CA3159857A1 - Agricultural compositions and methods of use thereof - Google Patents
Agricultural compositions and methods of use thereof Download PDFInfo
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- CA3159857A1 CA3159857A1 CA3159857A CA3159857A CA3159857A1 CA 3159857 A1 CA3159857 A1 CA 3159857A1 CA 3159857 A CA3159857 A CA 3159857A CA 3159857 A CA3159857 A CA 3159857A CA 3159857 A1 CA3159857 A1 CA 3159857A1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
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- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The present invention relates to an agricultural composition comprising a protoporphyrinogen oxidase (PPO) inhibitor, one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol and optionally, one or more auxin herbicides. The present invention further relates to a method of controlling weeds comprising applying concurrently or sequentially a PPO inhibitor and one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol, and optionally one or more auxin herbicides to the weeds or an area in need of weed control.
Description
AGRICULTURAL COMPOSITIONS AND METHODS OF USE THEREOF
FIELD OF THE INVENTION
[001] The present invention relates to an agricultural composition comprising a protoporphyrinogen oxidase (FPO) inhibitor, one or more fertilizers comprising a sugar alcohol selected from the group consisting of marmitol and sorbitol and optionally, one or more auxin herbicides. The present invention further relates to a method of controlling weeds comprising applying concurrently or sequentially a PPO inhibitor and one or more fertilizers comprising a sugar alcohol selected from. the group consisting of rnannitol and sorbitol, and optionally one or more auxin herbicides to the weeds or an area in need of weed control.
BACKGROUND OF THE INVENTION
FIELD OF THE INVENTION
[001] The present invention relates to an agricultural composition comprising a protoporphyrinogen oxidase (FPO) inhibitor, one or more fertilizers comprising a sugar alcohol selected from the group consisting of marmitol and sorbitol and optionally, one or more auxin herbicides. The present invention further relates to a method of controlling weeds comprising applying concurrently or sequentially a PPO inhibitor and one or more fertilizers comprising a sugar alcohol selected from. the group consisting of rnannitol and sorbitol, and optionally one or more auxin herbicides to the weeds or an area in need of weed control.
BACKGROUND OF THE INVENTION
[002] Unwanted plants, such as weeds, reduce the amount of resources available to crop plants and can have a negative effect on crop plant yield and quality. For example, a weed infestation reportedly was responsible for an 80% reduction in soybean yields. Bruce, LA., and J.J. Kells, Horseweed (Conyza Canadensis) control in no-tillage soybeans (Glycine max) with preplant and preemergence herbicides, Weed Techno1,1990, 4, 642-647. Unwanted plants in crop plant environments include broadleaves, grasses and sedges. To save time, money and resources, grass herbicides are often mixed with broadleaf herbicides to control a range of weeds. Further, to combat herbicide resistance multiple herbicides having different modes of action may be applied together.
[0031 As mentioned above, one way to control multiple weeds is to apply multiple herbicides sequentially or concurrently. However, when applying multiple herbicides, care must be taken to ensure that each of the herbicides are stable in their composition and effective when combined in either a formulation, a tank mix or after application..
[004] Protopoiphyrinogen oxidase ("PPO") inhibitors are herbicides that primarily control broadleaf weeds. PPO inhibitors create highly toxic molecules upon contact with the weed that result in destruction of plant tissue. PPO inhibitors are also effective against some grasses.
10051 Auxin herbicides primarily control broadleaf weeds. Auxin herbicides are plant growth regulators that mimic auxin and result in uncontrolled growth and death. These herbicides have been used successfully for over 60 years to control broadleaf weeds in cereal crops. Auxin herbicides are not effective against grasses.
1006] Accordingly, there is a need in the art for a composition containing PPO
inhibitors that is effective when combined with auxin herbicides to save time, money and resources. This composition should be stable and effective upon application.
SUMMARY OF THE INVENTION
[007] The present invention is directed to an agricultural composition comprising a protcporphyrinogen oxidase ("PPO") inhibitor, one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol and optionally, one or more auxin herbicides.
[008i The present invention is further directed to a method of controlling weeds comprising applying concurrently or sequentially a PPO inhibitor and a one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol, and optionally one or more auxin herbicides to the weeds or an area in need of weed control, DETAILED DESCRIPTION OF THE INVENTION
[009] The Applicant has unexpectedly discovered that the addition of one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol to agricultural compositions containing a protoporphyrinogen oxidase inhibitor ("PPO inhibitor") provides stable composition and effective application when combined with auxin herbicides.
[010] In one embodiment, the present invention is directed to an agricultural composition comprising a PPO inhibitor and one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol.
[0111 As used herein the term "protoporphyrinogen oxidase inhibitor" or "PP() inhibitors"
refers, but is not limited to, any compound capable of inhibiting the oxidation of protoporphyrinogen through interaction with the protoporphyrinogen oxidase enzyme, including those compounds not yet discovered or synthesized. Current PPO inhibitors include, but are not limited to, dipheny]ethers such as acifluorfen-sodium, bifenox, chlornitrofen, chlornethoxyfen, ethyoxyfen-ethyl, fluoroglycofen-ethyl, fomesafen, lactofen and oxyfluor.fen, N-phenylphthalimides such as cinidon-ethyl, flumiclorac and flurnioxazin, oxadiazoles such as oxadiargyl and oxadiazon, oxazolidinediones such as pentoxazone, phenylpyrazoles such as fluazolate and pyraflufen-ethyl, pyrirnidindiones such as benzfendizone, butafenacil and saflufenacil, thiadiazoles such as fluthiacet-methyl arid thidiazimin, triazolinones such as azafenidin, carfentrazone-ethyl and sulfentrazone and others such as flufenpyr-ethyl, proftnazol and pyraclonil.
