CA2469482A1 - Method for the application of a viscous composition to the surface of a paper web and their products - Google Patents
Method for the application of a viscous composition to the surface of a paper web and their products Download PDFInfo
- Publication number
- CA2469482A1 CA2469482A1 CA002469482A CA2469482A CA2469482A1 CA 2469482 A1 CA2469482 A1 CA 2469482A1 CA 002469482 A CA002469482 A CA 002469482A CA 2469482 A CA2469482 A CA 2469482A CA 2469482 A1 CA2469482 A1 CA 2469482A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- web
- paper
- product
- paper web
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract 69
- 238000000034 method Methods 0.000 title claims abstract 31
- 239000000835 fiber Substances 0.000 claims abstract 13
- 239000000654 additive Substances 0.000 claims abstract 10
- 239000000126 substance Substances 0.000 claims abstract 10
- 230000000996 additive effect Effects 0.000 claims abstract 9
- -1 polysiloxane Polymers 0.000 claims abstract 8
- 229920001296 polysiloxane Polymers 0.000 claims abstract 8
- 230000000699 topical effect Effects 0.000 claims abstract 8
- 230000002209 hydrophobic effect Effects 0.000 claims 12
- 230000002238 attenuated effect Effects 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 4
- 239000007787 solid Substances 0.000 claims 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims 2
- 239000002562 thickening agent Substances 0.000 claims 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 230000000202 analgesic effect Effects 0.000 claims 1
- 239000000058 anti acne agent Substances 0.000 claims 1
- 230000002421 anti-septic effect Effects 0.000 claims 1
- 229940124340 antiacne agent Drugs 0.000 claims 1
- 239000003429 antifungal agent Substances 0.000 claims 1
- 229940121375 antifungal agent Drugs 0.000 claims 1
- 239000004599 antimicrobial Substances 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 239000002537 cosmetic Substances 0.000 claims 1
- 230000003247 decreasing effect Effects 0.000 claims 1
- 229960000735 docosanol Drugs 0.000 claims 1
- 239000003814 drug Substances 0.000 claims 1
- 229940079593 drug Drugs 0.000 claims 1
- 239000003974 emollient agent Substances 0.000 claims 1
- 230000009969 flowable effect Effects 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000003906 humectant Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 230000003020 moisturizing effect Effects 0.000 claims 1
- 239000000516 sunscreening agent Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/0005—Processes or apparatus specially adapted for applying liquids or other fluent materials to finished paper or board, e.g. impregnating, coating
- D21H5/0047—Processes or apparatus specially adapted for applying liquids or other fluent materials to finished paper or board, e.g. impregnating, coating by spraying or projecting
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/18—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising waxes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/32—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming a linkage containing silicon in the main chain of the macromolecule
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/46—Pouring or allowing the fluid to flow in a continuous stream on to the surface, the entire stream being carried away by the paper
- D21H23/48—Curtain coaters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
- Sanitary Thin Papers (AREA)
Abstract
A method is disclosed for topical application of compositions containing a chemical additive onto a paper web. The present invention is also directed to paper products formed from the method. In general, the method includes the steps of extruding a composition containing a chemical additive through a meltblown die and then applying the composition to a moving paper web. In one embodiment, the chemical composition is extruded into fibers and applied to the paper web. The chemical composition can contain, for instance, various additives, such as a polysiloxane softener.
Claims (59)
1. A process for applying a chemical additive to a paper web comprising the steps of:
providing a paper web; and extruding a viscous composition containing a chemical additive onto the paper web, said composition being extruded through a meltblown die in a manner that forms attenuated fibers that are applied to the paper web.
providing a paper web; and extruding a viscous composition containing a chemical additive onto the paper web, said composition being extruded through a meltblown die in a manner that forms attenuated fibers that are applied to the paper web.
2. A process as defined in claim 1, wherein said composition is a hydrophobic composition.
3. A process as defined in claim 1, wherein said composition is applied so as to cover from about 20% to about 80% of the surface area of a side of the web.
4. A process as defined in claim 1, wherein said viscous composition comprises a softener.
5. A process as defined in claim 5, wherein said softener comprises a polysiloxane.
6. A process as defined in claim 1, wherein said composition comprises a material selected from the group consisting of an anti-acne agent, an anti-microbial agent, an anti-fungal agent, an antiseptic, an antioxidant, a cosmetic astringent, a drug astringent, an aiological agent, an emollient, an external analgesic, a humectant, a moisturizing agent, a skin conditioning agent, a skin exfoliating agent, a sunscreen agent, and mixtures thereof.
