CN104059257A - Abrasion-resistance oil-resistance rubber composite material - Google Patents
Abrasion-resistance oil-resistance rubber composite material Download PDFInfo
- Publication number
- CN104059257A CN104059257A CN201410275562.7A CN201410275562A CN104059257A CN 104059257 A CN104059257 A CN 104059257A CN 201410275562 A CN201410275562 A CN 201410275562A CN 104059257 A CN104059257 A CN 104059257A
- Authority
- CN
- China
- Prior art keywords
- parts
- resistance
- rubber
- oil
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an abrasion-resistance oil-resistance rubber composite material, and belongs to the technical field of rubber. The composite material is prepared from the following components in parts by weight: 70-90 parts of butadiene-acrylonitrile rubber, 50-60 parts of ethylene-propylene-diene monomer rubber, 20-30 parts of natural rubber, 3-5 parts of sulfur, 0.8-2 parts of accelerant M, 2-6 parts of zinc oxide, 1-4 parts of stearic acid, 2-5 parts of nano-silicon nitride, 2-6 parts of carbon nano-tube, 1-2 parts of anti-aging agent and 0.5-1.5 parts of paraffin. According to the abrasion-resistance oil-resistance rubber composite material, the butadiene-acrylonitrile rubber with good abrasion resistance, ethylene-propylene-diene monomer rubber and natural rubber are used as substrates, and nano-silicon nitride and the carbon nano-tube are added, so that the mechanical performance of the composite material can be improved, and the oil resistance and oil resistance of the composite material can be reinforced. The composite material has high strength and aging resistance.
Description
Technical field
The invention belongs to rubber technology field, specifically a kind of wear-resistance and oil-resistance rubber composite.
Background technology
Paracril (nitrilebutadienerubber), is called for short NBR.Paracril is made through emulsion polymerization by divinyl and vinyl cyanide, and paracril mainly adopts low temperature emulsion polymerization to produce, and oil-proofness is fabulous, and wear resistance is higher, and thermotolerance is better, and bonding force is strong.Its shortcoming is that lower temperature resistance is poor, ozone resistance is poor, and electrical property is inferior, and elasticity is slightly low.The performance of paracril is affected by acrylonitrile content, improve, but elasticity, winter hardiness reduces along with acrylonitrile content increases tensile strength, thermotolerance, oil-proofness, resistance to air loss, hardness.Paracril ozone resistance and electrical insulation capability are not good.
Terpolymer EP rubber is the terpolymer of ethene, propylene and non-conjugated diene hydrocarbon, and its topmost characteristic is exactly its superior resistance to oxidation, anti-ozone and erosion-resistant ability.
Abrasive rubber material, because self possessing the functional of uniqueness, has developed into the Yi Zhi main force in field of novel.Nearly all rubber all must add a certain amount of weighting agent just can be used for being prepared with the rubber item of use in the course of processing.
Summary of the invention
The object of the present invention is to provide a kind of wear-resistance and oil-resistance rubber composite.
Object of the present invention can be achieved through the following technical solutions:
A kind of wear-resistance and oil-resistance rubber composite, it is characterized in that, by the component of following weight part, formed: paracril 70-90 part, terpolymer EP rubber 50-60 part, natural rubber 20-30 part, sulphur 3-5 part, captax 0.8-2 part, zinc oxide 2-6 part, stearic acid 1-4 part, nano-silicon nitride 2-5 part, carbon nanotube 2-6 part, anti-aging agent 1-2 part, paraffin 0.5-1.5 part.
The present invention is comprised of the component of following weight part: 80 parts of paracrils, 55 parts of terpolymer EP rubbers, 25 parts of natural rubbers, 4 parts, sulphur, 1.5 parts of captaxs, 4 parts, zinc oxide, 2.5 parts of stearic acid, 3.5 parts of nano-silicon nitrides, 4 parts of carbon nanotubes, 1.5 parts, anti-aging agent, 1 part, paraffin.
Anti-aging agent of the present invention is that anti-aging agent RD, antioxidant 4010NA are with the mixing of arbitrary proportion.
