CN104211159B - Surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device - Google Patents
Surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device Download PDFInfo
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- CN104211159B CN104211159B CN201410424797.8A CN201410424797A CN104211159B CN 104211159 B CN104211159 B CN 104211159B CN 201410424797 A CN201410424797 A CN 201410424797A CN 104211159 B CN104211159 B CN 104211159B
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- water
- waste water
- aerating apparatus
- surfactivity
- ejector
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- 239000002351 wastewater Substances 0.000 title claims abstract description 37
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 239000003054 catalyst Substances 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 43
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000005276 aerator Methods 0.000 claims abstract description 11
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 10
- 239000002033 PVDF binder Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims abstract description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 238000005273 aeration Methods 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- -1 glycerin fatty acid ester Chemical class 0.000 claims description 9
- 235000011187 glycerol Nutrition 0.000 claims description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000012528 membrane Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 238000006555 catalytic reaction Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000010865 sewage Substances 0.000 abstract description 2
- 239000003814 drug Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000019600 saltiness Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009279 wet oxidation reaction Methods 0.000 description 1
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- Separation Using Semi-Permeable Membranes (AREA)
- Catalysts (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The present invention relates to surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device, belong to sewage treatment area, apparatus of the present invention are made up of former water inlet (1), exhaust outlet (2), water distributor (3), aerating apparatus (4), filling tube (5), air water redistributor (6), air channel (7), effluent weir (8), effluent collection place (9), high-pressure pump (10), ejector (11) and diaphragm type aerator (12); Ejector (11) is connected with high-pressure pump (10), water distributor (3) is connected with former water inlet (1), be positioned at aerating apparatus (4) below, it is inner that filling tube (5) is placed in aerating apparatus (4).Ejector of the present invention adopts PVDF as valve body material, and abradability spy is excellent, and physical strength is large, sturdy and durable corrosion-resistant; This device saves production cost, practical, and clearance is high, and the clearance of the high-concentration ammonia nitrogenous wastewater after apparatus of the present invention process, up to more than 99.9%, alleviates the pollution to environment.
Description
Technical field
The invention discloses surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device, belong to sewage treatment area.
Background technology
Pharmaceutical industry waste water mainly comprises washing water and the large class of flushing waste water four of antibiotic production wastewater, synthetic drugs factory effluent, Chinese patent medicine production wastewater and all kinds of formulation manufacturing processes.The feature of its waste water is complicated component, organic content is high, toxicity is large, colourity is dark and saltiness is high, and particularly biochemical is very poor, and intermittently discharged, belong to unmanageable trade effluent.Along with the development of China's medicine industry, pharmacy waste water becomes one of important source of pollution gradually, how to process the difficult problem that such waste water is current environment protection.
At present, the method utilizing catalyst effect to make high-concentration ammonia nitrogen in waste water change into nitrogen becomes possibility, such as: Lee fish, the one that Zhang Rong etc. describe in document " ammonia nitrogen in Co_Bi catalyst wet oxidation degraded percolate " processes high-concentration ammonia nitrogenous wastewater with Co/Bi catalyzer, ammonia is converted into nitrogen discharge, but need high temperature 125 ~ 320 DEG C, just katalysis is played under high pressure 0.5 ~ 2.0MPa condition, this certainly will cause the huge consumption of the energy, the processing costs brought thus is too expensive, cannot run in reality generates.Traditional ammonia still process method take water vapour as stripping medium, but need strong basicity environment simultaneously, and the ammonia nitrogen in waste water is with NH
3form drain in air, easily cause secondary pollution risk, in order to eliminate the secondary pollution brought environment, people generally adopt H
2o or dilute sulphuric acid absorb ammonia, but this product utilizing absorption treatment process to obtain is impure, and concentration is too low, does not have marketable value, remains a kind of waste water also existed with ammonia nitrogen in high density.
Summary of the invention
The running cost that the object of the invention is to exist for prior art scheme is high, and power consumption is large, there is secondary pollution problems, provide surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device, solve in prior art and pollute greatly, cost is high, the problem that ammonia nitrogen removal frank is low.
In order to achieve the above object, concrete technical scheme of the present invention is: surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device is made up of former water inlet (1), exhaust outlet (2), water distributor (3), aerating apparatus (4), filling tube (5), air water redistributor (6), air channel (7), effluent weir (8), effluent collection place (9), high-pressure pump (10), ejector (11) and diaphragm type aerator (12); Ejector (11) is connected with high-pressure pump (10), water distributor (3) is connected with former water inlet (1), be positioned at aerating apparatus (4) below, it is inner that filling tube (5) is placed in aerating apparatus (4).
