BR122024015000A2 - MIXTURE OF BEESWAX AND A LACTYLATE ESTER TO IMPROVE SUN PROTECTION OF COMPOSITIONS INCLUDING UV FILTERS, COMPOSITION, AND THEIR USES - Google Patents

Abstract

The present invention relates to a mixture for improving the sun protection of compositions comprising UV filters, the mixture consisting of: (a) beeswax; and (b) at least one lactylate ester.

Description

AREA OF INVENTION

[0001] The present invention relates to a composition comprising at least one UV filter, beeswax and at least one lactylate ester and to the use thereof.

BACKGROUND OF THE INVENTION

[0002] UV absorbers are compounds that have a pronounced absorption capacity for ultraviolet radiation. They are mainly used as sunscreens in cosmetic, dermatological and pharmacological preparations, but also to improve the light resistance of industrial products such as paints, varnishes, plastics, textiles, polymers such as, for example, polymers and copolymers of mono- and di-olefins, polystyrenes, polyurethanes, polyamides, polyesters, polyureas and polycarbonates, packaging materials and rubbers.

[0003] UV rays are classified according to their wavelength as UVA rays (320-400 nm, UVA-I: 340-400 nm, UVA-II: 320-340 nm) or UVB rays (280-320 nm). UV rays can cause acute and chronic damage to the skin, the type of damage depending on the wavelength of the radiation. For example, UVB radiation can cause sunburn (erythema) extending to more severe skin burns. Other harmful effects of UVB rays include reduction in enzyme activities, weakening of the immune system, disturbances in DNA structure and changes in the cell membrane. UVA rays penetrate into the deeper layers of the skin where they can accelerate the skin aging process. The shorter-wave UVA-II radiation contributes to the development of sunburn. In addition, UVA radiation can trigger phototoxic or photoallergic reactions in the skin. Frequent and unprotected irradiation of the skin by sunlight leads to a loss of skin elasticity and to an increased development of wrinkles and, in extreme cases, pathological changes in the skin extending to skin cancer are observed. To mitigate these negative effects of UV radiation, materials that absorb or reflect UV light, generally called UV absorbers, are used in cosmetic, dermatological and pharmacological preparations. UV absorbers are classified as UVA and UVB absorbers depending on the site of their maximum absorption; if a UV absorber absorbs both UVA and UVB, it is referred to as a broadband UVA/B absorber.

[0004] The degree of effectiveness of cosmetic, dermatological, and pharmacological compositions for protecting human skin from erythema that is caused by UV radiation is determined by their Sun Protection Factor (SPF), which is the ratio of the energy required to show the first definite redness (erythema) of protected human skin to the energy required to show the first definite redness of unprotected human skin. The amount of energy required for the first signs of erythema on Fitzpatrick Class 2 (light Caucasian) human skin is 200 J/m2, which is also known as the Minimum Erythemic Dose (MED). Natural sunlight at 40°N on a clear day will deliver this dose in about 10 minutes. Thus, a cosmetic, dermatological or pharmacological preparation for the treatment of human skin from erythema with an SPF of 50 will theoretically protect the skin from sunburn for 500 minutes. In addition to the SPF, most regulatory authorities also stipulate that formulations intended to protect human skin from erythema must also have sufficient absorption in the UVA range of the spectrum.

[0005] To obtain the desired cosmetic protection from UV radiation, dermatological and pharmacological compositions contain a mixture of UV filters with varying concentrations and the choice of UV filters used is determined by the legislation within the country or economic area. For example, UV filters that can be used for skin protection are regulated in the USA by the American FDA through its OTC monograph system and are regulated in the European Union by the Cosmetics Regulation. Regulations covering the use of UV filters exist in other countries and regions as well. These regulations not only stipulate the filters that can be used, but also set a maximum level of use for each UV filter.

[0006] To obtain the desired protection, large amounts of UV filters tend to be used in the formulations increasing the cost in use. Large amounts of UV filters in sunscreen formulations also tend to have an undesirable burden on the environment due to their persistence and lack of biodegradability. In addition, they release a suboptimal sensory appeal for use due to their stickiness and oiliness.

[0007] The phenomenon of increasing the photoprotection of a composition without increasing the amount of UV filters is called SPF enhancement. Some materials that have this SPF enhancement effect, so-called SPF boosters, have been described and tend to be polymeric or glass beads in nature. Examples are styrene/acrylate copolymers sold under the trade name Sunspheres® available from Dow Chemical or glass microspheres sold under the trade name Luxsil® available from Presperse, or Q-Cel 570 available from PQ Corporation, ScotchliteTMK20 from 3M. These synthetic microbeads are not readily biodegradable and remain persistent in the marine environment. Other polymeric examples are Cyclopentasiloxane, Acrylates/Dimethicone Copolymer sold under the trade name KP 545 available from Shin-Etsu Silicones, Dimethicone (and) Acrylates/Dimethicone Copolymer sold under the trade name KP 545L available from Shin-Etsu Silicones. Both of these last two examples are silicone polymers that are persistent in the environment.

PURPOSE OF THE INVENTION

[0008] Accordingly, it is an object of the present invention to provide a unique non-UV absorbent blend of readily biodegradable, non-polymeric ingredients derived from natural and sustainable sources to significantly reduce the amount of UV filters used in a composition to deliver the same protection as provided by a composition containing larger amounts of UV filters without the blend, while at the same time significantly providing the sensory appeal of the composition. Furthermore, the use of such a blend is expected to contribute to the water resistance of the formulation in that the UV filters in the formulation are retained on the skin after immersion in water and washing off. Another object of the invention is to provide an ingredient that can easily be incorporated into many types of cosmetic compositions such as creams, lotions, sprays, sticks and balms. Another object of the invention is for the blend to improve the film-forming properties of the composition so that the film that is formed when the composition is applied to a surface is more homogeneous.

BRIEF DESCRIPTION OF THE INVENTION

[0009] This object of the present invention is solved by a mixture for improving the sun protection of compositions comprising UV filters, the mixture consisting of (a) beeswax; and (b) at least one lactylate ester.

[0010] It has surprisingly been found that the mixture of the present invention is provided in its photoprotective properties. Furthermore, the mixture of the present invention is provided in its sensory attributes and water resistance. Furthermore, the mixture of the present invention shows improved properties with respect to its film-forming properties. This means that the film is formed when the composition that is applied to a surface is more homogeneous and can thus better and more uniformly protect the skin.

[0011] Another advantage of the blend of the present invention is that components (a) and (b), i.e. beeswax and at least one lactylate ester, are derived from natural and sustainable sources.

[0012] In a preferred embodiment according to the invention the at least one lactylate ester is selected from alkyl lactate salts wherein the alkyl chain comprises 8 to 22 carbon atoms. In a more preferred embodiment according to the invention the lactate ester is sodium stearoyl lactylate.

COMPOSITIONS

[0013] One embodiment of the present invention relates to a composition, particularly a cosmetic, dermatological or pharmaceutical composition, comprising the mixture consisting of (a) beeswax; and, (b) at least one lactylate ester. The composition comprising the mixture preferably in amounts of from about 0.5 to about 10 wt. %, preferably from about 1.0 to about 7.5 wt. %, more preferably from about 1.0 to about 5.0 wt. % and most preferably from about 1.0 to about 3.0 wt. % - calculated on the total composition. In a more preferred embodiment of the invention, the composition is a cosmetic composition.

[0014] The composition may represent, for example, a cosmetic cream, lotion, spray, emulsion, ointment, gel or mousse and the like. Typical examples are sunscreen products and facial moisturizers that also protect the skin against UV radiation. The preparations according to the invention may contain anti-dandruff agents, radiation prevention agents, radiation inhibition agents, antioxidants, astringents, perspiration inhibitors, antiseptic agents, antistatic agents, binders, buffers, carrier materials, chelating agents, cell stimulants, cleaning agents, personal care agents, deodorizing agents, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibers, film-forming agents, fixatives, foaming agents, foam stabilizers, foam-preventing substances, foam boosters, gelling agents, gel-forming agents, hair care agents, hair fixing agents, hair straightening agents, moisture-giving agents, moisturizing substances, moisture-retaining substances, bleaching agents, reinforcing agents, stain-removing agents, optical brightening agents, impregnating agents, dirt repellents, friction reducing agents, lubricants, moisturizing creams, ointments, opacifying agents, plasticizing agents, coating agents, polishes, shining agents, polymers, powders, proteins, relubricating agents, abrasive agents, silicones, hair promoting agents, cooling agents, skin cooling agents, warming agents, skin warming agents, stabilizers, UV absorbing agents, UV filters, detergents, thickeners, vitamins, oils, waxes, fats, phospholipids, saturated fatty acids, mono- or polyunsaturated fatty acids, α-hydroxy acids, polyhydroxy fatty acids, liquidifiers, dyes, color protecting agents, pigments, odorous substances, polyols, surfactants, electrolytes, organic solvents or silicone derivatives and the like as auxiliaries and additional additives.

[0015] In one embodiment according to the invention the composition exhibits a sun protection factor (SPF) of at least 2. Methods of measuring the SPF of a composition are well known in the art and are, for example, described in ISO 24444:2010. In another embodiment according to the invention the composition exhibits a UVA protection factor of at least 370 nm. This can be measured by the Critical Wavelength Method for in vitro determination of UVA protection. In another embodiment according to the invention the composition exhibits a ratio of UVA I absorbance to total UVB + UVA absorbance greater than or equal to 0.70, which is in accordance with the proposal submitted by the US FDA published under https://federalregister.goV/d/2019-03019. In another embodiment according to the invention, the composition exhibits a UVA protection factor of at least one third of the SPF, as measured by ISO 24443:2012 standard for in vitro determination of UVA protection.

SURFACTANTS

[0016] Preferred auxiliaries and additives are anionic and/or amphoteric or zwitterionic surfactants. Cationic and nonionic surfactants may also be present in the composition. Suitable examples are mentioned in conjunction with the paragraph dealing with emulsifiers.

