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BR122019010641B1 - combination, method to control harmful phytopathogenic fungi and use of said combination - Google Patents

combination, method to control harmful phytopathogenic fungi and use of said combination Download PDF

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Publication number
BR122019010641B1
BR122019010641B1 BR122019010641-0A BR122019010641A BR122019010641B1 BR 122019010641 B1 BR122019010641 B1 BR 122019010641B1 BR 122019010641 A BR122019010641 A BR 122019010641A BR 122019010641 B1 BR122019010641 B1 BR 122019010641B1
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BR
Brazil
Prior art keywords
plants
species
plant
event
methyl
Prior art date
Application number
BR122019010641-0A
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Portuguese (pt)
Inventor
Ulrike Wachendorff-Neumann
Sebastian Hoffmann
Pierre Wasnaire
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Bayer Intellectual Property Gmbh
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Application filed by Bayer Intellectual Property Gmbh filed Critical Bayer Intellectual Property Gmbh
Publication of BR122019010641B1 publication Critical patent/BR122019010641B1/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
    • A01N45/02—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring having three carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14—Di-thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
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    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
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    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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    • A01N59/16—Heavy metals; Compounds thereof
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  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
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Abstract

A presente invenção diz respeito a uma combinação compreendendo pelo menos uma tiazolilisoxazolina de fórmula (I) e um fluopirame. Além disso, o presente pedido diz respeito a um método para controle de fungos fitopatogênicos prejudiciais compreeendendo a referida combinação aplicada aos fungos fitopatogênicos prejudiciais e/ou ao seu habitat, e o uso da referida combinação para o controle de fungos fitopatogênicos prejudiciais para o tratamento de plantas transgênicas, bem como para o tratamento de sementes e de sementes de plantas transgênicas.The present invention relates to a combination comprising at least one thiazolylisoxazoline of formula (I) and a fluopyram. In addition, the present application concerns a method for controlling harmful phytopathogenic fungi comprising the aforementioned combination applied to harmful phytopathogenic fungi and / or their habitat, and the use of said combination for the control of harmful phytopathogenic fungi for the treatment of transgenic plants, as well as for the treatment of seeds and seeds of transgenic plants.

Description

[001] A presente invenção diz respeito a combinações de compostos ativos, em particular, em uma composição fungicida, que compreendem (A) uma tiazolilisoxazolina de fórmula estrutural (I) e um outro composto ativo sob o ponto de vista fungicida (B). Além disso, a invenção diz respeito a um método para controlar curativa ou preventivamente os fungos fitopatogénicos de plantas ou de culturas, à utilização de uma combinação de acordo com a invenção para o tratamento de sementes, a um método para a protecção de sementes e ainda às sementes tratadas.[001] The present invention relates to combinations of active compounds, in particular, in a fungicidal composition, which comprise (A) a thiazolylisoxazoline of structural formula (I) and another fungicidal active compound (B). In addition, the invention relates to a method to curatively or preventively control phytopathogenic fungi from plants or crops, to the use of a combination according to the invention for seed treatment, to a method for protecting seeds and yet treated seeds.

[002] Sabe-se já que determinadas tiazolilisoxazolinas podem ser utilizadas como fungicidas (ver, documentos WO 2008/013925, WO 2008/013622, WO 2009/094407, WO 2009/094445, WO 2009/055514, WO 2010/065579, WO 2011/85170 e WO 2011/076699).[002] It is already known that certain thiazolylisoxazolines can be used as fungicides (see, WO 2008/013925, WO 2008/013622, WO 2009/094407, WO 2009/094445, WO 2009/055514, WO 2010/065579, WO 2011/85170 and WO 2011/076699).

[003] Visto que os requisitos ecológicos e económicos em termos de ingredientes ativos modernos, por exemplo, fungicidas, estão constantemente a aumentar, por exemplos, no que diz respeito ao espectro de atividade, à toxicidade, à selectividade, à taxa de aplicação, à formação de resíduos e a uma produção favorável, podendo ainda existir problemas, por exemplo, em termos de resistências, existe uma necessidade constante para o desenvolvimento de novas composições fungicidas que apresentem vantagens, pelo menos em algumas áreas, sobre as composições conhecidos.[003] Since ecological and economic requirements in terms of modern active ingredients, for example, fungicides, are constantly increasing, for example, with regard to the spectrum of activity, toxicity, selectivity, application rate, the formation of residues and a favorable production, although there may still be problems, for example, in terms of resistance, there is a constant need for the development of new fungicidal compositions that present advantages, at least in some areas, over the known compositions.

[004] A presente invenção proporciona combinações/composições de compostos ativos que, em alguns aspectos, atingem o objectivo referido.[004] The present invention provides combinations / compositions of active compounds that, in some aspects, achieve the stated objective.

[005] De um modo surpreendente, concluiu-se agora que as combinações de acordo com a invenção proporcionam não apenas o aumento do espectro de ação no que diz respeito ao patogénio a controlar, o que seria em princípio esperado, mas alcançam um efeito sinergístico que excede o intervalo de ação do componente (A) e do componente (B) de duas formas. Em primeiro lugar, as taxas de aplicação do componente (A) e do componente (B) são reduzidas ao passo que a ação permanece igualmente boa. Em segundo lugar, a combinação atinge ainda um elevado grau de controle do fitopatogênio, mesmo quando os dois compostos individuais se tornaram totalmente ineficazes para um tal intervalo de taxas de aplicação reduzido. Por um lado, tal permite um alargamento substancial do espectro de fitopatogênios que é possível controlar e, por outro lado, um aumento da segurança durante a utilização.[005] Surprisingly, it has now been concluded that the combinations according to the invention provide not only an increase in the spectrum of action with respect to the pathogen to be controlled, which would in principle be expected, but achieve a synergistic effect which exceeds the action range of component (A) and component (B) in two ways. First, the application rates for component (A) and component (B) are reduced while the action remains equally good. Second, the combination still achieves a high degree of phytopathogen control, even when the two individual compounds have become totally ineffective for such a reduced range of application rates. On the one hand, this allows for a substantial widening of the spectrum of phytopathogens that can be controlled and, on the other hand, an increase in safety during use.

[006] Para além da atividade fungicida sinergística, as combinações de compostos ativos de acordo com a invenção possuem outras propriedades surpreendentes, as quais, em um sentido mais amplo, também podem ser designadas sinergísticas, tais como, por exemplo:[006] In addition to the synergistic fungicidal activity, the combinations of active compounds according to the invention have other surprising properties, which, in a broader sense, can also be called synergistic, such as, for example:

[007] Para além da atividade fungicida sinergística, as combinações de compostos ativos de acordo com a invenção possuem outras propriedades surpreendentes que, em um sentido mais amplo, também podem ser designadas como sinergísticas, tais como, por exemplo: alargamento do espectro de atividade a outros fitopatogênios, por exemplo, a estirpes resistentes de doenças de plantas; taxas de aplicação mais baixas dos compostos ativos; controle suficiente de pragas com o auxílio das combinações de compostos ativos de acordo com a invenção mesmo a taxas de aplicação para as quais os compostos individuais apresentam nenhuma ou virtualmente nenhuma atividade; comportamento vantajoso durante a formulação ou durante a utilização, por exemplo, durante a moagem, crivagem, emulsionamento, dissolução ou dispersão; estabilidade ao armazenamento ou estabilidade à luz melhoradas; formação vantajosa de resíduos; comportamento toxicológico ou ecotoxicológico melhorado; propriedades melhoradas da planta, por exemplo, melhor crescimento, rendimentos de colheita aumentados, um sistema de raízes com melhor desenvolvimento, uma área de folha mais larga, folhas mais verdes, rebentos mais fortes, menos sementes necessárias, fitotoxicidade inferior, mobilização do sistema de defesa da planta, boa compatibilidade com plantas. Assim, a utilização das combinações ou composições de compostos ativos de acordo com a invenção contribui consideravelmente para manter as plantas de cereais jovens saudáveis, o que aumenta, por exemplo, a sobrevivência ao inverno das sementes de cereais tratadas, garantindo também a qualidade e o rendimento. Além do mais, as combinações de compostos ativos de acordo com a invenção podem contribuir para uma ação sistémica aumentada. Mesmo no caso dos compostos individuais da combinação não apresentarem propriedades sistémicas suficientes, as combinações de compostos ativos de acordo com a invenção podem ainda apresentar esta propriedade. De um modo semelhante, as combinações de compostos ativos de acordo com a invenção podem proporcionar uma persistência mais elevada da ação fungicida.[007] In addition to the synergistic fungicidal activity, the combinations of active compounds according to the invention have other surprising properties that, in a broader sense, can also be designated as synergistic, such as, for example: widening the activity spectrum other phytopathogens, for example, resistant strains of plant diseases; lower application rates of active compounds; sufficient pest control with the aid of combinations of active compounds according to the invention even at application rates for which the individual compounds have no or virtually no activity; advantageous behavior during formulation or during use, for example, during milling, sieving, emulsifying, dissolving or dispersing; improved storage stability or light stability; advantageous waste formation; improved toxicological or ecotoxicological behavior; improved plant properties, for example, better growth, increased crop yields, a better developed root system, a wider leaf area, greener leaves, stronger shoots, less seeds needed, lower phytotoxicity, mobilization of the plant defense, good compatibility with plants. Thus, the use of combinations or compositions of active compounds according to the invention contributes considerably to keeping young cereal plants healthy, which increases, for example, the winter survival of treated cereal seeds, also guaranteeing the quality and Yield. Furthermore, the combinations of active compounds according to the invention can contribute to an increased systemic action. Even if the individual compounds in the combination do not have sufficient systemic properties, the combinations of active compounds according to the invention can still have this property. Similarly, combinations of active compounds according to the invention can provide a higher persistence of the fungicidal action.

[008] Assim sendo, a presente invenção proporciona uma combinação que compreende: (A) pelo menos uma tiazolilisoxazolina de formula estrutural (I)

Figure img0001
em que[008] Accordingly, the present invention provides a combination comprising: (A) at least one thiazolylisoxazoline of structural formula (I)
Figure img0001
on what

[009] o símbolo R1 representa fenila, que é pelo menos substituído com um metilsulfoniloxi e, facultativamente, pode ser adicionalmente substituído com um substituinte seecionado entre o conjunto constituído por metil, metoxi, flúor ou cloro,[009] the symbol R1 represents phenyl, which is at least replaced with a methylsulfonyloxy and, optionally, can be additionally substituted with a substituent selected from the group consisting of methyl, methoxy, fluorine or chlorine,

[010] ou um seu sal aceitável sob o ponto de vista agroquímico,[010] or an agrochemical acceptable salt thereof,

[011] e (B) pelo menos um outro composto ativo seecionado entre os conjuntos seguintes (1) inibidores da síntese de ergosterol, (2) inibidores da cadeia respiratória no complexo I ou II, (3) inibidores da cadeia respiratória no complexo III, (4) inibidores da mitose e da divisão celular, (5) compostos capazes de apresentar uma ação multilocal, (6) compostos capazes de induzir uma defesa no hospedeiro, (7) inibidores da biossíntese de aminoácidos e/ou de proteínas, (8) inibidores da produção de ATP, (9) inibidores da síntese da parede celular, (10) inibidores da síntese de lípidos e de membranas, (11) inibidores da biossíntese de melanina, (12) inibidores da síntese de ácidos nucleicos, (13) inibidores da transdução de sinal, (14) compostos capazes de actuar como desacoplador, (15) outros fungicidas.[011] and (B) at least one other active compound selected from the following sets (1) inhibitors of ergosterol synthesis, (2) respiratory chain inhibitors in complex I or II, (3) respiratory chain inhibitors in complex III , (4) inhibitors of mitosis and cell division, (5) compounds capable of having a multilocal action, (6) compounds capable of inducing a defense in the host, (7) inhibitors of amino acid and / or protein biosynthesis, ( 8) inhibitors of ATP production, (9) inhibitors of cell wall synthesis, (10) inhibitors of lipid and membrane synthesis, (11) inhibitors of melanin biosynthesis, (12) inhibitors of nucleic acid synthesis, ( 13) signal transduction inhibitors, (14) compounds capable of acting as a decoupler, (15) other fungicides.

[012] São preferidas as combinações que compreendem pelo menos um composto de fórmula estrutural (I) seecionado entre o conjunto constituído por (I-1) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-fenila, (I-2) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-6- fluorofenila, (I-3) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-3- clorofenila, (I-4) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-5- metilfenila, (I-5) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-5- clorofenila, (I-6) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-4- metilfenila, (I-7) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-4- clorofenila, (I-8) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-6- clorofenila.[012] Combinations comprising at least one compound of structural formula (I) selected from the group consisting of 2- {3- [2- (1 - {[3,5 (2- {3- [2- (1 - {[3,5 -bis- (difluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazole -5-yl} -phenyl, 2- {3- [2- (1 - {[3,5-bis- (difluoromethyl) -1H-pyrazol-1-yl] -acetyl (I-2) methanesulfonate } -piperidine-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -6-fluorophenyl, (I-3) methane- 2- {3- [2- (1 - {[3,5-bis- (difluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4-yl) - 1,3-thiazole sulfonate 4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl, 2- {3- [2- (1 - {[ 3,5-bis- (difluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1, 2- {3- [2- (1 - {[3,5-bis- (difluoromethyl) -1H-pyrazole-2-oxazol-5-yl} -5-methylphenyl, -1H-pyrazol-1 -yl] -acetyl} -piperidine-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -5-chlorophenyl, (I -6) methane 2- {3- [2- (1 - {[3,5-bis- (difluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4-yl)-1,3-thiazole sulfonate -4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -4-methylphenyl, 2- {3- [2- (1- { [3,5-bis- (difluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1 , 2-oxazol-5-yl} -4-chlorophenyl, 2- {3- [2- (1 - {[3,5-bis- (difluoromethyl) -1H-pyrazole- (2-methanesulfonate) -1H-pyrazole- 1-yl] -acetyl} -piperidine-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -6-chlorophenyl.

[013] Na descrição seguinte, os números entre parêntesis à frente de um nome de composto representam o n° de registo CAS do referido composto.[013] In the following description, the numbers in parentheses in front of a compound name represent the CAS registration number of that compound.

