CN104263145A - Water-based thermosetting glass winebottle stoving varnish and preparation method thereof - Google Patents
Water-based thermosetting glass winebottle stoving varnish and preparation method thereof Download PDFInfo
- Publication number
- CN104263145A CN104263145A CN201410436119.3A CN201410436119A CN104263145A CN 104263145 A CN104263145 A CN 104263145A CN 201410436119 A CN201410436119 A CN 201410436119A CN 104263145 A CN104263145 A CN 104263145A
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- CN
- China
- Prior art keywords
- water
- wine bottle
- baking vanish
- acrylic resin
- thermosetting glass
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Surface Treatment Of Glass (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a water-based thermosetting glass winebottle stoving varnish and a preparation method thereof. The water-based thermosetting glass winebottle stoving varnish consists of a colorant, a water-based acrylic resin solution, amino resin, a dispersing agent BYK-191, an addition agent and water. The preparation method comprises the following steps: mixing a part of water-based acrylic resin solution with the dispersing agent BYK-191, the colorant and the addition agent, carrying out shear dispersing to solid grain size not greater than 10mu m to obtain a sizing agent; adding the remained water-based acrylic resin solution, amino resin, cosolvent and water in the sizing agent and stirring uniformly to obtain the varnish. The preparation method is simple; the materials are low in price; the prepared water-based thermosetting glass winebottle stoving varnish is low in cost and environment-friendly, and has the characteristics of good adhesive force to glass substrates, good alcohol-resistant, water-resistant and abrasion-resistant performances and high hardness, and the like.
Description
Technical field
The present invention relates to a kind of aqueous thermosetting glass wine bottle baking vanish and preparation method thereof, belong to bottle baking vanish field.
Background technology
The coating protection of glass and glasswork has demand widely, as bottle, lamp decoration, scent flask, lens and glassware etc. all need protective layer and decorative coveringn with decoration in industry and civilian neighborhood.At present, the glass paint of domestic application mostly is solvent based product, in production and application, have employed the organic solvents such as a large amount of benzene classes, there is following shortcoming: 1) VOC content is high, VOC is acknowledged as one of primary pollution source of current global atmosphere pollution, and solvent based coating can give out a large amount of VOC, because water-miscible paint uses water as dissolving carrier, so no matter be in its production process, when being also used to application, give out VOC to air hardly.2) organic solvent toxicity is large, and harm operator's is healthy.3) reinforcement of environmental regulation, the production of such solvent based coating and range of application are narrowing.
Summary of the invention
The object of the invention is to be to provide that a kind of cost is low, environmental protection, have sticking power good to glass substrate, resistance to alcohol, water-fast and wear resisting property good, the aqueous thermosetting glass wine bottle baking vanish of hardness high.
Another object of the present invention is to provide a kind of simple to operate, method that low cost prepares described aqueous thermosetting glass wine bottle baking vanish.
The invention provides a kind of aqueous thermosetting glass wine bottle baking vanish, this glass wine bottle baking vanish is made up of following mass percent component:
Described water-borne acrylic resin solution solid content is 30% ~ 60%, and wherein, water-borne acrylic resin is for containing one or more groups in carboxyl, hydroxyl or siloxanes, and the polymkeric substance of molecular weight between 30000 ~ 60000.
Preferred aminoresin is full methyl-etherified melamine resin, part methyl-etherified melamine resin or high imino-methyl-etherified melamine resin; Most preferably be the special C303 of U.S.'s cyanogen and/or the special C325 of U.S.'s cyanogen.
Preferred staining agent is metallized dye and/or many rings pigment dyestuff; Most preferably be that metallized dye rhodo, metallized dye are sky blue, No. 254, pigment dyestuff red in one or more.
Preferred auxiliary agent is one or more in defoamer, flow agent, dispersing auxiliary, solubility promoter, PH conditioning agent, thickening material, adhesion promoter.
Preferred defoamer is polyether siloxane copolymer, as TEGO 904W.
Preferred PH conditioning agent is AMP-95 or dimethylethanolamine.
Preferred thickening material is polyurethanes thickening material.
Preferred solubility promoter is one or more in butyl glycol ether, butyl, ethanol; Most preferably be ethanol.
Preferred dispersing auxiliary is TEGO505.