(0121 In a preferred embodiment the PP() inhibitor is selected from the group consisting of is selected from the group consisting of ethyl [342-ehloro-41-fluoro-5-(1-methyl-6-trifitioromethyI-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenox>,7]-2-pyridyloxylacetate, flumioxa:zirt, lactofen, fomesafen, saflufenacil, sulfentrazone and triftudirrioxazin.. In a more preferred embodiment, the PPO inhibitor is ethyl [342-chloro-4-fluoro-540 -methy1-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrabydropyrimidin-3-y0phenoxy]-2-pyridyloxyjacetate.
10131 In another preferred embodiment, the ['PC) inhibitor may be present in compositions of the present invention at a concentration from about OA % to about 99.9% 'JAIN, more preferabb from about I% to about 99% wk.
10141 In another preferred embodiment, the one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol further comprise nitrogen and iron.
Marini-Plex FE is a mannitol comprising fertilizer that further comprises 5%
wily nitrogen and 5% wi'v iron.
10151 In another preferred embodiment, the one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol may be present in compositions of the present invention at a concentration from about 0.1% to about 99.9% w/v, more preferably from about I% to about 99% wk.
1016] In another embodiment, the compositions of the present invention further comprise one or more auxin herbicides.
[017] In a preferred embodiment, the one or more auxins is selected from the group consisting of dicamba, 2,4-D, dichloroprop, (4-chloro-2-methylphenoxy)acelic acid (MCPA), 4-(4-chloro-2 methylphenoxy)butanoic acid (MCPB), mecoprop, picloram, quinclorac, triclopyr, fluroxypyr, *loran', aminopyralidõ clopyralid and aminocyclopyrachlor and agricultural acceptable salts and esters thereof. In a more preferred embodiment, the one or more auxins is a salt of dicamba.
In an even more preferred embodiment, the salt of dicamba is selected from the group consisting of dicamba-biproantine, dicamba-diglycolamine, and dicamba-tetrabutylamine.
[018] In another preferred embodiment, the one or more auxins may be present in compositions of the present invention at a concentration from about 0.1% to about 99.9%
wry, more preferably from about I% to about 99% wilv.
10191 The compositions of the present invention may further comprise one or more excipients selected from the group consisting of solvents, anti-caking agents, stabilizers, anti-foaming agents, slip agents, humectants, dispersants, wetting agents:, thickening agents, emulsifiers, anti-freeze agents and preservatives. Other components that enhance the biological activity of these ingredients may optionally be included.
[0201 The compositions of the present invention can be applied by any convenient means_ Those skilled in the art are familiar with the modes of application that include foliar applications such as spraying, chemigation (a process of applying the mixture through the irrigation system) or by granular application.
(0211 The compositions of the present invention can be prepared as concentrate formulations, as ready-to-use formulations or as a tank mix.
[022] in another embodiment, the present invention is further directed to a method of controlling weeds comprising applying concurrently or sequentially a PPO
inhibitor and one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol and optionally, one or more auxin herbicides to the weeds or an area in need of weed control.
[0231 In a preferred embodiment, the PPO inhibitor may be applied at a rate from about 1 to about 1,000 grams per hectare ("g/HA:"), more preferably from about I to about 100 g/HA and even more preferably from about 10 to about 50 &OA and yet even more preferably from about to about 30 g/HA and most preferably at about 20 g/HA.
10241 In another preferred embodiment, the one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol may be applied at a rate from about I
to about 100 liters per hectare ("L/HA"), more preferably from about 2 to about 50 MIA and even more preferably from about 5 to about 20 LIIIA, yet even more preferably from about 12 to about 16 LIHA and most preferably at about 14 L/HA.
[025] In another preferred embodiment, the one or more auxin herbicides may be applied at a rate from about 1, to about 1,000 WHA, more preferably from about 10 to about 100 glHA.
[026] In another embodiment, the weed controlled by the compositions of the present invention is at least one of Waterbemp (Amaranthus tubercuiatus), Horseweed (Convza Canadensis), Ivyleaflkilomingglory (Ipomoea hederacea), Pitted Momingglory (Ipornoea lacunose), Common Ragweed (Ambrosia artemisiffblia), Giant Ragweed (Ambrosia trifida), Large Crabgrass (Digitaria sanguinahs), Palmer Amaranth (Arnaranthus pa/men), Broadleaf Signalgrass (Rrachiaria platyhylla), Common Barnyardgrass (Echinochloa crus-galli), Yellow Nutsedge (Cyperus esculentus), Eclipta (Eclipta prostrate), Lambseptatters (Chenopodium species), Velvetleaf (Abutilon theophrasti), Fortail (Setaria species), Giant Foxtail (Setaria _Taber , Volunteer Corn (Zea ;nays) and annual grasses. As used herein, ammal grasses include corn, sorghums, wheat, lye, barley, and oats. In a preferred embodiment, the weed controlled is selected from the group consisting of common batnyardgra.ss, broadleaf grass and volunteer corn.
[027] In another embodiment, the area in need of weed control may include any area that is desired to have a reduced number of weeds or to be free of weeds For example, compositions of the present invention may be applied to an area used to grow crop plants, such as a field orchard, or vineyard_ Mixtures of the present invention can also be applied to non--agricultural areas in need of weed control such as lawns, golf courses, or parks.
