CN104446139B - A kind of stone material architecture adhesion agent and preparation method thereof - Google Patents
A kind of stone material architecture adhesion agent and preparation method thereof Download PDFInfo
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- CN104446139B CN104446139B CN201410684663.XA CN201410684663A CN104446139B CN 104446139 B CN104446139 B CN 104446139B CN 201410684663 A CN201410684663 A CN 201410684663A CN 104446139 B CN104446139 B CN 104446139B
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Abstract
Stone material architecture adhesion agent of the present invention; Be made up of the raw material of following weight number: nano oxidized boron 10 ~ 12 parts, nano barium phthalate 1 ~ 1.5 part, propylenedicarboxylic acid 12 ~ 15 parts, 9 ~ 12 parts, hydroxyethyl urea, polyoxyethylene glycol 20 ~ 25 parts, tetraethoxy 6 ~ 9 parts, Natvosol 9 ~ 12 parts, 6101 epoxy resin 22 ~ 28 parts, 12 ~ 15 parts, ultra-fine albite powder, sodium starch glycolate 8 ~ 10 parts, quadrol 6 ~ 9 parts.This stone material architecture adhesion agent, has outstanding bonding force, does is stretching adhesive strength 1.51? Mpa; And intensity is high, heatproof, water-fast, ageing-resistant performance is excellent, and the back draft adhesive strength after thermal ageing is 1.39Mpa; Good bonding strength is had to all kinds of main stone material.
Description
Technical field
The invention belongs to building material field, relate to a kind of architecture adhesion agent, more particularly, relate to a kind of stone material architecture adhesion agent and preparation method thereof.
Background technology
Over nearly 20 years, along with the fast development of building industry and the raising day by day of Popular Aesthetics standard, building decoration material develops into the phase of prosperity.The market requirement products such as in large size, the high compaction of the finishing material being representative with stone material, ceramic tile, require that tackiness agent supporting with it should possess remarkable adhesiveproperties, lower shrinking percentage and the usage safety performance in extreme environment, and in the urgent need to a kind of can the high-performance stone adhesive of rapid construction.
Stone adhesive (having another name called " stone material binding agent " " stone material glue ") is as the term suggests be exactly a kind of clay being used for pasting various stone material.The decoration demand of modern architecture to stone material is increasing, and to the aesthetics of stone decoration, firmness constantly improves, so general cement can not meet the demand of architectural design.The birth of stone adhesive, is just used to the requirement for meeting stone material stickup.Market has several different kind, cloud stone glue, AB glue, the glue of silicon cave glue etc. and so on is all difficult construction, is not durable, easily aging.Stone adhesive is exactly to bond with stone material well, and easily, working life is long in construction, is more suitable for the construction of large-scale stone material.
Summary of the invention
The object of the invention is to overcome deficiency of the prior art, provides a kind of stone material architecture adhesion agent, and this stone material architecture adhesion agent, have outstanding bonding force, and intensity is high, and heatproof, water-fast, ageing-resistant performance is excellent; Good bonding strength is had to all kinds of main stone material.
Stone material architecture adhesion agent of the present invention; Be made up of the raw material of following parts by weight: nano oxidized boron 10 ~ 12 parts, nano barium phthalate 1 ~ 1.5 part, propylenedicarboxylic acid 12 ~ 15 parts, 9 ~ 12 parts, hydroxyethyl urea, polyoxyethylene glycol 20 ~ 25 parts, tetraethoxy 6 ~ 9 parts, Natvosol 9 ~ 12 parts, 6101 epoxy resin 22 ~ 28 parts, 12 ~ 15 parts, ultra-fine albite powder, sodium starch glycolate 8 ~ 10 parts, quadrol 6 ~ 9 parts.
As optimization, this stone material architecture adhesion agent, is made up of the raw material of following parts by weight: the nano oxidized boron 11 parts of median size 20nm, the nano barium phthalate 1.2 parts of median size 30nm, propylenedicarboxylic acid 13 parts, 9 parts, hydroxyethyl urea, polyoxyethylene glycol 22 parts, tetraethoxy 8 parts, Natvosol 10 parts, 6101 epoxy resin 25 parts, 13 parts, ultra-fine albite powder, sodium starch glycolate 9 parts, quadrol 8 parts.
