CA2010042A1 - Conversion of pulp and paper mill waste solids to papermaking pulp - Google Patents

Abstract

Abstract A process for the production of papermaking fiber or pulp from waste solids emanating from pulp and paper mills, particularly waste solids in process water streams containing fibrous solids that cannot be directly recycled by paper mill "saveall" devices, from pulp and paper mill process water streams conveyed by the sewerage system to wastewater treatment plant facilities, and from "sludge" emanating from the underflow of a primary clarifier or sedimentation basin at pulp and paper mill wastewater treatment facilities either before or after the "sludge" is thickened and dewatered. The said process comprises a defibering stage to release individual fibers from bundles, a screening stage to separate long fiber and debris from short fiber and clay, a centrifugal cleaning stage to separate debris from the long fiber, a bleaching stage to increase the brightness of the fiber, a dewatering stage to remove excess water from the pulp, a clarification stage to separate the short fiber-clay-debris from the defibering effluent which is substantially recycled, and a biological treatment process to remove dissolved organic materials from the excess water generated which can be either discharged from the process or recycled as process water. The said process produces a papermaking fiber or pulp from waste pulp and paper mill waste solids that is substantially the same quality as the papermaking fiber or pulp used by the pulp and paper mill producing the waste solids.

Description

CONVERSION O~ PULP AND PAPER MILL
WASTE SOLIDS TO PAPERMAKING PULP
Back round of the Invention This invention relates to a process converting pulp and paper mill waste solids into a papermaking fibrous pulp of substantially the same quality as used by the pulp and paper mill to make its paper products~
State of the Art The manufacture of paper involves the blending of pulp ~mainly wood fiber) with clay filler, retention aids such as alum, and other chemicals as deemed desirable, and running the slurry on a paper machine to form a sheet that is dewatered and dried.
In this process, fiber and filler escape. Many mills employ "saveall" devices including polydisc filters, gravity drum filters, vacuum filters, dissolved air flotation cells, and sedimentation basins that capture to some degree the fiber and filler. These solids are then directly recycled.
Despite the presence of "saveall~ devices in the paper mill, discharge of fiber and clay from the paper machine area is unavoidable due to leaks, mistakes in operation, or dumping of batches to make grade or color changes on a paper machine. These solids are discharged as a slurry to the sewerage system of the paper mill. The paper mill sewerage system can either discharge to the sewerage system of a municipality or terminate at the paper mill's own wastewater treatment facilities.
In a paper mill wastewater treatment facility, the wastewater would first enter a sedimentation basin or clarifier (called the prirnary sedimentation basin or clarifier) or in some instances a dissolved air flotation device that captures suspended material (substantially fiber and clay contaminated with random debris) with or without the aid of coagulants or flocculants. The suspended material then forms a concentrated slurry containing normally 1~ to 5~ solids. This slurry or "sludge" is then pumped to a gravity thickener (if required to further concentrate the suspension) and then to a dewatering device (most normally a belt filter press, vacuum filter, or screw press) tha increases sludge solids content normally in the range of 20% to 50~O
Many wastewater treatment facilites also have an aerobic biological treatment process such as the activated sludge process that generates a biological sludge upon further treatment of the wastewater to remove dissolved biodegradable organic materials called BOD.
Mills that make both pulp from wood and paper from the pulp produced (called in~egrated facilities) will have wastewater containing waste solids from the pulp mill. The pulp mill wastewater may or may not be segregated from the paper mill wastewater. If not, pulp mill solids will be present in the sludge from the primary clarifier.
Therefore differentiation is made between paper mill sludge solids, pulp mill sludge ~olids, and biological treatment sludge solids. The invention herein described is most useful in relationship to paper mill sludge solids but will also apply to pulp mill sludge solids that contain appreciable quantities of wood filler. It is advantageous to not mix biological treatment plant sludge solids and non-fibrous pulp mill sludge solids with the pulp and paper mill wastewater fibrous solids. If paper mill, pulp mill, and biological solids are mixed together,the process described by this invention will be a~