[0281 As used herein, all numerical values relating to amounts, weight percentages and the like are defined as "about" or "approximately" each particular value, plus or minus 10 %. For example, the phrase "at least 5.0 % by weight" is to be understood as "at least 4.5 % to 5.5 % by weight." Therefore, amounts within 10 % of the claimed values are encompassed by the scope of the clairns.
[0291 Throughout the application, the singular fbrms "a," "an," and "the"
include plural reference unless the context clearly dictates otherwise_ 1030j These representative embodiments are in no way limiting and are described solely to illustrate some aspects of the invention_ 10311 Further, the following examples are offered by way of illustration only and not by way of EXAMPLES
10321 Agridex is a crop oil concentrate and is a registered trademark of and available from Bayer CropScience.
10331 Intact' contains 43.13% polyethylene glycol, choline chloride and guar gum and is available from Precision laboratories.
[034i Manni-Plexel FE was used as the source of mannitol andlor sorbitol comprising fertilizer.
Manni-Plex is available from and a registered trademark of Brandt Consolidated Inc.
.
.
Example 1:- -Marini tO1 Sorbitol -comprisinzThetilizers increase Performstwe of S-3100 in.
Barnyard Grass_ 0:0351 4 trials were conducted on the efficacy of ethyl [342-chloro-4-fluoro-5-(1-methyl-6-noromethy1-2,4-di oxo-12,3,4-tetrahydropyrimidin-3-y Ophenoxyl -2-pyridyloxylacetate ("S-3100") with or without a mannitol and/or sorbitol comprising fertilizer.
Specifically, 4 pots of barnyard grass were grown to 10 inches in height. These pots were placed in a spray chamber for treatment. All compositions contained 1% v/v of Agridex . The composition containing S-3100 and fertilizer contained 1% lily of Intact-rm. Treatments and results can be found in Table 1, below.
Table 1 Days After Treatment (%
Application Rate control) Treatment (per Hectare)
[0031 As mentioned above, one way to control multiple weeds is to apply multiple herbicides sequentially or concurrently. However, when applying multiple herbicides, care must be taken to ensure that each of the herbicides are stable in their composition and effective when combined in either a formulation, a tank mix or after application..
[004] Protopoiphyrinogen oxidase ("PPO") inhibitors are herbicides that primarily control broadleaf weeds. PPO inhibitors create highly toxic molecules upon contact with the weed that result in destruction of plant tissue. PPO inhibitors are also effective against some grasses.
10051 Auxin herbicides primarily control broadleaf weeds. Auxin herbicides are plant growth regulators that mimic auxin and result in uncontrolled growth and death. These herbicides have been used successfully for over 60 years to control broadleaf weeds in cereal crops. Auxin herbicides are not effective against grasses.
1006] Accordingly, there is a need in the art for a composition containing PPO
inhibitors that is effective when combined with auxin herbicides to save time, money and resources. This composition should be stable and effective upon application.
SUMMARY OF THE INVENTION
[007] The present invention is directed to an agricultural composition comprising a protcporphyrinogen oxidase ("PPO") inhibitor, one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol and optionally, one or more auxin herbicides.
[008i The present invention is further directed to a method of controlling weeds comprising applying concurrently or sequentially a PPO inhibitor and a one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol, and optionally one or more auxin herbicides to the weeds or an area in need of weed control, DETAILED DESCRIPTION OF THE INVENTION
[009] The Applicant has unexpectedly discovered that the addition of one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol to agricultural compositions containing a protoporphyrinogen oxidase inhibitor ("PPO inhibitor") provides stable composition and effective application when combined with auxin herbicides.
[010] In one embodiment, the present invention is directed to an agricultural composition comprising a PPO inhibitor and one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol.
[0111 As used herein the term "protoporphyrinogen oxidase inhibitor" or "PP() inhibitors"
refers, but is not limited to, any compound capable of inhibiting the oxidation of protoporphyrinogen through interaction with the protoporphyrinogen oxidase enzyme, including those compounds not yet discovered or synthesized. Current PPO inhibitors include, but are not limited to, dipheny]ethers such as acifluorfen-sodium, bifenox, chlornitrofen, chlornethoxyfen, ethyoxyfen-ethyl, fluoroglycofen-ethyl, fomesafen, lactofen and oxyfluor.fen, N-phenylphthalimides such as cinidon-ethyl, flumiclorac and flurnioxazin, oxadiazoles such as oxadiargyl and oxadiazon, oxazolidinediones such as pentoxazone, phenylpyrazoles such as fluazolate and pyraflufen-ethyl, pyrirnidindiones such as benzfendizone, butafenacil and saflufenacil, thiadiazoles such as fluthiacet-methyl arid thidiazimin, triazolinones such as azafenidin, carfentrazone-ethyl and sulfentrazone and others such as flufenpyr-ethyl, proftnazol and pyraclonil.
(0121 In a preferred embodiment the PP() inhibitor is selected from the group consisting of is selected from the group consisting of ethyl [342-ehloro-41-fluoro-5-(1-methyl-6-trifitioromethyI-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenox>,7]-2-pyridyloxylacetate, flumioxa:zirt, lactofen, fomesafen, saflufenacil, sulfentrazone and triftudirrioxazin.. In a more preferred embodiment, the PPO inhibitor is ethyl [342-chloro-4-fluoro-540 -methy1-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrabydropyrimidin-3-y0phenoxy]-2-pyridyloxyjacetate.
