 parts of chemical compounds Is, 4 parts of methanonaphthalene sodium sulfonates, 5 parts reach profit dispersant D909S, 1.5 parts of Morwet EFW, 8 parts of soluble starches, bentonites complement to 100% and be added together; carry out co-grinding; again after adding water and mediating, add in the comminutor that certain specification screen cloth is housed and carry out granulation.And then drying, screening (by screen cloth scope), 60% spiral shell mite ester compounds I water-dispersible granules can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell mite ester alternative costs specification, new 60% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I water-dispersible granules (1:1) can also be formed.
Embodiment 7,24% spiral shell worm ester compounds I water-dispersible granules
By recipe requirements; the sodium salt of 20 parts of spiral shell worm esters, 4 parts of chemical compounds Is, 2 parts of oleic acid methylaminoethyl sodium sulfonates, 4 parts of alkyl naphthalene sulfonic acid condensation polymers, 4 parts of alkylnaphthalene sulfonate formaldehyde condensation products, 5 parts of PEG 8000s, 15 parts of sodium sulphate, diatomite are complemented to 100% and are added together; carry out co-grinding; again after adding water and mediating, add in the comminutor that certain specification screen cloth is housed and carry out granulation.And then drying, screening (by screen cloth scope), 24% spiral shell worm ester compounds I water-dispersible granules can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell worm ester alternative costs specification, new 24% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I water-dispersible granules can also be formed.
Embodiment 8,21% spiral shell mite ester compounds I suspending agent
By recipe requirements, by the sodium salt of 1 part of spiral shell mite ester, 20 parts of chemical compounds Is, 2 parts of agriculture breast 1601#, 5 parts of agriculture breast 0201B, 3 parts of alkyl naphthalene sulfonic acid condensation polymers, 0.2 part of xanthans, 0.8 part of white carbon, 5 parts of ethylene glycol, complement to 100% with water, join in blending tank successively and mix, first carry out coarse crushing, homogenize through high shear, then be pumped in sand mill and carry out fine grinding, the granularity of sand milling material is detected with particles distribution instrument, after particle diameter reaches standard-required, filter, 21% spiral shell mite ester compounds I suspending agent can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell mite ester alternative costs specification, new 21% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I suspending agent can also be formed.
Example 9,50% spiral shell worm ethyl ester compound I suspending agent (1:1)
By recipe requirements, by 25 parts of spiral shell worm ethyl esters, 25 parts of chemical compounds Is, 4 parts of dispersant SP-28F, 3 parts of wetting agent SP-SC3266,2 parts of agriculture breast T-20,0.1 part of xanthans, 0.5 part of white carbon, 5 parts of ethylene glycol, complement to 100% with water, join in blending tank successively and mix, first carry out coarse crushing, homogenize through high shear, then be pumped in sand mill and carry out fine grinding, the granularity of sand milling material is detected with particles distribution instrument, after particle diameter reaches standard-required, filter, 50% spiral shell worm ethyl ester compound I suspending agent can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell worm ethyl ester alternative costs specification, new 50% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I suspending agent (1:1) can also be formed.
Embodiment 10,21% spiral shell mite ester compounds I microemulsion
By recipe requirements, 1 part of spiral shell mite ester, 20 parts of chemical compounds Is, 6 parts of agriculture breast 0201B, 5 parts of agriculture breast NP-15,8 parts of agriculture breasts, 2201,2 parts of Nongru-700 #, 10 parts of dimethyl sulfoxide (DMSO)s, 15 parts of cyclohexanone are added together, make to be dissolved into homogeneous oil phase, surplus water complements to 100%, under high velocity agitation, aqueous phase joined oil phase or oil phase is joined aqueous phase, forming 21% spiral shell mite ester compounds I microemulsion of favorable dispersibility.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell mite ester alternative costs specification, new 21% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I microemulsion can also be formed.
Embodiment 11,21% spiral shell mite ester compounds I soluble concentrate
By recipe requirements, 1 part of spiral shell mite ester, 20 parts of chemical compounds Is, 7 parts of agriculture breast 2201#, 3 parts of agriculture breast 0201B, 3 parts of agriculture breast 100#, 1 part of Nongru-700 #, 10 parts of N-methyl-pyrrolidon, 6 parts of tributyl phosphates, the molten fibers of methyl are complemented to 100% and mix, use hot bath heating for dissolving if desired, 21% spiral shell mite ester compounds I soluble concentrate can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell mite ester alternative costs specification, new 21% acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I soluble concentrate can also be formed.