successfully applied but the expense and difficulty of processing wlll be greater than if biological sludge solids and non-fibrous pulp solids were not incorprated with the pulp and paper mill fibrous sludge solids~
The main component o paper mill waste solids are wood fiber and clay contaminated with amounts of random debris. The type of fiber contained in the waste solids is substantially the same as the fiber contained in the pulp used by the mill to make its paper products. However, the waste solids fiber will be inf-erior compared to the papermaking pulp fiber with respect to fiber length, strength and other physical properties. This fact, along with a high percentage of clay and random debris contained in the waste solids in comparison to the papermaking fiber, makes the waste solids not suitable to be directly recycled.
Furthermore, the fiber may contain dyes that make it unsuitable for making certain grades of paper.
Specifically~ the sludge fiber contains more fiber fines and clay than the pulp used to make paper. Nevertheless the sludge will contain a substantial portion of long fiber that will be of a quality substantially the same as the fiber used by the mill to make paper provided it can be separated from the fiber fines! clay and other debris contained in the sludge.
In this regard it should be mentioned that fiber emanating from a mill that uses primarily virgin pulps to make paper will likely have a higher % of long fiber in its sludge solids compared to a mill that uses waste paper as its primary source of raw pulp. Waste paper also contains appreciable amounts of clay filler or coating pigments that invariably end up in the wastewater emanating from a paper millO

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Paper mills usually dispose of their sludge in a landfill where they must pay the cost o~
transportation of the sludge to the land fill and are charged a disposal or tipping fee. Some paper mills dispose of the sludge by landspreading where they must pay the cost of transportation to the landspread site, pay a user fee or purchase land, and spread the material A few pulp and paper mills incinerate sludge in dedicated facilities or include it in fuel for existing power boilers. However, the capital cost for dedicated facilities are high and the fuel value of many sludges is low due to high ash and water contents and low heating value of the fiber itself. The steam generated by power boilers has a low intrinsic value.
Others have suggested that the sludge be converted into useful by-products. Conversion of paper mill sludges into valuable by-products is taught, for example, by UOS~ Patent 4,481,072 where paper mill sludge is treated with alkali then dewatered. The filtrate issused to prepare white liquor in the Kraft pulping process and the solids added to furnishes used in the manufacture of paperboard and fiberboard.
U~S. Patent 3,876,497 teaches a process of wet oxidation of a sludge to generate energy and reoover a clay product useful as a paper making filler.
UOS. Patent 4,356,060 teaches a method of heating the sludge to evaporate water and convert to granules. The granules are then milled and forced through a screen. The product can be used as insulating material or filler in pipe insulation, roofing material, or similar products~
U~S. Patent 4,221,751 teaches a method of molding an article such as a pallet frorn paper mill sludge.