[0017] Typical examples of anionic and zwtterionic surfactants include: Almondamidopropylamine oxide, Almondamidopropyl betaine, Aminopropyl laurylglutamine, C12-15 ammonium alkyl sulfate, C12-16 ammonium alkyl sulfate, Ammonium caprylic sulfate, Ammonium cocomonoglyceride sulfate, Ammonium coco-sulfate, Ammonium cocoyl isethionate, Ammonium cocoyl sarcosinate, C12-15 ammonium pareth sulfate, C9-10 ammonium perfluoroalkylsulfonate, Ammonium dinonyl sulfosuccinate, Ammonium dodecylbenzenesulfonate, Ammonium isostearate, Ammonium laureth-6 carboxylate, Ammonium laureth-8 carboxylate, Ammonium, Ammonium Laureth Sulfate, Ammonium Laureth-5 Sulfate, Ammonium Laureth-7 Sulfate, Ammonium Laureth-9 Sulfate, Ammonium Laureth-12 Sulfate, Ammonium Lauryl Sarcosinate, Ammonium Lauryl Sulfate, Ammonium Lauryl Sulfosuccinate, Ammonium Myreth Sulfate, Ammonium Myristyl Sulfate, Ammonium Nonoxynol-4 Sulfate, Ammonium Nonoxynol-30 Sulfate, Ammonium Oleate, Ammonium Palm Kernel Sulfate, Ammonium Stearate, Ammonium Thallate, AMPD-lsostearoyl Hydrolyzed Collagen, AMPD-Rosin Hydrolyzed Collagen, AMP-lsostearoyl Hydrolyzed Collagen, AMP-lsostearoyl Hydrolyzed Keratin, AMP-Isostearoyl Hydrolyzed Soy Protein, AMP-Isostearoyl Hydrolyzed Wheat Protein, Apricot, Amidopropyl Betaine, Arachidic Acid, Hexyldecyl Arginine Phosphate, Avocado Oil Glycereth-8 Esters, Babassu Acid, Babassuamidopropylamine Oxide, Babassuamidopropyl Betaine, Beeswax Acid, Behenamidopropyl Betaine, Behenamine Oxide, Beheneth-25, Beheneth-30, Behenic Acid, Behenyl Betaine, Bis-Butyldimethicone Polyglyceryl-3, Butyxytol-5 Carboxylic Acid, Butyxytol-19 Carboxylic Acid, Butyldimonium Chloride, Hydroxypropyl Butyl Glucosides, Chloride Butyldimoniumhydroxypropyl Laurylglucosides, Butyl Glucoside, Butyl Glucoside Caprate, Butyl Glucosides Hydroxypropyltrimonium Chloride, Butyloctanoic Acid, C18-36 Acid, C20-40 Acid, C30-50 Acid, C16-22 Acid Amide MEA, Calcium Dodecylbenzenesulfonate, Calcium Lauroyl Taurate, C9-16 Alkane/Cycloalkane, C10-14 Alkyl Benzenesulfonic Acid, C12-14 Alkyl Diaminoethylglycine HCL, C9-15 Alkyl Phosphate, Candida Bombicola/Glucose/Methyl Rapeseed Ferment, Canolamidopropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glucoside, Capryl/Capramidopropyl Betaine, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Caprylic Acid, Capryloyl Collagen Amino Acid, Capryloyl Glycine, Caproyl Hydrolyzed Collagen, Caproyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acid, Capryloyl Silk Amino Acid, Caprylyl/Capryl Glycoside, Caprylyl/Capryl Wheat Bran/Straw Glycosides, Caprylyl Glycoside, Caprylyl Glyceryl Ether, Caprylyl Pyrrolidone, Carnitine, Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ce- Teareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Ceteareth-4 Phosphate teareth-5, Ceteareth-10 Phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Cetoleth-22, Cetoleth-24, Cetoleth-25, Cetoleth-30, Cetyl Betaine, Chrysanthemum Sinense Flower Extract, C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidoethyl Betaine, Cocamidopropylamine Oxide, Cocamidopropyl Betainamide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid, Coceth-7 Carboxylic Acid, Coceth-4 Glycoside, Cocoamphodipropionic Acid, Cocobetainamido Amphopropionate, Coco-Betaine, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Coco-Glucoside, Cocoglycoside Hydroxypropyltrimonium Chloride, Coco-Hydroxysultaine, Coco-Morpholine Oxide, Coconut Acid, Coconut Oil Glycereth-8 Esters, Coconut/Oleamidopropyl Betaine, Coco-Sultaine, Coco/Amidopropyl Sunflower Betaine, Cocoylcholine Methosulfate, Cocoyl Glutamic Acid, Cocoyl Hydrolyzed Collagen, Cocoyl Hydrolyzed Keratin, Cocoyl Hydrolyzed Oat Protein, Cocoyl Hydrolyzed Rice Protein, Cocoyl Hydrolyzed Silk, Cocoyl Hydrolyzed Soy Protein Cocoyl, Cocoyl Hydrolyzed Wheat Protein, Cocoyl Sarcosine, Corn Acid, Cottonseed Acid, Cottonseed Oil Glycereth-8 Esters, C10-16 Pareth-1, C10-16 Pareth-2, C11-13 Pareth-6, C11-13 Pareth-9, C11-13 Pareth-10, C11-15 Pareth-30, C11-15 Pareth-40, C12-13 Pareth-1, C12-13 Pareth-23, C12-14 Pareth-5, C12 14 Pareth-9, C13-15 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 Carboxylic Acid, C9-11 Pareth-8 Carboxylic Acid, C11-15 Pareth-7 Carboxylic Acid, C12-13 Pareth-5 Carboxylic Acid, C12-13 Pareth-7 Carboxylic Acid, C12-13 Pareth-8 Carboxylic Acid, C12-13 Pareth-12 Carboxylic Acid, C12-15 Pareth-7 Carboxylic Acid, C12-15 Pareth-8 Carboxylic Acid, C12-15 Pareth-12 Carboxylic Acid, C14-15 Pareth-8 Carboxylic Acid, C6-10 Pareth-4 Phosphate, C12-13 Pareth-2 Phosphate, C12-13 Pareth-10 Phosphate, C12-15 Pareth-6 Phosphate, C12-15 Pareth-8 Phosphate, C12-15 Pareth-10 Phosphate, C12-16 Pareth-6 Phosphate, C4-18 Perfluoroalkylethyl Thiohydroxypropyltrimonium Chloride, Cupuasuamidopropyl Betaine, DEA-C12-13 Alkyl Sul fact, DEA-C12-15 Alkyl Sulfate, DEA-Ceteareth- 2 Phosphate, DEA-Cethyl Sulfate, DEA-Cocoamphodipropionate, DEA-C12-13 Pareth-3 Sulfate, DEA-Cyclocarboxypropyloleate, DEA-dodecylbenzenessulfonate, DEA-lstearate, DEA-Laureth Sulfate, Sulfate DEA-Lauryl, DEA-Linoleate, DEA-Methyl Myristate Sulfonate, DEA-Mireth Sulfate, DEA-Myristate, DEA-Myristyl Sulfate, DEA-Oleth-5 Phosphate, DEA-Oleth-10 Phosphate, DEA-Oleth-20 Phosphate, DEA PG-Oleate, Deceth-7 Carboxylic Acid, Deceth-7 Glucoside, Deceth-9 Phosphate, Decylamine Oxide, Decyl Betaine, Decyl Glucoside, Decyltetradeceth-30, Decyltetradecylamine Oxide, Diammonium Sulfosuccinate Lauramido-MEA, Diammonium Lauryl Sulfosuccinate, Diammonium Sulfosuccinate Oleamido PEG-2, Dibutoxymethane, Di-CI 2 15 Pareth-2 Phosphate, Di-CI 2-15 Pareth-4 Phosphate, Di-CI 2-15 Pareth-6 Phosphate, Di- C12-15 Pareth-8 Phosphate, Di-CI 2-15 Pareth-10 Phosphate, Didodecyl Butanetetracarboxylate, Diethylamine Laureth Sulfate, Diethylhexyl Sodium Sulfosuccinate, Dihydroxyethyl C8-10 Alkoxypropylamine Oxide, Dihydroxyethyl C9-11 Alkoxypropylamine Oxide, Dihydroxyethyl C12-15 Alkoxypropylamine Oxide, Dihydroxyethyl Cocamine Oxide, Dihydroxyethyl Lauramine Oxide, Dihydroxyethyl Stearamine Oxide, Dihydroxyethyl Tallowamine, Dilaureth-4 Phosphate, Dimethicone PEG-7 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG/PPG-7/4 Phosphate, Dimethicone PEG/PPG-12/4 Phosphate, Dimethicone/Polyglycerin-3 Crosspolymer, Dimethicone Propyl PG-Betaine, Dimyristyl Phosphate, Dioleoylamidoethyl Hydroxyethylmonium Methosulfate, DIPA-Hydrogenated Cocoate, DIPA-Lanolate, DIPA-Myristate, Dipotassium Capryloyl Glutamate, Dipotassium Lauryl Sulfosuccinate, Dipotassium Undecylenoyl Glutamate, Babassustarch MEA-Disodium Sulfosuccinate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Capryloyl Glutamate, Disodium Cetearyl Sulfosuccinate, Disodium Cetyl Phenyl Ether Disulfonate, Disodium Cetyl Sulfosuccinate, Cocamido MEA-Disodium Sulfosuccinate, Cocamido MIPA PEG-4 Disodium Sulfosuccinate, Cocamido MIPA-Disodium Sulfosuccinate, Cocamido PEG-3 Disodium Sulfosuccinate, Disodium Coceth-3 Sulfosuccinate, Disodium Cocoamphocarboxyethylhydroxypropylsulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Coco-Glycoside Sulfosuccinate, Coco-Sulfosuccinate Disodium Cocoyl Butyl Gluceth-10 Sulfosuccinate, Disodium Cocoyl Glutamate Disodium C12-14 Pareth-1 Sulfosuccinate, Disodium C12-14 Pareth-2 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium C12-14 Sec- Pareth-3 Sulfosuccinate, Disodium C12-14 Sec-Pareth-5 Sulfosuccinate, Disodium C12-14 Sec-Pareth-7 Sulfosuccinate, Disodium C12-14 Sec-Pareth-9 Sulfosuccinate, Disodium C12-14 Sec-Pareth-12 Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosuccinate, Disodium Decyl Phenyl Ether Disulfonate, Disodium Dihydroxyethyl Sulfosuccinylundecylenate, Disodium Ethylene Dicocamide PEG-15 Disulfate, Disodium Hydrogenated Cottonseed Glyceride Sulfosuccinate, Disodium Hydrogenated Tallow Glutamate, Disodium Hydroxidecyl Sorbitol Citrate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamido MEA-Sulfosuccinate, Disodium Isostearamido MIPA-Sulfosuccinate, Disodium Isostearoamphodiacetate, Disodium Isostearoamphodipropionate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Lauramido MEA-Disodium Sulfosuccinate, Lauramido MIPA Glycol Sulfosuccinate Disodium, Lauramido PEG-2 Sulfosuccinate Disodium, Lauramido PEG-5 Sulfosuccinate Disodium, Laureth-5 Carboxyamphodiacetate Disodium, Laureth-7 Citrate Disodium Laureth Sulfosuccinate, Laureth-6 Sulfosuccinate Disodium, Laureth-9 Sulfosuccinate Disodium, Laureth-12 Sulfosuccinate Disodium Lauriminobihydroxypropylsulfonate Disodium Lauriminodiacetate Disodium Lauriminodipropionate Tocopheryl Lauriminodipropionate Disodium Phosphate, Disodium Lauroamphodiacetate Disodium Lauroamphodipropionate, N-Lauroyl Disodium Asparate, Disodium Lauroyl Glutamate, Disodium Lauryl Phenyl Ether Disulfonate, Disodium Lauryl Sulfosuccinate, Myristamide MEA-Disodium Sulfosuccinate, Nonoxynol-10 Sulfosuccinate Disodium, Oleamido MEA-Disodium Sulfosuccinate, Oleamido MIPA-Disodium Sulfosuccinate, Oleamido PEG-2 Sulfosuccinate Disodium, Oleoamphodipropionate Disodium, Oleth-3 Sulfosuccinate Disodium, Oleyl Phosphate Disodium, Oleyl Sulfosuccinate Disodium, Palmitamide PEG-2 Sulfosuccinate Disodium, Palmitole-starch PEG-2 Sulfosuccinate Disodium, PEG-4 Cocamide MIPA-Disodium Sulfosuccinate, PEG-12 Dimethicone Sulfosuccinate, Disodium Sulfosuccinate, PEG-8 Palm Glycerides, Disodium PPG-2-Isodeceth-7 Carboxyamphodiacetate, Disodium Ricinoleamido MEA-Sulfosuccinate, Disodium Sitoestereth-14 Sulfosuccinate, Disodium Soyamphodiacetate, Disodium Stearamido MEA-Sulfosuccinate, Disodium Steariminodipropionate, Disodium Stearoamphodiacetate, Disodium Stearoyl Glutamate, Disodium Stearyl Sulfosuccinamate, Disodium Stearyl Sulfosuccinate, Disodium 2-Sulfolaurate, Disodium 2-Sulfopalmitate, Tallowamido MEA-Sulfosuccinate, Tallowamido MEA-Sulfosuccinate Disodium, Disodium Tallowanphodiacetate, Disodium Tallowiminodipropionate, Disodium Tallow Sulfosuccinamate, Disodium Tridecylsulfosuccinate, Disodium Undecylenamido MEA-Sulfosuccinate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Undecylenoyl Glutamate, Disodium Wheat Germ Starch MEA-Sulfosuccinate, Disodium Wheat Germ Phosphate, Di-TEA-Cocamide Diacetate, Di-TEA-Oleamido PEG-2 Sulfosuccinate, Di-TEA-Palmitoyl Asparate, Ditridecyl Sodium Sulfosuccinate, Dodecylbenzene Sulfonic Acid, Erucamidepropyl Hydroxysultaine, Sodium Carboxylic Acid Ethylexeth-3, Ethyl PEG-15 Cocamine Sulfate, Glyceryl Capryl Etherhexyldecanoic Acid, Hydrogenated Coconut Acid, Hydrogenated Laneth-25, Hydrogenated Menhaden Acid, Hydrogenated Palm Acid, Hydrogenated Palm Seed Amine Oxide, Hydrogenated Tallow Acid, Hydrogenated Tallow Amine Oxide, Hydrogenated Tallow Betaine, Hydrogenated Tallow-25, Hydrogenated Tallowyl Glutamic Acid, Hydrolyzed Bombicola Candi Extract, Hydroxyceteth-60, Hydroxyethyl Acetomonium PG-Dimethicone, Hydroxyethylbutylamine Laureth Sulfate, Hydroxyethyl Carboxymethyl Cocamidopropylamine, Hydroxyethyl Hydroxypropyl C12-15 Oxide Alkoxypropylamine, Hydroxylauryl/Hydroxymyristyl Betaine, Hydroxystearic Acid, C10-40 lsoalkyl Hydroxysuccinimidyl Acidate, C21-22 lsoalkyl Hydroxysuccinimidyl Acidate, Hydroxysultaines, IPDI/PEG-15 Soybean Oxide Copolymer, IPDI/PEG-15 Soybean Ethosulfate Copolymer, IPDI/PEG-15 Soybean Glycinate Copolymer, lsoceteth-30, lsolaureth-4 Phosphate, lsopolyglyceryl-3 Dimethicone, lsopolyglyceryl-3 Dimethiconol, lsopropanolamine Lanolate, lsopropylamine Dodecylbenzenesulfonate, lsostearamidopropylamine Oxide, lsostearamidopropyl Betaine, lsostearamidopropyl Morpholine Oxide, lsosteareth-8, lsosteareth-16, lsosteareth-22, lsosteareth-25, lsosteareth-50, Isostearic Acid, lsostearoyl Hydrolyzed Collagen, PEG-150 Jojoba Oil Esters, PEG-80 Jojoba Wax Esters, PEG-120 Jojoba Wax Esters, Laneth-20, Laneth-25, Laneth-40, Laneth-50, Laneth-60, Laneth-75, Lanolin Acid, Lauramidopropylamine Oxide, Lauramidopropyl Betaine, Lauramidopropyl Hydroxysultaine, Lauramine Oxide, Acid Lauraminopropionic Acid, Laurdimoniumhydroxypropyl Decylglucoside Chloride, Laurdimoniumhydroxypropyl Laurylglucoside Chloride, Laureth-16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-38, Laureth-40, Laureth-3 Carboxylic Acid, Laureth-4 Carboxylic Acid, Laureth-5 Carboxylic Acid, Laureth-6 Carboxylic Acid, Laureth-8 Carboxylic Acid, Laureth-10 Carboxylic Acid, Laureth-11 Carboxylic Acid, Laureth-12 Carboxylic Acid, Laureth-13 Carboxylic Acid, Laureth-14 Carboxylic Acid, Laureth-17 Carboxylic Acid, Laureth-18 Carboxylic Acid, Laureth-19 Carboxylic Acid, Laureth-20 Carboxylic Acid, Laureth-21 Carboxylic Acid, Laureth-22 Carboxylic Acid, Laureth-23 Carboxylic Acid, Laureth-24 Carboxylic Acid, Laureth-25 Carboxylic Acid, Laureth-26 Carboxylic Acid, Laureth-27 Carboxylic Acid, Laureth-28 Carboxylic Acid, Laureth-29 Carboxylic Acid, Laureth-30 Carboxylic Acid, Laureth-31 Carboxylic Acid, Laureth-32 Carboxylic Acid, Laureth-33 Carboxylic Acid, Laureth-34 Carboxylic Acid, Laureth-35 Carboxylic Acid, Laureth-36 Carboxylic Acid, Laureth-37 Carboxylic Acid, Laureth-38 Carboxylic Acid, Laureth-39 Carboxylic Acid, Laureth-40 Carboxylic Acid, Laureth-41 Carboxylic Acid, Laureth Laureth-6, Laureth-7 Citrate, Laureth-1 Phosphate, Laureth-2 Phosphate, Laureth-3 Phosphate, Laureth-4 Phosphate, Laureth-7 Phosphate, Laureth-8 Phosphate, Laureth-7 Tartrate, Lauric Acid, Laurimino Bispropanediol, Lauriminodipropionic Acid, Lauroamphodipropionic Acid, Lauroyl Beta-Alanine, Lauroyl Collagen Amino Acids, Lauroyl Ethyltrimonium Methosulfate, Hydrolyzed Lauroyl Collagen, Lauroyl Hydrolyzed Elastin, Lauroyl Methyl Glucamide, Lauroyl Sarcosine, Lauroyl Silk Amino Acids, Lauryl Betaine, Lauryl Dimethicone/Polyglycerin-3 Crosspolymer, Sodium Chloride, Lauryldimoniumhydroxypropyl Cocoglycosides, Lauryl Glucoside, Lauryl Glucoside Hydroxypropyltrimonium Chloride, Lauryl Glycol Hydroxypropyl Ether, Lauryl Hydroxysultaine, Lauryl Melamide, Lauryl Methylglucamide, Lauryl/Myristyl Glycol Hydroxypropyl Ether, Lauryl/Myristyl Wheat Bran/Straw Glycosides, Polyglyceryl-3 Lauryl Dimethicone Polydimethylsiloxyethyl, Lauryl Pyrrolidone, Lauryl Sultaine, Linoleic Acid, Linolenic Acid, Linseed Acid, Lysine Cocoate, Macadamia Seed Glycereth-8 Esters, Magnesium Coceth Sulfate, Magnesium Coco-Sulfate, Magnesium Isododecylbenzenesulfonate, Carbomer, Magnesium Laureth-11 Boxylate, Magnesium Laureth Sulfate, Magnesium Laureth-5 Sulfate, Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfonate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myreth Sulfate, Magnesium Oleth Sulfate, Magnesium/TEA-Coco-Sulfate, Manicouagan Clay, MEA-Cocoate, MEA-Laureth-6 Carboxylate, MEA-Laureth Sulfate, MEA-Lauryl Sulfate, MEA-Carboxylate PPG-6 Laureth-7 Carboxylate MEA-PPG-8-Steareth-7, MEA-Undecylenate, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, Methoxy PEG-450 Amidoglutaroyl Succinimide, Methoxy PEG-450 Starch Hydroxysuccinimidyl Succinamate, Methoxy PEG-450 Maleimide, Methyl Morpholine Oxide, Milk-amidopropyl Amine Oxide, Milk-amidopropyl Betaine, Milk-amidopropylamine Oxide, Milk-amidopropyl Betaine, MIPA C12-15 Pareth Sulfate, MIPA-Dodecylbenzenesulfonate, MIPA-Laureth Sulfate, MIPA-Lauryl Sulfate, Isopropanolamine Lanolate Blend, Isopropanolamine Lauryl Sulfate Blend, Isopropanolamine Myristate Blend, Morpholine Oleate, Morpholine Stearate, Myreth-3 Carboxylic Acid, Myreth-5 Carboxylic Acid, Myristalkonium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myristamine Oxide, Myristaminopropionic Acid, Myristic Acid, Myristoyl Ethyltrimonium Methosulfate, Myristyl Glutamic Acid, Myristoyl Hydrolyzed Collagen, Myristoyl Sarcosine, Myristyl Betaine, Myristyl Oxide/Cetyl Amine, Myristyldimonium Chloride, Hydroxypropyl Cocoglycosides, Myristyl Glucoside, Myristyl Phosphate, Nonoxynol-20, Nonoxynol-23, Nonoxynol-25, Nonoxynol-30, Nonoxynol-35, Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 Carboxylic Acid, Nonoxynol-8 Carboxylic Acid, Nonoxynol-10 Carboxylic Acid, Nonoxynol-3 Phosphate, Nonoxynol-4 Phosphate, Nonoxynol-6 Phosphate, Nonoxynol-9 Phosphate, Nonoxynol-10 Phosphate, Nonoxynol-11 Phosphate, Nonoxynol-12 Phosphate, Nonoxynol-13 Phosphate, Nonoxynol-14 Phosphate, Nonoxynol-15 Phosphate, Nonoxynol-16 Phosphate, Nonoxynol-17 Phosphate, Nonoxynol-18 Phosphate, Nonoxynol-19 Phosphate, Nonoxynol-20 Phosphate, Nonoxynol-21 Phosphate, Nonoxynol-22 Phosphate, Nonoxynol-23 Phosphate, Nonoxynol-24 Phosphate, Nonoxynol-25 Phosphate, Nonoxynol-26 Phosphate, Nonoxynol-27 Phosphate, Nonoxynol-28 Phosphate, Nonoxynol-29 Phosphate, Nonoxynol-30 Phosphate, Nonoxynol-31 Phosphate, Nonoxynol-32 Phosphate, Nonoxynol-33 Phosphate, Non Nonoxynol-10, Nonyl Nonoxynol-30, Nonyl Nonoxynol-49, Nonyl Nonoxynol-100, Nonyl Nonoxynol-150, Nonyl Nonoxynol Phosphate-7, Nonyl Nonoxynol Phosphate-8, Nonyl Nonoxynol Phosphate-9, Nonyl Nonoxynol Phosphate-10, Nonyl Phosphate Nonoxynol-11, Nonyl Phosphate Nonoxynol-15, Nonyl Phosphate Nonoxynol-24, Oatamidopropyl Betaine, Octoxynol-16, Octoxynol-25, Octoxynol-30, Octoxynol-33, Octoxynol-40, Octoxynol-70, Octoxynol-20 Carboxylic Acid, Octyldodeceth-20, Octyldodeceth-25, Octyldodeceth-30, Oleamidopropylamine Oxide, Oleamidopropyl Betaine, Oleamidopropyl Hydroxysultaine, Oleamine Oxide, Oleic Acid, Oleoyl Hydrolyzed Collagen, Oleoyl Sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleth-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Olivamidopropylamine Oxide, Olivamidopropyl Betaine, Olive Acid, Olivoyl Hydrolyzed Wheat Protein, Ophiopogon Extract Stearate, Ozonated Oleth-10, Ozonated PEG-10 Oleate, Ozonated PEG-14 Oleate, Ozonated Polysorbate 80, Palm Acid, Palmamidopropyl Betaine, Palmeth-2 Phosphate, Palmitamidopropylamine Oxide, Palmitamidopropyl Betaine, Palmitamine Oxide, Palmitic Acid, Palmitoyl Collagen Amino Acids, Palmitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Milk Protein, Palmitoyl Hydrolyzed Wheat Protein, Palmitoyl Keratin Amino Acids, Palmitoyl Oligopeptide, Palmitoyl Silk Amino Acids, Palm Kernel Acid, Palm Kernel Amidopropyl Betaine, Pear Seed Oil Glycereth-8 Esters, Peanut Acid, PEG-10 Castor Oil, PEG-40 Castor Oil, PEG-44 Castor Oil, PEG-50 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocamide, PEG-8 Cocamide, PEG-12 Cocamide, PEG-150 Dibehenate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, Laurate PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Sodium Sulfate, PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tallow, PEG-80 Glyceryl Tallow, PEG-82 Glyceryl Tallow, PEG-130 Glyceryl Tallow, PEG-200 Glyceryl Tallow, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil, PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin, PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-75 Laurate PEG-150, PEG-70 Mango Glycerides, PEG-20 Manitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanate, PEG-30 Oleamine, PEG-20 Oleate, PEG-23 Oleate, PEG-32 Oleate, PEG-36 Oleate, PEG-75 Oleate, PEG-150 Oleate, PEG-20 Palmitate, PEG-150 Polyglyceryl-2 Tristearate, PEG/PPG-28/21 Dimethicone Acetate, PEG/PPG- 24/18 Dimethicone Butyl Ether, Copolymer PEG/PPG-3/17, PEG/PPG-5/35 Copolymer, PEG/PPG-8/55 Copolymer, PEG/PPG-10/30 Copolymer, PEG/PPG-10/65 Copolymer, PEG/PPG-12/35 Copolymer, PEG/PPG-16/17 Copolymer, PEG/PPG-20/9 Copolymer, PEG/PPG-20/20 Copolymer, PEG/PPG-20/60 Copolymer, PEG/PPG-20/65 Copolymer, PEG/PPG-22/25 Copolymer, PEG/PPG-28/30 Copolymer, PEG/PPG-30-35 Copolymer, PEG/PPG-30/55 Copolymer, PEG/PPG-35/40 Copolymer, PEG/PPG-50/40, PEG/PPG-150/35 Copolymer, PEG/PPG-160/30 Copolymer, PEG/PPG-190/60 Copolymer, PEG/PPG-200/40 Copolymer, PEG/PPG-300/55 Copolymer, PEG/PPG-20/22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG/PPG-4/2 Propyleptyl Ether, PEG/PPG-6/2 Propyleptyl Ether, PEG-7/PPG-2 Propyleptyl Ether, PEG/PPG-8/2 Propyleptyl Ether, PEG/PPG-10/2 Propyleptyl Ether, PEG/PPG-14/2 Propyleptyl Ether, PEG/PPG-40/2, PEG/PPG-10/2 Ricinoleate, PEG/PPG-32/3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glycerides, PEG-75 Shorea Butter Glycerides, PEG-20 Sorbitan Stearate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Tearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearamide Carboxylic Acid, PEG-9 Stearamide Carboxylic Acid, PEG-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG- 120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallate, PEG-50 Tallow Amide, PEG-2 Tallow Amide DEA, PEG-20 Tallow, PEG-66 Trihydroxystearin, PEG-200 Trihydroxystearin, PEG-60 Tsubakiate Glycerides, Pelargonic Acid, Pentadoxynol-200, Pheneth-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288, Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG/PPG-24/19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomaderris Kumerahou Flower/Leaf Extract, Poria Cocos Extract, Potassium Abietoyl Hydrolyzed Collagen, Potassium Basuate, Potassium Behenate, C9-15 Alkyl Potassium Phosphate, C11-15 Alkyl Potassium Phosphate, C12-13 Alkyl Potassium Phosphate, Potassium C12-14 Alkyl Phosphate, Potassium Caprate, Potassium Capryloyl Glutamate, Potassium Capryloyl Hydrolyzed Rice Protein, Potassium Castorate, Potassium Cocoate, Potassium Cocoyl Glutamate, Potassium Cocoyl Glycinate, Potassium Cocoyl Hydrolyzed Casein, Potassium Cocoyl Hydrolyzed Collagen, Potassium Cocoyl Hydrolyzed Corn Protein, Potassium Cocoyl Hydrolyzed Keratin, Potassium Cocoyl Hydrolyzed Oat Protein, Potassium Cocoyl Hydrolyzed Potato Protein Potassium, Potassium Cocoyl Hydrolyzed Rice Bran Protein, Potassium Cocoyl Hydrolyzed Rice Protein, Potassium Cocoyl Hydrolyzed Silk, Potassium Cocoyl Hydrolyzed Soy Protein, Potassium Cocoyl Hydrolyzed Wheat Protein, Potassium Cocoyl Hydrolyzed Yeast Protein, Potassium Cocoyl PCA, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Cornate, Potassium Cyclocarboxypropyloleate, Potassium Dihydroxyethyl Cocamide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecylbenzenesulfonate, Potassium Hemp Seed, Potassium Hydrogenated Cocoate, Potassium Hydrogenated Palmate, Potassium Hydrogenated Tallow, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolate, Potassium Laurate, Potassium Laureth-3 Carboxylate, Potassium Laureth-4 Carboxylate, Potassium Laureth-5 Carboxylate, Potassium Laureth-6 Carboxylate, Potassium Laureth-10 Carboxylate, Potassium Laureth Phosphate, Potassium Lauroyl Collagen Amino Acids, Potassium Lauroyl Glutamate Potassium, Potassium Lauroyl Hydrolyzed Collagen, Potassium Lauroyl Hydrolyzed Pea Protein, Potassium Lauroyl Hydrolyzed Soy Protein, Potassium Lauroyl PCA, Potassium Lauroyl Pea Amino Acid, Potassium Lauroyl Sarcosinate, Potassium Lauroyl Silk Amino Acids, Potassium Lauroyl Wheat Amino Acids, Potassium Lauryl Phosphate, Potassium Lauryl Sulfate, Potassium Linoleate, Potassium Metaphosphate, Potassium Methyl Cocoyl Taurate, Potassium Myristate, Potassium Myristoyl Glutamate, Potassium Myristoyl Hydrolyzed Collagen, Potassium Octoxynol-12 Phosphate, Potassium Oleate, Potassium Oleoyl Hydrolyzed Collagen, Potassium Olivate, Potassium Olivoyl Hydrolyzed Oat Protein, Potassium Olivoyl Hydrolyzed Wheat Protein, Potassium Olivoyl/Lauryl Wheat Amino Acids, Potassium Olivoyl PCA, Potassium Palmate, Potassium Palmitate, Potassium Palmitoyl Hydrolyzed Corn Protein, Potassium Palmitoyl Hydrolyzed Oat Protein, Potassium Palmitoyl Hydrolyzed Rice Protein, Potassium Palmitoyl Hydrolyzed Sweet Almond Protein, Potassium Palmitoyl Hydrolyzed Wheat Protein, Potassium Palm Kernelate, Potassium Peanutate, Potassium Rapeseedate, Potassium Ricinoleate, Potassium Safflowerate, Potassium Soyate, Potassium Stearate, Potassium Stearoyl Hydrolyzed Collagen, Potassium Thallate, Potassium Tallow, Potassium Taurate, Potassium Taurine Laurate, Potassium Trideceth-3 Carboxylate, Potassium Trideceth-4 Carboxylate, Potassium Trideceth-7 Carboxylate, Potassium Trideceth-15 Carboxylate, Potassium Trideceth-19 Carboxylate, Potassium Trideceth-6 Phosphate, Potassium Trideceth-7 Phosphate, Potassium Tsubakiate, Potassium Undecylenate, Potassium Undecylenoyl Hydrolyzed Collagen, Potassium Undecylenoyl Hydrolyzed Rice Protein, PPG-30-Buteth-30, PPG-36-Buteth-36, PPG-38-Buteth-37, PPG-30-Capryleth-4 Phosphate, PPG-10 Cetyl Ether Phosphate, PPG-2 C9-11 Pa- reth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylic Acid, PPG-30 Ethylexeth-4 Phosphate, PPG-20-Glycereth-30, PPG-2 Hydroxyethyl Coco- co/lsostearamide, PPG-2- lsodeceth-8, PPG-2- lsodeceth-10, PPG-2- lsodeceth-18, PPG-2- lsodeceth-25, PPG-4- lsodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Acid, Rice Bran Acid, Rice Oil Glycereth-8 Esters, Ricinoleamidopropyl Betaine, Ricinoleic Acid, Ricinoleth-40, Safflower Acid, Sapindus Oahuensis Fruit Extract, Saponaria Officinalis Root Powder, Saponins, Sekken-K, Sekken-Na/K, Sekken Soji, Sekken Soji-K, Glycereth-8 Sesame Oil Esters, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butter Amidopropyl Betaine, Glycereth-8 Shea Butter Esters, Sodium Arachidylserine, Sodium Arganampohoacetate, Sodium Astrocarium Murumuruate, Sodium Avocadoate, Sodium Babassuanfoacetate, Sodium Babassuu Sulfate, Sodium Behenate, Sodium Bisglycol Ricinosulfosuccinate, Bis-Hydroxyethylglycinate Sodium Coco-Glycosides Crosspolymer, Sodium Lauryl Glycosides Crosspolymer, Borageamidopropyl PG-Dimonium Chloride Phosphate Sodium, Sodium Butoxynol-12 Sulfate, Sodium Hydroxypropyl Butylglycoside Phosphate, Sodium C13-17 Alkane Sulfonate, Sodium C14-18 Alkane Sulfonate, Sodium C12-15 Alkoxypropyl Sodium Iminodipropionate, C10-16 Alkyl Sodium Sulfate, C11-15 Alkyl Sodium Sulfate, C12-13 Alkyl Sodium Sulfate, C12-15 Alkyl Sodium Sulfate, C12-18 Alkyl Sodium Sulfate, C16-20 Alkyl Sodium Sulfate, C9-22 Alkyl Sec Sodium Sulfonate, C14-17 Alkyl Sec Sodium Sulfonate, Sodium Caprate, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropylsulfonate, Sodium Caproamphopropionate, Sodium Caproyl Methyltaurate, Sodium Caprylate, Sodium Capryleth-2 Carboxylate, Sodium Capryleth-9 Carboxylate, Sodium Capryloamphoacetate, Sodium Capryloamphohydroxypropylsulfonate, Sodium Capryloamphopropionate, Sodium Capryloyl Glutamate, Sodium Capryloyl Hydrolyzed Wheat Protein, Sodium Caprylyl PG-Sulfonate, Sodium Caprylyl Sulfonate, Sodium Castorate, Sodium Ceteareth-13 Carboxylate, Sodium Cetearyl Sulfate, Sodium Ceteth-13 Carboxylate, Sodium Cetyl Sulfate, Cocamidopropyl PG-Dimonium Sodium Chloride Phosphate, Sodium Cocaminopropionate, Sodium Coceth Sulfate, Sodium Co-ceth-30 Sulfate, Sodium Cocoabutteramphoacetate, Sodium Cocoa Butterate, Sodium Cocoamphoacetate, Sodium Cocoamphohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cocoate, Sodium Coco/Babassu/Andiroba Sulfate, Sodium Coco/Babassu Sulfate, Sodium Cocoglycoside Hydroxypropyl Phosphate, Sodium Cocoglycoside Hydroxypropylsulfonate, Sodium Coco-Glucoside Tartrate, Sodium Cocoglyceryl Ether Sulfonate, Sodium Hydrogenated Coconut/Tallow Sulfate, Sodium Cocoiminodiacetate, Sodium Cocomonoglyceride Sulfate, Sodium Coco-Polymer Sulfate, PG-Dimonium Chloride Phosphate Sodium, Sodium Coco-Sulfate, Sodium Coco-Sulfoacetate, Sodium Cocoyl Alaninate, Sodium Cocoyl Amino Acids, Sodium Cocoyl Collagen Amino Acids, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutaminate, Sodium Cocoyl Glycinate, Sodium Cocoyl/Hydrogenated Tallow Glutamate, Sodium Cocoyl Hydrolyzed Collagen, Sodium Cocoyl Hydrolyzed Keratin, Sodium Cocoyl Hydrolyzed Rice Protein, Sodium Cocoyl Hydrolyzed Silk, Sodium Cocoyl Hydrolyzed Soy Protein, Sodium Cocoyl Sweet Almond Protein, Sodium Cocoyl Hydrolyzed Wheat Protein, Cocoyl Hydrolyzed Wheat Protein Glutamate Sodium, Sodium Cocoyl Isethionate, Sodium Cocoyl Methylaminopropionate, Sodium Cocoyl Oat Amino Acids, Sodium Cocoyl/Palmoyl/Sunflower Oil Glutamate, Sodium Cocoyl Proline, Sodium Cocoyl Sarcosine, Sodium Cocoyl Taurate, Sodium Cocoyl Threoninate, Sodium Cocoyl Wheat Amino Acids, Sodium C12-14 Olefin Sulfonate, C14-16 Olefin Sulfonate, C14-18 Olefin Sulfonate, C16-18 Olefin Sulfonate, Sodium Cornamphopropionate, Sodium Cottonseed Acetate, C13-15 Pareth-8 Butyl Phosphate, C9-11 Sodium Sodium Pareth-6 Carboxylate, C11-15 Pareth-7 Sodium Carboxylate, C12-13 Pareth-5 Sodium Carboxylate, C12-13 Pareth-8 Sodium Carboxylate, C12-13 Pareth-12 Sodium Carboxylate, C12-15 Pareth-6 Sodium Carboxylate, C12-15 Pareth-7 Sodium Carboxylate, C12-15 Pareth-8 Sodium Carboxylate, C14-15 Pareth-8 Sodium Carboxylate, C12-14 Sec- Pareth-8 Sodium Carboxylate, C14-15 Pareth-PG Sodium Sulfonate, C12-13 Pareth-2 Sodium Phosphate, C13-15 Pareth-8 Sodium Phosphate, C9-15 Pareth-3 Sodium Sulfate, C10-15 Sodium Pareth Sulfate, C10-16 Sodium Pareth-2 Sulfate, Sodium C12-13 Pareth Sulfate, Sodium C12-15 Pareth Sulfate, C12-15 Pareth-3 Sodium Sulfate, C13-15 Pareth-3 Sodium Sulfate, C12-14 Sec-Pareth-3 Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfonate, Sodium C12-15 Pareth-7 Sulfonate, C12-15 Pareth-15 Sodium Sulfonate, Sodium Deceth-2 Carboxylate, Sodium Deceth Sulfate, Sodium Decylbenzenesulfonate, Sodium Hydroxypropyl Decylglucoside Phosphate, Decylglucoside Hydroxypropylsulfonate Sodium DiLaureth-7 Citrate, Sodium Dilaureth-10 Phosphate, Sodium Dilinoleamidopropyl PG-Dimonium Chloride Phosphate, Sodium Dilinoleate, Sodium Dioleth-8 Phosphate, Sodium Dodecylbenzenesulfonate, Sodium Ethyl 2-Sulfolaurate, Sodium Glyceryl Oleate Phosphate, Sodium Grapeseedamidopropyl PG-Dimonium Chloride Phosphate, Sodium Grapeseedanphoacetate, Sodium Grapeseedate, Sodium Hempseedanphoacetate, Sodium Hexeth-4 Carboxylate, Sodium Hydrogenated Cocoate, Sodium Hydrogenated Methyl Isethionate, Sodium Palmate, Sodium Hydrogenated Tallow Oil Glutamate, Sodium Tallow Oil Glutamate Sodium Hydrogenated Castor Oil, Sodium Hydroxylauryldimonium Ethyl Phosphate, Sodium Hydroxypropyl Palm Kernelate Sulfonate, Sodium Decylglucoside Hydroxypropylphosphate Crosspolymer, Sodium Laurylglucoside Hydroxypropylsulfonate Crosspolymer, Sodium Cocoglycoside Hydroxypropylsulfonate Crosspolymer, Sodium Hydroxypropylsulfonate Decylglucoside Crosspolymer, Sodium Laurylglucoside Hydroxypropylsulfonate Crosspolymer, Sodium Hydroxystearate, Sodium Isostearate, Sodium Isosteareth-6 Carboxylate, Sodium Isosteareth-11 Carboxylate, Sodium Isostearoamphoacetate, Sodium Isostearoamphopropionate, Methyltaurate Sodium N-Isostearoyl, Sodium Laneth Sulfate, Sodium Lanolate, Sodium Larate, Sodium Lauramido Diacetate, Sodium Lauraminopropionate, Sodium Laurate, Sodium Laureth-3 Carboxylate, Sodium Laureth-4 Carboxylate, Laureth-5 Sodium Carboxylate, Laureth-6 Sodium Carboxylate, Laureth-8 Sodium Carboxylate, Laureth-11 Sodium Carboxylate, Laureth-12 Sodium Carboxylate, Laureth-13 Sodium Carboxylate, Laureth-14 Sodium Carboxylate, Laureth-16 Sodium Carboxylate, Laureth-17 Sodium Carboxylate, Sodium Laureth Sulfate, Laureth-5 Sodium Sulfate, Laureth-7 Sodium Sulfate Sodium, Sodium Laureth-8 Sulfate, Sodium Laureth-12 Sulfate, Sodium Laureth-40 Sulfate, Sodium Laureth-7 Tartrate, Sodium Lauriminodipropionate, Sodium Lauroamphoacetate, Sodium Lauroamphohydroxypropylsulfonate, Sodium Lauroampho Phosphate PG-Acetate, Sodium Lauroamphopropionate, Sodium Lauroyl Asparate, Sodium Lauroyl Collagen Amino Acids, Sodium Lauroyl Glycine Propionate, Sodium Hydrolyzed Lauroyl Collagen, Sodium Lauroyl Hydrolyzed Silk, Sodium Lauroyl Hydroxypropyl Sulfonate, Sodium Lauroyl Isethionate, Sodium Lauroyl Methylaminopropionate, Sodium Lauroyl Methyl Isethionate, Amino Acid Sodium Lauroyl Millet Acids, Sodium Lauroyl/Myristoyl Asparate, Sodium Lauroyl Oat Amino Acids, Sodium Lauroyl Sarcosinate, Sodium Lauryl Silk Amino Acids, Sodium Lauroyl Taurate, Sodium Lauryl Wheat Amino Acids, Sodium Lauryl Diethylenediaminoglycinate, Sodium Lauryl Glucose Carboxylate, Sodium Laurylglucosides Hydroxypropyl Phosphate, Sodium Lauryl Glycol Carboxylate, Sodium Lauryl Hydroxyacetamide Sulfate, Sodium Lauryl Phosphate, Sodium Laureth Sulfate, Sodium Laureth Sulfate, Sodium Laureth Sulfate, Sodium Linoleate, Sodium Macadamia Seedate, Sodium Mangoamphoacetate, Sodium Mangoseedate, Sodium Laureth-2 Sulfosuccinate/MEA, PPG-2 Sodium Methoxy Acetate, Sodium Methyl Cocoyl Taurate, Sodium Methyl Lauroyl Taurate, Sodium Methyl Myristoyl Taurate, Methyl Oleoyl Sodium Taurate, Sodium Methyl Palmitoyl Taurate, Sodium Methyl Stearoyl Taurate, Sodium Methyl 2-Sulfolaurate, Sodium Methyl 2-Sulfopalmitate, Sodium Methyltaurate Isopalmitate, Sodium Methyltaurate Isopalmitate, Sodium Cocoyl Methyltaurate Methyltaurine, Sodium Myreth Sulfate, Sodium Myristate, Sodium Myristoamphoacetate, Sodium Myristoyl Glutamate, Sodium Myristoyl Hydrolyzed Collagen, Sodium Myristoyl Isethionate, Sodium Myristoyl Sarcosinate, Sodium Myristyl Sulfate, Nonoxynol-6 Sodium Phosphate, Nonoxynol-9 Sodium Phosphate, Nonoxynol-1 Sodium Sulfate, Nonoxynol-3 Sodium Sulfate, Nonoxynol-4 Sodium Sulfate, Nonoxynol-6 Sodium Sulfate, Nonoxynol-8 Sodium Sulfate, Nonoxynol-10 Sodium Sulfate, Nonoxynol-25 Sodium Sulfate, Octoxynol-2 Sodium Ethane Sulfonate, Octoxynol-2 Sodium Sulfate, Octoxynol-6 Sodium Sulfate, Octoxynol-9 Sodium Sulfate, Sodium Oleate, Sodium Oleoamphoacetate, Sodium Oleoamphohydroxypropylsulfonate, Sodium Oleoamphopropionate, Oleoyl Sodium Hydrolyzed Collagen, Sodium Oleoyl Isethionate, Sodium Oleth Sulfate, Sodium Oleyl Methyl Isethionate, Sodium Oleyl Sulfate, Sodium Olivamphoacetate, Sodium Olivate, Sodium Olivoyl Glutamate, Sodium Palmamphoacetate, Sodium Palmate, Sodium Palm Glyceride Sulfonate, Sodium Palmitate, Palmitoyl Sodium Hydrolyzed Collagen, Sodium Palmitoyl Hydrolyzed Wheat Protein, Sodium Palmitoyl Sarcosinate, Sodium Palm Kernelate, Sodium Palm Kerneloyl Isethionate, Sodium Palmoyl Glutamate, Sodium Passiflora Edulis See- tate, Sodium Peanutamphoacetate, Sodium Pe- nuatate, PEG-6 Sodium Cocamide Carboxylate, PEG-8 Sodium Cocamide Carboxylate, PEG-4 Sodium Cocamide Sulfate, PEG-3 Sodium Lauramide Carboxylate, PEG-4 Sodium Lauramide Carboxylate, PEG-8 Palm Glycerides Sodium Carboxylate, Pentaerythrityl Hydroxypropyl lminodiacetate Sodium Dendrimer, PPG-2 Propoxy Sodium Acetate, Sodium Rapeseedate, Sodium Ricebranamphoacetate, Sodium Ricinoleate, Sodium Ricinoleoamphoacetate, Sodium Hippophaecetate, Sodium Rosinate, Sodium Safflower, Sodium Safflower Oil Hydrolyzed Soy Protein, Sodium Sesame-seedate, Sodium Sesanphoacetate, Sodium Sheabutteramphoacetate, Sodium Soybean Protein, Sodium Stearoate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Stearoyl Casein, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl Hydrolyzed Silk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Lactalbumin, Sodium Stearoyl Methyl Isethionate, Sodium Stearoyl Oat Protein, Sodium Stearoyl Pea Protein, Sodium Stearoyl Soy Protein, Stearyl Dimethyl Glycine, Sodium Stearyl Sulfate, Sodium Sunflower Seed Amphoacetate, Sodium Surfactin, Sodium Seed Anacetate, Sodium Sweet Almondate, Sodium Talc, Sodium Tallate, Sodium Tallow Amphoacetate, Sodium Tallowate, Sodium Tallowate Sulfate, Sodium Tamanuseedate, Sodium Taurate, Sodium Cocoyl Methyltaurate, Sodium Taurine Laurate, Sodium Amino Acids/TEA-Lauroyl Collagen, Sodium/TEA-Lauroyl Collagen Hydrolysate, Sodium/TEA-Lauroyl Hydrolyzed Keratin, Sodium Amino Acids/TEA-Lauroyl Keratin, Amino Acids/TEA-Lauroyl Sodium/TEA-Undecylenoyl Collagen, Sodium/TEA-Undecylenoyl Hydrolyzed Collagen, Sodium/TEA-Undecylenoyl Hydrolyzed Corn Protein, Sodium/TEA-Undecylenoyl Hydrolyzed Soy Protein, Sodium/TEA-Undecylenoyl Hydrolyzed Wheat Protein, Sodium Theobroma Grandiflorum Seedate, Sodium Trideceth-3 Carboxylate, Sodium Trideceth-4 Carboxylate, Sodium Trideceth-6 Carboxylate, Sodium Trideceth-7 Carboxylate, Sodium Trideceth-8 Carboxylate, Sodium Trideceth-12 Carboxylate, Sodium Trideceth-15 Carboxylate, Sodium Trideceth-19 Carboxylate, Sodium Trideceth Sulfate Sodium, Sodium Tridecylbenzenesulfonate, Sodium Tridecyl Sulfate, Trimethylolpropane Hydroxypropylaminodiacetate Sodium Dendrimer, Sodium Undeceth-5 Carboxylate, Sodium Undecylenate, Sodium Undecyleneamphoacetate, Sodium Undecyleneamphopropionate, Sodium Undecylenoyl Glutamate, Sodium Wheat Germ Amphoacetate, Sorbeth-160 Tristearate, Soybean Acid, Soybean Starchpropylamine Oxide, Soybean Starchpropyl Betaine, Glycereth-8 Soybean Oil Esters, Stearamido Propylamine Oxide, Stearamido Propyl Betaine, Stearamine Oxide, Steareth-15, Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyltrimonium Chloride, Stearoyl Glutamic Acid, Stearoyl Sarcosine, Stearyl Betaine, Stearyldimonium Hydroxypropyl Butylglycosides, Stearyldimonium Hydroxypropyl Decylglycosides, Stearyldimonium Hydroxypropyl Laurylglycosides, Sulfated Castor Oil, Sulfated Coconut Oil, Sulfated Glyceryl Oleate, Sulfated Olive Oil, Peanut Oil Sulfated, Sunflower Amide MEA, Sunflower Seed Acid, Sunflower Seed Amidopropyl Hydroxyethyldimonium Chloride, Glycereth-8 Sunflower Seed Oil Esters, Tall Oil Acid, Tallow Acid, Tallow Amidopropylamine Oxide, Tallow Amidopropyl Betaine, Tallow Amidopropyl Hydroxysultaine, Tallow Amine Oxide, Tallow Betaine, Dihydroxyethyl Tallow Betaine, Tallow Oil Ethyl Glycoside, TEA-Abietoyl Hydrolyzed Collagen, TEA-C12-14 Alkyl Phosphate, TEA-C10-15 Alkyl Sulfate, TEA-C11-15 Alkyl Sulfate, TEA-C12-13 Alkyl Sulfate, TEA-C12-14 Alkyl Sulfate, TEA- C12-15 Alkyl Sulfate, TEA- C14-17 Alkyl Sec Sulfonate, TEA- Canolate, TEA-Cocamide Diacetate, TEA-Cocoate, TEA-Coco- Sulfate, TEA-Cocoyl Alaninate, TEA-Cocoyl Glutamate, TEA-Cocoyl Glutaminate, TEA-Cocoyl Glycinate, TEA-Cocoyl Hydrolyzed Collagen, TEA-Cocoyl Hydrolyzed Soy Protein, TEA-Cocoyl Sarcosinate, PEG-7 TEA-Dimethicone Phosphate, TEA-Dodecylbenzenesulfonate, TEA-Hydrogenated Cocoate, Tallow Oil Glutamate TEA-Hydrogenated, TEA-Isostearate, TEA-Isostearate Hydrolyzed Collagen, TEA-Lauraminopropionate, TEA-Laurate, TEA-Laurate/Myristate, TEA-Laureth Sulfate, TEA-Lauroyl Collagen Amino Acids, TEA-Lauroyl Glutamate, TEA-Lauroyl Hydrolyzed Collagen, TEA-Lauroyl Keratin Amino Acids, TEA-Lauroyl Methylaminopropionate, TEA-Lauroyl/Myristoyl Asparate, TEA-Lauroyl Sarcosinate, TEA-Lauryl Phosphate, TEA-Lauryl Sulfate, TEA-Myristaminopropionate, TEA-Myristate, TEA-Myristoyl Hydrolyzed Collagen, TEA-Oleate, TEA-Oleoyl Hydrolyzed Collagen, TEA-Oleoyl Sarcosinate, TEA-Oleyl Sulfate, TEA-Palmitate, TEA-Palm Kernel Sarcosinate, TEA-PEG-3 Cocamide Sulfate, TEA-Rosinate, TEA-Stearate, TEA-Thallate, TEA-Tridecylbenzenesulfonate, TEA-Undecylenate, TEA-Undecylenoyl Hydrolyzed Collagen, Tetramethyl Decinediol, Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate, TIPA-Laureth Sulfate, TIPA-Lauryl Sulfate, TIPA-Myristate, TIPA-Stearate, Tocopheryl Phosphate, Trehalose Undecylenoate, TM-C12-15 Pareth-2 Phosphate, TM-C12-15 Pareth-6 Phosphate, TM-C12- 15 Pareth-8 Phosphate, TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Tri- deceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate, Tridecylbenzenesulfonic Acid, Trilaureth-9 Citrate, Hydroxypropyl Bis-Hydroxyethylamine Trimethylolpropane Dendrimer, PG-Trisodium Lauroamphoacetate Chloride Phosphate, Undecanoic Acid, Carboxylic Acid Undeceth-5, Undecylenamidopropylamine Oxide, Undecylenamidopropyl Betaine, Undecylenic Acid, Undecylenyl Collagen Amino Acids, Undecylenyl Glycine, Hydrolyzed Undecylenyl Collagen, Undecylenyl Wheat Amino Acids, Undecyl Glucoside, Wheat Germ Acid, Wheat Germamidopropylamine Oxide, Wheat Germamidopropyl Betaine, Yucca Schidigera Leaf/Root/Stem Extract, Yucca Schidigera Stem Extract, Zinc Coceth Sulfate and Zinc Coco-Sulfate.

