CA2116561A1 - Pipe joint and process for producing pipe joints made of polyolefin - Google Patents
Pipe joint and process for producing pipe joints made of polyolefinInfo
- Publication number
- CA2116561A1 CA2116561A1 CA002116561A CA2116561A CA2116561A1 CA 2116561 A1 CA2116561 A1 CA 2116561A1 CA 002116561 A CA002116561 A CA 002116561A CA 2116561 A CA2116561 A CA 2116561A CA 2116561 A1 CA2116561 A1 CA 2116561A1
- Authority
- CA
- Canada
- Prior art keywords
- tube
- connector member
- tube end
- self
- conduit connection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L47/00—Connecting arrangements or other fittings specially adapted to be made of plastics or to be used with pipes made of plastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/66—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by liberation of internal stresses, e.g. shrinking of one of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C57/00—Shaping of tube ends, e.g. flanging, belling or closing; Apparatus therefor, e.g. collapsible mandrels
- B29C57/02—Belling or enlarging, e.g. combined with forming a groove
- B29C57/04—Belling or enlarging, e.g. combined with forming a groove using mechanical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/112—Single lapped joints
- B29C66/1122—Single lap to lap joints, i.e. overlap joints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
- B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
- B29C66/1222—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a lapped joint-segment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
- B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
- B29C66/1226—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least one bevelled joint-segment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/522—Joining tubular articles
- B29C66/5221—Joining tubular articles for forming coaxial connections, i.e. the tubular articles to be joined forming a zero angle relative to each other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/52—Joining tubular articles, bars or profiled elements
- B29C66/522—Joining tubular articles
- B29C66/5229—Joining tubular articles involving the use of a socket
- B29C66/52297—Joining tubular articles involving the use of a socket said socket comprising slip-off prevention means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L47/00—Connecting arrangements or other fittings specially adapted to be made of plastics or to be used with pipes made of plastics
- F16L47/20—Connecting arrangements or other fittings specially adapted to be made of plastics or to be used with pipes made of plastics based principally on specific properties of plastics
- F16L47/22—Connecting arrangements or other fittings specially adapted to be made of plastics or to be used with pipes made of plastics based principally on specific properties of plastics using shrink-down material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C57/00—Shaping of tube ends, e.g. flanging, belling or closing; Apparatus therefor, e.g. collapsible mandrels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C61/00—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/116—Single bevelled joints, i.e. one of the parts to be joined being bevelled in the joint area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/737—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined
- B29C66/7371—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined oriented or heat-shrinkable
- B29C66/73715—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the state of the material of the parts to be joined oriented or heat-shrinkable heat-shrinkable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Branch Pipes, Bends, And The Like (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Non-Disconnectible Joints And Screw-Threaded Joints (AREA)
- Details Of Indoor Wiring (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
An end (13) of a pipe (12) made of polyolefin is cold-deformed, i.e. at the ambient temperature, by means of a spreading mandrel.
After the spreading mandrel is removed, the enlarged pipe end (13) and a desired connecting piece or the end (11) of another pipe (10) are plugged onto each other. The polyolefin pipe end (13) is then deformed back to the original shape and forms by self-redeformation a solid and gas-tight connection with the connecting piece or the end (11) of the other pipe (10).
After the spreading mandrel is removed, the enlarged pipe end (13) and a desired connecting piece or the end (11) of another pipe (10) are plugged onto each other. The polyolefin pipe end (13) is then deformed back to the original shape and forms by self-redeformation a solid and gas-tight connection with the connecting piece or the end (11) of the other pipe (10).
Description
211 6~ fiI
Tu~e Conduit Connection and Method of Producing the Same from Polyolefins The invention relates to a method of producing a tube con-duit connection in which method a tube end of a tube made of polyolefin, is expanded and placed onto a conneckor member, as well as a tube conduit connection thus produced.
In a known method of this type as published in German Pub-lished Patent Application No. P 38 17 442.1, there is described such tube conduit connection by means of, for example, a shrink-on sleeve which bridges the connector members of two :15 tubes. The shrink-on sleeve may be made of, for example, a thermo-elastic material like cross-linked polyolefin. The shrink-on sleeve is connected to the connector members in that the cross-linked polyolefin, after being heated above the crystallite melting point, can be deformed in the heated con-;20 dition and pushed with expansion onto the connector members inthe heated condition. In the same manner, the tube end of a tube made of cross-linked polyolefin also can be pushed onto a c~nnector member, for example, a T-piece.
. . .
From European Published Patent Application No. 0 102 919 there is also known a tube conduit connection made of a connector member, which also may be a tube end, and a tube end. The tube end is firmly and sealingly connected to an end portion of the connector member or the tube ~end by heating above the crystallite melting point and self-reconversion. The tube_e~d has~an internal diameter which is smaller than the outer diameter of the connector member or the tube.