U.S~ Patent 4~285,842 teaches a method for producing a fibrous fire protection agent from sludge.
U.Sq Patents 3,907,728 and 3,909,470 teach a method of making plywood adhesives extended with paper mill fines~
The invention described differs in that it teaches a method of separation of high quality fiber from paper mill sludge and the cleaning and bleaching of tha fiber such that it can be directly recycled.
Therefore, though all the above inventions relate to conversion of paper mill sludge to useful by-products, none are directed at direct conversion of sludge solids into a pulp that can be directly recycled or alternatively used by another paper mill that uses a similar quality pulp to make its paper products.
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It is the object of this invention to provide an efficient and economical method for the separation of the long fiber pulp fraction contained in pulp and paper mill waste solids from other waste solids and conversion of the long fiber pulp fraction into a pulp that can be uti].ized directly by the paper mill generating the waste solids to make paper products, or utilized by some other paper mill that uses a pulp to make paper products similar to the mill generating the waste solids.
It is a further object of the invention to process waste pulp and paper mill solids in a manner to eliminate to the highest practical extent the pumping of water by use of gravity flow whenever possible~
It is still a further object of the invention to process the waste paper mill solids in a manner where excess water emanating from particular unit operations within the process invention, flow countercurrently to the processing of waste paper mill solids in order to reuse process water to the hiyhest practical extent. There is provided a biological treatment process in a particular mode of operation that processes the total excess water from the process invention to remove biodegradable organic material to make the excess water safe for discharge to the aquatic environment or to be further recycled as process water. If the effluent is further recycled as process water, the present invention will either have no discharge of excess water to the aquatic environment or a very small discharge with the amount of discharge dependent on the waste content of the incoming waste solids to the process invention.
In accordance with the present invention, the waste paper mill solids are carried into the process as a very dilute slurry as in a wastewater discharge, or as a concentrated slurry or "sludge" as emanates from the under~low of a sedimentation basin or clarifier or the ~loat from a dissolved air flotation unit, or as a dewatered material as produced by a clewatering device as a belt press, screw press, vacuum filter, polydisc vacuum filter, or gravity drum filter.
The first processing step ~ould be to defiber the waste solids which releases individual fibers from fiber bundles. This processing step is essential when a dewatered sludge is handled. This processing step may or may not be necessary when a sludge is handled from the underflow of a sedimentation basin or clarifier or dissolved air flotation unit. This processing step is normally not necessary when handling a wastewater. The defibered waste solids are then processed by a vibrating screen that separates the long fiber (plus large debris) that is retained on ths screen from the short fiber and clay that passes throuyh the screen. The short fiber and clay is then concentrated by a sedimentation (or flotation) process after addition of coagulants and flocculants to aid in the sedimentation (or flotation) process. The thickened short fiber-clay-debris slurry is then dewatered on a belt press, screw press, or vacuum filter.
The long fiber fraction is cleaned of debris using centrifugal cleaners known as hydrocyclones. The rejected debris is added to the short fiber-clay fraction. The cleaned long fiber is then dewatered on a vibrating screen and sent to a bleach tank where bleaching chemicals and steam are added to aid in the bleaching process. This processing step is necessary to remove color from the long fiber and to increase its brightnessO The bleached pulp is then set to a dewatering device to remove water ~or ease in transportation. Alternatively, the pulp can be directly recycled in slurry form.
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The invention is illustrated in the accompanying drawing wherein:
FIG. 1 is a flow diagram of a particular mode of operation of the pulp and paper mill sludge conversion process of the present invention; and, FIG. 2 is a flow diagram of an alternate mode of operation, including variation therein, representing the process of the present invention in its most basic form.
Detailed Descr_ption of the Invention Referring now to the drawing in detail, raw paper mill sludge is introduced by means of line 11 into a defibering tank 12 equipped with a mixing device tha will disperse the fibersO Dilution water is added (if necessary) via line 14 from clarifier effluent collection basin 16 motivated by pump lSo The 4~

consistency of the sludge in the defibering tank would normally be in the range of 2 to 5% solids if the raw sludge is obtained from the underflow of a primary clarifier. If dewatered raw sludge is added where the pulp consistency is normally above 20% solids, dilution water can be added to lower the consistency.
The advantage in defibering at a high consistency is to reduce energy consumption and the size of the defibering vessel. The purpose of the defibering stage is to release individual pulp fibers from bundles. This process is aided by the addition of detergent chemicals via line 13~ Laundry detergents, sodium hydroxide, sodium oleate, and sodium silicate are chemicals that can be added to aid in defibering.
The pulp slurry is carried by line 17 onto vibrating screen 18. The purpose of the vibrating screen is to separate the long fiber (plus large debris) from the short fiber (fiber fines) and clay.
The vibrating screen contains a screen with mesh size in the range of 10 to 400 mesh~ The selection of screen mesh size depends on the amount of short fiber it is desirable to include in the pulp. The smaller the screen openings, the more short fiber and clay will be retained and the less the hydraulic loading can be exerted per sguare foot of screen surface area. Other screening devices such as a "sidehill" screen may be substituted for a vibrating screen.
The fiber retained on the screen is washed by water carried by line 20 from the clarifier water storage tank 16 motivated by pump 19. The water is applied onto the vibrating screen by nozzles mounted on top of the screen. This method reduces the amount of water applied to the vibrating screen. Alternatively, the wash water can be added directly to the concentrated pulp slurry carried by line 17 and then applied to vibrating screen 18.