[014] São ainda preferidas as combinações que compreendem pelo menos um outro composto ativo (B) seecionado entre os conjuntos seguintes: ((1) inibidores da biossíntese de ergosterol, por exemplo, (1.1) aldimorf (1704-28-5), (1.2) azaconazole (60207-31-0), (1.3) bitertanol (55179-31-2), (1.4) bromuconazole (116255-48-2), (1.5) ciproconazole (113096- 99-4), (1.6) diclobutrazole (75736-33-3), (1.7) difenoconazole (119446-68-3), (1.8) diniconazole (83657-24- 3), (1.9) diniconazole-M (83657-18-5), (1.10) dodemorf (1593-77-7), (1.11) acetato de dodemorf (31717-87-0), (1.12) epoxiconazole (106325-08-0), (1.13) etaconazole (60207-93-4), (1.14) fenarimol (60168-88-9), (1.15) fenbuconazole (114369-43-6), (1.16) fen-hexamida (126833-17-8), (1.17) fenpropidina (67306-00-7), (1.18) fenpropimorf (67306-03-0), (1.19) fluquinconazole (136426- 54-5), (1.20) flurprimidol (56425-91-3), (1.21) flusilazole (85509-19-9), (1.22) flutriafol (76674-21-0), (1.23) furconazole (112839-33-5), (1.24) furconazole-cis (112839- 32-4), (1.25) hexaconazole (79983-71-4), (1.26) imazalila (60534-80-7), (1.27) sulfato de imazalila (58594-72-2), (1.28) imibenconazole (86598-92-7), (1.29) ipconazole (125225-28-7), (1.30) metconazole (125116-23-6), (1.31) miclobutanila (88671-89-0), (1.32) naftifina (65472-88-0), (1.33) nuarimol (63284-71-9), (1.34) oxpoconazole (174212- 12-5), (1.35) paclobutrazol (76738-62-0), (1.36) pefurazoato (101903-30-4), (1.37) penconazole (66246-88-6), (1.38) piperalina (3478-94-2), (1.39) procloraz (67747-09- 5), (1.40) propiconazole (60207-90-1), (1.41) protioconazole (178928-70-6), (1.42) piributicarb (88678- 67-5), (1.43) pirifenox (88283-41-4), (1.44) quinconazole (103970-75-8), (1.45) simeconazole (149508-90-7), (1.46) espiroxamina (118134-30-8), (1.47) tebuconazole (107534-96- 3), (1.48) terbinafina (91161-71-6), (1.49) tetraconazole (112281-77-3), (1.50) triadimefona (43121-43-3), (1.51) triadimenol (89482-17-7), (1.52) tridemorf (81412-43-3), (1.53) triflumizole (68694-11-1), (1.54) triforina (26644- 46-2), (1.55) triticonazole (131983-72-7), (1.56) uniconazole (83657-22-1), (1.57) uniconazole-p (83657-17- 4), (1.58) viniconazole (77174-66-4), (1.59) voriconazole (137234-62-9), (1.60) 1-(4-clorofenil)-2-(1H-1,2,4-triazol1-il)-ciclo-heptanol (129586-32-9), (1.61) 1-(2,2-dimetil2,3-di-hidro-1H-indeno-1-il)-1H-imidazol-5-carboxilato de metila (110323-95-0), (1.62) N'-{5-(difluorometil)-2-metil4-[3-(trimetilsilil)-propoxi]-fenil}-N-etil-Nmetilimidoformamida, (1.63) N-etil-N-metil-N'-{2-metil-5- (trifluorometil)-4-[3-(trimetilsilil)-propoxi]-fenil}- imidoformamida, (1.64) 1H-imidazol-1-carbotioato de O-[1- (4-metoxifenoxi)-3,3-dimetilbutano-2-il] (111226-71-2); (2) inibidores da cadeia respiratória no complexo I ou II, por exemplo, (2.1) bixafeno (581809-46-3), (2.2) boscalid (188425-85-6), (2.3) carboxina (5234-68-4), (2.4) diflumetorim (130339-07-0), (2.5) fenfuram (24691-80-3), (2.6) fluopiram (658066-35-4), (2.7) flutolanila (66332-96- 5), (2.8) fluxapiroxad (907204-31-3), (2.9) furametpir (123572-88-3), (2.10) furmeciclox (60568-05-0), (2.11) isopirazam (mistura de racemato syn-epimérico 1RS,4SR,9RS e de racemato anti-epimérico 1RS,4SR,9SR) (881685-58-1), (2.12) isopirazam (racemato anti-epimérico 1RS,4SR,9SR), (2.13) isopirazam (enantiómero anti-epimérico 1R,4S,9S), (2.14) isopirazam (enantiómero anti-epimérico 1S,4R,9R), (2.15) isopirazam (racemato syn-epimérico 1RS,4SR,9RS), (2.16) isopirazam (enantiómero syn-epimérico 1R,4S,9R), (2.17) isopirazam (enantiómero syn-epimérico 1S,4R,9S), (2.18) mepronila (55814-41-0), (2.19) oxicarboxina (5259- 88-1), (2.20) penflufeno (494793-67-8), (2.21) pentiopirad (183675-82-3), (2.22) sedaxano (874967-67-6), (2.23) tifluzamida (130000-40-7), (2.24) 1-metil-N-[2-(1,1,2,2- tetrafluoroetoxi)-fenil]-3-(trifluorometil)-1H-pirazole-4- carboxamida, (2.25) 3-(difluorometil)-1-metil-N-[2- (1,1,2,2-tetrafluoroetoxi)-fenil]-1H-pirazole-4- carboxamida, (2.26) 3-(difluoro-metil)-N-[4-flúor-2- (1,1,2,3,3,3-hexafluoropropoxi)-fenil]-1-metil-1H-pirazole4-carboxamida, (2.27) N-[1-(2,4-diclorofenil)-1-metoxipropano-2-il]-3-(difluorometil)-1-metil-1H-pirazole4-carboxamida (1092400-95-7), (2.28) 5,8-diflúor-N-[2-(2- flúor-4-{[4-(trifluorometil)-piridina-2-il]-oxi}-fenil)- etil]-quinazolina-4-amina (1210070-84-0), (2.29) benzovindiflupir, (2.30) N-[(1S,4R)-9-(diclorometileno)- 1,2,3,4-tetra-hidro-1,4-metanonaftaleno-5-il]-3- (difluorometil)-1-metil-1H-pirazole-4-carboxamida, (2.31) N-[(1R,4S)-9-(diclorometileno)-1,2,3,4-tetra-hidro-1,4- metanonaftaleno-5-il]-3-(difluorometil)-1-metil-1Hpirazole-4-carboxamida, (2.32) 3-(difluorometil)-1-metil-N- (1,1,3-trimetil-2,3-di-hidro-1H-indeno-4-il)-1H-pirazol-4- carboxamida, (2.33) 1,3,5-trimetil-N-(1,1,3-trimetil-2,3- di-hidro-1H-indeno-4-il)-1H-pirazol-4-carboxamida, (2.34) 1-metil-3-(trifluorometil)-N-(1,3,3-trimetil-2,3-di-hidro1H-indeno-4-il)-1H-pirazol-4-carboxamida, (2.35) 1-metil-3- (trifluorometil)-N-[(1S)-1,3,3-trimetil-2,3-di-hidro-1Hindeno-4-il]-1H-pirazol-4-carboxamida, (2.36) 1-metil-3- (trifluorometil)-N-[(1R)-1,3,3-trimetil-2,3-di-hidro-1Hindeno-4-il]-1H-pirazol-4-carboxamida, (2.37) 3- (difluorometil)-1-metil-N-[(3S)-1,1,3-trimetil-2,3-dihidro-1H-indeno-4-il]-1H-pirazol-4-carboxamida, (2.38) 3- (difluorometil)-1-metil-N-[(3R)-1,1,3-trimetil-2,3-dihidro-1H-indeno-4-il]-1H-pirazol-4-carboxamida, (2.39) 1,3,5-trimetil-N-[(3R)-1,1,3-trimetil-2,3-di-hidro-1Hindeno-4-il]-1H-pirazol-4-carboxamida, (2.40) 1,3,5- trimetil-N-[(3S)-1,1,3-trimetil-2,3-di-hidro-1H-indeno-4- il]-1H-pirazol-4-carboxamida; (3) inibidores da cadeia respiratória no complexo III, por exemplo, (3.1) ametoctradina (865318-97-4), (3.2) amisulbrom (348635-87-0), (3.3) azoxistrobina (131860-33-8), (3.4) ciazofamida (120116-88-3), (3.5) coumetoxistrobina (850881-30-0), (3.6) coumoxistrobina (850881-70-8), (3.7) dimoxistrobina (141600-52-4), (3.8) enestroburina (238410-11-2), (3.9) famoxadona (131807-57- 3), (3.10) fenamidona (161326-34-7), (3.11) fenoxistrobina (918162-02-4), (3.12) fluoxastrobina (361377-29-9), (3.13) cresoxim-metila (143390-89-0), (3.14) metominostrobina (133408-50-1), (3.15) orisastrobina (189892-69-1), (3.16) picoxistrobina (117428-22-5), (3.17) piraclostrobina (175013-18-0), (3.18) pirametostrobina (915410-70-7), (3.19) piraoxistrobina (862588-11-2), (3.20) piribencarb (799247-52-2), (3.21) triclopiricarb (902760-40-1), (3.22) trifloxistrobina (141517-21-7), (3.23) (2E)-2-(2-{[6-(3- cloro-2-metilfenoxi)-5-fluoropirimidina-4-il]-oxi}-fenil)- 2-(methoxi-imino)-N-metiletanamida, (3.24) (2E)-2-(metoxiimino)-N-metil-2-(2-{[({(1E)-1-[3-(trifluorometil)-fenil]- etilideno}-amino)-oxi]-metil}-fenil)-etanamida, (3.25) (2E)-2-(metoxi-imino)-N-metil-2-{2-[(E)-({1-[3- (trifluorometil)-fenil]-etoxi}-imino)-metil]-fenil}- etanamida (158169-73-4), (3.26) (2E)-2-{2-[({[(1E)-1-(3- {[(E)-1-flúor-2-feniletenil]-oxi}-fenil)-etilideno]-amino}- oxi)-metil]-fenil}-2-(metoxi-imino)-N-metiletanamida (326896-28-0), (3.27) (2E)-2-{2-[({[(2E,3E)-4-(2,6- diclorofenil)-but-3-eno-2-ilideno]-amino}-oxi)-metil]- fenil}-2-(metoxi-imino)-N-metiletanamida, (3.28) 2-cloro-N- (1,1,3-trimetil-2,3-di-hidro-1H-indeno-4-il)-piridina-3- carboxamida (119899-14-8), (3.29) 5-metoxi-2-metil-4-(2- {[({(1E)-1-[3-(trifluorometil)-fenil]-etilideno}-amino)- oxi]-metil}-fenil)-2,4-di-hidro-3H-1,2,4-triazol-3-ona, (3.30) (2E)-2-{2-[({ciclopropil-[(4-metoxifenil)-imino]- metil}-sulfanil)-metil]-fenil}-3-metoxiprop-2-enoato de metila (149601-03-6), (3.31) N-(3-etil-3,5,5-trimetilciclohexil)-3-(formilamino)-2-hidroxibenzamida (226551-21-9), (3.32) 2-{2-[(2,5-dimetilfenoxi)-metil]-fenil}-2-metoxi-Nmetilacetamida (173662-97-0), (3.33) (2R)-2-{2-[(2,5- dimetilfenoxi)-metil]-fenil}-2-metoxi-N-metilacetamida (394657-24-0); (4) inibidores de mitose e da divisão celular, por exemplo, (4.1) benomila (17804-35-2), (4.2) carbendazim (10605-21-7), (4.3) clorofenazole (3574-96-7), (4.4) dietofencarb (87130-20-9), (4.5) etaboxam (162650-77-3), (4.6) fluopicolida (239110-15-7), (4.7) fuberidazole (3878- 19-1), (4.8) pencicurona (66063-05-6), (4.9) tiabendazole (148-79-8), (4.10) tiofanato de metila (23564-05-8), (4.11) tiofanato (23564-06-9), (4.12) zoxamida (156052-68-5), (4.13) 5-cloro-7-(4-metilpiperidina-1-il)-6-(2,4,6- trifluorofenil)-[1,2,4]triazolo[1,5-a]pirimidina (214706- 53-3), (4.14) 3-cloro-5-(6-cloropiridina-3-il)-6-metil-4- (2,4,6-trifluorofenil)-piridazina (1002756-87-7); (5) compostos capazes de apresentar uma ação multilocal, tais como, por exemplo, (5.1) mistura de bordeaux (8011-63-0), (5.2) captafol (2425-06-1), (5.3) captano (133-06-2), (5.4) clorotalonila (1897-45-6), (5.5) hidróxido de cobre (20427-59-2), (5.6) naftenato de cobre (1338-02-9), (5.7) óxido de cobre (1317-39-1), (5.8) oxicloreto de cobre (1332-40-7), (5.9) sulfato de cobre(2+) (7758-98-7), (5.10) diclofluanida (1085-98-9), (5.11) ditianona (3347-22-6), (5.12) dodina (2439-10-3), (5.13) base livre de dodina, (5.14) ferbam (14484-64-1), (5.15) fluorofolpet (719-96-0), (5.16) folpet (133-07-3), (5.17) guazatina (108173-90-6), (5.18) acetato de guazatina, (5.19) iminoctadina (13516-27-3), (5.20) albesilato de iminoctadina (169202-06-6), (5.21) triacetato de iminoctadina (57520-17-9), (5.22) mancopper (53988-93-5), (5.23) mancozeb (8018-01-7), (5.24) maneb (12427-38-2), (5.25) metiram (9006-42-2), (5.26) metiram de zinco (9006- 42-2), (5.27) oxina de cobre (10380-28-6), (5.28) propamidina (104-32-5), (5.29) propineb (12071-83-9), (5.30) enxofre e preparações de enxofre, incluindo polissulfureto de cálcio (7704-34-9), (5.31) tiram (137-26- 8), (5.32) tolilfluanida (731-27-1), (5.33) zineb (12122- 67-7), (5.34) ziram (137-30-4); (6) compostos capazes de induzir uma defesa no hospedeiro, tais como, por exemplo, (6.1) acibenzolar-Smetila (135158-54-2), (6.2) isotianila (224049-04-1), (6.3) probenazole (27605-76-1), (6.4) tiadinila (223580-51-6); (7) inibidores da biossíntese de aminoácidos e/ou de proteínas, por exemplo, (7.1) andoprim (23951-85-1), (7.2) blasticidina-S (2079-00-7), (7.3) ciprodinila (121552-61- 2), (7.4) casugamicina (6980-18-3), (7.5) hidrato do cloridrato de casugamicina (19408-46-9), (7.6) mepanipirim (110235-47-7), (7.7) pirimetanila (53112-28-0), (7.8) 3-(5- flúor-3,3,4,4-tetrametil-3,4-di-hidroisoquinolina-1-il)- quinolina (861647-32-7); (8) inibidores da produção de ATP, por exemplo, (8.1) acetato de fentina (900-95-8), (8.2) cloreto de fentina (639-58-7), (8.3) hidróxido de fentina (76-87-9), (8.4) siltiofam (175217-20-6); (9) inibidores da síntese da parede celular, por exemplo, (9.1) bentiavalicarb (177406-68-7), (9.2) dimetomorf (110488-70-5), (9.3) flumorf (211867-47-9), (9.4) iprovalicarb (140923-17-7), (9.5) mandipropamid (374726-62-2), (9.6) polioxinas (11113-80-7), (9.7) polioxorim (22976-86-9), (9.8) validamicina A (37248-47-8), (9.9) valifenalato (283159-94-4; 283159-90-0); (10) inibidores da síntese de lípidos e de membranas, por exemplo, (10.1) bifenila (92-52-4), (10.2) cloroneb (2675-77-6), (10.3) diclorano (99-30-9), (10.4) edifenfos (17109-49-8), (10.5) etridiazole (2593-15-9), (10.6) iodocarb (55406-53-6), (10.7) iprobenfos (26087-47-8), (10.8) isoprotiolano (50512-35-1), (10.9) propamocarb (25606-41-1), (10.10) cloridrato de propamocarb (25606-41- 1), (10.11) protiocarb (19622-08-3), (10.12) pirazofos (13457-18-6), (10.13) quintozeno (82-68-8), (10.14) tecnazeno (117-18-0), (10.15) tolclofos-metila (57018-04- 9); (11) inibidores da biossíntese de melanina, por exemplo, (11.1) carpropamida (104030-54-8), (11.2) diclocimet (139920-32-4), (11.3) fenoxanila (115852-48-7), (11.4) ftalida (27355-22-2), (11.5) piroquilona (57369-32-1), (11.6) triciclazole (41814-78-2), (11.7) {3-metil-1-[(4- metilbenzoíl)-amino]-butano-2-il}-carbamato de 2,2,2- trifluoroetila (851524-22-6); (12) inibidores da síntese de ácidos nucleicos, por exemplo, (12.1) benalaxila (71626-11-4), (12.2) benalaxil-M (quiralaxil) (98243-83-5), (12.3) bupirimato (41483-43-6), (12.4) clozilacon (67932-85-8), (12.5) dimetirimol (5221- 53-4), (12.6) etirimol (23947-60-6), (12.7) furalaxila (57646-30-7), (12.8) himexazol (10004-44-1), (12.9) metalaxila (57837-19-1), (12.10) metalaxil-M (mefenoxam) (70630-17-0), (12.11) ofurace (58810-48-3), (12.12) oxadixila (77732-09-3), (12.13) ácido oxolínico (14698-29- 4); (13) inibidores da transdução de sinal, por exemplo, (13.1) clozolinato (84332-86-5), (13.2) fenpiclonila (74738-17-3), (13.3) fludioxonila (131341-86-1), (13.4) iprodiona (36734-19-7), (13.5) procimidona (32809-16-8), (13.6) quinoxifeno (124495-18-7), (13.7) vinclozolina (50471-44-8); (14) compostos capazes de actuar como desacopladores, tais como, por exemplo, (14.1) binapacrila (485-31-4), (14.2) dinocap (131-72-6), (14.3) ferimzona (89269-64-7), (14.4) fluazinam (79622-59-6), (14.5) meptildinocap (131- 72-6); (15) (15) outros compostos, tais como, por exemplo, (15.1) bentiazole (21564-17-0), (15.2) betoxazina (163269- 30-5), (15.3) capsimicina (70694-08-5), (15.4) carvone (99- 49-0), (15.5) quinometionato (2439-01-2), (15.6) piriofenona (clazafenona) (688046-61-9), (15.7) cufraneb (11096-18-7), (15.8) ciflufenamida (180409-60-3), (15.9) cimoxanila (57966-95-7), (15.10) cipro-sulfamida (221667- 31-8), (15.11) dazomet (533-74-4), (15.12) debacarb (62732- 91-6), (15.13) diclorofeno (97-23-4), (15.14) diclomezina (62865-36-5), (15.15) difenzoquat (49866-87-7), (15.16) metilsulfato de difenzoquat (43222-48-6), (15.17) difenilamina (122-39-4), (15.18) ecomato, (15.19) fenpirazamina (473798-59-3), (15.20) flumetover (154025-04- 4), (15.21) fluoroimida (41205-21-4), (15.22) flu-sulfamida (106917-52-6), (15.23) flutianila (304900-25-2), (15.24) fosetil-alumínio (39148-24-8), (15.25) fosetil-cálcio, (15.26) fosetil-sódio (39148-16-8), (15.27) hexaclorobenzeno (118-74-1), (15.28) irumamicina (81604-73- 1), (15.29) metasulfocarb (66952-49-6), (15.30) isotiocianato de metila (556-61-6), (15.31) metrafenona (220899-03-6), (15.32) mildiomicina (67527-71-3), (15.33) natamicina (7681-93-8), (15.34) dimetilditiocarbamato de níquel (15521-65-0), (15.35) nitrotal-isopropila (10552-74- 6), (15.36) octilinona (26530-20-1), (15.37) oxamocarb (917242-12-7), (15.38) oxifentiina (34407-87-9), (15.39) pentaclorofenol e sais (87-86-5), (15.40) fenotrina, (15.41) ácido fosforose e seus sais (13598-36-2), (15.42) propamocarb-fosetilato, (15.43) propanosina-sódio (88498- 02-6), (15.44) proquinazida (189278-12-4), (15.45) pirimorf (868390-90-3), (15.45e) (2E)-3-(4-terc-butilfenil)-3-(2- cloropiridina-4-il)-1-(morfolina-4-il)-prop-2-eno-1-ona (1231776-28-5), (15.45z) (2Z)-3-(4-terc-butilfenil)-3-(2- cloropiridina-4-il)-1-(morfolina-4-il)-prop-2-eno-1-ona (1231776-29-6), (15.46) pirrolnitrino (1018-71-9), (15.47) tebufloquina (376645-78-2), (15.48) tecloftalam (76280-91- 6), (15.49) tolnifanida (304911-98-6), (15.50) triazoxido (72459-58-6), (15.51) triclamida (70193-21-4), (15.52) zarilamida (84527-51-5), (15.53) 2-metil-propanoato de (3S,6S,7R,8R)-8-benzil-3-[({3-[(isobutiriloxi)-metoxi]-4- metoxi-piridina-2-il}-carbonil)-amino]-6-metil-4,9-dioxo1,5-dioxonano-7-ila (517875-34-2), (15.54) 1-(4-{4-[(5R)-5- (2,6-difluorofenil)-4,5-di-hidro-1,2-oxazol-3-il]-1,3- tiazol-2-il}-piperidina-1-il)-2-[5-metil-3- (trifluorometil)-1H-pirazol-1-il]-etanona (1003319-79-6), (15.55) 1-(4-{4-[(5S)-5-(2,6-difluorofenil)-4,5-di-hidro1,2-oxazol-3-il]-1,3-tiazol-2-il}-piperidina-1-il)-2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]-etanona (1003319- 80-9), (15.56) 1-(4-{4-[5-(2,6-difluorofenil)-4,5-di-hidro1,2-oxazol-3-il]-1,3-tiazol-2-il}-piperidina-1-il)-2-[5- metil-3-(trifluorometil)-1H-pirazol-1-il]-etanona (1003318- 67-9), (15.57) 1H-imidazol-1-carboxilato de 1-(4- metoxifenoxi)-3,3-dimetilbutano-2-ila (111227-17-9), (15.58) 2,3,5,6-tetracloro-4-(metilsulfonil)-piridina (13108-52-6), (15.59) 2,3-dibutil-6-clorotieno[2,3- d]pirimidina-4(3H)-ona (221451-58-7), (15.60) 2,6-dimetil1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirrole-1,3,5,7(2H,6H)- tetrona, (15.61) 2-[5-metil-3-(trifluorometil)-1H-pirazol1-il]-1-(4-{4-[(5R)-5-fenil-4,5-di-hidro-1,2-oxazol-3-il]- 1,3-tiazol-2-il}-piperidina-1-il)-etanona (1003316-53-7), (15.62) 2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]-1- (4-{4-[(5S)-5-fenil-4,5-di-hidro-1,2-oxazol-3-il]-1,3- tiazol-2-il}-piperidina-1-il)-etanona (1003316-54-8), (15.63) 2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]-1- {4-[4-(5-fenil-4,5-di-hidro-1,2-oxazol-3-il)-1,3-tiazol-2- il]-piperidina-1-il}-etanona (1003316-51-5), (15.64) 2- butoxi-6-iodo-3-propil-4H-cromeno-4-ona, (15.65) 2-cloro-5- [2-cloro-1-(2,6-diflúor-4-metoxifenil)-4-metil-1H-imidazol5-il]-piridina, (15.66) 2-fenilfenol e sais (90-43-7), (15.67) 3-(4,4,5-triflúor-3,3-dimetil-3,4-dihidroisoquinolina-1-il)-quinolina (861647-85-0), (15.68) 3,4,5-tricloropiridina-2,6-dicarbonitrila (17824-85-0), (15.69) 3-[5-(4-clorofenil)-2,3-dimetil-1,2-oxazolidina-3- il]-piridina, (15.70) 3-cloro-5-(4-clorofenil)-4-(2,6- difluorofenil)-6-metilpiridazina, (15.71) 4-(4-clorofenil)- 5-(2,6-difluorofenil)-3,6-dimetilpiridazina, (15.72) 5- amino-1,3,4-tiadiazole-2-tiol, (15.73) 5-cloro-N'-fenil-N'-(prop-2-ino-1-il)-tiofeno-2-sulfono-hidrazida (134-31-6), (15.74) 5-flúor-2-[(4-fluorobenzil)-oxi]-pirimidina-4-amina (1174376-11-4), (15.75) 5-flúor-2-[(4-metilbenzil)-oxi]- pirimidina-4-amina (1174376-25-0), (15.76) 5-metil-6-octil- [1,2,4]triazolo[1,5-a]pirimidina-7-amina, (15.77) (2Z)-3- amino-2-ciano-3-fenilprop-2-enoato de etila, (15.78) N'-(4- {[3-(4-clorobenzil)-1,2,4-tiadiazol-5-il]-oxi}-2,5- dimetilfenil)-N-etil-N-metilimidoformamida, (15.79) N-(4- clorobenzil)-3-[3-metoxi-4-(prop-2-ino-1-iloxi)-fenil]- propanamida, (15.80) N-[(4-clorofenil)-(ciano)-metil]-3-[3- metoxi-4-(prop-2-ino-1-iloxi)-fenil]-propanamida, (15.81) N-[(5-bromo-3-cloro-piridina-2-il)-metil]-2,4- dicloropiridina-3-carboxamida, (15.82) N-[1-(5-bromo-3- cloropiridina-2-il)-etil]-2,4-dicloropiridina-3- carboxamida, (15.83) N-[1-(5-bromo-3-cloropiridina-2-il)- etil]-2-flúor-4-iodopiridina-3-carboxamida, (15.84) N-{(E)- [(ciclo-propilmetoxi)-imino]-[6-(difluorometoxi)-2,3- difluorofenil]-metil}-2-fenil-acetamida (221201-92-9), (15.85) N-{(Z)-[(ciclopropilmetoxi)-imino]-[6- (difluorometoxi)-2,3-difluorofenil]-metil}-2-fenilacetamida (221201-92-9), (15.86) N'-{4-[(3-terc-butil-4-ciano-1,2- tiazol-5-il)-oxi]-2-cloro-5-metilfenil}-N-etil-N-metilimidoformamida, (15.87) N-metil-2-(1-{[5-metil-3- (trifluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- N-(1,2,3,4-tetra-hidronaftaleno-1-il)-1,3-tiazole-4- carboxamida (922514-49-6), (15.88) N-metil-2-(1-{[5-metil3-(trifluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4- il)-N-[(1R)-1,2,3,4-tetra-hidronaftaleno-1-il]-1,3-tiazole4-carboxamida (922514-07-6), (15.89) N-metil-2-(1-{[5- metil-3-(trifluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)-N-[(1S)-1,2,3,4-tetra-hidronaftaleno-1- il]-1,3-tiazole-4-carboxamida (922514-48-5), (15.90) {6- [({[(1-metil-1H-tetrazol-5-il)-(fenil)-metilideno]-amino}- oxi)-metil]-piridina-2-il}-carbamato de pentila, (15.91) ácido fenazina-1-carboxílico, (15.92) quinolina-8-ol (134- 31-6), (15.93) sulfato de quinolina-8-ol (2:1) (134-31-6), (15.94) {6-[({[(1-metil-1H-tetrazol-5-il)-(fenil)- metileno]-amino}-oxi)-metil]-piridina-2-il}-carbamato de terc-butila; (16) outros compostos, tais como, por exemplo, (16.1) 1- metil-3-(trifluorometil)-N-[2'-(trifluorometil)-bifenil-2- il]-1H-pirazole-4-carboxamida, (16.2) N-(4'-clorobifenil-2- il)-3-(difluorometil)-1-metil-1H-pirazole-4-carboxamida, (16.3) N-(2',4'-dichlorobifenil-2-il)-3-(difluorometil)-1- metil-1H-pirazole-4-carboxamida, (16.4) 3-(difluorometil)- 1-metil-N-[4'-(trifluorometil)-bifenil-2-il]-1H-pirazole-4- carboxamida, (16.5) N-(2',5'-difluorobifenil-2-il)-1-metil3-(trifluorometil)-1H-pirazole-4-carboxamida, (16.6) 3- (difluorometil)-1-metil-N-[4'-(prop-1-ino-1-il)-bifenil-2- il]-1H-pirazole-4-carboxamida, (16.7) 5-flúor-1,3-dimetilN-[4'-(prop-1-ino-1-il)-bifenil-2-il]-1H-pirazole-4- carboxamida, (16.8) 2-cloro-N-[4'-(prop-1-ino-1-il)- bifenil-2-il]-piridina-3-carboxamida, (16.9) 3- (difluorometil)-N-[4'-(3,3-dimetilbut-1-ino-1-il)-bifenil2-il]-1-metil-1H-pirazole-4-carboxamida, (16.10) N-[4'- (3,3-dimetil-but-1-ino-1-il)-bifenil-2-il]-5-flúor-1,3- dimetil-1H-pirazole-4-carboxamida, (16.11) 3- (difluorometil)-N-(4'-etinilbifenil-2-il)-1-metil-1Hpirazole-4-carboxamida, (16.12) N-(4'-etinilbifenil-2-il)- 5-flúor-1,3-dimetil-1H-pirazole-4-carboxamida, (16.13) 2-cloro-N-(4'-etinilbifenil-2-il)-piridina-3-carboxamida, (16.14) 2-cloro-N-[4'-(3,3-dimetilbut-1-ino-1-il)-bifenil2-il]-piridina-3-carboxamida, (16.15) 4-(difluorometil)-2- metil-N-[4'-(trifluorometil)-bifenil-2-il]-1,3-tiazole-5- carboxamida, (16.16) 5-flúor-N-[4'-(3-hidroxi-3-metilbut-1- ino-1-il)-bifenil-2-il]-1,3-dimetil-1H-pirazole-4- carboxamida, (16.17) 2-cloro-N-[4'-(3-hidroxi-3-metilbut-1- ino-1-il)-bifenil-2-il]-piridina-3-carboxamida, (16.18) 3- (difluorometil)-N-[4'-(3-metoxi-3-metilbut-1-ino-1-il)- bifenil-2-il]-1-metil-1H-pirazole-4-carboxamida, (16.19) 5- flúor-N-[4'-(3-metoxi-3-metilbut-1-ino-1-il)-bifenil-2-il]- 1,3-dimetil-1H-pirazole-4-carboxamida, (16.20) 2-cloro-N- [4'-(3-metoxi-3-metilbut-1-ino-1-il)-bifenil-2-il]- piridina-3-carboxamida, (16.21) (5-bromo-2-metoxi-4- metilpiridina-3-il)-(2,3,4-trimetoxi-6-metilfenil)- metanona, (16.22) N-[2-(4-{[3-(4-clorofenil)-prop-2-ino-1- il]-oxi}-3-metoxifenil)-etil]-N2-(metilsulfonil)-valinamida (220706-93-4), (16.23) ácido 4-oxo-4-[(2-feniletil)amino]- butanóico, (16.24) {6-[({[(Z)-(1-metil-1H-tetrazol-5-il)- (fenil)-metileno]-amino}-oxi)-metil]-piridina-2-il}- carbamato de but-3-ino-1-ila, (16.25) 4-amino-5- fluoropirimidina-2-ol (forma mesomérica: 6-amino-5- fluoropirimidina-2(1H)-ona), (16.26) 3,4,5-trihidroxibenzoato de propila.[014] Combinations comprising at least one other active compound (B) selected from the following sets are further preferred: ((1) ergosterol biosynthesis inhibitors, for example, (1.1) aldimorf (1704-28-5), (1.2) azaconazole (60207-31-0), (1.3) bitertanol (55179-31-2), (1.4) bromuconazole (116255-48-2), (1.5) cyproconazole (113096- 99-4), (1.6 ) diclobutrazole (75736-33-3), (1.7) diphenoconazole (119446-68-3), (1.8) diniconazole (83657-24- 3), (1.9) diniconazole-M (83657-18-5), (1.10 ) dodemorf (1593-77-7), (1.11) dodemorf acetate (31717-87-0), (1.12) epoxiconazole (106325-08-0), (1.13) etaconazole (60207-93-4), (1.14 ) fenarimol (60168-88-9), (1.15) fenbuconazole (114369-43-6), (1.16) fen-hexamide (126833-17-8), (1.17) phenpropidine (67306-00-7), (1.18 ) fenpropimorf (67306-03-0), (1.19) fluquinconazole (136426- 54-5), (1.20) flurprimidol (56425-91-3), (1.21) flusilazole (85509-19-9), (1.22) flutriafol (76674-21-0), (1.23) furconazole (112839-33-5), (1.24) furconazole-c is (112839- 32-4), (1.25) hexaconazole (79983-71-4), (1.26) imazalil (60534-80-7), (1.27) imazalyl sulfate (58594-72-2), (1.28) imibenconazole (86598-92-7), (1.29) ipconazole (125225-28-7), (1.30) metconazole (125116-23-6), (1.31) myclobutanil (88671-89-0), (1.32) naphthifine ( 65472-88-0), (1.33) nuarimol (63284-71-9), (1.34) oxpoconazole (174212-12-12), (1.35) paclobutrazol (76738-62-0), (1.36) pefurazoate (101903- 30-4), (1.37) penconazole (66246-88-6), (1.38) piperalin (3478-94-2), (1.39) prochloraz (67747-09- 5), (1.40) propiconazole (60207-90- 1), (1.41) protioconazole (178928-70-6), (1.42) pyributicarb (88678- 67-5), (1.43) pyrifenox (88283-41-4), (1.44) quinconazole (103970-75-8) , (1.45) simeconazole (149508-90-7), (1.46) spiroxamine (118134-30-8), (1.47) tebuconazole (107534-96- 3), (1.48) terbinafine (91161-71-6), ( 1.49) tetraconazole (112281-77-3), (1.50) triadimefone (43121-43-3), (1.51) triadimenol (89482-17-7), (1.52) tridemorf (81412-43-3), (1.53) triflumizole (68694-1 1-1), (1.54) triforin (26644- 46-2), (1.55) triticonazole (131983-72-7), (1.56) uniconazole (83657-22-1), (1.57) uniconazole-p (83657- 17-4), (1.58) viniconazole (77174-66-4), (1.59) voriconazole (137234-62-9), (1.60) 1- (4-chlorophenyl) -2- (1H-1,2,4 -triazol1-yl) -cycloheptanol (129586-32-9), (1.61) 1- (2,2-dimethyl2,3-dihydro-1H-indeno-1-yl) -1H-imidazole-5- methyl carboxylate (110323-95-0), (1.62) N '- {5- (difluoromethyl) -2-methyl4- [3- (trimethylsilyl) -propoxy] -phenyl} -N-ethyl-Nmethylimidoformamide, (1.63) N-ethyl-N-methyl-N '- {2-methyl-5- (trifluoromethyl) -4- [3- (trimethylsilyl) -propoxy] -phenyl} - imidoformamide, (1.64) 1H-imidazole-1-carbothioate O- [1- (4-methoxyphenoxy) -3,3-dimethylbutane-2-yl] (111226-71-2); (2) respiratory chain inhibitors in complex I or II, for example, (2.1) bixafen (581809-46-3), (2.2) boscalid (188425-85-6), (2.3) carboxine (5234-68-4 ), (2.4) diflumetorim (130339-07-0), (2.5) fenfuram (24691-80-3), (2.6) fluopyram (658066-35-4), (2.7) flutolanyl (66332-96-5), (2.8) fluxpyroxad (907204-31-3), (2.9) furametpir (123572-88-3), (2.10) furmeciclox (60568-05-0), (2.11) isopirazam (mixture of syn-epimeric racemate 1RS, 4SR , 9RS and anti-epimeric racemate 1RS, 4SR, 9SR) (881685-58-1), (2.12) isopirazam (anti-epimeric racemate 1RS, 4SR, 9SR), (2.13) isopirazam (anti-epimeric enantiomer 1R, 4S , 9S), (2.14) isopirazam (anti-epimeric enantiomer 1S, 4R, 9R), (2.15) isopirazam (syn-epimeric racemate 1RS, 4SR, 9RS), (2.16) isopirazam (syn-epimeric enantiomer 1R, 4S, 9R ), (2.17) isopyrazam (syn-epimeric enantiomer 1S, 4R, 9S), (2.18) mepronyl (55814-41-0), (2.19) oxycarboxine (5259- 88-1), (2.20) penflufen (494793-67 -8), (2.21) pentiopirad (183675-82-3), (2.22) silkxane (874 967-67-6), (2.23) tifluzamide (130000-40-7), (2.24) 1-methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) -phenyl] -3- (trifluoromethyl ) -1H-pyrazole-4-carboxamide, (2.25) 3- (difluoromethyl) -1-methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) -phenyl] -1H-pyrazole-4-carboxamide , (2.26) 3- (difluoro-methyl) -N- [4-fluoro-2- (1,1,2,3,3,3-hexafluoropropoxy) -phenyl] -1-methyl-1H-pyrazole4-carboxamide, (2.27) N- [1- (2,4-dichlorophenyl) -1-methoxypropane-2-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole4-carboxamide (1092400-95-7), (2.28 ) 5,8-difluoro-N- [2- (2-fluoro-4 - {[4- (trifluoromethyl) -pyridine-2-yl] -oxy} -phenyl) - ethyl] -quinazoline-4-amine (1210070 -84-0), (2.29) benzovindiflupir, (2.30) N - [(1S, 4R) -9- (dichloromethylene) - 1,2,3,4-tetrahydro-1,4-methanonaphthalene-5-yl ] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.31) N - [(1R, 4S) -9- (dichloromethylene) -1,2,3,4-tetrahydro- 1,4- methanonaphthalene-5-yl] -3- (difluoromethyl) -1-methyl-1Hpyazole-4-carboxamide, (2.32) 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethyl -2,3-dihydro-1H-indeno-4-yl) -1H-pyrazole -4-carboxamide, (2.33) 1,3,5-trimethyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-indeno-4-yl) -1H-pyrazol-4- carboxamide, (2.34) 1-methyl-3- (trifluoromethyl) -N- (1,3,3-trimethyl-2,3-dihydro1H-indeno-4-yl) -1H-pyrazol-4-carboxamide, ( 2.35) 1-methyl-3- (trifluoromethyl) -N - [(1S) -1,3,3-trimethyl-2,3-dihydro-1Hindene-4-yl] -1H-pyrazol-4-carboxamide, (2.36) 1-methyl-3- (trifluoromethyl) -N - [(1R) -1,3,3-trimethyl-2,3-dihydro-1Hindene-4-yl] -1H-pyrazol-4-carboxamide , (2.37) 3- (difluoromethyl) -1-methyl-N - [(3S) -1,1,3-trimethyl-2,3-dihydro-1H-indeno-4-yl] -1H-pyrazole-4- carboxamide, (2.38) 3- (difluoromethyl) -1-methyl-N - [(3R) -1,1,3-trimethyl-2,3-dihydro-1H-indeno-4-yl] -1H-pyrazole-4 -carboxamide, (2.39) 1,3,5-trimethyl-N - [(3R) -1,1,3-trimethyl-2,3-dihydro-1Hindene-4-yl] -1H-pyrazol-4- carboxamide, (2.40) 1,3,5-trimethyl-N - [(3S) -1,1,3-trimethyl-2,3-dihydro-1H-indeno-4-yl] -1H-pyrazole-4 -carboxamide; (3) respiratory chain inhibitors in complex III, for example, (3.1) ametoctradine (865318-97-4), (3.2) amisulbrom (348635-87-0), (3.3) azoxystrobin (131860-33-8), (3.4) cyazofamide (120116-88-3), (3.5) coumetoxystrobin (850881-30-0), (3.6) coumoxystrobin (850881-70-8), (3.7) dimoxystrobin (141600-52-4), (3.8 ) enestroburin (238410-11-2), (3.9) famoxadone (131807-57-3), (3.10) phenamidone (161326-34-7), (3.11) phenoxystrobin (918162-02-4), (3.12) fluoxastrobin (361377-29-9), (3.13) cresoxim-methyl (143390-89-0), (3.14) metominostrobin (133408-50-1), (3.15) orisastrobin (189892-69-1), (3.16) picoxystrobin (117428-22-5), (3.17) pyraclostrobin (175013-18-0), (3.18) pirametostrobin (915410-70-7), (3.19) piraoxystrobin (862588-11-2), (3.20) pyribencarb (799247 -52-2), (3.21) triclopyricarb (902760-40-1), (3.22) trifloxystrobin (141517-21-7), (3.23) (2E) -2- (2 - {[6- (3- chlorine -2-methylphenoxy) -5-fluoropyrimidine-4-yl] -oxy} -phenyl) - 2- (methoxyimino) -N-methylethylamide, (3.24) (2E) -2- ( methoxyimino) -N-methyl-2- (2 - {[({(1E) -1- [3- (trifluoromethyl) -phenyl] -ethylidene} -amino) -oxy] -methyl} -phenyl) -ethanamide, ( 3.25) (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) -phenyl] -ethoxy} -imino) -methyl] -phenyl} - ethanamide (158169-73-4), (3.26) (2E) -2- {2 - [({[(1E) -1- (3- {[(E) -1-fluorine-2- phenyletenyl] -oxy} -phenyl) -ethylidene] -amino} -oxy) -methyl] -phenyl} -2- (methoxyimino) -N-methylethylamide (326896-28-0), (3.27) (2E) - 2- {2 - [({[(2E, 3E) -4- (2,6-dichlorophenyl) -but-3-ene-2-ylidene] -amino} -oxy) -methyl] - phenyl} -2- (methoxyimino) -N-methylethylamide, (3.28) 2-chloro-N- (1,1,3-trimethyl-2,3-dihydro-1H-indeno-4-yl) -pyridine-3-carboxamide (119899-14-8), (3.29) 5-methoxy-2-methyl-4- (2- {[({(1E) -1- [3- (trifluoromethyl) -phenyl] -ethylidene} -amino) - oxy] -methyl} -phenyl) -2,4-dihydro-3H-1,2,4-triazole-3-one, (3.30) (2E) -2- {2 - [({cyclopropyl - [( Methyl 4-methoxyphenyl) -imino] -methyl} -sulfanyl) -methyl] -phenyl} -3-methoxyprop-2-enoate (149601-03-6), (3.31) N- (3-ethyl-3,5 , 5-trimethylcyclohexyl) -3- (formylamino) -2-hydroxybenzamide (2 26551-21-9), (3.32) 2- {2 - [(2,5-dimethylphenoxy) -methyl] -phenyl} -2-methoxy-Nmethylacetamide (173662-97-0), (3.33) (2R) - 2- {2 - [(2,5-dimethylphenoxy) -methyl] -phenyl} -2-methoxy-N-methylacetamide (394657-24-0); (4) mitosis and cell division inhibitors, for example, (4.1) benomyl (17804-35-2), (4.2) carbendazim (10605-21-7), (4.3) chlorophenazole (3574-96-7), (4.4) dietofencarb (87130-20-9), (4.5) etaboxam (162650-77-3), (4.6) fluopicolide (239110-15-7), (4.7) fuberidazole (3878-19-19-1), (4.8 ) pencicurone (66063-05-6), (4.9) thiabendazole (148-79-8), (4.10) methyl thiophanate (23564-05-8), (4.11) thiophanate (23564-06-9), (4.12 ) zoxamide (156052-68-5), (4.13) 5-chloro-7- (4-methylpiperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] triazole [ 1,5-a] pyrimidine (214706- 53-3), (4.14) 3-chloro-5- (6-chloropyridine-3-yl) -6-methyl-4- (2,4,6-trifluorophenyl) - pyridazine (1002756-87-7); (5) compounds capable of having a multilocal action, such as, for example, (5.1) mixture of bordeaux (8011-63-0), (5.2) captafol (2425-06-1), (5.3) captano (133- 06-2), (5.4) chlorothalonil (1897-45-6), (5.5) copper hydroxide (20427-59-2), (5.6) copper naphthenate (1338-02-9), (5.7) oxide copper (1317-39-1), (5.8) copper oxychloride (1332-40-7), (5.9) copper sulfate (2+) (7758-98-7), (5.10) dichlofluanide (1085-98- 9), (5.11) dithianone (3347-22-6), (5.12) dodine (2439-10-3), (5.13) dodine free base, (5.14) ferbam (14484-64-1), (5.15) fluorofolpet (719-96-0), (5.16) folpet (133-07-3), (5.17) guazatin (108173-90-6), (5.18) guazatin acetate, (5.19) iminoctadine (13516-27-3 ), (5.20) iminoctadine albesylate (169202-06-6), (5.21) iminoctadine triacetate (57520-17-9), (5.22) mancopper (53988-93-5), (5.23) mancozeb (8018-01 -7), (5.24) maneb (12427-38-2), (5.25) meth (9006-42-2), (5.26) zinc meth (9006- 42-2), (5.27) copper oxine (10380 -28-6), (5.28) propamidi na (104-32-5), (5.29) propineb (12071-83-9), (5.30) sulfur and sulfur preparations, including calcium polysulfide (7704-34-9), (5.31) draw (137-26 - 8), (5.32) tolylfluanide (731-27-1), (5.33) zineb (12122- 67-7), (5.34) ziram (137-30-4); (6) compounds capable of inducing a defense in the host, such as, for example, (6.1) acibenzolar-Smethyl (135158-54-2), (6.2) isothianyl (224049-04-1), (6.3) probenazole (27605 -76-1), (6.4) thiadinyl (223580-51-6); (7) amino acid and / or protein biosynthesis inhibitors, for example, (7.1) andoprim (23951-85-1), (7.2) blasticidin-S (2079-00-7), (7.3) cyprodinil (121552- 61-2), (7.4) casugamycin (6980-18-3), (7.5) casugamycin hydrochloride hydrate (19408-46-9), (7.6) mepanipirim (110235-47-7), (7.7) pyrimethanil ( 53112-28-0), (7.8) 3- (5- fluorine-3,3,4,4-tetramethyl-3,4-dihydroisoquinoline-1-yl) -quinoline (861647-32-7); (8) inhibitors of ATP production, for example, (8.1) phentin acetate (900-95-8), (8.2) phentin chloride (639-58-7), (8.3) fentine hydroxide (76-87 -9), (8.4) siltiofam (175217-20-6); (9) cell wall synthesis inhibitors, for example, (9.1) bentiavalicarb (177406-68-7), (9.2) dimetomorf (110488-70-5), (9.3) flumorf (211867-47-9), ( 9.4) iprovalicarb (140923-17-7), (9.5) mandipropamid (374726-62-2), (9.6) polyoxins (11113-80-7), (9.7) polyoxorin (22976-86-9), (9.8) validamycin A (37248-47-8), (9.9) valifenalate (283159-94-4; 283159-90-0); (10) inhibitors of lipid and membrane synthesis, for example, (10.1) biphenyl (92-52-4), (10.2) chloroneb (2675-77-6), (10.3) dichlorane (99-30-9) , (10.4) edifenfos (17109-49-8), (10.5) etridiazole (2593-15-9), (10.6) iodocarb (55406-53-6), (10.7) iprobenfos (26087-47-8), ( 10.8) isoprothiolane (50512-35-1), (10.9) propamocarb (25606-41-1), (10.10) propamocarb hydrochloride (25606-41-1), (10.11) protiocarb (19622-08-3), ( 10.12) pyrazophos (13457-18-6), (10.13) quintozene (82-68-8), (10.14) tecnazene (117-18-0), (10.15) tolclofos-methyl (57018-04-9); (11) melanin biosynthesis inhibitors, for example, (11.1) carpropamide (104030-54-8), (11.2) diclocimet (139920-32-4), (11.3) phenoxanil (115852-48-7), (11.4) ) phthalide (27355-22-2), (11.5) pyrokylone (57369-32-1), (11.6) tricyclazole (41814-78-2), (11.7) {3-methyl-1 - [(4-methylbenzoyl) -amino] -butane-2-yl}-2,2,2-trifluoroethyl carbamate (851524-22-6); (12) nucleic acid synthesis inhibitors, for example, (12.1) benalaxyl (71626-11-4), (12.2) benalaxyl-M (chiralaxyl) (98243-83-5), (12.3) bupirimate (41483-43 -6), (12.4) clozilacon (67932-85-8), (12.5) dimethyrimol (5221- 53-4), (12.6) ethirimol (23947-60-6), (12.7) furalaxila (57646-30-7 ), (12.8) himexazole (10004-44-1), (12.9) metalaxyl (57837-19-1), (12.10) metalaxyl-M (mefenoxam) (70630-17-0), (12.11) ofurace (58810- 48-3), (12.12) oxadixyl (77732-09-3), (12.13) oxolinic acid (14698-29- 4); (13) signal transduction inhibitors, for example, (13.1) clozolinate (84332-86-5), (13.2) fenpiclonil (74738-17-3), (13.3) fludioxonil (131341-86-1), (13.4 ) iprodione (36734-19-7), (13.5) procymidone (32809-16-8), (13.6) quinoxyphene (124495-18-7), (13.7) vinclozoline (50471-44-8); (14) compounds capable of acting as decouplers, such as, for example, (14.1) binapacryl (485-31-4), (14.2) dinocap (131-72-6), (14.3) ferimzone (89269-64-7 ), (14.4) fluazinam (79622-59-6), (14.5) meptildinocap (131- 72-6); (15) (15) other compounds, such as, for example, (15.1) bentiazole (21564-17-0), (15.2) betoxazine (163269-30-5), (15.3) capsimicin (70694-08-5) , (15.4) carvone (99- 49-0), (15.5) quinomethionate (2439-01-2), (15.6) pyrophenone (clazafenone) (688046-61-9), (15.7) cufraneb (11096-18-7 ), (15.8) cyflufenamide (180409-60-3), (15.9) cymoxanil (57966-95-7), (15.10) cypro-sulfamide (221667- 31-8), (15.11) dazomet (533-74-4 ), (15.12) debacarb (62732- 91-6), (15.13) dichlorophene (97-23-4), (15.14) diclomezine (62865-36-5), (15.15) difenzoquat (49866-87-7), (15.16) difenzoquat methyl sulfate (43222-48-6), (15.17) diphenylamine (122-39-4), (15.18) ecomato, (15.19) phenpyrazamine (473798-59-3), (15.20) flumetover (154025- 04-4), (15.21) fluoroimide (41205-21-4), (15.22) fluosulfamide (106917-52-6), (15.23) flutyanyl (304900-25-2), (15.24) fosetyl aluminum ( 39148-24-8), (15.25) phosethyl-calcium, (15.26) phosethyl-sodium (39148-16-8), (15.27) hexachlorobenzene (118-74-1), (15.28) irumamycin (81604-73 - 1), (15.29) metasulfocarb (66952-49-6), (15.30) methyl isothiocyanate (556-61-6), (15.31) metrafenone (220899-03-6), (15.32) mildiomycin (67527-71) -3), (15.33) natamycin (7681-93-8), (15.34) nickel dimethyldithiocarbamate (15521-65-0), (15.35) nitrotal-isopropyl (10552-74- 6), (15.36) octylinone (26530 -20-1), (15.37) oxamocarb (917242-12-7), (15.38) oxyphenol (34407-87-9), (15.39) pentachlorophenol and salts (87-86-5), (15.40) phenothrin, ( 15.41) phosphorous acid and its salts (13598-36-2), (15.42) propamocarb-phosethylate, (15.43) propanosine-sodium (88498-2-6), (15.44) proquinazide (189278-12-4), (15.45) ) pyrimorf (868390-90-3), (15.45e) (2E) -3- (4-tert-butylphenyl) -3- (2-chloropyridine-4-yl) -1- (morpholine-4-yl) - prop-2-ene-1-one (1231776-28-5), (15.45z) (2Z) -3- (4-tert-butylphenyl) -3- (2-chloropyridine-4-yl) -1- ( morpholine-4-yl) -prop-2-ene-1-one (1231776-29-6), (15.46) pyrrolnitrino (1018-71-9), (15.47) tebufloquina (376645-78-2), (15.48 ) keyboard software (76280-91- 6), (15.49) tolnifanide (304911-9 8-6), (15.50) triazoxide (72459-58-6), (15.51) triclamide (70193-21-4), (15.52) zaryl amide (84527-51-5), (15.53) 2-methylpropanoate (3S, 6S, 7R, 8R) -8-benzyl-3 - [({3 - [(isobutyryloxy) -methoxy] -4-methoxy-pyridine-2-yl} -carbonyl) -amino] -6-methyl- 4,9-dioxo1,5-dioxonane-7-yl (517875-34-2), (15.54) 1- (4- {4 - [(5R) -5- (2,6-difluorophenyl) -4.5 -dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} -piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazole -1-yl] -ethanone (1003319-79-6), (15.55) 1- (4- {4 - [(5S) -5- (2,6-difluorophenyl) -4,5-dihydro1,2 -oxazol-3-yl] -1,3-thiazol-2-yl} -piperidine-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -ethanone ( 1003319- 80-9), (15.56) 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro1,2-oxazol-3-yl] -1,3- thiazol-2-yl} -piperidine-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -ethanone (1003318- 67-9), (15.57) 1H- 1- (4-methoxyphenoxy) -3,3-dimethylbutane-2-yl imidazole-1-carboxylate (111227-17-9), (15.58) 2,3,5,6-tetrachlor-4- (methylsulfonyl) - pyridine (13108-52-6), (15.59) 2,3-dibu tyl-6-chlorothieno [2,3- d] pyrimidine-4 (3H) -one (221451-58-7), (15.60) 2,6-dimethyl1H, 5H- [1,4] dithino [2,3- c: 5,6-c '] dipyrrole-1,3,5,7 (2H, 6H) - tetrone, (15.61) 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol1-yl] -1 - (4- {4 - [(5R) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] - 1,3-thiazol-2-yl} -piperidine-1- yl) -ethanone (1003316-53-7), (15.62) 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4 - [(5S) - 5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} -piperidin-1-yl) -ethanone (1003316-54-8), (15.63) 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- {4- [4- (5-phenyl-4,5-dihydro-1,2- oxazol-3-yl) -1,3-thiazol-2-yl] -piperidine-1-yl} -ethanone (1003316-51-5), (15.64) 2-butoxy-6-iodo-3-propyl-4H -chromene-4-one, (15.65) 2-chloro-5- [2-chloro-1- (2,6-difluoro-4-methoxyphenyl) -4-methyl-1H-imidazol5-yl] -pyridine, (15.66 ) 2-phenylphenol and salts (90-43-7), (15.67) 3- (4,4,5-trifluor-3,3-dimethyl-3,4-dihydroisoquinoline-1-yl) -quinoline (861647-85 -0), (15.68) 3,4,5-trichloropyridine-2,6-dicarbonitrile (17824-85-0), (15.69) 3- [5- (4-clo rophenyl) -2,3-dimethyl-1,2-oxazolidin-3-yl] -pyridine, (15.70) 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine , (15.71) 4- (4-chlorophenyl) - 5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, (15.72) 5- amino-1,3,4-thiadiazole-2-thiol, (15.73) 5-chloro-N'-phenyl-N '- (prop-2-yn-1-yl) -thiophene-2-sulfono-hydrazide (134-31-6), (15.74) 5-fluor-2 - [( 4-fluorobenzyl) -oxy] -pyrimidine-4-amine (1174376-11-4), (15.75) 5-fluorine-2 - [(4-methylbenzyl) -oxy] - pyrimidine-4-amine (1174376-25- 0), (15.76) 5-methyl-6-octyl [1,2,4] triazolo [1,5-a] pyrimidine-7-amine, (15.77) (2Z) -3-amino-2-cyano- Ethyl 3-phenylprop-2-enoate, (15.78) N '- (4- {[3- (4-chlorobenzyl) -1,2,4-thiadiazol-5-yl] -oxy} -2,5-dimethylphenyl ) -N-ethyl-N-methylimidoformamide, (15.79) N- (4-chlorobenzyl) -3- [3-methoxy-4- (prop-2-yne-1-yloxy) -phenyl] - propanamide, (15.80) N - [(4-chlorophenyl) - (cyano) -methyl] -3- [3-methoxy-4- (prop-2-yne-1-yloxy) -phenyl] -propanamide, (15.81) N - [(5 -bromo-3-chloro-pyridine-2-yl) -methyl] -2,4-dichloropyridine-3-carboxamide, (15.82) N- [1- (5 -bromo-3-chloropyridine-2-yl) -ethyl] -2,4-dichloropyridine-3-carboxamide, (15.83) N- [1- (5-bromo-3-chloropyridine-2-yl) - ethyl] - 2-fluoro-4-iodopyridine-3-carboxamide, (15.84) N - {(E) - [(cyclo-propylmethoxy) -imino] - [6- (difluoromethoxy) -2,3-difluorophenyl] -methyl} -2 -phenyl-acetamide (221201-92-9), (15.85) N - {(Z) - [(cyclopropylmethoxy) -imino] - [6- (difluoromethoxy) -2,3-difluorophenyl] -methyl} -2-phenylacetamide (221201-92-9), (15.86) N '- {4 - [(3-tert-butyl-4-cyano-1,2-thiazol-5-yl) -oxy] -2-chloro-5-methylphenyl } -N-ethyl-N-methylimidoformamide, (15.87) N-methyl-2- (1 - {[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4- yl) - N- (1,2,3,4-tetrahydronaphthalene-1-yl) -1,3-thiazole-4-carboxamide (922514-49-6), (15.88) N-methyl-2- ( 1 - {[5-methyl3- (trifluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4-yl) -N - [(1R) -1,2,3,4-tetrahydronaphthalene- 1-yl] -1,3-thiazole4-carboxamide (922514-07-6), (15.89) N-methyl-2- (1 - {[5-methyl-3- (trifluoromethyl) -1H-pyrazole-1- yl] -acetyl} -piperidine-4-yl) -N - [(1S) -1,2,3,4-tetrahydronaphthalene-1 - yl] -1,3-thiazole-4-carboxamide (922514-48-5), (15.90) {6- [({[(1-methyl-1H-tetrazol-5-yl) - (phenyl) -methylidene ] -amino} - oxy) -methyl] -pyridine-2-yl} -pentyl carbamate, (15.91) phenazine-1-carboxylic acid, (15.92) quinoline-8-ol (134- 31-6), (15.93 ) quinoline-8-ol (2: 1) (134-31-6), (15.94) {6 - [({[(1-methyl-1H-tetrazol-5-yl) - (phenyl) - methylene ] -amino} -oxy) -methyl] -pyridine-2-yl} -tert-butyl carbamate; (16) other compounds, such as, for example, (16.1) 1-methyl-3- (trifluoromethyl) -N- [2 '- (trifluoromethyl) -biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (16.2) N- (4'-chlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (16.3) N- (2 ', 4'-dichlorobiphenyl-2- yl) -3- (difluoromethyl) -1- methyl-1H-pyrazole-4-carboxamide, (16.4) 3- (difluoromethyl) - 1-methyl-N- [4 '- (trifluoromethyl) -biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (16.5) N- (2 ', 5'-difluorobiphenyl-2-yl) -1-methyl3- (trifluoromethyl) -1H-pyrazole-4-carboxamide, (16.6) 3- ( difluoromethyl) -1-methyl-N- [4 '- (prop-1-yne-1-yl) -biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (16.7) 5-fluorine-1,3 -dimethylN- [4 '- (prop-1-yne-1-yl) -biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (16.8) 2-chloro-N- [4' - (prop- 1-ino-1-yl) - biphenyl-2-yl] -pyridine-3-carboxamide, (16.9) 3- (difluoromethyl) -N- [4 '- (3,3-dimethylbut-1-ino-1- yl) -biphenyl2-yl] -1-methyl-1H-pyrazole-4-carboxamide, (16.10) N- [4'- (3,3-dimethyl-but-1-ino-1-yl) -biphenyl-2 -yl] -5-fluorine-1,3-dimethyl-1H-pyrazole-4-carboxamide, ( 16.11) 3- (difluoromethyl) -N- (4'-ethinylbiphenyl-2-yl) -1-methyl-1Hpyazole-4-carboxamide, (16.12) N- (4'-ethinylbiphenyl-2-yl) - 5-fluorine -1,3-dimethyl-1H-pyrazole-4-carboxamide, (16.13) 2-chloro-N- (4'-ethynylbiphenyl-2-yl) -pyridine-3-carboxamide, (16.14) 2-chloro-N- [4 '- (3,3-dimethylbut-1-ino-1-yl) -biphenyl2-yl] -pyridine-3-carboxamide, (16.15) 4- (difluoromethyl) -2- methyl-N- [4'- (trifluoromethyl) -biphenyl-2-yl] -1,3-thiazole-5-carboxamide, (16.16) 5-fluorine-N- [4 '- (3-hydroxy-3-methylbut-1-ino-1-yl ) -biphenyl-2-yl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, (16.17) 2-chloro-N- [4 '- (3-hydroxy-3-methylbut-1-ino-1 -yl) -biphenyl-2-yl] -pyridine-3-carboxamide, (16.18) 3- (difluoromethyl) -N- [4 '- (3-methoxy-3-methylbut-1-ino-1-yl) - biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, (16.19) 5- fluorine-N- [4 '- (3-methoxy-3-methylbut-1-ino-1-yl) - biphenyl-2-yl] - 1,3-dimethyl-1H-pyrazole-4-carboxamide, (16.20) 2-chloro-N- [4 '- (3-methoxy-3-methylbut-1-ino-1-yl ) -biphenyl-2-yl] - pyridine-3-carboxamide, (16.21) (5-bromo-2-methoxy-4-methylpyridine-3-yl) - (2, 3,4-trimethoxy-6-methylphenyl) - methanone, (16.22) N- [2- (4 - {[3- (4-chlorophenyl) -prop-2-yne-1-yl] -oxy} -3- methoxyphenyl) -ethyl] -N2- (methylsulfonyl) -valinamide (220706-93-4), (16.23) 4-oxo-4 - [(2-phenylethyl) amino] - butanoic acid, (16.24) {6 - [( {[(Z) - (1-methyl-1H-tetrazol-5-yl) - (phenyl) -methylene] -amino} -oxy) -methyl] -pyridine-2-yl} - but-3-ino carbamate -1-yl, (16.25) 4-amino-5-fluoropyrimidine-2-ol (mesomeric form: 6-amino-5-fluoropyrimidine-2 (1H) -one), (16.26) 3,4,5-trihydroxybenzoate propyl.

[015] Todos os parceiros de mistura referidos das classes (1) a (16) podem, caso os seus grupos funcionais o permitam, facultativamente formar sais com bases ou ácidos adequados.[015] All mixing partners mentioned in classes (1) to (16) may, if their functional groups permit, optionally form salts with suitable bases or acids.