10131 In another preferred embodiment, the ['PC) inhibitor may be present in compositions of the present invention at a concentration from about OA % to about 99.9% 'JAIN, more preferabb from about I% to about 99% wk.
10141 In another preferred embodiment, the one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol further comprise nitrogen and iron.
Marini-Plex FE is a mannitol comprising fertilizer that further comprises 5%
wily nitrogen and 5% wi'v iron.
10151 In another preferred embodiment, the one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol may be present in compositions of the present invention at a concentration from about 0.1% to about 99.9% w/v, more preferably from about I% to about 99% wk.
1016] In another embodiment, the compositions of the present invention further comprise one or more auxin herbicides.
[017] In a preferred embodiment, the one or more auxins is selected from the group consisting of dicamba, 2,4-D, dichloroprop, (4-chloro-2-methylphenoxy)acelic acid (MCPA), 4-(4-chloro-2 methylphenoxy)butanoic acid (MCPB), mecoprop, picloram, quinclorac, triclopyr, fluroxypyr, *loran', aminopyralidõ clopyralid and aminocyclopyrachlor and agricultural acceptable salts and esters thereof. In a more preferred embodiment, the one or more auxins is a salt of dicamba.
In an even more preferred embodiment, the salt of dicamba is selected from the group consisting of dicamba-biproantine, dicamba-diglycolamine, and dicamba-tetrabutylamine.
[018] In another preferred embodiment, the one or more auxins may be present in compositions of the present invention at a concentration from about 0.1% to about 99.9%
wry, more preferably from about I% to about 99% wilv.
10191 The compositions of the present invention may further comprise one or more excipients selected from the group consisting of solvents, anti-caking agents, stabilizers, anti-foaming agents, slip agents, humectants, dispersants, wetting agents:, thickening agents, emulsifiers, anti-freeze agents and preservatives. Other components that enhance the biological activity of these ingredients may optionally be included.
[0201 The compositions of the present invention can be applied by any convenient means_ Those skilled in the art are familiar with the modes of application that include foliar applications such as spraying, chemigation (a process of applying the mixture through the irrigation system) or by granular application.
(0211 The compositions of the present invention can be prepared as concentrate formulations, as ready-to-use formulations or as a tank mix.
[022] in another embodiment, the present invention is further directed to a method of controlling weeds comprising applying concurrently or sequentially a PPO
inhibitor and one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol and optionally, one or more auxin herbicides to the weeds or an area in need of weed control.
[0231 In a preferred embodiment, the PPO inhibitor may be applied at a rate from about 1 to about 1,000 grams per hectare ("g/HA:"), more preferably from about I to about 100 g/HA and even more preferably from about 10 to about 50 &OA and yet even more preferably from about to about 30 g/HA and most preferably at about 20 g/HA.
10241 In another preferred embodiment, the one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol may be applied at a rate from about I
to about 100 liters per hectare ("L/HA"), more preferably from about 2 to about 50 MIA and even more preferably from about 5 to about 20 LIIIA, yet even more preferably from about 12 to about 16 LIHA and most preferably at about 14 L/HA.
[025] In another preferred embodiment, the one or more auxin herbicides may be applied at a rate from about 1, to about 1,000 WHA, more preferably from about 10 to about 100 glHA.
[026] In another embodiment, the weed controlled by the compositions of the present invention is at least one of Waterbemp (Amaranthus tubercuiatus), Horseweed (Convza Canadensis), Ivyleaflkilomingglory (Ipomoea hederacea), Pitted Momingglory (Ipornoea lacunose), Common Ragweed (Ambrosia artemisiffblia), Giant Ragweed (Ambrosia trifida), Large Crabgrass (Digitaria sanguinahs), Palmer Amaranth (Arnaranthus pa/men), Broadleaf Signalgrass (Rrachiaria platyhylla), Common Barnyardgrass (Echinochloa crus-galli), Yellow Nutsedge (Cyperus esculentus), Eclipta (Eclipta prostrate), Lambseptatters (Chenopodium species), Velvetleaf (Abutilon theophrasti), Fortail (Setaria species), Giant Foxtail (Setaria _Taber , Volunteer Corn (Zea ;nays) and annual grasses. As used herein, ammal grasses include corn, sorghums, wheat, lye, barley, and oats. In a preferred embodiment, the weed controlled is selected from the group consisting of common batnyardgra.ss, broadleaf grass and volunteer corn.
[027] In another embodiment, the area in need of weed control may include any area that is desired to have a reduced number of weeds or to be free of weeds For example, compositions of the present invention may be applied to an area used to grow crop plants, such as a field orchard, or vineyard_ Mixtures of the present invention can also be applied to non--agricultural areas in need of weed control such as lawns, golf courses, or parks.
[0281 As used herein, all numerical values relating to amounts, weight percentages and the like are defined as "about" or "approximately" each particular value, plus or minus 10 %. For example, the phrase "at least 5.0 % by weight" is to be understood as "at least 4.5 % to 5.5 % by weight." Therefore, amounts within 10 % of the claimed values are encompassed by the scope of the clairns.
[0291 Throughout the application, the singular fbrms "a," "an," and "the"
include plural reference unless the context clearly dictates otherwise_ 1030j These representative embodiments are in no way limiting and are described solely to illustrate some aspects of the invention_ 10311 Further, the following examples are offered by way of illustration only and not by way of EXAMPLES
10321 Agridex is a crop oil concentrate and is a registered trademark of and available from Bayer CropScience.
10331 Intact' contains 43.13% polyethylene glycol, choline chloride and guar gum and is available from Precision laboratories.