The vibrating screen 18 underflow, containi.ng primarily short fiber and clay, is carried via line 21 to the collection basin 22 equipped with a mixing device~ A coagulant is added via line 23 to collection basin 22 to allow the short fiber and clay to form a settleable mass o solidsO
Additional water streams enter collection basin 22. One stream is carried via line 24 from collection basin 53 and is the overflow from that basin. Another stream is carried via line 25 from tertiary hydrocyclone 65 and contains rejects from that device. The rejects are mainly fiber and high specific gravity debris. This material aids in the settling and dewatering of the short fiber and clay suspension formed in collection basin 23. Another stream is carried via ].ine 26 from dewatering device 40 and is the water removed when the short fiber-clay-debris sludge is dewatered.
The flow is then carried via line 27 to clarifier or sedimentation basin 29. Flocculants are injected into line 27 via line 28 to allow the short fiber-clay-debris suspension to reach particle sizes large enough to allow the material to settle at a rapid rate. The short fiber-clay-debris mixture settles to the bottom of the clarifier and the clarified effluent, substantially free of short fiber-clay-debris then is carried by line 30 to the clarified water storage basin 16. The clarified wa~er is then recycled to the defibering tank 12 and vibrating screen 18. In this manner, the water used in defibering is substantially recycled.
Excess water, overflows from clarified water co].lection basin 16 via line 31 to an aerobic biological treatment process 32. There the excess water is treated to remove dissolved organic materials _9_ generating a biological sludge. Air is added via line 33 to supply oxygen for respiration of the biological organisms.
The biological sludge is separated from the treated effluent via gravity sedimentation within the biological treatment process 320 The treated ef1uent is carried from biological process 32 via line 34. The treated effluent is substantilly free of oxygen demanding organic substances and suspended materialsO
It is therefore normally safe to discharge to an aquatic environment. Alternatively, the overflow from collection basin 16 can be discharged directly to a sewer via line 35 where it can be treated in wastewater treatment facilities at the paper mill or in municipal facilities or other facilities as provided.
The excess biological sludge is carried via line 36 motivated by pump 37 into a sludge dewatering device 40, preferably a belt press or screw press or vacuum filter. There it is mixed with the short fiber-clay debris sludge carried via line 38 motivated by pump 39 from clarifier 29. Dewatered sludge is carried via line 41 from dewatering device 40. This material can be disposed of by landfill or landspread or composted or possibly incinerated. Excess water is carried via line 26 back to cllection basin 22.
The processing up ~o this point has the purpose of removing short fiber and clay from the long fiber in paper mill sludge. The long fiber is carried via line 42 from vibrating screen 18 to mixing tank 43 equipped with a mixing device~ The mixing intensity in mixing tank 43 is normally not as intense as in defibering tank 12 since the fiber enters in slurry form and has already been substantially defibered.
Two other streams enter primary mixing tank 43. One stream is carried via line 44 from secondary hydrocyclone 60 and represents the accepted fiber from that device. The second stream is carried via line 45 and comes from collection basin 53 which accepts the underflow from vibrating screen 51. These streams dilute the substantially dewatered long fiber suspension carried via line 42 from vibrating screen 18.
The contents of mixing tank 43 is carried via line 46 motivated by pump 47 into a primary hydrocyclone 48 which imparts a centrifugal force to the slurry causing debris of specific weight greater than that of water to be separated from the fiber. The slurry containing debris called "rejects" is carried via line 49 to a secondary mixing tank 57. The slurry containing fiber substantially removed of debris called "accepts" is carried via line 50 onto vibrating screen 51. Vibrating screen 51 substantially dewaters the fiber which is then carried via line 78 to bleach tank 67. Other screening devices such as a "sidehill' screen may be substituted for a vibrating screen.
The underflow from vibrating screen 51 is carried via line 52 to collection basin 53. Collection basin 53 also accepts the overflow carried via line 54 from collection basin 76. Flow from collection basin 53 flows via line 45 to primary mixing tank 43, via line 56 to secondary mixing tank 57, and via line 55 to tertiary mixing tank 62. The level of water in collection basin 53 is relatively constant with the excess overflowing via line 24 into collection basin 22. Whenever the level of water in mixing tanks 43, 57, or 62 drops, the flow of water via lines 45~ 56, and 55 respectively from collection basin 53 will increase due to he difference in hydrostatic pressure. This will halt a further decrease in water level causin~ the system to reach a state of hydrostatic equilibrium.