Described ejector (11) adopts PVDF as valve body material, resist chemical and solvent resistant characteristic strong, wear resistant spy is excellent, and physical strength is large, nozzle diameter at 15 ~ 20mm, working pressure 0.15Mpa.
Described aerating apparatus (4) inside is containing diaphragm type aerator (12), and aeration membrane runs average pore 60-80 μm, and air flow quantity is 1.5-3.0m
3/ h, coefficient of oxygen utilization 16.8-28.7%, aeration time controls at about 2.0h; Filling tube has added surfactivity catalyzer glycerin fatty acid ester and fatty acid zinc in (5), and its mass ratio respectively accounts for half.
Principle of work of the present invention is: high-concentration ammonia nitrogenous wastewater flows into former water inlet (1) and enters in water distributor (3), water distributor (3) water distribution uniformity, former water is sent into aerating apparatus (4) via ejector (11) by high-pressure pump (10), ejector (11) adopts PVDF as valve body material, resist chemical and solvent resistant characteristic strong, wear resistant spy is excellent, physical strength is large, nozzle diameter is at 15 ~ 20mm, working pressure 0.15Mpa, aerating apparatus (4) inside is containing diaphragm type aerator, aeration membrane runs average pore 60-80 μm, air flow quantity is 1.5-3.0m
3/ h, coefficient of oxygen utilization 16.8-28.7%, aeration time controls at about 2.0h, filling tube has added surfactivity catalyzer glycerin fatty acid ester and fatty acid zinc in (5), surfactivity catalyzer glycerin fatty acid ester after waste water and air mix completely and in packing layer reacts, reacted waste water carries out catalyzed reaction again through air water redistributor (4), final reaction gained nitrogen is discharged from exhaust outlet (2) by air channel (7), and waste water flow into effluent collection place (9) through effluent weir (8).The clearance of the high-concentration ammonia nitrogenous wastewater after apparatus of the present invention process is up to more than 99.9%.
Significant advantage of the present invention is:
(1) ejector adopts PVDF as valve body material, and abradability spy is excellent, and physical strength is large, sturdy and durable corrosion-resistant;
(2) this device saves production cost, practical, alleviates the pollution to environment.
Accompanying drawing explanation
Fig. 1 is schematic diagram of the present invention
Wherein: the former water inlet of 1-, 2-exhaust outlet, 3-water distributor, 4-aerating apparatus, 5-filling tube, 6-air water redistributor, 7-air channel, 8-effluent weir, 9-effluent collection place, 10-high-pressure pump, 11-ejector, 12-diaphragm type aerator.
Embodiment
Below in conjunction with drawings and Examples, technical solution of the present invention is further illustrated.
As shown in Figure 1, the invention provides surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device, be made up of former water inlet (1), exhaust outlet (2), water distributor (3), aerating apparatus (4), filling tube (5), air water redistributor (6), air channel (7), effluent weir (8), effluent collection place (9), high-pressure pump (10), ejector (11) and diaphragm type aerator (12); Ejector (11) is connected with high-pressure pump (10), water distributor (3) is connected with former water inlet (1), be positioned at aerating apparatus (4) below, it is inner that filling tube (5) is placed in aerating apparatus (4); Described ejector (11) adopts PVDF as valve body material, resist chemical and solvent resistant characteristic strong, wear resistant spy is excellent, and physical strength is large, nozzle diameter at 15 ~ 20mm, working pressure 0.15Mpa; Described aerating apparatus (4) inside is containing diaphragm type aerator (12), and aeration membrane runs average pore 60-80 μm, and air flow quantity is 1.5-3.0m
3/ h, coefficient of oxygen utilization 16.8-28.7%, aeration time controls at about 2.0h; Filling tube has added surfactivity catalyzer glycerin fatty acid ester and fatty acid zinc in (5).
