CN104119697A - Disperse sapphire blue dye composition, dye product and application of dye product - Google Patents
Disperse sapphire blue dye composition, dye product and application of dye product Download PDFInfo
- Publication number
- CN104119697A CN104119697A CN201410306370.8A CN201410306370A CN104119697A CN 104119697 A CN104119697 A CN 104119697A CN 201410306370 A CN201410306370 A CN 201410306370A CN 104119697 A CN104119697 A CN 104119697A
- Authority
- CN
- China
- Prior art keywords
- component
- blue dye
- sapphire blue
- dispersion
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052594 sapphire Inorganic materials 0.000 title claims abstract description 42
- 239000010980 sapphire Substances 0.000 title claims abstract description 42
- 239000001045 blue dye Substances 0.000 title claims abstract description 41
- 239000000975 dye Substances 0.000 title claims abstract description 26
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 238000004043 dyeing Methods 0.000 claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 8
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 6
- 239000002657 fibrous material Substances 0.000 claims abstract description 5
- 239000000986 disperse dye Substances 0.000 claims abstract description 3
- 238000007639 printing Methods 0.000 claims abstract description 3
- 239000006185 dispersion Substances 0.000 claims description 29
- 239000002131 composite material Substances 0.000 claims description 23
- 238000002360 preparation method Methods 0.000 claims description 18
- 239000012752 auxiliary agent Substances 0.000 claims description 13
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- 239000007859 condensation product Substances 0.000 claims description 6
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 claims description 2
- 125000005466 alkylenyl group Chemical group 0.000 claims description 2
- 235000019357 lignosulphonate Nutrition 0.000 claims description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 2
- 229920002334 Spandex Polymers 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 abstract description 6
- 239000004759 spandex Substances 0.000 abstract description 6
- 238000005406 washing Methods 0.000 abstract description 3
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 2
- 229920004934 Dacron® Polymers 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000001089 thermophoresis Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
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- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a disperse sapphire blue dye composition, a dye product and application of the dye product. The disperse sapphire blue dye composition comprises component A and component B, wherein the component A is one or more than one of dye monomer compounds shown in a formula (I); the component B is one or more than one of dye monomer compounds shown in a formula (II); based on the component A and the component B, the mass fraction of the component A is 1%-99%, and the mass fraction of the component B is 1%-99%. The disperse sapphire blue dye product mainly comprises the disperse sapphire blue dye composition and assistants according to the claim 1, and the weight ratio of the assistant to the disperse dye composition is (0.2-5) to 1. When the disperse sapphire blue dye product is applied to printing and dyeing of hydrophobic fiber materials, especially dacron/spandex blended fabrics, all fastnesses are excellent and the washing fastness is outstanding especially.
Description
(1) technical field
The invention belongs to dispersed dye preparation field, relate in particular to a kind of the hydrophobic fiber material especially sapphire blue dye composite of dispersion and goods thereof of terylene and blended fabric dyeing and stamp of being suitable for.
(2) background technology
" three height " staining technique is all emphasis of research to all kinds of textile products, comprises current mass-produced polyester/cellulosic fibre polycomponent product, so-called " three height " staining technique, i.e. high colour-fast rate, high enhancing and high color fastness.The dark heavy colour dyestuff high for lifting force often causes fastness to decline for reducing thermophoresis phenomenon, nowadays for the more excellent dispersed dye of the various performances of exploitation adopt dispersed dye compound synergic technology conventionally.
(3) summary of the invention
For addressing the above problem, the invention provides the sapphire blue dye preparations of a kind of dispersion that disperses sapphire blue dye composite, made by said composition and application thereof, this disperses sapphire blue dye preparations, be applied to hydrophobic fiber material polyester fibre/spandex BLENDED FABRIC when printing and dyeing particularly, every fastness is good, and particularly washing fastness is outstanding.