Beneficial effect of the present invention: it is matrix that the good paracril of wear resisting property, terpolymer EP rubber and natural rubber are take in the present invention, add nano-silicon nitride, carbon nanotube, improved the mechanical property of matrix material, the oil resistant wear resisting property that has strengthened matrix material, matrix material of the present invention has very large intensity, ageing-resistant performance.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
A wear-resistance and oil-resistance rubber composite, forms and formula is: 80 parts of paracrils, 55 parts of terpolymer EP rubbers, 25 parts of natural rubbers, 4 parts, sulphur, 1.5 parts of captaxs, 4 parts, zinc oxide, 2.5 parts of stearic acid, 3.5 parts of nano-silicon nitrides, 4 parts of carbon nanotubes, 1 part of anti-aging agent RD, 0.5 part of antioxidant 4010NA, 1 part, paraffin.
Embodiment 2
A wear-resistance and oil-resistance rubber composite, forms and formula is: 72 parts of paracrils, 60 parts of terpolymer EP rubbers, 20 parts of natural rubbers, 3 parts, sulphur, 0.8 part of captax, 2 parts, zinc oxide, 1 part of stearic acid, 2 parts of nano-silicon nitrides, 2 parts of carbon nanotubes, 10.3 parts of anti-aging agent RDs, 0.7 part of antioxidant 4010NA, 0.5 part, paraffin.
Embodiment 3
A wear-resistance and oil-resistance rubber composite, forms and formula is: 87 parts of paracrils, 50 parts of terpolymer EP rubbers, 30 parts of natural rubbers, 5 parts, sulphur, 2 parts of captaxs, 6 parts, zinc oxide, 4 parts of stearic acid, 5 parts of nano-silicon nitrides, 6 parts of carbon nanotubes, 1 part of anti-aging agent RD, 1 part of antioxidant 4010NA, 1.5 parts, paraffin.
Claims (3)
1. a wear-resistance and oil-resistance rubber composite, it is characterized in that, by the component of following weight part, formed: paracril 70-90 part, terpolymer EP rubber 50-60 part, natural rubber 20-30 part, sulphur 3-5 part, captax 0.8-2 part, zinc oxide 2-6 part, stearic acid 1-4 part, nano-silicon nitride 2-5 part, carbon nanotube 2-6 part, anti-aging agent 1-2 part, paraffin 0.5-1.5 part.
2. wear-resistance and oil-resistance rubber composite according to claim 1, it is characterized in that, by the component of following weight part, formed: 80 parts of paracrils, 55 parts of terpolymer EP rubbers, 25 parts of natural rubbers, 4 parts, sulphur, 1.5 parts of captaxs, 4 parts, zinc oxide, 2.5 parts of stearic acid, 3.5 parts of nano-silicon nitrides, 4 parts of carbon nanotubes, 1.5 parts, anti-aging agent, 1 part, paraffin.
3. wear-resistance and oil-resistance rubber composite according to claim 1 and 2, is characterized in that, described anti-aging agent is that anti-aging agent RD, antioxidant 4010NA are with the mixing of arbitrary proportion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410275562.7A CN104059257A (en) | 2014-06-20 | 2014-06-20 | Abrasion-resistance oil-resistance rubber composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410275562.7A CN104059257A (en) | 2014-06-20 | 2014-06-20 | Abrasion-resistance oil-resistance rubber composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104059257A true CN104059257A (en) | 2014-09-24 |
Family
ID=51547204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410275562.7A Pending CN104059257A (en) | 2014-06-20 | 2014-06-20 | Abrasion-resistance oil-resistance rubber composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104059257A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104358512A (en) * | 2014-10-21 | 2015-02-18 | 常熟市意润达商业设备厂 | Ladder truck |
| CN104499927A (en) * | 2014-10-21 | 2015-04-08 | 常熟市意润达商业设备厂 | Novel ladder truck |