Carrying out this method and producing the aforementioned tube conduit connection results in certain difficulties in practicebecause the cross-linked polyolefin must be heated to relatively high temperatures, for example, above 135C in the 2~ fi ~
case of cross-linked poly ethylene, and has sufficiently ready deformability only at this temperature. Therefore, it is decisive that the concerned parts are connected to each other within a brief time period such that there is no cooling below the crystallite melting temperature.
It i8 the object of the invention to provide a method of producing a tube conduit connection of the initially mentioned type and which method permits producing a secure tube conduit connection under normal, i.e. environmental temperatures. It is also an object of the invention to provide a tube conduit connection which can be produced under environmental conditions and constitutes a secure sealing connection.
According to the invention and with regard to the method, the object is achieved in that the end of the tube which has an internal diameter smaller than the external diameter of the connecting member, is reversibly expanded at environmental temperature with the assistance of an expanding mandrel to an internal diameter which~is greater than the external diameter of the connecting member,~and, after removal of the expanding mandrel, the still expanded end of the tube and the connecting member~ aré telescoped onto~each other, whereby the connecting member and the tube~end are firmly ~and sealingly inter-aonnected~ due~ to the self-reconversion of the reversibly expanded-~tube end.
-Regarding th2 tube~ conduit ~connection, this object is ac~ieved in that the~-tube end, which has been mechanically ; 30 expanded at -environmental ~temperature and ~which is self-; récon~ve~tib~at the ~environmental temperature! is firmly andséalingiy connected to the end portion of the connecting member.~
" --The invention is based on the surprising recognition that : polynlefing, in particular medium density, high density or cross-linked polyolef~ins, have sufficiently extensive, ~: , 2I16;&1 - 2~
reversible deformability even in the cold and partially crystalline condition, i.e. in a condition not heated above the crystallite melting point. This means that the polyolefin can be deformed or shaped under mechanical action, however, in S its deformed condition, tends to reassume the original shape.
Upon application of sufficiently strong forces, for example, by means of an expanding mandrel of conventional construction for expanding tubes, it is, therefore, possible to reversibly expand the tube ends of tubes made of polyolefins. Under the conditions prevailing at environmental ~ .
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21~6~61 temperature, the self-reconversion to the original condition, i.e. the original tube width, proceeds at relatively low speed so that the expanding mandrel can be removed from the expanded tube end and the still expanded tube end can be telescoped onto the respectively desired connector member. On the other hand, the speed of self-reconversion is sufficiently high so that there do not arise any undue waiting periods.
When compared to other materials, polyolefins have the advantage that the expansion as far as still existing after connection to the connector member, does not result in stress cracks.
The inventive method thus offers a particularly advan-tageous possibility of connecting tubes which are made of polyolefins, especially tubes made of medium density, high density or cross-linked polyolefins, with a respectively desired connector member~ without~the expense of heat energy.
When carryi~ng out this~method, there is obtained a particular-ly f~irm and seal-ing,~specifically~gas-tight connection~due to the~ self~-reconversi~on~of;~the ~expanded tube end~. During such self-reconversion,; the~ polyolefin~adapts to surface struc-i25~ tures which are~eventually~present at the connector member. As '~ ~examples~for~;such~;~surface~structures which increase the bon-ding 'gtrength,~'there- may~be~cons~idered beads,~lutes, grooves or~Xnurlings~whiah~are~ ngaged~by~the 'reconverted polyolefin.
; In~connection~with the'precedingly~described method further securiDg~of the-~produced tube~conduit connections is possible, if required.~This~ purpose~is served~by tube clamps of conven-tional'type~ However~ it~is~also possible to attach a tension ring to~the-tube~end~of the~ tube~which is made of polyolefin.
In 'the~e~ent that such tension;ring~is~also made~of reversibly deformable material,~ the~tension ring may be~ attached to the tube end from the start. It is, however, also possible to push , , : , 211~&1 a tension ring which is made of a material, for example, metal which is not or only little deformable, onto the tube-sided end of the tube conduit connection using known hydraulic means, after the tube conduit connection has been produced.
Exemplary embodiments of tube conduit connections produced in accordance with the inventive method are illustrated in the drawings and will be explained and described hereinbelow in detail with reference to the reference numerals. There are shown in : .
Figure 1 a sectional view of a tube conduit connection produced from a connector member and a tube end applied thereto according to the inventive method;
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Figure 2 a sectional view of a tube conduit connection as -shown in Figure 1 and containing a tension ring;
Figure 3 a sectional view of the inventive tube conduit connection formed between two tube ends.
.: .