[016] São ainda particularmente preferidas combinações que compreendem pelo menos um outro composto ativo (B) seecionado entre os conjuntos seguintes:[016] Combinations comprising at least one other active compound (B) selected from the following sets are also particularly preferred:

[017] (2.1) bixafeno, (2.2) boscalid, (2.6) fluopiram, (2.8) fluxapiroxad, (2.11) isopirazam (mistura de racemato syn-epimérico 1RS,4SR,9RS e de racemato anti-epimérico 1RS,4SR,9SR), (2.12) isopirazam (racemato anti-epimérico 1RS,4SR,9SR), (2.13) isopirazam (enantiómero anti-epimérico 1R,4S,9S), (2.14) isopirazam (enantiómero anti-epimérico 1S,4R,9R), (2.15) isopirazam (racemato syn-epimérico 1RS,4SR,9RS), (2.16) isopirazam (enantiómero syn-epimérico 1R,4S,9R), (2.17) isopirazam (enantiómero syn-epimérico 1S,4R,9S), (2.27) N-[1-(2,4-diclorofenil)-1-metoxipropano2-il]-3-(difluorometil)-1-metil-1H-pirazole-4-carboxamida, (2.29) N-[9-(diclorometileno)-1,2,3,4-tetra-hidro-1,4- metano-naftaleno-5-il]-3-(difluorometil)-1-metil-1Hpirazole-4-carboxamida, (3.1) ametoctradina, (3.2) amisulbrom, (3.3) azoxistrobina, (3.4) ciazofamida, (3.9) famoxadona, (3.10) fenamidona, (3.12) fluoxastrobina, (3.16) picoxistrobina, (3.17) piraclostrobina, (3.22) trifloxistrobina, (4.6) fluopicolida, (5.1) mistura de bordeaux, (5.4) clorotalonila, (5.5) hidróxido de cobre, (5.7) óxido de cobre, (5.8) oxicloreto de cobre, (5.9) sulfato de cobre(2+), (5.16) folpet, (5.23) mancozeb, (5.25) metiram, (5.26) metiram de zinco, (5.29) propineb, (5.30) enxofre e preparações de enxofre, incluindo polissulfureto de cálcio, (7.7) pirimetanila, (9.2) dimetomorf, (9.4) iprovalicarb, (9.5) mandipropamida, (10.9) propamocarb, (10.10) cloridrato de propamocarb, (12.9) metalaxila, (12.10) metalaxil-M (mefenoxam), (14.4) fluazinam, (15.9) cimoxanila, (15.24) fosetil-alumínio, (15.25) fosetil-cálcio, (15.26) fosetil-sódio, (15.41) ácido fosforoso e seus sais, (15.42) propamocarbfosetilato, (15.54) 1-(4-{4-[(5R)-5-(2,6-difluorofenil)- 4,5-di-hidro-1,2-oxazol-3-il]-1,3-tiazol-2-il}-piperidina1-il)-2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]- etanona, (15.55) 1-(4-{4-[(5S)-5-(2,6-difluorofenil)-4,5- di-hidro-1,2-oxazol-3-il]-1,3-tiazol-2-il}-piperidina-1- il)-2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]-etanona, (15.56) 1-(4-{4-[5-(2,6-difluorofenil)-4,5-di-hidro-1,2- oxazol-3-il]-1,3-tiazol-2-il}-piperidina-1-il)-2-[5-metil3-(trifluorometil)-1H-pirazol-1-il]-etanona, (15.60) 2,6- dimetil-1H,5H-[1,4]ditiino[2,3-c:5,6-c']dipirrole1,3,5,7(2H,6H)-tetrona, (15.90) {6-[({[(1-metil-1Htetrazol-5-il)-(fenil)-metilideno]-amino}-oxi)-metil]- piridina-2-il}-carbamato de pentila.[017] (2.1) bixafen, (2.2) boscalid, (2.6) fluopyram, (2.8) fluxpyroxad, (2.11) isopyrazam (mixture of syn-epimeric racemate 1RS, 4SR, 9RS and anti-epimeric racemate 1RS, 4SR, 9SR ), (2.12) isopyrazam (anti-epimeric racemate 1RS, 4SR, 9SR), (2.13) isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), (2.14) isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), (2.15) isopirazam (syn-epimeric racemate 1RS, 4SR, 9RS), (2.16) isopirazam (syn-epimeric enantiomer 1R, 4S, 9R), (2.17) isopirazam (syn-epimeric enantiomer 1S, 4R, 9S), (2.27 ) N- [1- (2,4-dichlorophenyl) -1-methoxypropane2-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.29) N- [9- (dichloromethylene) -1,2,3,4-tetrahydro-1,4-methane-naphthalene-5-yl] -3- (difluoromethyl) -1-methyl-1Hpyazole-4-carboxamide, (3.1) ametoctradine, (3.2) amisulbrom, (3.3) azoxystrobin, (3.4) cyzofamide, (3.9) famoxadone, (3.10) fenamidone, (3.12) fluoxastrobin, (3.16) picoxystrobin, (3.17) pyraclostrobin, (3.22) trifloxystrobin, (5.1) fluopicolide, (5.1) mix that of bordeaux, (5.4) chlorothalonil, (5.5) copper hydroxide, (5.7) copper oxide, (5.8) copper oxychloride, (5.9) copper sulfate (2+), (5.16) folpet, (5.23) mancozeb , (5.25) meth, (5.26) meth zinc, (5.29) propineb, (5.30) sulfur and sulfur preparations, including calcium polysulfide, (7.7) pyrimethanyl, (9.2) dimetomorf, (9.4) iprovalicarb, (9.5) mandipropamide, (10.9) propamocarb, (10.10) propamocarb hydrochloride, (12.9) metalaxyl, (12.10) metalaxyl-M (mefenoxam), (14.4) fluazinam, (15.9) cymoxanil, (15.24) fosetyl aluminum, (15.25) fosetyl -calcium, (15.26) phosethyl sodium, (15.41) phosphorous acid and its salts, (15.42) propamocarbphosetylate, (15.54) 1- (4- {4 - [(5R) -5- (2,6-difluorophenyl) - 4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} -piperidin1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H- pyrazol-1-yl] - ethanone, (15.55) 1- (4- {4 - [(5S) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3 -yl] -1,3-thiazol-2-yl} -piperidine-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -ethanone , (15.56) 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2- yl} -piperidin-1-yl) -2- [5-methyl3- (trifluoromethyl) -1H-pyrazol-1-yl] -ethanone, (15.60) 2,6-dimethyl-1H, 5H- [1,4] dithinoine [2,3-c: 5,6-c '] dipyrrole1,3,5,7 (2H, 6H) -tetrone, (15.90) {6 - [({[(1-methyl-1Htetrazol-5-yl ) - (phenyl) -methylidene] -amino} -oxy) -methyl] - pyridine-2-yl} -pentyl carbamate.

[018] Todos os parceiros de mistura referidos das classes (1) a (15) podem, caso os seus grupos funcionais o permitam, facultativamente formar sais com bases ou ácidos adequados.[018] All mixing partners referred to in classes (1) to (15) may, if their functional groups permit, optionally form salts with suitable bases or acids.

[019] De acordo com uma variante preferida, a invenção é dirigida a misturas que compreendem o composto (I-1), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-1) + (1.1), (I-1) + (1.2), (I-1) + (1.3), (I-1) + (1.4), (I-1) + (1.5), (I-1) + (1.6), (I-1) + (1.7), (I-1) + (1.8), (I-1) + (1.9), (I-1) + (1.10), (I-1) + (1.11), (I-1) + (1.12), (I-1) + (1.13), (I-1) + (1.14), (I-1) + (1.15), (I-1) + (1.16), (I-1) + (1.17), (I-1) + (1.18), (I-1) + (1.19), (I-1) + (1.20), (I-1) + (1.21), (I-1) + (1.22), (I-1) + (1.23), (I-1) + (1.24), (I-1) + (1.25), (I-1) + (1.26), (I-1) + (1.27), (I-1) + (1.28), (I-1) + (1.29), (I-1) + (1.30), (I-1) + (1.31), (I-1) + (1.32), (I-1) + (1.33), (I-1) + (1.34), (I-1) + (1.35), (I-1) + (1.36), (I-1) + (1.37), (I-1) + (1.38), (I-1) + (1.39), (I-1) + (1.40), (I-1) + (1.41), (I-1) + (1.42), (I-1) + (1.43), (I-1) + (1.44), (I-1) + (1.45), (I-1) + (1.46), (I-1) + (1.47), (I-1) + (1.48), (I-1) + (1.49), (I-1) + (1.50), (I-1) + (1.51), (I-1) + (1.52), (I-1) + (1.53), (I-1) + (1.54), (I-1) + (1.55), (I-1) + (1.56), (I-1) + (1.57), (I-1) + (1.58), (I-1) + (1.59), (I-1) + (1.60), (I-1) + (1.61), (I-1) + (1.62), (I-1) + (1.63), (I-1) + (1.64), (I-1) + (2.1), (I-1) + (2.2), (I-1) + (2.3), (I-1) + (2.4), (I-1) + (2.5), (I-1) + (2.6), (I-1) + (2.7), (I-1) + (2.8), (I-1) + (2.9), (I-1) + (2.10), (I-1) + (2.11), (I-1) + (2.12), (I-1) + (2.13), (I-1) + (2.14), (I-1) + (2.15), (I-1) + (2.16), (I-1) + (2.17), (I-1) + (2.18), (I-1) + (2.19), (I-1) + (2.20), (I-1) + (2.21), (I-1) + (2.22), (I-1) + (2.23), (I-1) + (2.24), (I-1) + (2.25), (I-1) + (2.26), (I-1) + (2.27), (I-1) + (2.28), (I-1) + (2.29), (I-1) + (3.1), (I-1) + (3.2), (I-1) + (3.3), (I-1) + (3.4), (I-1) + (3.5), (I-1) + (3.6), (I-1) + (3.7), (I-1) + (3.8), (I-1) + (3.9), (I-1) + (3.10), (I-1) + (3.11), (I-1) + (3.12), (I-1) + (3.13), (I-1) + (3.14), (I-1) + (3.15), (I-1) + (3.16), (I-1) + (3.17), (I-1) + (3.18), (I-1) + (3.19), (I-1) + (3.20), (I-1) + (3.21), (I-1) + (3.22), (I-1) + (3.23), (I-1) + (3.24), (I-1) + (3.25), (I-1) + (3.26), (I-1) + (3.27), (I-1) + (3.28), (I-1) + (3.29), (I-1) + (3.30), (I-1) + (3.31), (I-1) + (3.32), (I-1) + (3.33), (I-1) + (4.1), (I-1) + (4.2), (I-1) + (4.3), (I-1) + (4.4), (I-1) + (4.5), (I-1) + (4.6), (I-1) + (4.7), (I-1) + (4.8), (I-1) + (4.9), (I-1) + (4.10), (I-1) + (4.11), (I-1) + (4.12), (I-1) + (4.13), (I-1) + (4.14), (I-1) + (5.1), (I-1) + (5.2), (I-1) + (5.3), (I-1) + (5.4), (I-1) + (5.5), (I-1) + (5.6), (I-1) + (5.7), (I-1) + (5.8), (I-1) + (5.9), (I-1) + (5.10), (I-1) + (5.11), (I-1) + (5.12), (I-1) + (5.13), (I-1) + (5.14), (I-1) + (5.15), (I-1) + (5.16), (I-1) + (5.17), (I-1) + (5.18), (I-1) + (5.19), (I-1) + (5.20), (I-1) + (5.21), (I-1) + (5.22), (I-1) + (5.23), (I-1) + (5.24), (I-1) + (5.25), (I-1) + (5.26), (I-1) + (5.27), (I-1) + (5.28), (I-1) + (5.29), (I-1) + (5.30), (I-1) + (5.31), (I-1) + (5.32), (I-1) + (5.33), (I-1) + (5.34), (I-1) + (6.1), (I-1) + (6.2), (I-1) + (6.3), (I-1) + (6.4), (I-1) + (7.1), (I-1) + (7.2), (I-1) + (7.3), (I-1) + (7.4), (I-1) + (7.5), (I-1) + (7.6), (I-1) + (7.7), (I-1) + (7.8), (I-1) + (8.1), (I-1) + (8.2), (I-1) + (8.3), (I-1) + (8.4), (I-1) + (9.1), (I-1) + (9.2), (I-1) + (9.3), (I-1) + (9.4), (I-1) + (9.5), (I-1) + (9.6), (I-1) + (9.7), (I-1) + (9.8), (I-1) + (9.9), (I-1) + (10.1), (I-1) + (10.2), (I-1) + (10.3), (I-1) + (10.4), (I-1) + (10.5), (I-1) + (10.6), (I-1) + (10.7), (I-1) + (10.8), (I-1) + (10.9), (I-1) + (10.10), (I-1) + (10.11), (I-1) + (10.12), (I-1) + (10.13), (I-1) + (10.14), (I-1) + (10.15), (I-1) + (11.1), (I-1) + (11.2), (I-1) + (11.3), (I-1) + (11.4), (I-1) + (11.5), (I-1) + (11.6), (I-1) + (11.7), (I-1) + (12.1), (I-1) + (12.2), (I-1) + (12.3), (I-1) + (12.4), (I-1) + (12.5), (I-1) + (12.6), (I-1) + (12.7), (I-1) + (12.8), (I-1) + (12.9), (I-1) + (12.10), (I-1) + (12.11), (I-1) + (12.12), (I-1) + (12.13), (I-1) + (13.1), (I-1) + (13.2), (I-1) + (13.3), (I-1) + (13.4), (I-1) + (13.5), (I-1) + (13.6), (I-1) + (13.7), (I-1) + (14.1), (I-1) + (14.2), (I-1) + (14.3), (I-1) + (14.4), (I-1) + (14.5), (I-1) + (15.1), (I-1) + (15.2), (I-1) + (15.3), (I-1) + (15.4), (I-1) + (15.5), (I-1) + (15.6), (I-1) + (15.7), (I-1) + (15.8), (I-1) + (15.9), (I-1) + (15.10), (I-1) + (15.11), (I-1) + (15.12), (I-1) + (15.13), (I-1) + (15.14), (I-1) + (15.15), (I-1) + (15.16), (I-1) + (15.17), (I-1) + (15.18), (I-1) + (15.19), (I-1) + (15.20), (I-1) + (15.21), (I-1) + (15.22), (I-1) + (15.23), (I-1) + (15.24), (I-1) + (15.25), (I-1) + (15.26), (I-1) + (15.27), (I-1) + (15.28), (I-1) + (15.29), (I-1) + (15.30), (I-1) + (15.31), (I-1) + (15.32), (I-1) + (15.33), (I-1) + (15.34), (I-1) + (15.35), (I-1) + (15.36), (I-1) + (15.37), (I-1) + (15.38), (I-1) + (15.39), (I-1) + (15.41), (I-1) + (15.42), (I-1) + (15.43), (I-1) + (15.44), (I-1) + (15.45), (I-1) + (15.46), (I-1) + (15.47), (I-1) + (15.48), (I-1) + (15.49), (I-1) + (15.50), (I-1) + (15.51), (I-1) + (15.52), (I-1) + (15.53), (I-1) + (15.54), (I-1) + (15.55), (I-1) + (15.56), (I-1) + (15.57), (I-1) + (15.58), (I-1) + (15.59), (I-1) + (15.60), (I-1) + (15.61), (I-1) + (15.62), (I-1) + (15.63), (I-1) + (15.64), (I-1) + (15.65), (I-1) + (15.66), (I-1) + (15.67), (I-1) + (15.68), (I-1) + (15.69), (I-1) + (15.70), (I-1) + (15.71), (I-1) + (15.72), (I-1) + (15.73), (I-1) + (15.74), (I-1) + (15.75), (I-1) + (15.76), (I-1) + (15.77), (I-1) + (15.78), (I-1) + (15.79), (I-1) + (15.80), (I-1) + (15.81), (I-1) + (15.82), (I-1) + (15.83), (I-1) + (15.84), (I-1) + (15.85), (I-1) + (15.86), (I-1) + (15.87), (I-1) + (15.88), (I-1) + (15.89), (I-1) + (15.90), (I-1) + (15.91), (I-1) + (15.92), (I-1) + (15.93), (I-1) + (15.94).[019] According to a preferred variant, the invention is directed to mixtures comprising the compound (I-1), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures (I -1) + (1.1), (I-1) + (1.2), (I-1) + (1.3), (I-1) + (1.4), (I-1) + (1.5), (I -1) + (1.6), (I-1) + (1.7), (I-1) + (1.8), (I-1) + (1.9), (I-1) + (1.10), (I -1) + (1.11), (I-1) + (1.12), (I-1) + (1.13), (I-1) + (1.14), (I-1) + (1.15), (I -1) + (1.16), (I-1) + (1.17), (I-1) + (1.18), (I-1) + (1.19), (I-1) + (1.20), (I -1) + (1.21), (I-1) + (1.22), (I-1) + (1.23), (I-1) + (1.24), (I-1) + (1.25), (I -1) + (1.26), (I-1) + (1.27), (I-1) + (1.28), (I-1) + (1.29), (I-1) + (1.30), (I -1) + (1.31), (I-1) + (1.32), (I-1) + (1.33), (I-1) + (1.34), (I-1) + (1.35), (I -1) + (1.36), (I-1) + (1.37), (I-1) + (1.38), (I-1) + (1.39), (I-1) + (1.40), (I -1) + (1.41), (I-1) + (1.42), (I-1) + (1.43), (I-1) + (1.44), (I-1) + (1.45), (I -1) + (1.46), (I-1) + (1.47), (I-1) + (1.48), (I-1) + (1.49), (I-1) + (1.50), (I - 1) + (1.51), (I-1) + (1.52), (I-1) + (1.53), (I-1) + (1.54), (I-1) + (1.55), (I- 1) + (1.56), (I-1) + (1.57), (I-1) + (1.58), (I-1) + (1.59), (I-1) + (1.60), (I- 1) + (1.61), (I-1) + (1.62), (I-1) + (1.63), (I-1) + (1.64), (I-1) + (2.1), (I- 1) + (2.2), (I-1) + (2.3), (I-1) + (2.4), (I-1) + (2.5), (I-1) + (2.6), (I- 1) + (2.7), (I-1) + (2.8), (I-1) + (2.9), (I-1) + (2.10), (I-1) + (2.11), (I- 1) + (2.12), (I-1) + (2.13), (I-1) + (2.14), (I-1) + (2.15), (I-1) + (2.16), (I- 1) + (2.17), (I-1) + (2.18), (I-1) + (2.19), (I-1) + (2.20), (I-1) + (2.21), (I- 1) + (2.22), (I-1) + (2.23), (I-1) + (2.24), (I-1) + (2.25), (I-1) + (2.26), (I- 1) + (2.27), (I-1) + (2.28), (I-1) + (2.29), (I-1) + (3.1), (I-1) + (3.2), (I- 1) + (3.3), (I-1) + (3.4), (I-1) + (3.5), (I-1) + (3.6), (I-1) + (3.7), (I- 1) + (3.8), (I-1) + (3.9), (I-1) + (3.10), (I-1) + (3.11), (I-1) + (3.12), (I- 1) + (3.13), (I-1) + (3.14), (I-1) + (3.15), (I-1) + (3.16), (I-1) + (3.17), (I- 1) + (3.18), (I-1) + (3.19), (I-1) + (3.20), (I-1) + (3.21 ), (I-1) + (3.22), (I-1) + (3.23), (I-1) + (3.24), (I-1) + (3.25), (I-1) + (3.26 ), (I-1) + (3.27), (I-1) + (3.28), (I-1) + (3.29), (I-1) + (3.30), (I-1) + (3.31 ), (I-1) + (3.32), (I-1) + (3.33), (I-1) + (4.1), (I-1) + (4.2), (I-1) + (4.3 ), (I-1) + (4.4), (I-1) + (4.5), (I-1) + (4.6), (I-1) + (4.7), (I-1) + (4.8 ), (I-1) + (4.9), (I-1) + (4.10), (I-1) + (4.11), (I-1) + (4.12), (I-1) + (4.13 ), (I-1) + (4.14), (I-1) + (5.1), (I-1) + (5.2), (I-1) + (5.3), (I-1) + (5.4 ), (I-1) + (5.5), (I-1) + (5.6), (I-1) + (5.7), (I-1) + (5.8), (I-1) + (5.9 ), (I-1) + (5.10), (I-1) + (5.11), (I-1) + (5.12), (I-1) + (5.13), (I-1) + (5.14 ), (I-1) + (5.15), (I-1) + (5.16), (I-1) + (5.17), (I-1) + (5.18), (I-1) + (5.19 ), (I-1) + (5.20), (I-1) + (5.21), (I-1) + (5.22), (I-1) + (5.23), (I-1) + (5.24 ), (I-1) + (5.25), (I-1) + (5.26), (I-1) + (5.27), (I-1) + (5.28), (I-1) + (5.29 ), (I-1) + (5.30), (I-1) + (5.31), (I-1) + (5.32), (I-1) + (5.33), (I-1) + (5.34 ), (I-1) + (6.1), (I-1) + (6.2), (I-1) + (6.3), (I-1) + (6 .4), (I-1) + (7.1), (I-1) + (7.2), (I-1) + (7.3), (I-1) + (7.4), (I-1) + (7.5), (I-1) + (7.6), (I-1) + (7.7), (I-1) + (7.8), (I-1) + (8.1), (I-1) + (8.2), (I-1) + (8.3), (I-1) + (8.4), (I-1) + (9.1), (I-1) + (9.2), (I-1) + (9.3), (I-1) + (9.4), (I-1) + (9.5), (I-1) + (9.6), (I-1) + (9.7), (I-1) + (9.8), (I-1) + (9.9), (I-1) + (10.1), (I-1) + (10.2), (I-1) + (10.3), (I-1) + (10.4), (I-1) + (10.5), (I-1) + (10.6), (I-1) + (10.7), (I-1) + (10.8), (I-1) + (10.9), (I-1) + (10.10), (I-1) + (10.11), (I-1) + (10.12), (I-1) + (10.13), (I-1) + (10.14), (I-1) + (10.15), (I-1) + (11.1), (I-1) + (11.2), (I-1) + (11.3), (I-1) + (11.4), (I-1) + (11.5), (I-1) + (11.6), (I-1) + (11.7), (I-1) + (12.1), (I-1) + (12.2), (I-1) + (12.3), (I-1) + (12.4), (I-1) + (12.5), (I-1) + (12.6), (I-1) + (12.7), (I-1) + (12.8), (I-1) + (12.9), (I-1) + (12.10), (I-1) + (12.11), (I-1) + (12.12), (I-1) + (12.13), (I-1) + (13.1), (I-1) + (13.2), (I-1) + (13.3), (I-1) + (13.4), (I-1) + (13.5), (I-1) + (13.6), (I-1) + (13.7) , (I-1) + (14.1), (I-1) + (14.2), (I-1) + (14.3), (I-1) + (14.4), (I-1) + (14.5) , (I-1) + (15.1), (I-1) + (15.2), (I-1) + (15.3), (I-1) + (15.4), (I-1) + (15.5) , (I-1) + (15.6), (I-1) + (15.7), (I-1) + (15.8), (I-1) + (15.9), (I-1) + (15.10) , (I-1) + (15.11), (I-1) + (15.12), (I-1) + (15.13), (I-1) + (15.14), (I-1) + (15.15) , (I-1) + (15.16), (I-1) + (15.17), (I-1) + (15.18), (I-1) + (15.19), (I-1) + (15.20) , (I-1) + (15.21), (I-1) + (15.22), (I-1) + (15.23), (I-1) + (15.24), (I-1) + (15.25) , (I-1) + (15.26), (I-1) + (15.27), (I-1) + (15.28), (I-1) + (15.29), (I-1) + (15.30) , (I-1) + (15.31), (I-1) + (15.32), (I-1) + (15.33), (I-1) + (15.34), (I-1) + (15.35) , (I-1) + (15.36), (I-1) + (15.37), (I-1) + (15.38), (I-1) + (15.39), (I-1) + (15.41) , (I-1) + (15.42), (I-1) + (15.43), (I-1) + (15.44), (I-1) + (15.45), (I-1) + (15.46) , (I-1) + (15.47), (I-1) + (15.48), (I-1) + (15.49), (I-1) + (15.50), (I-1) + (15.51) , (I-1) + (15.52), (I-1) + (15.53), (I-1) + (15.54), (I-1) + (15.55), (I-1) + ( 15.56), (I-1) + (15.57), (I-1) + (15.58), (I-1) + (15.59), (I-1) + (15.60), (I-1) + ( 15.61), (I-1) + (15.62), (I-1) + (15.63), (I-1) + (15.64), (I-1) + (15.65), (I-1) + ( 15.66), (I-1) + (15.67), (I-1) + (15.68), (I-1) + (15.69), (I-1) + (15.70), (I-1) + ( 15.71), (I-1) + (15.72), (I-1) + (15.73), (I-1) + (15.74), (I-1) + (15.75), (I-1) + ( 15.76), (I-1) + (15.77), (I-1) + (15.78), (I-1) + (15.79), (I-1) + (15.80), (I-1) + ( 15.81), (I-1) + (15.82), (I-1) + (15.83), (I-1) + (15.84), (I-1) + (15.85), (I-1) + ( 15.86), (I-1) + (15.87), (I-1) + (15.88), (I-1) + (15.89), (I-1) + (15.90), (I-1) + ( 15.91), (I-1) + (15.92), (I-1) + (15.93), (I-1) + (15.94).

[020] De acordo com uma outra variante particularmente preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-1), enquanto composto de fórmulaestrutural (I) e um componente (B) e, em particular, às misturas (I-1) + (2.1), (I-1) + (2.2), (I-1) + (2.6), (I-1) + (2.8), (I-1) + (2.11), (I-1) + (2.12), (I-1) + (2.13), (I-1) + (2.14), (I-1) + (2.15), (I-1) + (2.16), (I-1) + (2.17), (I-1) + (2.29), (I-1) + (3.1), (I-1) + (3.2), (I-1) + (3.3), (I-1) + (3.4), (I-1) + (3.9), (I-1) + (3.10), (I-1) + (3.12), (I-1) + (3.16), (I-1) + (3.17), (I-1) + (3.22), (I-1) + (4.6), (I-1) + (5.1), (I-1) + (5.4), (I-1) + (5.5), (I-1) + (5.7), (I-1) + (5.8), (I-1) + (5.9), (I-1) + (5.16), (I-1) + (5.23), (I-1) + (5.25), (I-1) + (5.26), (I-1) + (5.29), (I-1) + (5.30), (I-1) + (7.7), (I-1) + (9.2), (I-1) + (9.4), (I-1) + (9.5), (I-1) + (10.9), (I-1) + (10.10), (I-1) + (12.9), (I-1) + (12.10), (I-1) + (14.4), (I-1) + (15.9), (I-1) + (15.24), (I-1) + (15.25), (I-1) + (15.26), (I-1) + (15.41), (I-1) + (15.42), (I-1) + (15.54), (I-1) + (15.55), (I-1) + (15.56), (I-1) + (15.60), (I-1) + (15.90).[020] According to another particularly preferred variant, the present invention is directed to mixtures comprising the compound (I-1), as a structural formula compound (I) and a component (B) and, in particular, to mixtures ( I-1) + (2.1), (I-1) + (2.2), (I-1) + (2.6), (I-1) + (2.8), (I-1) + (2.11), ( I-1) + (2.12), (I-1) + (2.13), (I-1) + (2.14), (I-1) + (2.15), (I-1) + (2.16), ( I-1) + (2.17), (I-1) + (2.29), (I-1) + (3.1), (I-1) + (3.2), (I-1) + (3.3), ( I-1) + (3.4), (I-1) + (3.9), (I-1) + (3.10), (I-1) + (3.12), (I-1) + (3.16), ( I-1) + (3.17), (I-1) + (3.22), (I-1) + (4.6), (I-1) + (5.1), (I-1) + (5.4), ( I-1) + (5.5), (I-1) + (5.7), (I-1) + (5.8), (I-1) + (5.9), (I-1) + (5.16), ( I-1) + (5.23), (I-1) + (5.25), (I-1) + (5.26), (I-1) + (5.29), (I-1) + (5.30), ( I-1) + (7.7), (I-1) + (9.2), (I-1) + (9.4), (I-1) + (9.5), (I-1) + (10.9), ( I-1) + (10.10), (I-1) + (12.9), (I-1) + (12.10), (I-1) + (14.4), (I-1) + (15.9), ( I-1) + (15.24), (I-1) + (15.25), (I-1) + (15.26), (I-1) + (15. 41), (I-1) + (15.42), (I-1) + (15.54), (I-1) + (15.55), (I-1) + (15.56), (I-1) + ( 15.60), (I-1) + (15.90).

[021] De acordo com uma variante preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-2), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-2) + (1.1), (I-2) + (1.2), (I-2) + (1.3), (I-2) + (1.4), (I-2) + (1.5), (I-2) + (1.6), (I-2) + (1.7), (I-2) + (1.8), (I-2) + (1.9), (I-2) + (1.10), (I-2) + (1.11), (I-2) + (1.12), (I-2) + (1.13), (I-2) + (1.14), (I-2) + (1.15), (I-2) + (1.16), (I2) + (1.17), (I-2) + (1.18), (I-2) + (1.19), (I-2) + (1.20), (I-2) + (1.21), (I-2) + (1.22), (I-2) + (1.23), (I2) + (1.24), (I-2) + (1.25), (I-2) + (1.26), (I-2) + (1.27), (I-2) + (1.28), (I-2) + (1.29), (I-2) + (1.30), (I2) + (1.31), (I-2) + (1.32), (I-2) + (1.33), (I-2) +(1.34), (I-2) + (1.35), (I-2) + (1.36), (I-2) + (1.37), (I2) + (1.38), (I-2) + (1.39), (I-2) + (1.40), (I-2) + (1.41), (I-2) + (1.42), (I-2) + (1.43), (I-2) + (1.44), (I2) + (1.45), (I-2) + (1.46), (I-2) + (1.47), (I-2) + (1.48), (I-2) + (1.49), (I-2) + (1.50), (I-2) + (1.51), (I2) + (1.52), (I-2) + (1.53), (I-2) + (1.54), (I-2) + (1.55), (I-2) + (1.56), (I-2) + (1.57), (I-2) + (1.58), (I2) + (1.59), (I-2) + (1.60), (I-2) + (1.61), (I-2) + (1.62), (I-2) + (1.63), (I-2) + (1.64), (I-2) + (2.1), (I2) + (2.2), (I-2) + (2.3), (I-2) + (2.4), (I-2) + (2.5), (I-2) + (2.6), (I-2) + (2.7), (I-2) + (2.8), (I-2) + (2.9), (I-2) + (2.10), (I-2) + (2.11), (I-2) + (2.12), (I-2) + (2.13), (I-2) + (2.14), (I-2) + (2.15), (I-2) + (2.16), (I2) + (2.17), (I-2) + (2.18), (I-2) + (2.19), (I-2) + (2.20), (I-2) + (2.21), (I-2) + (2.22), (I-2) + (2.23), (I2) + (2.24), (I-2) + (2.25), (I-2) + (2.26), (I-2) + (2.27), (I-2) + (2.28), (I-2) + (2.29), (I-2) + (3.1), (I2) + (3.2), (I-2) + (3.3), (I-2) + (3.4), (I-2) + (3.5), (I-2) + (3.6), (I-2) + (3.7), (I-2) + (3.8), (I-2) + (3.9), (I-2) + (3.10), (I-2) + (3.11), (I-2) + (3.12), (I-2) + (3.13), (I-2) + (3.14), (I-2) + (3.15), (I-2) + (3.16), (I2) + (3.17), (I-2) + (3.18), (I-2) + (3.19), (I-2) + (3.20), (I-2) + (3.21), (I-2) + (3.22), (I-2) + (3.23), (I2) + (3.24), (I-2) + (3.25), (I-2) + (3.26), (I-2) + (3.27), (I-2) + (3.28), (I-2) + (3.29), (I-2) + (3.30), (I2) + (3.31), (I-2) + (3.32), (I-2) + (3.33), (I-2) + (4.1), (I-2) + (4.2), (I-2) + (4.3), (I-2) + (4.4), (I-2) + (4.5), (I-2) + (4.6), (I-2) + (4.7), (I-2) + (4.8), (I-2) + (4.9), (I-2) + (4.10), (I-2) + (4.11), (I-2) + (4.12), (I-2) + (4.13), (I-2) + (4.14), (I-2) + (5.1), (I-2) + (5.2), (I-2) + (5.3), (I-2) + (5.4), (I-2) + (5.5), (I-2) + (5.6), (I-2) + (5.7), (I-2) + (5.8), (I-2) + (5.9), (I-2) + (5.10), (I2) + (5.11), (I-2) + (5.12), (I-2) + (5.13), (I-2) + (5.14), (I-2) + (5.15), (I-2) + (5.16), (I-2) + (5.17), (I2) + (5.18), (I-2) + (5.19), (I-2) + (5.20), (I-2) + (5.21), (I-2) + (5.22), (I-2) + (5.23), (I-2) + (5.24), (I2) + (5.25), (I-2) + (5.26), (I-2) + (5.27), (I-2) + (5.28), (I-2) + (5.29), (I-2) + (5.30), (I-2) + (5.31), (I2) + (5.32), (I-2) + (5.33), (I-2) + (5.34), (I-2) + (6.1), (I-2) + (6.2), (I-2) + (6.3), (I-2) + (6.4), (I-2) + (7.1), (I-2) + (7.2), (I-2) + (7.3), (I-2) + (7.4), (I-2) + (7.5), (I-2) + (7.6), (I-2) + (7.7), (I-2) + (7.8), (I-2) + (8.1), (I-2) + (8.2), (I-2) + (8.3), (I-2) + (8.4), (I-2) + (9.1), (I-2) + (9.2), (I-2) + (9.3), (I-2) + (9.4), (I-2) + (9.5), (I-2) + (9.6), (I-2) + (9.7), (I-2) + (9.8), (I-2) + (9.9), (I-2) + (10.1), (I-2) + (10.2), (I-2) + (10.3), (I-2) + (10.4), (I-2) + (10.5), (I-2) + (10.6), (I-2) + (10.7), (I2) + (10.8), (I-2) + (10.9), (I-2) + (10.10), (I-2) + (10.11), (I-2) + (10.12), (I-2) + (10.13), (I-2) + (10.14), (I-2) + (10.15), (I-2) + (11.1), (I-2) + (11.2), (I-2) + (11.3), (I-2) + (11.4), (I-2) + (11.5), (I-2) + (11.6), (I2) + (11.7), (I-2) + (12.1), (I-2) + (12.2), (I-2) + (12.3), (I-2) + (12.4), (I-2) + (12.5), (I-2) + (12.6), (I2) + (12.7), (I-2) + (12.8), (I-2) + (12.9), (I-2) + (12.10), (I-2) + (12.11), (I-2) + (12.12), (I-2) + (12.13), (I-2) + (13.1), (I-2) + (13.2), (I-2) + (13.3), (I-2) + (13.4), (I-2) + (13.5), (I-2) + (13.6), (I-2) + (13.7), (I2) + (14.1), (I-2) + (14.2), (I-2) + (14.3), (I-2) + (14.4), (I-2) + (14.5), (I-2) + (15.1), (I-2) + (15.2), (I2) + (15.3), (I-2) + (15.4), (I-2) + (15.5), (I-2) +(15.6), (I-2) + (15.7), (I-2) + (15.8), (I-2) + (15.9), (I2) + (15.10), (I-2) + (15.11), (I-2) + (15.12), (I-2) + (15.13), (I-2) + (15.14), (I-2) + (15.15), (I-2) + (15.16), (I-2) + (15.17), (I-2) + (15.18), (I-2) + (15.19), (I-2) + (15.20), (I-2) + (15.21), (I-2) + (15.22), (I-2) + (15.23), (I-2) + (15.24), (I-2) + (15.25), (I-2) + (15.26), (I-2) + (15.27), (I-2) + (15.28), (I-2) + (15.29), (I-2) + (15.30), (I-2) + (15.31), (I-2) + (15.32), (I-2) + (15.33), (I-2) + (15.34), (I-2) + (15.35), (I-2) + (15.36), (I-2) + (15.37), (I-2) + (15.38), (I-2) + (15.39), (I-2) + (15.41), (I-2) + (15.42), (I-2) + (15.43), (I-2) + (15.44), (I-2) + (15.45), (I-2) + (15.46), (I-2) + (15.47), (I-2) + (15.48), (I-2) + (15.49), (I-2) + (15.50), (I-2) + (15.51), (I-2) + (15.52), (I-2) + (15.53), (I-2) + (15.54), (I-2) + (15.55), (I-2) + (15.56), (I-2) + (15.57), (I-2) + (15.58), (I-2) + (15.59), (I-2) + (15.60), (I-2) + (15.61), (I-2) + (15.62), (I-2) + (15.63), (I-2) + (15.64), (I-2) + (15.65), (I-2) + (15.66), (I-2) + (15.67), (I-2) + (15.68), (I-2) + (15.69), (I-2) + (15.70), (I-2) + (15.71), (I-2) + (15.72), (I-2) + (15.73), (I-2) + (15.74), (I-2) + (15.75), (I-2) + (15.76), (I-2) + (15.77), (I-2) + (15.78), (I-2) + (15.79), (I-2) + (15.80), (I-2) + (15.81), (I-2) + (15.82), (I-2) + (15.83), (I-2) + (15.84), (I-2) + (15.85), (I-2) + (15.86), (I-2) + (15.87), (I-2) + (15.88), (I-2) + (15.89), (I-2) + (15.90), (I-2) + (15.91), (I-2) + (15.92), (I-2) + (15.93), (I-2) + (15.94).[021] According to a preferred variant, the present invention is directed to mixtures comprising the compound (I-2), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures ( I-2) + (1.1), (I-2) + (1.2), (I-2) + (1.3), (I-2) + (1.4), (I-2) + (1.5), ( I-2) + (1.6), (I-2) + (1.7), (I-2) + (1.8), (I-2) + (1.9), (I-2) + (1.10), ( I-2) + (1.11), (I-2) + (1.12), (I-2) + (1.13), (I-2) + (1.14), (I-2) + (1.15), ( I-2) + (1.16), (I2) + (1.17), (I-2) + (1.18), (I-2) + (1.19), (I-2) + (1.20), (I- 2) + (1.21), (I-2) + (1.22), (I-2) + (1.23), (I2) + (1.24), (I-2) + (1.25), (I-2) + (1.26), (I-2) + (1.27), (I-2) + (1.28), (I-2) + (1.29), (I-2) + (1.30), (I2) + ( 1.31), (I-2) + (1.32), (I-2) + (1.33), (I-2) + (1.34), (I-2) + (1.35), (I-2) + ( 1.36), (I-2) + (1.37), (I2) + (1.38), (I-2) + (1.39), (I-2) + (1.40), (I-2) + (1.41) , (I-2) + (1.42), (I-2) + (1.43), (I-2) + (1.44), (I2) + (1.45), (I-2) + (1.46), ( I-2) + (1.47), (I-2) + (1.48), (I-2) + (1.49), (I-2) + (1.50), (I-2) + (1.51), (I2) + (1.52), (I-2) + (1.53), (I-2) + (1.54), (I-2) + (1.55), (I -2) + (1.56), (I-2) + (1.57), (I-2) + (1.58), (I2) + (1.59), (I-2) + (1.60), (I-2 ) + (1.61), (I-2) + (1.62), (I-2) + (1.63), (I-2) + (1.64), (I-2) + (2.1), (I2) + (2.2), (I-2) + (2.3), (I-2) + (2.4), (I-2) + (2.5), (I-2) + (2.6), (I-2) + (2.7), (I-2) + (2.8), (I-2) + (2.9), (I-2) + (2.10), (I-2) + (2.11), (I-2) + (2.12), (I-2) + (2.13), (I-2) + (2.14), (I-2) + (2.15), (I-2) + (2.16), (I2) + (2.17 ), (I-2) + (2.18), (I-2) + (2.19), (I-2) + (2.20), (I-2) + (2.21), (I-2) + (2.22 ), (I-2) + (2.23), (I2) + (2.24), (I-2) + (2.25), (I-2) + (2.26), (I-2) + (2.27), (I-2) + (2.28), (I-2) + (2.29), (I-2) + (3.1), (I2) + (3.2), (I-2) + (3.3), (I -2) + (3.4), (I-2) + (3.5), (I-2) + (3.6), (I-2) + (3.7), (I-2) + (3.8), (I -2) + (3.9), (I-2) + (3.10), (I-2) + (3.11), (I-2) + (3.12), (I-2) + (3.13), (I -2) + (3.14), (I-2) + (3.15), (I-2) + (3.16), (I2) + (3.17), (I-2) + (3.18), (I-2 ) + (3.19), (I-2) + (3.20), (I-2) + (3.21), ( I-2) + (3.22), (I-2) + (3.23), (I2) + (3.24), (I-2) + (3.25), (I-2) + (3.26), (I- 2) + (3.27), (I-2) + (3.28), (I-2) + (3.29), (I-2) + (3.30), (I2) + (3.31), (I-2) + (3.32), (I-2) + (3.33), (I-2) + (4.1), (I-2) + (4.2), (I-2) + (4.3), (I-2) + (4.4), (I-2) + (4.5), (I-2) + (4.6), (I-2) + (4.7), (I-2) + (4.8), (I-2) + (4.9), (I-2) + (4.10), (I-2) + (4.11), (I-2) + (4.12), (I-2) + (4.13), (I-2) + (4.14), (I-2) + (5.1), (I-2) + (5.2), (I-2) + (5.3), (I-2) + (5.4), (I-2) + (5.5), (I-2) + (5.6), (I-2) + (5.7), (I-2) + (5.8), (I-2) + (5.9), (I-2) + (5.10), (I2) + (5.11), (I-2) + (5.12), (I-2) + (5.13), (I-2) + (5.14), (I-2) + ( 5.15), (I-2) + (5.16), (I-2) + (5.17), (I2) + (5.18), (I-2) + (5.19), (I-2) + (5.20) , (I-2) + (5.21), (I-2) + (5.22), (I-2) + (5.23), (I-2) + (5.24), (I2) + (5.25), ( I-2) + (5.26), (I-2) + (5.27), (I-2) + (5.28), (I-2) + (5.29), (I-2) + (5.30), ( I-2) + (5.31), (I2) + (5.32), (I-2) + (5.33), (I-2) + (5.34), (I-2) + (6.1), (I- 2) + (6.2), (I-2) + (6.3), (I-2) + (6.4), (I-2) + (7.1), (I-2) + (7.2), (I-2) + (7.3), (I-2) + (7.4), (I-2) + (7.5), (I-2) + (7.6), (I-2) + (7.7), (I-2) + (7.8), (I-2) + (8.1), (I-2) + (8.2), (I-2) + (8.3), (I-2) + (8.4), (I-2) + (9.1), (I-2) + (9.2), (I-2) + (9.3), (I-2) + (9.4), (I-2) + (9.5), (I-2) + (9.6), (I-2) + (9.7), (I-2) + (9.8), (I-2) + (9.9), (I-2) + (10.1), (I-2) + (10.2), (I-2) + (10.3), (I-2) + (10.4), (I-2) + (10.5), (I-2) + (10.6), (I-2) + (10.7), (I2) + (10.8), (I-2) + (10.9), (I-2) + ( 10.10), (I-2) + (10.11), (I-2) + (10.12), (I-2) + (10.13), (I-2) + (10.14), (I-2) + ( 10.15), (I-2) + (11.1), (I-2) + (11.2), (I-2) + (11.3), (I-2) + (11.4), (I-2) + ( 11.5), (I-2) + (11.6), (I2) + (11.7), (I-2) + (12.1), (I-2) + (12.2), (I-2) + (12.3) , (I-2) + (12.4), (I-2) + (12.5), (I-2) + (12.6), (I2) + (12.7), (I-2) + (12.8), ( I-2) + (12.9), (I-2) + (12.10), (I-2) + (12.11), (I-2) + (12.12), (I-2) + (12.13), ( I-2) + (13.1), (I-2) + (13.2), (I-2) + (13.3), (I-2) + (13.4), (I-2) + (13.5), ( I-2) + (13.6), (I-2) + (13.7), (I2) + (14. 1), (I-2) + (14.2), (I-2) + (14.3), (I-2) + (14.4), (I-2) + (14.5), (I-2) + ( 15.1), (I-2) + (15.2), (I2) + (15.3), (I-2) + (15.4), (I-2) + (15.5), (I-2) + (15.6) , (I-2) + (15.7), (I-2) + (15.8), (I-2) + (15.9), (I2) + (15.10), (I-2) + (15.11), ( I-2) + (15.12), (I-2) + (15.13), (I-2) + (15.14), (I-2) + (15.15), (I-2) + (15.16), ( I-2) + (15.17), (I-2) + (15.18), (I-2) + (15.19), (I-2) + (15.20), (I-2) + (15.21), ( I-2) + (15.22), (I-2) + (15.23), (I-2) + (15.24), (I-2) + (15.25), (I-2) + (15.26), ( I-2) + (15.27), (I-2) + (15.28), (I-2) + (15.29), (I-2) + (15.30), (I-2) + (15.31), ( I-2) + (15.32), (I-2) + (15.33), (I-2) + (15.34), (I-2) + (15.35), (I-2) + (15.36), ( I-2) + (15.37), (I-2) + (15.38), (I-2) + (15.39), (I-2) + (15.41), (I-2) + (15.42), ( I-2) + (15.43), (I-2) + (15.44), (I-2) + (15.45), (I-2) + (15.46), (I-2) + (15.47), ( I-2) + (15.48), (I-2) + (15.49), (I-2) + (15.50), (I-2) + (15.51), (I-2) + (15.52), ( I-2) + (15.53), (I-2) + (15.54), (I-2) + (15.55), (I-2) + (15.56), (I-2) + ( 15.57), (I-2) + (15.58), (I-2) + (15.59), (I-2) + (15.60), (I-2) + (15.61), (I-2) + ( 15.62), (I-2) + (15.63), (I-2) + (15.64), (I-2) + (15.65), (I-2) + (15.66), (I-2) + ( 15.67), (I-2) + (15.68), (I-2) + (15.69), (I-2) + (15.70), (I-2) + (15.71), (I-2) + ( 15.72), (I-2) + (15.73), (I-2) + (15.74), (I-2) + (15.75), (I-2) + (15.76), (I-2) + ( 15.77), (I-2) + (15.78), (I-2) + (15.79), (I-2) + (15.80), (I-2) + (15.81), (I-2) + ( 15.82), (I-2) + (15.83), (I-2) + (15.84), (I-2) + (15.85), (I-2) + (15.86), (I-2) + ( 15.87), (I-2) + (15.88), (I-2) + (15.89), (I-2) + (15.90), (I-2) + (15.91), (I-2) + ( 15.92), (I-2) + (15.93), (I-2) + (15.94).

