CA2448113A1 - Polymere et son utilisation dans la production de papier et de carton - Google Patents
Polymere et son utilisation dans la production de papier et de carton Download PDFInfo
- Publication number
- CA2448113A1 CA2448113A1 CA002448113A CA2448113A CA2448113A1 CA 2448113 A1 CA2448113 A1 CA 2448113A1 CA 002448113 A CA002448113 A CA 002448113A CA 2448113 A CA2448113 A CA 2448113A CA 2448113 A1 CA2448113 A1 CA 2448113A1
- Authority
- CA
- Canada
- Prior art keywords
- paper
- strength
- cationic
- starch
- web
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 229920000642 polymer Polymers 0.000 title description 4
- 239000000654 additive Substances 0.000 claims abstract description 24
- 230000000996 additive effect Effects 0.000 claims abstract description 14
- 239000005017 polysaccharide Substances 0.000 claims abstract description 13
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 12
- -1 cationic polysaccharide Chemical class 0.000 claims abstract description 10
- 150000004676 glycans Chemical class 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 8
- 125000002348 vinylic group Chemical group 0.000 claims abstract description 5
- 229920002472 Starch Polymers 0.000 claims description 35
- 235000019698 starch Nutrition 0.000 claims description 35
- 239000008107 starch Substances 0.000 claims description 34
- 238000006467 substitution reaction Methods 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 abstract description 25
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract description 8
- 229920001577 copolymer Polymers 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 2
- 239000000123 paper Substances 0.000 description 28
- 238000007792 addition Methods 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- 229920001131 Pulp (paper) Polymers 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011087 paperboard Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N alpha-ketodiacetal Natural products O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 229920002401 polyacrylamide Polymers 0.000 description 3
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000000703 Cerium Chemical class 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229940015043 glyoxal Drugs 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229940001584 sodium metabisulfite Drugs 0.000 description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920000945 Amylopectin Polymers 0.000 description 1
- 229920000856 Amylose Polymers 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001720 carbohydrates Chemical group 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 150000002303 glucose derivatives Chemical group 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic
Landscapes
- Paper (AREA)
- Extrusion Of Metal (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Graft Or Block Polymers (AREA)
Abstract
L'invention concerne un copolymère stabilisé avec un polysaccharide cationique, qui est utilisé comme additif destiné à la production de papier ou de carton et pouvant améliorer la résistance d'une bande humide. Dans ledit copolymère, un acrylamide ou métacrylamide, un acide carboxylique vinylique et éventuellement d'autres monomères vinyliques sont utilisés comme monomères. La résistance à l'état humide d'une bande correspond à la résistance d'une bande de papier ou de carton pendant la production pour une teneur en matière sèche de 20 à 60 %. L'additif de l'invention améliore non seulement la résistance de la bande humide, mais également la résistance superficielle du produit. Par comparaison avec les additifs de la technique antérieure, un rapport relatif faible entre le nombre de chaînes latérales et les groupes cationiques est utilisé, puisqu'un polysaccharide ayant un caractère cationique supérieur offre une meilleure stabilité.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20011085A FI113968B (fi) | 2001-05-23 | 2001-05-23 | Kationisella polysakkaridilla stabiloitu liuospolymeeri |
| FI20011085 | 2001-05-23 | ||
| PCT/FI2002/000428 WO2002095128A1 (fr) | 2001-05-23 | 2002-05-20 | Polymere et son utilisation dans la production de papier et de carton |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2448113A1 true CA2448113A1 (fr) | 2002-11-28 |
Family
ID=8561260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002448113A Abandoned CA2448113A1 (fr) | 2001-05-23 | 2002-05-20 | Polymere et son utilisation dans la production de papier et de carton |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20040149412A1 (fr) |
| EP (1) | EP1392919B1 (fr) |
| AT (1) | ATE459752T1 (fr) |
| CA (1) | CA2448113A1 (fr) |
| DE (1) | DE60235539D1 (fr) |
| ES (1) | ES2340840T3 (fr) |
| FI (1) | FI113968B (fr) |
| PT (1) | PT1392919E (fr) |
| WO (1) | WO2002095128A1 (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA200806140B (en) | 2005-12-15 | 2009-12-30 | Dow Global Technologies Inc | Improved cellulose articles containing an addictive composition |
| US8916640B2 (en) | 2006-07-06 | 2014-12-23 | Dow Global Technologies Llc | Blended polyolefin dispersions |