[034i Manni-Plexel FE was used as the source of mannitol andlor sorbitol comprising fertilizer.
Manni-Plex is available from and a registered trademark of Brandt Consolidated Inc.
.
.
Example 1:- -Marini tO1 Sorbitol -comprisinzThetilizers increase Performstwe of S-3100 in.
Barnyard Grass_ 0:0351 4 trials were conducted on the efficacy of ethyl [342-chloro-4-fluoro-5-(1-methyl-6-noromethy1-2,4-di oxo-12,3,4-tetrahydropyrimidin-3-y Ophenoxyl -2-pyridyloxylacetate ("S-3100") with or without a mannitol and/or sorbitol comprising fertilizer.
Specifically, 4 pots of barnyard grass were grown to 10 inches in height. These pots were placed in a spray chamber for treatment. All compositions contained 1% v/v of Agridex . The composition containing S-3100 and fertilizer contained 1% lily of Intact-rm. Treatments and results can be found in Table 1, below.
Table 1 Days After Treatment (%
Application Rate control) Treatment (per Hectare)
3 7 13 Untreated Si ..................................... Control S-3100 20 grams 73.3 85.2 84.7 Fertilizer 14 liters 0 ....0 10 S-3100 20 grams 88.7 93.2 88.0 Fertilizer 14 liters [0361 As seen in Table 1, above, at 3 days after treatment ("DAT") there was more than a 15%
increase in control of barnyard grass by S-3100 and fertilizer (88.7%) compared to S-3100 alone (733%). At 7 DAT, S-3100 and fertilizer (93.2%) demonstrated almost an 8%
increase in control of barnyard grass compared to S-3100 treatment alone (85.2%).
[037] Improved residual control was also observed at 13 DAT. At 13 DAT, S-3100 and fertilizer (88.0%) demonstrated an increase in control of barnyard grass compared to S4100 alone (84.7%). Increased activity was observed as increased speed of contract burn, more complete kill and less regrowth of barnyard grass plants.
.Exampie 2- telarinitol andlor Sorbitol compriSing Fertilizers Increase Performance of S-3100 in Broadleaf Grass.
10381 4 trials were conducted on the efficacy of ethyl [342-chloro-4-fluoro-5-(1-methy1-6-trifluorornethvi-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-y1)phenoxyl-2-pyridyloxviacetate C'S-3100") with or without a mannitol and/or sorbitol comprising fertilizer.
Specifically, 4 pots of broadleaf grass were grown to 10 inches in height. These pots were placed in a spray chamber for treatment. All compositions contained 1% viv of Agridex . The composition containing S-3100 and fertilizer contained 1% viv of IntactTM. Treatments and results can be found in Table 2, below.
Table 2 Days After Treatment (%
Application Rate control 'Treatment (per Hectare) ............ 3 fl 14 .
Untreated Control S-3100 20 Prat:EIS
75AH 93.0 84.2 i Fertilizer 14 liters .......... 10 10 10 l S-3100 1 20 grams 91.7 95.8 95.8 Fertilizer 1, 14 liters 103911 As seen in Table 2, above, at 3 days after treatment ("DAT") there was nearly a 17%
increase in control of broadleaf grass by 3-3100 and fertilizer (91.7%) compared to S-3100 alone (75.0%). At 7 DAT, S-3100 and fertilizer (95.8%) demonstrated nearly a 3%
increase in control of broadleaf grass compared to S-3100 treatment alone (93.0%).
[040] Improved residual control was also observed at 14 DAT. At 14 DAT, S-3100 and fertilizer (95.8%) demonstrated over an 11% increase in control of broadleaf grass compared to S-3100 alone (84.2%). Increased activity was observed as increased speed of contract burn, more complete kill and less regrowth of broadleaf grass plants.
Example 3- Mannitol and/or Sorbitol comprising Fertilizers Increase Performance of S-3100 in Giant Foxtail [0411 4 trials were conducted on the efficacy of ethyl [342-chloro-4-fluoro-5-0-no.ethvi-6-trifluoromethyl-2,4-dioxo-1,2,3õ4 -tetrahydropy rirnidin-3-y Ophenoxy]-2-py ridyloxy] acetate ("S-3100") with or without a mannitol and/or sorbitol comprising fertilizer.
Specifically, 4 pots of giant foxtail were grown to 10 inches in height. These pots were placed in a spray chamber for treatment. All compositions contained 1% viv of Agridexe. The composition containing S-3100 and fertilizer contained 1% viv of lntactTM. Treatments and results can be found in Table 3, below.
Table 3 .................................................. 7 ...................
Days After Treatment (%
Application Rate control) Treatment r Hectare) Untreated Control S-3100 ..... 20 grams 767 95,5 96.1 Fertilizer 14 liters S-3100 20 grams I 71.7 95:2 94.0 Fertilizer 14 liters =
[0421 As seen in Table 3, above, at 3, 7 and 14 days after treatment ("DAT") the addition of a mannhol comprising fertilizer to S-3100 maintained control of giant foxtail.
Exarnige 4- Matinitol and/or af rõ.õõpigul Fertilizers It creaSe Performance oLS3100 in .Volunteer Corn [0431 4 trials were conducted on the efficacy of ethyl [342-chloro-4-fluoro-5-(1-xnethyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yflphenoxyl-2-pyridyloxylacetate ("S-3100") with or without a mannitol andlor sorbitol comprising fertilizer.