When a kind of surfactivity catalyst treatment of the present invention pharmacy waste water middle and high concentration ammonia nitrogen device uses, principle of work of the present invention is: high-concentration ammonia nitrogenous wastewater flows into former water inlet (1) and enters in water distributor (3), water distributor (3) water distribution uniformity, former water is sent into aerating apparatus (4) via ejector (11) by high-pressure pump (10), ejector (11) adopts PVDF as valve body material, resist chemical and solvent resistant characteristic strong, wear resistant spy is excellent, physical strength is large, nozzle diameter is at 15 ~ 20mm, working pressure 0.15Mpa, aerating apparatus (4) inside is containing diaphragm type aerator (12), aeration membrane runs average pore 60-80 μm, air flow quantity is 1.5-3.0m
3/ h, coefficient of oxygen utilization 16.8-28.7%, aeration time controls at about 2.0h, filling tube has added surfactivity catalyzer glycerin fatty acid ester and fatty acid zinc in (5), surfactivity catalyzer glycerin fatty acid ester after waste water and air mix completely and in packing layer reacts, reacted waste water carries out catalyzed reaction again through air water redistributor (6), final reaction gained nitrogen is discharged from exhaust outlet (2) by air channel (7), and waste water flow into effluent collection place (9) through effluent weir (8).The clearance of the high-concentration ammonia nitrogenous wastewater after apparatus of the present invention process is up to more than 99.9%.
Above-described the preferred embodiment of the present invention; should be understood that; for a person skilled in the art; under the prerequisite not departing from structure of the present invention; some distortion and improvement can also be made; these also should be considered as protection scope of the present invention, and these all can not affect effect of the present invention and practical applicability.
Claims (3)
1. surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device, is characterized in that: this device is made up of former water inlet (1), exhaust outlet (2), water distributor (3), aerating apparatus (4), filling tube (5), air water redistributor (6), air channel (7), effluent weir (8), effluent collection place (9), high-pressure pump (10), ejector (11) and diaphragm type aerator (12), ejector (11) is connected with high-pressure pump (10), water distributor (3) is connected with former water inlet (1), be positioned at aerating apparatus (4) below, it is inner that filling tube (5) is placed in aerating apparatus (4), high-concentration ammonia nitrogenous wastewater flows into former water inlet (1) and enters in water distributor (3), water distributor (3) water distribution uniformity, former water is sent into aerating apparatus (4) via ejector (11) by high-pressure pump (10), aerating apparatus (4) inside is containing diaphragm type aerator, filling tube has added surfactivity catalyzer glycerin fatty acid ester and fatty acid zinc in (5), surfactivity catalyzer glycerin fatty acid ester after waste water and air mix completely and in packing layer reacts, reacted waste water carries out catalyzed reaction again through air water redistributor (6), final reaction gained nitrogen is discharged from exhaust outlet (2) by air channel (7), waste water flow into effluent collection place (9) through effluent weir (8).
2. surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device according to claim 1, it is characterized in that: described ejector (11) adopts PVDF as valve body material, resist chemical and solvent resistant characteristic strong, wear resistant spy is excellent, physical strength is large, nozzle diameter at 15 ~ 20mm, working pressure 0.15Mpa.
3. surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device according to claim 1, it is characterized in that: described aerating apparatus (4) inside is containing diaphragm type aerator (12), aeration membrane runs average pore 60-80 μm, and air flow quantity is 1.5-3.0m
3/ h, coefficient of oxygen utilization 16.8-28.7%, aeration time controls at 2.0h; Filling tube has added surfactivity catalyzer glycerin fatty acid ester and fatty acid zinc in (5), and its mass ratio respectively accounts for half.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410424797.8A CN104211159B (en) | 2014-08-26 | 2014-08-26 | Surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device |
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| CN201410424797.8A CN104211159B (en) | 2014-08-26 | 2014-08-26 | Surfactivity catalyst treatment pharmacy waste water middle and high concentration ammonia nitrogen device |
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| CN104211159A CN104211159A (en) | 2014-12-17 |
| CN104211159B true CN104211159B (en) | 2016-03-09 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323493A (en) * | 2008-07-24 | 2008-12-17 | 华南理工大学 | Waste water treatment apparatus based on ozone oxidation and aerating biological filter |
| CN102295328A (en) * | 2011-08-09 | 2011-12-28 | 江苏林格纯水设备有限公司 | Iron-carbon micro-electrolysis apparatus |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2672200B2 (en) * | 1991-05-24 | 1997-11-05 | 株式会社クボタ | Ozone contact reaction tank |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323493A (en) * | 2008-07-24 | 2008-12-17 | 华南理工大学 | Waste water treatment apparatus based on ozone oxidation and aerating biological filter |
| CN102295328A (en) * | 2011-08-09 | 2011-12-28 | 江苏林格纯水设备有限公司 | Iron-carbon micro-electrolysis apparatus |
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