Most preferred aqueous thermosetting glass wine bottle baking vanish formula is made up of following mass percent component:
Described water-borne acrylic resin solution solid content is 40% ~ 50%, and wherein, water-borne acrylic resin is for containing one or more groups in carboxyl, hydroxyl or siloxanes, and the multipolymer of molecular weight between 40000 ~ 50000.
Present invention also offers a kind of preparation method of described aqueous thermosetting glass wine bottle baking vanish, this preparation method is by part water-borne acrylic resin solution, mix with dispersant B YK-191, staining agent and auxiliary agent and shear and be dispersed to granularity and be not more than 10 microns, obtain slurry; Remaining part water-borne acrylic resin solution is added in described slurry, and aminoresin, solubility promoter and water, stir, to obtain final product.
Beneficial effect of the present invention: the present invention is by selecting water-borne acrylic resin solution, aminoresin and the dispersant B YK-191 etc. that matching is good, it is good that composite acquisition by a certain percentage has sticking power to glass substrate, resistance to alcohol, water-fast and wear resisting property good, the aqueous thermosetting glass baking varnish formula of the features such as strong hardness, this formula environmental protection, raw material low cost, fire-retardant, be applicable to promoting the use of on a large scale.In addition, aqueous thermosetting glass wine bottle baking vanish preparation method of the present invention is simple, meets industrial production.
Embodiment
Following examples are intended to further illustrate content of the present invention, instead of limit the scope of the invention.
Aqueous thermosetting bottle baking vanish is a kind of conventional glasswork pigmented coating, it needs to reach following requirement: 60 ° of gloss >90 of paint film, pencil hardness is 2H, sticking power <1 level, alcohol resistance (soaking 95% ethanol) >60 time; Alap VOC, does not contain hazardous substance; Pigment particle size is little and the control of narrowly distributing, fineness is less than 15 microns; PH value controls 7.5 ~ 9.5.
Embodiment 1
According to following formula composition, prepare aqueous thermosetting glass wine bottle baking vanish of the present invention: according to formula first by part water-borne acrylic resin solution (first adding about 70% of aqueous resin solution total mass), dispersant B YK191, staining agent etc. join in container, high speed shear is dispersed to fineness and reaches less than 10 microns, makes slurry; Again remaining water-borne acrylic resin solution, aminoresin, dispersing auxiliary, deionized water etc. are added in slurry, stir.Last adjusting viscosity, to prescribed value, namely obtains water fever curable type bottle paint product with screen filtrations more than 300 orders.
Below fill a prescription and 1 ~ 8 to adjust by 100 parts.
Draw samples carries out application performance test below, the test of sheet glass spraying paint film.
Get the water-based bottle baking vanish that a certain amount of above formula makes, be sprayed on the armourplate glass of 120mm*230mm*3mm, after room temperature surface drying, put into baking oven baking, 180 DEG C of bakings 8 minutes, coating thickness controlled at 10 ± 1 μm.Sheet glass is put into after 12h is placed in moisture eliminator cooling and detect film performance.Draw following detected result.
Claims (9)
1. an aqueous thermosetting glass wine bottle baking vanish, is characterized in that, is made up of following mass percent component:
Described water-borne acrylic resin solution solid content is 30% ~ 60%, and wherein, water-borne acrylic resin is for containing one or more groups in carboxyl, hydroxyl or siloxanes, and the polymkeric substance of molecular weight between 30000 ~ 60000.
2. aqueous thermosetting glass wine bottle baking vanish as claimed in claim 1, is characterized in that, described aminoresin is the special C303 of U.S.'s cyanogen and/or the special C325 of U.S.'s cyanogen.
3. aqueous thermosetting glass wine bottle baking vanish as claimed in claim 1, it is characterized in that, described staining agent is metallized dye and/or many rings pigment dyestuff.
4. aqueous thermosetting glass wine bottle baking vanish as claimed in claim 3, is characterized in that, described staining agent is that metallized dye rhodo, metallized dye are sky blue, No. 254, pigment dyestuff red in one or more.
5. aqueous thermosetting glass wine bottle baking vanish as claimed in claim 1, it is characterized in that, described auxiliary agent is one or more in defoamer, flow agent, dispersing auxiliary, solubility promoter, PH conditioning agent, thickening material, adhesion promoter.
6. the aqueous thermosetting glass wine bottle baking vanish as described in any one of Claims 1 to 5, is characterized in that, is made up of following mass percent component:
Described water-borne acrylic resin solution solid content is 40% ~ 50%, and wherein, water-borne acrylic resin is for containing one or more groups in carboxyl, hydroxyl or siloxanes, and the polymkeric substance of molecular weight between 40000 ~ 50000.