7. A process as defined in claim 1, wherein said composition has a viscosity of at least about 1000 cps.
8. A process as defined in claim 1, wherein said composition has a viscosity of at least about 2000 cps.
9. A process as defined in claim 1, wherein said composition is applied to said paper web in an amount of from about 0.1% to about 10% by weight of said web.
10. A process as defined in claim 1, wherein said composition forms continuous fibers as said composition is extruded through said meltblown die.
11. A process as defined in claim 1, wherein said fibers exiting said meltblown die have a diameter of from about 5 microns to about 100 microns.~~
12. A process as defined in claim 1, further comprising heating the viscous composition prior to extruding the composition through the meltblown die.
13. A process as defined in claim 1, wherein the composition is applied to the paper web in an amount sufficient to increase the cross direction wet:dry ratio by at least 25%.
14. A process as defined in claim 1, wherein upon application of the composition to the paper web, the wet strength of the paper web is increased and the dry strength of the paper web is decreased.
15. A process as defined in claim 1, wherein the composition comprises a thickener.
16. A process as defined in claim 1, wherein the composition contains no surfactants.
17. A process as defined in claim 1, wherein the viscous composition comprises a solids content of at least about 80%.
18. A process as defined in claim 1, wherein the treated paper web has a Wet Out Time of no more than 3 seconds greater than the web untreated.
19. A process as defined in claim 1, wherein the treated paper web has a Wet Out Time of no more than 1 second greater than the web untreated.
20. A process as defined in claim 2, wherein the hydrophobic composition is applied so as to cover from about 30% to about 60% of the surface area of the side of the web.
21. A process as defined in claim 1, wherein after the composition has been applied to the web, the web has a cross direction wet:dry ratio of at least 0.45.
22. A process as defined in claim 1, wherein after the composition has been applied to the web, the web has a cross direction wet:dry ratio of at least 0.50.
23. A process as defined in claim 15, wherein said thickener comprises polyethylene oxide.
24. A paper product as defined in claim 1, wherein the fibers have a diameter of from about 5 microns to about 100 microns.
25. A process as defined in claim 2, wherein the composition is applied to both sides of the paper web and the treated web has a Wet Out Time of less than 5 seconds.
26. A paper product comprising:
a paper web comprising cellulosic fibers; and a topical viscous composition applied to at least one side of said paper web, said viscous composition comprising a chemical additive, said viscous composition being present on said paper web in the form of fibers.
a paper web comprising cellulosic fibers; and a topical viscous composition applied to at least one side of said paper web, said viscous composition comprising a chemical additive, said viscous composition being present on said paper web in the form of fibers.
27. A paper product as defined in claim 26, wherein said paper web has a basis weight of less than about 60 gsm.
28. A paper product as defined in claim 26, wherein after the composition has been applied to the paper web, the paper web has a cross direction wet:dry ratio of at least 0.45.
29. A paper product as defined in claim 26, wherein the paper web comprises a tissue web having a basis weight of less than about 50 gsm and wherein the viscous composition comprises a polysiloxane, said tissue web after being treated with the composition having a wet:dry ratio of at least 0.45.
30. A paper product as defined in claim 26, wherein the paper web has a basis weight of from about 25 gsm to about 45 gsm and a Wet Out Time of less than about 5 seconds.
31. A paper product as defined in claim 26, wherein the topical composition is applied to both sides of the web.
32. A paper product as defined in claim 26, wherein the paper product has a Wet Out Time of no more than 3 seconds greater than the paper web untreated with the topical composition.
33. A paper product as defined in claim 26, wherein the fibers comprise continuous filaments.
34. A paper product as defined in claim 26, wherein said topical composition is a hydrophobic composition.
35. A paper product as defined in claim 34, wherein the hydrophobic composition comprises a polysiloxane.
36. A paper product as defined in claim 34, wherein the hydrophobic composition consists essentially of a polysiloxane.
37. A paper product as defined in claim 26, wherein the topical composition is solid at ambient temperatures.
38. A paper product as defined in claim 26, wherein the topical composition covers from about 20% to about 80% of the surface area of the side of the web to which it is applied.
39. A paper product as defined in claim 26, wherein the chemical additive is an aminopolydialkylsiloxane.
40. A paper product as defined in claim 26, wherein the chemical additive is a neat polysiloxane.
41. A paper product as defined in claim 26, wherein the topical viscous composition comprises a solids content of at least about 80%.