Prepare the method for this material architecture adhesion agent, comprise the following steps:
(1) by the nano barium phthalate 1.2 parts mixing of polyoxyethylene glycol 22 parts, tetraethoxy 8 parts, propylenedicarboxylic acid 13 parts, 9 parts, hydroxyethyl urea, median size 30nm, 30 minutes are stirred with the speed of 400 ~ 500 turns/min under 130 ~ 150 DEG C of conditions, then add the nano oxidized boron 11 parts of median size 20nm, stir 10 minutes with the speed of 600 ~ 800 turns/min;
(2) 6101 epoxy resin 25 parts, the mixing of 13 parts, ultra-fine albite powder, Natvosol 10 parts, sodium starch glycolate 9 parts are joined in the mixture in step (1) successively, stir 15 minutes with the speed of 300 ~ 400 turns/min; Then under 80 ~ 90 DEG C of conditions, with Hangzhou Success Ultrasonic Equipment Co., Ltd YPS59B ultrasonic stirring dispersion machine process 40 minutes; Then add quadrol 8 parts to stir 5 minutes with the speed of 800 ~ 1000 turns/min.
Detect according to the standard-required of JC/T547-2005C2, detected result shows.This stone material architecture adhesion agent, has outstanding bonding force, and stretching adhesive strength is 1.51Mpa; And intensity is high, heatproof, water-fast, ageing-resistant performance is excellent, and stretching adhesive strength after after thermal ageing is 1.39Mpa; Good bonding strength is had to all kinds of stone materials.
Embodiment
The invention will be further described for embodiment plan given below; but can not be interpreted as it is limiting the scope of the invention; those skilled in the art to nonessential improvement and adjustment more of the present invention, still belong to protection scope of the present invention according to content of the present invention.
Embodiment 1:(1) by the nano barium phthalate 1.2 kilograms mixing of polyoxyethylene glycol 22 kilograms, tetraethoxy 8 kilograms, propylenedicarboxylic acid 13 kilograms, 9 kilograms, hydroxyethyl urea, median size 30nm, 30 minutes are stirred with the speed of 400 ~ 500 turns/min under 130 ~ 150 DEG C of conditions, then add the nano oxidized boron 11 kilograms of median size 20nm, stir 10 minutes with the speed of 600 ~ 800 turns/min;
(2) Ba Ling petrochemical industry 6101 epoxy resin 25 kilograms, the 13 kilograms of mixing of the ultra-fine albite powder of 1250 order, Natvosol 10 kilograms, sodium starch glycolate 9 kilograms are joined in the mixture in step (1) successively, stir 15 minutes with the speed of 300 ~ 400 turns/min; Then under 80 ~ 90 DEG C of conditions, with ultrasonic stirring dispersion machine process 40 minutes; Add quadrol 8 kilograms to stir 5 minutes with the speed of 800 ~ 1000 turns/min;
Detect according to the standard-required of JC/T547-2005C2, detected result is as following table 1.
Embodiment 2:(1) by the nano barium phthalate 1 kilogram mixing of polyoxyethylene glycol 20 kilograms, tetraethoxy 6 kilograms, propylenedicarboxylic acid 12 kilograms, 9 kilograms, hydroxyethyl urea, median size 30nm, 30 minutes are stirred with the speed of 400 ~ 500 turns/min under 130 ~ 150 DEG C of conditions, then add the nano oxidized boron 10 kilograms of median size 20nm, stir 10 minutes with the speed of 600 ~ 800 turns/min;
(2) 6101 epoxy resin 22 kilograms, the 12 kilograms of mixing of the ultra-fine albite powder of 1250 order, Natvosol 9 kilograms, sodium starch glycolate 8 kilograms are joined in the mixture in step (1) successively, stir 15 minutes with the speed of 300 ~ 400 turns/min; Then under 80 ~ 90 DEG C of conditions, with ultrasonic stirring dispersion machine process 40 minutes; Add quadrol 6 kilograms to stir 5 minutes with the speed of 800 ~ 1000 turns/min;
Detect according to the standard-required of JC/T547-2005C2, detected result is as following table 2.
Embodiment 3:(1) by the nano barium phthalate 1.5 kilograms mixing of polyoxyethylene glycol 25 kilograms, tetraethoxy 9 kilograms, propylenedicarboxylic acid 15 kilograms, 12 kilograms, hydroxyethyl urea, median size 30nm, 30 minutes are stirred with the speed of 400 ~ 500 turns/min under 130 ~ 150 DEG C of conditions, then add the nano oxidized boron 12 kilograms of median size 20nm, stir 10 minutes with the speed of 600 ~ 800 turns/min;
(2) 6101 epoxy resin 28 kilograms, the 15 kilograms of mixing of the ultra-fine albite powder of 1250 order, Natvosol 12 kilograms, sodium starch glycolate 10 kilograms are joined in the mixture in step (1) successively, stir 15 minutes with the speed of 300 ~ 400 turns/min; Then under 80 ~ 90 DEG C of conditions, with ultrasonic stirring dispersion machine process 40 minutes; Add quadrol 9 kilograms to stir 5 minutes with the speed of 800 ~ 1000 turns/min;
Detect according to the standard-required of JC/T547-2005C2, detected result is as following table 3.