Specificallyõ 4 pots of volunteer corn were grown to 15 inches in height. These pots were placed in a spray chamber for treatment. All compositions contained 1% v/v of Agridex . The composition containing S-3100 and fertilizer contained 1% Of of Intact-rm. Treatments and results can be found in Table
increase in control of barnyard grass by S-3100 and fertilizer (88.7%) compared to S-3100 alone (733%). At 7 DAT, S-3100 and fertilizer (93.2%) demonstrated almost an 8%
increase in control of barnyard grass compared to S-3100 treatment alone (85.2%).
[037] Improved residual control was also observed at 13 DAT. At 13 DAT, S-3100 and fertilizer (88.0%) demonstrated an increase in control of barnyard grass compared to S4100 alone (84.7%). Increased activity was observed as increased speed of contract burn, more complete kill and less regrowth of barnyard grass plants.
.Exampie 2- telarinitol andlor Sorbitol compriSing Fertilizers Increase Performance of S-3100 in Broadleaf Grass.
10381 4 trials were conducted on the efficacy of ethyl [342-chloro-4-fluoro-5-(1-methy1-6-trifluorornethvi-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-y1)phenoxyl-2-pyridyloxviacetate C'S-3100") with or without a mannitol and/or sorbitol comprising fertilizer.
Specifically, 4 pots of broadleaf grass were grown to 10 inches in height. These pots were placed in a spray chamber for treatment. All compositions contained 1% viv of Agridex . The composition containing S-3100 and fertilizer contained 1% viv of IntactTM. Treatments and results can be found in Table 2, below.
Table 2 Days After Treatment (%
Application Rate control 'Treatment (per Hectare) ............ 3 fl 14 .
Untreated Control S-3100 20 Prat:EIS
75AH 93.0 84.2 i Fertilizer 14 liters .......... 10 10 10 l S-3100 1 20 grams 91.7 95.8 95.8 Fertilizer 1, 14 liters 103911 As seen in Table 2, above, at 3 days after treatment ("DAT") there was nearly a 17%
increase in control of broadleaf grass by 3-3100 and fertilizer (91.7%) compared to S-3100 alone (75.0%). At 7 DAT, S-3100 and fertilizer (95.8%) demonstrated nearly a 3%
increase in control of broadleaf grass compared to S-3100 treatment alone (93.0%).
[040] Improved residual control was also observed at 14 DAT. At 14 DAT, S-3100 and fertilizer (95.8%) demonstrated over an 11% increase in control of broadleaf grass compared to S-3100 alone (84.2%). Increased activity was observed as increased speed of contract burn, more complete kill and less regrowth of broadleaf grass plants.
Example 3- Mannitol and/or Sorbitol comprising Fertilizers Increase Performance of S-3100 in Giant Foxtail [0411 4 trials were conducted on the efficacy of ethyl [342-chloro-4-fluoro-5-0-no.ethvi-6-trifluoromethyl-2,4-dioxo-1,2,3õ4 -tetrahydropy rirnidin-3-y Ophenoxy]-2-py ridyloxy] acetate ("S-3100") with or without a mannitol and/or sorbitol comprising fertilizer.
Specifically, 4 pots of giant foxtail were grown to 10 inches in height. These pots were placed in a spray chamber for treatment. All compositions contained 1% viv of Agridexe. The composition containing S-3100 and fertilizer contained 1% viv of lntactTM. Treatments and results can be found in Table 3, below.
Table 3 .................................................. 7 ...................
Days After Treatment (%
Application Rate control) Treatment r Hectare) Untreated Control S-3100 ..... 20 grams 767 95,5 96.1 Fertilizer 14 liters S-3100 20 grams I 71.7 95:2 94.0 Fertilizer 14 liters =
[0421 As seen in Table 3, above, at 3, 7 and 14 days after treatment ("DAT") the addition of a mannhol comprising fertilizer to S-3100 maintained control of giant foxtail.
Exarnige 4- Matinitol and/or af rõ.õõpigul Fertilizers It creaSe Performance oLS3100 in .Volunteer Corn [0431 4 trials were conducted on the efficacy of ethyl [342-chloro-4-fluoro-5-(1-xnethyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yflphenoxyl-2-pyridyloxylacetate ("S-3100") with or without a mannitol andlor sorbitol comprising fertilizer.
Specificallyõ 4 pots of volunteer corn were grown to 15 inches in height. These pots were placed in a spray chamber for treatment. All compositions contained 1% v/v of Agridex . The composition containing S-3100 and fertilizer contained 1% Of of Intact-rm. Treatments and results can be found in Table
4, below.
Table 4 Jo
Table 4 Jo
5 Days After Treatment (%
Application Rate control) Treatment (per Hectare) Untreated Control S-3100 20 grams 65.0 59.2 56.7 Fertilizer 14 liters 8.3 5.0 10.0 I
8-3100 20 grams 83.3 95.3 95.2 1 Fertilizer 14 liters 1044] As seen in Table 4, above, at 3 days after treatment ("DAV') there was more than an 18%
increase in control of volunteer corn by S-3100 and fertilizer (93.3%) compared to S-3100 alone (65.0%). At 7 DAT, 8-3100 and fertilizer (95.3%) demonstrated a 36% increase in control of volunteer corn compared to S-3100 treatment alone (59.2%).
Improved residual control was also observed at 14 DAT. At 14 DAT, 8-3100 and fertilizer (95.2%) demonstrated more than a 38% increase in control of volunteer corn compared to 8-3100 alone (56.7%). Increased activity was observed as increased speed of contract burn, more complete kill and less regrowth of volunteer corn.