[022] De acordo com uma outra variante particularmente preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-2), enquanto composto de fórmula estrutural (I) e um componente (B) e, em particular, às misturas (I-2) + (2.1), (I-2) + (2.2), (I-2) + (2.6), (I-2) + (2.8), (I-2) + (2.11), (I-2) + (2.12), (I-2) + (2.13), (I-2) + (2.14), (I-2) + (2.15), (I-2) + (2.16), (I-2) + (2.17), (I-2) + (2.29), (I-2) + (3.1), (I-2) + (3.2), (I-2) + (3.3), (I-2) + (3.4), (I-2) + (3.9), (I-2) + (3.10), (I2) + (3.12), (I-2) + (3.16), (I-2) + (3.17), (I-2) + (3.22), (I-2) + (4.6), (I-2) + (5.1), (I-2) + (5.4), (I-2) + (5.5), (I-2) + (5.7), (I-2) + (5.8), (I-2) + (5.9), (I-2) + (5.16), (I-2) + (5.23), (I-2) + (5.25), (I-2) + (5.26), (I-2) + (5.29), (I-2) + (5.30), (I-2) + (7.7), (I-2) + (9.2), (I-2) + (9.4), (I-2) + (9.5), (I-2) + (10.9), (I-2) + (10.10), (I-2) + (12.9), (I-2) + (12.10), (I-2) + (14.4), (I-2) + (15.9), (I-2) + (15.24), (I-2) + (15.25), (I-2) + (15.26), (I-2) + (15.41), (I-2) + (15.42), (I-2) + (15.54), (I-2) + (15.55), (I-2) + (15.56), (I-2) + (15.60), (I-2) + (15.90).[022] According to another particularly preferred variant, the present invention is directed to mixtures comprising the compound (I-2), as a compound of structural formula (I) and a component (B) and, in particular, to mixtures (I-2) + (2.1), (I-2) + (2.2), (I-2) + (2.6), (I-2) + (2.8), (I-2) + (2.11), (I-2) + (2.12), (I-2) + (2.13), (I-2) + (2.14), (I-2) + (2.15), (I-2) + (2.16), (I-2) + (2.17), (I-2) + (2.29), (I-2) + (3.1), (I-2) + (3.2), (I-2) + (3.3), (I-2) + (3.4), (I-2) + (3.9), (I-2) + (3.10), (I2) + (3.12), (I-2) + (3.16), (I -2) + (3.17), (I-2) + (3.22), (I-2) + (4.6), (I-2) + (5.1), (I-2) + (5.4), (I -2) + (5.5), (I-2) + (5.7), (I-2) + (5.8), (I-2) + (5.9), (I-2) + (5.16), (I -2) + (5.23), (I-2) + (5.25), (I-2) + (5.26), (I-2) + (5.29), (I-2) + (5.30), (I -2) + (7.7), (I-2) + (9.2), (I-2) + (9.4), (I-2) + (9.5), (I-2) + (10.9), (I -2) + (10.10), (I-2) + (12.9), (I-2) + (12.10), (I-2) + (14.4), (I-2) + (15.9), (I -2) + (15.24), (I-2) + (15.25), (I-2) + (15.26), (I-2) + (15. 41), (I-2) + (15.42), (I-2) + (15.54), (I-2) + (15.55), (I-2) + (15.56), (I-2) + ( 15.60), (I-2) + (15.90).

[023] De acordo com uma variante preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-3), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-3) + (1.1), (I-3) + (1.2), (I-3) + (1.3), (I-3) + (1.4), (I-3) + (1.5), (I-3) + (1.6), (I-3) + (1.7), (I-3) + (1.8), (I-3) + (1.9), (I-3) + (1.10), (I-3) + (1.11), (I-3) + (1.12), (I-3) + (1.13), (I-3) + (1.14), (I-3) + (1.15), (I-3) + (1.16), (I3) + (1.17), (I-3) + (1.18), (I-3) + (1.19), (I-3) + (1.20), (I-3) + (1.21), (I-3) + (1.22), (I-3) + (1.23), (I3) + (1.24), (I-3) + (1.25), (I-3) + (1.26), (I-3) + (1.27), (I-3) + (1.28), (I-3) + (1.29), (I-3) + (1.30), (I3) + (1.31), (I-3) + (1.32), (I-3) + (1.33), (I-3) + (1.34), (I-3) + (1.35), (I-3) + (1.36), (I-3) + (1.37), (I3) + (1.38), (I-3) + (1.39), (I-3) + (1.40), (I-3) +(1.41), (I-3) + (1.42), (I-3) + (1.43), (I-3) + (1.44), (I3) + (1.45), (I-3) + (1.46), (I-3) + (1.47), (I-3) + (1.48), (I-3) + (1.49), (I-3) + (1.50), (I-3) + (1.51), (I3) + (1.52), (I-3) + (1.53), (I-3) + (1.54), (I-3) + (1.55), (I-3) + (1.56), (I-3) + (1.57), (I-3) + (1.58), (I3) + (1.59), (I-3) + (1.60), (I-3) + (1.61), (I-3) + (1.62), (I-3) + (1.63), (I-3) + (1.64), (I-3) + (2.1), (I3) + (2.2), (I-3) + (2.3), (I-3) + (2.4), (I-3) + (2.5), (I-3) + (2.6), (I-3) + (2.7), (I-3) + (2.8), (I-3) + (2.9), (I-3) + (2.10), (I-3) + (2.11), (I-3) + (2.12), (I-3) + (2.13), (I-3) + (2.14), (I-3) + (2.15), (I-3) + (2.16), (I3) + (2.17), (I-3) + (2.18), (I-3) + (2.19), (I-3) + (2.20), (I-3) + (2.21), (I-3) + (2.22), (I-3) + (2.23), (I3) + (2.24), (I-3) + (2.25), (I-3) + (2.26), (I-3) + (2.27), (I-3) + (2.28), (I-3) + (2.29), (I-3) + (3.1), (I3) + (3.2), (I-3) + (3.3), (I-3) + (3.4), (I-3) + (3.5), (I-3) + (3.6), (I-3) + (3.7), (I-3) + (3.8), (I-3) + (3.9), (I-3) + (3.10), (I-3) + (3.11), (I-3) + (3.12), (I-3) + (3.13), (I-3) + (3.14), (I-3) + (3.15), (I-3) + (3.16), (I3) + (3.17), (I-3) + (3.18), (I-3) + (3.19), (I-3) + (3.20), (I-3) + (3.21), (I-3) + (3.22), (I-3) + (3.23), (I3) + (3.24), (I-3) + (3.25), (I-3) + (3.26), (I-3) + (3.27), (I-3) + (3.28), (I-3) + (3.29), (I-3) + (3.30), (I3) + (3.31), (I-3) + (3.32), (I-3) + (3.33), (I-3) + (4.1), (I-3) + (4.2), (I-3) + (4.3), (I-3) + (4.4), (I-3) + (4.5), (I-3) + (4.6), (I-3) + (4.7), (I-3) + (4.8), (I-3) + (4.9), (I-3) + (4.10), (I-3) + (4.11), (I-3) + (4.12), (I-3) + (4.13), (I-3) + (4.14), (I-3) + (5.1), (I-3) + (5.2), (I-3) + (5.3), (I-3) + (5.4), (I-3) + (5.5), (I-3) + (5.6), (I-3) + (5.7), (I-3) + (5.8), (I-3) + (5.9), (I-3) + (5.10), (I3) + (5.11), (I-3) + (5.12), (I-3) + (5.13), (I-3) + (5.14), (I-3) + (5.15), (I-3) + (5.16), (I-3) + (5.17), (I3) + (5.18), (I-3) + (5.19), (I-3) + (5.20), (I-3) + (5.21), (I-3) + (5.22), (I-3) + (5.23), (I-3) + (5.24), (I3) + (5.25), (I-3) + (5.26), (I-3) + (5.27), (I-3) + (5.28), (I-3) + (5.29), (I-3) + (5.30), (I-3) + (5.31), (I3) + (5.32), (I-3) + (5.33), (I-3) + (5.34), (I-3) + (6.1), (I-3) + (6.2), (I-3) + (6.3), (I-3) + (6.4), (I-3) + (7.1), (I-3) + (7.2), (I-3) + (7.3), (I-3) + (7.4), (I-3) + (7.5), (I-3) + (7.6), (I-3) + (7.7), (I-3) + (7.8), (I-3) + (8.1), (I-3) + (8.2), (I-3) + (8.3), (I-3) + (8.4), (I-3) + (9.1), (I-3) + (9.2), (I-3) + (9.3), (I-3) + (9.4), (I-3) + (9.5), (I-3) + (9.6), (I-3) + (9.7), (I-3) + (9.8), (I-3) + (9.9), (I-3) + (10.1), (I-3) + (10.2), (I-3) + (10.3), (I-3) + (10.4), (I-3) + (10.5), (I-3) + (10.6), (I-3) + (10.7), (I3) + (10.8), (I-3) + (10.9), (I-3) + (10.10), (I-3) + (10.11), (I-3) + (10.12), (I-3) + (10.13), (I-3) + (10.14), (I-3) + (10.15), (I-3) + (11.1), (I-3) + (11.2), (I-3) + (11.3), (I-3) + (11.4), (I-3) + (11.5), (I-3) + (11.6), (I3) + (11.7), (I-3) + (12.1), (I-3) + (12.2), (I-3) + (12.3), (I-3) + (12.4), (I-3) + (12.5), (I-3) + (12.6), (I3) + (12.7), (I-3) + (12.8), (I-3) + (12.9), (I-3) + (12.10), (I-3) + (12.11), (I-3) + (12.12), (I-3) + (12.13), (I-3) + (13.1), (I-3) + (13.2), (I-3) + (13.3), (I-3) + (13.4), (I-3) + (13.5), (I-3) + (13.6), (I-3) + (13.7), (I3) + (14.1), (I-3) + (14.2), (I-3) + (14.3), (I-3) + (14.4), (I-3) + (14.5), (I-3) + (15.1), (I-3) + (15.2), (I3) + (15.3), (I-3) + (15.4), (I-3) + (15.5), (I-3) + (15.6), (I-3) + (15.7), (I-3) + (15.8), (I-3) + (15.9), (I3) + (15.10), (I-3) + (15.11), (I-3) + (15.12), (I-3) +(15.13), (I-3) + (15.14), (I-3) + (15.15), (I-3) + (15.16), (I-3) + (15.17), (I-3) + (15.18), (I-3) + (15.19), (I-3) + (15.20), (I-3) + (15.21), (I-3) + (15.22), (I-3) + (15.23), (I-3) + (15.24), (I-3) + (15.25), (I-3) + (15.26), (I-3) + (15.27), (I-3) + (15.28), (I-3) + (15.29), (I-3) + (15.30), (I-3) + (15.31), (I-3) + (15.32), (I-3) + (15.33), (I-3) + (15.34), (I-3) + (15.35), (I-3) + (15.36), (I-3) + (15.37), (I-3) + (15.38), (I-3) + (15.39), (I-3) + (15.41), (I-3) + (15.42), (I-3) + (15.43), (I-3) + (15.44), (I-3) + (15.45), (I-3) + (15.46), (I-3) + (15.47), (I-3) + (15.48), (I-3) + (15.49), (I-3) + (15.50), (I-3) + (15.51), (I-3) + (15.52), (I-3) + (15.53), (I-3) + (15.54), (I-3) + (15.55), (I-3) + (15.56), (I-3) + (15.57), (I-3) + (15.58), (I-3) + (15.59), (I-3) + (15.60), (I-3) + (15.61), (I-3) + (15.62), (I-3) + (15.63), (I-3) + (15.64), (I-3) + (15.65), (I-3) + (15.66), (I-3) + (15.67), (I-3) + (15.68), (I-3) + (15.69), (I-3) + (15.70), (I-3) + (15.71), (I-3) + (15.72), (I-3) + (15.73), (I-3) + (15.74), (I-3) + (15.75), (I-3) + (15.76), (I-3) + (15.77), (I-3) + (15.78), (I-3) + (15.79), (I-3) + (15.80), (I-3) + (15.81), (I-3) + (15.82), (I-3) + (15.83), (I-3) + (15.84), (I-3) + (15.85), (I-3) + (15.86), (I-3) + (15.87), (I-3) + (15.88), (I-3) + (15.89), (I-3) + (15.90), (I-3) + (15.91), (I-3) + (15.92), (I-3) + (15.93), (I-3) + (15.94).[023] According to a preferred variant, the present invention is directed to mixtures comprising the compound (I-3), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures ( I-3) + (1.1), (I-3) + (1.2), (I-3) + (1.3), (I-3) + (1.4), (I-3) + (1.5), ( I-3) + (1.6), (I-3) + (1.7), (I-3) + (1.8), (I-3) + (1.9), (I-3) + (1.10), ( I-3) + (1.11), (I-3) + (1.12), (I-3) + (1.13), (I-3) + (1.14), (I-3) + (1.15), ( I-3) + (1.16), (I3) + (1.17), (I-3) + (1.18), (I-3) + (1.19), (I-3) + (1.20), (I- 3) + (1.21), (I-3) + (1.22), (I-3) + (1.23), (I3) + (1.24), (I-3) + (1.25), (I-3) + (1.26), (I-3) + (1.27), (I-3) + (1.28), (I-3) + (1.29), (I-3) + (1.30), (I3) + ( 1.31), (I-3) + (1.32), (I-3) + (1.33), (I-3) + (1.34), (I-3) + (1.35), (I-3) + ( 1.36), (I-3) + (1.37), (I3) + (1.38), (I-3) + (1.39), (I-3) + (1.40), (I-3) + (1.41) , (I-3) + (1.42), (I-3) + (1.43), (I-3) + (1.44), (I3) + (1.45), (I-3) + (1.46), ( I-3) + (1.47), (I-3) + (1.48), (I-3) + (1.49), (I-3) + (1.50), (I-3) + (1.51), (I3) + (1.52), (I-3) + (1.53), (I-3) + (1.54), (I-3) + (1.55), (I -3) + (1.56), (I-3) + (1.57), (I-3) + (1.58), (I3) + (1.59), (I-3) + (1.60), (I-3 ) + (1.61), (I-3) + (1.62), (I-3) + (1.63), (I-3) + (1.64), (I-3) + (2.1), (I3) + (2.2), (I-3) + (2.3), (I-3) + (2.4), (I-3) + (2.5), (I-3) + (2.6), (I-3) + (2.7), (I-3) + (2.8), (I-3) + (2.9), (I-3) + (2.10), (I-3) + (2.11), (I-3) + (2.12), (I-3) + (2.13), (I-3) + (2.14), (I-3) + (2.15), (I-3) + (2.16), (I3) + (2.17 ), (I-3) + (2.18), (I-3) + (2.19), (I-3) + (2.20), (I-3) + (2.21), (I-3) + (2.22 ), (I-3) + (2.23), (I3) + (2.24), (I-3) + (2.25), (I-3) + (2.26), (I-3) + (2.27), (I-3) + (2.28), (I-3) + (2.29), (I-3) + (3.1), (I3) + (3.2), (I-3) + (3.3), (I -3) + (3.4), (I-3) + (3.5), (I-3) + (3.6), (I-3) + (3.7), (I-3) + (3.8), (I -3) + (3.9), (I-3) + (3.10), (I-3) + (3.11), (I-3) + (3.12), (I-3) + (3.13), (I -3) + (3.14), (I-3) + (3.15), (I-3) + (3.16), (I3) + (3.17), (I-3) + (3.18), (I-3 ) + (3.19), (I-3) + (3.20), (I-3) + (3.21), ( I-3) + (3.22), (I-3) + (3.23), (I3) + (3.24), (I-3) + (3.25), (I-3) + (3.26), (I- 3) + (3.27), (I-3) + (3.28), (I-3) + (3.29), (I-3) + (3.30), (I3) + (3.31), (I-3) + (3.32), (I-3) + (3.33), (I-3) + (4.1), (I-3) + (4.2), (I-3) + (4.3), (I-3) + (4.4), (I-3) + (4.5), (I-3) + (4.6), (I-3) + (4.7), (I-3) + (4.8), (I-3) + (4.9), (I-3) + (4.10), (I-3) + (4.11), (I-3) + (4.12), (I-3) + (4.13), (I-3) + (4.14), (I-3) + (5.1), (I-3) + (5.2), (I-3) + (5.3), (I-3) + (5.4), (I-3) + (5.5), (I-3) + (5.6), (I-3) + (5.7), (I-3) + (5.8), (I-3) + (5.9), (I-3) + (5.10), (I3) + (5.11), (I-3) + (5.12), (I-3) + (5.13), (I-3) + (5.14), (I-3) + ( 5.15), (I-3) + (5.16), (I-3) + (5.17), (I3) + (5.18), (I-3) + (5.19), (I-3) + (5.20) , (I-3) + (5.21), (I-3) + (5.22), (I-3) + (5.23), (I-3) + (5.24), (I3) + (5.25), ( I-3) + (5.26), (I-3) + (5.27), (I-3) + (5.28), (I-3) + (5.29), (I-3) + (5.30), ( I-3) + (5.31), (I3) + (5.32), (I-3) + (5.33), (I-3) + (5.34), (I-3) + (6.1), (I- 3) + (6.2), (I-3) + (6.3), (I-3) + (6.4), (I-3) + (7.1), (I-3) + (7.2), (I-3) + (7.3), (I-3) + (7.4), (I-3) + (7.5), (I-3) + (7.6), (I-3) + (7.7), (I-3) + (7.8), (I-3) + (8.1), (I-3) + (8.2), (I-3) + (8.3), (I-3) + (8.4), (I-3) + (9.1), (I-3) + (9.2), (I-3) + (9.3), (I-3) + (9.4), (I-3) + (9.5), (I-3) + (9.6), (I-3) + (9.7), (I-3) + (9.8), (I-3) + (9.9), (I-3) + (10.1), (I-3) + (10.2), (I-3) + (10.3), (I-3) + (10.4), (I-3) + (10.5), (I-3) + (10.6), (I-3) + (10.7), (I3) + (10.8), (I-3) + (10.9), (I-3) + ( 10.10), (I-3) + (10.11), (I-3) + (10.12), (I-3) + (10.13), (I-3) + (10.14), (I-3) + ( 10.15), (I-3) + (11.1), (I-3) + (11.2), (I-3) + (11.3), (I-3) + (11.4), (I-3) + ( 11.5), (I-3) + (11.6), (I3) + (11.7), (I-3) + (12.1), (I-3) + (12.2), (I-3) + (12.3) , (I-3) + (12.4), (I-3) + (12.5), (I-3) + (12.6), (I3) + (12.7), (I-3) + (12.8), ( I-3) + (12.9), (I-3) + (12.10), (I-3) + (12.11), (I-3) + (12.12), (I-3) + (12.13), ( I-3) + (13.1), (I-3) + (13.2), (I-3) + (13.3), (I-3) + (13.4), (I-3) + (13.5), ( I-3) + (13.6), (I-3) + (13.7), (I3) + (14. 1), (I-3) + (14.2), (I-3) + (14.3), (I-3) + (14.4), (I-3) + (14.5), (I-3) + ( 15.1), (I-3) + (15.2), (I3) + (15.3), (I-3) + (15.4), (I-3) + (15.5), (I-3) + (15.6) , (I-3) + (15.7), (I-3) + (15.8), (I-3) + (15.9), (I3) + (15.10), (I-3) + (15.11), ( I-3) + (15.12), (I-3) + (15.13), (I-3) + (15.14), (I-3) + (15.15), (I-3) + (15.16), ( I-3) + (15.17), (I-3) + (15.18), (I-3) + (15.19), (I-3) + (15.20), (I-3) + (15.21), ( I-3) + (15.22), (I-3) + (15.23), (I-3) + (15.24), (I-3) + (15.25), (I-3) + (15.26), ( I-3) + (15.27), (I-3) + (15.28), (I-3) + (15.29), (I-3) + (15.30), (I-3) + (15.31), ( I-3) + (15.32), (I-3) + (15.33), (I-3) + (15.34), (I-3) + (15.35), (I-3) + (15.36), ( I-3) + (15.37), (I-3) + (15.38), (I-3) + (15.39), (I-3) + (15.41), (I-3) + (15.42), ( I-3) + (15.43), (I-3) + (15.44), (I-3) + (15.45), (I-3) + (15.46), (I-3) + (15.47), ( I-3) + (15.48), (I-3) + (15.49), (I-3) + (15.50), (I-3) + (15.51), (I-3) + (15.52), ( I-3) + (15.53), (I-3) + (15.54), (I-3) + (15.55), (I-3) + (15.56), (I-3) + ( 15.57), (I-3) + (15.58), (I-3) + (15.59), (I-3) + (15.60), (I-3) + (15.61), (I-3) + ( 15.62), (I-3) + (15.63), (I-3) + (15.64), (I-3) + (15.65), (I-3) + (15.66), (I-3) + ( 15.67), (I-3) + (15.68), (I-3) + (15.69), (I-3) + (15.70), (I-3) + (15.71), (I-3) + ( 15.72), (I-3) + (15.73), (I-3) + (15.74), (I-3) + (15.75), (I-3) + (15.76), (I-3) + ( 15.77), (I-3) + (15.78), (I-3) + (15.79), (I-3) + (15.80), (I-3) + (15.81), (I-3) + ( 15.82), (I-3) + (15.83), (I-3) + (15.84), (I-3) + (15.85), (I-3) + (15.86), (I-3) + ( 15.87), (I-3) + (15.88), (I-3) + (15.89), (I-3) + (15.90), (I-3) + (15.91), (I-3) + ( 15.92), (I-3) + (15.93), (I-3) + (15.94).

[024] De acordo com uma outra variante particularmente preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-3), enquanto composto de fórmula estrutural (I) e um componente (B) e, em particular, às misturas (I-3) + (2.1), (I-3) + (2.2), (I-3) + (2.6), (I-3) + (2.8), (I-3) + (2.11), (I-3) + (2.12), (I-3) + (2.13), (I-3) + (2.14), (I-3) + (2.15), (I-3) + (2.16), (I-3) +(2.17), (I-3) + (2.29), (I-3) + (3.1), (I-3) + (3.2), (I-3) + (3.3), (I-3) + (3.4), (I-3) + (3.9), (I-3) + (3.10), (I3) + (3.12), (I-3) + (3.16), (I-3) + (3.17), (I-3) + (3.22), (I-3) + (4.6), (I-3) + (5.1), (I-3) + (5.4), (I-3) + (5.5), (I-3) + (5.7), (I-3) + (5.8), (I-3) + (5.9), (I-3) + (5.16), (I-3) + (5.23), (I-3) + (5.25), (I-3) + (5.26), (I-3) + (5.29), (I-3) + (5.30), (I-3) + (7.7), (I-3) + (9.2), (I-3) + (9.4), (I-3) + (9.5), (I-3) + (10.9), (I-3) + (10.10), (I-3) + (12.9), (I-3) + (12.10), (I-3) + (14.4), (I-3) + (15.9), (I-3) + (15.24), (I-3) + (15.25), (I-3) + (15.26), (I-3) + (15.41), (I-3) + (15.42), (I-3) + (15.54), (I-3) + (15.55), (I-3) + (15.56), (I-3) + (15.60), (I-3) + (15.90).[024] According to another particularly preferred variant, the present invention is directed to mixtures comprising the compound (I-3), as a compound of structural formula (I) and a component (B) and, in particular, to mixtures (I-3) + (2.1), (I-3) + (2.2), (I-3) + (2.6), (I-3) + (2.8), (I-3) + (2.11), (I-3) + (2.12), (I-3) + (2.13), (I-3) + (2.14), (I-3) + (2.15), (I-3) + (2.16), (I-3) + (2.17), (I-3) + (2.29), (I-3) + (3.1), (I-3) + (3.2), (I-3) + (3.3), (I-3) + (3.4), (I-3) + (3.9), (I-3) + (3.10), (I3) + (3.12), (I-3) + (3.16), (I -3) + (3.17), (I-3) + (3.22), (I-3) + (4.6), (I-3) + (5.1), (I-3) + (5.4), (I -3) + (5.5), (I-3) + (5.7), (I-3) + (5.8), (I-3) + (5.9), (I-3) + (5.16), (I -3) + (5.23), (I-3) + (5.25), (I-3) + (5.26), (I-3) + (5.29), (I-3) + (5.30), (I -3) + (7.7), (I-3) + (9.2), (I-3) + (9.4), (I-3) + (9.5), (I-3) + (10.9), (I -3) + (10.10), (I-3) + (12.9), (I-3) + (12.10), (I-3) + (14.4), (I-3) + (15.9), (I -3) + (15.24), (I-3) + (15.25), (I-3) + (15.26), (I-3) + (15.4 1), (I-3) + (15.42), (I-3) + (15.54), (I-3) + (15.55), (I-3) + (15.56), (I-3) + ( 15.60), (I-3) + (15.90).