The technical solution used in the present invention is:
The sapphire blue dye composite of a kind of dispersion, it is characterized in that: comprise component A and B component, wherein component A is selected from one or more in the dye monomer compound of structure as shown in formula I, B component is selected from one or more in the dye monomer compound of structure as shown in formula II, component A based on described and B component, the massfraction of component A is 1～99%, and the massfraction of B component is 1～99%;
In above-mentioned formula I, R
1for H, C
1～C
4alkyl, C
1～C
4alkoxyl group or CF
3; R
2for C
1～C
8alkyl or-(CH
2)
m-O-R
8; R
3for C
1～C
8alkyl ,-(CH
2)
n-O-R
9or-(CH
2)
p-Ph; R
8, R
9independently be selected from separately C
1～C
4alkyl, m, n, p are independently 2 or 3 separately;
In above-mentioned formula II, X is Cl or Br, R
4for H or C
1～C
4alkoxyl group, R
5, R
6independent is separately C
1～C
4alkyl, C
1～C
4the C that replaces of alkoxyl group
1～C
4alkyl or phenyl, R
7for C
1～C
4alkyl.
As preferably, in formula (I), R
1for methyl, R
2, R
3for C
6h
13.
As preferably, in formula (II), X is Br, R
4for H, R
5, R
6independent is separately methyl or ethyl, R
7for methyl.
Further, the sapphire blue dye composite of dispersion of the present invention, is comprised of component A and B component, the component A based on described and B component, and the massfraction of component A is 1～99%, preferably 1-70%, more preferably 5-45%; The massfraction of B component is 1～99%, preferably 30-99%, more preferably 55-95%.
Component A of the present invention is one or more in following formula (I-1)～(I-10) preferably:
Described B component is one or more in following formula (II-1)～(II-8) preferably:
Ph represents phenyl.
The sapphire blue dye composite of dispersion of the present invention, more preferably it is comprised of component A and B component, wherein:
Component A is selected from least one in formula (I-1)～(I-2);
B component is selected from least one in formula (II-1)～(II-4);
Based on above component A and B component, the quality percentage composition of component A is 5-45%, and the quality percentage composition of B component is 55～95%.
The sapphire blue dye composite of dispersion of the present invention, as commodity selling or be applied to textile materials when painted, also needs to add auxiliary agent to carry out aftertreatment conventionally.Therefore, the present invention also provides a kind of dispersion sapphire blue dye preparations, and it mainly contains the described sapphire blue dye composite of dispersion and auxiliary agent, and the ratio of the weight of auxiliary agent and disperse dye composition is 0.2～5:1.Described auxiliary agent is dispersed dye conventional dispersion agent, diffusant and other tensio-active agents etc. when composite, and preferred auxiliary agent is one of following or two or more mixture wherein: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products (as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF)), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, xylogen 83A) etc.
The present invention is concrete recommends the sapphire blue dye composite of dispersion and auxiliary agent that the sapphire blue dye preparations of described dispersion is 1:0.2～5 by weight ratio to form, wherein disperse sapphire blue dye composite to be comprised of component A and B component, component A is selected from one or more in formula (I-1)～(I-10); B component is selected from one or more in formula (II-1)～(II-8); Based on component A and B component, the quality percentage composition of component A is 1～70%, and the quality percentage composition of B component is 30～99%.
The preparation method of the sapphire blue dye preparations of dispersion of the present invention is as follows:
Component A and the represented dye monomer compound (former dyestuff) of B component are pressed after above-mentioned proportioning mixing, under the existence of auxiliary agent, water or other wetting agent, with pulverizers such as sand mill or shredders, carry out corpusculed; Also after component A and the represented dye monomer compound of B component can being carried out to corpusculed processing with pulverizers such as sand mill or shredders respectively under the existence of auxiliary agent, water or other wetting agent in addition, with above-mentioned ratio, mix.The sapphire blue dye composite of dispersion of the present invention, aqueous with can be after sand mill or shredder grinding, after spraying is dry, can be powdery, particulate state.This is to well known to a person skilled in the art preparation method.
Former dyestuff shown in formula of the present invention (I), formula II, can adopt mode well known in the art synthetic, also can, according to the method preparation of introducing in patent JP01077583A, JP50111378A, JP58104954A, also can adopt commercially available prod.
The present invention also provides the application in especially wash at hydrophobic fiber material/spandex dyeing of the sapphire blue dye preparations of described dispersion.
The sapphire blue dye preparations of dispersion that the sapphire blue dye composite of dispersion of the present invention is made, for dyeing and the stamp of particularly wash/spandex of hydrophobic material fiber, coloured light is gorgeous, and synchronous dye uptake is good, and lifting force is good, is applicable to deep colour dyeing, and washing fastness is outstanding.