Application Rate control) Treatment (per Hectare) Untreated Control S-3100 20 grams 65.0 59.2 56.7 Fertilizer 14 liters 8.3 5.0 10.0 I
8-3100 20 grams 83.3 95.3 95.2 1 Fertilizer 14 liters 1044] As seen in Table 4, above, at 3 days after treatment ("DAV') there was more than an 18%
increase in control of volunteer corn by S-3100 and fertilizer (93.3%) compared to S-3100 alone (65.0%). At 7 DAT, 8-3100 and fertilizer (95.3%) demonstrated a 36% increase in control of volunteer corn compared to S-3100 treatment alone (59.2%).
Improved residual control was also observed at 14 DAT. At 14 DAT, 8-3100 and fertilizer (95.2%) demonstrated more than a 38% increase in control of volunteer corn compared to 8-3100 alone (56.7%). Increased activity was observed as increased speed of contract burn, more complete kill and less regrowth of volunteer corn.
Claims
WHAT IS CLAIMED IS:
I . An agricultural composition comprising a protoporphyrinogen oxidase (PPO) inhibitor and one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol.
2. The cornposition of claim 1, wherein the PPO inhibitor is selected from the group consisting of ethyl [342-ch1oro-4-fluoro-5-(1-methy1-6-trifluoromethy1-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxylacetate, flumioxazin, lactoten, fomesafen, sallufenacil, sulfentrazone and trifludimoxazin.
3. The composition of claim 2, wherein the PPO inhibitor is ethyl [342-ch1oro-441uoro-5-(1 -methy1-6-trifluoromethy I -2,4-dioxo- 1 ,2õ3,44etrahydropyrimidin-3-yl)phenoxyl-2-pyridyloxy]acetate.
4. The cornposition of claim I, wherein the one or more fertilizers fiirther comprise nitrogen and iron_ 5. The composition of claim 4, wherein the one or more fertilizers comprise about 5% \YIN' nitrogen and about 5% w/v iron, wherein w/v denotes weight by total volurne of the composition.
6. The cornposition of clairn I, further comprising one or more auxin herbicides.
7. The cornposition of clairn 6, wherein the one or more auxin herbicides is selected from the group consisting of dicamba, 2,4-D, dicbloroprop, (4-chloro-2-methylphenoxy)acetic acid (MCPA), 4-(4-chloro-2 methylphenoxy)butanoic acid (MCPB), mecoprop, picloram, quindorac, triclopyr, fluroxypyr, picloram, aminopyrand, clopyralid and arninocyclopyrachlor and agricultural acceptable salts and esters thereof.
8. The composition of claim 7.. wherein the one or more auxin herbicides is a salt of dicamba.
9, The cornposition of claim 8, where in th.e salt of dicarnba is selected frorn the group consisting of dicamba-hiproamine, dicarnba-diglycolarnine, and dicarnba-tetrabutylamine.
10. An agricultural composition comprising ethyl [342-chloro-4-fhioro-5-(1-methyl-6-trifluorornethy1-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yOphenoxy]-2-pyridyloxyjacetate and a fertilizer comprising mannitol, nitrogen and iron.
11. The composition of claim 10, further comprising a salt of dicamba.
12. A method of controlling weeds com.prising applying concurrently or sequentially a protoporphyrinogen oxidase (PPO) inhibitor and one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol to the weeds or an area in need of weed control.
13. The method of claim 12, further comprising applying concurrently or sequentially one or more auxin herbicides to the weeds or an area in need of weed control.
14. The method of claim 12, wherein the PPO thhibitor is applied at a rate from about 1 to about 100 grams per hectAre.
15. The method of claim 12, wherein the PPO inhibitor is applied at a rate from about 10 to about 50 grams per hectare.
16. The method of claim 12, wherein the WO inhibitor is applied at a rate of 20 grams per hectare.
17. The method of claim 12, wherein the one or more fertilizers comprising a sugar akohol selected from the group consisting of mannitol and sorbitol is applied at a rate about 100 to about 100,000 grams per hectare.
18. The method of clairn 12, wherein the one or more sugar alcohols is applied at a rate about 1,000 to about 30,000 grams per hectare.
i 9. The method of claim 12, wherein the one or more fertilizers comprising a sugar akohol selected from the group consisting of mannitol and sorbitol is applied of about 6,800 grams per hectare.
20. The method of claim 13, wherein the one or more auxin herbicides is applied at a rate about 1 to about 1,000 grarns per hectare.
I . An agricultural composition comprising a protoporphyrinogen oxidase (PPO) inhibitor and one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol.
2. The cornposition of claim 1, wherein the PPO inhibitor is selected from the group consisting of ethyl [342-ch1oro-4-fluoro-5-(1-methy1-6-trifluoromethy1-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxylacetate, flumioxazin, lactoten, fomesafen, sallufenacil, sulfentrazone and trifludimoxazin.
3. The composition of claim 2, wherein the PPO inhibitor is ethyl [342-ch1oro-441uoro-5-(1 -methy1-6-trifluoromethy I -2,4-dioxo- 1 ,2õ3,44etrahydropyrimidin-3-yl)phenoxyl-2-pyridyloxy]acetate.
4. The cornposition of claim I, wherein the one or more fertilizers fiirther comprise nitrogen and iron_ 5. The composition of claim 4, wherein the one or more fertilizers comprise about 5% \YIN' nitrogen and about 5% w/v iron, wherein w/v denotes weight by total volurne of the composition.