-,-In the sectional view of Figure 1, there will be recognised Z5 a connector member 1 which~ may constitute, for example, a -s~raight tube~piece, an angle tube or any other connector for connecting two tubes~,~ however, also a triple connector piece ~like a~T-piece. This~connector member~1 is made of a material like~metal, glass, ceramic, plastic or any other material selected with~the~view of the intended purpose of use. At each - ~ ~ j;UnCt-10~ ~place ;the~connector member l is provided with a sur--face structure~for~ incréasing~the~ bonding strength. In the illustrated exemplary embodiment, this surface structure is formed by a thickened end ;portion 2 which tapers towards the end. Instead, there may be provided;one or more beads, flutes or grooves or also knurlings or the like.
2li6~6l .
The illustration of Figure 1 shows a tube 3 made of poly-olefin, preferably medium density or high density, particu-larly cross-linked polyolefin. The internal diameter of the tube 3 is smaller than the external diameter of the connector member 1; as illustrated, the internal diameter may be sub-stantially equal to the internal diameter of the connector member 1 whereby there can be prevented the formation of flow resistance due to constrictions or deposits formed at the con-strictions from the medium flowing through the connector mem-ber 1 and the tube 3. For producing the tube connection, the tube end 4 i5 expanded at environmental temperature, using, for example~ a conventional expanding mandrel, to an extent such that the internal diameter of the tube end 4 is at least as wide as the external diameter of the connector member 1 in the area of the thickened end portion 2. After being pushed beyond the thickened end portion 2, the tube end 4 is subject to self-reconversion to the original dimensions. As a conse-quence, the tube~end 4, as illustrated, adapts to the external profile of the connector member 1. Since the tube end 4 origi-nally~had an internal ~diameter which is smaller than the ex-~ternal diameter~of the connector momber 1, the tube end 4tightly engage8~along;its~1ength the~end~portion 2 of the con-nector member 1.~ There is thus formod in~ the ond a relatively large-area, very~tight connèction between the tube end 4 and the eonn-ctor;mombor~
Piguré ~2 ~shows a ~furthor- ombodiment of tho aforedescribed tube conduit,connection and correponding members therein are ~3~ pro~ided with-~the~same~reférenco~numorals~. In this embodiment, a~tengion ring~S~is provided~as ~additional socuring means for producing~-a sealing;~connoction-~between~the tube end 4 and the connector~mémber~ This~ tension~ring 5~preferably is made of ~: the 8amæ material as~ tho~tubo 3.~I~n~the~ilIustrated exemplary embodiment, the tube~3; as wé11 as ;the tension ring 5 are made of cross-linked poly~ethylone.~ Tho intornal diameter of the tension r~ing 5 is c losely adapted to ~tho~external diameter of :
211~.~1 " ''' the tube 3 and is pushed onto the tube end 4 prior to making the tube conduit connection. During the subsequent expanding operation, the tension ring 5 is temporarily expanded con-jointly with the tube end 4 such that the expanded tube end ~
is placed onto the end portion 2 of the connector member 1 to-gether with the applied tension ring 5. Subsequent self-recon-version, then, results in the sealing connection between the tube end 4 and the end portion 2 of the connector member 1 in the aforedescribed manner, whereby also the tension ring 5 contracts and thus additionally presses the tube end 4 against the end portion 2 in the area of the tension ring 5.
Figure 3 shows a tube conduit connection formed between two tube ends. Both the tubes may consist of the same or different materials; preferably, the tubes are made of cross-linked polyolefin and serve as conducting tubes for corrosive media.
As an example there are mentioned industrial, however, par-ticularly domestic waste waters which require especially cor-rosion resistant tube materials and with respect to which tubes made of cross-linked polyolefin have proven useful in practice.
In the illustrated exemplary embodiment, the two tubes have the same internal and external diameters. This, however, is not significant since the same tube conduit connection can also be produced between tubes of different diameters, if de-sired, provided that the differences in the internal diameters do not result in undue flow resistance and deposits. A first tube 10 has a first tube end 11; a second tube 12 has a second tube end 13. I~t will be seen that the internal diameter of the secon-d ~tube end 13 is expanded and this expanded second tube end 13 is pushed onto the first tube end 11 of the first tube 10. This expansion is carried out using, for example, a con-ventional expanding mandrel at environmental temperature, as in the previous exemplary embodiments, and is subject to the described self-reconversion due to which the expanded tube end - 13 tends to reassume its original shape. The large-area tight 2116~1 engagement between the two tube ends 11 and 13 produces, also in this case, a sealed tube conduit connection which, due to the corrosion resistance of the material against the aforemen-tioned waste water, will not leak even after long-time use.
