CN104592569B - 电缆用阻燃天然橡胶套及其制备方法 - Google Patents
电缆用阻燃天然橡胶套及其制备方法 Download PDFInfo
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- CN104592569B CN104592569B CN201510011672.7A CN201510011672A CN104592569B CN 104592569 B CN104592569 B CN 104592569B CN 201510011672 A CN201510011672 A CN 201510011672A CN 104592569 B CN104592569 B CN 104592569B
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- natural rubber
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- weight portion
- retardant natural
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- 244000043261 Hevea brasiliensis Species 0.000 title claims abstract description 72
- 229920003052 natural elastomer Polymers 0.000 title claims abstract description 72
- 229920001194 natural rubber Polymers 0.000 title claims abstract description 72
- 239000003063 flame retardant Substances 0.000 title claims abstract description 65
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 229920001971 elastomer Polymers 0.000 claims abstract description 28
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 16
- 238000004073 vulcanization Methods 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 229910001593 boehmite Inorganic materials 0.000 claims abstract description 11
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims abstract description 11
- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229910000022 magnesium bicarbonate Inorganic materials 0.000 claims abstract description 11
- 235000014824 magnesium bicarbonate Nutrition 0.000 claims abstract description 11
- 239000002370 magnesium bicarbonate Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 239000012188 paraffin wax Substances 0.000 claims abstract description 11
- 235000015393 sodium molybdate Nutrition 0.000 claims abstract description 11
- 239000011684 sodium molybdate Substances 0.000 claims abstract description 11
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004305 biphenyl Substances 0.000 claims abstract description 9
- 235000010290 biphenyl Nutrition 0.000 claims abstract description 9
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims abstract description 9
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000010070 extrusion (rubber) Methods 0.000 claims abstract description 7
- 238000000465 moulding Methods 0.000 claims abstract description 7
- 230000008774 maternal effect Effects 0.000 claims abstract description 4
- 238000003801 milling Methods 0.000 claims abstract description 4
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 12
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 12
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 12
- -1 phenyl phosphate ester Chemical class 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 238000005987 sulfurization reaction Methods 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 4
- 125000001246 bromo group Chemical class Br* 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims 2
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 claims 1
- MJSQSKNNMZQLQZ-UHFFFAOYSA-N 1-butylperoxy-2-propan-2-ylbenzene Chemical compound CCCCOOC1=CC=CC=C1C(C)C MJSQSKNNMZQLQZ-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SEPPVOUBHWNCAW-FNORWQNLSA-N (E)-4-oxonon-2-enal Chemical compound CCCCCC(=O)\C=C\C=O SEPPVOUBHWNCAW-FNORWQNLSA-N 0.000 description 1
- LLBZPESJRQGYMB-UHFFFAOYSA-N 4-one Natural products O1C(C(=O)CC)CC(C)C11C2(C)CCC(C3(C)C(C(C)(CO)C(OC4C(C(O)C(O)C(COC5C(C(O)C(O)CO5)OC5C(C(OC6C(C(O)C(O)C(CO)O6)O)C(O)C(CO)O5)OC5C(C(O)C(O)C(C)O5)O)O4)O)CC3)CC3)=C3C2(C)CC1 LLBZPESJRQGYMB-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- MYTXSIIBTKJBCA-UHFFFAOYSA-N O=C(C1=CC=CC=C1)OOC(C1=CC=CC=C1)=O.Cl.Cl Chemical compound O=C(C1=CC=CC=C1)OOC(C1=CC=CC=C1)=O.Cl.Cl MYTXSIIBTKJBCA-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- WYUHQMAEVAHKNJ-UHFFFAOYSA-N benzene;2-propan-2-ylperoxypropane Chemical compound C1=CC=CC=C1.CC(C)OOC(C)C WYUHQMAEVAHKNJ-UHFFFAOYSA-N 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