[0018] In a preferred embodiment according to the invention the percentage content of surfactants in the composition may be from 0.1 to 10% by weight and is preferably from 0.5 to 5% by weight based on this composition. OIL BODIES

[0019] The composition may also contain oily bodies, also called lipids, such as for example: (i) linear or branched saturated paraffins (mineral oils) having 15 or more C atoms, in particular having 18 to 45 C atoms; (ii) esters having 12 or more C atoms, linear or branched fatty acids having 6 to 30 C atoms and linear or branched, saturated or unsaturated mono-, di-, triols having 3 to 45 C atoms, these esters having no free hydroxyl group; (iii) esters of benzoic acid, linear, branched, saturated or unsaturated monoalkanols having 8 to 20 C atoms; (iv) monoesters or diesters of alcohols having 3 to 45 C atoms and naphthalene-monocarboxylic or dicarboxylic acids; especially C6-C18 esters of naphthalene monocarboxylic acid and di-C6-C18 esters of naphthalenedicarboxylic acid; (v) linear or branched di-C6-C18-alkyl ethers, saturated or unsaturated; (vi) silicone oils; (vii) 2-alkyl-1-alkanols of formula (III) where Q1 is a linear or branched alkyl radical having 6 to 24 C atoms and Q2 is a linear or branched alkyl radical having 4 to 16 C atoms.

[0020] An oil phase or oil component in the restricted (and preferred) sense of the present invention, that is to say of the inventively limited substances or substances present only in a minor fraction, encompasses the following groups of substances: (i) linear or branched saturated paraffins having 20 to 32 C atoms; (ii) esters having at least 14 C atoms of linear or branched saturated fatty acids having 8 to 24 C atoms and linear or branched, saturated or unsaturated mono, di or triols having 3 to 24 C atoms, these esters containing no free hydroxyl groups; (iii) esters of benzoic acid and linear and branched, saturated monoalcohols having 10 to 18 C atoms; (iv) alkylenediol dicaprylate caprates especially propylenediol dicaprylate caprate; (v) saturated, branched or lenear di-C6-C18-alkyl ethers, especially (straight chain) di-C6-C12-alkyl ethers; (vi) silicone oils from the group of cyclotrisiloxanes, cyclopentasiloxanes, dimethylpolysiloxanes, diethylpolysiloxanes, methylphenylpolysiloxanes, diphenylpolysiloxanes and hybrid forms thereof; (vii) 2-alkyl-1-alkanols having 12 to 32 C atoms of the formula (III) in which Q1 is a (preferably linear) alkyl radical having 6 to 18 C atoms and Q2 is a (preferably linear) alkyl radical having 4 to 16 C atoms.

[0021] An oil phase in the narrower (and more preferred) sense of the present invention encompasses the following groups of substances: (i) linear or branched saturated paraffins having 20 to 32 C atoms such as isoeicosane or squalane; (ii) esters having at least 16 C atoms of linear or branched saturated fatty acids having 8 to 18 C atoms and linear or branched, saturated mono-, di- or triols having 3 to 18 C atoms, these esters not containing any three hydroxyl groups; (iii) esters of benzoic acid and linear or branched, saturated monoalkanols having 12 to 15 C atoms, especially C12-15-alkyl benzoates; (iv) alkylenediol dicaprylates caprate especially propylenediol dicaprylate caprate; (v) straight chain di-C6-C10-alkyl esters; especially di-n-octyl ether (dicaprilyl ether); (vi) silicone oils of the group undecamethylcyclotrisiloxane, cyclomethicone, decamethylcyclopentasiloxane, dimethylpolysiloxanes, diethylpolysiloxanes, methylphenylpolysiloxanes and diphenylpolysiloxanes; (vii) 2-alkyl-1-alkanols having 12 to 32 C atoms of the formula (III) where Q1 is an alkyl radical (preferably linear) having 6 to 18 C atoms and Q2 is an alkyl radical (preferably linear) having 4 to 16 C atoms.

[0022] Particularly preferred components of type (i) in the oil phase are as follows: isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate, oleyl oleate, oleyl erucate, erucil oleate, erucil erucate, 2-ethylhexyl isostearate, isotridecyl isononanoate, methyl ester ... 2-ethylhexyl, caprylic/capric triglyceride, alkylenediol dicaprylate caprate especially Propylenediol dicaprylate caprate; and also synthetic, semi-synthetic and natural mixtures of such esters, e.g. jojoba oil.

[0023] The fatty acid triglycerides (oily components of type (i) in the oil phase) may also be in the form of, or a constituent of, synthetic, semi-synthetic and/or natural oils, examples being olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and mixtures thereof.

[0024] Particularly preferred oil components of type (vii) in the oil phase are as follows: 2-butyl-1-octanol, 2-hexyl-1-decanol, 2-octyl-1-dodecanol, 2-decyltetradecanol, 2-dodecyl-1-hexadecanol and 2-tetradecyl-1-octadecanol.

[0025] Particularly preferred oil components in the oil phase are mixtures comprising C12-C15-alkyl benzoate and 2-ethylhexyl isostearate, mixtures comprising C12-C15-alkyl benzoate and isotridecyl isononanoate, mixtures comprising C12-C15-alkyl benzoate, 2-ethylhexyl isostearate and isotridecyl isononanoate, mixtures comprising cyclomethicone and isotridecyl isononanoate, and mixtures comprising cyclomethicone and 2-ethylhexyl isostearate.