Also in this case, as in the exemplary embodiment illu-strated in Figure 2, the connection can be additionally secured by means of a tension ring; however, it must be ob-served in such case that no undue deformation of the first tube end 11 i8 produced under the compressive pressure exerted by such tension ring. Such deformation may present a flow resistance to the throughflowing waste water or may give rise to deposits formed from the waste water in the region of the connection area. Instead of the tension ring, a bonding agent may be employed, if desired, for additionaIly securing the connection area.
Tubes which are made of cross-linked polyolefin, therefore, are used in waste water technology also for this reason, because in this~manner~secure, self-seal~ing connections can be readily made~between~tw~o ~smooth tubes~. Additionally, there is obtained~the~;further~advantage~that the tubes 10 and~13, which ~are ~prodùced~;in~a;continuous~process,~ can also be placed or laid~a~ continuous~tubes~without there~being required specific ~ 25 angle tubes or'other'~-connécting ~mémbers in order to place or ^~ lay~the~-'tubes -in~accordance~with a predetermined pattern or course~.'Th~èréfore,~connections~between *ubes must only be made ;at''the'-i'n ~ '-''and'ou'tl'et'~'locations.~
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'1; ~ ~ ~ , ' ' ' ' - : ,:
- , ,
Tu~e Conduit Connection and Method of Producing the Same from Polyolefins The invention relates to a method of producing a tube con-duit connection in which method a tube end of a tube made of polyolefin, is expanded and placed onto a conneckor member, as well as a tube conduit connection thus produced.
In a known method of this type as published in German Pub-lished Patent Application No. P 38 17 442.1, there is described such tube conduit connection by means of, for example, a shrink-on sleeve which bridges the connector members of two :15 tubes. The shrink-on sleeve may be made of, for example, a thermo-elastic material like cross-linked polyolefin. The shrink-on sleeve is connected to the connector members in that the cross-linked polyolefin, after being heated above the crystallite melting point, can be deformed in the heated con-;20 dition and pushed with expansion onto the connector members inthe heated condition. In the same manner, the tube end of a tube made of cross-linked polyolefin also can be pushed onto a c~nnector member, for example, a T-piece.
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From European Published Patent Application No. 0 102 919 there is also known a tube conduit connection made of a connector member, which also may be a tube end, and a tube end. The tube end is firmly and sealingly connected to an end portion of the connector member or the tube ~end by heating above the crystallite melting point and self-reconversion. The tube_e~d has~an internal diameter which is smaller than the outer diameter of the connector member or the tube.
Carrying out this method and producing the aforementioned tube conduit connection results in certain difficulties in practicebecause the cross-linked polyolefin must be heated to relatively high temperatures, for example, above 135C in the 2~ fi ~
case of cross-linked poly ethylene, and has sufficiently ready deformability only at this temperature. Therefore, it is decisive that the concerned parts are connected to each other within a brief time period such that there is no cooling below the crystallite melting temperature.
It i8 the object of the invention to provide a method of producing a tube conduit connection of the initially mentioned type and which method permits producing a secure tube conduit connection under normal, i.e. environmental temperatures. It is also an object of the invention to provide a tube conduit connection which can be produced under environmental conditions and constitutes a secure sealing connection.
According to the invention and with regard to the method, the object is achieved in that the end of the tube which has an internal diameter smaller than the external diameter of the connecting member, is reversibly expanded at environmental temperature with the assistance of an expanding mandrel to an internal diameter which~is greater than the external diameter of the connecting member,~and, after removal of the expanding mandrel, the still expanded end of the tube and the connecting member~ aré telescoped onto~each other, whereby the connecting member and the tube~end are firmly ~and sealingly inter-aonnected~ due~ to the self-reconversion of the reversibly expanded-~tube end.
-Regarding th2 tube~ conduit ~connection, this object is ac~ieved in that the~-tube end, which has been mechanically ; 30 expanded at -environmental ~temperature and ~which is self-; récon~ve~tib~at the ~environmental temperature! is firmly andséalingiy connected to the end portion of the connecting member.~
" --The invention is based on the surprising recognition that : polynlefing, in particular medium density, high density or cross-linked polyolef~ins, have sufficiently extensive, ~: , 2I16;&1 - 2~
reversible deformability even in the cold and partially crystalline condition, i.e. in a condition not heated above the crystallite melting point. This means that the polyolefin can be deformed or shaped under mechanical action, however, in S its deformed condition, tends to reassume the original shape.
Upon application of sufficiently strong forces, for example, by means of an expanding mandrel of conventional construction for expanding tubes, it is, therefore, possible to reversibly expand the tube ends of tubes made of polyolefins. Under the conditions prevailing at environmental ~ .
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21~6~61 temperature, the self-reconversion to the original condition, i.e. the original tube width, proceeds at relatively low speed so that the expanding mandrel can be removed from the expanded tube end and the still expanded tube end can be telescoped onto the respectively desired connector member. On the other hand, the speed of self-reconversion is sufficiently high so that there do not arise any undue waiting periods.