42. A paper product as defined in claim 31, wherein the product has a Wet Out Time of less than about 5 seconds.
43. A paper product as defined in claim 26, wherein the fibers are attenuated.
44. A paper product as defined in claim 31, wherein the product has a Wet Out Time of less than about 4.8 seconds.
45. A paper product as defined in claim 26, wherein the paper product comprises bath tissue.
46. A paper product as defined in claim 26, wherein said viscous composition consists essentially a softener.
47. A paper product as defined in claim 26, wherein said viscous composition is present on said paper web in an amount from about 0.1% to about 10% by weight, based upon the weight of the web.
48. A paper product as defined in claim 26, wherein the viscous composition is added to the paper web in an amount sufficient to increase the cross direction wet:dry ratio by at least 25%.
49. A paper product as defined in claim 26, wherein the viscous composition is added to the paper web in an amount sufficient to increase the cross direction wet:dry ratio by at least 40%.
50. A tissue product comprising:
a tissue web having a basis weight of from about 25 gsm to about 45 gsm; and a hydrophobic composition applied to both sides of the tissue web, the hydrophobic composition comprising a chemical additive, the hydrophobic composition being present on the web in the form of fibers, the composition being applied to each side of the web so as to cover from about 20% to about 80% of the surface area of each side of the web, the treated tissue web having a Wet Out Time of less than about 5 seconds.
a tissue web having a basis weight of from about 25 gsm to about 45 gsm; and a hydrophobic composition applied to both sides of the tissue web, the hydrophobic composition comprising a chemical additive, the hydrophobic composition being present on the web in the form of fibers, the composition being applied to each side of the web so as to cover from about 20% to about 80% of the surface area of each side of the web, the treated tissue web having a Wet Out Time of less than about 5 seconds.
51. A tissue product as defined in claim 50, wherein the hydrophobic composition is applied to the web in an amount sufficient to cover from about 30%
to about 60% of the surface area of both sides of the web.
to about 60% of the surface area of both sides of the web.
52. A tissue product as defined in claim 50, wherein the product has a Wet Out Time of less than about 4.8 seconds.
53. A tissue product as defined in claim 50, wherein the hydrophobic composition comprises a polysiloxane.
54. A tissue product as defined in claim 50, wherein the hydrophobic composition consists essentially of a polysiloxane.
55. A tissue product as defined in claim 50, wherein the hydrophobic composition is present on the paper web in a total amount of from about 0.1%
to about 5% by weight, based upon the weight of the web.
to about 5% by weight, based upon the weight of the web.
56. A tissue product as defined in claim 50, wherein the fibers are attenuated.
57. A process for applying an additive to a paper web comprising the steps of:
providing a paper web;
preheating a composition, the composition being a solid at ambient temperatures, the composition being preheated an amount sufficient to make the composition flowable; and extruding the preheated composition onto the paper web, the composition being extruded through a meltblown die, the composition having a viscosity sufficient for the composition to form fibers as the composition is extruded through the meltblown die, the fibers being attenuated prior to being deposited onto the paper web, the composition cooling and resolidifying once deposited onto the web.
providing a paper web;
preheating a composition, the composition being a solid at ambient temperatures, the composition being preheated an amount sufficient to make the composition flowable; and extruding the preheated composition onto the paper web, the composition being extruded through a meltblown die, the composition having a viscosity sufficient for the composition to form fibers as the composition is extruded through the meltblown die, the fibers being attenuated prior to being deposited onto the paper web, the composition cooling and resolidifying once deposited onto the web.