[025] De acordo com uma variante preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-4), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-4) + (1.1), (I-4) + (1.2), (I-4) + (1.3), (I-4) + (1.4), (I-4) + (1.5), (I-4) + (1.6), (I-4) + (1.7), (I-4) + (1.8), (I-4) + (1.9), (I-4) + (1.10), (I-4) + (1.11), (I-4) + (1.12), (I-4) + (1.13), (I-4) + (1.14), (I-4) + (1.15), (I-4) + (1.16), (I4) + (1.17), (I-4) + (1.18), (I-4) + (1.19), (I-4) + (1.20), (I-4) + (1.21), (I-4) + (1.22), (I-4) + (1.23), (I4) + (1.24), (I-4) + (1.25), (I-4) + (1.26), (I-4) + (1.27), (I-4) + (1.28), (I-4) + (1.29), (I-4) + (1.30), (I4) + (1.31), (I-4) + (1.32), (I-4) + (1.33), (I-4) + (1.34), (I-4) + (1.35), (I-4) + (1.36), (I-4) + (1.37), (I4) + (1.38), (I-4) + (1.39), (I-4) + (1.40), (I-4) + (1.41), (I-4) + (1.42), (I-4) + (1.43), (I-4) + (1.44), (I4) + (1.45), (I-4) + (1.46), (I-4) + (1.47), (I-4) +(1.48), (I-4) + (1.49), (I-4) + (1.50), (I-4) + (1.51), (I4) + (1.52), (I-4) + (1.53), (I-4) + (1.54), (I-4) + (1.55), (I-4) + (1.56), (I-4) + (1.57), (I-4) + (1.58), (I4) + (1.59), (I-4) + (1.60), (I-4) + (1.61), (I-4) + (1.62), (I-4) + (1.63), (I-4) + (1.64), (I-4) + (2.1), (I4) + (2.2), (I-4) + (2.3), (I-4) + (2.4), (I-4) + (2.5), (I-4) + (2.6), (I-4) + (2.7), (I-4) + (2.8), (I-4) + (2.9), (I-4) + (2.10), (I-4) + (2.11), (I-4) + (2.12), (I-4) + (2.13), (I-4) + (2.14), (I-4) + (2.15), (I-4) + (2.16), (I4) + (2.17), (I-4) + (2.18), (I-4) + (2.19), (I-4) + (2.20), (I-4) + (2.21), (I-4) + (2.22), (I-4) + (2.23), (I4) + (2.24), (I-4) + (2.25), (I-4) + (2.26), (I-4) + (2.27), (I-4) + (2.28), (I-4) + (2.29), (I-4) + (3.1), (I4) + (3.2), (I-4) + (3.3), (I-4) + (3.4), (I-4) + (3.5), (I-4) + (3.6), (I-4) + (3.7), (I-4) + (3.8), (I-4) + (3.9), (I-4) + (3.10), (I-4) + (3.11), (I-4) + (3.12), (I-4) + (3.13), (I-4) + (3.14), (I-4) + (3.15), (I-4) + (3.16), (I4) + (3.17), (I-4) + (3.18), (I-4) + (3.19), (I-4) + (3.20), (I-4) + (3.21), (I-4) + (3.22), (I-4) + (3.23), (I4) + (3.24), (I-4) + (3.25), (I-4) + (3.26), (I-4) + (3.27), (I-4) + (3.28), (I-4) + (3.29), (I-4) + (3.30), (I4) + (3.31), (I-4) + (3.32), (I-4) + (3.33), (I-4) + (4.1), (I-4) + (4.2), (I-4) + (4.3), (I-4) + (4.4), (I-4) + (4.5), (I-4) + (4.6), (I-4) + (4.7), (I-4) + (4.8), (I-4) + (4.9), (I-4) + (4.10), (I-4) + (4.11), (I-4) + (4.12), (I-4) + (4.13), (I-4) + (4.14), (I-4) + (5.1), (I-4) + (5.2), (I-4) + (5.3), (I-4) + (5.4), (I-4) + (5.5), (I-4) + (5.6), (I-4) + (5.7), (I-4) + (5.8), (I-4) + (5.9), (I-4) + (5.10), (I4) + (5.11), (I-4) + (5.12), (I-4) + (5.13), (I-4) + (5.14), (I-4) + (5.15), (I-4) + (5.16), (I-4) + (5.17), (I4) + (5.18), (I-4) + (5.19), (I-4) + (5.20), (I-4) + (5.21), (I-4) + (5.22), (I-4) + (5.23), (I-4) + (5.24), (I4) + (5.25), (I-4) + (5.26), (I-4) + (5.27), (I-4) + (5.28), (I-4) + (5.29), (I-4) + (5.30), (I-4) + (5.31), (I4) + (5.32), (I-4) + (5.33), (I-4) + (5.34), (I-4) + (6.1), (I-4) + (6.2), (I-4) + (6.3), (I-4) + (6.4), (I-4) + (7.1), (I-4) + (7.2), (I-4) + (7.3), (I-4) + (7.4), (I-4) + (7.5), (I-4) + (7.6), (I-4) + (7.7), (I-4) + (7.8), (I-4) + (8.1), (I-4) + (8.2), (I-4) + (8.3), (I-4) + (8.4), (I-4) + (9.1), (I-4) + (9.2), (I-4) + (9.3), (I-4) + (9.4), (I-4) + (9.5), (I-4) + (9.6), (I-4) + (9.7), (I-4) + (9.8), (I-4) + (9.9), (I-4) + (10.1), (I-4) + (10.2), (I-4) + (10.3), (I-4) + (10.4), (I-4) + (10.5), (I-4) + (10.6), (I-4) + (10.7), (I4) + (10.8), (I-4) + (10.9), (I-4) + (10.10), (I-4) + (10.11), (I-4) + (10.12), (I-4) + (10.13), (I-4) + (10.14), (I-4) + (10.15), (I-4) + (11.1), (I-4) + (11.2), (I-4) + (11.3), (I-4) + (11.4), (I-4) + (11.5), (I-4) + (11.6), (I4) + (11.7), (I-4) + (12.1), (I-4) + (12.2), (I-4) + (12.3), (I-4) + (12.4), (I-4) + (12.5), (I-4) + (12.6), (I4) + (12.7), (I-4) + (12.8), (I-4) + (12.9), (I-4) + (12.10), (I-4) + (12.11), (I-4) + (12.12), (I-4) + (12.13), (I-4) + (13.1), (I-4) + (13.2), (I-4) + (13.3), (I-4) + (13.4), (I-4) + (13.5), (I-4) + (13.6), (I-4) + (13.7), (I4) + (14.1), (I-4) + (14.2), (I-4) + (14.3), (I-4) + (14.4), (I-4) + (14.5), (I-4) + (15.1), (I-4) + (15.2), (I4) + (15.3), (I-4) + (15.4), (I-4) + (15.5), (I-4) + (15.6), (I-4) + (15.7), (I-4) + (15.8), (I-4) + (15.9), (I4) + (15.10), (I-4) + (15.11), (I-4) + (15.12), (I-4) + (15.13), (I-4) + (15.14), (I-4) + (15.15), (I-4) + (15.16), (I-4) + (15.17), (I-4) + (15.18), (I-4) + (15.19), (I-4) +(15.20), (I-4) + (15.21), (I-4) + (15.22), (I-4) + (15.23), (I-4) + (15.24), (I-4) + (15.25), (I-4) + (15.26), (I-4) + (15.27), (I-4) + (15.28), (I-4) + (15.29), (I-4) + (15.30), (I-4) + (15.31), (I-4) + (15.32), (I-4) + (15.33), (I-4) + (15.34), (I-4) + (15.35), (I-4) + (15.36), (I-4) + (15.37), (I-4) + (15.38), (I-4) + (15.39), (I-4) + (15.41), (I-4) + (15.42), (I-4) + (15.43), (I-4) + (15.44), (I-4) + (15.45), (I-4) + (15.46), (I-4) + (15.47), (I-4) + (15.48), (I-4) + (15.49), (I-4) + (15.50), (I-4) + (15.51), (I-4) + (15.52), (I-4) + (15.53), (I-4) + (15.54), (I-4) + (15.55), (I-4) + (15.56), (I-4) + (15.57), (I-4) + (15.58), (I-4) + (15.59), (I-4) + (15.60), (I-4) + (15.61), (I-4) + (15.62), (I-4) + (15.63), (I-4) + (15.64), (I-4) + (15.65), (I-4) + (15.66), (I-4) + (15.67), (I-4) + (15.68), (I-4) + (15.69), (I-4) + (15.70), (I-4) + (15.71), (I-4) + (15.72), (I-4) + (15.73), (I-4) + (15.74), (I-4) + (15.75), (I-4) + (15.76), (I-4) + (15.77), (I-4) + (15.78), (I-4) + (15.79), (I-4) + (15.80), (I-4) + (15.81), (I-4) + (15.82), (I-4) + (15.83), (I-4) + (15.84), (I-4) + (15.85), (I-4) + (15.86), (I-4) + (15.87), (I-4) + (15.88), (I-4) + (15.89), (I-4) + (15.90), (I-4) + (15.91), (I-4) + (15.92), (I-4) + (15.93), (I-4) + (15.94).[025] According to a preferred variant, the present invention is directed to mixtures comprising the compound (I-4), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures ( I-4) + (1.1), (I-4) + (1.2), (I-4) + (1.3), (I-4) + (1.4), (I-4) + (1.5), ( I-4) + (1.6), (I-4) + (1.7), (I-4) + (1.8), (I-4) + (1.9), (I-4) + (1.10), ( I-4) + (1.11), (I-4) + (1.12), (I-4) + (1.13), (I-4) + (1.14), (I-4) + (1.15), ( I-4) + (1.16), (I4) + (1.17), (I-4) + (1.18), (I-4) + (1.19), (I-4) + (1.20), (I- 4) + (1.21), (I-4) + (1.22), (I-4) + (1.23), (I4) + (1.24), (I-4) + (1.25), (I-4) + (1.26), (I-4) + (1.27), (I-4) + (1.28), (I-4) + (1.29), (I-4) + (1.30), (I4) + ( 1.31), (I-4) + (1.32), (I-4) + (1.33), (I-4) + (1.34), (I-4) + (1.35), (I-4) + ( 1.36), (I-4) + (1.37), (I4) + (1.38), (I-4) + (1.39), (I-4) + (1.40), (I-4) + (1.41) , (I-4) + (1.42), (I-4) + (1.43), (I-4) + (1.44), (I4) + (1.45), (I-4) + (1.46), ( I-4) + (1.47), (I-4) + (1.48), (I-4) + (1.49), (I-4) + (1.50), (I-4) + (1.51), (I4) + (1.52), (I-4) + (1.53), (I-4) + (1.54), (I-4) + (1.55), (I -4) + (1.56), (I-4) + (1.57), (I-4) + (1.58), (I4) + (1.59), (I-4) + (1.60), (I-4 ) + (1.61), (I-4) + (1.62), (I-4) + (1.63), (I-4) + (1.64), (I-4) + (2.1), (I4) + (2.2), (I-4) + (2.3), (I-4) + (2.4), (I-4) + (2.5), (I-4) + (2.6), (I-4) + (2.7), (I-4) + (2.8), (I-4) + (2.9), (I-4) + (2.10), (I-4) + (2.11), (I-4) + (2.12), (I-4) + (2.13), (I-4) + (2.14), (I-4) + (2.15), (I-4) + (2.16), (I4) + (2.17 ), (I-4) + (2.18), (I-4) + (2.19), (I-4) + (2.20), (I-4) + (2.21), (I-4) + (2.22 ), (I-4) + (2.23), (I4) + (2.24), (I-4) + (2.25), (I-4) + (2.26), (I-4) + (2.27), (I-4) + (2.28), (I-4) + (2.29), (I-4) + (3.1), (I4) + (3.2), (I-4) + (3.3), (I -4) + (3.4), (I-4) + (3.5), (I-4) + (3.6), (I-4) + (3.7), (I-4) + (3.8), (I -4) + (3.9), (I-4) + (3.10), (I-4) + (3.11), (I-4) + (3.12), (I-4) + (3.13), (I -4) + (3.14), (I-4) + (3.15), (I-4) + (3.16), (I4) + (3.17), (I-4) + (3.18), (I-4 ) + (3.19), (I-4) + (3.20), (I-4) + (3.21), ( I-4) + (3.22), (I-4) + (3.23), (I4) + (3.24), (I-4) + (3.25), (I-4) + (3.26), (I- 4) + (3.27), (I-4) + (3.28), (I-4) + (3.29), (I-4) + (3.30), (I4) + (3.31), (I-4) + (3.32), (I-4) + (3.33), (I-4) + (4.1), (I-4) + (4.2), (I-4) + (4.3), (I-4) + (4.4), (I-4) + (4.5), (I-4) + (4.6), (I-4) + (4.7), (I-4) + (4.8), (I-4) + (4.9), (I-4) + (4.10), (I-4) + (4.11), (I-4) + (4.12), (I-4) + (4.13), (I-4) + (4.14), (I-4) + (5.1), (I-4) + (5.2), (I-4) + (5.3), (I-4) + (5.4), (I-4) + (5.5), (I-4) + (5.6), (I-4) + (5.7), (I-4) + (5.8), (I-4) + (5.9), (I-4) + (5.10), (I4) + (5.11), (I-4) + (5.12), (I-4) + (5.13), (I-4) + (5.14), (I-4) + ( 5.15), (I-4) + (5.16), (I-4) + (5.17), (I4) + (5.18), (I-4) + (5.19), (I-4) + (5.20) , (I-4) + (5.21), (I-4) + (5.22), (I-4) + (5.23), (I-4) + (5.24), (I4) + (5.25), ( I-4) + (5.26), (I-4) + (5.27), (I-4) + (5.28), (I-4) + (5.29), (I-4) + (5.30), ( I-4) + (5.31), (I4) + (5.32), (I-4) + (5.33), (I-4) + (5.34), (I-4) + (6.1), (I- 4) + (6.2), (I-4) + (6.3), (I-4) + (6.4), (I-4) + (7.1), (I-4) + (7.2), (I-4) + (7.3), (I-4) + (7.4), (I-4) + (7.5), (I-4) + (7.6), (I-4) + (7.7), (I-4) + (7.8), (I-4) + (8.1), (I-4) + (8.2), (I-4) + (8.3), (I-4) + (8.4), (I-4) + (9.1), (I-4) + (9.2), (I-4) + (9.3), (I-4) + (9.4), (I-4) + (9.5), (I-4) + (9.6), (I-4) + (9.7), (I-4) + (9.8), (I-4) + (9.9), (I-4) + (10.1), (I-4) + (10.2), (I-4) + (10.3), (I-4) + (10.4), (I-4) + (10.5), (I-4) + (10.6), (I-4) + (10.7), (I4) + (10.8), (I-4) + (10.9), (I-4) + ( 10.10), (I-4) + (10.11), (I-4) + (10.12), (I-4) + (10.13), (I-4) + (10.14), (I-4) + ( 10.15), (I-4) + (11.1), (I-4) + (11.2), (I-4) + (11.3), (I-4) + (11.4), (I-4) + ( 11.5), (I-4) + (11.6), (I4) + (11.7), (I-4) + (12.1), (I-4) + (12.2), (I-4) + (12.3) , (I-4) + (12.4), (I-4) + (12.5), (I-4) + (12.6), (I4) + (12.7), (I-4) + (12.8), ( I-4) + (12.9), (I-4) + (12.10), (I-4) + (12.11), (I-4) + (12.12), (I-4) + (12.13), ( I-4) + (13.1), (I-4) + (13.2), (I-4) + (13.3), (I-4) + (13.4), (I-4) + (13.5), ( I-4) + (13.6), (I-4) + (13.7), (I4) + (14. 1), (I-4) + (14.2), (I-4) + (14.3), (I-4) + (14.4), (I-4) + (14.5), (I-4) + ( 15.1), (I-4) + (15.2), (I4) + (15.3), (I-4) + (15.4), (I-4) + (15.5), (I-4) + (15.6) , (I-4) + (15.7), (I-4) + (15.8), (I-4) + (15.9), (I4) + (15.10), (I-4) + (15.11), ( I-4) + (15.12), (I-4) + (15.13), (I-4) + (15.14), (I-4) + (15.15), (I-4) + (15.16), ( I-4) + (15.17), (I-4) + (15.18), (I-4) + (15.19), (I-4) + (15.20), (I-4) + (15.21), ( I-4) + (15.22), (I-4) + (15.23), (I-4) + (15.24), (I-4) + (15.25), (I-4) + (15.26), ( I-4) + (15.27), (I-4) + (15.28), (I-4) + (15.29), (I-4) + (15.30), (I-4) + (15.31), ( I-4) + (15.32), (I-4) + (15.33), (I-4) + (15.34), (I-4) + (15.35), (I-4) + (15.36), ( I-4) + (15.37), (I-4) + (15.38), (I-4) + (15.39), (I-4) + (15.41), (I-4) + (15.42), ( I-4) + (15.43), (I-4) + (15.44), (I-4) + (15.45), (I-4) + (15.46), (I-4) + (15.47), ( I-4) + (15.48), (I-4) + (15.49), (I-4) + (15.50), (I-4) + (15.51), (I-4) + (15.52), ( I-4) + (15.53), (I-4) + (15.54), (I-4) + (15.55), (I-4) + (15.56), (I-4) + ( 15.57), (I-4) + (15.58), (I-4) + (15.59), (I-4) + (15.60), (I-4) + (15.61), (I-4) + ( 15.62), (I-4) + (15.63), (I-4) + (15.64), (I-4) + (15.65), (I-4) + (15.66), (I-4) + ( 15.67), (I-4) + (15.68), (I-4) + (15.69), (I-4) + (15.70), (I-4) + (15.71), (I-4) + ( 15.72), (I-4) + (15.73), (I-4) + (15.74), (I-4) + (15.75), (I-4) + (15.76), (I-4) + ( 15.77), (I-4) + (15.78), (I-4) + (15.79), (I-4) + (15.80), (I-4) + (15.81), (I-4) + ( 15.82), (I-4) + (15.83), (I-4) + (15.84), (I-4) + (15.85), (I-4) + (15.86), (I-4) + ( 15.87), (I-4) + (15.88), (I-4) + (15.89), (I-4) + (15.90), (I-4) + (15.91), (I-4) + ( 15.92), (I-4) + (15.93), (I-4) + (15.94).

[026] De acordo com uma outra variante particularmente preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-4), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-4) + (2.1), (I-4) + (2.2), (I-4) + (2.6), (I-4) + (2.8), (I-4) + (2.11), (I-4) + (2.12), (I-4) + (2.13), (I-4) + (2.14), (I-4) + (2.15), (I-4) + (2.16), (I-4) + (2.17), (I-4) + (2.29), (I-4) + (3.1), (I-4) + (3.2), (I-4) + (3.3), (I-4) + (3.4), (I-4) + (3.9), (I-4) + (3.10), (I4) + (3.12), (I-4) + (3.16), (I-4) + (3.17), (I-4) + (3.22), (I-4) + (4.6), (I-4) + (5.1), (I-4) + (5.4), (I-4) + (5.5), (I-4) + (5.7), (I-4) + (5.8), (I-4) + (5.9), (I-4) + (5.16), (I-4) + (5.23), (I-4) + (5.25), (I-4) + (5.26), (I-4) + (5.29), (I-4) + (5.30), (I-4) + (7.7), (I-4) + (9.2), (I-4) + (9.4), (I-4) + (9.5), (I-4) + (10.9), (I-4) + (10.10), (I-4) + (12.9), (I-4) + (12.10), (I-4) + (14.4), (I-4) + (15.9), (I-4) + (15.24), (I-4) + (15.25), (I-4) + (15.26), (I-4) + (15.41), (I-4) + (15.42), (I-4) + (15.54), (I-4) + (15.55), (I-4) + (15.56), (I-4) + (15.60), (I-4) + (15.90).[026] According to another particularly preferred variant, the present invention is directed to mixtures comprising the compound (I-4), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures (I-4) + (2.1), (I-4) + (2.2), (I-4) + (2.6), (I-4) + (2.8), (I-4) + (2.11) , (I-4) + (2.12), (I-4) + (2.13), (I-4) + (2.14), (I-4) + (2.15), (I-4) + (2.16) , (I-4) + (2.17), (I-4) + (2.29), (I-4) + (3.1), (I-4) + (3.2), (I-4) + (3.3) , (I-4) + (3.4), (I-4) + (3.9), (I-4) + (3.10), (I4) + (3.12), (I-4) + (3.16), ( I-4) + (3.17), (I-4) + (3.22), (I-4) + (4.6), (I-4) + (5.1), (I-4) + (5.4), ( I-4) + (5.5), (I-4) + (5.7), (I-4) + (5.8), (I-4) + (5.9), (I-4) + (5.16), ( I-4) + (5.23), (I-4) + (5.25), (I-4) + (5.26), (I-4) + (5.29), (I-4) + (5.30), ( I-4) + (7.7), (I-4) + (9.2), (I-4) + (9.4), (I-4) + (9.5), (I-4) + (10.9), ( I-4) + (10.10), (I-4) + (12.9), (I-4) + (12.10), (I-4) + (14.4), (I-4) + (15.9), ( I-4) + (15.24), (I-4) + (15.25), (I-4) + (15.26), (I-4) + (15 .41), (I-4) + (15.42), (I-4) + (15.54), (I-4) + (15.55), (I-4) + (15.56), (I-4) + (15.60), (I-4) + (15.90).

[027] De acordo com uma variante preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-5), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-5) + (1.1), (I-5) + (1.2), (I-5) + (1.3), (I-5) + (1.4), (I-5) + (1.5), (I-5) + (1.6), (I-5) + (1.7), (I-5) + (1.8), (I-5) + (1.9), (I-5) + (1.10), (I-5) + (1.11), (I-5) + (1.12), (I-5) + (1.13), (I-5) + (1.14), (I-5) + (1.15), (I-5) + (1.16), (I5) + (1.17), (I-5) + (1.18), (I-5) + (1.19), (I-5) + (1.20), (I-5) + (1.21), (I-5) + (1.22), (I-5) + (1.23), (I5) + (1.24), (I-5) + (1.25), (I-5) + (1.26), (I-5) + (1.27), (I-5) + (1.28), (I-5) + (1.29), (I-5) + (1.30), (I5) + (1.31), (I-5) + (1.32), (I-5) + (1.33), (I-5) + (1.34), (I-5) + (1.35), (I-5) + (1.36), (I-5) + (1.37), (I5) + (1.38), (I-5) + (1.39), (I-5) + (1.40), (I-5) + (1.41), (I-5) + (1.42), (I-5) + (1.43), (I-5) + (1.44), (I5) + (1.45), (I-5) + (1.46), (I-5) + (1.47), (I-5) + (1.48), (I-5) + (1.49), (I-5) + (1.50), (I-5) + (1.51), (I5) + (1.52), (I-5) + (1.53), (I-5) + (1.54), (I-5) +(1.55), (I-5) + (1.56), (I-5) + (1.57), (I-5) + (1.58), (I5) + (1.59), (I-5) + (1.60), (I-5) + (1.61), (I-5) + (1.62), (I-5) + (1.63), (I-5) + (1.64), (I-5) + (2.1), (I5) + (2.2), (I-5) + (2.3), (I-5) + (2.4), (I-5) + (2.5), (I-5) + (2.6), (I-5) + (2.7), (I-5) + (2.8), (I-5) + (2.9), (I-5) + (2.10), (I-5) + (2.11), (I-5) + (2.12), (I-5) + (2.13), (I-5) + (2.14), (I-5) + (2.15), (I-5) + (2.16), (I5) + (2.17), (I-5) + (2.18), (I-5) + (2.19), (I-5) + (2.20), (I-5) + (2.21), (I-5) + (2.22), (I-5) + (2.23), (I5) + (2.24), (I-5) + (2.25), (I-5) + (2.26), (I-5) + (2.27), (I-5) + (2.28), (I-5) + (2.29), (I-5) + (3.1), (I5) + (3.2), (I-5) + (3.3), (I-5) + (3.4), (I-5) + (3.5), (I-5) + (3.6), (I-5) + (3.7), (I-5) + (3.8), (I-5) + (3.9), (I-5) + (3.10), (I-5) + (3.11), (I-5) + (3.12), (I-5) + (3.13), (I-5) + (3.14), (I-5) + (3.15), (I-5) + (3.16), (I5) + (3.17), (I-5) + (3.18), (I-5) + (3.19), (I-5) + (3.20), (I-5) + (3.21), (I-5) + (3.22), (I-5) + (3.23), (I5) + (3.24), (I-5) + (3.25), (I-5) + (3.26), (I-5) + (3.27), (I-5) + (3.28), (I-5) + (3.29), (I-5) + (3.30), (I5) + (3.31), (I-5) + (3.32), (I-5) + (3.33), (I-5) + (4.1), (I-5) + (4.2), (I-5) + (4.3), (I-5) + (4.4), (I-5) + (4.5), (I-5) + (4.6), (I-5) + (4.7), (I-5) + (4.8), (I-5) + (4.9), (I-5) + (4.10), (I-5) + (4.11), (I-5) + (4.12), (I-5) + (4.13), (I-5) + (4.14), (I-5) + (5.1), (I-5) + (5.2), (I-5) + (5.3), (I-5) + (5.4), (I-5) + (5.5), (I-5) + (5.6), (I-5) + (5.7), (I-5) + (5.8), (I-5) + (5.9), (I-5) + (5.10), (I5) + (5.11), (I-5) + (5.12), (I-5) + (5.13), (I-5) + (5.14), (I-5) + (5.15), (I-5) + (5.16), (I-5) + (5.17), (I5) + (5.18), (I-5) + (5.19), (I-5) + (5.20), (I-5) + (5.21), (I-5) + (5.22), (I-5) + (5.23), (I-5) + (5.24), (I5) + (5.25), (I-5) + (5.26), (I-5) + (5.27), (I-5) + (5.28), (I-5) + (5.29), (I-5) + (5.30), (I-5) + (5.31), (I5) + (5.32), (I-5) + (5.33), (I-5) + (5.34), (I-5) + (6.1), (I-5) + (6.2), (I-5) + (6.3), (I-5) + (6.4), (I-5) + (7.1), (I-5) + (7.2), (I-5) + (7.3), (I-5) + (7.4), (I-5) + (7.5), (I-5) + (7.6), (I-5) + (7.7), (I-5) + (7.8), (I-5) + (8.1), (I-5) + (8.2), (I-5) + (8.3), (I-5) + (8.4), (I-5) + (9.1), (I-5) + (9.2), (I-5) + (9.3), (I-5) + (9.4), (I-5) + (9.5), (I-5) + (9.6), (I-5) + (9.7), (I-5) + (9.8), (I-5) + (9.9), (I-5) + (10.1), (I-5) + (10.2), (I-5) + (10.3), (I-5) + (10.4), (I-5) + (10.5), (I-5) + (10.6), (I-5) + (10.7), (I5) + (10.8), (I-5) + (10.9), (I-5) + (10.10), (I-5) + (10.11), (I-5) + (10.12), (I-5) + (10.13), (I-5) + (10.14), (I-5) + (10.15), (I-5) + (11.1), (I-5) + (11.2), (I-5) + (11.3), (I-5) + (11.4), (I-5) + (11.5), (I-5) + (11.6), (I5) + (11.7), (I-5) + (12.1), (I-5) + (12.2), (I-5) + (12.3), (I-5) + (12.4), (I-5) + (12.5), (I-5) + (12.6), (I5) + (12.7), (I-5) + (12.8), (I-5) + (12.9), (I-5) + (12.10), (I-5) + (12.11), (I-5) + (12.12), (I-5) + (12.13), (I-5) + (13.1), (I-5) + (13.2), (I-5) + (13.3), (I-5) + (13.4), (I-5) + (13.5), (I-5) + (13.6), (I-5) + (13.7), (I5) + (14.1), (I-5) + (14.2), (I-5) + (14.3), (I-5) + (14.4), (I-5) + (14.5), (I-5) + (15.1), (I-5) + (15.2), (I5) + (15.3), (I-5) + (15.4), (I-5) + (15.5), (I-5) + (15.6), (I-5) + (15.7), (I-5) + (15.8), (I-5) + (15.9), (I5) + (15.10), (I-5) + (15.11), (I-5) + (15.12), (I-5) + (15.13), (I-5) + (15.14), (I-5) + (15.15), (I-5) + (15.16), (I-5) + (15.17), (I-5) + (15.18), (I-5) + (15.19), (I-5) + (15.20), (I-5) + (15.21), (I-5) + (15.22), (I-5) + (15.23), (I-5) + (15.24), (I-5) + (15.25), (I-5) + (15.26), (I-5) +(15.27), (I-5) + (15.28), (I-5) + (15.29), (I-5) + (15.30), (I-5) + (15.31), (I-5) + (15.32), (I-5) + (15.33), (I-5) + (15.34), (I-5) + (15.35), (I-5) + (15.36), (I-5) + (15.37), (I-5) + (15.38), (I-5) + (15.39), (I-5) + (15.41), (I-5) + (15.42), (I-5) + (15.43), (I-5) + (15.44), (I-5) + (15.45), (I-5) + (15.46), (I-5) + (15.47), (I-5) + (15.48), (I-5) + (15.49), (I-5) + (15.50), (I-5) + (15.51), (I-5) + (15.52), (I-5) + (15.53), (I-5) + (15.54), (I-5) + (15.55), (I-5) + (15.56), (I-5) + (15.57), (I-5) + (15.58), (I-5) + (15.59), (I-5) + (15.60), (I-5) + (15.61), (I-5) + (15.62), (I-5) + (15.63), (I-5) + (15.64), (I-5) + (15.65), (I-5) + (15.66), (I-5) + (15.67), (I-5) + (15.68), (I-5) + (15.69), (I-5) + (15.70), (I-5) + (15.71), (I-5) + (15.72), (I-5) + (15.73), (I-5) + (15.74), (I-5) + (15.75), (I-5) + (15.76), (I-5) + (15.77), (I-5) + (15.78), (I-5) + (15.79), (I-5) + (15.80), (I-5) + (15.81), (I-5) + (15.82), (I-5) + (15.83), (I-5) + (15.84), (I-5) + (15.85), (I-5) + (15.86), (I-5) + (15.87), (I-5) + (15.88), (I-5) + (15.89), (I-5) + (15.90), (I-5) + (15.91), (I-5) + (15.92), (I-5) + (15.93), (I-5) + (15.94).[027] According to a preferred variant, the present invention is directed to mixtures comprising the compound (I-5), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures ( I-5) + (1.1), (I-5) + (1.2), (I-5) + (1.3), (I-5) + (1.4), (I-5) + (1.5), ( I-5) + (1.6), (I-5) + (1.7), (I-5) + (1.8), (I-5) + (1.9), (I-5) + (1.10), ( I-5) + (1.11), (I-5) + (1.12), (I-5) + (1.13), (I-5) + (1.14), (I-5) + (1.15), ( I-5) + (1.16), (I5) + (1.17), (I-5) + (1.18), (I-5) + (1.19), (I-5) + (1.20), (I- 5) + (1.21), (I-5) + (1.22), (I-5) + (1.23), (I5) + (1.24), (I-5) + (1.25), (I-5) + (1.26), (I-5) + (1.27), (I-5) + (1.28), (I-5) + (1.29), (I-5) + (1.30), (I5) + ( 1.31), (I-5) + (1.32), (I-5) + (1.33), (I-5) + (1.34), (I-5) + (1.35), (I-5) + ( 1.36), (I-5) + (1.37), (I5) + (1.38), (I-5) + (1.39), (I-5) + (1.40), (I-5) + (1.41) , (I-5) + (1.42), (I-5) + (1.43), (I-5) + (1.44), (I5) + (1.45), (I-5) + (1.46), ( I-5) + (1.47), (I-5) + (1.48), (I-5) + (1.49), (I-5) + (1.50), (I-5) + (1.51), (I5) + (1.52), (I-5) + (1.53), (I-5) + (1.54), (I-5) + (1.55), (I -5) + (1.56), (I-5) + (1.57), (I-5) + (1.58), (I5) + (1.59), (I-5) + (1.60), (I-5 ) + (1.61), (I-5) + (1.62), (I-5) + (1.63), (I-5) + (1.64), (I-5) + (2.1), (I5) + (2.2), (I-5) + (2.3), (I-5) + (2.4), (I-5) + (2.5), (I-5) + (2.6), (I-5) + (2.7), (I-5) + (2.8), (I-5) + (2.9), (I-5) + (2.10), (I-5) + (2.11), (I-5) + (2.12), (I-5) + (2.13), (I-5) + (2.14), (I-5) + (2.15), (I-5) + (2.16), (I5) + (2.17 ), (I-5) + (2.18), (I-5) + (2.19), (I-5) + (2.20), (I-5) + (2.21), (I-5) + (2.22 ), (I-5) + (2.23), (I5) + (2.24), (I-5) + (2.25), (I-5) + (2.26), (I-5) + (2.27), (I-5) + (2.28), (I-5) + (2.29), (I-5) + (3.1), (I5) + (3.2), (I-5) + (3.3), (I -5) + (3.4), (I-5) + (3.5), (I-5) + (3.6), (I-5) + (3.7), (I-5) + (3.8), (I -5) + (3.9), (I-5) + (3.10), (I-5) + (3.11), (I-5) + (3.12), (I-5) + (3.13), (I -5) + (3.14), (I-5) + (3.15), (I-5) + (3.16), (I5) + (3.17), (I-5) + (3.18), (I-5 ) + (3.19), (I-5) + (3.20), (I-5) + (3.21), ( I-5) + (3.22), (I-5) + (3.23), (I5) + (3.24), (I-5) + (3.25), (I-5) + (3.26), (I- 5) + (3.27), (I-5) + (3.28), (I-5) + (3.29), (I-5) + (3.30), (I5) + (3.31), (I-5) + (3.32), (I-5) + (3.33), (I-5) + (4.1), (I-5) + (4.2), (I-5) + (4.3), (I-5) + (4.4), (I-5) + (4.5), (I-5) + (4.6), (I-5) + (4.7), (I-5) + (4.8), (I-5) + (4.9), (I-5) + (4.10), (I-5) + (4.11), (I-5) + (4.12), (I-5) + (4.13), (I-5) + (4.14), (I-5) + (5.1), (I-5) + (5.2), (I-5) + (5.3), (I-5) + (5.4), (I-5) + (5.5), (I-5) + (5.6), (I-5) + (5.7), (I-5) + (5.8), (I-5) + (5.9), (I-5) + (5.10), (I5) + (5.11), (I-5) + (5.12), (I-5) + (5.13), (I-5) + (5.14), (I-5) + ( 5.15), (I-5) + (5.16), (I-5) + (5.17), (I5) + (5.18), (I-5) + (5.19), (I-5) + (5.20) , (I-5) + (5.21), (I-5) + (5.22), (I-5) + (5.23), (I-5) + (5.24), (I5) + (5.25), ( I-5) + (5.26), (I-5) + (5.27), (I-5) + (5.28), (I-5) + (5.29), (I-5) + (5.30), ( I-5) + (5.31), (I5) + (5.32), (I-5) + (5.33), (I-5) + (5.34), (I-5) + (6.1), (I- 5) + (6.2), (I-5) + (6.3), (I-5) + (6.4), (I-5) + (7.1), (I-5) + (7.2), (I-5) + (7.3), (I-5) + (7.4), (I-5) + (7.5), (I-5) + (7.6), (I-5) + (7.7), (I-5) + (7.8), (I-5) + (8.1), (I-5) + (8.2), (I-5) + (8.3), (I-5) + (8.4), (I-5) + (9.1), (I-5) + (9.2), (I-5) + (9.3), (I-5) + (9.4), (I-5) + (9.5), (I-5) + (9.6), (I-5) + (9.7), (I-5) + (9.8), (I-5) + (9.9), (I-5) + (10.1), (I-5) + (10.2), (I-5) + (10.3), (I-5) + (10.4), (I-5) + (10.5), (I-5) + (10.6), (I-5) + (10.7), (I5) + (10.8), (I-5) + (10.9), (I-5) + ( 10.10), (I-5) + (10.11), (I-5) + (10.12), (I-5) + (10.13), (I-5) + (10.14), (I-5) + ( 10.15), (I-5) + (11.1), (I-5) + (11.2), (I-5) + (11.3), (I-5) + (11.4), (I-5) + ( 11.5), (I-5) + (11.6), (I5) + (11.7), (I-5) + (12.1), (I-5) + (12.2), (I-5) + (12.3) , (I-5) + (12.4), (I-5) + (12.5), (I-5) + (12.6), (I5) + (12.7), (I-5) + (12.8), ( I-5) + (12.9), (I-5) + (12.10), (I-5) + (12.11), (I-5) + (12.12), (I-5) + (12.13), ( I-5) + (13.1), (I-5) + (13.2), (I-5) + (13.3), (I-5) + (13.4), (I-5) + (13.5), ( I-5) + (13.6), (I-5) + (13.7), (I5) + (14. 1), (I-5) + (14.2), (I-5) + (14.3), (I-5) + (14.4), (I-5) + (14.5), (I-5) + ( 15.1), (I-5) + (15.2), (I5) + (15.3), (I-5) + (15.4), (I-5) + (15.5), (I-5) + (15.6) , (I-5) + (15.7), (I-5) + (15.8), (I-5) + (15.9), (I5) + (15.10), (I-5) + (15.11), ( I-5) + (15.12), (I-5) + (15.13), (I-5) + (15.14), (I-5) + (15.15), (I-5) + (15.16), ( I-5) + (15.17), (I-5) + (15.18), (I-5) + (15.19), (I-5) + (15.20), (I-5) + (15.21), ( I-5) + (15.22), (I-5) + (15.23), (I-5) + (15.24), (I-5) + (15.25), (I-5) + (15.26), ( I-5) + (15.27), (I-5) + (15.28), (I-5) + (15.29), (I-5) + (15.30), (I-5) + (15.31), ( I-5) + (15.32), (I-5) + (15.33), (I-5) + (15.34), (I-5) + (15.35), (I-5) + (15.36), ( I-5) + (15.37), (I-5) + (15.38), (I-5) + (15.39), (I-5) + (15.41), (I-5) + (15.42), ( I-5) + (15.43), (I-5) + (15.44), (I-5) + (15.45), (I-5) + (15.46), (I-5) + (15.47), ( I-5) + (15.48), (I-5) + (15.49), (I-5) + (15.50), (I-5) + (15.51), (I-5) + (15.52), ( I-5) + (15.53), (I-5) + (15.54), (I-5) + (15.55), (I-5) + (15.56), (I-5) + ( 15.57), (I-5) + (15.58), (I-5) + (15.59), (I-5) + (15.60), (I-5) + (15.61), (I-5) + ( 15.62), (I-5) + (15.63), (I-5) + (15.64), (I-5) + (15.65), (I-5) + (15.66), (I-5) + ( 15.67), (I-5) + (15.68), (I-5) + (15.69), (I-5) + (15.70), (I-5) + (15.71), (I-5) + ( 15.72), (I-5) + (15.73), (I-5) + (15.74), (I-5) + (15.75), (I-5) + (15.76), (I-5) + ( 15.77), (I-5) + (15.78), (I-5) + (15.79), (I-5) + (15.80), (I-5) + (15.81), (I-5) + ( 15.82), (I-5) + (15.83), (I-5) + (15.84), (I-5) + (15.85), (I-5) + (15.86), (I-5) + ( 15.87), (I-5) + (15.88), (I-5) + (15.89), (I-5) + (15.90), (I-5) + (15.91), (I-5) + ( 15.92), (I-5) + (15.93), (I-5) + (15.94).

[028] De acordo com uma outra variante particularmente preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-5), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-5) + (2.1), (I-5) + (2.2), (I-5) + (2.6), (I-5) + (2.8), (I-5) + (2.11), (I-5) + (2.12), (I-5) + (2.13), (I-5) + (2.14), (I-5) + (2.15), (I-5) + (2.16), (I-5) + (2.17), (I-5) + (2.29), (I-5) + (3.1), (I-5) + (3.2), (I-5) + (3.3), (I-5) + (3.4), (I-5) + (3.9), (I-5) + (3.10), (I5) + (3.12), (I-5) + (3.16), (I-5) + (3.17), (I-5) + (3.22), (I-5) + (4.6), (I-5) + (5.1), (I-5) + (5.4), (I-5) + (5.5), (I-5) + (5.7), (I-5) + (5.8), (I-5) + (5.9), (I-5) + (5.16), (I-5) + (5.23), (I-5) + (5.25), (I-5) + (5.26), (I-5) + (5.29), (I-5) + (5.30), (I-5) + (7.7), (I-5) + (9.2), (I-5) + (9.4), (I-5) + (9.5), (I-5) + (10.9), (I-5) + (10.10), (I-5) + (12.9), (I-5) + (12.10), (I-5) + (14.4), (I-5) + (15.9), (I-5) + (15.24), (I-5) + (15.25), (I-5) + (15.26), (I-5) + (15.41), (I-5) + (15.42), (I-5) + (15.54), (I-5) + (15.55), (I-5) + (15.56), (I-5) + (15.60), (I-5) + (15.90).[028] According to another particularly preferred variant, the present invention is directed to mixtures comprising the compound (I-5), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures (I-5) + (2.1), (I-5) + (2.2), (I-5) + (2.6), (I-5) + (2.8), (I-5) + (2.11) , (I-5) + (2.12), (I-5) + (2.13), (I-5) + (2.14), (I-5) + (2.15), (I-5) + (2.16) , (I-5) + (2.17), (I-5) + (2.29), (I-5) + (3.1), (I-5) + (3.2), (I-5) + (3.3) , (I-5) + (3.4), (I-5) + (3.9), (I-5) + (3.10), (I5) + (3.12), (I-5) + (3.16), ( I-5) + (3.17), (I-5) + (3.22), (I-5) + (4.6), (I-5) + (5.1), (I-5) + (5.4), ( I-5) + (5.5), (I-5) + (5.7), (I-5) + (5.8), (I-5) + (5.9), (I-5) + (5.16), ( I-5) + (5.23), (I-5) + (5.25), (I-5) + (5.26), (I-5) + (5.29), (I-5) + (5.30), ( I-5) + (7.7), (I-5) + (9.2), (I-5) + (9.4), (I-5) + (9.5), (I-5) + (10.9), ( I-5) + (10.10), (I-5) + (12.9), (I-5) + (12.10), (I-5) + (14.4), (I-5) + (15.9), ( I-5) + (15.24), (I-5) + (15.25), (I-5) + (15.26), (I-5) + (15 .41), (I-5) + (15.42), (I-5) + (15.54), (I-5) + (15.55), (I-5) + (15.56), (I-5) + (15.60), (I-5) + (15.90).