When compared to other materials, polyolefins have the advantage that the expansion as far as still existing after connection to the connector member, does not result in stress cracks.
The inventive method thus offers a particularly advan-tageous possibility of connecting tubes which are made of polyolefins, especially tubes made of medium density, high density or cross-linked polyolefins, with a respectively desired connector member~ without~the expense of heat energy.
When carryi~ng out this~method, there is obtained a particular-ly f~irm and seal-ing,~specifically~gas-tight connection~due to the~ self~-reconversi~on~of;~the ~expanded tube end~. During such self-reconversion,; the~ polyolefin~adapts to surface struc-i25~ tures which are~eventually~present at the connector member. As '~ ~examples~for~;such~;~surface~structures which increase the bon-ding 'gtrength,~'there- may~be~cons~idered beads,~lutes, grooves or~Xnurlings~whiah~are~ ngaged~by~the 'reconverted polyolefin.
; In~connection~with the'precedingly~described method further securiDg~of the-~produced tube~conduit connections is possible, if required.~This~ purpose~is served~by tube clamps of conven-tional'type~ However~ it~is~also possible to attach a tension ring to~the-tube~end~of the~ tube~which is made of polyolefin.
In 'the~e~ent that such tension;ring~is~also made~of reversibly deformable material,~ the~tension ring may be~ attached to the tube end from the start. It is, however, also possible to push , , : , 211~&1 a tension ring which is made of a material, for example, metal which is not or only little deformable, onto the tube-sided end of the tube conduit connection using known hydraulic means, after the tube conduit connection has been produced.
Exemplary embodiments of tube conduit connections produced in accordance with the inventive method are illustrated in the drawings and will be explained and described hereinbelow in detail with reference to the reference numerals. There are shown in : .
Figure 1 a sectional view of a tube conduit connection produced from a connector member and a tube end applied thereto according to the inventive method;
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Figure 2 a sectional view of a tube conduit connection as -shown in Figure 1 and containing a tension ring;
Figure 3 a sectional view of the inventive tube conduit connection formed between two tube ends.
.: .
-,-In the sectional view of Figure 1, there will be recognised Z5 a connector member 1 which~ may constitute, for example, a -s~raight tube~piece, an angle tube or any other connector for connecting two tubes~,~ however, also a triple connector piece ~like a~T-piece. This~connector member~1 is made of a material like~metal, glass, ceramic, plastic or any other material selected with~the~view of the intended purpose of use. At each - ~ ~ j;UnCt-10~ ~place ;the~connector member l is provided with a sur--face structure~for~ incréasing~the~ bonding strength. In the illustrated exemplary embodiment, this surface structure is formed by a thickened end ;portion 2 which tapers towards the end. Instead, there may be provided;one or more beads, flutes or grooves or also knurlings or the like.
2li6~6l .
The illustration of Figure 1 shows a tube 3 made of poly-olefin, preferably medium density or high density, particu-larly cross-linked polyolefin. The internal diameter of the tube 3 is smaller than the external diameter of the connector member 1; as illustrated, the internal diameter may be sub-stantially equal to the internal diameter of the connector member 1 whereby there can be prevented the formation of flow resistance due to constrictions or deposits formed at the con-strictions from the medium flowing through the connector mem-ber 1 and the tube 3. For producing the tube connection, the tube end 4 i5 expanded at environmental temperature, using, for example~ a conventional expanding mandrel, to an extent such that the internal diameter of the tube end 4 is at least as wide as the external diameter of the connector member 1 in the area of the thickened end portion 2. After being pushed beyond the thickened end portion 2, the tube end 4 is subject to self-reconversion to the original dimensions. As a conse-quence, the tube~end 4, as illustrated, adapts to the external profile of the connector member 1. Since the tube end 4 origi-nally~had an internal ~diameter which is smaller than the ex-~ternal diameter~of the connector momber 1, the tube end 4tightly engage8~along;its~1ength the~end~portion 2 of the con-nector member 1.~ There is thus formod in~ the ond a relatively large-area, very~tight connèction between the tube end 4 and the eonn-ctor;mombor~
Piguré ~2 ~shows a ~furthor- ombodiment of tho aforedescribed tube conduit,connection and correponding members therein are ~3~ pro~ided with-~the~same~reférenco~numorals~. In this embodiment, a~tengion ring~S~is provided~as ~additional socuring means for producing~-a sealing;~connoction-~between~the tube end 4 and the connector~mémber~ This~ tension~ring 5~preferably is made of ~: the 8amæ material as~ tho~tubo 3.~I~n~the~ilIustrated exemplary embodiment, the tube~3; as wé11 as ;the tension ring 5 are made of cross-linked poly~ethylone.~ Tho intornal diameter of the tension r~ing 5 is c losely adapted to ~tho~external diameter of :
211~.~1 " ''' the tube 3 and is pushed onto the tube end 4 prior to making the tube conduit connection. During the subsequent expanding operation, the tension ring 5 is temporarily expanded con-jointly with the tube end 4 such that the expanded tube end ~
is placed onto the end portion 2 of the connector member 1 to-gether with the applied tension ring 5. Subsequent self-recon-version, then, results in the sealing connection between the tube end 4 and the end portion 2 of the connector member 1 in the aforedescribed manner, whereby also the tension ring 5 contracts and thus additionally presses the tube end 4 against the end portion 2 in the area of the tension ring 5.