58. A process as defined in claim 57, wherein the composition comprises behenyl alcohol.
59. A process as defined in claim 57, wherein the composition contains a wax.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/029,118 | 2001-12-21 | ||
| US10/036,735 | 2001-12-21 | ||
| US10/036,735 US6805965B2 (en) | 2001-12-21 | 2001-12-21 | Method for the application of hydrophobic chemicals to tissue webs |
| US10/029,118 US6716309B2 (en) | 2001-12-21 | 2001-12-21 | Method for the application of viscous compositions to the surface of a paper web and products made therefrom |
| PCT/US2002/037651 WO2003057988A1 (en) | 2001-12-21 | 2002-11-21 | Method for the application of a viscous composition to the surface of a paper web and their products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2469482A1 true CA2469482A1 (en) | 2003-07-17 |
| CA2469482C CA2469482C (en) | 2012-01-17 |
Family
ID=26704561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2469482A Expired - Fee Related CA2469482C (en) | 2001-12-21 | 2002-11-21 | Method for the application of a viscous composition to the surface of a paper web and their products |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1456471A1 (en) |
| KR (1) | KR100994321B1 (en) |
| AU (1) | AU2002346497C1 (en) |
| BR (1) | BR0214789A (en) |
| CA (1) | CA2469482C (en) |
| MX (1) | MXPA04005293A (en) |
| TW (1) | TWI268974B (en) |
| WO (1) | WO2003057988A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6949168B2 (en) * | 2002-11-27 | 2005-09-27 | Kimberly-Clark Worldwide, Inc. | Soft paper product including beneficial agents |
| US8545574B2 (en) | 2003-06-17 | 2013-10-01 | The Procter & Gamble Company | Methods for treating fibrous structures |
| US7470345B2 (en) * | 2003-12-30 | 2008-12-30 | Kimberly-Clark Worldwide, Inc. | Rolled paper product having high bulk and softness |
| US7588662B2 (en) * | 2007-03-22 | 2009-09-15 | Kimberly-Clark Worldwide, Inc. | Tissue products containing non-fibrous polymeric surface structures and a topically-applied softening composition |
| DE102017124280A1 (en) * | 2017-10-18 | 2019-04-18 | Voith Patent Gmbh | Curtain coater and method for applying a coating medium |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4939016A (en) * | 1988-03-18 | 1990-07-03 | Kimberly-Clark Corporation | Hydraulically entangled nonwoven elastomeric web and method of forming the same |
| US5624676A (en) * | 1995-08-03 | 1997-04-29 | The Procter & Gamble Company | Lotioned tissue paper containing an emollient and a polyol polyester immobilizing agent |
| FI110274B (en) * | 1996-11-04 | 2002-12-31 | Metso Paper Inc | Method and apparatus for coating a moving cardboard web |
| US5990377A (en) * | 1997-03-21 | 1999-11-23 | Kimberly-Clark Worldwide, Inc. | Dual-zoned absorbent webs |
| US6183814B1 (en) * | 1997-05-23 | 2001-02-06 | Cargill, Incorporated | Coating grade polylactide and coated paper, preparation and uses thereof, and articles prepared therefrom |
| JP2001519237A (en) * | 1997-10-10 | 2001-10-23 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | Spray application of additive composition to sheet material |
| US6033723A (en) * | 1998-02-24 | 2000-03-07 | Imation Corp. | Method and apparatus for coating plurality of wet layers on flexible elongated web |
| US6126784A (en) * | 1999-05-05 | 2000-10-03 | The Procter & Gamble Company | Process for applying chemical papermaking additives to web substrate |
| US6322604B1 (en) * | 1999-07-22 | 2001-11-27 | Kimberly-Clark Worldwide, Inc | Filtration media and articles incorporating the same |
-
2002
- 2002-11-21 KR KR1020047008638A patent/KR100994321B1/en not_active IP Right Cessation
- 2002-11-21 BR BR0214789-0A patent/BR0214789A/en not_active Application Discontinuation
- 2002-11-21 MX MXPA04005293A patent/MXPA04005293A/en active IP Right Grant
- 2002-11-21 AU AU2002346497A patent/AU2002346497C1/en not_active Ceased
- 2002-11-21 CA CA2469482A patent/CA2469482C/en not_active Expired - Fee Related
- 2002-11-21 WO PCT/US2002/037651 patent/WO2003057988A1/en not_active Application Discontinuation
- 2002-11-21 EP EP02784562A patent/EP1456471A1/en not_active Withdrawn
- 2002-12-12 TW TW091135925A patent/TWI268974B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU2002346497B2 (en) | 2008-04-17 |
| CA2469482C (en) | 2012-01-17 |
| TW200304978A (en) | 2003-10-16 |
| BR0214789A (en) | 2004-12-14 |
| TWI268974B (en) | 2006-12-21 |
| AU2002346497C1 (en) | 2009-01-22 |
| KR20040068191A (en) | 2004-07-30 |
| KR100994321B1 (en) | 2010-11-12 |
| AU2002346497A1 (en) | 2003-07-24 |
| EP1456471A1 (en) | 2004-09-15 |
| MXPA04005293A (en) | 2004-09-13 |
| WO2003057988A1 (en) | 2003-07-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20161121 |