A1 | A2 | A3 | A4 | A5 | B1 | B2 | B3 | B4 | |
自熄性时间/s | 7 | 6 | 8 | 3 | 2 | 27 | 25 | 27 | 29 |
极限氧指数/% | 23 | 24 | 27 | 29 | 31 | 16 | 18 | 20 | 15 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510011672.7A CN104592569B (zh) | 2015-01-09 | 2015-01-09 | 电缆用阻燃天然橡胶套及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510011672.7A CN104592569B (zh) | 2015-01-09 | 2015-01-09 | 电缆用阻燃天然橡胶套及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN104592569A CN104592569A (zh) | 2015-05-06 |
CN104592569B true CN104592569B (zh) | 2016-08-24 |
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CN201510011672.7A Active CN104592569B (zh) | 2015-01-09 | 2015-01-09 | 电缆用阻燃天然橡胶套及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN104592569B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105419035A (zh) * | 2016-01-12 | 2016-03-23 | 芜湖航天特种电缆厂股份有限公司 | 一种抗拉伸电缆橡胶套及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040147659A1 (en) * | 2002-10-16 | 2004-07-29 | Nabaltec Nabwerk Aluminiumhydroxid Technologie GmbH | Flame retardant polymer composition |
CN102977585A (zh) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | 一种聚氨酯阻燃环保电缆料及其制备方法 |
CN103102544A (zh) * | 2012-11-14 | 2013-05-15 | 安徽金桥电缆有限公司 | 一种低烟无卤阻燃电缆料及其制备方法 |
CN103788436A (zh) * | 2014-01-16 | 2014-05-14 | 安徽复兴电缆集团有限公司 | 一种阻燃矿用电缆护套材料 |
CN103788426A (zh) * | 2014-01-21 | 2014-05-14 | 安徽华海特种电缆集团有限公司 | 一种防腐油井用电缆护套材料 |
-
2015
- 2015-01-09 CN CN201510011672.7A patent/CN104592569B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040147659A1 (en) * | 2002-10-16 | 2004-07-29 | Nabaltec Nabwerk Aluminiumhydroxid Technologie GmbH | Flame retardant polymer composition |
CN102977585A (zh) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | 一种聚氨酯阻燃环保电缆料及其制备方法 |
CN103102544A (zh) * | 2012-11-14 | 2013-05-15 | 安徽金桥电缆有限公司 | 一种低烟无卤阻燃电缆料及其制备方法 |
CN103788436A (zh) * | 2014-01-16 | 2014-05-14 | 安徽复兴电缆集团有限公司 | 一种阻燃矿用电缆护套材料 |
CN103788426A (zh) * | 2014-01-21 | 2014-05-14 | 安徽华海特种电缆集团有限公司 | 一种防腐油井用电缆护套材料 |
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Publication number | Publication date |
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CN104592569A (zh) | 2015-05-06 |
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Address after: 241000 Wuhu high tech Development Zone, Anhui, No. 15 Zhanghe Road Applicant after: WUHU SPACEFLIGHT SPECIAL CABLE FACTORY CO., LTD. Address before: 241000 Wuhu high tech Development Zone, Anhui, No. 15 Zhanghe Road Applicant before: Wuhu Aerospace Special Cable Factory |
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Inventor after: Fu Yonghai Inventor before: She Chen Inventor before: He Chenglong Inventor before: He Yuan Inventor before: Yang Chenfen |
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Effective date of registration: 20171220 Address after: 236800 Anhui Bozhou City Qiaocheng Xintiandi WAL-MART International Shopping Plaza, Bozhou Qiaocheng District, Guangming Road, Anhui Patentee after: Bozhou Jingxing Network Technology Co. Ltd. Address before: 241000 Wuhu high tech Development Zone, Anhui, No. 15 Zhanghe Road Patentee before: WUHU SPACEFLIGHT SPECIAL CABLE FACTORY CO., LTD. |
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Effective date of registration: 20191113 Address after: Zi Zi Xiang Zi Zi Cun, Quanjiao County, Chuzhou City, Anhui Province Patentee after: Chuzhou Junyue High Polymer New Material Co., Ltd. Address before: 236800 Anhui Bozhou City Qiaocheng Xintiandi WAL-MART International Shopping Plaza, Bozhou Qiaocheng District, Guangming Road, Anhui Patentee before: Bozhou Jingxing Network Technology Co. Ltd. |
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