[0026] Preferred oil bodies, which form constituents of the O/W emulsions, are, for example, Guerbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of C6-C22-linear fatty acids with C6-C22-linear or branched fatty alcohols or esters of C6-C13-branched carboxylic acids with C6-C22-linear or branched fatty alcohols, such as, for example, myristyl myristate, myristyl palmitate, amyristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, Cetyl myristate, Cetyl palmitate, Cetyl stearate, Cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, oleyl myristate, behenyl palmitate, behenyl, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucil myristate, erucil palmitate, erucil stearate, erucil isostearate, erucil oleate, erucil behenate and erucil erucate. Also suitable are esters of C6-C22-alkyl hydroxy acids with branched alcohols, in particular 2-ethylhexanol, esters of C18-C38-alkyl hydroxy carboxylic acids with linear or branched C6-C22-fatty alcohols, in particular dioctyl malate, esters of linear and/or branched fatty acids with polyhydric alcohols (such as, for example, propylene glycol, dimerdiol or trimertriol) and/or Guerbet alcohols, triglycerides based on C6-C10-fatty acids, liquid mono-/di-/triglyceride mixtures based on C6-C18-fatty acids, esters of C6-C22-fatty alcohols and/or Guerbet alcohols with aromatic carboxylic acids, in particular, benzoic acid esters of C2-C12-carboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, lenear or branched C6-C22-fatty alcohol carbonates such as, for example, dicaprylyl carbonate (Cetiol®CC), Guerbet carbonates based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, benzoic acid esters with linear and/or branched C6-C22-alcohols (e.g. Finsolv®TN), linear or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as, for example, dicaprylyl ether (Cetiol®OE), ring-opened products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicones, silicone methicone grades, etc.) and/or aliphatic or nphthalenic hydrocarbons, such as, for example, squalane, squalene or dialkylcyclohexanes.

EMULSIFIERS

[0027] Other nonionic or cationic surfactants may also be added to the preparations as emulsifiers, including, for example: • addition products of 2 to 30 mol of ethylene oxide and/or 0 to 5 mol of propylene oxide on C8-22 linear fatty alcohols, on C12-22 fatty acids and on alkyl phenols containing 8 to 15 carbon atoms in the alkyl group; • C12/18 fatty acid monoesters and diesters of addition products of 1 to 30 mol of ethylene oxide on glycerol; • glycerol mono- and diesters and sorbitan mono- and diesters of saturated and unsaturated fatty acids containing 6 to 22 carbon atoms and ethylene oxide addition products thereof; • addition products of 15 to 60 mol of ethylene oxide on castor oil and/or hydrogenated castor oil; • polyol esters and in particular polyglycerol esters such as, for example, polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimerate isostearate. Mixtures of compounds of several of these classes are also suitable; • addition products of 2 to 15 mol of ethylene oxide on castor oil and/or hydrogenated castor oil; • partial esters based on C6/22 linear, branched, unsaturated or saturated fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (e.g. sorbitol), alkyl glycosides (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) and polyglycosides (e.g. cellulose); • mono-, di- and trialkyl phosphates and mono-, di- and/or tri-PEG-alkyl phosphates and salts thereof; • wool wax alcohols; • corresponding polysiloxane/polyalkyl polyether copolymers and derivatives; • mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol and/or mixed esters of C6-22 fatty acids, methyl glucose and polyols, preferably glycerol or polyglycerol, • polyalkylene glycols and • glycerol carbonate.

[0028] The addition products of ethylene oxide and/or propylene oxide on fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or on castor oil are known commercially available products. They are homologous mixtures of which the average degree of alkoxylation corresponds to the ratio between the amounts of ethylene oxide and/or propylene oxide and substrate with which the addition reaction is carried out. The C12/18 fatty acid monoesters and diesters of ethylene oxide addition products on glycerol are known as lipid layer enhancers for cosmetic formulations. Preferred emulsifiers are described in more detail as follows:

[0029] Partial Glycerides. Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid glyceride, isostearic acid monoglyceride, stearic acid glyceride, oleic acid monoglyceride, oleic acid glyceride, ricinoleic acid monoglyceride, ricinoleic acid glyceride, linoleic acid monoglyceride, linoleic acid glyceride, linolenic acid monoglyceride, linolenic acid glyceride, erucic acid monoglyceride, erucic acid glyceride, tartaric acid monoglyceride, tartaric acid glyceride, citric acid monoglyceride, citric acid glyceride, malic acid monoglyceride, malic acid glyceride and technical mixtures which may still contain small amounts of triglyceride from the production process. Addition products of 1 to 30 and preferably 5 to 10 mol of ethylene oxide to the partial glycerides mentioned are also suitable.

[0030] Sorbitan esters. Suitable sorbitan esters are sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diricinoleate, sorbitan triricinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan monotartrate, sorbitan monoisostearate ... sorbitan, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and technical mixtures thereof. Addition products of 1 to 30 and preferably 5 to 10 mol of ethylene oxide on the sorbitan esters mentioned are also suitable.

[0031] Polyglycerol esters. Typical examples of suitable polyglycerol esters are Polyglyceryl-2 Dipolyhydroxystearate (Dehymuls®PGPH), Polyglyceryl-3-Diisostearate (Lameform®TGI), Polyglyceryl-4 Isostearate (Isolan®GI 34), Polyglyceryl-3 Oleate, Polyglyceryl -3 Diisostearyl Diisostearate (Isolan®PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care®450), Polyglyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010/90), Polyglyceryl -3 Cetyl Ether (Chimexane®NL), Polyglyceryl-3 Distearate (Cremophor®GS 32) and Polyglyceryl Polyricinoleate (Admul®WOL 1403), Polyglyceryl Isostearate Dimerate and mixtures thereof. Examples of other suitable polyolesters are mono-, di- and triesters of trimethylol propane or pentaerythritol with lauric acid, coco-fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like optionally reacted with 1 to 30 mol of ethylene oxide.

[0032] Tetraalkyl Ammonium Salts. Cationically active surfactants comprise the hydrophobic high molecular weight group required for surface activity on the cation upon dissociation in aqueous solution. An important representative group of cationic surfactants are the tetraalkyl ammonium salts of the general formula: (R1R2R3R4N+)X-. Here, R1 stands for C1-C8 alkyl(en)yl, R2, R3 and R4, independently of each other, for alkyl(en)yl radicals having 1 to 22 carbon atoms. X is a counterion, preferably selected from the group of halides, alkyl sulfates and alkyl carbonates. Cationic surfactants, in which the nitrogen group is replaced by two long acyl groups and two short alkyl(en)yl groups, are particularly preferred.

[0033] Esterquates. Another class of cationic surfactants particularly useful as co-surfactants for the present invention is represented by the so-called esterquates. Esterquates are generally intended to be triethanolamine ester salts of quaternized fatty acids. These are known compounds which can be obtained by the relevant methods of preparative organic chemistry. Reference is made in this connection to International Patent Application WO 91/01295 A1, according to which triethanolamine is partially esterified with fatty acids in the presence of hypophosphorous acid, air is passed through the reaction mixture and the whole is then quaternized with dimethyl sulfate or ethylene oxide. Furthermore, Almâ Patent DE 4308794 C1 describes a process for the production of esterquates in which the quaternization of triethylamine esters is carried out in the presence of suitable dispersants, preferably fatty alcohols.

[0034] Typical examples of esterquates suitable for use according to the invention are products of which the acyl component originates from monocarboxylic acids corresponding to the formula RCOOH wherein RCO is an acyl group containing 6 to 10 carbon atoms, and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof such as, for example, the so-called head-fractionated fatty acid. Esterquates of which the acyl component originates from monocarboxylic acids containing 8 to 10 carbon atoms are preferably used. Other esterquates are those in which the acyl component originates from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and/or dodecanedioic acid, but preferably adipic acid. In general, esterquates in which the acyl component originates from mixtures of monocarboxylic acids containing 6 to 22 carbon atoms, and adipic acid are preferably used. The molar ratio of mono- and dicarboxylic acids in the final esterquate may be in the range of 1:99 to 99:1 and is preferably in the range of 50:50 to 90:10 and more particularly in the range of 70:30 to 80:20. In addition to the quaternized fatty acid triethanolamine ester salts, other esterquates are quaternized ester salts of mono-/dicarboxylic acid mixtures with diethanolalkylamines or 1,2-dihydroxypropyldialkylamines. The esterquates can be obtained both from fatty acids and from the corresponding triglycerides in mixture with the corresponding dicarboxylic acids. Such a process, which is intended to be representative of the relevant prior art, is set forth in European Patent EP 0750606 B1. To produce the quaternized esters, mixtures of mono- and dicarboxylic acids and triethanolamine - based on the available carboxyl moieties - can be used in a molar ratio of 1.1:1 to 3:1. With the performance properties of esterquates in mind, a ratio of 1.2:1 to 2.2:1 and preferably 1.5:1 to 1.9:1 has proven to be particularly advantageous. The preferred esterquates are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9.

[0035] The use of a combination of anionic and/or amphoteric surfactants with one or more non-ionic surfactants is also advantageous. In a preferred embodiment according to the invention, the composition also comprises emulsifiers selected from the group consisting of: • Alkyl phosphate derivatives • Glyceryl oleate citrate derivatives • Glyceryl stearate citrate derivatives • Stearic acid esters • Sorbitan esters • Ethoxylated sorbitan esters • Ethoxylated mono-, di- and tri-glycerides • Methyl glucose esters

SUPERFATTING AGENTS AND CONSISTENCY FACTORS

[0036] The superfatting agents can be selected from such substances as, for example, lanolin and lecithin and, furthermore, polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, the fatty acid alkanolamides also serving as foam stabilizers.

[0037] The mainly used consistency factors are fatty alcohols or fatty hydroxyalcohols containing 12 to 22 and preferably 16 to 18 carbon atoms and also partial glycerides, fatty acids or hydroxyfatty acids. A combination of these substances with alkyl oligoglycosides and/or fatty acid N-methyl glucamides of the same chain length and/or polyglycerol poly-12-hydroxystearates is preferably used.

THICKENING AGENTS AND RHEOLOGY ADDITIVES

[0038] Suitable thickeners are polymeric thickeners such as Aerosil® types (hydrophilic silicas), polysaccharides, more especially xanthan gum, guar-guar, agar-agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, furthermore relatively high molecular weight polyethylene glycol monoesters and fatty acid diesters, polyacrylates (e.g. Carbopols® [Goodrich] or Synthalens® [Sigma]), polyacrylamides, polyvinyl alcohol and polyvinyl pyrrolidone, surfactants such as, for example, ethoxylated fatty acid glycerides, fatty acid esters with polyols, for example pentaerythritol or trimethylol propane, electrolytes and narrow-range fatty alcohol ethoxylates such as sodium chloride and ammonium chloride.

POLYMERS

[0039] Polymers suitable for improving the spreading of the composition over the skin or hair, or improving the water and/or sweat and/or rubbing resistance of the formula and improving the protection factor of the composition. Examples of such polymers are: VP/Eicosene copolymers sold under the trade name Antaron V-220 by International Speciality Products, VP/Hexadecene copolymer sold under the trade names Antaron V-216 and Antaron V-516 by International Speciality Products, Tricontanyl PVP sold under the trade name Antaron WP-660 by International Speciality Products, Isohexadecane and Ethylene/Propylene/Styrene copolymer and Butylene/Styrene copolymer sold under the trade names Versagel MC and MD by Penreco, Hydrogenated Polyisobutene and Ethylene/Propylene/Styrene copolymer and Butylene/Styrene copolymer sold under the trade name Versagel ME by Penreco, Acrylates/Octylacrylamide Copolymers sold under the trade names Dermacryl 79, Dermacryl AQF and Dermacril LT by AkzoNobel, Polyurethanes such as PPG-17/IPDI/DMPA copolymer sold under the trade name Avalure UR 450 & 525 sold by Noveon, Polyurethanes-2 and -4 sold under the trade names Avalure UR-405, -410, - 425, - 430 and - 445 525 sold by Noveon, Polyurethane 5 and Butyl Acetate and Isopropyl Alcohol sold under the trade names Avalure UR - 510 and - 525 sold by Noveon, Polyurethanes -1 and - 6 sold under the trade name Luviset PUR by BASF, Dimethylcarbonate/Hydrogenated Dilinoleyl Dimer copolymer sold under the trade name Cosmedia DC by Cognis.

[0040] Of course, as one skilled in the art knows, the dermatological and pharmacological compositions are not an exhaustive list and other suitable polymers not listed here may be used. Examples of such polymers can be found in the latest edition of the CTFA International Cosmetic Ingredient Dictionary.

[0041] The amount of polymers used to obtain the desired effect in the formulation range from 0.10% to 5.0% by weight of the composition and especially in the range from 0.25% to 3.0% by weight of the composition.

PEARLING WAXES

[0042] Suitable pearlizing waxes are, for example, alkylene glycol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially cocofatty acid diethanolamide; partial glycerides, especially stearic acid monoglyceride; esters of polybasic carboxylic acids, optionally hydroxysubstituted with fatty alcohols containing 6 to 22 carbon atoms, especially long-chain tartaric acid esters; fatty compounds, such as, for example, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates containing in total at least 24 carbon atoms, especially laurone and distearyl ether; fatty acids, such as stearic acid, hydroxystearic acid or behenic acid, ring-opened products of olefin epoxides containing 12 to 22 carbon atoms with fatty alcohols containing 12 to 22 carbon atoms and/or polyols containing 2 to 15 carbon atoms and 2 to 10 hydroxyl groups and mixtures thereof.