Figure 3 shows a tube conduit connection formed between two tube ends. Both the tubes may consist of the same or different materials; preferably, the tubes are made of cross-linked polyolefin and serve as conducting tubes for corrosive media.
As an example there are mentioned industrial, however, par-ticularly domestic waste waters which require especially cor-rosion resistant tube materials and with respect to which tubes made of cross-linked polyolefin have proven useful in practice.
In the illustrated exemplary embodiment, the two tubes have the same internal and external diameters. This, however, is not significant since the same tube conduit connection can also be produced between tubes of different diameters, if de-sired, provided that the differences in the internal diameters do not result in undue flow resistance and deposits. A first tube 10 has a first tube end 11; a second tube 12 has a second tube end 13. I~t will be seen that the internal diameter of the secon-d ~tube end 13 is expanded and this expanded second tube end 13 is pushed onto the first tube end 11 of the first tube 10. This expansion is carried out using, for example, a con-ventional expanding mandrel at environmental temperature, as in the previous exemplary embodiments, and is subject to the described self-reconversion due to which the expanded tube end - 13 tends to reassume its original shape. The large-area tight 2116~1 engagement between the two tube ends 11 and 13 produces, also in this case, a sealed tube conduit connection which, due to the corrosion resistance of the material against the aforemen-tioned waste water, will not leak even after long-time use.
Also in this case, as in the exemplary embodiment illu-strated in Figure 2, the connection can be additionally secured by means of a tension ring; however, it must be ob-served in such case that no undue deformation of the first tube end 11 i8 produced under the compressive pressure exerted by such tension ring. Such deformation may present a flow resistance to the throughflowing waste water or may give rise to deposits formed from the waste water in the region of the connection area. Instead of the tension ring, a bonding agent may be employed, if desired, for additionaIly securing the connection area.
Tubes which are made of cross-linked polyolefin, therefore, are used in waste water technology also for this reason, because in this~manner~secure, self-seal~ing connections can be readily made~between~tw~o ~smooth tubes~. Additionally, there is obtained~the~;further~advantage~that the tubes 10 and~13, which ~are ~prodùced~;in~a;continuous~process,~ can also be placed or laid~a~ continuous~tubes~without there~being required specific ~ 25 angle tubes or'other'~-connécting ~mémbers in order to place or ^~ lay~the~-'tubes -in~accordance~with a predetermined pattern or course~.'Th~èréfore,~connections~between *ubes must only be made ;at''the'-i'n ~ '-''and'ou'tl'et'~'locations.~
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Claims (15)
1. Method of producing a tube conduit connection in which method a tube end (4) of a tube (3) made of polyolefin, is expanded and placed onto a connector member (1), characterised in that the end (4) of the tube (3) which has an internal diameter smaller than the external diame-ter of the connector member (1), is reversibly expanded at environmental temperature with the assistance of an expan-ding mandrel to an internal diameter which is greater than the external diameter of the connector member (1), and that, after removal of the expanding mandrel, the still expanded end (4) of the tube (3) and the connector member (1) are telescoped onto each other, whereby the connector member (1) is firmly and sealingly connected to the tube end (4) due; to the self-reconversion of the reversibly expanded tube end (4).
2. Method according to claim 1, characterised in that an end portion (2) of the connector member (1) is provided with a surface structure for increasing the engagement surface at the tube end (4).
3. Method according to claim 1 or 2, characterised in that the connection is additionally secured by means of a tube clamp.
4. Method according to claim 1 or 2, characterised in that the connection is secured by means of a tension ring (5).
5. Method according to claim 4, characterised in that the tension ring (5) is made of a material which is expandable at environmental temperature and self-reconvertible and which is reversibly expanded conjointly with the tube end (4).
6. Method according to claim 4, characterised in that the tension ring is made of a material which is not or only little deformable, and hydraulically pushed onto the tube end surrounding the connector member after making the connection.