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The rejects from primary hydrocyclone 48 is carried via line 49 to secondary mixing tank 57. Two other s~reams enter secondary mixing tank 57. One stream is carried via line 56 from collection basin 53~ The other stream is accepted fiber from tertiary hydrocyclone 65 carried via line 66. The contents of secondary mixing tank 57 is carried via line 58 motivated by pump 59 into secondary hydrocyclone 60.
The accepted slurry is then carried via line 44 to primary mixing tank 43. The reject slurry is then carried via line 61 to tertiary mixing tank 62.
Tertiary mixing tank 62 has another stream entering via line 55 from collection basin 53. The contents of tertiary mixing tank 62 is carried via line 63 motivated by pump 64 into tertiary hydrocyclone 65. The accepted slurry then i5 carried via line 66 to secondary mixing tank 57. The rejected slurry is carried via line 25 to collection basin 22.
In this manner a high percentage of fiber can be cleaned of debris with the debris concentrated in a tertiary re~ect stream. Less stages of hydrocyclone cleaning will result in more fiber being carried in the reject stream to collection basin 22. More stages will result in less fiber being carried in the final reject stream.
The pulp retained by vibrating screen Sl is carried via line 78 to bleaching tank 67 where bleaching chemicals are added via line 68. Effective bleaching chemicals include sodium hypochlorite and hydrogen peroxide at dosages in the range of 0.01 to 0.1 gram of active bleach chemical per gram of fiber.
It is desirable to bleach under alkaline conditions with pH in the range of 9.0 to 11.5 and at a temperature in the range of 20-90 degrees C. The temperature of the bleach tank 67 is raised to the ~esired operating tempera~ure by means of injection of steam via line 77. These conditions increase effectiveness of the bleach chemicals and decrease the bleach tank holding time to achieve a given degree of pulp brightness.
A mixer is provided in bleaching tank 67 to disperse the bleaching chemicals. The slurry is then carried via line 69 motivated by pump 70 to a dewatering device 71 that can be a lap pulp machine or belt press or other device that removes water from pulp without damaging the integrity of the pulp fibers.
Fresh water is added via line 72 to provide a final rinse of the pulp in the drainage section of the belt press prior to the press section, The dewatered pulp then exits the machine via line 73. In lieu of fresh water, biologically treated effluent via line 34 can be pumped to dewatering device 71. In this manner, the process flow scheme discharges little or no wastewater e-ffluent.
The water removed from the dewatering device is carried via line 74 to a collection basin 76 that is connected via line 75 to the bleaching tank 67. Excess water overflows from collection basin 76 via line 54 to collection basin 53.
A significant feature of this process invention is the countercurrent flow of process water in relation to the flow of pulp. Relatively clean excess water flows from the bleach stage to the hydrocyclone stage then from the hydrocyclone stage to the defibering stageO This feature substantially reduces fresh water consumption. Eventually water leaves the process via the biological process effluent. The biological effluent, however, can be substituted for fresh water allowing further reduction in the consumption of fresh ~ater.

~14-Another significant feature of this process invention is the judicious use of gravity flow to substantially reduce the necessity to pump process waterO The lines where pumps are needed are clearly shown.
The flow relationship from the vibrating screen 18 to collection basin 22 to clarifier 29 to collection basin 16 is by gravity. Water is pumped from collection basin 16 to defibering tank 12 with the overflow flowing by gravity to biological process 32.
The flow relationships of collection basin 53 are particularly unique~ The underflow from vibrating screen 51 flows by gravity to collection basin 53.
Water flows by gravity to primary mixing tank 43, secondary mixing tank 57, tertiary mixing tank 62 with the overflow going to collection basin 22. This arrangement eliminates the need for several pumps~
Collection basin 76 water flows by gravity to bleach tank 67 with the overflow flowing by gravity to collection basin 53.