SILICONES

[0043] Suitable silicones may be chosen from the group consisting of: Acetylmethylsilanol Mannuronate, Acetylmethionyl Methylsilanol Elastinate/Behenyl Acrylates, Acrylate/Dimethicone Methacrylate Copolymer, Acrylates/Behenyl Methacrylate/Dimethicone Methacrylate Copolymer, Acrylates/Bis-Hydroxypropyl Dimethicone Crosspolymer, Acrylates/Dimethicone Copolymer, Acrylates/Dimethicone Methacrylate/Ethylhexyl Acrylate Copolymer, Acrylates/Dimethiconol Acrylate Copolymer, Acrylates/Ethylhexyl Acrylate/Dimethicone Methacrylate Copolymer, Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer, Acrylates/Polytrimethylsiloxymethacrylate, Acrylates/Propyl Trimethicone Methacrylate Copolymer, Acrylates/Stearyl Acrylate/Dimethicone Methacrylate Copolymer, Acrylates/Tridecyl Acrylate/Triethoxysilylpropyl Methacrylate/Dimethicone Methacrylate Copolymer, Acrylates/Trifluoropropylmethacrylate Copolymer Crylate/Polytrimethyl Siloxymethacrylate, Amino Bispropyl Dimethicone, Aminoethylaminopropyl Dimethicone, Aminopropyl Dimethicone, Aminopropyl Phenyl Trimethicone, Aminopropyl Triethoxysilane, PEG-7 Dimethicone Ammonium Sulfate, Amodimethicone, Amodimethicone Hydroxystearate, Amodimethicone/Silsesquioxane Copolymer, boxidecyl trisiloxane, Ascorbyl Methylsilanol Pectinate, Behenoxy Dimethicone, Behentrimonium Dimethicone Phthalate PEG-8, Behenyl Dimethicone, Bisamino PEG/PPG-41/3 Aminoethyl PG-Propyl Dimethicone, Bis-Aminopropyl/Ethoxy Aminopropyl Dimethicone, Bis(Butylbenzoate) Diaminotriazine Aminopropyltrisiloxane, Butyldimethicone Polyglyceryl-3, Bis-Butyloxymodimethicone/PEG-60 Copolymer, Bis(C13-15 Alkoxy) Hydroxybutamidoamodimethicone, Bis(C13-15 Alkoxy) PG- Amodimethicone, Bis-(C1-8 Alkyl Lauroyl Lysine Decylcarboxamide) Dimethicone, Bis-Cethyl Cetyl , Bis-Cetyl/PEG-8 Cetyl PEG-8 Dimethicone, Bis-Diphenylethyl Disiloxane, Bis-Ethyl Ethyl Methicone, Bis-Gluconamidoethylaminopropyl Dimethicone, Bis-Hydrogen Dimethicone, Bis-Hydroxyethoxypropyl Dimethyl in Bis-Hydroxylauryl, Dimethicone/IPDI Copolymer, Bis-Hydroxy/Methoxy Amodimethicone, Bis-Hydroxypropyl Dimethicone Behenate, Bis-Hydroxypropyl Dimethicone/SMDI Copolymer, Bis-Isobutyl PEG-14/Amodimethicone Copolymer, Bis-Isobutyl PEG-15/Amodimethicone Copolymer, Bis-Isobutyl PEG/PPG-20/35/Amodimethicone Copolymer, Bis-Isobutyl PEG/PPG-10/7/Dimethicone, Bis-Isobutyl PEG-24/PPG-7/Dimethicone Copolymer, Bis-PEG-1 Dimethicone, Bis-PEG-4 Dimethicone, Bis-PEG-8 Dimethicone, Bis-PEG-12 Dimethicone, Bis-PEG-20 Dimethicone, Bis-PEG-12 Dimethicone Beeswax, Bis-PEG-12 Dimethicone Candelillate, Bis-PEG-15 Dimethicone/IPDI Copolymer, Bis-PEG-15 Methyl Ether Dimethicone, Bis-PEG-18 Methyl Ether Dimethyl Silane, Bis-PEG/PPG-14/14 Dimethicone, Bis-PEG/PPG-15/5 Dimethicone, Bis-PEG/PPG-18/6 Dimethicone, Bis-PEG/PPG-20/20 Dimethicone, Bis-PEG/PPG-16/16 PEG/PPG-16/16 Dimethicone, Bis-PEG/PPG-20/5 PEG/PPG-20/5 Dimethicone, Bisphenylhexamethicone, Bis-Phenylpropyl Dimethicone, Bis-(Polyglyceryl-3) Dimethicone, Bis-(Polyglyceryl-7 Oxyphenylpropyl) Dimethicone, Bis-PPG-15 Dimethicone/IPDI Copolymer, Bis(PPG-7 Undeceneth-21) Dimethicone, Bis-Stearyl Dimethicone, Bis-Trimethoxysilylethyl Tetramethyldisiloxyethyl Dimethicone, Bis-Vinyldimethicone, Bis- Vinyl Dimethicone/Dimethicone, Borage Seed Oil PEG-7 Dimethicone Esters, Butyl Acrylate/C6-14 Perfluoroalkylethyl Acrylate/Mercaptopropyl Dimethicone Copolymer, Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer, Butyl Dimethicone Acrylate/Cyclohexylmethacrylate/Ethylhexyl A Crylate Copolymer, Dimethicone Butylmethacrylate/Methyl Methacrylate Cross-Polymer, Grape Seed Extract t-Butyl Dimethyl SiIIia, Butyl Polydimethylsiloxy Ethylene/Propylene/Vinylnorbornene Copolymer, C6-8 Alkyl C3-6 Alkyl Glycoside Dimethicone, C20-24 Alkyl Dimethicone,C24-28 Alkyl Dimethicone, C26-28 Alkyl Dimethicone, C30-45 Alkyl Dimethicone, C30-60 Alkyl Dimethicone, C32 Alkyl Dimethicone, C30-45 Alkyl Dimethicone/Polycyclohexene Oxide Crosspolymer, C26-28 Alkyldimethylsilyl Polypropylsilsesquioxane, C30-45 Alkyldimethylsilyl Polyprop ilsilsesquioxane, C20-24 Alkyl Methicone, C24-28 Alkyl Methicone, C26-28 Alkyl Methicone, C30-45 Alkyl Methicone, C20-28 Alkyl Perfluorodecylexy Dimethicone, C26-54 Alkyl Tetradecyl Dimethicone, Capryl Dimethicone, Caprylyl Dimethicone Ethoxy Glucoside, Caprylyl Methicone, Caprylyl Trimethicone, Carboxidecyl Trisiloxane, Cerothyl Dimethicone Esters Castor Oil Bis-Hydroxypropyl Dimethicone, Cetearyl Dimethicone Cross-Polymer, Cetearyl Dimethicone/Vinyl Dimethicone Cross-Polymer, Cetearyl Methicone, PEG-8 Dimethicone Cetrimonium Carboxide Scylla, Cetrimonium Phthalate Dimethicone PEG-7, Cetyl Behenyl Dimethicone, Cetyl Dimethicone, Cetyl Dimethicone/Bis-Vinyl Methicone Crosspolymer, Cetyl Hexacosyl Dimethicone, Cetyloxy Dimethicone, Cetyl PEG-8 Dimethicone, Cetyl PEG/PPG- 15/15 Butyl Ether Dimethicone, Cetyl PEG/PPG-7/3 Dimethicone, Cetyl PEG/PPG-10/1 Dimethicone, Cetyl Triethylmonium Phthalate Dimethicone PEG-8, Cetyl Triethylmonium Dimethicone Succinate PEG-8, Acetyl Tyrosinate Copper Methylsilanol, PCA Copper Methylsilanol, C4-14 Perfluoroalkylethoxy Dimethicone, Cycloethoxymethicone, Cloheptasiloxane, Cyclohexasiloxane, Cyclomethicone, Cyclopentasiloxane, Cyclophenylmethicone, Cyclotetrasiloxane, Cyclovinylmethicone, Cysteine Bis-PG-Propyl Silanetriol, DEA PG-Propyl PEG/PPG-18/21 Dimethicone, Diisostearyl Trimethylolpropane Siloxy Silicate, Dilauroyl Trimethylol Silicate propane Siloxy, Dimethicone PEG-7 Dilinoleamidopropyl Dimethylamine Phosphate, Dimethicone, Dimethicone Crosspolymer, Dimethicone Crosspolymer-3, Dimethicone/Divinyldimethicone/Silsesquioxane Crosspolymer, Dimethicone Ethoxyglucoside, Dimethicone Hydroxypropyl Trimonium Chloride, Dimethicone/Mercaptopropyl Methicone Copolymer, Dimethicone PEG-8 Dimethicone Adipate PEG-15 Dimethicone Acetate, PEG-7 Dimethicone Avocadoate, PEG-8 Dimethicone Avocadoate, PEG-8 Dimethicone Beeswax, PEG-8 Dimethicone Benzoate, PEG-8 Dimethicone Borageate, PEG-7 Dimethicone Cocoate, Polymer Dimethicone/PEG-10 Cross, Dimethicone/PEG-10/15 Cross Polymer, Dimethicone/PEG-15 Cross Polymer, PEG-7 Dimethicone Isostearate, PEG-8 Dimethicone Isostearate, PEG-7 Dimethicone Lactate, PEG-8 Dimethicone Lanolate, PEG-8 Dimethicone Laurate, Dimethicone PEG-8 Meadowfoamate, Octyldodecyl Dimethicone Citrate PEG-7, Dimethicone Olivate PEG-7, Dimethicone Olivate PEG-8, Dimethicone Phosphate PEG-7, Dimethicone Phthalate PEG-8, Dimethicone Phthalate PEG-10, Dimethicone Phthalate PEG-8, PEG-8 Dimethicone Polyacrylate, PEG/PPG-20/23 Dimethicone Benzoate, PEG/PPG-7/4 Dimethicone Phosphate, PEG/PPG-12/4 Dimethicone Phosphate, PEG-7 Dimethicone Succinate, PEG-8 Dimethicone Succinate, PEG-7 Dimethicone Sulphate, Dimethicone Undecylenate PEG-7, Dimethicone PG-Diethylmonium Chloride, Dimethicone/Phenyl Vinyl Dimethicone Cross-Polymer, Dimethicone/Polyglycerin-3 Cross-Polymer, Dimethicone/PPG-20 Cross-Polymer, Dimethicone Propylethylenediamine Behenate, Dimethicone Propyl PG-Betaine, Dimethicone Copolymer Dimethicone/Silsesquioxane, Dimethicone Silylate, Dimethicone/Vinyl Dimethicone Crosspolymer, Dimethicone/Vinyltrimethylsilyloxysilicate Crosspolymer, Dimethiconol, Dimethiconol Arginine, Dimethiconol Beeswax, Dimethiconol Behenate, Dimethiconol Borageate, Dimethiconol Candelylate, Dimethicone Dimethiconol, Dimethiconol Cysteine, Dimethiconol Dhupa Butter, Dimethiconol Dilinoleic Acid Fluoroalcohol, Dimethiconol Hydroxystearate, Dimethiconol Illipé Burterate, Dimethiconol/IPDI Copolymer, Dimethiconol Isostearate, Dimethiconol Kokum Butter, Dimethiconol Lactate Dimethiconol, Dimethiconol Meadowfoamate, Dimethiconol Methionine, Dimethiconol/Methylsilanol/Silicate Crosspolymer, Dimethiconol Mohwa Butyrate, Dimethiconol Panthenol, Dimethiconol Salt Butterate, Dimethiconol/Silica Crosspolymer, Dimethiconol/Silsesquioxane Copolymer, Dimethiconol Stearate, Dimethiconol/Stearyl, Methicone/Phenyl Trimethicone Copolymer, Dimethoxysilyl Ethylenediaminopropyl Dimethicone, Dimethylaminopropyl Starch PCA Dimethicone, Dimethyl Oxobenzodioxasilane, Dimethylsilanol Hyaluronate, Dioleyl Tocopheryl Methylsilanol, Diphenyl Amodimethicone, Diphenyl Dimethicone, Diphenyl Crosspolymer Dimethicone/Vinyl Diphenyl Dimethicone/Diphenyl Dimethicone Crosspolymer Silsesquioxane, Diphenylethyl Benzyloxy Dilsiloxane, Diphenylisopropyl Dimethicone, Diphenylsiloxy Phenyl/Propyl Trimethicone, Diphenylsiloxy Phenyl Trimethicone Dissiloxane, Amodimethicone Disodium Dissuccinamide, PEG Sulfosuccinate -12 Dimethicone Disodium, PEG-8 Lauryl Dimethicone Sulfosuccinate Disodium, Divinyldimethicone/Dimethicone Copolymer, Divinyldimethicone/Dimethicone Crosspolymer, Drometrizol Trisiloxane, Ethylhexyl Acrylate/VP/Dimethicone Methacrylate Copolymer, Ethyl Methicone, Ethyl Trisiloxane, Fluoro C2-8 Al kyldimethicone, Gluconamidopropyl Aminopropyl Dimethicone, 4-(2-Beta-Glucopyranosyloxy)Propoxy-2-Hydroxybenzophenone, Glyceryl Undecyl Dimethicone, Glycidoxy Dimethicone, Hexadecyl Methicone, Hexyl Dimethicone, Hexyl Methicone, Hexyltrimethoxysilane, Hydrogen Dimethicone, Hydrogen Dimethicone/Octyl Silsesquioxane Copolymer, PG-Propyl Dimethiconol from Hydrolyzed Collagen, PG-Propyl Methylsilanediol from Hydrolyzed Collagen, PG-Propyl Silanetriol from Hydrolyzed Collagen, PG-Propyl Methylsilanediol from Hydrolyzed Keratin, Hydrolyzed Sesame Protein PG-Propyl Methylsilanediol, PG-Propyl Methylsilanediol from Silk Hydrolyzed, Hydrolyzed Silk PG-Propyl Methylsilanediol Crosspolymer, Hydrolyzed Soy Protein/Dimethicone PEG-7 Acetate, Hydrolyzed Soy Protein PG-Propyl Methylsilanediol, Hydrolyzed Plant Protein PG-Propyl Silanetriol, Hydrolyzed Wheat Protein/Cystine Bis-PG-Propyl Silanetriol Copolymer, Hydrolyzed Wheat Protein/PEG-7 Dimethicone Acetate, Hydrolyzed Wheat Protein/PEG-7 Dimethicone Phosphate Copolymer, Hydrolyzed Wheat Protein PG-Propyl Methylsilanediol, Hydrolyzed Wheat Protein PG-Propyl Silanetriol, Hydroxyethyl Acetomonium PG-Dimethicone, Hydroxypropyldimethyl- cona, Hydroxypropyl Dimethicone Behenate, Hydroxypropyl Dimethicone Isostearate, Hydroxypropyl Dimethicone Stearate, Isobutyl Methacrylate/Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isobutyl Methacrylate/Trifluoroethyl Methacrylate/Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isopentyl Trimethoxycinnamate Trisiloxane, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropyl Titanium Triisostearate/Triethoxysilylethyl Dimethicone Crosspolymer, Isostearyl Carboxydecyl PEG-8 Dimethicone, Elastinate Lactoyl Methylsilanol, Lauryl Dimethicone, PEG-15 Lauryl Crosspolymer Dimethicone, PEG-10 Lauryl Dimethicone Phosphate, Lauryl Dimethicone/Polyglycerin-3 Cross-Polymer, Lauryl Methicone, Lauryl PEG-8 Dimethicone, Lauryl PEG-10 Methyl Ether Dimethicone, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Lauryl PEG/PPG-18/18 Methicone, Lauryl Phenylysopropyl Methicone na, Lauryl Phenylpropyl Methicone, Lauryl Polydimethylsiloxyethyl Dimethicone/Bis-Vinyldimethicone Cross Polymer, Lauryl Polyglyceryl- 3 Polydimethylsiloxyethyl Dimethicone, Lauryl Trimethicone, Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone, Methacryloyl Propyltrimethoxysilane, Methicone, Methoxy Copolymer Amodimethicone/Silsesquioxane, Methoxycinnamidopropyl Polysilsesquioxane, Methoxycinnamoylpropyl Silsesquioxane Silicate, Methoxy PEG-13 Ethyl Polysilsesquioxane, Methoxy PEG/PPG-7/3 Aminopropyl Dimethicone, Methoxy PEG/PPG-25/4 Dimethicone, Methoxy PEG-10 Propyltrimethoxysilane, Methyleugenyl PEG-8 Dimethicone, Methylpolysiloxane Emulsion, Methylsilanol Acetyl Methionate, Methylsilanol Acetyl Tyrosine, Methylsilanol Ascorbate, Methylsilanol Carboxymethyl Theophylline, Carboxymethyl Theophylline Alginate Methylsilanol, Methylsilanol Elastinate, Methylsilanol Glycyrrhizinate, Methylsil Hydroxyproline lanol, Hydroxyproline Methylsilanol Asparate, Methylsilanol Mannuronate, Methylsilanol PCA, PEG-7 Methylsilanol Glyceryl Cocoate, Methylsilanol/Silicate Cross Polymer, Methylsilanol Spirulinate, Tri-PEG-8 Methylsilanol Glyceryl Cocoate, Methyl Trimethicone, Methyltrimethoxysilane, PEG-7 Myristylamidopropyl Dimethylamine Dimethicone, Myristyl Methicone, Myristyl Trisiloxane, Nylon-611/Dimethicone Copolymer, PCA Dimethicone, PEG-7 Amodimethicone, PEG-8 Amodimethicone, PEG-8 Cetyl Dimethicone, PEG-3 Dimethicone, PEG-6 Dimethicone, PEG-7 Dimethicone, PEG-8 Dimethicone, PEG-9 Dimethicone, PEG-10 Dimethicone, PEG-12 Dimethicone, PEG-14 Dimethicone, PEG-17 Dimethicone, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoleate, PEG-8 Dimethicone/Dimer Dilinoleic Acid Copolymer, PEG-10 Dimethicone/Vinyl Dimethicone Crosspolymer, PEG-8 PG-Dimethicone Disteharmonium Chloride, PEG-10/Lauryl Dimethicone Crosspolymer, PEG-15/Lauryl Dimethicone Crosspolymer, PEG-15/Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, PEG-8 Methicone, PEG-6 Methicone Acetate, PEG-6 Dimethicone Methyl Ether, PEG-7 Dimethicone Methyl Ether, PEG-8 Dimethicone Methyl Ether, PEG-9 Dimethicone Methyl Ether, PEG-8 Dimethicone Methyl Ether ter Triethoxysilane, PEG-10 Nonafluorohexyl Dimethicone Copolymer, PEG-4 PEG-12 Dimethicone, PEG-8 PG-Coco-Glycoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG/PPG-20/22 Butyl Ether Dimethicone, PEG/PPG-22/22 Butyl Ether Dimethicone, PEG/PPG-23/23 Butyl Ether Dimethicone, PEG/PPG-24/18 Butyl Ether Dimethicone, PEG/ PPG-27/9 Butyl Ether Dimethicone, PEG/PPG-3/10 Dimethicone, PEG/ PPG-4/12 Dimethicone, PEG/PPG-6/4 Dimethicone, PEG/PPG-6/11 Dimethicone, -8/14 Dimethicone, PEG/PPG-8/26 Dimethicone, PEG/PPG-10/2 Dimethicone, PEG/PPG-12/16 Dimethicone, PEG/PPG-12/18 Dimethicone, PEG/PPG-14/4 Dimethicone, PEG/PPG-15/5 Dimethicone, PEG/PPG-15/15 Dimethicone, PEG/PPG-16/2 Dimethicone, PEG/PPG-16/8 Dimethicone, PEG/PPG-17/18 Dimethicone, PEG/PPG-18/6 Dimethicone, PEG/PPG-18/12 Dimethicone, PEG/PPG-20/6 Dimethicone , PEG/ PPG-20/15 Dimethicone, PEG/PPG-20/20 Dimethicone, PEG/PPG-20/23 Dimethicone, PEG/PPG-20/29 Dimethicone, PEG/PPG-22/23 Dimethicone, PEG/PPG-22/24 Dimethicone, PEG/PPG-23/6 Dimethicone, PEG/ Dimethicone, PEG/PPG-27/27 Dimethicone, PEG/PPG-30/10 Dimethicone, PEG/PPG-25/25 Dimethicone/Acrylates Copolymer, PEG/ PPG-20/22 Methyl Ether Dimethicone, PEG/PPG-24/24 Methyl Ether Glycidoxy Dimethicone, PEG/PPG-10/3 Oleyl Ether Dimethicone, PEG/PPG-5/3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorocaprylyl Ethoxysilylethyl Methicone, Perfluorononyl Dimethicone, Perfluorononyl Crosspolymer Dimethicone/Methicone/Amodimethicone, Perfluorononylethyl Carboxy decyl Behenyl Dimethicone, Perfluorononylethyl Carboxidecyl Hexacosyl Dimethicone, Perfluorononylethyl Carboxidecyl Lauryl/Behenyl Dimethicone, Perfluorononylethyl Carboxidecyl Lauryl Dimethicone, Perfluorononylethyl Carboxidecyl PEG-8 Dimethicone, Perfluorononylethyl Carboxidecyl PEG-10 na, Perfluorononylethyl Dimethicone/Methicone Copolymer, Perfluorononylethyl PEG-8 Dimethicone, Perfluorooctylethyl Stearyl Dimethicone, Perfluorooctylethyl/Diphenyl Dimethicone Copolymer, Perfluorooctylethyl Triethoxysilane, Perfluorooctylethyl Trimethoxysilane, Perfluorooctylethyl Trisiloxane, Perfluorooctyl Triethoxysilane, Phenethyl Dimethicone, Phenethyl Dissiloxane, Phenyl Dimethicone, Phenylisopropyl Dimethicone, Phenyl Methicone, Phenyl Methiconol, Phenylpropyldimethylsiloxysilicate, Phenylpropyl Ethyl Methicone, Phenyl Propyl Trimethicone, Phenyl Propyl Trimethicone/Diphenylmethicone, Phenyl Trimethicone, Platinum Divinyldisiloxane, Polyacrylate-6, year, Polydimethylsiloxyethyl Dimethicone/Bis-Vinyldimethicone Cross Polymer, Polydimethylsiloxyethyl Dimethicone/Methicone Copolymer, Polydimethylsiloxy PEG/PPG-24/19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG- 13 Butyl Ether Silsesquioxane, Polyglyceryl-3 Dissiloxane Dimethicone, Polymer Polyglyceryl-3/Lauryl Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Dimethicone Poly(Glycol Adipate)/Bis-Hydroxyethoxypropyl Copolymer, Polymethylsilsesquioxane, Polymethylsilsesquioxane/Trimethylsiloxysilicate, Polyphenylsilsesquioxane, Polypropylsilsesquioxane , Polysilicone-1, Polysilicone-2, Polysilicone-3, Polysilicone-4, Polysilicone-5, Polysilicone-6, Polysilicone-7, Polysilicone-8, Polysilicone-9, Polysilicone-10, Polysilicone-11, Polysilicone-12, Polysilicone-13, Polysilicone-14, Polysilicone-15, Polysilicone-16, Polysilicone-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysilicone-21, Polysilicone Cetyl Phosphate-18, Polysilicone Cross-Polymer-1, Polysilicone Stearate-18, Polyurethane-10, Potassium Dimethicone PEG-7 Panthenyl Phosphate, Potassium Dimethicone PEG- 7 Phosphate, PPG-12 Butyl Ether Dimethicone, PPG-2 Dimethicone, PPG-12 Dimethicone, PPG- 27 Dimethicone, PPG-4 Oleth-10 Dimethicone, Propoxytetramethyl Piperidinyl Dimethicone, Propyl Trimethicone, Quaternium-80, Retinoxytrimethylsilane, Silanediol Salicylate, Silanetriol, Arginate Silanetriol, Glutamate Silanetriol, Silanetriol Lysinate, Silanetriol Melaninate, Silanetriol Trehalose Ether, Silica, Dimethicone Silylate, Silica Dimethyl Silylate, Silica Silylate, Silicon Carbide, Silicone Quaternium-1, Silicone Quaternium-2, Silicone Quaternium-2 Panthenol Succinate, Silicone Quaternium-3, Silicone Quaternium-4, Silicone Quaternium-5, Silicone Quaternium-6, Silicone Quaternium-7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, Silicone Quaternium-16, Silicone Quaternium-16/Glycidoxy Dimethicone Crosspolymer, Silicone Quaternium-17, Silicone Quaternium-18, Silicone Quaternium-19, Silicone Quaternium-20, Silicone Quaternium-21, Silicone Quaternium-22, Silicone Quaternium-24, Silicone Quaternium-25, Siloxanetriol Alginate, Siloxanetriol Phytate, Simethicone, PEG-8 Sodium Carboxydecyl Dimethicone, PEG-7 Sodium Dimethicone Acetyl Methyltaurate, Sodium Hyaluronate Dimethylsilanol, Sodium Lactate Methylsilanol, Sodium Mannuronate Methylsilanol, PCA Sodium Methylsilanol, PG-Propyldimethicone Sodium Thiosulphate Copolymer, PG-Propyl Thio- Sodium Sulfate, Sodium Propoxyhydroxypropyl Thiosulfate Silica, Sorbityl Silanediol, Soy Triethoxysilylpropyldimonium Chloride, PEG-8 Stearalkonium Dimethicone Phthalate, Stearamido Propyl Dimethicone, PEG-7 Steardimonium Hydroxypropyl Panthenyl Dimethicone Phosphate, PEG-7 Steardimonium Hydroxypropyl Dimethicone Phosphate, Stearoxy Dimethicone, Stearoxymethicone/Dimethicone Copolymer, Stearoxytrimethylsilane, Stearyl Aminopropyl Methicone, Stearyl Dimethicone, Stearyl/Lauryl Methacrylate Crosspolymer, Stearyl Methicone, Stearyl Triethoxysilanok, Stearyl Trimethicone, Acrylates/C10-30 Alkyl Acrylate Crosspolymer Styrene/Acrylates/Dimethicone, Styrene/Acrylates/Dimethicone Copolymer, TEA-Dimethicone PEG-7 Phosphate, Tetrabutoxypropyl Trisiloxane, Tetramethyl Hexaphenyl Tetrasiloxane, Tetramethyl Tetraphenyl Trisiloxane, Tocopheryloxypropyl Trisiloxane, Trideceth-9 PG-Amodimethicone, Ilsilane, Triethoxysilylethyl Dimethicone/Methicone Copolymer, Triethoxysilylethyl Polydimethylsiloxyethyl Dimethicone, Triethoxysilylethyl Polydimethylsiloxyethyl Hexyl Dimethicone, Triethoxysilylpropylcarbamoyl Ethoxypropyl Butyl Dimethicone, Trifluoromethyl C1-4 Alkyl Dimethicone, Trifluoropropyl Cyclopentasiloxane, oxane Trifluoropropyl, Trifluoropropyl Dimethicone, Trifluoropropyl Dimethicone/PEG-10 Cross-Polymer, Trifluoropropyl Dimethicone/Trifluoropropyl Divinyldimethicone Cross-Polymer, Trifluoropropyl Dimethicone/Trifluoropropyl Vinyl, Dimethicone/Silsesquioxane Cross-Polymer, Trifluoropropyl Dimethiconol, Trifluoropropyl-dimethyl/Trimethylsiloxysilicate, Fluoropropyl Methicone, Trimethoxycaprylylsilane, Trimethoxysilyl Dimethicone, Trimethyl Pentaphenyl Trisiloxane, Trimethylsiloxymodimethicone, Trimethylsiloxyphenyl Dimethicone, Trimethylsiloxysilicate, Trimethylsiloxysilicate/Dimethicone Cross-Polymer, Trimethylsiloxysilicate/Dimethiconol Cross-Polymer, Pululan Trimethylsiloxysilylcarbamoyl, Trimethylsilyl Hydrolyzed Conchionyl Protein PG-Propyl Methylsilanediol Crosspolymer, Trimethylsilyl Hydrolyzed Silk PG-Propyl Methylsilanediol Crosspolymer, Trimethylsilyl Hydrolyzed Wheat Protein PG-Propyl Methylsilanediol Crosspolymer, Trimethylsilyl Pullulan, Trimethylsilyl Trimethylsiloxy Glycolate, Trimethylsilyl Trimethylsiloxy Lactate, Trimethylsilyl Trimethylsiloxy Salicylate, Triphenyl Trimethicone, Trisiloxane, Tris-Tributoxysiloxymethylsilane, Undecylcrylene Dimethicone, Vinyl Dimethicone, Vinyl Dimethicone/Lauryl Dimethicone Crosspolymer, Vinyl Dimethicone cona/Methicone Silsesquioxane, Vinyldimethyl/Trimethylsilyloxysilicate Stearyl Dimethicone Crosspolymer, VP/DimethiconylAcrylate/Polycarbamyl/Polyglycol Ester, Zinc Carboxydecyl Trisiloxane and Zinc Dimethicone PEG-8 Succinate and mixtures thereof.

[0044] Most preferably, the silicones to be contained in the mixture according to the present invention are Dimethicone, Cyclomethicone, Phenyl Trimethicone, Cyclohexasiloxane and Cyclopentasiloxane. A detailed overview of suitable volatile silicones can be found in Todd et al. in Cosm. Toil. 91, 27 (1976).

WAXES AND STABILIZERS

[0045] In addition to the natural oils used, waxes may also be present in the preparations, more especially natural waxes such as, for example, candelilla wax, carbauba wax, Japanese wax, esparto wax, cork wax, guaruma wax, rice oil wax, sugar cane wax, oricurium wax, mountain wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), uropygial fat, ceresin, ozokerite (earth wax), petroleum, paraffin waxes and microwaxes; chemically modified waxes (hard waxes) such as, for example, mountain ester waxes, sasol waxes, hydrogenated jojoba waxes and synthetic waxes such as, for example, polyalkylene waxes and polyethylene glycol waxes.

[0046] Metal salts of fatty acids such as, for example, magnesium aluminum and/or zinc stearate or ricinoleate can be used as stabilizers.

1,2-ALKANEDIOLS

[0047] In a particular preferred embodiment, the compositions may contain 1,2-alkanediols having 5 to 12 carbon atoms, such as 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, a mixture of 1,2-hexanediol and 1,2-octanediol, a mixture of 1,2-hexanediol and 1,2-decanediol, a mixture of 1,2-octanediol and 1,2-decanediol, a mixture of 1,2-hexanediol, 1,2-octanediol and 1,2-decanediol, preferably in amounts of from 0.1 to about 10 and preferably from about 1 to about 8 weight percent.

FATTY ALCOHOLS

[0048] The compositions may also encompass fatty alcohols having 6 to 30 C atoms. The fatty alcohols herein may be saturated or unsaturated and linear or branched. Furthermore, these fatty alcohols may in some cases be part of the oil phase (III) if they meet the definition provided herein. Alcohols which may be used are, for example, decanol, decenol, octanol, octenol, dodecanol, dodecenol, octadienol, decadienol, dodecadienol, oleyl alcohol, ricinoleyl alcohol, erucil alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, caprylic alcohol, capryl alcohol, linoleic alcohol, linolenyl alcohol and behenyl alcohol, and also Guerbet alcohols thereof, such as, for example, 2-octyl-1-dodecanol, the list being virtually as desired extended by other alcohols of related structural chemistry. Fatty alcohols preferably originate from natural fatty acids and are conventionally prepared from the corresponding fatty acid esters by reduction. Fatty alcohol fractions which are formed by the reduction of natural fats and fatty oils, such as beef tallow, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil, palm kernel oil, linseed oil, corn oil, castor oil, rapeseed oil, sesame oil, cocoa butter and coconut fat may also be used.