| US8476326B2 (en) * | 2006-09-22 | 2013-07-02 | Dow Global Technologies Llc | Fibrillated polyolefin foam |
| EP2543764A3 (fr) | 2007-09-28 | 2013-10-30 | Dow Global Technologies LLC | Article à base de cellulose avec dispersion d'oléfine de cristallinité supérieure |
| KR101513388B1 (ko) | 2011-04-28 | 2015-04-17 | 휴렛-팩커드 디벨롭먼트 컴퍼니, 엘.피. | 디지털 고속 잉크젯 웨브 프레스 인쇄에 이용되는 매체 |
| US11447618B2 (en) | 2016-03-01 | 2022-09-20 | Kemira Oyj | Polymer composition, its use and a surface size |
| JP7047310B2 (ja) * | 2017-09-28 | 2022-04-05 | 荒川化学工業株式会社 | 紙力増強剤及び紙 |
| CN109749012A (zh) * | 2019-01-24 | 2019-05-14 | 湖北中之天科技股份有限公司 | 一种环保型无氯聚丙烯酰胺湿强剂的生产方法及在造纸中的应用 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3006806A (en) * | 1957-02-15 | 1961-10-31 | Olin Mathieson | Sized paper and process therefor |
| JPS5691075A (en) * | 1979-12-26 | 1981-07-23 | Kao Corp | Size composition |
| DE3162325D1 (en) * | 1980-12-12 | 1984-03-22 | Bayer Ag | Paper-sizing agents and a process for their preparation |
| US4372814A (en) * | 1981-05-13 | 1983-02-08 | United States Gypsum Company | Paper having mineral filler for use in the production of gypsum wallboard |
| US4684708A (en) * | 1985-03-11 | 1987-08-04 | Akzo N.V. | Cationic grafted starch copolymers |
| DE3702712A1 (de) * | 1987-01-30 | 1988-08-11 | Basf Ag | Leimungsmittel fuer papier auf basis feinteiliger waessriger dispersionen |
| JP2622965B2 (ja) * | 1987-03-02 | 1997-06-25 | 星光化学工業株式会社 | 製紙用添加剤 |
| US4866151A (en) * | 1987-03-25 | 1989-09-12 | National Starch And Chemical Corporation | Polysaccharide graft polymers containing acetal groups and their conversion to aldehyde groups |
| IT1224421B (it) * | 1987-12-29 | 1990-10-04 | Lamberti Flli Spa | Galattomannani modificati e realtivo procedimento di preparazione |
| JP2620806B2 (ja) * | 1988-07-11 | 1997-06-18 | 星光化学工業株式会社 | 製紙用添加剤と製紙方法 |
| US4954220A (en) * | 1988-09-16 | 1990-09-04 | E. I. Du Pont De Nemours And Company | Polysilicate microgels as retention/drainage aids in papermaking |
| US5338406A (en) * | 1988-10-03 | 1994-08-16 | Hercules Incorporated | Dry strength additive for paper |
| US5049634A (en) * | 1989-09-22 | 1991-09-17 | National Starch And Chemical Investment Holding Corporation | Derivatized and/or crosslinked products from acetal- and aldehyde-containing polysaccharide graft polymers |
| US5122231A (en) * | 1990-06-08 | 1992-06-16 | Cargill, Incorporated | Cationic cross-linked starch for wet-end use in papermaking |
| DE4127733A1 (de) * | 1991-08-22 | 1993-02-25 | Basf Ag | Pfropfpolymerisate aus saccharidstrukturen enthaltenden naturstoffen oder deren derivaten und ethylenisch ungesaettigten verbindungen und ihre verwendung |
| US5695609A (en) * | 1992-01-20 | 1997-12-09 | Kemira Oy | Process for producing paper |
| JP2928785B2 (ja) * | 1993-10-08 | 1999-08-03 | 星光化学工業株式会社 | 製紙用添加剤 |
| US6034181A (en) * | 1995-08-25 | 2000-03-07 | Cytec Technology Corp. | Paper or board treating composition of carboxylated surface size and polyacrylamide |
| DE19610995C2 (de) * | 1996-03-21 | 2002-12-19 | Betzdearborn Inc | Papierleimungsmittel und -verfahren |
| GB9625006D0 (en) * | 1996-11-30 | 1997-01-15 | Roe Lee Paper Chemicals Compan | 'One-shot'rosin emulsion including starch derivative for paper sizing |
| US5859128A (en) * | 1997-10-30 | 1999-01-12 | E. I. Du Pont De Nemours And Company | Modified cationic starch composition for removing particles from aqueous dispersions |
| JP3876522B2 (ja) * | 1998-02-20 | 2007-01-31 | 星光Ｐｍｃ株式会社 | 製紙用紙力増強剤及び強力紙の製造法 |
| FI107174B (fi) * | 1998-07-10 | 2001-06-15 | Raisio Chem Oy | Paperinvalmistuksen lisäainekoostumus |
| US6451170B1 (en) * | 2000-08-10 | 2002-09-17 | Cargill, Incorporated | Starch compositions and methods for use in papermaking |
-
2001
- 2001-05-23 FI FI20011085A patent/FI113968B/fi not_active IP Right Cessation
-
2002
- 2002-05-20 PT PT02771660T patent/PT1392919E/pt unknown
- 2002-05-20 CA CA002448113A patent/CA2448113A1/fr not_active Abandoned
- 2002-05-20 EP EP02771660A patent/EP1392919B1/fr not_active Expired - Lifetime
- 2002-05-20 US US10/478,138 patent/US20040149412A1/en not_active Abandoned
- 2002-05-20 AT AT02771660T patent/ATE459752T1/de active
- 2002-05-20 DE DE60235539T patent/DE60235539D1/de not_active Expired - Lifetime
- 2002-05-20 WO PCT/FI2002/000428 patent/WO2002095128A1/fr not_active Application Discontinuation
- 2002-05-20 ES ES02771660T patent/ES2340840T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FI20011085A0 (fi) | 2001-05-23 |
| PT1392919E (pt) | 2010-03-26 |
| EP1392919B1 (fr) | 2010-03-03 |
| FI20011085A (fi) | 2002-11-24 |
| FI113968B (fi) | 2004-07-15 |
| US20040149412A1 (en) | 2004-08-05 |
| ES2340840T3 (es) | 2010-06-10 |
| WO2002095128A9 (fr) | 2003-01-23 |
| ATE459752T1 (de) | 2010-03-15 |
| DE60235539D1 (de) | 2010-04-15 |
| WO2002095128A1 (fr) | 2002-11-28 |
| EP1392919A1 (fr) | 2004-03-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued | ||
| FZDE | Discontinued |
Effective date: 20120216 |