7. Tube conduit connection made of a connector member (1) and a tube end (4) which is mechanically expanded and firmly and sealingly connected to an end portion (2) of the connector member (1) by self-reconversion, the tube (3) having an internal diameter which is smaller than the external diameter of the connector member (1), characterised in that the tube end (4) which is mechanically expanded at environmental temperature and self-reconverted at environmental temperature, is firmly and sealingly connected to the end portion (2) of the connector member (1).
8. Tube conduit connection according to claim 7, characterised in that the end portion (2) of the connector member (1) is provided with a surface structure for increasing the engagement surface with the tube end (4).
9. Tube conduit connection according to claim 7 or 8, characterised by a tension ring (5) which is applied to the tube end (4) and which is made of a material which is expandable and self-reconvertible at environmental temperature.
10. Tube conduit connection according to any one of claims 7 to 9, characterised in that the tube (3) is selected from a medium density, high density or cross-linked polyolefin.
11. Tube conduit connection made of a first tube end (11) of a first tube (10) and a mechanically expanded, self-reconvertible second tube end (13) of a self-reconvertible tube (12), said second tube end being firmly and sealingly connected with the first tube end (11), characterised in that the second tube end (13) which is mechanically expanded at environmental temperature and self-reconvertible at environmental temperature, is firmly and sealingly connected with the first tube end (11).
12. Tube conduit connection according to claim 11, characterised in that the first tube end (11) of the first tube (10) is provided with a surface structure for increasing the engagement surface with the second tube end (13).
13. Tube conduit connection according to claim 11 or 12, characterised in that the connection is secured by means of a tension ring.
14. Tube conduit connection according to claim 13, characterised in that the tension ring is made of a material which is expandable and self-reconvertible at environmental temperature.
15. Tube conduit connection according to any one of claims 11 to 14, characterised in that the first and second tube (10,12) are made of medium density, high density or cross-linked polyolefin.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP91114686.8 | 1991-08-31 | ||
EP91114686A EP0530387B2 (en) | 1991-08-31 | 1991-08-31 | Pipeline connection and method of manufacturing pipeline connections made of polyolefine |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2116561A1 true CA2116561A1 (en) | 1993-03-18 |
Family
ID=8207102
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002116561A Abandoned CA2116561A1 (en) | 1991-08-31 | 1992-08-21 | Pipe joint and process for producing pipe joints made of polyolefin |
Country Status (23)
Country | Link |
---|---|
EP (1) | EP0530387B2 (en) |
JP (1) | JP3223977B2 (en) |
KR (1) | KR100250347B1 (en) |
AT (1) | ATE129795T1 (en) |
AU (1) | AU669665B2 (en) |
CA (1) | CA2116561A1 (en) |
CZ (1) | CZ286291B6 (en) |
DE (1) | DE59106833D1 (en) |
DK (1) | DK0530387T4 (en) |
ES (1) | ES2081406T5 (en) |
FI (1) | FI940864A0 (en) |
GR (2) | GR3018275T3 (en) |
HK (1) | HK100096A (en) |
HU (1) | HU215296B (en) |
IL (1) | IL102958A (en) |
NO (1) | NO311952B1 (en) |
NZ (1) | NZ244134A (en) |
PL (1) | PL170053B1 (en) |
PT (1) | PT100823B (en) |
SK (1) | SK282175B6 (en) |
TR (1) | TR27381A (en) |
WO (1) | WO1993005332A1 (en) |
ZA (1) | ZA926585B (en) |
Cited By (1)
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GB2486952B (en) * | 2010-12-14 | 2016-04-06 | Mercury Plastics Inc | Method for making a reservoir |
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AT398725B (en) * | 1992-10-21 | 1995-01-25 | Schnallinger Helfried Ing | METHOD FOR PRODUCING EXHAUST SLEEVES ON PLASTIC PIPES |
DE4310000C2 (en) * | 1993-03-27 | 2002-03-28 | Wirsbo Pex Gmbh | Pipe connection, pipe connector and use of a hydraulic device for making pipe connections |
DE9417116U1 (en) * | 1994-10-25 | 1995-01-19 | Wirsbo Rohrproduktion und Vertriebs-GmbH, 63150 Heusenstamm | Multiple pipe connector |