UV FILTERS AND PRIMARY SUN PROTECTION FACTORS

[0049] In another preferred embodiment, the compositions contain UV filters alone or in combinations with each other. The combinations can range from 2 to more than 10 UV filters preferably with models of UVB, UBA and broadband UV filters. Suitable UV filters are, for example, organic UV absorbers of the class of 4-aminobenzoic acid and derivatives, benzophenone derivatives, salicylate derivatives, diphenylacrylates, 3-imidazol-4-ylacrylic acid and its esters, benzofuran derivatives, benzylidenemalonate derivatives, UV-absorbing polymers containing one or more organosilicon radicals, cinnamic acid derivatives, camphor derivatives, trianilino-s-triazine derivatives, 2-hydroxyphenylbenzotriazole derivatives, menthyl anthranilate, benzotriazole derivatives, merocyanine dye derivative, e.g. Methoxy Propylamino Cyclohexenylidene Ethoxyethyl Cyanoacetate and indole derivatives. Specific UV filters that can be used are, for example, as follows:

[0061] Suitable UVA filters are, for example, the following: • Avobenzone (Neo Heliopan® 357); • Terephthalylidene dibornanesulfonic acid and salts (Mexoryl® SX); • Hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (Uvinul® A Plus); • 2,2’-(1,4-phenylene)bis-[1H-benzimidazole-4,5-disulfonic acid], disodium salt (Neo Heliopan® AP); • Methyl anthranilate (Neo Heliopan® MA); • Methoxy Propylamino Cyclohexenylidene Ethoxyethyl Cyanoacetate

[0062] Suitable UVB filters include: • p-Aminobenzoic acid; • Ethyl p-aminobenzoate (25 mol) ethoxylated; • 2-ethylhexyl p-dimethylaminobenzoate; • 2-ethylhexyl p-methoxycinnamate (Neo Heliopan®AV); • Isoamyl p-methoxycinnamate (Neo Heliopan®E 1000); • Triethanolamine salicylate (Neo Heliopan®TS); • 2-phenylbenzimidazole sulfonic acid (Neo Heliopan® Hydro) and its salts; • 3-(4'-trimethylammonium)benzylidenebornan-2-one methyl sulfate; • 3-(4'-sulfo)benzylidenebornan-2-one and salts; • 3-(4'-methylbenzylidene)-d,l-camphor (Neo Heliopan®MBC); • N-[(2 and 4)-[2-(oxoborn-3-ylidene)methyl]benzyl]acrylamide polymer; • 4,4'-[(6-[4-(1,1-dimethyl)aminocarbonyl)phenylamino]-1,3,5-triazine-2,4-diyl)diimino]bis(2-ethyl -benzoic acid hexyl ester) (Uvasorb®HEB); • Benzylidenemalonate-polysiloxane (Parsol®SLX); • Octocrylene (Neo Heliopan®303); • Octisalate (Neo Heliopan®OS); • Homosalate (Neo Heliopan®HMS);• Tris(2-ethylhexyl)4,4',4"-(1,3,5-triazine-2,4,6-tri-yl-triimino)tribenzoate (Uvinul®T150) • Methoxy Propylamino Cycle -hexenylidene Ethoxyethyl Cyanoacetate

[0063] Suitable broadband filters are, for example: • Bemotrizinol (Neo Heliopan®BMT) • 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid (sulisobenzo- one, benzophenone-4) or its salts; • 2-hydroxy-4-methoxybenzophenone (Neo Heliopan®BB, Oxybenzone, benzophenone-3); • 2,2´-dihydroxy-4,4´-dimethoxy-5,5´-disulfobenzophenone disodium; • Phenol, -(2H-benzotriazol-2-yl-4-methyl-6-(2-methyl-3-(1,3,3,3-tetramethyl-1-(trimethylsilyl)oxy)disyloxyanyl)propyl), (Mexoryl®XL); • 2,2’-methylenebis(6-(2H-benztriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)-phenol), Tinosorb®M); • Tris-Biphenyl Triazine (Tinosorb®A2B); • 2,4-bis[[(3-(2-propyloxy)-2-hydroxypropyloxy)-2-hydroxy]phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine; • 2,4-bis[[4-(2-ethylhexyloxy)-2-hydroxy]phenyl]-6-[4-(2-methoxyethyl-carbonyl)phenylamino]-1,3,5-triazine; • 2,4-bis[[4-(3-(2-propyloxy)-2-hydroxypropyloxy)-2-hydroxy]phenyl]-6-[4-(2-ethylcarboxyl)phenylamino]-1,3,5-triazine; • 2,4-bis[[4-(2-ethylhexyloxy)-2-hydroxy]phenyl]-6-(1-methylpyrrol-2-yl)-1,3,5-triazine; • 2,4-bis[[4-tris(trimethylsiloxysilylpropyloxy)-2-hydroxy]phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine; • 2,4-bis[[4-(2‘‘-methylpropenyloxy)-2-hydroxy]phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine; • 2,4-bis[[4-(1‘,1‘,1‘,3‘,5‘,5‘,5‘-heptamethylsiloxy-2‘‘- methylpropyloxy)-2-hydroxy]phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine; and • (5,6, 5',6'-tetraphenyl-3,3'-(1,4-Phenylene)bis(1,2,4-triazine),

[0064] It is also possible to use additional particulate UV filters or inorganic pigments, which if desired can be rendered hydrophobic, such as zinc oxides (ZnO), titanium oxides (TiO2), iron oxides (Fe2O3), zirconium oxides (ZrO2), silicon oxides (SiO2), manganese oxides (e.g. MnO), aluminum oxides (Al2O3), cerium oxides (e.g. Ce2O3) and/or mixtures thereof in amounts of 0.5% to 25%.

[0065] In a preferred embodiment according to the invention, the composition comprises at least one UVA filter selected from the group consisting of: Butyl Methoxydibenzoylmethane (Neo Heliopan® 357), Terephthalylidenedibornanesulfonic acid and salts (Mexoryl®SX), Hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (Uvinul®A Plus), Menthyl anthranilate (Neo Heliopan®MA), 2,2'-(1,4-phenylene)bis-[1H-benzimidazole-4,5-disulfonic acid], disodium salt (Neo Heliopan®AP), Methoxy Propylamino Cyclohexenylidene Ethoxyethyl Cyanoacetate and mixtures thereof.

[0066] In another preferred embodiment, according to the present invention, the composition comprises at least one UVB filter selected from the group consisting of Octocrylene (Neo Heliopan® 303), Homosalate (Neo Heliopan® HMS), Octisalate (Neo Heliopan® OS), 2-ethylhexyl p-dimethylaminobenzoate, triethanolamine salicylate (Neo Heliopan® TS), 2-ethylhexyl p-methoxycinnamate (Neo Heliopan® AV), Isoamyl p-methoxycinnamate (Neo Heliopan® E 1000), 2-phenylbenzimidazole sulfonic acid (Neo Heliopan® Hydro) and its salts, 3-(4'-methylbenzylidene)-d,l-camphor (Neo Heliopan® MBC), 4,4'-[(6-[4- (1,1-dimethyl)aminocarbonyl)phenylamino]-1,3,5-triazine-2,4-diyl)diimino]bis(benzoic acid 2-ethylhexyl ester) (Uvasorb®HEB), benzylidenemalonate-polysiloxane (Parsol®SLX), (Tris(2-ethylhexyl)4,4’,4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate (Uvinul®T150), Methoxy Propylamino Cyclohexenylidene Ethoxyethyl Cyanoacetate, and mixtures thereof.

[0067] In another preferred embodiment, according to the present invention, the composition comprises at least one broadband filter selected from the group consisting of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (Neo Heliopan®BMT), 2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid (sulisobenzone, benzophenone-4) or its salts, 2-hydroxy-4-methoxybenzophenone (Neo Heliopan®BB, Oxybenzone, benzophenone-3), Phenol, -(2H-benzotriazol-2-yl-4-methyl-6-(2-methyl-3-(1,3,3,3-tetramethyl-1-(trimethylsilyl)oxy)disyloxyanyl)propyl), (Mexoryl®XL), 2,2'- methylenebis(6-(2H-benztriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)-phenol), Tinosorb®M), Tris-Biphenyl Triazine (Tinosorb®A2B), (5,6,5',6'-tetraphenyl- 3,3'-(1,4-phenylene)bis(1,2,4-triazine), and mixtures thereof.

[0068] In one embodiment according to the invention, the total amount of oil-soluble UV filters that can be used, which are for example but not limited to avobenzone and/or 2-ethylhexyl 4-dimethylaminobenzoate and/or meradimate, and/or 2-ethylhexyl salicylate and/or homosalate and/or octinoxate and/or isoamyl p-methoxycinnamate and/or octocrylene and/or methyl benzylidene camphor and/or Uvasorb HEB and/or Uvinul A Plus, and/or Mexoryl XL and/or Benzophenone-3 and/or Parsol SLX and/or Bemotrizinol and/or Methoxy Propylamino Cyclohexenylidene Ethoxyethyl Cyanoacetate is in the range of 0.1 to 55 wt%, particularly in the range of 0.5 to 40% by weight, more particularly in the range of 1 to 30% by weight, based on the total weight of the composition.

[0069] In one embodiment according to the invention, the amount of isoamyl octinoxate or p-methoxycinnamate when used as a UV filter is in the range of 0.1 to 20.0 wt%, preferably in the range of 0.3 to 15 wt% and most preferably in the range of 0.5 to 10.0 wt%, based on the total weight of the composition.

[0070] In one embodiment according to the invention, the amount of octocrylene is in the range of 0.1 to 20.0% by weight, preferably in the range of 0.3 to 15% by weight and more preferably in the range of 0.5 to 10.0% by weight, based on the total weight of the composition.

[0071] In one embodiment according to the invention, the amount of salicylate esters is in the range of 0.1 to 20.0% by weight, preferably in the range of 0.3 to 15% by weight and more preferably in the range of 0.5 to 10.0% by weight, based on the total weight of the composition.

[0072] When octisalate is chosen as UV filter, it is advantageous that its total amount ranges from 0.1 to 5.0% by weight, based on the total weight of the composition. When homosalate is chosen as UV filter, it is advantageous that its total amount ranges from 0.1 to 15.0% by weight, based on the total weight of the composition.

[0073] In one embodiment according to the invention, the amount of Avobenzone is in the range of 0.1 to 10.0% by weight, preferably in the range of 0.3 to 7.0% by weight and more preferably in the range of 0.5 to 5.0% by weight, based on the total weight of the composition.

[0074] In one embodiment according to the invention, the amount of Methylbenzylidene Camphor when used as a UV filter is in the range of 0.1 to 4.0% by weight, preferably in the range of 0.3 to 4.0% by weight and more preferably in the range of 0.5 to 3.0% by weight, based on the total weight of the composition.

[0075] In one embodiment according to the invention, the amount of Bemotrizinol is in the range of 0.1 to 10.0% by weight, preferably in the range of 0.3 to 7.0% by weight and more preferably in the range of 0.5 to 5.0% by weight, based on the total weight of the composition.

[0076] In one embodiment according to the invention, the total amount of microfine organic and/or inorganic pigments, for example but not limited to zinc oxide (coated and uncoated) and/or titanium dioxide (coated or uncoated) that can be used when used as additional UV filters in compositions according to the invention can be in the range of 0.1 to 35% by weight, preferably in the range of 0.3 to 25% by weight and more preferably in the range of 0.5 to 20.0% by weight and most preferably in the range of 0.75% to 10.0% by weight, based on the total weight of the composition. When titanium dioxide is chosen as the UV filter, it is advantageous that its total amount ranges from 0.1% to 20.0% by weight, based on the total weight of the composition. When zinc oxide is chosen as a UV filter, it is advantageous that its total amount ranges from 0.1% to 20.0% by weight, based on the total weight of the composition.

[0077] The amount of Uvasorb HEB, when used as an additional UV filter according to the invention, is in the range of 0.1 to 10.0%, preferably in the range of 0.3 to 7.0% and more preferably in the range of 0.5 to 5.0% of the total formulation.

[0078] The amount of Uvinul T-150, when used as an additional UV filter according to the invention, is in the range of 0.1 to 10.0%, preferably in the range of 0.3 to 7.0% and more preferably in the range of 0.5 to 5.0% of the total formulation.

[0079] In one embodiment according to the invention, the total amount of organic insoluble particulate UV filters when used as additional UV filters according to the invention, which are for example but not limited to 2,2'-methylenebis(6-(2H-benzotriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)-phenol), (Tinosorb M), Tris-Biphenyl Triazine (Tinosorb®A2B) and (5,6,5',6'-tetraphenyl-3,3'-(1,4-phenylene)bis(1,2,4-triazine) is in the range of 0.5 to 5% of the total formulation.

[0080] The amount of 2,2'-methylenebis(6-(2H-benzotriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)-phenol), (Tinosorb M) when used as an additional UV filter according to the invention is in the range of 0.1 to 10.0%, preferably in the range of 0.3 to 7.0% and more preferably in the range of 0.5 to 5.0% of the total formulation.

[0081] The amount of Tris-Biphenyl Triazine (Tinosorb® A2B), when used as an additional UV filter according to the invention, is in the range of 0.1 to 10.0%, preferably in the range of 0.3 to 7.0% and more preferably in the range of 0.5 to 5.0% of the total formulation.

[0082] The amount of benzylidenemalonate-polysiloxane (Parsol®SLX), when used as an additional UV filter according to the invention, is in the range of 0.1 to 10.0%, preferably in the range of 0.3 to 7.0% and more preferably in the range of 0.5 to 5.0% of the total formulation.

[0083] In one embodiment of the invention, the total amount of all sulfonated water-soluble UV filters when used as UV filters, such as, for example, but not limited to, phenylbenzimidazole sulfonic acid and/or disodium phenyl dibenzimidazole tetrasulfonic acid and/or benzophenone-4 and/or terephthalylidenedibornanesulfonic acid and/or 3-(4'-trimethylammonium)benzylidenebornan-2-one methyl sulfate and/or 3-(4'-sulfo)benzylidenebornan-2-one and their salts in cosmetic and pharmaceutical preparations, preferably dermatological preparations, is in the range of 0.1 to 15.0% and more particularly in the range of 0.5 to 10.0% and more particularly in the range of 1.0 to 8.0% of the total formulation.

[0084] The amount of disodium phenyl dibenzimidazole tetrasulfonate and its salts, when used as an additional UV filter according to the invention, is in the range of 0.1 to 10.0%, preferably in the range of 0.3 to 8% and more preferably in the range of 0.5 to 5.0% of the total formulation.

[0085] The amount of phenylbenzimidazole sulfonic acid and its salts, when used as an additional UV filter according to the invention, is in the range of 0.1 to 10.0%, preferably in the range of 0.3 to 8% and more preferably in the range of 0.5 to 5.0% of the total formulation.

[0086] The amount of Mexoryl SX and its salts when used as an additional UV filter according to the invention is in the range of 0.1 to 10.0%, preferably in the range of 0.3 to 8% and most preferably in the range of 0.5 to 5.0% of the total formulation.

[0087] Advantageous primary and also secondary sun protection ingredients are mentioned in WO 2005 123101 A1. Advantageously, these preparations contain at least one UVA filter and/or at least one UVB filter and/or at least one inorganic pigment. The preparations can be present here in various forms, such as those conventionally used for sun protection preparations. Thus, they can be in the form of a solution, an emulsion of the water-in-oil (W/O) or oil-in-water (O/W) type or a multiple emulsion, for example of the water-in-oil-in-water (W/O/W) type, a gel, a hydrodispersion, a solid stick or an aerosol.

[0088] In another preferred embodiment, a formulation according to the invention contains a total amount of sun protection agents, i.e. in particular UV filters and/or inorganic pigments (UV filtering pigments) such that the formulation according to the invention has a light protection factor greater than or equal to 2 (preferably greater than or equal to 5). Such formulations according to the invention are particularly suitable for protecting the skin and hair.

SECONDARY SUNSCREEN INGREDIENTS

[0089] In addition to the above-mentioned groups of primary sunscreen ingredients, secondary sunscreen ingredients of the antioxidant type may also be used. Secondary sunscreen factors of the antioxidant type interrupt the photochemical reaction chain that is initiated when ultraviolet rays penetrate the skin. Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotinoids, carotenes (e.g. alpha-carotene, beta-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, liponic acid and its derivatives (e.g. dihydroliponic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl esters, palmitoyl, oleyl, alpha-linoleyl, cholesteryl and glyceryl thereof) and their salts, dilaurylthiodipropionate, distearylthiodipropionate, thiodipropionic acid and their derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and sulfoximine compounds (e.g. buthionine and sulfoximines, homocysteine sulfoximine, buthionine sulfones, penta-, hexa- and hepta- thionine sulfoximine) in very small compatible dosages, also (metal) chelators (e.g. alpha-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), alpha-hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g. linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and their derivatives (e.g. ascorbyl palmitate, Mg-ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (e.g. vitamin E acetate), vitamin A and derivatives (vitamin A palmitate) and coniferyl benzoate from benzoin resin, rutinic acid and its derivatives, glycosyl rutin, doferulic acid, furfurylidene glucitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiac resin acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (e.g. dispersions in ethanol), zinc and its derivatives (e.g. ZnO, ZnSO4), selenium and derivatives thereof (e.g. selenium methionine), stilbenes and their derivatives (e.g. stilbene oxide, trans-stilbene oxide) and derivatives of these active substances suitable for the purposes of the invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids).

PIGMENTS

[0085] Advantageous inorganic secondary light protection factors are pigments, preferably inorganic pigments based on finely dispersed metal oxides and/or other metal compounds which are insoluble or sparingly soluble in water, in particular the oxides of titanium (TiO2), zinc (ZnO), iron (e.g. Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminum (A12O3), cerium (e.g. Ce2O3), mixed oxides of the corresponding metals and mixtures of such oxides. These pigments are either X-ray amorphous or X-ray non-amorphous. X-ray amorphous oxide pigments are metal oxides or semimetallic oxides that reveal no or no recognizable crystal structure in X-ray diffraction experiments. These pigments are often obtained by flame reaction, for example, by reacting a metal or semimetallic halide with hydrogen and air (or pure oxygen) in a flame.

[0086] X-ray amorphous oxide pigments are used as thickeners and thixotropic agents, flow aids for emulsion stabilization and dispersion and as carrier substance (e.g. to increase the volume of finely divided powders). X-ray amorphous oxide pigments which are known and frequently used in cosmetic or dermatological galenics are, for example, high-purity silicon oxide. Preference is given to high-purity X-ray amorphous silicon dioxide pigments with a particle size in the range of 5 to 40 nm and an active surface area (BET) in the range of 50 to 400 m2/g, preferably 150 to 300 m2/g, whereby the particles are to be regarded as spherical particles of very uniform size. Macroscopically, silicon dioxide pigments are recognizable as loose white powders. Silicon dioxide pigments are sold commercially under the name Aerosil® (CAS-No. 7631-85-9) or Carb-O-Sil.

[0087] Advantageous Aerosil® grades are, for example, Aerosil®0X50, Aerosil®130, Aerosil®150, Aerosil®200, Aerosil®300, Aerosil®380, Aerosil®MQX 80, Aerosil®MOX 170 , Aerosil®COK 84, Aerosil®R 202, Aerosil®R 805, Aerosil®R 812, Aerosil®R 972, Aerosil®R 974, Aerosil®R976.

[0088] The compositions according to the present invention may comprise 0.1 to 20% by weight, advantageously 0.5 to 10% by weight, more preferably 1 to 5% by weight, based on the total weight of the compositions, of X-ray amorphous oxide pigments.

[0089] The non-amorphous inorganic pigments for X-rays are, according to the present invention, advantageously in hydrophobic form, i.e. they have been surface treated to repel water. This surface treatment may involve providing the pigments with a thin hydrophobic layer by processes known per se. Such a process involves, for example, the production of the hydrophobic surface layer by a reaction according to n TiO2 + m(RO)3Si-R‘ ^ n TiO2 (surf.) where n and m are stoichiometric parameters to be used as desired, and R and R' are the desired organic radicals. Hydrophobic pigments prepared analogously to DE A 33 14 742, for example, are advantageous.

[0098] In a preferred embodiment according to the invention, the composition comprises at least one pigment selected from the group consisting of zinc oxide, titanium dioxide and mixtures thereof.

[0099] The total amount of inorganic pigments, in particular hydrophobic inorganic micro pigments, in the finished cosmetic, dermatological and pharmacological composition according to the invention can advantageously be chosen in the range of 0.1 to 30% by weight, preferably 0.1 to 10.0% by weight, preferably 0.5 to 6.0% by weight, based on the total weight of the compositions.

ANTIOXIDANTS

[00100] An additional content of antioxidants in the compositions of the present invention is generally preferred. According to the present invention, favorable antioxidants that can be used are all antioxidants usual or suitable for cosmetic, dermatological and pharmacological preparations. Antioxidants are advantageously chosen from the group of amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (e.g. α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and the glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl esters, palmitoyl, oleyl, γ-linoleyl, cholesteryl and glyceryl) and salts thereof, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and their derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and sulfoximine compounds (e.g. buthionine sulfoximines, homocysteine sulfoximine, buthionine sulfones, penta-, hexa-, heptathionine sulfoximine) at very low tolerated doses (e.g. pmol to μmol/kg), and also (metal)chelating agents (e.g. α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g. citric acid, lactic acid, maleic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g., γ-linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and derivatives (e.g., ascorbyl palmitate, Mg-ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (e.g., vitamin E acetate), vitamin A and derivatives (vitamin A palmitate), and coniferyl benzoate from benzoin resin, rutinic acid and derivatives thereof, α-glycosylrutin, ferulic acid, furfurylidene glucitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiacic acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, zinc and its derivatives (e.g. ZnO, ZnSO4), selenium and its derivatives (e.g. selenomethionine), stilbenes and their derivatives (e.g. stilbene oxide, trans-stilbene oxide) and derivatives (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids), acetophenone derivatives such as hydroxyacetophenone and its mixtures with phenoxyethanol and/or pentane 1,2-diol and/or hexane 1,2-diol and/or caprylyl 1,2-diol are suitable according to the present invention.

[00101] The amount of the above-mentioned antioxidants (one or more compounds) in the composition is preferably 0.001 to 30 wt%, more preferably 0.05 to 20 wt%, and most preferably 1 to 10 wt%, based on the total weight of the composition.

VITAMINS

[00102] In a preferred embodiment, the composition of the invention may advantageously also comprise vitamins and vitamin precursors, whereby all vitamins and vitamin precursors suitable or customary for cosmetic and/or dermatological applications may be used. Particularly noteworthy here are vitamins and vitamin precursors such as tocopherols, vitamin A, niacin and niacinamide, other vitamins of the B complex, in particular biotin, and vitamin C and panthenol and its derivatives, in particular panthenol esters and ethers, and cationically derivatized panthenols such as panthenol triacetate, panthenol monoethyl ether and its monoacetate, and cationic panthenol derivatives. If vitamin E and/or its derivatives represent the antioxidant(s), it is advantageous to choose their respective concentrations in the range of 0.001 to 10% by weight, based on the total weight of the composition. If vitamin A or its derivatives, or carotenes or their derivatives represent the antioxidant(s), it is advantageous to choose their respective concentrations in the range of 0.001 to 10% by weight, based on the total weight of the composition.

PLANT EXTRACTS

[00103] The compositions may also include plant extracts, which are conventionally prepared by extraction from the whole plant, but also in individual cases exclusively from the flower and/or leaves, wood, bark or roots of the plant. As regards the plant extracts which may be used, reference is made in particular to the extracts listed in the table from page 44 of the 3rd edition of the Leitfaden zur Inhaltsstoffdeklaration kosmetischer Mittel [Manu al of Declaration of the Constituents of Cosmetic Compositions], published by Industrieverband Korperpflegemittel und Waschmittel e.V. (IKW), Frankfurt. Extracts that are particularly beneficial are those of aloe, witch hazel, seaweed, oak bark, pink willow, nettle, dead nettle, hops, chamomile, yarrow, arnica, calendula, burdock root, horsetail, hawthorn, linden blossom, almond, pine, horse chestnut, sandalwood, juniper, coconut, mango, apricot, orange, lemon, lime, grapefruit, apple, green tea, grapefruit pip, wheat, oats, barley, sage, thyme, wild thyme, rosemary, birch, mallow, sage, willow bark, restharrow, coltsfoot, hibiscus, ginseng and ginger root.

[00104] In this context, extracts of aloe vera, chamomile, seaweed, rosemary, marigold, ginseng, cucumber, sage, nettle, lime blossom, arnica and witch hazel are particularly preferred. Mixtures of two or more plant extracts may also be used. Extraction agents that may be used for the preparation of the plant extracts mentioned are, inter alia, water, alcohols and mixtures thereof. Among the alcohols, preference is given to lower alcohols such as ethanol and isopropanol, but also to polyhydric alcohols such as ethylene glycol, propylene glycol and butylene glycol, in particular as the sole extraction agent and in a mixture with water. The plant extracts may be used both in pure and diluted form.