Embodiment 12,21% spiral shell mite ester compounds I water dispersible oil suspending agent
By recipe requirements, 1 part of spiral shell mite ester, 20 parts of chemical compounds Is, 4 parts of agriculture breast 0201B, 3 parts of agriculture breast 500#, 5 parts of agriculture breast AEO-3,3 parts of agriculture breast S-80,3 parts of white carbons, methyl oleate are complemented to 100% to join in blending tank successively and mix, first carry out coarse crushing, homogenize through high shear, then be pumped in sand mill and carry out fine grinding, the granularity of sand milling material is detected with particles distribution instrument, after particle diameter reaches standard-required, filter, 21% spiral shell mite ester compounds I water dispersible oil suspending agent can be obtained.
By the one in the acetyl-CoA carboxylase inhibitor class desinsection/mite agent described by spiral shell mite ester alternative costs specification, 21% new acetyl-CoA carboxylase inhibitor class desinsection/mite immunomodulator compounds I water dispersible oil suspending agent can also be formed.
Indoor biological determination of activity
The composition of embodiment 13 containing chemical compounds I is to the synergism determination of Tetranychus cinnabarinus
For examination object: Tetranychus cinnabarinus (Tetranychus cinnabarinus Boisduval), become mite, the sensitive strain of indoor feeding.
Test condition: temperature: 24 ~ 26 DEG C, humidity: RH60%, illumination: L:D=14:10
Test method: adopt pot-spraying method.The potted plant Kidney bean seedling of sizing (2 true leaves) of hot-house culture, stays a slice true leaf, is connected into mite 40-60 head thereon.Adopt Airbrush spray-on process liquid process examination material, naturally dry in the shade.First process blank, then repeat aforesaid operations from low to high according to experimental scheme dosage, often process 4 times and repeat.Be placed in observation ward by the examination worm after process, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, borer population of living, and calculates lethality.
Evaluate and adopt Bliss method, the method is one of classical way evaluating mixture effect.The independent joint action concept that Bliss proposes according to it is thought, theoretical lethality P during Mixture Use of Insecticides can calculate with following formula:
P=P
m+P
n(1-P
m)
P
mit is the lethality (%) of the first active component target when concentration is m; P
nthe lethality (%) of target when be the second active component working concentration being n.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.
The results are shown in Table 1.
The table 1 chemical compounds I synergism determination that Tetranychus cinnabarinus become to mite used in combination with spiral shell mite ester
Claims (8)
1. the insecticide acaricide composition containing acetyl coenzyme A inhibitor insecticides, is characterized in that: composition contains A, B two kinds of active components, and the ratio of weight and number between component A and B component two component is 1:99-99:1;
Active component A is selected from the chemical compounds I shown in following structural formula, and active component B is selected from acetyl-CoA carboxylase inhibitor class desinsection/mite agent;
Described active component A structure is as follows:
2., according to composition according to claim 1, it is characterized in that:
Described acetyl-CoA carboxylase inhibitor class desinsection/mite agent is selected from spiral shell mite ester, spiral shell worm ester or spiral shell worm ethyl ester.
3. according to the composition described in claim 1 or 2, it is characterized in that: described active component A is chemical compounds I, active component B is selected from spiral shell mite ester; The ratio of weight and number of two kinds of active components is 1:20-20:1.
4. according to composition according to claim 1, it is characterized in that: composition can be configured to missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble concentrate, wetting powder or water dispersible oil suspending agent.
5. according to composition according to claim 4, it is characterized in that: in composition, the cumulative amount of active component is between 0.5%-95%.
6. according to composition according to claim 5, it is characterized in that: in composition, the cumulative amount of active component is between 1%-85%.
7., according to an application for the insecticide acaricide composition containing acetyl coenzyme A inhibitor insecticides according to claim 1, it is characterized in that: described composition for the preparation of insecticidal/acaricidal agent, for controlling pest or urban health insect.
8. according to the application of the insecticide acaricide composition containing acetyl coenzyme A inhibitor insecticides according to claim 1, it is characterized in that: in effective dose, the described composition being prepared into insecticidal/acaricidal agent is imposed on the medium of insect or its growth needing to control.
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| CN109691451A (en) * | 2017-10-24 | 2019-04-30 | 沈阳中化农药化工研发有限公司 | A kind of Insecticiding-miticiding synergistic composition of the mite of azoles containing second nitrile and its application |
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