Considering now a specific example, dewatered paper mill sludge was obtained off of the belt press of a non-integrated fine paper mill using an approximately equal mixture by weight of hardwood and soft~ood bleached Kraft virgin pulps with a small percentage of secondary fiber added. The sludge was defibered at 4.75% consistency with no detergent added and was screened on a vibrating screen containing a 200 mesh screen with 57.2% of the fiber retained on the screen. Hydrocycloning was performed at 0.7~
consistency with the accepts screened on a vibrating screen containing a 200 mesh screen. Bleaching was performed at 70 degrees C using sodium hypochlorite at a dosage of 0.025 g/g fiber at a pH of lO.S. Handsheet samples of as received sludge (AR) and processed sludge (PS) were then prepared according to standard procedures and the paper properties measured. These properties were compared to handsheets prepared of hardwood bleached Kraft (HWBK) and softwood bleached Kraft (SWBK) pulp. The results are given below:
HWBK SWBK PS AR
Ash ~ 0.16%0.16~ 0.40% 8.1%
Bauer-McNett (~ retained on) 28 rlesh 1.1%60.4% 38.0~ 18.3 48 ~Sesh 50~5% 28.13 37.1% 23.4%
100 Mesh 22.6%5.1% 9.7~ 7.3%
200 Mesh 9.3%300~ 508% 6.4 Thru 200 16.5%3.4% 9.4% 44.6 Freeness tCSF)740 790 710 400 Brightness 84 80 77 47 Burst (psi~ 6.5 20.1 19.8 10.8 Tear (g) 10.6 42.8 12.4 6.1 Tensile (lb/in) 7.5 11.3 14.0 8.7 Stretch (%) 1.052.62 2.32 1.47 TEA (kg/m2) 1.014.22 4.30 1.68 ET (lb/in) 1441 1562 1960 1397 The processing substantially impro~ed all of the paper properties tested compared to as received paper mill sludge. Furthermore, the paper properties of the processed sludge were as a rule between that of a hardwood and softwood Kraft pulp as indicated in the Table. Exceptions were that the brightness was somewhat inferior and the tensile, TEA and ET superior.
Although the invention has been described specifically with respect to the recovery of a long fiber pulp with respect to paper mill wastewater - 1 s~ 2 treatment plant sludge collected by the primary clarifier at the wastewater treatment plant, it will be appreciated that the present invention is applicable to paper mill sludge that has already been dewatered or to the wastewater itself prior to entering the primary clarifier. If dewatered sludge is used in the process, the mixing energy in the defibering tank will be higher and the time needed to defiber longer. If wastewater is used, defibering is unnecessary, and the wastewater can be sent directly to the vibrating screen 18.
The invention would also apply to process water streams in the pulp or paper mill that are normally sewered because the solids are not suitab~e for direct recycle if captured in "saveall" devices~
In this regard, the solids captured by a "saveall"
device within the pulp or paper mill can be processed by means of the process invention described to make them suitable for direct recycle.
Referring now to Fig. ~, there is shown a floor diagram including the most basic elements of the process of the present invention and including variations in the basic process. In this regard, it has been shown that certain process steps may be performed in slightly different order, the countercurrent e~fluent flow recycled somewhat differe-ntly, and certain steps even eliminated or modified, dependin~ primarily on the nature of the waste solids introduced to the process~ As indicated previously, the process will accept and suitably treat waste solids directly ~rom primary clarification at the mill (i.e. primary sludge which has not been dewatered), dewatered primary sludge, or even wastewater directly from the mill without any primary treatment. In addition, if the mill waste treatment plant includes a biological process, the biological -17- ~ 3~