SKIN LIGHTENING AGENTS

[00105] An additional content of skin lightening ingredients in the compositions according to the present invention is also possible. Such skin lightening ingredients that can be used are, for example, but not limited to the following: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives such as, for example, kojic dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, hydroquinone, hydroquinone derivatives, styryl resorcinol derivatives (e.g., 4-(1-phenylethyl)1,3-benzenediol), sulfur-containing molecules such as glutathione or cysteine, for example, alpha-hydroxy acids (e.g., citric acid, lactic acid, malic acid) and their derivatives, N-acetyltyrosine and derivatives, undecenoylphenylalanine, gluconic acid, chromone derivatives such as aloesin, flavonoids, thymol derivatives, 1-aminoethylphosphinic acid, thiourea, ellagic acid, nicotinamide, zinc salts such as zinc chloride or zinc gluconate, e.g. thujaplicin and derivatives, triterpenes such as maslic acid, sterols such as ergosterol, benzofuranones such as senkyunolide, vinyl and ethylguaiacol, dionic acids such as octodecenedionic acid and azelaic acid, nitric oxide synthesis inhibitors such as L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiocitrulline, metal chelators (e.g. alpha-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin, humic acid, gallic acid, bile extracts, bilirubin, biliverdin), retinoids, soy milk, soy extract, serine protease inhibitors or lipoic acid or other synthetic or natural active compounds for skin and hair lightening, these compounds also being used in the form of plant extracts, such as bearberry extract, rice extract, papaya extract, licorice root extract or concentrated constituents thereof, such as glabridin or licochalcone A, Artocarpus extract, extracts of Rumex and Ramulus species, extracts of pine species (Pinus) and extracts of Vitis species or concentrated stilbene derivatives thereof, extracts of saxifrage, blackberry, Scutelleria and/or grapes.

ACTIVE INGREDIENTS THAT MODULATE SKIN PIGMENTATION

[00106] The preferred active ingredients for hair lightening are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinols and 4-(1-phenylethyl)1,3-dihydroxybenzene (phenylethyl resorcinol), cyclohexylcarbamates (preferably one or more cyclohexyl carbamates described in WO 2010/122178 and WO 2010/097480), sulfur-containing molecules, preferably glutathione or cysteine, alpha-hydroxy acids (decayone, methyl esters ... preferably citric acid, lactic acid, malic acid), salts and esters thereof, N-acetyl tyrosine and derivatives, undecenoyl phenylalanine, gluconic acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethyl phosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, thujaplicin and derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably senkgosunolide, vinyl guiacol, ethyl guiaol, dionic acids, preferably octodecenedionic acid and/or azelaic acid, nitrogen oxide synthesis inhibitors, preferably L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiocitrulline, chelators of metal (preferably alpha-hydroxy fatty acids, phytic acid, humic acid, bile acid, bile extracts, EDTA, EGTA and their derivatives), retinoids, milk and soy extract, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for skin and hair lightening, the latter preferably used in the form of a plant extract, preferably bearberry extract, rice extract, papaya extract, turmeric extract, blackberry extract, bengkoang extract, walnut extract, licorice root extract or concentrated or isolated constituents thereof, preferably glabridin or licochalcone A, artocarpus extract, extract of rumex and ramulus species, extracts of pine species (pinus), extracts of vitis species or isolated or concentrated stilbene derivatives thereof, saxifrage extract, scutellaria extract, grape extract and/or microalgae extract, in particular, Tetrasel-mis suecica Extract.

[00107] Advantageous skin tanning active ingredients in this regard are tyrosinase substrates or substrate analogues such as L-tyrosine, N-acetyl tyrosine, L-DOPA or L-dihydroxyphenylalanine, xanthine alkaloids such as caffeine, theobromine and theophylline and their derivatives, proopiomelanocortin peptides such as ACTH, alpha-MSH, peptide analogues and other substances that bind to the melanocortin receptor, peptides such as Val-Gly-Val-Ala-Pro-Gly, Lys-Ile-Gly-Arg-Lys or Leu-Ile-Gly-Lys, purines, pyrimidines, folic acid, copper salts such as copper gluconate, chloride or pyrrolidonate, 1,3,4-oxadiazole-2-thiols such as 5-pyrazin-2-yl-1,3,4-oxadiazole-2-thiol, curcumin, zinc diglycinate (Zn(GIy)2), manganese(II) bicarbonate complexes ("pseudocat-alases") as described for example in EP 0 584 178, tetrasubstituted cyclohexene derivatives as described for example in WO 2005/032501, isoprenoids as described in WO 2005/102252 and in WO 2006/010661, melanin derivatives such as Melasyn-100 and MelanZe, diacylglycerols, aliphatic or cyclic diols, psoralens, prostaglandins and their analogues, adenylate cyclase activators and compounds that activate the transfer of melanomas to keratinocytes, such as serine proteases or PAR-2 receptor agonists, extracts of plants and plant parts of chrysanthemum species, Sanguisorba species, walnut extracts, annatto extracts, rhubarb extracts, extracts of microalgae, in particular Isochrysis galbana, trehalose, erythrulose and dihydroxyacetone. Flavonoids that cause dyeing or darkening of the skin and hair (e.g. quercetin, rhamnetin, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosmin and diosmetin, morin, quercitrin, narin, hesperidin, phloridzin and phlogenin) may also be used.

[00108] The amount of the above-mentioned examples of additional active ingredients for modulating skin and hair pigmentation (one or more compounds) in the products according to the invention is then preferably 0.00001 to 30% by weight, preferably 0.0001 to 20% by weight, with particular preference 0.001 to 5% by weight, based on the total weight of the preparation.

PHYSIOLOGICAL COOLING AGENTS

[00109] The compositions may also contain one or more substances with a physiological cooling effect (cooling agents), which are preferably selected here from the following list: menthol and menthol derivatives (e.g., L-menthol, D-menthol, racemic menthol, isomenthol, neoisomenthol, neomenthol), menthyl ethers (e.g., (I-menthoxy)-1,2-propandiol, (l-menthoxy)-2-methyl-1,2-propandiol, l-menthyl-methyl ether), menthyl esters (e.g., menthylformate, menthyl acetate, menthyl isobutyrate, menthyl lactates, L-menthyl-L-lactate, L-menthyl-D-lactate, menthyl-(2-methoxy)acetate, menthyl-(2-methoxyethoxy)acetate, menthylpyroglutamate), menthylcarbonate (e.g. menthylpropyleneglycolcarbonate, menthylethyleneglycolcarbonate, menthylglycerolcarbonate or mixtures thereof), half-esters of menthols with a dicarboxylic acid or its derivatives (e.g. monomenthylsuccinate, monomenthylglutarate, monomenthylmalonate, O-methylsuccinic acid N,N-(dimethyl)amide ester, O-menthylsuccinic acid ester amide), menthanecarboxylic acid amides (in this case preferably menthanecarboxylic acid N-ethylamide [WS3] or Na-(menthanecarbonyl)glycineethyl ester [WS5] as described in US 4,150,052, menthanecarboxylic acid N-(4-cyanophenyl)amide or menthanecarboxylic acid N-(4-cyanomethylphenyl)amide as described in WO 2005 049553 A1, N- (alkoxyalkyl)amides) of methanecarboxylic acid, menthone and menthone derivatives (e.g. L-menthone glycerol ketal), 2,3-dimethyl-2-(2-propyl)butyric acid derivatives (e.g. 2,3-dimethyl-2-(2-propyl)-butyric acid N-methylamide [WS23]), isopulegol or its esters (I-(-)-isopulegol, I-(-)-isopulegolacetate), menthane derivatives (e.g. p-menthane-3,8-diol), cubebol or synthetic or natural mixtures containing cubebol, pyrrolidone derivatives of cycloalkyldione derivatives (e.g. 3-methyl-2(1-pyrrolidinyl)-2-cyclopentene-1-one) or tetrahydropyrimidine-2-one (e.g. icilin or related compounds as described in WO 2004/026840), other carboxamides (e.g. N-(2-(pyridin-2-yl)ethyl)-3-p-menthanecarboxamide or related compounds), (1R,2S,5R)-N-(4-Methoxyphenyl)-5-methyl-2-(1-isopropyl)cyclohexanecarboxamide [WS12], oxamates (preferably those described in EP 2033688 A2).

ANTI-INFLAMMATORY AGENTS

[00110] The compositions may also comprise anti-inflammatory and/or anti-redness and/or itch-relieving active compounds (anti-irritants). All anti-inflammatory or redness and/or itch-relieving active compounds that are suitable or usual for cosmetic, dermatological and pharmacological compositions may be used herein. The anti-inflammatory and redness and/or itch-relieving active compounds that are advantageously used are steroidal anti-inflammatory substances of the corticosteroid type, such as hydrocortisone, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone, the list being possible to be extended by the addition of other steroidal anti-inflammatory drugs. Non-steroidal anti-inflammatory drugs may also be used. Those that should be mentioned here by way of example are oxicams, such as piroxicam or tenoxicam; salicylates, such as aspirin, Disalcid, Solprin or fendosal; acetic acid derivatives, such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or clindanac; fenamates, such as mefenamic, meclofenamic, flufenamic or niflumic; propionic acid derivatives, such as ibuprofen, naproxen, benoxaprofen or pyrazoles, such as phenylbutazone, oxyphenylbutazone, febrazone or azapropazone.

[00111] Alternatively, natural anti-inflammatory or anti-redness and/or itch-relieving substances may be employed. Plant extracts, specific fractions of highly active plant extracts and high-purity active substances isolated from plant extracts may be used. Extracts, fractions and active substances of chamomile, aloe vera, Commiphora species, Rubia species, willow, pink willowherb, oats, and also pure substances such as, inter alia, bisabolol, apigenin 7-glucoside, boswellic acid, phytosterols, glycyrrhizic acid, glabridin or licochalcone A, are particularly preferred. The compositions of the present invention may also comprise mixtures of two or more active anti-inflammatory compounds. Bisabolol, boswellic acid, and also highly pure extracts and active compounds isolated from oats and Echinacea are particularly preferred for use in the context of the invention as anti-inflammatory and redness and/or itching relieving substances, and alpha-bisabolol and highly pure extracts and active compounds isolated from oats are especially preferred.

[00112] Preferred anti-inflammatory agents may be selected from the group consisting of: (i) steroidal anti-inflammatory substances of the corticosteroid type, in particular hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone, (ii) non-steroidal anti-inflammatory substances, in particular oxicams such as piroxicam or tenoxicam, salicylates such as aspirin, disalcid, solprin or fendosal, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or clindanac, fenamates such as mefenamic, meclofenamic, flufenamic or niflumic, propionic acid derivatives such as ibuprofen, naproxen or benoxaprofen, pyrazoles such as phenylbutazone, oxyphenylbutazone, febrazone or azapropazone, (iii) natural or naturally occurring anti-inflammatory substances or substances which relieve redness and/or itching, in particular extracts or fractions of chamomile, Aloe vera, Commiphora species, Rubia species, willow, willowherb, oats, calendula, arnica, St. John's wort, honeysuckle, rosemary, Passiflora incarnata, witch hazel, ginger or Echinacea, or their individual active compounds, (iv) histamine receptor antagonists, serine protease inhibitors (e.g. from soy extracts), TRPV1 antagonists (e.g. 4-t-butylcyclohexanol), NK1 antagonists (e.g. Aprepitant, Hydroxyphenyl Propamidobenzoic Acid), NK1 agonists cannabinoid receptor antagonists (e.g. Palmitoyl Ethanolamine) and TRPV3 antagonists.

[00106] The amount of anti-irritants (one or more compounds) in the composition is preferably 0.0001% to 20% by weight, with particular preference 0.0001% to 10% by weight, in particular 0.001% to 5% by weight, based on the total weight of the composition.

ANTIMICROBIAL AGENTS

[00107] Suitable antimicrobial agents are in principle all substances effective against Gram-positive bacteria, such as, for example, 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N’-(3,4-dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxydiphenyl ether (triclosan), 4-chloro-3,5-dimethylphenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy)-1,2-propanediol, 3-iodo-2-propynylbutylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial fragrances, thymol, thyme oil, eugenol, clove oil, menthol, peppermint oil, farnesol, phenoxyethanol, glycerol monocaprate, glycerol monocaprylate, glycerol monolaurate (GML), diglycerol monocaprate (DMC), N-alkylamides of salicylic acid, such as, for example, n-octylsalicylamid or n-decylsalicylamid.

[00108] In a preferred embodiment according to the invention, the composition comprises 4-hydroxyacetophenone, o-cymen-5-ol or mixtures thereof.

ENZYME INHIBITORS

[00109] Suitable enzyme inhibitors are, for example, esterase inhibitors. These are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and, in particular, triethyl citrate (Hydagen CAT). The substances inhibit enzyme activity, thereby reducing the formation of odors. Other substances which are suitable esterase inhibitors are sterol sulfates or phosphates, such as, for example, lanosterol, cholesterol, campesterol, stigmasterol and sitosterol sulfate or phosphate, dicarboxylic acids and their esters, such as, for example, glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid and diethyl malonate, hydroxycarboxylic acids and their esters, such as, for example, citric acid, malic acid, tartaric acid or diethyl tartrate and zinc glycinate.

ODOR ABSORBERS AND ANTIPERSPIRANT ACTIVE AGENTS

[00110] Suitable odour absorbents are substances which are capable of absorbing and largely retaining odour-forming compounds. They lower the partial pressure of the individual components, thereby also reducing their diffusion rate. It is important that the perfumes remain intact during this process. Odour absorbents are not effective against bacteria. They comprise, for example, as the main constituent, a complex zinc salt of ricinoleic acid or specific, largely odour-neutral fragrances which are known to those skilled in the art as "fixatives", such as, for example, extracts of labdanum or styrax or certain derivatives of abietic acid. Odour masking agents are fragrances or perfume oils which, in addition to their odour-masking function, also give deodorants their respective fragrance note. Perfume oils which may be mentioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts from flowers, stems and leaves, fruits, fruit peels, roots, woods, herbs and grasses, needles and twigs, resins and balsams. Also suitable are products of animal origin, such as civet and castoreum. Typical synthetic fragrance compounds are ester, ether, aldehyde, ketone, alcohol and hydrocarbon products. Ester-type fragrance compounds are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styralyl propionate and benzyl salicylate. The ethers include, for example, benzyl ethyl ether, and the aldehydes include, for example, the linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronelloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal, the ketones include, for example, the ionones and methyl cedryl ketone, the alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linaol, phenylethyl alcohol and terpineol, and the hydrocarbons include mainly the terpenes and balsams. Preference is, however, given to the use of mixtures of different fragrances which together produce a pleasant fragrance note. Essential oils with relatively low volatility, which are mainly used as aroma components, are also suitable as fragrance oils, for example, sage oil, chamomile oil, clove oil, lemon balm oil, peppermint oil, cinnamon leaf oil, linden blossom oil, juniper oil, vetiver oil, frankincense oil, galbanum oil, labdanum oil and lavender oil. Preference is given to the use of bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, a-hexylcinnamaldehyde, geraniol, benzyl lacetone, cyclamen aldehyde, linalool, boisambrene forte, ambroxan, indole, hedione, sandelice, lemon oil, mandarin oil, orange oil, allyl amyl glycolate, cyclovertal, lavender oil, sage oil, β-damascane, geranium oil, bourbon, cyclohexyl salicylate, Vertofix co-eur, iso-E-super, Fixolide NP, evernil, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, irotyl and floramat alone or in mixtures.

[00111] Suitable antiperspirant astringent active ingredients are primarily aluminum, zirconium or zinc salts. Such suitable antihydrotic active ingredients are, for example, aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesquichlorohydrate and their complex compounds, for example with 1,2-propylene glycol, aluminum hydroxyallantoinate, aluminum chloride tartrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate and their complex compounds, for example with amino acids such as glycine.

FILM FORMERS AND ANTI-DANDRUFF AGENTS

[00112] Standard film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinyl pyrrolidone, vinyl pyrrolidone/vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid and their salts and similar compounds.

[00113] Suitable anti-dandruff agents are Pirocton Olamin (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), Baypival® (Climbazole), Ketoconazole® (4-acetyl-1-{4-[2-(2,4-dichlorophenyl)r-2-(1H-imidazol-1-ylmethyl)-1,3-dioxylan-c-4-ylmethyl-oxyphenyl}-piperazine, ketoconazole, elubiol, selenium disulfide, colloidal sulfur, sulfur polyethylene glycol sorbitan monooleate, sulfur ricinol polyethoxylate, sulfur tar distillate, salicylic acid (or in combination with hexachlorophene), undecylenic acid, sodium sulfosuccinate Na salt monoethanolamide, Lamepon®UD (protein/undecylenic acid condensate), zinc pyrithione, aluminum pyrithione and magnesium pyrithione sulfate/magnesium dipyrithione.

TRANSPORTERS, HYDROTROPES AND MOISTURE RETENTION REGULATORS

[00114] Preferred cosmetic carrier materials are solid or liquid at 25°C and 1013 mbar (including highly viscous substances) such as, for example, glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water and mixtures of two or more of said liquid carrier materials with water. Optionally, these preparations according to the invention can be produced using preservatives or solubilizers. Other preferred liquid carrier substances, which can be a component of a preparation according to the invention, are selected from the group consisting of oils, such as vegetable oil, neutral oil and mineral oil.

[00115] Preferred solid carrier materials, which can be a component of a preparation according to the invention, are hydrocolloids, such as starches, degraded starches, chemically or physically modified starches, dextrins, maltodextrins (powdered) (preferably with a dextrose equivalent value of 5 to 25, preferably of 10-20), lactose, silicon dioxide, glucose, modified celluloses, gum arabic, gum ghatti, tragacanth, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, locust bean flour, alginates, agar, pectin and inulin and mixtures of two or more of these solids, in particular maltodextrins (preferably with a dextrose equivalent value of 15-20), lactose, silicon dioxide and/or glucose.

[00116] Furthermore, hydrotropes, for example ethanol, isopropyl alcohol or polyols, can be used to improve the flow behavior. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols may contain other functional groups, more especially amino groups, or may be modified with nitrogen. Typical examples are • glycerol; • alkylene glycols, such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1000 Dalton; • technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10, such as, for example, technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight; • methylol compounds, such as, in particular, trimethylol ethane, trimethylol propane, trimethylol butane, pentaerythritol and dipentaerythritol; • lower alkyl glycosides, particularly those containing 1 to 8 carbon atoms in the alkyl group, for example methyl and butyl glycoside; • sugar alcohols containing 5 to 12 carbon atoms, for example sorbitol or mannitol, • sugars containing 5 to 12 carbon atoms, for example glucose or sucrose; • amino sugars, for example glycamine; • dialcoholamines, such as diethanolamine or 2-aminopropane-1,3-diol.

[00117] Preferred moisture retention regulators include sodium lactate, urea, alcohols, sorbitol, glycerol, propylene glycol, aliphatic 1,2-diols having a C number of 5-10, collagen, elastin or hyaluronic acid, diacyl adipates, petrolatum, ectoin, urocanic acid, lecithin, panthenol, phytantriol, lycopene, algae extract, ceramides, cholesterol, glycolipids, chitosan, chondroitin sulfate, polyamino acids and polyamino sugars, lanolin, lanolin esters, amino acids, alpha-hydroxy acids (e.g., citric acid, lactic acid, malic acid) and their derivatives, sugars (e.g., inositol), alpha-hydroxy fatty acids, phytosterols, triterpenic acids such as methyl esters, ... betulinic or ursolic acid, seaweed extracts.

PRESERVATIVES

[00118] Suitable preservatives which are preferably chosen herein are those such as benzoic acid, its esters and salts, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienoic acid (sorbic acid) and its salts, formaldehyde and paraformaldehyde, 2-hydroxybiphenyl ether and its salts, 2-zinc sulfidopyridine N-oxide, inorganic sulfites and bisulphites, sodium iodate, chlorobutanol, 4-ethylmercuryl(II)-5-amino-1,3-bis(2-hydroxybenzoic acid), its salts and esters, dehydracetic acid, formic acid, 1,6-bis(4-amidino-2-bromophenoxy)-n-hexane and its salts, the sodium salt of ethylmercury(II)- thiosalicylic acid, phenylmercury and its salts, 10-undecylenic acid and its salts, 5-amino-1,3-bis(2-ethylhexyl)-5-methyl-hexahydropyrimidine, 5-bro-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3-propanediol, 2,4-dichlorobenzyl alcohol, N-(4-chlorophenyl)-N’-(3,4-dichlorophenyl)urea, 4-chloro-m-cresol, 2,4,4'-trichloro-2’-hydroxydiphenyl ether, 4-chloro-3,5-dimethylphenol, 1,1'-methylene-bis(3-(1-hydroxymethyl-2,4-dioximidazolidin-5-yl)urea), poly(hexamethylene diguanide) hydrochloride, 2-phenoxyethanol, hexamethylenetetramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azoniaadamantane chloride, 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethyl-2-butanone, 1,3 bis-(hydroxymethyl)- 5,5-dimethyl-2,4-imidazolidinedione, benzyl alcohol, octopirox, 1,2-dibromo-2,4-dicyanobutane, 2,2'-methylenebis(6-bromo-4-chlorophenol), bromochlorophene, mixture of 5-chloro-2-methyl-3(2H)-isothiazolinone and 2-methyl-3(2H)isothiazolinone with magnesium chloride and magnesium nitrate, benzyl-4-chlorophenol , 2-chloroacetamide, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, 1-phenoxypropan-2-ol, N-alkyl(C12-C22)trimethylammonium chloride bromide, 4,4-dimethyl-1,3-oxazolidine, N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)-N'-hydroxymethylurea, 1,6-bis(4-amidinophenoxy)-n-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo[3.3.0]octane, 3-(4-chlorophenoxy)-1,2-propanediol, hyamines, (C8-C18) alkyl chloride dimethylbenzylammonium, (C8-C18)-alkyl dimethylbenzylammonium bromide, (C8-C18)-alkyl dimethylbenzylammonium saccharinate, benzyl hemiformal, 3-iodo-2-propynyl butylcarbamate, sodium hydroxymethylaminoacetate or sodium hydroxymethylaminoacetate.

[00119] In various cases, it may also be advantageous to employ substances which are primarily used to inhibit the growth of undesirable microorganisms on or in animal organisms in the compositions of the invention. In this regard, in addition to conventional preservatives, other active compounds worth mentioning, in addition to the large group of conventional antibiotics, are in particular the products relevant for cosmetics, such as triclosan, climbazole, octoxyglycerol, octopirox (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)-pyridone, 2-aminoethanol), chitosan, farnesol, glycerol monolaurate or combinations of the substances mentioned, which are used, inter alia, against underarm odor, foot odor or the formation of dandruff. Also ingredients having multifunctional properties, including the ability to reduce the growth of bacteria, yeasts and molds, may be used in the compositions covered by the invention. These may include, but are not limited to, pentane 1,2-diol, hexane 1,2-diol, caprylyl 1,2-diol, decyl 1,2-diol, tropolone, hydroxyacetophenone, ethylhexyl glycerin, phenoxyethanol as individual ingredients or a mixture of 2 or more thereof.