[029] De acordo com uma variante preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-6), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-6) + (1.1), (I-6) + (1.2), (I-6) + (1.3), (I-6) + (1.4), (I-6) + (1.5), (I-6) + (1.6), (I-6) + (1.7), (I-6) + (1.8), (I-6) + (1.9), (I-6) + (1.10), (I-6) + (1.11), (I-6) + (1.12), (I-6) + (1.13), (I-6) + (1.14), (I-6) + (1.15), (I-6) + (1.16), (I6) + (1.17), (I-6) + (1.18), (I-6) + (1.19), (I-6) + (1.20), (I-6) + (1.21), (I-6) + (1.22), (I-6) + (1.23), (I6) + (1.24), (I-6) + (1.25), (I-6) + (1.26), (I-6) + (1.27), (I-6) + (1.28), (I-6) + (1.29), (I-6) + (1.30), (I6) + (1.31), (I-6) + (1.32), (I-6) + (1.33), (I-6) + (1.34), (I-6) + (1.35), (I-6) + (1.36), (I-6) + (1.37), (I6) + (1.38), (I-6) + (1.39), (I-6) + (1.40), (I-6) + (1.41), (I-6) + (1.42), (I-6) + (1.43), (I-6) + (1.44), (I6) + (1.45), (I-6) + (1.46), (I-6) + (1.47), (I-6) + (1.48), (I-6) + (1.49), (I-6) + (1.50), (I-6) + (1.51), (I6) + (1.52), (I-6) + (1.53), (I-6) + (1.54), (I-6) + (1.55), (I-6) + (1.56), (I-6) + (1.57), (I-6) + (1.58), (I6) + (1.59), (I-6) + (1.60), (I-6) + (1.61), (I-6) +(1.62), (I-6) + (1.63), (I-6) + (1.64), (I-6) + (2.1), (I6) + (2.2), (I-6) + (2.3), (I-6) + (2.4), (I-6) + (2.5), (I-6) + (2.6), (I-6) + (2.7), (I-6) + (2.8), (I-6) + (2.9), (I-6) + (2.10), (I-6) + (2.11), (I-6) + (2.12), (I-6) + (2.13), (I-6) + (2.14), (I-6) + (2.15), (I-6) + (2.16), (I6) + (2.17), (I-6) + (2.18), (I-6) + (2.19), (I-6) + (2.20), (I-6) + (2.21), (I-6) + (2.22), (I-6) + (2.23), (I6) + (2.24), (I-6) + (2.25), (I-6) + (2.26), (I-6) + (2.27), (I-6) + (2.28), (I-6) + (2.29), (I-6) + (3.1), (I6) + (3.2), (I-6) + (3.3), (I-6) + (3.4), (I-6) + (3.5), (I-6) + (3.6), (I-6) + (3.7), (I-6) + (3.8), (I-6) + (3.9), (I-6) + (3.10), (I-6) + (3.11), (I-6) + (3.12), (I-6) + (3.13), (I-6) + (3.14), (I-6) + (3.15), (I-6) + (3.16), (I6) + (3.17), (I-6) + (3.18), (I-6) + (3.19), (I-6) + (3.20), (I-6) + (3.21), (I-6) + (3.22), (I-6) + (3.23), (I6) + (3.24), (I-6) + (3.25), (I-6) + (3.26), (I-6) + (3.27), (I-6) + (3.28), (I-6) + (3.29), (I-6) + (3.30), (I6) + (3.31), (I-6) + (3.32), (I-6) + (3.33), (I-6) + (4.1), (I-6) + (4.2), (I-6) + (4.3), (I-6) + (4.4), (I-6) + (4.5), (I-6) + (4.6), (I-6) + (4.7), (I-6) + (4.8), (I-6) + (4.9), (I-6) + (4.10), (I-6) + (4.11), (I-6) + (4.12), (I-6) + (4.13), (I-6) + (4.14), (I-6) + (5.1), (I-6) + (5.2), (I-6) + (5.3), (I-6) + (5.4), (I-6) + (5.5), (I-6) + (5.6), (I-6) + (5.7), (I-6) + (5.8), (I-6) + (5.9), (I-6) + (5.10), (I6) + (5.11), (I-6) + (5.12), (I-6) + (5.13), (I-6) + (5.14), (I-6) + (5.15), (I-6) + (5.16), (I-6) + (5.17), (I6) + (5.18), (I-6) + (5.19), (I-6) + (5.20), (I-6) + (5.21), (I-6) + (5.22), (I-6) + (5.23), (I-6) + (5.24), (I6) + (5.25), (I-6) + (5.26), (I-6) + (5.27), (I-6) + (5.28), (I-6) + (5.29), (I-6) + (5.30), (I-6) + (5.31), (I6) + (5.32), (I-6) + (5.33), (I-6) + (5.34), (I-6) + (6.1), (I-6) + (6.2), (I-6) + (6.3), (I-6) + (6.4), (I-6) + (7.1), (I-6) + (7.2), (I-6) + (7.3), (I-6) + (7.4), (I-6) + (7.5), (I-6) + (7.6), (I-6) + (7.7), (I-6) + (7.8), (I-6) + (8.1), (I-6) + (8.2), (I-6) + (8.3), (I-6) + (8.4), (I-6) + (9.1), (I-6) + (9.2), (I-6) + (9.3), (I-6) + (9.4), (I-6) + (9.5), (I-6) + (9.6), (I-6) + (9.7), (I-6) + (9.8), (I-6) + (9.9), (I-6) + (10.1), (I-6) + (10.2), (I-6) + (10.3), (I-6) + (10.4), (I-6) + (10.5), (I-6) + (10.6), (I-6) + (10.7), (I6) + (10.8), (I-6) + (10.9), (I-6) + (10.10), (I-6) + (10.11), (I-6) + (10.12), (I-6) + (10.13), (I-6) + (10.14), (I-6) + (10.15), (I-6) + (11.1), (I-6) + (11.2), (I-6) + (11.3), (I-6) + (11.4), (I-6) + (11.5), (I-6) + (11.6), (I6) + (11.7), (I-6) + (12.1), (I-6) + (12.2), (I-6) + (12.3), (I-6) + (12.4), (I-6) + (12.5), (I-6) + (12.6), (I6) + (12.7), (I-6) + (12.8), (I-6) + (12.9), (I-6) + (12.10), (I-6) + (12.11), (I-6) + (12.12), (I-6) + (12.13), (I-6) + (13.1), (I-6) + (13.2), (I-6) + (13.3), (I-6) + (13.4), (I-6) + (13.5), (I-6) + (13.6), (I-6) + (13.7), (I6) + (14.1), (I-6) + (14.2), (I-6) + (14.3), (I-6) + (14.4), (I-6) + (14.5), (I-6) + (15.1), (I-6) + (15.2), (I6) + (15.3), (I-6) + (15.4), (I-6) + (15.5), (I-6) + (15.6), (I-6) + (15.7), (I-6) + (15.8), (I-6) + (15.9), (I6) + (15.10), (I-6) + (15.11), (I-6) + (15.12), (I-6) + (15.13), (I-6) + (15.14), (I-6) + (15.15), (I-6) + (15.16), (I-6) + (15.17), (I-6) + (15.18), (I-6) + (15.19), (I-6) + (15.20), (I-6) + (15.21), (I-6) + (15.22), (I-6) + (15.23), (I-6) + (15.24), (I-6) + (15.25), (I-6) + (15.26), (I-6) + (15.27), (I-6) + (15.28), (I-6) + (15.29), (I-6) + (15.30), (I-6) + (15.31), (I-6) + (15.32), (I-6) + (15.33), (I-6) +(15.34), (I-6) + (15.35), (I-6) + (15.36), (I-6) + (15.37), (I-6) + (15.38), (I-6) + (15.39), (I-6) + (15.41), (I-6) + (15.42), (I-6) + (15.43), (I-6) + (15.44), (I-6) + (15.45), (I-6) + (15.46), (I-6) + (15.47), (I-6) + (15.48), (I-6) + (15.49), (I-6) + (15.50), (I-6) + (15.51), (I-6) + (15.52), (I-6) + (15.53), (I-6) + (15.54), (I-6) + (15.55), (I-6) + (15.56), (I-6) + (15.57), (I-6) + (15.58), (I-6) + (15.59), (I-6) + (15.60), (I-6) + (15.61), (I-6) + (15.62), (I-6) + (15.63), (I-6) + (15.64), (I-6) + (15.65), (I-6) + (15.66), (I-6) + (15.67), (I-6) + (15.68), (I-6) + (15.69), (I-6) + (15.70), (I-6) + (15.71), (I-6) + (15.72), (I-6) + (15.73), (I-6) + (15.74), (I-6) + (15.75), (I-6) + (15.76), (I-6) + (15.77), (I-6) + (15.78), (I-6) + (15.79), (I-6) + (15.80), (I-6) + (15.81), (I-6) + (15.82), (I-6) + (15.83), (I-6) + (15.84), (I-6) + (15.85), (I-6) + (15.86), (I-6) + (15.87), (I-6) + (15.88), (I-6) + (15.89), (I-6) + (15.90), (I-6) + (15.91), (I-6) + (15.92), (I-6) + (15.93), (I-6) + (15.94).[029] According to a preferred variant, the present invention is directed to mixtures comprising the compound (I-6), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures ( I-6) + (1.1), (I-6) + (1.2), (I-6) + (1.3), (I-6) + (1.4), (I-6) + (1.5), ( I-6) + (1.6), (I-6) + (1.7), (I-6) + (1.8), (I-6) + (1.9), (I-6) + (1.10), ( I-6) + (1.11), (I-6) + (1.12), (I-6) + (1.13), (I-6) + (1.14), (I-6) + (1.15), ( I-6) + (1.16), (I6) + (1.17), (I-6) + (1.18), (I-6) + (1.19), (I-6) + (1.20), (I- 6) + (1.21), (I-6) + (1.22), (I-6) + (1.23), (I6) + (1.24), (I-6) + (1.25), (I-6) + (1.26), (I-6) + (1.27), (I-6) + (1.28), (I-6) + (1.29), (I-6) + (1.30), (I6) + ( 1.31), (I-6) + (1.32), (I-6) + (1.33), (I-6) + (1.34), (I-6) + (1.35), (I-6) + ( 1.36), (I-6) + (1.37), (I6) + (1.38), (I-6) + (1.39), (I-6) + (1.40), (I-6) + (1.41) , (I-6) + (1.42), (I-6) + (1.43), (I-6) + (1.44), (I6) + (1.45), (I-6) + (1.46), ( I-6) + (1.47), (I-6) + (1.48), (I-6) + (1.49), (I-6) + (1.50), (I-6) + (1.51), (I6) + (1.52), (I-6) + (1.53), (I-6) + (1.54), (I-6) + (1.55), (I -6) + (1.56), (I-6) + (1.57), (I-6) + (1.58), (I6) + (1.59), (I-6) + (1.60), (I-6 ) + (1.61), (I-6) + (1.62), (I-6) + (1.63), (I-6) + (1.64), (I-6) + (2.1), (I6) + (2.2), (I-6) + (2.3), (I-6) + (2.4), (I-6) + (2.5), (I-6) + (2.6), (I-6) + (2.7), (I-6) + (2.8), (I-6) + (2.9), (I-6) + (2.10), (I-6) + (2.11), (I-6) + (2.12), (I-6) + (2.13), (I-6) + (2.14), (I-6) + (2.15), (I-6) + (2.16), (I6) + (2.17 ), (I-6) + (2.18), (I-6) + (2.19), (I-6) + (2.20), (I-6) + (2.21), (I-6) + (2.22 ), (I-6) + (2.23), (I6) + (2.24), (I-6) + (2.25), (I-6) + (2.26), (I-6) + (2.27), (I-6) + (2.28), (I-6) + (2.29), (I-6) + (3.1), (I6) + (3.2), (I-6) + (3.3), (I -6) + (3.4), (I-6) + (3.5), (I-6) + (3.6), (I-6) + (3.7), (I-6) + (3.8), (I -6) + (3.9), (I-6) + (3.10), (I-6) + (3.11), (I-6) + (3.12), (I-6) + (3.13), (I -6) + (3.14), (I-6) + (3.15), (I-6) + (3.16), (I6) + (3.17), (I-6) + (3.18), (I-6 ) + (3.19), (I-6) + (3.20), (I-6) + (3.21), ( I-6) + (3.22), (I-6) + (3.23), (I6) + (3.24), (I-6) + (3.25), (I-6) + (3.26), (I- 6) + (3.27), (I-6) + (3.28), (I-6) + (3.29), (I-6) + (3.30), (I6) + (3.31), (I-6) + (3.32), (I-6) + (3.33), (I-6) + (4.1), (I-6) + (4.2), (I-6) + (4.3), (I-6) + (4.4), (I-6) + (4.5), (I-6) + (4.6), (I-6) + (4.7), (I-6) + (4.8), (I-6) + (4.9), (I-6) + (4.10), (I-6) + (4.11), (I-6) + (4.12), (I-6) + (4.13), (I-6) + (4.14), (I-6) + (5.1), (I-6) + (5.2), (I-6) + (5.3), (I-6) + (5.4), (I-6) + (5.5), (I-6) + (5.6), (I-6) + (5.7), (I-6) + (5.8), (I-6) + (5.9), (I-6) + (5.10), (I6) + (5.11), (I-6) + (5.12), (I-6) + (5.13), (I-6) + (5.14), (I-6) + ( 5.15), (I-6) + (5.16), (I-6) + (5.17), (I6) + (5.18), (I-6) + (5.19), (I-6) + (5.20) , (I-6) + (5.21), (I-6) + (5.22), (I-6) + (5.23), (I-6) + (5.24), (I6) + (5.25), ( I-6) + (5.26), (I-6) + (5.27), (I-6) + (5.28), (I-6) + (5.29), (I-6) + (5.30), ( I-6) + (5.31), (I6) + (5.32), (I-6) + (5.33), (I-6) + (5.34), (I-6) + (6.1), (I- 6) + (6.2), (I-6) + (6.3), (I-6) + (6.4), (I-6) + (7.1), (I-6) + (7.2), (I-6) + (7.3), (I-6) + (7.4), (I-6) + (7.5), (I-6) + (7.6), (I-6) + (7.7), (I-6) + (7.8), (I-6) + (8.1), (I-6) + (8.2), (I-6) + (8.3), (I-6) + (8.4), (I-6) + (9.1), (I-6) + (9.2), (I-6) + (9.3), (I-6) + (9.4), (I-6) + (9.5), (I-6) + (9.6), (I-6) + (9.7), (I-6) + (9.8), (I-6) + (9.9), (I-6) + (10.1), (I-6) + (10.2), (I-6) + (10.3), (I-6) + (10.4), (I-6) + (10.5), (I-6) + (10.6), (I-6) + (10.7), (I6) + (10.8), (I-6) + (10.9), (I-6) + ( 10.10), (I-6) + (10.11), (I-6) + (10.12), (I-6) + (10.13), (I-6) + (10.14), (I-6) + ( 10.15), (I-6) + (11.1), (I-6) + (11.2), (I-6) + (11.3), (I-6) + (11.4), (I-6) + ( 11.5), (I-6) + (11.6), (I6) + (11.7), (I-6) + (12.1), (I-6) + (12.2), (I-6) + (12.3) , (I-6) + (12.4), (I-6) + (12.5), (I-6) + (12.6), (I6) + (12.7), (I-6) + (12.8), ( I-6) + (12.9), (I-6) + (12.10), (I-6) + (12.11), (I-6) + (12.12), (I-6) + (12.13), ( I-6) + (13.1), (I-6) + (13.2), (I-6) + (13.3), (I-6) + (13.4), (I-6) + (13.5), ( I-6) + (13.6), (I-6) + (13.7), (I6) + (14. 1), (I-6) + (14.2), (I-6) + (14.3), (I-6) + (14.4), (I-6) + (14.5), (I-6) + ( 15.1), (I-6) + (15.2), (I6) + (15.3), (I-6) + (15.4), (I-6) + (15.5), (I-6) + (15.6) , (I-6) + (15.7), (I-6) + (15.8), (I-6) + (15.9), (I6) + (15.10), (I-6) + (15.11), ( I-6) + (15.12), (I-6) + (15.13), (I-6) + (15.14), (I-6) + (15.15), (I-6) + (15.16), ( I-6) + (15.17), (I-6) + (15.18), (I-6) + (15.19), (I-6) + (15.20), (I-6) + (15.21), ( I-6) + (15.22), (I-6) + (15.23), (I-6) + (15.24), (I-6) + (15.25), (I-6) + (15.26), ( I-6) + (15.27), (I-6) + (15.28), (I-6) + (15.29), (I-6) + (15.30), (I-6) + (15.31), ( I-6) + (15.32), (I-6) + (15.33), (I-6) + (15.34), (I-6) + (15.35), (I-6) + (15.36), ( I-6) + (15.37), (I-6) + (15.38), (I-6) + (15.39), (I-6) + (15.41), (I-6) + (15.42), ( I-6) + (15.43), (I-6) + (15.44), (I-6) + (15.45), (I-6) + (15.46), (I-6) + (15.47), ( I-6) + (15.48), (I-6) + (15.49), (I-6) + (15.50), (I-6) + (15.51), (I-6) + (15.52), ( I-6) + (15.53), (I-6) + (15.54), (I-6) + (15.55), (I-6) + (15.56), (I-6) + ( 15.57), (I-6) + (15.58), (I-6) + (15.59), (I-6) + (15.60), (I-6) + (15.61), (I-6) + ( 15.62), (I-6) + (15.63), (I-6) + (15.64), (I-6) + (15.65), (I-6) + (15.66), (I-6) + ( 15.67), (I-6) + (15.68), (I-6) + (15.69), (I-6) + (15.70), (I-6) + (15.71), (I-6) + ( 15.72), (I-6) + (15.73), (I-6) + (15.74), (I-6) + (15.75), (I-6) + (15.76), (I-6) + ( 15.77), (I-6) + (15.78), (I-6) + (15.79), (I-6) + (15.80), (I-6) + (15.81), (I-6) + ( 15.82), (I-6) + (15.83), (I-6) + (15.84), (I-6) + (15.85), (I-6) + (15.86), (I-6) + ( 15.87), (I-6) + (15.88), (I-6) + (15.89), (I-6) + (15.90), (I-6) + (15.91), (I-6) + ( 15.92), (I-6) + (15.93), (I-6) + (15.94).

[030] De acordo com uma outra variante particularmente preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-6), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-6) + (2.1), (I-6) + (2.2), (I-6) + (2.6), (I-6) + (2.8), (I-6) + (2.11), (I-6) + (2.12), (I-6) + (2.13), (I-6) + (2.14), (I-6) + (2.15), (I-6) + (2.16), (I-6) + (2.17), (I-6) + (2.29), (I-6) + (3.1), (I-6) + (3.2), (I-6) + (3.3), (I-6) + (3.4), (I-6) + (3.9), (I-6) + (3.10), (I6) + (3.12), (I-6) + (3.16), (I-6) + (3.17), (I-6) + (3.22), (I-6) + (4.6), (I-6) + (5.1), (I-6) + (5.4), (I-6) + (5.5), (I-6) + (5.7), (I-6) + (5.8), (I-6) + (5.9), (I-6) + (5.16), (I-6) + (5.23), (I-6) + (5.25), (I-6) + (5.26), (I-6) + (5.29), (I-6) + (5.30), (I-6) + (7.7), (I-6) + (9.2), (I-6) + (9.4), (I-6) + (9.5), (I-6) + (10.9), (I-6) + (10.10), (I-6) + (12.9), (I-6) + (12.10), (I-6) + (14.4), (I-6) + (15.9), (I-6) + (15.24), (I-6) + (15.25), (I-6) + (15.26), (I-6) + (15.41), (I-6) + (15.42), (I-6) + (15.54), (I-6) + (15.55), (I-6) + (15.56), (I-6) + (15.60), (I-6) + (15.90).[030] According to another particularly preferred variant, the present invention is directed to mixtures comprising the compound (I-6), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures (I-6) + (2.1), (I-6) + (2.2), (I-6) + (2.6), (I-6) + (2.8), (I-6) + (2.11) , (I-6) + (2.12), (I-6) + (2.13), (I-6) + (2.14), (I-6) + (2.15), (I-6) + (2.16) , (I-6) + (2.17), (I-6) + (2.29), (I-6) + (3.1), (I-6) + (3.2), (I-6) + (3.3) , (I-6) + (3.4), (I-6) + (3.9), (I-6) + (3.10), (I6) + (3.12), (I-6) + (3.16), ( I-6) + (3.17), (I-6) + (3.22), (I-6) + (4.6), (I-6) + (5.1), (I-6) + (5.4), ( I-6) + (5.5), (I-6) + (5.7), (I-6) + (5.8), (I-6) + (5.9), (I-6) + (5.16), ( I-6) + (5.23), (I-6) + (5.25), (I-6) + (5.26), (I-6) + (5.29), (I-6) + (5.30), ( I-6) + (7.7), (I-6) + (9.2), (I-6) + (9.4), (I-6) + (9.5), (I-6) + (10.9), ( I-6) + (10.10), (I-6) + (12.9), (I-6) + (12.10), (I-6) + (14.4), (I-6) + (15.9), ( I-6) + (15.24), (I-6) + (15.25), (I-6) + (15.26), (I-6) + (15 .41), (I-6) + (15.42), (I-6) + (15.54), (I-6) + (15.55), (I-6) + (15.56), (I-6) + (15.60), (I-6) + (15.90).

[031] De acordo com uma variante preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-7), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-7) + (1.1), (I-7) + (1.2), (I-7) + (1.3), (I-7) + (1.4), (I-7) + (1.5), (I-7) + (1.6), (I-7) + (1.7), (I-7) + (1.8), (I-7) + (1.9), (I-7) + (1.10), (I-7) + (1.11), (I-7) + (1.12), (I-7) + (1.13), (I-7) + (1.14), (I-7) + (1.15), (I-7) + (1.16), (I7) + (1.17), (I-7) + (1.18), (I-7) + (1.19), (I-7) + (1.20), (I-7) + (1.21), (I-7) + (1.22), (I-7) + (1.23), (I7) + (1.24), (I-7) + (1.25), (I-7) + (1.26), (I-7) + (1.27), (I-7) + (1.28), (I-7) + (1.29), (I-7) + (1.30), (I7) + (1.31), (I-7) + (1.32), (I-7) + (1.33), (I-7) + (1.34), (I-7) + (1.35), (I-7) + (1.36), (I-7) + (1.37), (I7) + (1.38), (I-7) + (1.39), (I-7) + (1.40), (I-7) + (1.41), (I-7) + (1.42), (I-7) + (1.43), (I-7) + (1.44), (I7) + (1.45), (I-7) + (1.46), (I-7) + (1.47), (I-7) + (1.48), (I-7) + (1.49), (I-7) + (1.50), (I-7) + (1.51), (I7) + (1.52), (I-7) + (1.53), (I-7) + (1.54), (I-7) + (1.55), (I-7) + (1.56), (I-7) + (1.57), (I-7) + (1.58), (I7) + (1.59), (I-7) + (1.60), (I-7) + (1.61), (I-7) + (1.62), (I-7) + (1.63), (I-7) + (1.64), (I-7) + (2.1), (I7) + (2.2), (I-7) + (2.3), (I-7) + (2.4), (I-7) + (2.5), (I-7) + (2.6), (I-7) + (2.7), (I-7) + (2.8), (I-7) + (2.9), (I-7) + (2.10), (I-7) + (2.11), (I-7) + (2.12), (I-7) + (2.13), (I-7) + (2.14), (I-7) + (2.15), (I-7) + (2.16), (I7) + (2.17), (I-7) + (2.18), (I-7) + (2.19), (I-7) + (2.20), (I-7) + (2.21), (I-7) + (2.22), (I-7) + (2.23), (I7) + (2.24), (I-7) + (2.25), (I-7) + (2.26), (I-7) + (2.27), (I-7) + (2.28), (I-7) + (2.29), (I-7) + (3.1), (I7) + (3.2), (I-7) + (3.3), (I-7) + (3.4), (I-7) + (3.5), (I-7) + (3.6), (I-7) + (3.7), (I-7) + (3.8), (I-7) + (3.9), (I-7) + (3.10), (I-7) + (3.11), (I-7) + (3.12), (I-7) + (3.13), (I-7) + (3.14), (I-7) + (3.15), (I-7) + (3.16), (I7) + (3.17), (I-7) + (3.18), (I-7) + (3.19), (I-7) + (3.20), (I-7) + (3.21), (I-7) + (3.22), (I-7) + (3.23), (I7) + (3.24), (I-7) + (3.25), (I-7) + (3.26), (I-7) + (3.27), (I-7) + (3.28), (I-7) + (3.29), (I-7) + (3.30), (I7) + (3.31), (I-7) + (3.32), (I-7) + (3.33), (I-7) + (4.1), (I-7) + (4.2), (I-7) + (4.3), (I-7) + (4.4), (I-7) + (4.5), (I-7) + (4.6), (I-7) + (4.7), (I-7) + (4.8), (I-7) + (4.9), (I-7) + (4.10), (I-7) + (4.11), (I-7) + (4.12), (I-7) + (4.13), (I-7) + (4.14), (I-7) + (5.1), (I-7) + (5.2), (I-7) + (5.3), (I-7) + (5.4), (I-7) + (5.5), (I-7) + (5.6), (I-7) + (5.7), (I-7) + (5.8), (I-7) + (5.9), (I-7) + (5.10), (I7) + (5.11), (I-7) + (5.12), (I-7) + (5.13), (I-7) + (5.14), (I-7) + (5.15), (I-7) + (5.16), (I-7) + (5.17), (I7) + (5.18), (I-7) + (5.19), (I-7) + (5.20), (I-7) + (5.21), (I-7) + (5.22), (I-7) + (5.23), (I-7) + (5.24), (I7) + (5.25), (I-7) + (5.26), (I-7) + (5.27), (I-7) + (5.28), (I-7) + (5.29), (I-7) + (5.30), (I-7) + (5.31), (I7) + (5.32), (I-7) + (5.33), (I-7) + (5.34), (I-7) + (6.1), (I-7) + (6.2), (I-7) + (6.3), (I-7) + (6.4), (I-7) + (7.1), (I-7) + (7.2), (I-7) + (7.3), (I-7) + (7.4), (I-7) + (7.5), (I-7) + (7.6), (I-7) + (7.7), (I-7) + (7.8), (I-7) + (8.1), (I-7) + (8.2), (I-7) + (8.3), (I-7) + (8.4), (I-7) + (9.1), (I-7) + (9.2), (I-7) + (9.3), (I-7) + (9.4), (I-7) + (9.5), (I-7) + (9.6), (I-7) + (9.7), (I-7) + (9.8), (I-7) + (9.9), (I-7) + (10.1), (I-7) + (10.2), (I-7) + (10.3), (I-7) + (10.4), (I-7) + (10.5), (I-7) + (10.6), (I-7) + (10.7), (I7) + (10.8), (I-7) + (10.9), (I-7) + (10.10), (I-7) + (10.11), (I-7) + (10.12), (I-7) + (10.13), (I-7) + (10.14), (I-7) + (10.15), (I-7) + (11.1), (I-7) + (11.2), (I-7) + (11.3), (I-7) + (11.4), (I-7) + (11.5), (I-7) + (11.6), (I7) + (11.7), (I-7) + (12.1), (I-7) + (12.2), (I-7) + (12.3), (I-7) + (12.4), (I-7) + (12.5), (I-7) + (12.6), (I7) + (12.7), (I-7) + (12.8), (I-7) + (12.9), (I-7) + (12.10), (I-7) + (12.11), (I-7) + (12.12), (I-7) + (12.13), (I-7) + (13.1), (I-7) + (13.2), (I-7) + (13.3), (I-7) + (13.4), (I-7) + (13.5), (I-7) + (13.6), (I-7) + (13.7), (I7) + (14.1), (I-7) + (14.2), (I-7) + (14.3), (I-7) + (14.4), (I-7) + (14.5), (I-7) + (15.1), (I-7) + (15.2), (I7) + (15.3), (I-7) + (15.4), (I-7) + (15.5), (I-7) + (15.6), (I-7) + (15.7), (I-7) + (15.8), (I-7) + (15.9), (I7) + (15.10), (I-7) + (15.11), (I-7) + (15.12), (I-7) + (15.13), (I-7) + (15.14), (I-7) + (15.15), (I-7) + (15.16), (I-7) + (15.17), (I-7) + (15.18), (I-7) + (15.19), (I-7) + (15.20), (I-7) + (15.21), (I-7) + (15.22), (I-7) + (15.23), (I-7) + (15.24), (I-7) + (15.25), (I-7) + (15.26), (I-7) + (15.27), (I-7) + (15.28), (I-7) + (15.29), (I-7) + (15.30), (I-7) + (15.31), (I-7) + (15.32), (I-7) + (15.33), (I-7) + (15.34), (I-7) + (15.35), (I-7) + (15.36), (I-7) + (15.37), (I-7) + (15.38), (I-7) + (15.39), (I-7) + (15.41), (I-7) +(15.42), (I-7) + (15.43), (I-7) + (15.44), (I-7) + (15.45), (I-7) + (15.46), (I-7) + (15.47), (I-7) + (15.48), (I-7) + (15.49), (I-7) + (15.50), (I-7) + (15.51), (I-7) + (15.52), (I-7) + (15.53), (I-7) + (15.54), (I-7) + (15.55), (I-7) + (15.56), (I-7) + (15.57), (I-7) + (15.58), (I-7) + (15.59), (I-7) + (15.60), (I-7) + (15.61), (I-7) + (15.62), (I-7) + (15.63), (I-7) + (15.64), (I-7) + (15.65), (I-7) + (15.66), (I-7) + (15.67), (I-7) + (15.68), (I-7) + (15.69), (I-7) + (15.70), (I-7) + (15.71), (I-7) + (15.72), (I-7) + (15.73), (I-7) + (15.74), (I-7) + (15.75), (I-7) + (15.76), (I-7) + (15.77), (I-7) + (15.78), (I-7) + (15.79), (I-7) + (15.80), (I-7) + (15.81), (I-7) + (15.82), (I-7) + (15.83), (I-7) + (15.84), (I-7) + (15.85), (I-7) + (15.86), (I-7) + (15.87), (I-7) + (15.88), (I-7) + (15.89), (I-7) + (15.90), (I-7) + (15.91), (I-7) + (15.92), (I-7) + (15.93), (I-7) + (15.94).[031] According to a preferred variant, the present invention is directed to mixtures comprising the compound (I-7), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures ( I-7) + (1.1), (I-7) + (1.2), (I-7) + (1.3), (I-7) + (1.4), (I-7) + (1.5), ( I-7) + (1.6), (I-7) + (1.7), (I-7) + (1.8), (I-7) + (1.9), (I-7) + (1.10), ( I-7) + (1.11), (I-7) + (1.12), (I-7) + (1.13), (I-7) + (1.14), (I-7) + (1.15), ( I-7) + (1.16), (I7) + (1.17), (I-7) + (1.18), (I-7) + (1.19), (I-7) + (1.20), (I- 7) + (1.21), (I-7) + (1.22), (I-7) + (1.23), (I7) + (1.24), (I-7) + (1.25), (I-7) + (1.26), (I-7) + (1.27), (I-7) + (1.28), (I-7) + (1.29), (I-7) + (1.30), (I7) + ( 1.31), (I-7) + (1.32), (I-7) + (1.33), (I-7) + (1.34), (I-7) + (1.35), (I-7) + ( 1.36), (I-7) + (1.37), (I7) + (1.38), (I-7) + (1.39), (I-7) + (1.40), (I-7) + (1.41) , (I-7) + (1.42), (I-7) + (1.43), (I-7) + (1.44), (I7) + (1.45), (I-7) + (1.46), ( I-7) + (1.47), (I-7) + (1.48), (I-7) + (1.49), (I-7) + (1.50), (I-7) + (1.51), (I7) + (1.52), (I-7) + (1.53), (I-7) + (1.54), (I-7) + (1.55), (I -7) + (1.56), (I-7) + (1.57), (I-7) + (1.58), (I7) + (1.59), (I-7) + (1.60), (I-7 ) + (1.61), (I-7) + (1.62), (I-7) + (1.63), (I-7) + (1.64), (I-7) + (2.1), (I7) + (2.2), (I-7) + (2.3), (I-7) + (2.4), (I-7) + (2.5), (I-7) + (2.6), (I-7) + (2.7), (I-7) + (2.8), (I-7) + (2.9), (I-7) + (2.10), (I-7) + (2.11), (I-7) + (2.12), (I-7) + (2.13), (I-7) + (2.14), (I-7) + (2.15), (I-7) + (2.16), (I7) + (2.17 ), (I-7) + (2.18), (I-7) + (2.19), (I-7) + (2.20), (I-7) + (2.21), (I-7) + (2.22 ), (I-7) + (2.23), (I7) + (2.24), (I-7) + (2.25), (I-7) + (2.26), (I-7) + (2.27), (I-7) + (2.28), (I-7) + (2.29), (I-7) + (3.1), (I7) + (3.2), (I-7) + (3.3), (I -7) + (3.4), (I-7) + (3.5), (I-7) + (3.6), (I-7) + (3.7), (I-7) + (3.8), (I -7) + (3.9), (I-7) + (3.10), (I-7) + (3.11), (I-7) + (3.12), (I-7) + (3.13), (I -7) + (3.14), (I-7) + (3.15), (I-7) + (3.16), (I7) + (3.17), (I-7) + (3.18), (I-7 ) + (3.19), (I-7) + (3.20), (I-7) + (3.21), (I-7) + (3.22), (I-7) + (3.23), (I7) + (3.24), (I-7) + (3.25), (I-7) + (3.26), (I -7) + (3.27), (I-7) + (3.28), (I-7) + (3.29), (I-7) + (3.30), (I7) + (3.31), (I-7 ) + (3.32), (I-7) + (3.33), (I-7) + (4.1), (I-7) + (4.2), (I-7) + (4.3), (I-7 ) + (4.4), (I-7) + (4.5), (I-7) + (4.6), (I-7) + (4.7), (I-7) + (4.8), (I-7 ) + (4.9), (I-7) + (4.10), (I-7) + (4.11), (I-7) + (4.12), (I-7) + (4.13), (I-7 ) + (4.14), (I-7) + (5.1), (I-7) + (5.2), (I-7) + (5.3), (I-7) + (5.4), (I-7 ) + (5.5), (I-7) + (5.6), (I-7) + (5.7), (I-7) + (5.8), (I-7) + (5.9), (I-7 ) + (5.10), (I7) + (5.11), (I-7) + (5.12), (I-7) + (5.13), (I-7) + (5.14), (I-7) + (5.15), (I-7) + (5.16), (I-7) + (5.17), (I7) + (5.18), (I-7) + (5.19), (I-7) + (5.20 ), (I-7) + (5.21), (I-7) + (5.22), (I-7) + (5.23), (I-7) + (5.24), (I7) + (5.25), (I-7) + (5.26), (I-7) + (5.27), (I-7) + (5.28), (I-7) + (5.29), (I-7) + (5.30), (I-7) + (5.31), (I7) + (5.32), (I-7) + (5.33), (I-7) + (5.34), (I-7) + (6.1), (I -7) + (6.2), (I-7) + (6.3), (I-7) + (6.4), (I-7 ) + (7.1), (I-7) + (7.2), (I-7) + (7.3), (I-7) + (7.4), (I-7) + (7.5), (I-7 ) + (7.6), (I-7) + (7.7), (I-7) + (7.8), (I-7) + (8.1), (I-7) + (8.2), (I-7 ) + (8.3), (I-7) + (8.4), (I-7) + (9.1), (I-7) + (9.2), (I-7) + (9.3), (I-7 ) + (9.4), (I-7) + (9.5), (I-7) + (9.6), (I-7) + (9.7), (I-7) + (9.8), (I-7 ) + (9.9), (I-7) + (10.1), (I-7) + (10.2), (I-7) + (10.3), (I-7) + (10.4), (I-7 ) + (10.5), (I-7) + (10.6), (I-7) + (10.7), (I7) + (10.8), (I-7) + (10.9), (I-7) + (10.10), (I-7) + (10.11), (I-7) + (10.12), (I-7) + (10.13), (I-7) + (10.14), (I-7) + (10.15), (I-7) + (11.1), (I-7) + (11.2), (I-7) + (11.3), (I-7) + (11.4), (I-7) + (11.5), (I-7) + (11.6), (I7) + (11.7), (I-7) + (12.1), (I-7) + (12.2), (I-7) + (12.3 ), (I-7) + (12.4), (I-7) + (12.5), (I-7) + (12.6), (I7) + (12.7), (I-7) + (12.8), (I-7) + (12.9), (I-7) + (12.10), (I-7) + (12.11), (I-7) + (12.12), (I-7) + (12.13), (I-7) + (13.1), (I-7) + (13.2), (I-7) + (13.3), (I-7) + (13.4), (I-7) + (13.5), (I-7) + (13.6), (I-7) + (13.7), (I7) + (14 .1), (I-7) + (14.2), (I-7) + (14.3), (I-7) + (14.4), (I-7) + (14.5), (I-7) + (15.1), (I-7) + (15.2), (I7) + (15.3), (I-7) + (15.4), (I-7) + (15.5), (I-7) + (15.6 ), (I-7) + (15.7), (I-7) + (15.8), (I-7) + (15.9), (I7) + (15.10), (I-7) + (15.11), (I-7) + (15.12), (I-7) + (15.13), (I-7) + (15.14), (I-7) + (15.15), (I-7) + (15.16), (I-7) + (15.17), (I-7) + (15.18), (I-7) + (15.19), (I-7) + (15.20), (I-7) + (15.21), (I-7) + (15.22), (I-7) + (15.23), (I-7) + (15.24), (I-7) + (15.25), (I-7) + (15.26), (I-7) + (15.27), (I-7) + (15.28), (I-7) + (15.29), (I-7) + (15.30), (I-7) + (15.31), (I-7) + (15.32), (I-7) + (15.33), (I-7) + (15.34), (I-7) + (15.35), (I-7) + (15.36), (I-7) + (15.37), (I-7) + (15.38), (I-7) + (15.39), (I-7) + (15.41), (I-7) + (15.42), (I-7) + (15.43), (I-7) + (15.44), (I-7) + (15.45), (I-7) + (15.46), (I-7) + (15.47), (I-7) + (15.48), (I-7) + (15.49), (I-7) + (15.50), (I-7) + (15.51), (I-7) + (15.52), (I-7) + (15.53), (I-7) + (15.54), (I-7) + (15.55), (I-7) + (15.56), (I-7) + (15.57), (I-7) + (15.58), (I-7) + (15.59), (I-7) + (15.60), (I-7) + (15.61), (I-7) + (15.62), (I-7) + (15.63), (I-7) + (15.64), (I-7) + (15.65), (I-7) + (15.66), (I-7) + (15.67), (I-7) + (15.68), (I-7) + (15.69), (I-7) + (15.70), (I-7) + (15.71), (I-7) + (15.72), (I-7) + (15.73), (I-7) + (15.74), (I-7) + (15.75), (I-7) + (15.76), (I-7) + (15.77), (I-7) + (15.78), (I-7) + (15.79), (I-7) + (15.80), (I-7) + (15.81), (I-7) + (15.82), (I-7) + (15.83), (I-7) + (15.84), (I-7) + (15.85), (I-7) + (15.86), (I-7) + (15.87), (I-7) + (15.88), (I-7) + (15.89), (I-7) + (15.90), (I-7) + (15.91), (I-7) + (15.92), (I-7) + (15.93), (I-7) + (15.94).

[032] De acordo com uma outra variante particularmente preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-7), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-7) + (2.1), (I-7) + (2.2), (I-7) + (2.6), (I-7) + (2.8), (I-7) + (2.11), (I-7) + (2.12), (I-7) + (2.13), (I-7) + (2.14), (I-7) + (2.15), (I-7) + (2.16), (I-7) + (2.17), (I-7) + (2.29), (I-7) + (3.1), (I-7) + (3.2), (I-7) + (3.3), (I-7) + (3.4), (I-7) + (3.9), (I-7) + (3.10), (I7) + (3.12), (I-7) + (3.16), (I-7) + (3.17), (I-7) + (3.22), (I-7) + (4.6), (I-7) + (5.1), (I-7) + (5.4), (I-7) + (5.5), (I-7) + (5.7), (I-7) + (5.8), (I-7) + (5.9), (I-7) + (5.16), (I-7) + (5.23), (I-7) + (5.25), (I-7) + (5.26), (I-7) + (5.29), (I-7) + (5.30), (I-7) + (7.7), (I-7) + (9.2), (I-7) + (9.4), (I-7) + (9.5), (I-7) + (10.9), (I-7) + (10.10), (I-7) + (12.9), (I-7) + (12.10), (I-7) + (14.4), (I-7) + (15.9), (I-7) + (15.24), (I-7) + (15.25), (I-7) + (15.26), (I-7) + (15.41), (I-7) + (15.42), (I-7) + (15.54), (I-7) + (15.55), (I-7) + (15.56), (I-7) + (15.60), (I-7) + (15.90).[032] According to another particularly preferred variant, the present invention is directed to mixtures comprising the compound (I-7), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures (I-7) + (2.1), (I-7) + (2.2), (I-7) + (2.6), (I-7) + (2.8), (I-7) + (2.11) , (I-7) + (2.12), (I-7) + (2.13), (I-7) + (2.14), (I-7) + (2.15), (I-7) + (2.16) , (I-7) + (2.17), (I-7) + (2.29), (I-7) + (3.1), (I-7) + (3.2), (I-7) + (3.3) , (I-7) + (3.4), (I-7) + (3.9), (I-7) + (3.10), (I7) + (3.12), (I-7) + (3.16), ( I-7) + (3.17), (I-7) + (3.22), (I-7) + (4.6), (I-7) + (5.1), (I-7) + (5.4), ( I-7) + (5.5), (I-7) + (5.7), (I-7) + (5.8), (I-7) + (5.9), (I-7) + (5.16), ( I-7) + (5.23), (I-7) + (5.25), (I-7) + (5.26), (I-7) + (5.29), (I-7) + (5.30), ( I-7) + (7.7), (I-7) + (9.2), (I-7) + (9.4), (I-7) + (9.5), (I-7) + (10.9), ( I-7) + (10.10), (I-7) + (12.9), (I-7) + (12.10), (I-7) + (14.4), (I-7) + (15.9), ( I-7) + (15.24), (I-7) + (15.25), (I-7) + (15.26), (I-7) + (15 .41), (I-7) + (15.42), (I-7) + (15.54), (I-7) + (15.55), (I-7) + (15.56), (I-7) + (15.60), (I-7) + (15.90).