sludga will ordinarily be combined with the primary sludge from the clarifier and such a combined sludge may also be utilized in the process of the present invention.
As previously described with respect to the Fig~ 1 embodiment of the process, waste solids may be introduced into the Fig. 2 process via line 11 to the defibering tank 12. Defibering is particularly important if the waste solids comprise dewatered sludge. It has also been found that defibering is enhanced at elevated temperatures and, therefore, steam may be admitted directly into the defibering tank via line 80. However, the waste solids may also be introduced into the process in a substantially dsfibered state and, in such cases, the defibering tank 12 may be eliminated, as when utilizing primary sludge which has not been dewatered.
In the process of Fig. 2, first vibrating screen 18 has been eliminated and the waste solid slurry is directed via line 17 (or via line lla if sufficiently defibered) to a grit chamber 79. The grit chamber may be utilized to provide a gross separation of lar~e heavy materials and may also provide for the flotation separation of large lighter materials. It is possible, however, to also eliminate grit chamber 79 and direct the incoming waste solid slurry directly to mixing tank 43 via line llb, if prior to entry into the process, the waste solids have been subjected to a basic separation process to re~ove large and/or heavy debris. Detergents or chelating agents may be added to the mixing tank via line 13a, particularly iE no specific prior defibering step has been employed. The mixing tank also receives the overflow from collection basin 76 via line 54, as will be described in more detail. The waste solids proceed from the mixing tank via line 46 and pump 47 to the hydrocyclone system 48 where the random debris is separated from the slurry and the rejected debris is directed via line 49 to the collection basin 22.
The accepts from the hydrocyclone system, comprising long fibers, fiber fines and clay, flows via line 50 to the vibrating screen 51. The long fibers are retained on the screen 51 and the underflow comprising the fiber fines and clay is directed via line 52 to the collection basin 22. The fiber retained on screen may be washed with overflow effluent from the collection basin 76 via line 54a.
The processing of the long fiber retained on the vibrating screen 51 is thereafter identical to the process described and shown in Fig. 1. Thus, the long fibers are bleached in bleach tank 67 with the addition of bleaching chemicals 68 and, preferably, at an elevated temperature supplied by steam via line 77.
The bleached long fiber slurry is carried via line 69 and pump 70 to a suitable dewatering device 71 where the pulp fiber is simultaneously washed with fresh water via line 72 or recycled treatecl effluent from the biological process 32 via line 34. The effluent from the dewatering and washing device 71 flows via line 74 to collection basin 76 where it is recycled via line 75 to the bleach ~ank 67. The excess effluent o~ over10w from collection basin 76 provides a countercurrent gravity flow which is recycled back to the process upstream of the vibrating screen 51. Specifically, the flow may be directed back to the mixing tank 43 and/or to provide wash water for the vibrating screen 510 The secondary and tertiary treatment steps in the process shown in Fig. 1 have been eliminated in the Fig. 2 process. Thus, the Fig. 2 process also eliminates collection basin 53. It is understood, - 2 ID~
however, that the basic modifications shown and described with respect to Fig. 2 may include secondary and tertiary processing, if desired.
The rejected debris from hydrocyclone system 48 and the fiber fines and clay from vibrating screen 51 are directed via lines 49 and 52, respectively, to the collection basin 22 in a manner similar to that described with respect to the Fig. 1 embodiment. These combined effluents are clarified in essentially the same manner in clarifier 29 with the clarified effluent flowing via line 30 to collection basin 16. From collection basic 16 the clarified effluent may be pumped back into the process at any convenient point upstream of the hydrocyclone system 48, depending on which o the optional pre-cyclone steps are utilizedL
The overflow from the collection basin 16 flows via line 31 to the biological process 32 (with an alternate discharge via line 35 to the sewer).
Also consistent with the Fig 1 embodiment, the sludge from the clarifier 29, comprising principally fiber fines and clay, is pumped via line 38 to the dewatering device 40. The biological sludge from the process 32 is also directed to the dewatering device 40 from which a dewatered sludge comprising short fibers, clay, debris and biological sludge is obtained.
The excess water from the dewatering device 40 may be recycled via line 26 to the collection basin 22 as shown and described with respect to the Fig. 1 embodiment. However, clay and short fiber fines in the sludge from the clarifier 29 are particularly difficult to dewater and, as a res~lt, the excess water from the dewatering device 40 often contains a fairly heavy concentration of clay and fiber fines. Recycling the excess water via line 26 to the clarifier 29 may impose an undesirable heavy loading on the clarifier, as well as an increasing concentration of clay and fines in the clarified effluent passed to collection basin 16.
Therefore, in a modified process step, the excess water from the dewatering device 40 is recycled via line 81 directly to the biological process 32. The biological process has been found to be particularly effective in removing clay and fines where the biological sludge will adsorb or enmesh the suspended clay and fiber fines which, when transferred as a part of the biological sludge to the dewatering device via line 36, will be readily removed as a part of the dewatered sludgeO Although the same fiber fines and clay in the excess water ~ight be considered to be theoretically subject to the same biological process treatment due to their inclusion in the overflow from collection basin 16 in line 31, such indirect removal does not alleviate any possible excess loading on the clarifier and concentration of clay and fines in the clarified effluent which may be recycled back to the process.
Thus, the direc~ biological treatment of the excess water effluent from the dewatering device 40 provides a substantial enhancement to the overall process. The excess water from the dewatering device 40 may optionally be recycled to the collection basin via line 26~ This optional flow path may be particulary useful where the waste solids being treated in the process have a particularly low level of clay and fines.
However, direct recycling via line 81 to the biological process has been found to work particularly well.

Various modes of carrying out the present invention are contemplated as being within the scope o~
the following claims particularly pointing out and distinctly claimin~ the subject matter which is regarded as the invention.