6. The cornposition of clairn I, further comprising one or more auxin herbicides.
7. The cornposition of clairn 6, wherein the one or more auxin herbicides is selected from the group consisting of dicamba, 2,4-D, dicbloroprop, (4-chloro-2-methylphenoxy)acetic acid (MCPA), 4-(4-chloro-2 methylphenoxy)butanoic acid (MCPB), mecoprop, picloram, quindorac, triclopyr, fluroxypyr, picloram, aminopyrand, clopyralid and arninocyclopyrachlor and agricultural acceptable salts and esters thereof.
8. The composition of claim 7.. wherein the one or more auxin herbicides is a salt of dicamba.
9, The cornposition of claim 8, where in th.e salt of dicarnba is selected frorn the group consisting of dicamba-hiproamine, dicarnba-diglycolarnine, and dicarnba-tetrabutylamine.
10. An agricultural composition comprising ethyl [342-chloro-4-fhioro-5-(1-methyl-6-trifluorornethy1-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yOphenoxy]-2-pyridyloxyjacetate and a fertilizer comprising mannitol, nitrogen and iron.
11. The composition of claim 10, further comprising a salt of dicamba.
12. A method of controlling weeds com.prising applying concurrently or sequentially a protoporphyrinogen oxidase (PPO) inhibitor and one or more fertilizers comprising a sugar alcohol selected from the group consisting of mannitol and sorbitol to the weeds or an area in need of weed control.
13. The method of claim 12, further comprising applying concurrently or sequentially one or more auxin herbicides to the weeds or an area in need of weed control.
14. The method of claim 12, wherein the PPO thhibitor is applied at a rate from about 1 to about 100 grams per hectAre.
15. The method of claim 12, wherein the PPO inhibitor is applied at a rate from about 10 to about 50 grams per hectare.
16. The method of claim 12, wherein the WO inhibitor is applied at a rate of 20 grams per hectare.
17. The method of claim 12, wherein the one or more fertilizers comprising a sugar akohol selected from the group consisting of mannitol and sorbitol is applied at a rate about 100 to about 100,000 grams per hectare.
18. The method of clairn 12, wherein the one or more sugar alcohols is applied at a rate about 1,000 to about 30,000 grams per hectare.
i 9. The method of claim 12, wherein the one or more fertilizers comprising a sugar akohol selected from the group consisting of mannitol and sorbitol is applied of about 6,800 grams per hectare.
20. The method of claim 13, wherein the one or more auxin herbicides is applied at a rate about 1 to about 1,000 grarns per hectare.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201962949642P | 2019-12-18 | 2019-12-18 | |
| US62/949,642 | 2019-12-18 | ||
| PCT/US2020/065188 WO2021126895A1 (en) | 2019-12-18 | 2020-12-16 | Agricultural compositions and methods of use thereof |
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| Publication Number | Publication Date |
|---|---|
| CA3159857A1 true CA3159857A1 (en) | 2021-06-24 |
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| CA3159857A Pending CA3159857A1 (en) | 2019-12-18 | 2020-12-16 | Agricultural compositions and methods of use thereof |
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| US (1) | US20210186020A1 (en) |
| JP (1) | JP2023507748A (en) |
| AR (1) | AR120787A1 (en) |
| AU (1) | AU2020407049A1 (en) |
| BR (1) | BR112022011376A2 (en) |
| CA (1) | CA3159857A1 (en) |
| MX (1) | MX2022007008A (en) |
| WO (1) | WO2021126895A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009112836A2 (en) * | 2008-03-12 | 2009-09-17 | Syngenta Limited. | Pickering emulsion formulations |
| EP2822387A1 (en) * | 2012-03-01 | 2015-01-14 | Basf Se | Agrochemical compositions |
| RU2654634C2 (en) * | 2013-09-25 | 2018-05-21 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Methods of weed control in chicory |
| CA2998866C (en) * | 2015-09-16 | 2024-01-23 | Attune Agriculture, Llc | Improved adjuvants for agricultural chemicals |
| CA3025912A1 (en) * | 2016-05-31 | 2017-12-07 | Novozymes Bioag A/S | Stable liquid inoculant compositions and coated plant propagation materials comprising same |
| WO2019126713A1 (en) * | 2017-12-22 | 2019-06-27 | Monsanto Technology Llc | Herbicidal mixtures |
| JP2022044850A (en) * | 2019-04-09 | 2022-03-18 | 住友化学株式会社 | Method of controlling weeds in cultivation area of field corn |
| US11690375B2 (en) * | 2019-12-18 | 2023-07-04 | Valent U.S.A., Llc | Agricultural compositions and methods of use thereof |
-
2020
- 2020-12-16 JP JP2022537088A patent/JP2023507748A/en active Pending
- 2020-12-16 MX MX2022007008A patent/MX2022007008A/en unknown
- 2020-12-16 AU AU2020407049A patent/AU2020407049A1/en active Pending
- 2020-12-16 WO PCT/US2020/065188 patent/WO2021126895A1/en active Application Filing
- 2020-12-16 CA CA3159857A patent/CA3159857A1/en active Pending
- 2020-12-16 US US17/123,584 patent/US20210186020A1/en not_active Abandoned
- 2020-12-16 BR BR112022011376A patent/BR112022011376A2/en unknown
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| AR120787A1 (en) | 2022-03-16 |
| WO2021126895A1 (en) | 2021-06-24 |
| BR112022011376A2 (en) | 2022-08-23 |
| US20210186020A1 (en) | 2021-06-24 |
| MX2022007008A (en) | 2022-06-17 |
| AU2020407049A1 (en) | 2022-06-23 |
| JP2023507748A (en) | 2023-02-27 |
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