7. aqueous thermosetting glass wine bottle baking vanish as claimed in claim 1, it is characterized in that, described solubility promoter is one or more in butyl glycol ether, butyl, ethanol.
8. aqueous thermosetting glass wine bottle baking vanish as claimed in claim 1, it is characterized in that, described dispersing auxiliary is TEGO505.
9. the preparation method of an aqueous thermosetting glass wine bottle baking vanish as claimed in claim 1, it is characterized in that, by part water-borne acrylic resin solution, mix with dispersant B YK-191, staining agent and auxiliary agent and shear and be dispersed to granularity and be not more than 10 microns, obtain slurry; Remaining part water-borne acrylic resin solution is added in described slurry, and aminoresin, solubility promoter and water, stir, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410436119.3A CN104263145A (en) | 2014-08-29 | 2014-08-29 | Water-based thermosetting glass winebottle stoving varnish and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410436119.3A CN104263145A (en) | 2014-08-29 | 2014-08-29 | Water-based thermosetting glass winebottle stoving varnish and preparation method thereof |
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| CN104263145A true CN104263145A (en) | 2015-01-07 |
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| CN201410436119.3A Pending CN104263145A (en) | 2014-08-29 | 2014-08-29 | Water-based thermosetting glass winebottle stoving varnish and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927526A (en) * | 2015-07-08 | 2015-09-23 | 安庆联泰电子科技有限公司 | Water-borne acrylic amino baking varnish special for intelligent ashtray metal shell |
| CN106147443A (en) * | 2016-07-01 | 2016-11-23 | 太仓市金新涂料有限公司 | A kind of luster, high-hardness and high modification acrylic acrylic acid baking vanish and preparation method thereof |
| CN106221515A (en) * | 2016-08-30 | 2016-12-14 | 广州产协高分子有限公司 | A kind of water paint for bottle and preparation method thereof |
| CN106280843A (en) * | 2016-08-04 | 2017-01-04 | 丹阳市日月漆业有限公司 | A kind of acrylic resin modified anti-flaming dope |
| CN107083138A (en) * | 2016-05-20 | 2017-08-22 | 南京长江涂料有限公司 | A kind of glass wine bottle base material water soluble acrylic acid amido coatings soaked based on resistance to wine |
| CN108300036A (en) * | 2017-08-29 | 2018-07-20 | 河北晨阳工贸集团有限公司 | A kind of farm implement aqueous dip-coating baking vanish and preparation method thereof |
| CN108410227A (en) * | 2018-03-01 | 2018-08-17 | 温州环诺新材料科技有限公司 | A kind of universal aqueous wheel hub baking vanish |
| CN109535903A (en) * | 2018-11-06 | 2019-03-29 | 韶关市合众化工有限公司 | A kind of preparation method of the fire-retardant baking vanish of water soluble acrylic acid amino of coating automotive oil tank |
| CN109535870A (en) * | 2017-07-25 | 2019-03-29 | 佩特化工(上海)有限公司 | A kind of highlight water-based coating of perfume glass bottle |
| CN111234636A (en) * | 2020-03-31 | 2020-06-05 | 浙江材华科技有限公司 | Macromolecular coloring agent type transparent water-based glass baking varnish and preparation method thereof |
| IT201900019896A1 (en) * | 2019-10-28 | 2021-04-28 | Ambrosia Srl | COMPOUND FOR THE COATING OF AN OBJECT MADE OF GLASS AND / OR CERAMIC AND GLASS AND / OR CERAMIC OBJECT COVERED WITH THIS COMPOUND |
| CN116179033A (en) * | 2023-02-14 | 2023-05-30 | 陈宏华 | Water-based glass varnish and preparation method thereof |
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| CN101845255A (en) * | 2010-03-09 | 2010-09-29 | 汉森漆业(福建)有限公司 | Water-based baking paint for glass substrate and preparation and use methods thereof |
| CN102492354A (en) * | 2011-11-25 | 2012-06-13 | 上海涂料有限公司上海造漆厂 | Water-based baking coating for anti-theft door as well as preparation method and application thereof |