[033] De acordo com uma variante preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-8), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-8) + (1.1), (I-8) + (1.2), (I-8) + (1.3), (I-8) + (1.4), (I-8) + (1.5), (I-8) + (1.6), (I-8) + (1.7), (I-8) + (1.8), (I-8) + (1.9), (I-8) + (1.10), (I-8) + (1.11), (I-8) + (1.12), (I-8) + (1.13), (I-8) + (1.14), (I-8) + (1.15), (I-8) + (1.16), (I8) + (1.17), (I-8) + (1.18), (I-8) + (1.19), (I-8) + (1.20), (I-8) + (1.21), (I-8) + (1.22), (I-8) + (1.23), (I8) + (1.24), (I-8) + (1.25), (I-8) + (1.26), (I-8) + (1.27), (I-8) + (1.28), (I-8) + (1.29), (I-8) + (1.30), (I8) + (1.31), (I-8) + (1.32), (I-8) + (1.33), (I-8) + (1.34), (I-8) + (1.35), (I-8) + (1.36), (I-8) + (1.37), (I8) + (1.38), (I-8) + (1.39), (I-8) + (1.40), (I-8) + (1.41), (I-8) + (1.42), (I-8) + (1.43), (I-8) + (1.44), (I8) + (1.45), (I-8) + (1.46), (I-8) + (1.47), (I-8) + (1.48), (I-8) + (1.49), (I-8) + (1.50), (I-8) + (1.51), (I8) + (1.52), (I-8) + (1.53), (I-8) + (1.54), (I-8) + (1.55), (I-8) + (1.56), (I-8) + (1.57), (I-8) + (1.58), (I8) + (1.59), (I-8) + (1.60), (I-8) + (1.61), (I-8) + (1.62), (I-8) + (1.63), (I-8) + (1.64), (I-8) + (2.1), (I8) + (2.2), (I-8) + (2.3), (I-8) + (2.4), (I-8) + (2.5), (I-8) + (2.6), (I-8) + (2.7), (I-8) + (2.8), (I-8) + (2.9), (I-8) + (2.10), (I-8) + (2.11), (I-8) + (2.12), (I-8) +(2.13), (I-8) + (2.14), (I-8) + (2.15), (I-8) + (2.16), (I8) + (2.17), (I-8) + (2.18), (I-8) + (2.19), (I-8) + (2.20), (I-8) + (2.21), (I-8) + (2.22), (I-8) + (2.23), (I8) + (2.24), (I-8) + (2.25), (I-8) + (2.26), (I-8) + (2.27), (I-8) + (2.28), (I-8) + (2.29), (I-8) + (3.1), (I8) + (3.2), (I-8) + (3.3), (I-8) + (3.4), (I-8) + (3.5), (I-8) + (3.6), (I-8) + (3.7), (I-8) + (3.8), (I-8) + (3.9), (I-8) + (3.10), (I-8) + (3.11), (I-8) + (3.12), (I-8) + (3.13), (I-8) + (3.14), (I-8) + (3.15), (I-8) + (3.16), (I8) + (3.17), (I-8) + (3.18), (I-8) + (3.19), (I-8) + (3.20), (I-8) + (3.21), (I-8) + (3.22), (I-8) + (3.23), (I8) + (3.24), (I-8) + (3.25), (I-8) + (3.26), (I-8) + (3.27), (I-8) + (3.28), (I-8) + (3.29), (I-8) + (3.30), (I8) + (3.31), (I-8) + (3.32), (I-8) + (3.33), (I-8) + (4.1), (I-8) + (4.2), (I-8) + (4.3), (I-8) + (4.4), (I-8) + (4.5), (I-8) + (4.6), (I-8) + (4.7), (I-8) + (4.8), (I-8) + (4.9), (I-8) + (4.10), (I-8) + (4.11), (I-8) + (4.12), (I-8) + (4.13), (I-8) + (4.14), (I-8) + (5.1), (I-8) + (5.2), (I-8) + (5.3), (I-8) + (5.4), (I-8) + (5.5), (I-8) + (5.6), (I-8) + (5.7), (I-8) + (5.8), (I-8) + (5.9), (I-8) + (5.10), (I8) + (5.11), (I-8) + (5.12), (I-8) + (5.13), (I-8) + (5.14), (I-8) + (5.15), (I-8) + (5.16), (I-8) + (5.17), (I8) + (5.18), (I-8) + (5.19), (I-8) + (5.20), (I-8) + (5.21), (I-8) + (5.22), (I-8) + (5.23), (I-8) + (5.24), (I8) + (5.25), (I-8) + (5.26), (I-8) + (5.27), (I-8) + (5.28), (I-8) + (5.29), (I-8) + (5.30), (I-8) + (5.31), (I8) + (5.32), (I-8) + (5.33), (I-8) + (5.34), (I-8) + (6.1), (I-8) + (6.2), (I-8) + (6.3), (I-8) + (6.4), (I-8) + (7.1), (I-8) + (7.2), (I-8) + (7.3), (I-8) + (7.4), (I-8) + (7.5), (I-8) + (7.6), (I-8) + (7.7), (I-8) + (7.8), (I-8) + (8.1), (I-8) + (8.2), (I-8) + (8.3), (I-8) + (8.4), (I-8) + (9.1), (I-8) + (9.2), (I-8) + (9.3), (I-8) + (9.4), (I-8) + (9.5), (I-8) + (9.6), (I-8) + (9.7), (I-8) + (9.8), (I-8) + (9.9), (I-8) + (10.1), (I-8) + (10.2), (I-8) + (10.3), (I-8) + (10.4), (I-8) + (10.5), (I-8) + (10.6), (I-8) + (10.7), (I8) + (10.8), (I-8) + (10.9), (I-8) + (10.10), (I-8) + (10.11), (I-8) + (10.12), (I-8) + (10.13), (I-8) + (10.14), (I-8) + (10.15), (I-8) + (11.1), (I-8) + (11.2), (I-8) + (11.3), (I-8) + (11.4), (I-8) + (11.5), (I-8) + (11.6), (I8) + (11.7), (I-8) + (12.1), (I-8) + (12.2), (I-8) + (12.3), (I-8) + (12.4), (I-8) + (12.5), (I-8) + (12.6), (I8) + (12.7), (I-8) + (12.8), (I-8) + (12.9), (I-8) + (12.10), (I-8) + (12.11), (I-8) + (12.12), (I-8) + (12.13), (I-8) + (13.1), (I-8) + (13.2), (I-8) + (13.3), (I-8) + (13.4), (I-8) + (13.5), (I-8) + (13.6), (I-8) + (13.7), (I8) + (14.1), (I-8) + (14.2), (I-8) + (14.3), (I-8) + (14.4), (I-8) + (14.5), (I-8) + (15.1), (I-8) + (15.2), (I8) + (15.3), (I-8) + (15.4), (I-8) + (15.5), (I-8) + (15.6), (I-8) + (15.7), (I-8) + (15.8), (I-8) + (15.9), (I8) + (15.10), (I-8) + (15.11), (I-8) + (15.12), (I-8) + (15.13), (I-8) + (15.14), (I-8) + (15.15), (I-8) + (15.16), (I-8) + (15.17), (I-8) + (15.18), (I-8) + (15.19), (I-8) + (15.20), (I-8) + (15.21), (I-8) + (15.22), (I-8) + (15.23), (I-8) + (15.24), (I-8) + (15.25), (I-8) + (15.26), (I-8) + (15.27), (I-8) + (15.28), (I-8) + (15.29), (I-8) + (15.30), (I-8) + (15.31), (I-8) + (15.32), (I-8) + (15.33), (I-8) + (15.34), (I-8) + (15.35), (I-8) + (15.36), (I-8) + (15.37), (I-8) + (15.38), (I-8) + (15.39), (I-8) + (15.41), (I-8) + (15.42), (I-8) + (15.43), (I-8) + (15.44), (I-8) + (15.45), (I-8) + (15.46), (I-8) + (15.47), (I-8) + (15.48), (I-8) +(15.49), (I-8) + (15.50), (I-8) + (15.51), (I-8) + (15.52), (I-8) + (15.53), (I-8) + (15.54), (I-8) + (15.55), (I-8) + (15.56), (I-8) + (15.57), (I-8) + (15.58), (I-8) + (15.59), (I-8) + (15.60), (I-8) + (15.61), (I-8) + (15.62), (I-8) + (15.63), (I-8) + (15.64), (I-8) + (15.65), (I-8) + (15.66), (I-8) + (15.67), (I-8) + (15.68), (I-8) + (15.69), (I-8) + (15.70), (I-8) + (15.71), (I-8) + (15.72), (I-8) + (15.73), (I-8) + (15.74), (I-8) + (15.75), (I-8) + (15.76), (I-8) + (15.77), (I-8) + (15.78), (I-8) + (15.79), (I-8) + (15.80), (I-8) + (15.81), (I-8) + (15.82), (I-8) + (15.83), (I-8) + (15.84), (I-8) + (15.85), (I-8) + (15.86), (I-8) + (15.87), (I-8) + (15.88), (I-8) + (15.89), (I-8) + (15.90), (I-8) + (15.91), (I-8) + (15.92), (I-8) + (15.93), (I-8) + (15.94)[033] According to a preferred variant, the present invention is directed to mixtures comprising the compound (I-8), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures ( I-8) + (1.1), (I-8) + (1.2), (I-8) + (1.3), (I-8) + (1.4), (I-8) + (1.5), ( I-8) + (1.6), (I-8) + (1.7), (I-8) + (1.8), (I-8) + (1.9), (I-8) + (1.10), ( I-8) + (1.11), (I-8) + (1.12), (I-8) + (1.13), (I-8) + (1.14), (I-8) + (1.15), ( I-8) + (1.16), (I8) + (1.17), (I-8) + (1.18), (I-8) + (1.19), (I-8) + (1.20), (I- 8) + (1.21), (I-8) + (1.22), (I-8) + (1.23), (I8) + (1.24), (I-8) + (1.25), (I-8) + (1.26), (I-8) + (1.27), (I-8) + (1.28), (I-8) + (1.29), (I-8) + (1.30), (I8) + ( 1.31), (I-8) + (1.32), (I-8) + (1.33), (I-8) + (1.34), (I-8) + (1.35), (I-8) + ( 1.36), (I-8) + (1.37), (I8) + (1.38), (I-8) + (1.39), (I-8) + (1.40), (I-8) + (1.41) , (I-8) + (1.42), (I-8) + (1.43), (I-8) + (1.44), (I8) + (1.45), (I-8) + (1.46), ( I-8) + (1.47), (I-8) + (1.48), (I-8) + (1.49), (I-8) + (1.50), (I-8) + (1.51), (I8) + (1.52), (I-8) + (1.53), (I-8) + (1.54), (I-8) + (1.55), (I -8) + (1.56), (I-8) + (1.57), (I-8) + (1.58), (I8) + (1.59), (I-8) + (1.60), (I-8 ) + (1.61), (I-8) + (1.62), (I-8) + (1.63), (I-8) + (1.64), (I-8) + (2.1), (I8) + (2.2), (I-8) + (2.3), (I-8) + (2.4), (I-8) + (2.5), (I-8) + (2.6), (I-8) + (2.7), (I-8) + (2.8), (I-8) + (2.9), (I-8) + (2.10), (I-8) + (2.11), (I-8) + (2.12), (I-8) + (2.13), (I-8) + (2.14), (I-8) + (2.15), (I-8) + (2.16), (I8) + (2.17 ), (I-8) + (2.18), (I-8) + (2.19), (I-8) + (2.20), (I-8) + (2.21), (I-8) + (2.22 ), (I-8) + (2.23), (I8) + (2.24), (I-8) + (2.25), (I-8) + (2.26), (I-8) + (2.27), (I-8) + (2.28), (I-8) + (2.29), (I-8) + (3.1), (I8) + (3.2), (I-8) + (3.3), (I -8) + (3.4), (I-8) + (3.5), (I-8) + (3.6), (I-8) + (3.7), (I-8) + (3.8), (I -8) + (3.9), (I-8) + (3.10), (I-8) + (3.11), (I-8) + (3.12), (I-8) + (3.13), (I -8) + (3.14), (I-8) + (3.15), (I-8) + (3.16), (I8) + (3.17), (I-8) + (3.18), (I-8 ) + (3.19), (I-8) + (3.20), (I-8) + (3.21), ( I-8) + (3.22), (I-8) + (3.23), (I8) + (3.24), (I-8) + (3.25), (I-8) + (3.26), (I- 8) + (3.27), (I-8) + (3.28), (I-8) + (3.29), (I-8) + (3.30), (I8) + (3.31), (I-8) + (3.32), (I-8) + (3.33), (I-8) + (4.1), (I-8) + (4.2), (I-8) + (4.3), (I-8) + (4.4), (I-8) + (4.5), (I-8) + (4.6), (I-8) + (4.7), (I-8) + (4.8), (I-8) + (4.9), (I-8) + (4.10), (I-8) + (4.11), (I-8) + (4.12), (I-8) + (4.13), (I-8) + (4.14), (I-8) + (5.1), (I-8) + (5.2), (I-8) + (5.3), (I-8) + (5.4), (I-8) + (5.5), (I-8) + (5.6), (I-8) + (5.7), (I-8) + (5.8), (I-8) + (5.9), (I-8) + (5.10), (I8) + (5.11), (I-8) + (5.12), (I-8) + (5.13), (I-8) + (5.14), (I-8) + ( 5.15), (I-8) + (5.16), (I-8) + (5.17), (I8) + (5.18), (I-8) + (5.19), (I-8) + (5.20) , (I-8) + (5.21), (I-8) + (5.22), (I-8) + (5.23), (I-8) + (5.24), (I8) + (5.25), ( I-8) + (5.26), (I-8) + (5.27), (I-8) + (5.28), (I-8) + (5.29), (I-8) + (5.30), ( I-8) + (5.31), (I8) + (5.32), (I-8) + (5.33), (I-8) + (5.34), (I-8) + (6.1), (I- 8) + (6.2), (I-8) + (6.3), (I-8) + (6.4), (I-8) + (7.1), (I-8) + (7.2), (I-8) + (7.3), (I-8) + (7.4), (I-8) + (7.5), (I-8) + (7.6), (I-8) + (7.7), (I-8) + (7.8), (I-8) + (8.1), (I-8) + (8.2), (I-8) + (8.3), (I-8) + (8.4), (I-8) + (9.1), (I-8) + (9.2), (I-8) + (9.3), (I-8) + (9.4), (I-8) + (9.5), (I-8) + (9.6), (I-8) + (9.7), (I-8) + (9.8), (I-8) + (9.9), (I-8) + (10.1), (I-8) + (10.2), (I-8) + (10.3), (I-8) + (10.4), (I-8) + (10.5), (I-8) + (10.6), (I-8) + (10.7), (I8) + (10.8), (I-8) + (10.9), (I-8) + ( 10.10), (I-8) + (10.11), (I-8) + (10.12), (I-8) + (10.13), (I-8) + (10.14), (I-8) + ( 10.15), (I-8) + (11.1), (I-8) + (11.2), (I-8) + (11.3), (I-8) + (11.4), (I-8) + ( 11.5), (I-8) + (11.6), (I8) + (11.7), (I-8) + (12.1), (I-8) + (12.2), (I-8) + (12.3) , (I-8) + (12.4), (I-8) + (12.5), (I-8) + (12.6), (I8) + (12.7), (I-8) + (12.8), ( I-8) + (12.9), (I-8) + (12.10), (I-8) + (12.11), (I-8) + (12.12), (I-8) + (12.13), ( I-8) + (13.1), (I-8) + (13.2), (I-8) + (13.3), (I-8) + (13.4), (I-8) + (13.5), ( I-8) + (13.6), (I-8) + (13.7), (I8) + (14. 1), (I-8) + (14.2), (I-8) + (14.3), (I-8) + (14.4), (I-8) + (14.5), (I-8) + ( 15.1), (I-8) + (15.2), (I8) + (15.3), (I-8) + (15.4), (I-8) + (15.5), (I-8) + (15.6) , (I-8) + (15.7), (I-8) + (15.8), (I-8) + (15.9), (I8) + (15.10), (I-8) + (15.11), ( I-8) + (15.12), (I-8) + (15.13), (I-8) + (15.14), (I-8) + (15.15), (I-8) + (15.16), ( I-8) + (15.17), (I-8) + (15.18), (I-8) + (15.19), (I-8) + (15.20), (I-8) + (15.21), ( I-8) + (15.22), (I-8) + (15.23), (I-8) + (15.24), (I-8) + (15.25), (I-8) + (15.26), ( I-8) + (15.27), (I-8) + (15.28), (I-8) + (15.29), (I-8) + (15.30), (I-8) + (15.31), ( I-8) + (15.32), (I-8) + (15.33), (I-8) + (15.34), (I-8) + (15.35), (I-8) + (15.36), ( I-8) + (15.37), (I-8) + (15.38), (I-8) + (15.39), (I-8) + (15.41), (I-8) + (15.42), ( I-8) + (15.43), (I-8) + (15.44), (I-8) + (15.45), (I-8) + (15.46), (I-8) + (15.47), ( I-8) + (15.48), (I-8) + (15.49), (I-8) + (15.50), (I-8) + (15.51), (I-8) + (15.52), ( I-8) + (15.53), (I-8) + (15.54), (I-8) + (15.55), (I-8) + (15.56), (I-8) + ( 15.57), (I-8) + (15.58), (I-8) + (15.59), (I-8) + (15.60), (I-8) + (15.61), (I-8) + ( 15.62), (I-8) + (15.63), (I-8) + (15.64), (I-8) + (15.65), (I-8) + (15.66), (I-8) + ( 15.67), (I-8) + (15.68), (I-8) + (15.69), (I-8) + (15.70), (I-8) + (15.71), (I-8) + ( 15.72), (I-8) + (15.73), (I-8) + (15.74), (I-8) + (15.75), (I-8) + (15.76), (I-8) + ( 15.77), (I-8) + (15.78), (I-8) + (15.79), (I-8) + (15.80), (I-8) + (15.81), (I-8) + ( 15.82), (I-8) + (15.83), (I-8) + (15.84), (I-8) + (15.85), (I-8) + (15.86), (I-8) + ( 15.87), (I-8) + (15.88), (I-8) + (15.89), (I-8) + (15.90), (I-8) + (15.91), (I-8) + ( 15.92), (I-8) + (15.93), (I-8) + (15.94)

[034] De acordo com uma outra variante particularmente preferida, a presente invenção é dirigida a misturas que compreendem o composto (I-8), enquanto composto de fórmula estrutural (I), e um componente (B) e, em particular, às misturas (I-8) + (2.1), (I-8) + (2.2), (I-8) + (2.6), (I-8) + (2.8), (I-8) + (2.11), (I-8) + (2.12), (I-8) + (2.13), (I-8) + (2.14), (I-8) + (2.15), (I-8) + (2.16), (I-8) + (2.17), (I-8) + (2.29), (I-8) + (3.1), (I-8) + (3.2), (I-8) + (3.3), (I-8) + (3.4), (I-8) + (3.9), (I-8) + (3.10), (I8) + (3.12), (I-8) + (3.16), (I-8) + (3.17), (I-8) + (3.22), (I-8) + (4.6), (I-8) + (5.1), (I-8) + (5.4), (I-8) + (5.5), (I-8) + (5.7), (I-8) + (5.8), (I-8) + (5.9), (I-8) + (5.16), (I-8) + (5.23), (I-8) + (5.25), (I-8) + (5.26), (I-8) + (5.29), (I-8) + (5.30), (I-8) + (7.7), (I-8) + (9.2), (I-8) + (9.4), (I-8) + (9.5), (I-8) + (10.9), (I-8) + (10.10), (I-8) + (12.9), (I-8) + (12.10), (I-8) + (14.4), (I-8) + (15.9), (I-8) + (15.24), (I-8) + (15.25), (I-8) +(15.26), (I-8) + (15.41), (I-8) + (15.42), (I-8) + (15.54), (I-8) + (15.55), (I-8) + (15.56), (I-8) + (15.60), (I-8) + (15.90).[034] According to another particularly preferred variant, the present invention is directed to mixtures comprising the compound (I-8), as a compound of structural formula (I), and a component (B) and, in particular, to mixtures (I-8) + (2.1), (I-8) + (2.2), (I-8) + (2.6), (I-8) + (2.8), (I-8) + (2.11) , (I-8) + (2.12), (I-8) + (2.13), (I-8) + (2.14), (I-8) + (2.15), (I-8) + (2.16) , (I-8) + (2.17), (I-8) + (2.29), (I-8) + (3.1), (I-8) + (3.2), (I-8) + (3.3) , (I-8) + (3.4), (I-8) + (3.9), (I-8) + (3.10), (I8) + (3.12), (I-8) + (3.16), ( I-8) + (3.17), (I-8) + (3.22), (I-8) + (4.6), (I-8) + (5.1), (I-8) + (5.4), ( I-8) + (5.5), (I-8) + (5.7), (I-8) + (5.8), (I-8) + (5.9), (I-8) + (5.16), ( I-8) + (5.23), (I-8) + (5.25), (I-8) + (5.26), (I-8) + (5.29), (I-8) + (5.30), ( I-8) + (7.7), (I-8) + (9.2), (I-8) + (9.4), (I-8) + (9.5), (I-8) + (10.9), ( I-8) + (10.10), (I-8) + (12.9), (I-8) + (12.10), (I-8) + (14.4), (I-8) + (15.9), ( I-8) + (15.24), (I-8) + (15.25), (I-8) + (15.26), (I-8) + (15. 41), (I-8) + (15.42), (I-8) + (15.54), (I-8) + (15.55), (I-8) + (15.56), (I-8) + ( 15.60), (I-8) + (15.90).

[035] Caso os compostos ativos nas combinações de compostos ativos de acordo com a invenção estejam presentes em determinadas proporções em peso, então o efeito sinergístico é particularmente pronunciado. No entanto, as proporções em peso dos compostos ativos nas combinações de compostos ativos podem variar em um intervalo relativamente alargado.[035] If the active compounds in the combinations of active compounds according to the invention are present in certain proportions by weight, then the synergistic effect is particularly pronounced. However, the weight ratios of the active compounds in the active compound combinations can vary over a relatively wide range.

[036] Nas combinações de acordo com a invenção, os compostos (A) e (B) estão presentes em uma proporção em peso sinergisticamente eficaz entre A:B compreendida entre 500:1 e 1:5000, de preferência, em uma proporção em peso entre 300:1 e 1:2000 e, mais preferencialmente, em uma proporção em peso entre 200:1 e 1:1000. Como outras proporções entre A:B que é possível utilizar de acordo com a presente invenção com preferência crescente na ordem apresentada refere-se: 250:1 a 1:250, 220:1 a 1:220, 200:1 a 1:200, 170:1 a 1:170, 140:1 a 1:140, 120:1 a 1:120, 100:1 a 1:100, 95:1 a 1:95, 90:1 a 1:90, 85:1 a 1:85, 80:1 a 1:80, 75:1 a 1:75, 70:1 a 1:70, 65:1 a 1:65, 60:1 a 1:60, 55:1 a 1:55, 45:1 a 1:45, 40:1 a 1:40, 35:1 a 1:35, 30:1 a 1:30, 25:1 a 1:25, 15:1 a 1:15, 10:1 a 1:10, 5:1 a 1:5, 4:1 a 1:4, 3:1 a 1:3, 2:1 a 1:2.[036] In the combinations according to the invention, compounds (A) and (B) are present in a synergistically effective weight ratio between A: B comprised between 500: 1 and 1: 5000, preferably in a proportion in weight between 300: 1 and 1: 2000 and, more preferably, in a weight ratio between 200: 1 and 1: 1000. As other proportions between A: B that can be used according to the present invention with increasing preference in the order presented refer to: 250: 1 to 1: 250, 220: 1 to 1: 220, 200: 1 to 1: 200 , 170: 1 to 1: 170, 140: 1 to 1: 140, 120: 1 to 1: 120, 100: 1 to 1: 100, 95: 1 to 1:95, 90: 1 to 1:90, 85 : 1 to 1:85, 80: 1 to 1:80, 75: 1 to 1:75, 70: 1 to 1:70, 65: 1 to 1:65, 60: 1 to 1:60, 55: 1 to 1:55, 45: 1 to 1:45, 40: 1 to 1:40, 35: 1 to 1:35, 30: 1 to 1:30, 25: 1 to 1:25, 15: 1 to 1 : 15, 10: 1 to 1:10, 5: 1 to 1: 5, 4: 1 to 1: 4, 3: 1 to 1: 3, 2: 1 to 1: 2.

[037] Como outras proporções preferidas entre A:B que é possível utilizar de acordo com a presente invenção refere- se: 1:1 a 1:5000, 1:1 a 1:2000, 1:1 a 1:1000, 1:10 a 1:5000, 1:10 a 1:2000, 1:10 a 1:1000, 1:20 a 1:5000, 1:20 a 1:2000, 1:20 a 1:1000, 1:100 a 1:5000, 1:100 a 1:2000, 1:100 a 1:1000, 1:200 a 1:5000, 1:200 a 1:2000, 1:200 a 1:1000, 1:500 a 1:5000, 1:500 a 1:2000, 1:500 a 1:1000.[037] Other preferred ratios between A: B that can be used according to the present invention include: 1: 1 to 1: 5000, 1: 1 to 1: 2000, 1: 1 to 1: 1000, 1 : 10 to 1: 5000, 1:10 to 1: 2000, 1:10 to 1: 1000, 1:20 to 1: 5000, 1:20 to 1: 2000, 1:20 to 1: 1000, 1: 100 to 1: 5000, 1: 100 to 1: 2000, 1: 100 to 1: 1000, 1: 200 to 1: 5000, 1: 200 to 1: 2000, 1: 200 to 1: 1000, 1: 500 to 1 : 5000, 1: 500 to 1: 2000, 1: 500 to 1: 1000.

[038] Como outras proporções preferidas entre A:B que é possível utilizar de acordo com a presente invenção refere- se: 500:1 a 1:50, 500:1 a 1:2, 500:1 a 10:1, 500:1 a 20:1, 500:1 a 100:1, 300:1 a 1:50, 300:1 a 1:2, 300:1 a 10:1, 300:1 a 20:1, 300:1 a 100:1, 250:1 a 1:50, 250:1 a 1:2, 250:1 a 10:1, 250:1 a 20:1, 250:1 a 100:1, 200:1 a 1:50, 200:1 a 1:2, 200:1 a 10:1, 200:1 a 20:1, 200:1 a 100:1.[038] As other preferred proportions between A: B that can be used according to the present invention are: 500: 1 to 1:50, 500: 1 to 1: 2, 500: 1 to 10: 1, 500 : 1 to 20: 1, 500: 1 to 100: 1, 300: 1 to 1:50, 300: 1 to 1: 2, 300: 1 to 10: 1, 300: 1 to 20: 1, 300: 1 to 100: 1, 250: 1 to 1:50, 250: 1 to 1: 2, 250: 1 to 10: 1, 250: 1 to 20: 1, 250: 1 to 100: 1, 200: 1 to 1 : 50, 200: 1 to 1: 2, 200: 1 to 10: 1, 200: 1 to 20: 1, 200: 1 to 100: 1.

[039] Quando um composto (A) ou um composto (B) possa estar presente como misturas de várias formas isoméricas possíveis, em particular, de estereoisómeros, tais como, por exemplo, isómeros E e Z, isómeros treo e eritro e também isómeros ópticos, e, se adequado, também como tautómeros, então são reivindicados os isómeros E e Z e os isómeros treo e eritro e também os isómeros ópticos (R e S), quaisquer misturas destes isómeros, bem como as formas tautoméricas possíveis.[039] When a compound (A) or a compound (B) can be present as mixtures of several possible isomeric forms, in particular, of stereoisomers, such as, for example, E and Z isomers, threus and erythro isomers and also isomers optical, and, if appropriate, also as tautomers, then the E and Z isomers and the threus and erythro isomers and also the optical isomers (R and S) are claimed, any mixtures of these isomers, as well as the possible tautomeric forms.

[040] Os compostos (A) ou compostos (B) que possuam pelo menos um centro básico são capazes de formar, por exemplo, sais de adição de ácido, v.g., com ácidos inorgânicos fortes, tais como ácidos minerais, v.g., ácido perclórico, ácido sulfúrico, ácido nítrico, ácido nitroso, ácido fosfórico ou ácido hidro-hálico, com ácidos carboxílicos orgânicos fortes, tais como ácidos alcano(C1-C4)- carboxílicos não substituídos ou substituídos, v.g., substituídos com halo, v.g., ácido acético, ácidos dicarboxílico saturados ou insaturados, v.g., ácido oxálico, malónico, succínico, maleico, fumárico e ftálico, ácidos hidroxicarboxílicos, v.g., ácido ascórbico, láctico, málico, tartárico e cítrico, ou ácido benzoico, ou com ácidos orgânicos sulfônicos, tais como ácidos alcano(C1-C4)- ou aril-sulfônicos substituídos ou não substituídos, v.g., substituídos com halo, por exemplo, ácido metano- ou p- tolueno-sulfônico. Os compostos (A) ou compostos (B) que possuam pelo menos um grupo ácido são capazes de formar, por exemplo, sais com bases, v.g., sais metálicos, tais como sais de metais alcalinos ou de metais alcalino- terrosos, v.g., sais de sódio, potássio ou magnésio, ou sais com amónia ou com uma amina orgânica, tais como morfolina, piperidina, pirrolidina, uma mono-, di- ou tri- (alquil inferior)-amina, v.g., etil-, dietil-, trietil- ou dimetil-propil-amina, ou uma mono-, di- ou tri-hidroxi- (alquil inferior)-amina, v.g., mono-, di- ou tri- etanolamina. Além disso, facultativamente, é possível formar os sais internos correspondentes. No contexto da invenção, são preferidos sais vantajosos sob o ponto de vista agroquímico. À luz da relação próxima entre os compostos (A) ou os compostos (B) na forma livre e na forma dos seus sais, aqui anterior e posteriormente, qualquer referência aos compostos livres (A) ou aos compostos livres (B) ou aos seus sais deverá compreender também os sais correspondentes ou os compostos livres (A) ou compostos livres (B), respectivamente, quando tal seja adequado e expediente. O equivalente também se aplica aos tautómeros dos compostos (A) ou dos compostos (B) e aos seus sais.[040] Compounds (A) or compounds (B) having at least one basic center are capable of forming, for example, acid addition salts, eg, with strong inorganic acids, such as mineral acids, eg, perchloric acid , sulfuric acid, nitric acid, nitrous acid, phosphoric acid or hydrohalic acid, with strong organic carboxylic acids, such as (C1-C4) alkane - unsubstituted or substituted carboxylic acids, eg, substituted with halo, eg, acetic acid , saturated or unsaturated dicarboxylic acids, eg oxalic, malonic, succinic, maleic, fumaric and phthalic acid, hydroxycarboxylic acids, eg ascorbic, lactic, malic, tartaric and citric acid, or benzoic acid, or with organic sulfonic acids, such as alkane (C1-C4) acids - or substituted or unsubstituted aryl sulfonic acids, eg, substituted with halo, for example, methane- or p-toluenesulfonic acid. Compounds (A) or compounds (B) which have at least one acid group are capable of forming, for example, salts with bases, eg metal salts, such as alkali metal or alkaline earth metal salts, eg, salts sodium, potassium or magnesium, or salts with ammonia or with an organic amine, such as morpholine, piperidine, pyrrolidine, a mono-, di- or tri- (lower alkyl) -amine, eg, ethyl-, diethyl-, triethyl - or dimethyl-propyl-amine, or a mono-, di- or trihydroxy- (lower alkyl) -amine, eg, mono-, di- or tri-ethanolamine. In addition, optionally, it is possible to form the corresponding internal salts. In the context of the invention, agrochemical advantageous salts are preferred. In light of the close relationship between compounds (A) or compounds (B) in free form and in the form of their salts, here before and after, any reference to free compounds (A) or free compounds (B) or their compounds salts should also comprise the corresponding salts or free compounds (A) or free compounds (B), respectively, when appropriate and expedient. The equivalent also applies to the tautomers of compounds (A) or compounds (B) and their salts.

[041] De acordo com a invenção, a expressão “combinação” designa as várias combinações de compostos (A) e (B), por exemplo, em uma forma de “mistura pronta a utilizar” individual, em uma mistura combinada para pulverização constituída por formulações separadas dos compostos ativos individuais, tais como uma “mistura de tanque”, e em uma utilização combinada dos ingredientes ativos individuais quando aplicados de um modo sequencial, isto é, um após o outro em um período de tempo relativamente curto, tal como algumas horas ou dias. De preferência, a ordem para a aplicação dos compostos (A) e (B) não é importante para o funcionamento da presente invenção.[041] According to the invention, the term "combination" means the various combinations of compounds (A) and (B), for example, in an individual "ready-to-use mixture" form, in a combined mixture for spraying by separate formulations of the individual active compounds, such as a “tank mix”, and in a combined use of the individual active ingredients when applied in a sequential manner, that is, one after the other in a relatively short period of time, such as a few hours or days. Preferably, the order for the application of compounds (A) and (B) is not important for the functioning of the present invention.

Composição / FormulaçãoComposition / Formulation

[042] Além do mais, a presente invenção diz respeito a composição para o combate/controle de microrganismos indesejáveis que compreendem as combinações de compostos ativos de acordo com a invenção. De preferência, as composições são composições fungicidas que compreendem auxiliares, solventes, veículos, tensioativos e cargas adequados sob o ponto de vista agrícola.[042] Furthermore, the present invention relates to the composition for combating / controlling undesirable microorganisms comprising the combinations of active compounds according to the invention. Preferably, the compositions are fungicidal compositions comprising agriculturally suitable auxiliaries, solvents, vehicles, surfactants and fillers.

[043] No contexto da presente invenção, a expressão “controle de microrganismos prejudiciais” designa uma redução na infestação pelos microrganismos prejudiciais, em comparação com a planta não tratada, medido como eficácia fungicida, de preferência uma redução de 25% a 50% em comparação com a planta não tratada (100%), mais preferencialmente, uma redução de 40% a 79% em comparação com a planta não tratada e, ainda mais preferencialmente, a infecção pelos microrganismos prejudiciais é completamente suprimida (de 70% a 100%). O controle pode ser curativo, isto é para o tratamento de plantas já infectadas, ou protectivo, para a protecção de plantas que não foram ainda infectadas.[043] In the context of the present invention, the term "control of harmful microorganisms" means a reduction in infestation by harmful microorganisms, compared to the untreated plant, measured as fungicidal efficacy, preferably a 25% to 50% reduction in compared to the untreated plant (100%), more preferably, a 40% to 79% reduction compared to the untreated plant and, even more preferably, the infection by harmful microorganisms is completely suppressed (from 70% to 100% ). The control can be curative, that is, for the treatment of plants already infected, or protective, for the protection of plants that have not yet been infected.

[044] A expressão “quantidade eficaz mas não fitotóxica” designa uma quantidade da composição da invenção que é suficiente para controlar a doença fúngica da planta de um modo satisfatório ou para erradicar a doença fúngica completamente e que, em simultâneo, não causa quaisquer sintomas significativos de fitotoxicidade. De um modo geral, esta taxa de aplicação pode variar em um intervalo relativamente alargado. Esta depende de diversos fatores, por exemplo, do fungo que se pretende controlar, da planta, das condições climáticas e dos ingredientes das composições da invenção.[044] The term "effective but not phytotoxic amount" means an amount of the composition of the invention that is sufficient to satisfactorily control fungal disease of the plant or to eradicate fungal disease completely and, at the same time, does not cause any symptoms phytotoxicity. In general, this application rate can vary over a relatively wide range. This depends on several factors, for example, the fungus to be controlled, the plant, the climatic conditions and the ingredients of the compositions of the invention.

[045] Como solventes orgânicos adequados refere-se todos os solventes orgânicos polares e não polares normalmente utilizados para propósitos de formulação. Como solventes preferidos refere-se os seecionados entre cetonas, v.g., metil-isobutil-cetona e ciclo-hexanona, amidas, v.g., dimetilformamida e amidas de ácido alcanocarboxílico, v.g., N,N-dimetildecanoamida e N,N-dimetiloctanamida, também solventes cíclicos, v.g., N-metil-pirrolidona, N-octil- pirrolidona, N-dodecil-pirrolidona, N-octil-caprolactama, N-dodecil-caprolactama e butirolactona, bem como solventes polares fortes, v.g., sulfóxido de dimetila, e hidrocarbonetos aromáticos, v.g., xilol, Solvesso™, óleos minerais, v.g., essência branca, petróleo, alquilbenzenos e óleos para máquinas, também ésteres, v.g., acetato de éter monometílico de propilenoglicol, éster dibutílico de ácido adípico, éster hexílico de ácido acético, éster heptílico de ácido acético, éster tri-n-butílico de ácido cítrico e éster di-n-butílico de ácido ftálico, e também álcoois, v.g., álcool benzílico e 1-metoxi-2-propanol.[045] Suitable organic solvents include all polar and non-polar organic solvents normally used for formulation purposes. Preferred solvents include those divided between ketones, eg, methyl isobutyl ketone and cyclohexanone, amides, eg, dimethylformamide and amides of alkanecarboxylic acid, eg, N, N-dimethyldecanoamide and N, N-dimethyloctanamide, also solvents cyclic, eg, N-methyl-pyrrolidone, N-octyl-pyrrolidone, N-dodecyl-pyrrolidone, N-octyl-caprolactam, N-dodecyl-caprolactam and butyrolactone, as well as strong polar solvents, eg, dimethyl sulfoxide, and hydrocarbons aromatics, eg, xylol, Solvesso ™, mineral oils, eg white essence, petroleum, alkylbenzenes and machine oils, also esters, eg, propylene glycol monomethyl ether acetate, adipic acid dibutyl ester, acetic acid hexyl ester, ester heptyl acetic acid, citric acid tri-n-butyl ester and phthalic acid di-n-butyl ester, and also alcohols, eg, benzyl alcohol and 1-methoxy-2-propanol.

[046] Além disso, a invenção diz respeito a um método para combater microrganismos indesejáveis, o qual é caracterizado pelo fato de se aplicarem as combinações de compostos ativos de acordo com a invenção aos fungos fitopatogénicos e/ou ao seu habitat.[046] In addition, the invention relates to a method for combating undesirable microorganisms, which is characterized by the fact that the combinations of active compounds according to the invention are applied to phytopathogenic fungi and / or their habitat.

[047] De acordo com a invenção, como veículo pretende-se designar uma substância orgânica ou inorgânica, natural ou sintética, que é misturada ou combinada com os compostos ativos para se obter uma melhor aplicabilidade, em particular, para aplicação a plantas ou partes de plantas ou a sementes. o veículo, o qual pode ser sólido ou líquido, é normalmente inerte e deverá ser adequado para utilização em agricultura.[047] According to the invention, the vehicle is intended to designate an organic or inorganic substance, natural or synthetic, which is mixed or combined with the active compounds to obtain a better applicability, in particular, for application to plants or parts plants or seeds. the vehicle, which can be solid or liquid, is normally inert and should be suitable for use in agriculture.

[048] Como veículos sólidos ou líquidos úteis refere-se: por exemplo, sais de amónio e poeiras de rochas naturais, tais como caolinas, argilas, talco, giz, quartzo, atapulgite, montmorilonite ou terra de diatomáceas, e poeiras de rochas sintéticas, tais como sílica finamente dividida, óxido de alumínio e silicatos naturais ou sintéticos, resinas, ceras, fertilizantes sólidos, água, álcoois, em particular, butanol, solventes orgânicos, óleos minerais e vegetais, e seus derivados. De igual modo, é possível utilizar misturas destes veículos.[048] Useful solid or liquid vehicles include: for example, ammonium salts and natural rock dust, such as kaolin, clays, talc, chalk, quartz, atapulgite, montmorillonite or diatomaceous earth, and synthetic rock dust , such as finely divided silica, aluminum oxide and natural or synthetic silicates, resins, waxes, solid fertilizers, water, alcohols, in particular, butanol, organic solvents, mineral and vegetable oils, and their derivatives. Likewise, it is possible to use mixtures of these vehicles.

[049] Como cargas ou veículos sólidos adequados refere-se partículas inorgânicas, v.g., carbonatos, silicatos, sulfatos e óxidos com um tamanho de partícula médio compreendido entre 0,005 e 20 μm e, de preferência, entre 0,02 e 10 μm, por exemplo, sulfato de amónio, fosfato de amónio, ureia, carbonato de cálcio, sulfato de cálcio, sulfato de magnésio, óxido de magnésio, óxido de alumínio, dióxido de silício, as designadas partículas finas de sílica, geles de sílica, silicatos naturais ou sintéticos e alumino-silicatos e produtos de plantas, tais como farinhas de cereais, madeira em pó/serradura e pó de celulose.[049] Suitable solid loads or vehicles include inorganic particles, eg, carbonates, silicates, sulphates and oxides with an average particle size between 0.005 and 20 μm and preferably between 0.02 and 10 μm, for example example, ammonium sulfate, ammonium phosphate, urea, calcium carbonate, calcium sulfate, magnesium sulfate, magnesium oxide, aluminum oxide, silicon dioxide, so-called fine particles of silica, silica gels, natural silicates or synthetic and aluminum-silicates and plant products such as cereal flours, wood powder / sawdust and cellulose powder.