| CN104893046A (en) * | 2015-06-19 | 2015-09-09 | 江苏华神特种橡胶制品股份有限公司 | Oil-proof abrasion-resisting rubber |
| CN104893111A (en) * | 2015-04-29 | 2015-09-09 | 安徽嘉木橡塑工业有限公司 | Low temperature low toxicity resistant rubber |
| CN105111533A (en) * | 2015-08-17 | 2015-12-02 | 繁昌县菲德通讯材料设计有限公司 | Anti-aging, oil resistant and high strength composite cable material |
| CN105384988A (en) * | 2015-11-24 | 2016-03-09 | 丹阳镇威汽配有限公司 | Rubber material for windshield wipers and preparation method for rubber material |
| CN106084340A (en) * | 2016-06-14 | 2016-11-09 | 航天材料及工艺研究所 | A kind of method preparing the carbon nano-tube filled nitrile rubber of heat oxygen aging resistance |
| CN106867045A (en) * | 2017-02-23 | 2017-06-20 | 安徽中鼎密封件股份有限公司 | A kind of stabilizer bar bushing and preparation method thereof |
| CN108395588A (en) * | 2018-01-17 | 2018-08-14 | 宁国市顺鑫金属制品有限公司 | The strong forging press cushion pad and preparation method thereof of wear-resistant antibacterial ability |
| CN108517111A (en) * | 2018-04-18 | 2018-09-11 | 安徽斯瑞尔阀门有限公司 | A kind of composite material and preparation method for valve seal |
| CN108976508A (en) * | 2018-06-25 | 2018-12-11 | 合肥欧仕嘉机电设备有限公司 | A kind of fuel rubber pipe and preparation method thereof |
| CN109401076A (en) * | 2018-09-27 | 2019-03-01 | 安徽龙川橡塑科技有限公司 | A kind of high-temperature resistant rubber material and preparation method thereof |
| CN112341680A (en) * | 2020-12-14 | 2021-02-09 | 华东理工大学 | Method for preparing anti-aging nitrile rubber from modified carbon nano tubes |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62172043A (en) * | 1986-01-23 | 1987-07-29 | Japan Synthetic Rubber Co Ltd | Rubber composition and laminated material thereof |
| CN102504358A (en) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | High-heat-conductivity rubber composite material and preparation method thereof |
| CN102585768A (en) * | 2012-01-09 | 2012-07-18 | 丁庆军 | Braided fiber-based friction material and preparation method thereof |
| CN103351486A (en) * | 2013-06-28 | 2013-10-16 | 青岛国强环保科技有限公司 | Abrasion-resistant environment-friendly rubber |
| CN103435863A (en) * | 2013-07-16 | 2013-12-11 | 安徽省天马泵阀集团有限公司 | High-pressure reciprocating sealing gasket for pump valve and preparation method thereof |
-
2014
- 2014-06-20 CN CN201410275562.7A patent/CN104059257A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62172043A (en) * | 1986-01-23 | 1987-07-29 | Japan Synthetic Rubber Co Ltd | Rubber composition and laminated material thereof |
| CN102504358A (en) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | High-heat-conductivity rubber composite material and preparation method thereof |
| CN102585768A (en) * | 2012-01-09 | 2012-07-18 | 丁庆军 | Braided fiber-based friction material and preparation method thereof |
| CN103351486A (en) * | 2013-06-28 | 2013-10-16 | 青岛国强环保科技有限公司 | Abrasion-resistant environment-friendly rubber |
| CN103435863A (en) * | 2013-07-16 | 2013-12-11 | 安徽省天马泵阀集团有限公司 | High-pressure reciprocating sealing gasket for pump valve and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 中国化工学会橡胶专业委员会: "《橡胶助剂手册》", 30 April 2000 * |
| 黄静: "三元共混橡胶中填料的相选择分布", 《橡胶参考资料》 * |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104358512A (en) * | 2014-10-21 | 2015-02-18 | 常熟市意润达商业设备厂 | Ladder truck |
| CN104499927A (en) * | 2014-10-21 | 2015-04-08 | 常熟市意润达商业设备厂 | Novel ladder truck |
| CN104893111A (en) * | 2015-04-29 | 2015-09-09 | 安徽嘉木橡塑工业有限公司 | Low temperature low toxicity resistant rubber |
| CN104893046A (en) * | 2015-06-19 | 2015-09-09 | 江苏华神特种橡胶制品股份有限公司 | Oil-proof abrasion-resisting rubber |