(4) specific embodiments
Below in conjunction with specific embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
Embodiment 1-18
According to continuous data shown in following table 1, former dyestuff, auxiliary agent by the dispersed dye shown in formula I, (II), add water and fully mix, and with sand mill, carries out grinding distribution, is then dried, and obtains disperseing sapphire blue dye preparations.
Table 1 unit: (gram)
Comparative example 1～4:
By disclosed embodiment 4 in CN103740136A as a comparison case 1.
By disclosed embodiment 1, embodiment 4 in CN103408968A as a comparison case 2,3;
By disclosed embodiment 1 in CN102732061A as a comparison case 4.
Dyeing embodiment 19:
Take the dispersed dye goods of 1.5 grams of embodiment 1-18, comparative example 1～4, be dispersed in separately in 500 ml waters, after drawing 20 milliliters, mix with the water of 60 milliliters, with acetic acid, adjust pH to 4.5, put into 2 grams of polyester fibre/spandex fabrics, be warming up to 70 ℃, continue with approximately 2 ℃/min gradient increased temperature to 130 ℃, insulation dyeing 45 minutes.Then be cooled to about 80 ℃ and use hot water wash 10min, dry.Adopt standard ISO 105-X12, AATCC61-2A, ISO105-P01 to test respectively its rub resistance, water-fastness, color fastness to sublimation, the results are shown in Table 2.
Table 2 unit: level
Test result shows: sapphire blue dispersed dye product application provided by the invention is in water-repellent fabrics, and particularly during polyester fibre/spandex BLENDED FABRIC, every fastness properties is excellent, is suitable as high-grade dyestuff.
Claims (10)
1. one kind is disperseed sapphire blue dye composite, comprise component A and B component, wherein component A is selected from one or more in the dye monomer compound of structure as shown in formula I, B component is selected from one or more in the dye monomer compound of structure as shown in formula II, component A based on described and B component, the massfraction of component A is 1～99%, and the massfraction of B component is 1～99%;
In above-mentioned formula I, R
1for H, C
1～C
4alkyl, C
1～C
4alkoxyl group or CF
3; R
2for C
1～C
8alkyl or-(CH
2)
m-O-R
8; R
3for C
1～C
8alkyl ,-(CH
2)
n-O-R
9or-(CH
2)
p-Ph; R
8, R
9independently be selected from separately C
1～C
4alkyl, m, n, p are independently 2 or 3 separately;
In above-mentioned formula II, X is Cl or Br, R
4for H or C
1～C
4alkoxyl group, R
5, R
6independent is separately C
1～C
4alkyl, C
1～C
4the C that replaces of alkoxyl group
1～C
4alkyl or phenyl, R
7for C
1～C
4alkyl.
2. the sapphire blue dye composite of dispersion as claimed in claim 1, it is characterized in that: the sapphire blue dye composite of described dispersion is comprised of component A and B component, component A based on described and B component, the massfraction of component A is 1～99%, the massfraction of B component is 1～99%.
3. the sapphire blue dye composite of dispersion as claimed in claim 1 or 2, is characterized in that: the massfraction of component A is 1-70%, and the massfraction of B component is 30-99%.
4. the sapphire blue dye composite of dispersion as claimed in claim 1 or 2, is characterized in that: the massfraction of component A is 5-45%, and the massfraction of B component is 55-95%.
5. the sapphire blue dye composite of dispersion as claimed in claim 1 or 2, is characterized in that: described component A is selected from one or more in following formula (I-1)～(I-10):
6. the sapphire blue dye composite of dispersion as claimed in claim 1 or 2, is characterized in that: described B component is selected from one or more in following formula (II-1)～(II-8):
Ph represents phenyl.
7. disperse a sapphire blue dye preparations, it mainly contains the sapphire blue dye composite of dispersion as claimed in claim 1 and auxiliary agent, and the ratio of the weight of auxiliary agent and disperse dye composition is 0.2～5:1.
8. the sapphire blue dye preparations of dispersion as claimed in claim 7, is characterized in that: described auxiliary agent is selected from one of following or two or more mixture wherein: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products, naphthalene sulfonic acidformaldehyde condensation product, benzyl naphthalene sulfonic formaldehyde condensation compound, sodium lignosulfonate.