FI108574B (en) * | 1995-06-09 | 2002-02-15 | Uponor Suomi Oy | Compression connection between pipes |
ES2179444T3 (en) * | 1998-06-11 | 2003-01-16 | Sica Spa | APPLIANCE WITH MULTIPLE OPERATING STAGES FOR MOLDING STABLE STAMPED BOCKS IN THE FINAL CONNECTIONS OF TUBE UNION MADE OF THERMOPLASTIC MATERIAL. |
FI20020107A0 (en) | 2002-01-21 | 2002-01-21 | Uponor Innovation Ab | R ÷ rstuds |
JP2005180662A (en) | 2003-12-22 | 2005-07-07 | Honda Motor Co Ltd | Quick connector with resin tube |
EP1741968A1 (en) | 2005-07-08 | 2007-01-10 | Uponor Innovation Ab | Clamping ring |
FI119657B (en) * | 2006-08-25 | 2009-01-30 | Uponor Innovation Ab | Method and arrangement for connecting a pipe to a joint and a pipe joint |
CA2691616C (en) | 2007-07-02 | 2014-05-13 | Uponor Innovation Ab | Method of forming a clamping ring and a clamping ring |
US8146225B2 (en) | 2007-12-14 | 2012-04-03 | Uponor Innovation Ab | Method of forming a clamping ring and a clamping ring |
EP2481966A1 (en) | 2011-02-01 | 2012-08-01 | Uponor Innovation AB | Clamping ring |
US11541581B2 (en) | 2016-09-02 | 2023-01-03 | Zurn Industries, Llc | Injection molded cold-expansion compression collar |
US11543065B2 (en) | 2016-09-02 | 2023-01-03 | Zurn Industries, Llc | Extruded cold-expansion compression collar |
US11054076B2 (en) | 2016-11-04 | 2021-07-06 | Zurn Industries, Llc | Reinforcing ring with sleeve |
CN107696390B (en) | 2017-11-01 | 2019-07-12 | 乐清市东博机电有限公司 | A kind of method manufacturing clamping ring and its manufacture the equipment of clamping ring, injection molding machine |
FR3114860B1 (en) | 2020-10-05 | 2022-08-19 | Stelia Aerospace | Aircraft fluid line comprising a thermoplastic pipe and a connector |
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SE390802B (en) * | 1973-11-27 | 1977-01-24 | Atomenergi Ab | PROCEDURE FOR ASSEMBLING DETAILS OF WORKED POLYMERS |
EP0102919A3 (en) * | 1982-08-30 | 1985-05-22 | HUBER & SUHNER AG KABEL-, KAUTSCHUK-, KUNSTSTOFF-WERKE | Method of connecting tubes, and connection manufactured according thereto |
FR2555283B1 (en) * | 1983-11-22 | 1986-08-22 | Gresle Paul | TUBE CONNECTION SYSTEM |
DE3817442C2 (en) * | 1988-05-21 | 1994-02-03 | Platzer Schwedenbau Gmbh | Clampless pipe connection |
-
1991
- 1991-08-31 AT AT91114686T patent/ATE129795T1/en not_active IP Right Cessation
- 1991-08-31 EP EP91114686A patent/EP0530387B2/en not_active Expired - Lifetime
- 1991-08-31 DK DK91114686T patent/DK0530387T4/en active
- 1991-08-31 ES ES91114686T patent/ES2081406T5/en not_active Expired - Lifetime
- 1991-08-31 DE DE59106833T patent/DE59106833D1/en not_active Expired - Lifetime
-
1992
- 1992-08-21 HU HU9400390A patent/HU215296B/en not_active IP Right Cessation
- 1992-08-21 SK SK215-94A patent/SK282175B6/en unknown
- 1992-08-21 AU AU24401/92A patent/AU669665B2/en not_active Ceased
- 1992-08-21 KR KR1019940700632A patent/KR100250347B1/en not_active IP Right Cessation
- 1992-08-21 PL PL92302308A patent/PL170053B1/en unknown
- 1992-08-21 JP JP50488693A patent/JP3223977B2/en not_active Expired - Fee Related
- 1992-08-21 CZ CZ1994322A patent/CZ286291B6/en not_active IP Right Cessation
- 1992-08-21 CA CA002116561A patent/CA2116561A1/en not_active Abandoned
- 1992-08-21 WO PCT/EP1992/001923 patent/WO1993005332A1/en active IP Right Grant
- 1992-08-26 IL IL10295892A patent/IL102958A/en active IP Right Review Request
- 1992-08-28 NZ NZ24413492A patent/NZ244134A/en unknown
- 1992-08-28 PT PT100823A patent/PT100823B/en active IP Right Grant
- 1992-08-31 ZA ZA926585A patent/ZA926585B/en unknown
- 1992-08-31 TR TR00831/92A patent/TR27381A/en unknown
-
1994
- 1994-02-24 FI FI940864A patent/FI940864A0/en unknown
- 1994-02-25 NO NO19940672A patent/NO311952B1/en not_active IP Right Cessation
-
1995
- 1995-11-30 GR GR950403393T patent/GR3018275T3/en unknown
-
1996
- 1996-06-06 HK HK100096A patent/HK100096A/en not_active IP Right Cessation
-
1999
- 1999-12-20 GR GR990403283T patent/GR3032196T3/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2486952B (en) * | 2010-12-14 | 2016-04-06 | Mercury Plastics Inc | Method for making a reservoir |
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