[00120] Furthermore, the compositions of the invention may also comprise substances with a cooling action. Individual active cooling compounds which are preferred for use in the context of the present invention are listed below. The skilled person is able to supplement the following list with a large number of other active cooling compounds; the listed active cooling compounds can also be used in combination with each other: l-menthol, d-menthol, racemic menthol, menthone glycerol acetal (trade name: Frescolat®MGA), menthyl lactate (trade name: Frescolat®ML, menthyl lactate is preferably l-menthyl lactate, in particular l-menthyl l-lactate), menthyl ethyl starch oxalate (Frescolat® X-Cool), substituted menthyl-3-carboxylic acid amides (e.g. menthyl-3-carboxylic acid N-ethylamide), 2-isopropyl-N-2,3-trimethylbutanamide, substituted cyclohexanecarboxylic acid amides, 3-menthoxypropane-1,2-diol, 2-hydroxyethyl menthyl carbonate, 2-hydroxypropyl menthyl carbonate, N-acetylglycine menthyl ester, isopulegol, menthyl hydroxycarboxylic acid esters (e.g., menthyl 3-hydroxy-butyrate), monomenthyl succinate, 2-mercaptocyclodecanone, menthyl 2-pyrrolidin-5-onecarboxylate, 2,3-dihydroxy-p-menthane, 3,3,5-trimethylcyclohexanone glycerol ketal, 3-menthyl 3,6-di- and trioxa-alkanoates, 3-menthyl methoxyacetate, icilin.

[00121] In a particular preferred embodiment, the compositions may comprise preservatives chosen from 4-hydroxyacetophenone, o-cymen-5-ol or mixtures thereof.

PERFUME OILS AND FRAGRANCES

[00122] Suitable perfume oils are mixtures of natural and synthetic perfumes. Natural perfumes include extracts of flowers (orris, lavender, rose, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, cumin, juniper), fruit peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calmus), woods (pine, sandalwood, guaiac wood, cedar, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), needles and twigs (firs, spruces, pines, dwarf pines), resins and balsams (galbanum, elemi, benzoin, myrrh, frankincense, opoponax). Animal raw materials, e.g. civet and castor oil, can also be used. Typical synthetic perfume compounds are ester, ether, aldehyde, ketone, alkyd and hydrocarbon type products. Examples of ester type perfume compounds are benzyl acetate, phenoxyethyl isobutyrate, p-tert-cyclohexylacetate, and methyl ester. butyl, linalyl acetate, dimethyl benzyl carbynyl acetate, phenyl ethyl acetate, linalyl benzoate, benzyl formate, ethylmethyl phenyl glycinate, allyl cyclohexyl propionate, styralyl propionate and benzyl salicylate. Ethers include, for example, benzyl ethyl ether, while aldehydes include, for example, the linear alkanals containing 8 to 18 carbon atoms, citral, citronellal, citronelloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal. Examples of suitable ketones are ionones, α-isomethyl ionone and methyl cedryl ketone. Suitable alcohols are anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl ether and terpineol. Hydrocarbons include mainly terpenes and balsams. However, it is preferable to use mixtures of different perfume compounds that together produce a pleasant perfume. Other suitable perfume oils are essential oils of relatively low volatility that are used primarily as aroma components. Examples are sage oil, chamomile oil, clove oil, melissa oil, peppermint oil, cinnamon leaf oil, lime blossom oil, juniper oil, vetiver oil, frankincense oil, galbanum oil, labdanum oil and lavendin oil. The following are preferably used individually or in the form of mixtures: bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, hexyl cinnamaldehyde, geraniol, benzyl acetone, cyclamen aldehyde, linalool, boisambrene, ambroxan, indole, hedione, sandelice, citrus oil, tangerine oil, orange oil, allyl glycolate, cyclovertal, lavendine oil, claria oil, damascane, bourbon geranium oil, cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romillat, irotila and floramat.

DYES

[00123] Suitable colorants are any of the substances suitable and approved for cosmetic purposes, as listed, for example, in the publication "Kosmetische Fârbemittel" of the Farbstoff-kommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pages 81 to 106. Examples include cochineal red A (C.I. 16255), duck blue V (C.I. 42051), indigo carmine (C.I. 73015), chlorophyllin (C.I. 75810), quinoline yellow (C.I. 47005), titanium dioxide (C.I. 77891), indanthrene blue RS (C.I. 69800) and madder lake (C.I. 58000). Luminol can also be present as a luminescent dye. Suitable colored pigments are, for example, titanium dioxide, mica, iron oxides (e.g. Fe2O3 Fe3O4, FeO(OH)) and/or tin oxide. Suitable dyes are, for example, carmine, Berlin blue, chromium oxide green, ultramarine blue and/or manganese violet.

PREPARATIONS

[00124] Preferred compositions according to the present inventions are selected from the group of products for the treatment, protection, care and cleansing of the skin and/or hair or as a make-up product, preferably as a leave-on product (meaning that the one or more compounds of formula (I) remain on the skin and/or hair for a longer period of time, compared to rinse-off products, so that the moisturizing and/or anti-aging and/or healing action thereof is more pronounced). Preferably, the compositions represent alcoholic emulsions and sprays.

[00125] The formulations according to the invention are preferably in the form of an emulsion, for example W/O (water-in-oil), O/W (oil-in-water), W/O/W (water-in-oil-in-water) emulsions, O/W/O (oil-in-water-in-oil) emulsion, PIT emulsion, Pickering emulsion, low-oil emulsion, micro- or nanoemulsion, a solution, for example in oil (fatty oils or fatty acid esters, in particular C2-C30 esters of C6-C32 fatty acids) or silicone oil, dispersion, suspension, cream, lotion or milk, depending on the production method and ingredients, a gel (including hydrogel, hydrodispersion gel, oleogel), spray (for example pump spray or propellant spray) or a foam or an impregnating solution for cosmetic wipes, a detergent, for example, soap, synthetic detergent, liquid wash, shower and bath preparation, bath product (capsule, oil, tablet, salt, bath salt, soap, etc.), effervescent preparation, a skin care product such as, for example, an emulsion (as described above), ointment, paste, gel (as described above), oil, balm, serum, powder (e.g. face powder, body powder), a mask, a pencil, stick, roll-on, pump, aerosol (foaming, non-foaming or after-foaming), a deodorant and/or antiperspirant, mouthwash and mouthwash, a foot care product (including keratolytic, deodorant), an insect repellent, a sunscreen, an after-sun preparation, a shaving product, an aftershave balm, a pre- and after-shave lotion, a depilatory agent, a hair care product such as, for example, shampoo (including 2-in-1 shampoo, anti-dandruff shampoo, baby shampoo, dry scalp shampoo, concentrated shampoo), conditioner, hair tonic, hair water, hair rinse, styling cream, pomade, permanent hold lotion, hair spray, styling aid (e.g. gel or wax), hair straightening agent (detangling agent, relaxer), hair dye such as, for example, temporary direct dye hair dye, semi-permanent hair dye, permanent hair dye, hair conditioner, hair mousse, eye product, makeup, makeup remover or baby product.

[00126] In a preferred embodiment, the compositions represent emulsions (i) comprising an oil phase comprising additives selected from the group consisting of hydrocarbon oils, waxes, silicone oils, natural oils, fatty acid esters, fatty alcohols, antioxidants, chelating agents, skin lightening agents, tanning accelerating agents, insect repellent agents, moisturizing agents, water resistant polymers, and mixtures thereof and/or (b) comprising an aqueous phase comprising additives selected from the group consisting of antioxidants, preservatives, chelators, and mixtures thereof,

[00127] The auxiliary substances and additives may be included in amounts of 5 to 99% of the body weight, preferably 10 to 80% of the body weight, based on the total weight of the formulation. The amounts of cosmetic or dermatological auxiliary agents and perfume additives to be used in each case can be readily determined by the person skilled in the art by simple trial and error, depending on the nature of the particular product.

[00128] The preparations may also contain water in an amount of up to 99% of the body weight, preferably from 5 to 80% of the body weight, based on the total weight of the preparation,

[00129] In another preferred embodiment, according to the present invention, the composition has a UVA protection factor of at least 370 nm, as measured by the Critical Wavelength Method for in vitro determination of UVA protection. The critical wavelength is defined as the wavelength at which the integral of the spectral absorbance curve reaches 90% of the integral over the UV spectrum from 290 to 400 nm. The method of its determination is described in the United States Federal Register FR volume 77, no. 92, June 17, 2011, pages 35664-3565. The minimum critical wavelength allowed to fulfill the broad spectrum protection claim is 370 nm.

[00130] In another preferred embodiment, according to the present invention, the composition is used in a cosmetic, pharmaceutical or dermatological composition, more preferred an active pharmacological composition.

INDUSTRIAL APPLICATION

[00131] Another object of the present invention relates to a non-therapeutic method for protecting human skin and hair against UV radiation comprising or consisting of the following steps: (i) providing the mixture or a composition as defined above, and (ii) placing said mixture or said composition in contact with said human skin or hair.

[00132] Another object of the present invention relates to the use of the mixture and/or the composition, both as defined above, to improve the sensory properties of skin and hair care formulations. Furthermore, the present invention also encompasses the use of the mixture and/or the composition, as defined above, to protect human skin and hair against UV radiation. Finally, the present invention also relates to the use of the mixture and/or the composition, both as defined above, to improve the film-forming properties of skin and hair care formulations,

[00133] For the sake of good order, it is hereby established that all preferred combinations and ranges, including all preferred embodiments, also count with respect to the method and use as described above. Any repetition is therefore not necessary.

[00133] For the sake of good order, it is hereby established that all preferred combinations and ranges, including all preferred embodiments, also count with respect to the method and use as described above. Any repetition is therefore not necessary.

[00134] The following examples are intended to illustrate the present invention without limiting it. All cited quantities, proportions and percentages are, unless otherwise indicated, based on the weight and total amount or total weight of the compositions. EXAMPLES FORMULATION EXAMPLES Example 1 Sunscreen Lotion (O/W), Expected SPF 50+ Manufacturing Procedure

[00135] Add all phase A components together and heat with stirring to 80°C. Then add Carbopol® and Keltrol® with stirring. Add all phase C components together and heat to 80°C with stirring, then add to phase A/B. Homogenize with an Ultra Turrax® (13000 rpm/1 minute per 100g of emulsion). Cool to room temperature while stirring and add phase D with stirring. Example 2 Sunscreen lotion (O/W), expected SPF 50+

Manufacturing Procedure

[00136] Add all phase A components together and heat with stirring to 80°C, then add Keltrol® with stirring. Add all phase C components together and heat with stirring to 80°C, then add to phase A/B. Homogenize with an Ultra Turrax® (13000 rpm/1 minute per 100g emulsion). Then add Phase D with stirring. Cool to room temperature while stirring. Example 3 Sunscreen lotion (O/W) - SPF 50 expected Manufacturing Procedure

[00103] Add all phase A components together and stir until homogeneous. Then add Aristoflex® with stirring. Add all phase C components together and heat to 80°C with stirring, then add to phase A/B. Homogenize with an Ultra Turrax® (13000rpm/1 minute per 100g emulsion). Cool to room temperature while stirring. Then add Phase D with stirring. Example 4 Sunscreen lotion (O/W) - SPF 50 expected 97/124 98/124

Manufacturing Procedure

[00137] Add all phase A components together and heat with stirring to 80°C. Add all phase B components except for Aristoflex together and heat with stirring to 80°C. Then add Aristoflex® with stirring, and homogenize with an Ultra Turrax® (13000 rpm/1 minute per 100g of emulsion); Cool to room temperature while stirring, Add phase C with stirring. Example 5 Very low viscosity sunscreen lotions (O/W) - SPF 50 expected

Manufacturing Procedure

[00138] Add all phase A components together and heat to 80°C with stirring until homogeneous. Add the first four components of Phase B together with stirring until all the Neo Heliopan Hydro®ter has dissolved. Add the remaining phase B components together with stirring while heating to 80°C. Add phase B to phase A with stirring, and homogenize with an Ultra Turrax® (13000 rpm/ 1 minute per 100g of emulsion). Cool to room temperature while stirring and add phase C with stirring. Example 6Very low viscosity sunscreen lotions (O/W) - SPF 50+ expected 102/124 103/124

Manufacturing Procedure

[00139] Add all phase A components together and heat to 80°C with stirring until homogeneous. Add the first four components of Phase B together with stirring until all the Neo Helio pan Hydro® has dissolved. Add the remaining phase B components together with stirring whilst heating to 80°C. Add phase B to phase A with stirring, and homogenize with an Ultra Turrax® (13000rpm/1 minute per 100g of emulsion). Cool to room temperature whilst stirring and add phase C with stirring. Example 7Sunscreen Oils - SPFs 50+ and 30 expected Manufacturing Procedure

[00140] Mix all components together except the fragrance and heat to 60°C with stirring until a clear homogeneous solution is obtained. Cool to room temperature and then add the fragrance with stirring. Example 8 Anti-Aging Sunscreen Lotion (O/W) - SPF 30 expected 104/124 105/124 106/124

Manufacturing Procedure

[00140] Phase A: Mix the components without Keltrol®CG-T to approximately 85°C, Homogenize for a short time with an Ultra Turrax®. Phase B: Mix the components and heat to approximately 80°C until dissolved. Add phase B to phase A while stirring. Cool while stirring to 60°C and homogenize with an Ultra Turrax®. Then cool to room temperature while stirring. Phase C: Add all ingredients step by step and stir until homogenized with an Ultra Turrax®. Example 9 Sunscreen spray - SPF 50 expected 107/124

Manufacturing Procedure

[00141] Phase A: Mix the ingredients without Pemulen®TR2 to approximately 80°C with stirring. Add Pemulen®TR2 and homogenize for a short time, approximately 0.5 min, with an Ultra Turrax® T25. Phase B: Dissolve ExpertGel® in water while stirring. When dissolved, add the remaining ingredients and stir until a clear solution is obtained. Heat slightly if necessary to solubilize SymSave®H. Add the water phase B without stirring to the hot oil phase A. Homogenize with an Ultra Turrax® for approximately 5 min. Stir until cool. Phase C: Mix the addition ingredients and then phase A/B. Cool while stirring. Phase D: Add these separately to phases A/B/C with stirring at room temperature. Then homogenize for a short time. Example 10 Broad Spectrum O/W Water Resistant - SPF 50+ expected

Manufacturing Procedure

[00142] Phase A: Heat all components except Xanthan Gum to 85°C. Then add Xanthan Gum and mix. Phase B: Heat all components to 85°C and add to Part A with stirring, stir to room temperature, Phase C: Add Part C to Parts A & B and mix. Example 11 Sunscreen lotion with tanning accelerator - SPF 30 expected 109/124 110/124

Manufacturing Procedure

[00143] Phase A: Mix the ingredients to approximately 85°C without Keltrol® and Aristoflex®, when all the ingredients are dissolved, add Keltrol® and Aristoflex® and homogenize with an Ultra Turrax® for a short time. Part B: Mix the ingredients with stirring to approximately 80°C. Add the hot phase B to the hot phase A. Cool with stirring to 60°C and start homogenization with an Ultra Turrax®. Cool to room temperature while stirring. Part C: Add the ingredients with stirring and homogenize for a short time. Example 12 CC Cream - SPF 50 expected 112/124 113/124

Manufacturing Procedure

[00144] Phase A: Mix the ingredients to approximately 85°C without Keltrol®, Aristoflex®, when all the ingredients are dissolved, add Keltrol®, Aristoflex® and homogenize with an Ultra Turrax® for a short period of time. Phase B: Add the water and neutralizing agents Biotive® L-Arginine and the sodium hydroxide solution and stir until homogeneous. Then add the Neo Heliopan® Hydro and stir until everything is dissolved. Add the remaining ingredients without Dragocolor® to phase B and heat to approximately 80°C, add Dragocolor® and homogenize for a short period of time then add the hot phase B to the hot phase A. Cool while stirring to 60°C and start homogenization with an Ultra Turrax® (13000 rpm/1 minute per 100g emulsion). Cool to room temperature while stirring. Part C: Add the ingredients to parts A/B as listed with stirring. Part D: Add the ingredients with stirring and homogenize for a short period of time. Example 13 Sunscreen sticks - expected SPFs of 30 and 50+

Manufacturing Procedure

[00145] Phase A: Mix the ingredients and heat with stirring to approximately 80°C. Maintain the temperature. Phase B: Mix the ingredients then add phase B to phase A and homogenize. Maintain the temperature. Stir slowly to allow entrapped air to escape from the mass, transfer to rod holders at 75 to 80°C. Example 14 Sunscreen cream (W/O) - expected SPF 50, water resistant

Manufacturing Procedure

[00146] Part A: Mix the ingredients with agitation at approximately 85°C. Part B: Mix the ingredients with agitation at approximately 85°C then add to phase A. Allow to cool with agitation then homogenize. Part C: Stir at room temperature. Example 15 Water resistant alcohol spray - SPF 50 expected

Manufacturing Procedure

[00147] Part A: Disperse the Dermacrila and KP-545 in the alcohol and then mix the other Ingredients with stirring at approximately 60°C and cool to room temperature. Part B: Mix the Ingredients with stirring at room temperature then add A with stirring and then homogenize. Part C: Stir at room temperature. Example 16 Anti-aging facial lotion (O/W) - expected SPF > 50 115/124 116/124 117/124 118/124 120/124

Manufacturing Procedure

[00148] Phase A: Mix the components without silica and Pemulen to approximately 85°C, then add the other parts. Homogenize briefly with an Ultra Turrax®. Phase B: Mix the components and heat to approximately 50°C until dissolved. Homogenize briefly with an Ultra Turrax®. Add phase B to phase A while stirring. Cool while stirring to 30°C and homogenize with an Ultra Turrax®. Then cool to room temperature while stirring. Phase C: Add all ingredients step by step and stir until homogeneous with an Ultra Turrax®. Example 17 Broad spectrum O/W water resistant - SPF 50+ without octocylene expected 122/124

Manufacturing Procedure

[00149] Phase A: Heat all components except Xanthan Gum to 85°C. Then add Xanthan Gum and homogenize. Phase B: Heat all components to 85°C and add to Part A with stirring, stir to room temperature, Phase C: Add Part C to Parts A & B and homogenize.

Example 18 Sunscreen Lotion (O/W) - Expected SPF 50+ Octinoxate and Oxybenzone Free Manufacturing Procedure

[00150] Phase A: Heat all components except xanthan gum to 85°C. Then add the xanthan gum and mix. Phase B: Dissolve all ingredients of phase B at room temperature and add to Part A and mix. Stir at room temperature. Phase C: Add Part C to Parts A and B and mix until homogeneous. 124/124

Claims (13)

1. Mixture for improving sun protection of compositions comprising UV filters, characterized by the fact that it consists of (a) beeswax; and (b) sodium stearoyl lactylate. 2. Composition, characterized by the fact that it comprises the mixture, as defined in claim 1, the composition further comprising at least one UVA filter selected from the group consisting of: • Butyl methoxydibenzoylmethane (Neo Heliopan® 357) • Terephthalylidene dibornanesulfonic acid and salts (Mexoryl® SX), • Hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (Uvinul®A Plus), • Methyl anthranilate (Neo Heliopan®MA), • 2,2’-(1,4-phenylene)bis-[1H-benzimidazole-4,5-disulfonic acid], disodium salt (Neo Heliopan®AP), • Methoxy Propylamino Cyclohexenylidene Ethoxyethyl Cyanoacetate, and mixtures thereof; and the composition further comprising at least one UVB filter selected from the group consisting of: • Octocrylene (Neo Heliopan®303) • Homosalate (Neo Heliopan®HMS) • Octisalate (Neo Heliopan®OS) • 2-ethylhexyl p-dimethylaminobenzoate; • Triethanolamine salicylate (Neo Heliopan®TS); • 2-ethylhexyl p-methoxycinnamate (Neo Heliopan®AV); • Isoamyl p-methoxycinnamate (Neo Heliopan®E 1000); • 2-phenylbenzimidazole sulfonic acid (Neo Heliopan® Hydro) and its salts • 3-(4'-methylbenzylidene)-d,l-camphor (Neo Heliopan®MBC) • 4,4’-[(6-[4-(1,1-dimethyl)aminocarbonyl)phenylamino]-1,3,5-triazine-2,4-di-yl)di-imino]bis(2-ethylhexylbenzoic acid ester) (Uvasorb®HEB); • Benzylidenemalonate-polysiloxane (Parsol®SLX); • (Tris(2-ethylhexyl)4,4',4"-(1,3,5-triazine-2,4,6-tri-yl-triimino)tribenzoate (Uvinul®T150); • Methoxy Propylamino Cyclohexenylidene Ethoxyethyl Cyanoacetate; and mixtures thereof. 3. Composition according to claim 2, characterized in that it further comprises at least one wide-band filter selected from the group consisting of: • Bis-Ethylhexyloxyphenyl Methoxyphenyl Triazine (Neo Heliopan® BMT) • 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid (sulisobenzone, benzophenone-4) or its salts, • 2-hydroxy-4-methoxybenzophenone (Neo Heliopan®BB, Oxybenzone, benzophenone-3) • Phenol, -(2H-benzotriazol-2-yl-4-methyl-6-(2-methyl-3-(1,3,3,3-tetramethyl-1-(trimethylsilyl)oxy)disyloxyanyl)propyl), (Mexoryl®XL) • 2,2'-methylenebis(6-(2H-benztriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)-phenol), Tinosorb®M) • Tris-Biphenyl Triazine (Tinosorb®A2B); • (5,6, 5',6'-tetraphenyl-3,3'-(1,4-Phenylene)bis(1,2,4-triazine); and mixtures thereof. 4. Composition according to claim 2 or 3, characterized in that it further comprises at least one pigment selected from the group consisting of zinc oxide, titanium dioxide and mixtures thereof. 5. Composition according to any one of claims 2 to 4, characterized in that it presents a sun protection factor (SPF) of at least 2. 6. Composition according to any one of claims 2 to 5, characterized in that it has a UVA protection factor of at least 370 nm. 7. Composition according to any one of claims 2 to 6, characterized in that it presents a ratio between the UVA absorbance and the total UVB + UVA absorbance that is greater than or equal to 0.70. 8. Composition according to any one of claims 2 to 7, characterized in that it further comprises at least one 1,2-alkanediol having from 5 to 12 carbon atoms. 9. Composition according to any one of claims 2 to 8, characterized in that it further comprises 4-hydroxyacetophenone, o-cymen-5-ol or mixtures thereof. 10. Composition according to any one of claims 2 to 9, characterized in that it further comprises emulsifiers selected from the group consisting of alkyl phosphates, glyceryl oleate citrates, glyceryl stearate citrates, stearic acid esters, sorbitan esters, ethoxylated sorbitan esters, ethoxylated mono-, di- and tri-glycerides, methyl glucose esters. 11. Use of the mixture as defined in claim 1 and/or the composition as defined in any one of claims 2 to 10, characterized in that it is for protecting human skin and hair against UV radiation. 12. Use of the mixture as defined in claim 1 and/or the composition as defined in any one of claims 2 to 10 for improving the film-forming properties of skin and hair care formulations. 13. Use of the mixture as defined in claim 1 and/or the composition as defined in any one of claims 2 to 10 for improving the sensory properties of skin and hair care formulations.