9. the sapphire blue dye preparations of dispersion as claimed in claim 8, it is characterized in that: the sapphire blue dye composite of dispersion and auxiliary agent that the sapphire blue dye preparations of described dispersion is 1:0.2～5 by weight ratio form, wherein disperse sapphire blue dye composite to be comprised of component A and B component, component A is selected from one or more in formula (I-1)～(I-10); B component is selected from one or more in formula (II-1)～(II-8); Based on component A and B component, the quality percentage composition of component A is 1～70%, and the quality percentage composition of B component is 30～99%.
10. the application of the sapphire blue dye preparations of dispersion as claimed in claim 7 in hydrophobic fiber material printing and dyeing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410306370.8A CN104119697B (en) | 2014-06-30 | 2014-06-30 | The sapphire blue dye composite of a kind of dispersion, dye preparations and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410306370.8A CN104119697B (en) | 2014-06-30 | 2014-06-30 | The sapphire blue dye composite of a kind of dispersion, dye preparations and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119697A true CN104119697A (en) | 2014-10-29 |
| CN104119697B CN104119697B (en) | 2017-01-04 |
Family
ID=51765344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410306370.8A Active CN104119697B (en) | 2014-06-30 | 2014-06-30 | The sapphire blue dye composite of a kind of dispersion, dye preparations and application thereof |
Country Status (1)
| Country | Link |
|---|---|
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788995A (en) * | 2015-03-16 | 2015-07-22 | 太湖亚太精化有限公司 | Dispersed royal blue dye composition, dye product and application of dye product |
| CN105693547A (en) * | 2015-11-19 | 2016-06-22 | 浙江闰土研究院有限公司 | Novel compound crystal form and preparing method and application thereof |
| CN111909535A (en) * | 2020-08-10 | 2020-11-10 | 孙晓敏 | Multifunctional dye for clothing |
| CN113527908A (en) * | 2021-06-30 | 2021-10-22 | 浙江龙盛集团股份有限公司 | Disperse blue dye composition and dye product |
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|---|---|---|---|---|
| JPH06329927A (en) * | 1993-05-17 | 1994-11-29 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| JPH1129716A (en) * | 1997-05-14 | 1999-02-02 | Sumitomo Chem Co Ltd | Disperse dye composition |
| CN102585550A (en) * | 2011-12-31 | 2012-07-18 | 浙江博澳染料工业有限公司 | Blue disperse dye |
| CN103613953A (en) * | 2013-11-08 | 2014-03-05 | 浙江长征化工有限公司 | Disperse blue dye composition, disperse dye, and preparation method and application of disperse dye |
| CN103740136A (en) * | 2013-12-29 | 2014-04-23 | 浙江龙盛集团股份有限公司 | High-fastness turquoise blue disperse dye composition |
-
2014
- 2014-06-30 CN CN201410306370.8A patent/CN104119697B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06329927A (en) * | 1993-05-17 | 1994-11-29 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| JPH1129716A (en) * | 1997-05-14 | 1999-02-02 | Sumitomo Chem Co Ltd | Disperse dye composition |
| CN102585550A (en) * | 2011-12-31 | 2012-07-18 | 浙江博澳染料工业有限公司 | Blue disperse dye |
| CN103613953A (en) * | 2013-11-08 | 2014-03-05 | 浙江长征化工有限公司 | Disperse blue dye composition, disperse dye, and preparation method and application of disperse dye |
| CN103740136A (en) * | 2013-12-29 | 2014-04-23 | 浙江龙盛集团股份有限公司 | High-fastness turquoise blue disperse dye composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788995A (en) * | 2015-03-16 | 2015-07-22 | 太湖亚太精化有限公司 | Dispersed royal blue dye composition, dye product and application of dye product |
| CN105693547A (en) * | 2015-11-19 | 2016-06-22 | 浙江闰土研究院有限公司 | Novel compound crystal form and preparing method and application thereof |
| CN111909535A (en) * | 2020-08-10 | 2020-11-10 | 孙晓敏 | Multifunctional dye for clothing |
| CN113527908A (en) * | 2021-06-30 | 2021-10-22 | 浙江龙盛集团股份有限公司 | Disperse blue dye composition and dye product |
| CN113527908B (en) * | 2021-06-30 | 2023-11-21 | 浙江龙盛集团股份有限公司 | Disperse blue dye composition and dye product |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104119697B (en) | 2017-01-04 |
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