Claims (12)

1. A continuous process for converting waste solids including long fibers, fiber fines, clay and random debris from pulp and paper mill waste water into a papermaking fiber or pulp that is substantially the same quality as the papermaking fiber or pulp used by the pulp and paper mill producing the waste solids, which process comprises the steps of:
(a) introducing into the process waste solids which are defibered to release individual fibers from fiber bundles;
(b) removing the random debris from the waste solids using a centrifugal cleaner;
(c) screening the waste solids to separate the long fibers from the fiber fines and clay;
(d) bleaching the long fibers with the addition of bleaching chemicals;
(e) washing and dewatering the bleached long fibers;
(f) separating the random debris removed in step (b) and the fiber fines and clay separated in step (c) from the water effluent by a clarification process;
(g) recycling the clarified water effluent in step (f) to the process upstream of step (e) (h) recycling the water effluent in step (e) to step (d);
(i) recycling the excess water effluent in step (e) to the process upstream of step (c);
(j) biologically treating the excess water effluent from step (f) and discharging the treated excess water effluent from the process or recycling to step (e); and, (k) dewatering the debris-fiber fines-clay biological sludge generated in steps (f) and (j).

2. The process according to claim 1 including the additional step of recycling directly the excess water effluent in step (k) to step (j).

3. A continuous process for converting waste solids including long fibers, fiber finest clay and random debris from pulp and paper mill waste water into a papermaking fiber or pulp that is substantially the same quality as the papermaking fiber or pulp used by the pulp and paper mill producing the waste solids, which process comprises the steps of:
(a) introducing into the process waste solids which are defibered to release individual fibers from fiber bundles;
(b) centrifugally cleaning the waste solids to remove the random debris;
(c) screening the waste solids to separate the long fibers from the fiber fines and clay;
(d) bleaching the long fibers with the addition of bleaching chemicals;
(e) washing and dewatering the bleached long fibers;
(f) recycling at least a portion of the water effluents in steps (b), (c) and (e) to an upstream process step;
(g) separating the random debris, fiber fines and clay from the excess water effluent in steps (b), (c) and (e) by a clarification process;
(h) removing dissolved organics and suspended clay and fiber fines from the effluent and sludge generated in step (g) in a biological process; and, (i) dewatering the combined sludge generated in steps (g) and (h).

4. The process according to claim 3 including the step of recycling the treated water effluent in step (h) to step (e).

5. A continuous process for converting waste solids including long fibers, fiber fines, clay and random debris from pulp and paper mill wastewater into a papermaking fiber or pulp that is substantially the same quality as the papermaking fiber or pulp used by the pulp and paper mill producing the waste solids, which process comprises:
(a) defibering the waste solids in a slurry by mechanical means with chemicals added if necessary to assist in the release of individual fibers from fiber bundles;
(b) screening the defibered waste solids on a vibrating screen or other screening device to separate the long fiber from the fiber fines and clay;
(c) cleaning the long fibers of random debris using a centrifugal cleaner;
(d) bleaching the long fibers to increase brightness at elevated temperatures with the addition of bleaching chemicals;
(e) dewatering the long fiber pulp to make it suitable for transportation;
(f) separating fiber fines and clay in step (b) and rejected debris in step (c) from the water effluent using a coagulation process followed by a clarification process;
(g) recycling of the clarified water effluent in step (f) back to step (a);
(h) biologically treating the excess clarified water effluent step (f) and discharging the treated excess water effluent from the process or recycling to step (e) as pulp wash water;

(i) feeding the excess water effluent in step (c) to step (a);
(j) feeding the excess water effluent in step (d) to step (c); and, (k) dewatering the fiber fines-clay-debris-biological sludge generated in steps (E) and (h).

6. A process according to claim 5 wherein the waste solids are derived from a float of a dissolved air floatation unit located at the pulp and paper mill wastewater treatment plant.

7. A process according to claim 5 wherein the waste solids are derived from a thickening or dewatering device at the pulp and paper mill wastewater treatment plant.

8. A process according to claim 5 wherein the waste solids are derived from the wastewater emanating from the paper or pulp mill sewage system.

9. A process according to claim 5 wherein the waste solids are derived from a pulp or paper mill process water stream normally sewered.

10. A process according to claim 5 wherein the waste solids are derived from a pulp or paper mill "saveall" device and are not suitable! for direct recycle.

11. A process according to claim S wherein sodium hypochlorite bleach is used in step (d) at dosages of 0.01 to 0.1 g/g fiber under alkaline conditions at a temperature in the range of 20°C. to 90°C.

12. A process according to claim 5 wherein hydrogen peroxide bleach is used in step (d) at dosages of 0.01 to 0.1 g/g fiber under alkaline conditions at a temperature in the range of 20°C. to 90°C.