Claims (3)
1. a stone material architecture adhesion agent, is characterized in that by the raw material of following parts by weight: nano oxidized boron 10 ~ 12 parts, nano barium phthalate 1 ~ 1.5 part, propylenedicarboxylic acid 12 ~ 15 parts, 9 ~ 12 parts, hydroxyethyl urea, polyoxyethylene glycol 20 ~ 25 parts, tetraethoxy 6 ~ 9 parts, Natvosol 9 ~ 12 parts, 6101 epoxy resin 22 ~ 28 parts, 12 ~ 15 parts, ultra-fine albite powder, sodium starch glycolate 8 ~ 10 parts, quadrol 6 ~ 9 parts are made.
2. stone material architecture adhesion agent according to claim 1, is characterized in that being made up of the raw material of following parts by weight: the nano oxidized boron 11 parts of median size 20nm, the nano barium phthalate 1.2 parts of median size 30nm, propylenedicarboxylic acid 13 parts, 9 parts, hydroxyethyl urea, polyoxyethylene glycol 22 parts, tetraethoxy 8 parts, Natvosol 10 parts, 6101 epoxy resin 25 parts, 13 parts, ultra-fine albite powder, sodium starch glycolate 9 parts, quadrol 8 parts.
3. prepare a method for stone material architecture adhesion agent described in claim 2, it is characterized in that comprising the following steps:
(1) by the nano barium phthalate 1.2 parts mixing of polyoxyethylene glycol 22 parts, tetraethoxy 8 parts, propylenedicarboxylic acid 13 parts, 9 parts, hydroxyethyl urea, median size 30nm, 30 minutes are stirred with the speed of 400 ~ 500 turns/min under 130 ~ 150 DEG C of conditions, then add the nano oxidized boron 11 parts of median size 20nm, stir 10 minutes with the speed of 600 ~ 800 turns/min;
(2) 6101 epoxy resin 25 parts, the mixing of 13 parts, ultra-fine albite powder, Natvosol 10 parts, sodium starch glycolate 9 parts are joined in the mixture in step (1) successively, stir 15 minutes with the speed of 300 ~ 400 turns/min; Then under 80 ~ 90 DEG C of conditions, with ultrasonic stirring dispersion machine process 40 minutes; Add quadrol 8 parts to stir 5 minutes with the speed of 800 ~ 1000 turns/min.
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| CN201410684663.XA CN104446139B (en) | 2014-11-25 | 2014-11-25 | A kind of stone material architecture adhesion agent and preparation method thereof |
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| CN201410684663.XA CN104446139B (en) | 2014-11-25 | 2014-11-25 | A kind of stone material architecture adhesion agent and preparation method thereof |
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| CN104446139A CN104446139A (en) | 2015-03-25 |
| CN104446139B true CN104446139B (en) | 2016-04-27 |
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| CN106149938A (en) * | 2016-08-17 | 2016-11-23 | 中国十七冶集团有限公司 | The U-shaped steel of a kind of cold bending thin wall and the composite floor of straw board and manufacture method |
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| CN102690080B (en) * | 2012-06-06 | 2013-09-18 | 湖南柯盛新材料有限公司 | Rough stone block reinforcement adhesive and using method thereof |
| KR101382374B1 (en) * | 2012-07-05 | 2014-04-08 | 대한민국 | Epoxy resin adhesive for conservation treatment of stone cultural heritage |
| CN103865460B (en) * | 2014-03-13 | 2016-01-20 | 漳州市奈特新型建材有限责任公司 | Resin combination and its preparation method and application |
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Inventor after: Shang Feng Inventor after: Ge Haifeng Inventor after: Wang Zhiyong Inventor after: Sun Yuling Inventor after: He Zhihua Inventor after: Li Ming Inventor after: Jiang Hongyu Inventor after: Chen Hongfang Inventor after: Zheng Wenpeng Inventor after: Lai Qingbin Inventor before: Li Baoji |
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Effective date of registration: 20160317 Address after: 471000, Luoyang City, Henan province Luolong ancient city road, Tang Dynasty Supreme 20-3-1811 Applicant after: Yan Siliang Address before: 030009 Taiyuan University of Technology, 79 West Avenue, Wan Berlin District, Shanxi, Taiyuan, Yingze Applicant before: Li Baoji |
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