| CN102821948A (en) * | 2010-03-30 | 2012-12-12 | 新日铁住金不锈钢株式会社 | Clear-coated stainless steel sheet with excellent pressure mark resistance and scratch resistance |
| CN103113797A (en) * | 2012-05-11 | 2013-05-22 | 哈尔滨博元生物科技有限公司 | Single-component aqueous environment-friendly glass paint |
-
2014
- 2014-08-29 CN CN201410436119.3A patent/CN104263145A/en active Pending
Patent Citations (4)
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| CN101845255A (en) * | 2010-03-09 | 2010-09-29 | 汉森漆业(福建)有限公司 | Water-based baking paint for glass substrate and preparation and use methods thereof |
| CN102821948A (en) * | 2010-03-30 | 2012-12-12 | 新日铁住金不锈钢株式会社 | Clear-coated stainless steel sheet with excellent pressure mark resistance and scratch resistance |
| CN102492354A (en) * | 2011-11-25 | 2012-06-13 | 上海涂料有限公司上海造漆厂 | Water-based baking coating for anti-theft door as well as preparation method and application thereof |
| CN103113797A (en) * | 2012-05-11 | 2013-05-22 | 哈尔滨博元生物科技有限公司 | Single-component aqueous environment-friendly glass paint |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104927526A (en) * | 2015-07-08 | 2015-09-23 | 安庆联泰电子科技有限公司 | Water-borne acrylic amino baking varnish special for intelligent ashtray metal shell |
| CN107083138A (en) * | 2016-05-20 | 2017-08-22 | 南京长江涂料有限公司 | A kind of glass wine bottle base material water soluble acrylic acid amido coatings soaked based on resistance to wine |
| CN107083138B (en) * | 2016-05-20 | 2020-06-19 | 南京长江涂料有限公司 | Water-based acrylic amino coating based on wine soaking resistance for glass wine bottle base material |
| CN106147443A (en) * | 2016-07-01 | 2016-11-23 | 太仓市金新涂料有限公司 | A kind of luster, high-hardness and high modification acrylic acrylic acid baking vanish and preparation method thereof |
| CN106280843A (en) * | 2016-08-04 | 2017-01-04 | 丹阳市日月漆业有限公司 | A kind of acrylic resin modified anti-flaming dope |
| CN106221515A (en) * | 2016-08-30 | 2016-12-14 | 广州产协高分子有限公司 | A kind of water paint for bottle and preparation method thereof |
| CN106221515B (en) * | 2016-08-30 | 2019-08-06 | 广州产协高分子有限公司 | A kind of water paint and preparation method thereof for bottle |
| CN109535870A (en) * | 2017-07-25 | 2019-03-29 | 佩特化工(上海)有限公司 | A kind of highlight water-based coating of perfume glass bottle |
| CN109535870B (en) * | 2017-07-25 | 2021-03-02 | 佩特化工(上海)有限公司 | High-gloss water-based paint for perfume glass bottle |
| CN108300036A (en) * | 2017-08-29 | 2018-07-20 | 河北晨阳工贸集团有限公司 | A kind of farm implement aqueous dip-coating baking vanish and preparation method thereof |
| CN108410227A (en) * | 2018-03-01 | 2018-08-17 | 温州环诺新材料科技有限公司 | A kind of universal aqueous wheel hub baking vanish |
| CN109535903A (en) * | 2018-11-06 | 2019-03-29 | 韶关市合众化工有限公司 | A kind of preparation method of the fire-retardant baking vanish of water soluble acrylic acid amino of coating automotive oil tank |
| IT201900019896A1 (en) * | 2019-10-28 | 2021-04-28 | Ambrosia Srl | COMPOUND FOR THE COATING OF AN OBJECT MADE OF GLASS AND / OR CERAMIC AND GLASS AND / OR CERAMIC OBJECT COVERED WITH THIS COMPOUND |
| WO2021084414A1 (en) * | 2019-10-28 | 2021-05-06 | Ambrosia Srl | Coating for an object made of glass and/or ceramic and glass and/or ceramic object comprising said coating |
| CN111234636A (en) * | 2020-03-31 | 2020-06-05 | 浙江材华科技有限公司 | Macromolecular coloring agent type transparent water-based glass baking varnish and preparation method thereof |
| CN116179033A (en) * | 2023-02-14 | 2023-05-30 | 陈宏华 | Water-based glass varnish and preparation method thereof |
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| C06 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150107 |
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| RJ01 | Rejection of invention patent application after publication |