| CN105111533A (en) * | 2015-08-17 | 2015-12-02 | 繁昌县菲德通讯材料设计有限公司 | Anti-aging, oil resistant and high strength composite cable material |
| CN105384988A (en) * | 2015-11-24 | 2016-03-09 | 丹阳镇威汽配有限公司 | Rubber material for windshield wipers and preparation method for rubber material |
| CN106084340A (en) * | 2016-06-14 | 2016-11-09 | 航天材料及工艺研究所 | A kind of method preparing the carbon nano-tube filled nitrile rubber of heat oxygen aging resistance |
| CN106867045A (en) * | 2017-02-23 | 2017-06-20 | 安徽中鼎密封件股份有限公司 | A kind of stabilizer bar bushing and preparation method thereof |
| CN106867045B (en) * | 2017-02-23 | 2018-09-25 | 安徽中鼎密封件股份有限公司 | A kind of stabilizer bar bushing and preparation method thereof |
| CN108395588A (en) * | 2018-01-17 | 2018-08-14 | 宁国市顺鑫金属制品有限公司 | The strong forging press cushion pad and preparation method thereof of wear-resistant antibacterial ability |
| CN108517111A (en) * | 2018-04-18 | 2018-09-11 | 安徽斯瑞尔阀门有限公司 | A kind of composite material and preparation method for valve seal |
| CN108976508A (en) * | 2018-06-25 | 2018-12-11 | 合肥欧仕嘉机电设备有限公司 | A kind of fuel rubber pipe and preparation method thereof |
| CN109401076A (en) * | 2018-09-27 | 2019-03-01 | 安徽龙川橡塑科技有限公司 | A kind of high-temperature resistant rubber material and preparation method thereof |
| CN112341680A (en) * | 2020-12-14 | 2021-02-09 | 华东理工大学 | Method for preparing anti-aging nitrile rubber from modified carbon nano tubes |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104059257A (en) | Abrasion-resistance oil-resistance rubber composite material | |
| CN102352061B (en) | Oil resistant rubber | |
| CN102634089B (en) | Tyre tread rubber composition used in hard mine area and production method of tyre tread rubber composition in hard mine area | |
| CN103289150A (en) | Cold-resistant wear-resistant nitrile rubber sealing material and preparation method thereof | |
| CN108192162B (en) | A kind of Sports shoe sole abrasive rubber and preparation method thereof | |
| CN102002176A (en) | Hydrogenated nitrile-butadiene rubber composition | |
| CN110128718B (en) | Nitrile rubber with low compression set and preparation method thereof | |
| CN107266753B (en) | High tensile, high-wearing feature graphene/rubber composite wiper item and preparation method | |
| CN103613855A (en) | High-strength wear-resistant rubber pipe | |
| CN103804738A (en) | High-temperature stator rubber material and preparation method thereof | |
| CN103012870A (en) | Modified carcass ply compound of all-steel radial tire | |
| CN104861234A (en) | Wear-resistant styrene butadiene rubber material | |
| CN110845778A (en) | High-performance rubber composite material and preparation method thereof | |
| CN102977532A (en) | Acrylate rubber composition | |
| CN105218891A (en) | At the bottom of a kind of novel and portable skid-proof rubber | |
| CN104693547A (en) | Oil-resistant and wear-resistant rubber pad | |
| CN108384076B (en) | Outsole formula with high oil resistance, antistatic property and slip resistance and preparation method thereof | |
| CN104231976A (en) | Heat-resistant conveyor belt covering rubber | |
| CN103483705A (en) | Inner liner compound for truck tire | |
| CN105524305A (en) | Tread rubber for engineering tire | |
| CN105399994A (en) | Low heat generation and high thermal conductivity tire sidewall rubber composition | |
| CN104151650A (en) | Rubber composition containing modified rubber | |
| CN103739889B (en) | A kind of Automobile tire tread composite material | |
| CN103992521A (en) | Acid-resistant rubber tube | |
| CN114316401B (en) | Cutting-resistant low-heat-generation mining engineering tire tread rubber and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140924 |