[050] Como veículos sólidos úteis para grânulos refere- se: por exemplo, rochas naturais esmagadas ou fracionadas, tais como calcite, mármore, pedra-pomes, sepiolite, dolomite e grânulos sintéticos de farinhas inorgânicas ou orgânicas, bem como grânulos de materiais orgânicos, tais como serradura, cascas de coco, espigas de milho e caules de tabaco.[050] As solid vehicles useful for granules are: for example, crushed or fractionated natural rocks, such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic or organic flours, as well as granules of organic materials , such as sawdust, coconut shells, corn cobs and tobacco stems.

[051] Como cargas ou veículos gasosos liquefeitos úteis refere-se aqueles líquidos que são gasosos à temperatura padrão e sob pressão padrão, por exemplo, propulsores de aerossóis, tais como hidrocarbonetos halogenados, bem como butano, propano, azoto e dióxido de carbono.[051] Useful liquids or gaseous vehicles are those liquids that are gaseous at standard temperature and standard pressure, for example aerosol propellants such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.

[052] Nas formulações é possível utilizar adesivos, tais como carboximetil-celulose, e polímeros naturais e sintéticos sob a forma de pós, grânulos ou aglomerados, tais como goma-arábica, álcool polivinílico, ou então fosfolípidos naturais, tais como cefalinas e lecitinas, e fosfolípidos sintéticos. Outros aditivos podem ser óleos minerais e vegetais.[052] It is possible to use adhesives, such as carboxymethylcellulose, and natural and synthetic polymers in the form of powders, granules or agglomerates, such as gum arabic, polyvinyl alcohol, or natural phospholipids, such as cephalins and lecithins. , and synthetic phospholipids. Other additives can be mineral and vegetable oils.

[053] Caso a carga utilizada seja a água, então é possível utilizar, por exemplo, solventes orgânicos como solventes auxiliares. Como solventes líquidos adequados refere-se, essencialmente: compostos aromáticos, tais como xileno, tolueno ou alquilnaftalenos, compostos aromáticos clorados ou compostos alifáticos clorados, tais como clorobenzenos, cloroetilenos ou cloreto de metileno, hidrocarbonetos alifáticos, tais como ciclo-hexano ou parafinas, por exemplo, fracções de óleos minerais, óleos minerais ou vegetais, álcoois, tais como butanol ou glicol, e também seus éteres e ésteres, cetonas, tais como acetona, metil-etil-cetona, metil-isobutil-cetona ou ciclo-hexanona, solventes fortemente polares, tais como dimetilformamida e sulfóxido de dimetila, e também água.[053] If the charge used is water, then it is possible to use, for example, organic solvents as auxiliary solvents. Suitable liquid solvents are essentially: aromatic compounds, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic compounds or chlorinated aliphatic compounds, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example, fractions of mineral oils, mineral or vegetable oils, alcohols, such as butanol or glycol, and also their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, and also water.

[054] As composições de acordo com a invenção podem compreender outros componentes suplementares, tais como, por exemplo, tensioativos. Como tensioativos adequados refere-se emulsificantes, dispersantes ou agentes humectantes que possuam propriedades iónicas ou não iónicas, ou misturas destes tensioativos. Como exemplos destes refere-se sais de ácido poliacrílico, sais de ácido ligno-sulfônico, sais de ácido fenolsulfônico ou de ácido naftaleno-sulfônico, policondensados de óxido de etileno com álcoois gordos ou com aminas gordas, fenóis substituídos (de preferência, alquilfenóis ou arilfenóis), sais de ésteres sulfo-succínicos, derivados de taurina (de preferência, tauratos de alquila), ésteres fosfóricos de álcoois ou fenóis polietoxilados, ésteres gordos de polióis e derivados de compostos que contenham sulfatos, sulfonatos e fosfatos. A presença de um tensioativo é necessária no caso de um dos compostos ativos e/ou de um dos veículos inertes ser insolúvel em água, quando a aplicação tem lugar em água. A proporção de tensioativo está compreendida entre 5% e 40% em peso da composição de acordo com a invenção.[054] The compositions according to the invention can comprise other supplementary components, such as, for example, surfactants. Suitable surfactants include emulsifiers, dispersants or wetting agents that have ionic or nonionic properties, or mixtures of these surfactants. Examples of these include salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty amines, substituted phenols (preferably alkylphenols or arylphenols), salts of sulfo-succinic esters, taurine derivatives (preferably alkyl taurates), phosphoric esters of polyethoxylated alcohols or phenols, fatty esters of polyols and derivatives of compounds containing sulphates, sulphonates and phosphates. The presence of a surfactant is necessary if one of the active compounds and / or one of the inert vehicles is insoluble in water, when the application takes place in water. The proportion of surfactant is between 5% and 40% by weight of the composition according to the invention.

[055] Como tensioativos adequados (adjuvantes, emulsificantes, dispersantes, colóides protectores, agentes humectantes e adesivos) refere-se todas as substâncias iónicas e não iónicas comuns, por exemplo, nonilfenóis etoxilados, éter polialquileno-glicólico de álcoois lineares ou ramificados, produtos de reação de alquilfenóis com óxido de etileno e/ou óxido de propileno, produtos de reação de aminas de ácidos gordos com óxido de etileno e/ou óxido de propileno, também ésteres de ácidos gordos, sulfonatos de alquila, sulfatos de alquila, éter-sulfatos de alquila, éter-fosfatos de alquila, sulfato de arila, arilalquilfenóis etoxilados, v.g., etoxilados de tristiril- fenol, bem como arilalquilfenóis etoxilados e propoxilados, tais como etoxilatos e propoxilatos de arilalquilfenol sulfatados ou fosfatados. Como outros exemplos refere-se polímeros solúveis em água, naturais ou sintéticos, v.g., ligno-sulfonatos, gelatina, goma-arábica, fosfolípidos, amido, amido modificado hidrofóbico e derivados de celulose, em particular, éster de celulose e éter de celulose, bem como álcool polivinílico, acetato de polivinila, polivinilpirrolidona, ácido poliacrílico, ácido polimetacrílico e co-polimeriases de ácido (met)acrílico e ésteres de ácido (met)acrílico, bem como co-polimerisatos de ácido metacrílico e de ésteres de ácido metacrílico que são neutralizados com hidróxidos de metais alcalinos e também produtos de condensação de sais de ácido naftaleno- sulfônico facultativamente substituído com formaldeído.[055] Suitable surfactants (adjuvants, emulsifiers, dispersants, protective colloids, wetting agents and adhesives) include all common ionic and non-ionic substances, for example, ethoxylated nonylphenols, linear or branched polyalkylene glycol ether, products reaction of alkylphenols with ethylene oxide and / or propylene oxide, reaction products of fatty acid amines with ethylene oxide and / or propylene oxide, also esters of fatty acids, alkyl sulfonates, alkyl sulfates, ether- alkyl sulfates, alkyl ether phosphates, aryl sulfate, ethoxylated arylalkylphenols, eg, tristyrylphenol ethoxylates, as well as ethoxylated and propoxylated arylalkylphenols, such as sulfated or phosphateed arylalkylphenyl ethoxylates and propoxylates. Other examples include water-soluble polymers, natural or synthetic, eg, lignosulphonates, gelatin, gum arabic, phospholipids, starch, hydrophobic modified starch and cellulose derivatives, in particular cellulose ester and cellulose ether, as well as polyvinyl alcohol, polyvinyl acetate, polyvinylpyrrolidone, polyacrylic acid, polymethacrylic acid and co-polymerases of (meth) acrylic acid and (meth) acrylic acid esters, as well as co-polymerases of methacrylic acid and methacrylic acid esters that they are neutralized with alkali metal hydroxides and also products of condensation of salts of naphthalenesulfonic acid optionally substituted with formaldehyde.

[056] É possível utilizar corantes tais como pigmentos inorgânicos, por exemplo, óxido de ferro, óxido de titânio, azul da Prússia, e corantes orgânicos, tais como corantes de alizarina, corantes azo e corantes de ftalocianina de metal, e nutrientes vestigiais, tais como sais de ferro, manganês, boro, cobre, cobalto, molibdénio e zinco.[056] It is possible to use dyes such as inorganic pigments, for example, iron oxide, titanium oxide, Prussian blue, and organic dyes, such as alizarin dyes, azo dyes and metal phthalocyanine dyes, and trace nutrients, such as iron, manganese, boron, copper, cobalt, molybdenum and zinc salts.

[057] Como anti-espumantes que podem estar presentes nas formulações refere-se, v.g., emulsões de silicone, álcoois de cadeias grandes, ácidos gordos e seus sais, bem como substâncias flúor-orgânicas, e suas misturas.[057] The defoamers that may be present in the formulations include, e.g., silicone emulsions, large-chain alcohols, fatty acids and their salts, as well as fluorine-organic substances, and mixtures thereof.

[058] Como exemplos de espessantes refere-se polissacáridos, v.g., goma de xantano ou goma V, silicatos, v.g., atapulgite, bentonite, bem como partículas finas de sílica.[058] Examples of thickeners include polysaccharides, e.g., xanthan gum or gum V, silicates, e.g., atapulgite, bentonite, as well as fine silica particles.

[059] Se adequado, também podem estar presentes outros componentes adicionais, por exemplo, colóides protectores, aglutinantes, adesivos, espessantes, substâncias tixotrópicas, penetrantes, estabilizadores, agentes sequestrantes, formadores de complexos. De um modo geral, os compostos ativos podem ser combinados com qualquer aditivo sólido ou líquido habitualmente utilizado para propósitos de formulação.[059] If appropriate, other additional components may also be present, for example, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetrants, stabilizers, sequestering agents, complexing agents. In general, the active compounds can be combined with any solid or liquid additive commonly used for formulation purposes.

[060] As composições da invenção podem ser utilizadas tal qual ou, dependendo das suas propriedades físicas e/ou químicas particulares, sob a forma das suas formulações ou sob formas de utilização preparadas a partir destas, tais como aerossóis, suspensões em cápsula, concentrados de neblina fria, concentrados de neblina quente, grânulos encapsulados, grânulos finos, concentrados fluidificáveis para o tratamento de sementes, soluções prontas a utilizar, pós para polvilhamento, concentrados emulsionáveis, emulsões de óleo em água, emulsões de água em óleo, macrogânulos, microgânulos, pós dispersáveis em óleo, concentrados fluidificáveis miscíveis em óleo, líquidos miscíveis em óleo, gás (sob pressão), produtos para a geração de gás, espumas, pastas, sementes revestidas com pesticida, concentrados em suspensão, concentrados em suspo-emulsão, concentrados solúveis, suspensões, pós humectáveis, pós solúveis, poeiras e grânulos, grânulos ou comprimidos solúveis em água e dispersáveis em água, pós solúveis em água e dispersáveis em água para o tratamento de sementes, pós humectáveis, produtos naturais e substâncias sintéticas impregnadas com ingrediente ativo, e também microencapsulações em substâncias poliméricas e em materiais de revestimento para sementes, bem como formulações ULV de nebulização a frio e de nebulização a quente.[060] The compositions of the invention can be used as is or, depending on their particular physical and / or chemical properties, in the form of their formulations or in forms of use prepared from them, such as aerosols, capsule suspensions, concentrates cold mist, hot mist concentrates, encapsulated granules, fine granules, fluidizable concentrates for seed treatment, ready-to-use solutions, dusting powders, emulsifiable concentrates, oil-in-water emulsions, water-in-oil emulsions, macrogranules, microgranules , oil-dispersible powders, oil-miscible fluidizable concentrates, oil-miscible liquids, gas (under pressure), products for gas generation, foams, pastes, pesticide-coated seeds, suspension concentrates, suspo-emulsion concentrates, concentrates soluble, suspensions, humectable powders, soluble powders, dust and granules, granules or tablets soluble in water and dispersible in water a, water-soluble and water-dispersible powders for the treatment of seeds, wettable powders, natural products and synthetic substances impregnated with active ingredient, and also microencapsulations in polymeric substances and in seed coating materials, as well as ULV nebulization formulations a cold and hot fogging.

[061] As composições da invenção compreendem não só formulações prontas a utilizar e que podem ser aplicadas com um aparelho adequado à planta ou à semente, mas também concentrados comerciais que têm de ser diluídos com água antes da utilização. Como aplicações convencionais refere- se, por exemplo, diluição em água e subsequente pulverização das águas-mãe de pulverização resultantes, aplicação após diluição em óleo, aplicação directa sem diluição, tratamento de sementes ou aplicação de grânulos ao solo.[061] The compositions of the invention comprise not only ready-to-use formulations that can be applied with an apparatus suitable for the plant or seed, but also commercial concentrates that must be diluted with water before use. Conventional applications include, for example, dilution in water and subsequent spraying of the resulting spray water, application after dilution in oil, direct application without dilution, seed treatment or application of granules to the soil.

[062] De um modo geral, as composições de acordo com a invenção compreendem entre 0,05% e 99% em peso, 0,01% e 98% em peso, de preferência, entre 0,1% e 95% em peso, mais preferencialmente, entre 0,5% e 90% em peso da combinação de compostos ativos de acordo com a invenção e, ainda mais preferencialmente, entre 10% e 70% em peso.[062] In general, the compositions according to the invention comprise between 0.05% and 99% by weight, 0.01% and 98% by weight, preferably between 0.1% and 95% by weight , more preferably, between 0.5% and 90% by weight of the combination of active compounds according to the invention and, even more preferably, between 10% and 70% by weight.

[063] Os teores em ingredientes ativos nas formas de aplicação preparadas a partir de formulações comerciais podem variar em um intervalo amplo. A concentração em ingredientes ativos nas formas de aplicação está normalmente compreendida entre 0,000001% e 95% em peso e, de preferência, entre 0,0001% e 2% em peso.[063] The levels of active ingredients in application forms prepared from commercial formulations can vary over a wide range. The concentration of active ingredients in the application forms is normally between 0.000001% and 95% by weight and preferably between 0.0001% and 2% by weight.

[064] As formulações mencionadas podem ser preparadas de um modo conhecido per se, por exemplo, por mistura dos ingredientes ativos com pelo menos uma carga, solvente ou diluente, adjuvante, emulsificantes, dispersante e/ou aglutinante ou fixador, agente humectante, repelente de água, se adequado dessecantes e estabilizadores de UV e, se adequado, corantes e pigmentos, anti-espumantes, conservantes, espessantes inorgânicos e orgânicos, adesivos, giberelinas e também outros auxiliares de processamento convencionais, bem como água. Em função do tipo de formulação a preparar, podem ser necessários outros passos de processamento, v.g., moagem a húmido, moagem a seco e granulação.[064] The mentioned formulations can be prepared in a manner known per se, for example, by mixing the active ingredients with at least one filler, solvent or diluent, adjuvant, emulsifiers, dispersant and / or binder or fixative, wetting agent, repellent of water, if appropriate desiccants and UV stabilizers and, if appropriate, dyes and pigments, defoamers, preservatives, inorganic and organic thickeners, adhesives, gibberellins and also other conventional processing aids, as well as water. Depending on the type of formulation to be prepared, further processing steps, e.g. wet grinding, dry grinding and granulation, may be necessary.

[065] A composição da invenção pode estar presente tal qual ou nas suas formulações (comerciais) e nas formas de utilização preparadas a partir destas, sob a forma de mistura com outros ingredientes ativos (conhecidos), tais como insecticidas, atractores, esterilizantes, bactericidas, acaricidas, nematicidas, fungicidas, reguladores do crescimento, herbicidas, fertilizantes, agentes fitoprotectores e/ou semioquímicos.[065] The composition of the invention can be present as such or in its (commercial) formulations and in the forms of use prepared therefrom, in the form of a mixture with other active ingredients (known), such as insecticides, attractants, sterilizers, bactericides, acaricides, nematicides, fungicides, growth regulators, herbicides, fertilizers, phytoprotective and / or semi-chemical agents.

[066] As composições de acordo com a invenção não compreendem apenas as composições prontas a utilizar, as quais podem ser aplicadas através de aparelhos adequados às plantas ou às sementes, mas também concentrados comerciais que têm de ser diluídos com água antes da utilização.[066] The compositions according to the invention not only comprise ready-to-use compositions, which can be applied through devices suitable for plants or seeds, but also commercial concentrates that must be diluted with water before use.

[067] O tratamento de acordo com a invenção de plantas e de partes de plantas com os compostos ativos ou composições é efectuado directamente ou por meio da ação no seu meio envolvente, habitat ou espaço de armazenagem através de métodos de tratamento convencionais, por exemplo, imersão, pulverização, atomização, irrigação, evaporação, polvilhamento, nebulização, disseminação, aplicação de espuma, aplicação por pincelagem, difusão, enxaguamento (aspersão), irrigação gota a gota e, no caso do material de propagação, em particular no caso das sementes, sob a forma de um pó para o tratamento de sementes a seco, uma solução para o tratamento de sementes, um pó solúvel em água para o tratamento com pastas, por incrustação, por revestimento com uma ou várias camadas, etc.. Além disso, é possível aplicar os compostos ativos pelo método de volume ultra- reduzido ou por injecção da preparação de composto ativo ou do próprio composto ativo no solo.[067] The treatment according to the invention of plants and parts of plants with the active compounds or compositions is carried out directly or by acting on their surroundings, habitat or storage space through conventional treatment methods, for example , immersion, spraying, atomization, irrigation, evaporation, dusting, misting, dissemination, application of foam, application by brushing, diffusion, rinsing (spraying), drip irrigation and, in the case of propagating material, in particular in the case of seeds, in the form of a powder for the treatment of dry seeds, a solution for the treatment of seeds, a water-soluble powder for treatment with pastes, by inlay, by coating with one or more layers, etc. In addition In addition, it is possible to apply the active compounds by the ultra-reduced volume method or by injecting the active compound preparation or the active compound itself into the soil.

Protecção de plantas/culturasPlant / crop protection

[068] Os ingredientes ativos ou composições da invenção possuem uma potente atividade microbicida e podem ser utilizados para o controle de microrganismos indesejados, tais como fungos e bactérias, na protecção de culturas e na protecção de materiais.[068] The active ingredients or compositions of the invention have a potent microbicidal activity and can be used for the control of unwanted microorganisms, such as fungi and bacteria, in crop protection and material protection.

[069] A invenção também diz respeito a um método para o controle de microrganismos indesejados, caracterizado pelo fato de se aplicarem os ingredientes ativos da invenção aos fungos fitopatogénicos, bactérias fitopatogénicas e/ou ao seu habitat.[069] The invention also concerns a method for the control of unwanted microorganisms, characterized by the fact that the active ingredients of the invention are applied to phytopathogenic fungi, phytopathogenic bacteria and / or their habitat.

[070] Os fungicidas podem ser utilizados na protecção de culturas para o controle de fungos fitopatogénicos. Estes são caracterizados por uma eficácia extraordinária contra um espectro alargado de fungos fitopatogénicos, incluindo patogénios provenientes do solo, os quais são, em particular, membros das classes Plasmodiophoromycetes, Peronosporomycetes (Syn. Oomycetes), Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes e Deuteromycetes (Syn. Fungi imperfecti). Alguns fungicidas são ativos sob o ponto de vista sistémico e podem ser utilizados na protecção de plantas como revestimentos foliares, revestimento para sementes ou fungicidas para o solo. Além disso, são adequados para combater fungos, que infestam, por exemplo, a madeira e as raízes de plantas.[070] Fungicides can be used in crop protection to control phytopathogenic fungi. These are characterized by their extraordinary effectiveness against a wide spectrum of phytopathogenic fungi, including pathogens from the soil, which are, in particular, members of the classes Plasmodiophoromycetes, Peronosporomycetes (Syn. Oomycetes), Chytridiomycetes, Zygomycetes, Ascomycetes, Deidomycetes and Basidiomycetes Syn. Fungi imperfecti). Some fungicides are systemically active and can be used to protect plants such as leaf coatings, seed coatings or soil fungicides. In addition, they are suitable for combating fungi, which infest, for example, wood and plant roots.

[071] Os bactericidas podem ser utilizados na protecção de culturas para o controle de Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae e Streptomycetaceae.[071] Bactericides can be used in crop protection to control Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.

[072] Como exemplos não limitativos de patogénios de doenças fúngicas que é possível tratar de acordo com a invenção refere-se:[072] As non-limiting examples of pathogens of fungal diseases that can be treated according to the invention are:

[073] doenças provocadas por patogénios do míldio, por exemplo, da espécie Blumeria, por exemplo, Blumeria graminis; da espécie Podosphaera, por exemplo, Podosphaera leucotricha; da espécie Sphaerotheca, por exemplo, Sphaerotheca fuliginea; da espécie Uncinula, por exemplo, Uncinula necator;[073] diseases caused by pathogens of downy mildew, for example, of the species Blumeria, for example, Blumeria graminis; of the species Podosphaera, for example, Podosphaera leucotricha; Sphaerotheca species, for example, Sphaerotheca fuliginea; of the species Uncinula, for example, Uncinula necator;

[074] doenças provocadas por patogénios da doença da ferrugem, por exemplo, da espécie de Gymnosporangium, por exemplo, Gymnosporangium sabinae; da espécie Hemileia, por exemplo, Hemileia vastatrix; da espécie Phakopsora, por exemplo, Phakopsora pachyrhizi ou Phakopsora meibomiae; da espécie Puccinia, por exemplo, Puccinia recondita, P. triticina, P. graminis ou P. striiformis; da espécie Uromyces, por exemplo, Uromyces appendiculatus;[074] diseases caused by pathogens of rust disease, for example, Gymnosporangium species, for example, Gymnosporangium sabinae; of the Hemileia species, for example, Hemileia vastatrix; Phakopsora species, for example, Phakopsora pachyrhizi or Phakopsora meibomiae; of the Puccinia species, for example, Puccinia recondita, P. triticina, P. graminis or P. striiformis; Uromyces species, for example, Uromyces appendiculatus;

[075] doenças provocadas por patogénios do grupo de Oomycetes, por exemplo, da espécie Albugo, por exemplo, Albugo candida; da espécie Bremia, por exemplo, Bremia lactucae; da espécie Peronospora, por exemplo, Peronospora pisi ou P. brassicae; da espécie Phytophthora, por exemplo, Phytophthora infestans; da espécie Plasmopara, por exemplo, Plasmopara viticola; da espécie Pseudoperonospora, por exemplo, Pseudoperonospora humuli ou Pseudoperonospora cubensis; da espécie Pythium, por exemplo, Pythium ultimum;[075] diseases caused by pathogens of the Oomycetes group, for example, of the Albugo species, for example, Albugo candida; Bremia species, for example, Bremia lactucae; Peronospora species, for example, Peronospora pisi or P. brassicae; Phytophthora species, for example, Phytophthora infestans; of the species Plasmopara, for example, Plasmopara viticola; of the species Pseudoperonospora, for example, Pseudoperonospora humuli or Pseudoperonospora cubensis; Pythium species, for example, Pythium ultimum;

[076] doenças de manchas nas folhas e doenças de murchidão nas folhas provocadas, por exemplo, pela espécie Alternaria, por exemplo, Alternaria solani; espécie Cercospora, por exemplo, Cercospora beticola; espécie Cladosporium, por exemplo, Cladosporium cucumerinum; espécie Cochliobolus, por exemplo, Cochliobolus sativus (forma conídea: Drechslera, syn: Helminthosporium), Cochliobolus miyabeanus; espécie Colletotrichum, por exemplo, Colletotrichum lindemuthanium; espécie Cycloconium, por exemplo, Cycloconium oleaginum; espécie Diaporthe, por exemplo, Diaporthe citri; espécie Elsinoe, por exemplo, Elsinoe fawcettii; espécie Gloeosporium, por exemplo, Gloeosporium laeticolor; espécie Glomerella, por exemplo, Glomerella cingulata; espécie Guignardia, por exemplo, Guignardia bidwelli; espécie Leptosphaeria, por exemplo, Leptosphaeria maculans, Leptosphaeria nodorum; espécie Magnaporthe, por exemplo, Magnaporthe grisea; espécie Microdochium, por exemplo, Microdochium nivale; espécie Mycosphaerella, por exemplo, Mycosphaerella graminicola, M. arachidicola e M. fijiensis; espécie Phaeosphaeria, por exemplo, Phaeosphaeria nodorum; espécie Pyrenophora, por exemplo, Pyrenophora teres, Pyrenophora tritici repentis; espécie Ramularia, por exemplo, Ramularia collo-cygni, Ramularia areola; espécie Rhynchosporium, por exemplo, Rhynchosporium secalis; espécie Septoria, por exemplo, Septoria apii, Septoria lycopersii; espécie Typhula, por exemplo, Typhula incarnata; espécie Venturia, por exemplo, Venturia inaequalis;[076] leaf spot diseases and leaf wilt diseases caused, for example, by the species Alternaria, for example, Alternaria solani; Cercospora species, for example, Cercospora beticola; Cladosporium species, for example, Cladosporium cucumerinum; Cochliobolus species, for example, Cochliobolus sativus (conideal form: Drechslera, syn: Helminthosporium), Cochliobolus miyabeanus; Colletotrichum species, for example, Colletotrichum lindemuthanium; Cycloconium species, for example, Cycloconium oleaginum; Diaporthe species, for example, Diaporthe citri; Elsinoe species, for example, Elsinoe fawcettii; Gloeosporium species, for example, Gloeosporium laeticolor; Glomerella species, for example, Glomerella cingulata; Guignardia species, for example, Guignardia bidwelli; Leptosphaeria species, for example, Leptosphaeria maculans, Leptosphaeria nodorum; Magnaporthe species, for example, Magnaporthe grisea; Microdochium species, for example, Microdochium nivale; Mycosphaerella species, for example, Mycosphaerella graminicola, M. arachidicola and M. fijiensis; Phaeosphaeria species, for example, Phaeosphaeria nodorum; Pyrenophora species, for example, Pyrenophora teres, Pyrenophora tritici repentis; Ramularia species, for example, Ramularia collo-cygni, Ramularia areola; Rhynchosporium species, for example, Rhynchosporium secalis; Septoria species, for example, Septoria apii, Septoria lycopersii; Typhula species, for example, Typhula incarnata; Venturia species, for example, Venturia inaequalis;

[077] doenças das raízes e do caule provocadas, por exemplo, pela espécie Corticium, por exemplo, Corticium graminearum; espécie Fusarium, por exemplo, Fusarium oxysporum; espécie Gaeumannomyces, por exemplo, Gaeumannomyces graminis; espécie Rhizoctonia, por exemplo, Rhizoctonia solani; doenças por Sarocladium provocadas, por exemplo, por espécie Sarocladium oryzae; doenças por Sclerotium provocadas, por exemplo, por Sclerotium oryzae; espécie Tapesia, por exemplo, Tapesia acuformis; espécie Thielaviopsis, por exemplo, Thielaviopsis basicola;[077] root and stem diseases caused, for example, by the species Corticium, for example, Corticium graminearum; Fusarium species, for example, Fusarium oxysporum; Gaeumannomyces species, for example, Gaeumannomyces graminis; Rhizoctonia species, for example, Rhizoctonia solani; Sarocladium diseases caused, for example, by Sarocladium oryzae species; Sclerotium diseases caused, for example, by Sclerotium oryzae; Tapesia species, for example, Tapesia acuformis; Thielaviopsis species, for example, Thielaviopsis basicola;

[078] doenças da espiga e do panículo (incluindo espigas de milho) provocadas, por exemplo, pela espécie Alternaria, por exemplo, Alternaria spp.; espécie Aspergillus, por exemplo, Aspergillus flavus; espécie Cladosporium, por exemplo, Cladosporium cladosporioides; espécie Claviceps, por exemplo, Claviceps purpurea; espécie Fusarium, por exemplo, Fusarium culmorum; espécie Gibberella, por exemplo, Gibberella zeae; espécie Monographella, por exemplo, Monographella nivalis; espécie Septoria, por exemplo, Septoria nodorum;[078] diseases of the ear and panicle (including ears of corn) caused, for example, by the species Alternaria, for example, Alternaria spp .; Aspergillus species, for example, Aspergillus flavus; Cladosporium species, for example, Cladosporium cladosporioides; Claviceps species, for example, Claviceps purpurea; Fusarium species, for example, Fusarium culmorum; Gibberella species, for example, Gibberella zeae; Monographella species, for example, Monographella nivalis; Septoria species, for example, Septoria nodorum;

[079] doenças provocadas por fungos de cárie, por exemplo, espécie Sphacelotheca, por exemplo, Sphacelotheca reiliana; espécie Tilletia, por exemplo, Tilletia caries, T. controversa; espécie Urocystis, por exemplo, Urocystis occulta; espécie Ustilago, por exemplo, Ustilago nuda, U. nuda tritici;[079] diseases caused by caries fungi, for example, Sphacelotheca species, for example, Sphacelotheca reiliana; Tilletia species, for example, Tilletia caries, T. controversa; Urocystis species, for example, Urocystis occulta; Ustilago species, for example, Ustilago nuda, U. nuda tritici;

[080] podridão dos frutos provocada, por exemplo, pela espécie Aspergillus, por exemplo, Aspergillus flavus; espécie Botrytis, por exemplo, Botrytis cinerea; espécie Penicillium, por exemplo, Penicillium expansum e P. purpurogenum; espécie Sclerotinia, por exemplo, Sclerotinia sclerotiorum; espécie Verticilium, por exemplo, Verticilium alboatrum;[080] fruit rot caused, for example, by the species Aspergillus, for example, Aspergillus flavus; Botrytis species, for example, Botrytis cinerea; Penicillium species, for example, Penicillium expansum and P. purpurogenum; Sclerotinia species, for example, Sclerotinia sclerotiorum; Verticilium species, for example, Verticilium alboatrum;

[081] doenças de podridão e murchidão provenientes das sementes e do solo, e também doenças de estacas, provocadas, por exemplo, pela espécie Alternaria, por exemplo, Alternaria brassicicola; espécie Aphanomyces, provocadas, por exemplo, por Aphanomyces euteiches; espécie Ascochyta, provocadas, por exemplo, por Ascochyta lentis; espécie Aspergillus, provocadas, por exemplo, por Aspergillus flavus; espécie Cladosporium, provocadas, por exemplo, por Cladosporium herbarum; espécie Cochliobolus, provocadas, por exemplo, por Cochliobolus sativus (forma conídea: Drechslera, Bipolaris syn: Helminthosporium); espécie Colletotrichum, provocadas, por exemplo, por Colletotrichum coccodes; espécie Fusarium, provocadas, por exemplo, por Fusarium culmorum; espécie Gibberella, provocadas, por exemplo, por Gibberella zeae; espécie Macrophomina, provocadas, por exemplo, por Macrophomina phaseolina; espécie Monographella, provocadas, por exemplo, por Monographella nivalis; espécie Penicillium, provocadas, por exemplo, por Penicillium expansum; espécie Phoma, provocadas, por exemplo, por Phoma lingam; espécie Phomopsis, provocadas, por exemplo, por Phomopsis sojae; espécie Phytophthora, provocadas, por exemplo, por Phytophthora cactorum; espécie Pyrenophora, provocadas, por exemplo, por Pyrenophora graminea; espécie Pyricularia, provocadas, por exemplo, por Pyricularia oryzae; espécie Pythium, provocadas, por exemplo, por Pythium ultimum; espécie Rhizoctonia, provocadas, por exemplo, por Rhizoctonia solani; espécie Rhizopus, provocadas, por exemplo, por Rhizopus oryzae; espécie Sclerotium, provocadas, por exemplo, por Sclerotium rolfsii; espécie Septoria, provocadas, por exemplo, por Septoria nodorum; espécie Typhula, provocadas, por exemplo, por Typhula incarnata; espécie Verticillium, provocadas, por exemplo, por Verticillium dahliae;[081] rot and wilt diseases from seeds and soil, as well as cuttings diseases, caused, for example, by the Alternaria species, for example, Alternaria brassicicola; Aphanomyces species, caused, for example, by Aphanomyces euteiches; Ascochyta species, caused, for example, by Ascochyta lentis; Aspergillus species, caused, for example, by Aspergillus flavus; Cladosporium species, caused, for example, by Cladosporium herbarum; Cochliobolus species, caused, for example, by Cochliobolus sativus (conideal form: Drechslera, Bipolaris syn: Helminthosporium); Colletotrichum species, caused, for example, by Colletotrichum coccodes; Fusarium species, caused, for example, by Fusarium culmorum; Gibberella species, caused, for example, by Gibberella zeae; Macrophomina species, caused, for example, by Macrophomina phaseolina; Monographella species, caused, for example, by Monographella nivalis; Penicillium species, caused, for example, by Penicillium expansum; Phoma species, caused, for example, by Phoma lingam; Phomopsis species, caused, for example, by Phomopsisoyae; Phytophthora species, caused, for example, by Phytophthora cactorum; Pyrenophora species, caused, for example, by Pyrenophora graminea; Pyricularia species, caused, for example, by Pyricularia oryzae; Pythium species, caused, for example, by Pythium ultimum; Rhizoctonia species, caused, for example, by Rhizoctonia solani; Rhizopus species, caused, for example, by Rhizopus oryzae; Sclerotium species, caused, for example, by Sclerotium rolfsii; Septoria species, caused, for example, by Septoria nodorum; Typhula species, caused, for example, by Typhula incarnata; Verticillium species, caused, for example, by Verticillium dahliae;

[082] cancros, tumores e vassoura de bruxa provocados, por exemplo, pela espécie Nectria, por exemplo, Nectria galligena;[082] cancers, tumors and witches' broom caused, for example, by the species Nectria, for example, Nectria galligena;

[083] doenças de murchidão provocadas, por exemplo, pela espécie Monilinia, por exemplo, Monilinia laxa;[083] wilting diseases caused, for example, by the species Monilinia, for example, Monilinia laxa;

[084] doenças de deformações de folhas ou encaracolamento de folhas, provocadas, por exemplo, pela espécie Exobasidium, por exemplo, Exobasidium vexans; espécie Taphrina, por exemplo, Taphrina deformans;[084] diseases of leaf deformation or leaf curl, caused, for example, by the species Exobasidium, for example, Exobasidium vexans; Taphrina species, for example, Taphrina deformans;

[085] doenças degenerativas de plantas para madeira provocadas, por exemplo, pela espécie Esca, por exemplo, Phaeomoniella chlamydospora, Phaeoacremonium aleophilum e Fomitiporia mediterranea; doença viral por Eutypa provocadas, por exemplo, por Eutypa lata; doenças por Ganoderma provocadas, por exemplo, Ganoderma boninense; doenças por Rigidoporus provocadas, por exemplo, por Rigidoporus lignosus;[085] degenerative diseases of plants for wood caused, for example, by the species Esca, for example, Phaeomoniella chlamydospora, Phaeoacremonium aleophilum and Fomitiporia mediterranea; viral Eutypa disease caused, for example, by Eutypa lata; Ganoderma diseases caused, for example, Ganoderma boninense; Rigidoporus diseases caused, for example, by Rigidoporus lignosus;

[086] doenças de flores e de sementes provocadas, por exemplo, pela espécie Botrytis, por exemplo, Botrytis cinerea;[086] flower and seed diseases caused, for example, by the species Botrytis, for example, Botrytis cinerea;

[087] doenças de tubérculos de plantas provocadas, por exemplo, pela espécie Rhizoctonia, por exemplo, Rhizoctonia solani; espécie Helminthosporium, por exemplo, Helminthosporium solani;[087] plant tuber diseases caused, for example, by the species Rhizoctonia, for example, Rhizoctonia solani; Helminthosporium species, for example, Helminthosporium solani;

[088] ramificações da raiz provocadas, por exemplo, pela espécie Plasmodiophora, por exemplo, Plasmodiophora brassicae;[088] root ramifications caused, for example, by the species Plasmodiophora, for example, Plasmodiophora brassicae;

[089] doenças provocadas por patogénios bacterianos, por exemplo, da espécie Xanthomonas, por exemplo, Xanthomonas campestris pv. oryzae; espécie Pseudomonas, por exemplo, Pseudomonas syringae pv. lachrymans; espécie Erwinia, por exemplo, Erwinia amylovora.[089] diseases caused by bacterial pathogens, for example, of the species Xanthomonas, for example, Xanthomonas campestris pv. oryzae; Pseudomonas species, for example, Pseudomonas syringae pv. lachrymans; Erwinia species, for example, Erwinia amylovora.

[090] De preferência, é possível controlar as seguintes doenças da soja:[090] Preferably, it is possible to control the following soy diseases:

[091] doenças fúngicas em folhas, caules, vagens e sementes provocadas, por exemplo, por manchas de folhas por Alternaria (Alternaria spec. atrans tenuissima), antracnose (Colletotrichum gloeosporoides dematium var. truncatum), manchas castanhas (Septoria glycines), machas e degradação de folhas por cercospora (Cercospora kikuchii), degradação de folhas por choanephora (Choanephora infundibulifera trispora (Syn.)), manchas nas folhas por dactuliophora (Dactuliophora glycines), míldio (Peronospora manshurica), degradação por drechslera (Drechslera glycini), manchas nas folhas olho de sapo (Cercospora sojina), manchas nas folhas por leptosphaerulina (Leptosphaerulina trifolii), manchas nas folhas por phyllostica (Phyllosticta sojaecola), murchidão das vagens e caule (Phomopsis sojae), míldio (Microsphaera diffusa), manchas nas folhas por pyrenochaeta (Pyrenochaeta glycines), murchidão das partes aéreas, folhagem e estrutura por rhizoctonia (Rhizoctonia solani), ferrugem (Phakopsora pachyrhizi, Phakopsora meibomiae), sarna (Sphaceloma glycines), murchidão das folhas por stemphylium (Stemphylium botryosum), manchas alvo (Corynespora cassiicola).[091] fungal diseases on leaves, stems, pods and seeds caused, for example, by leaf spots by Alternaria (Alternaria spec. Atrans tenuissima), anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), brown spots (Septoria glycines), males and leaf degradation by cercospora (Cercospora kikuchii), leaf degradation by choanephora (Choanephora infundibulifera trispora (Syn.)), leaf spots by dactuliophora (Dactuliophora glycines), downy mildew (Peronospora manshurica), degradation by drechslera (drechslera) frog's eye leaf spots (Cercospora sojina), leptosphaerulina leaflet (Leptosphaerulina trifolii), phyllostica leaflet (Phyllostictaoyaecola), pod wilting and stem (Phomopsis soye), mildew (Microsphaera diffusa), leaf spots by pyrenochaeta (Pyrenochaeta glycines), wilting of aerial parts, foliage and structure by rhizoctonia (Rhizoctonia solani), rust (Phakopsora pachy rhizi, Phakopsora meibomiae), scabies (Sphaceloma glycines), wilting of the leaves by stemphylium (Stemphylium botryosum), target spots (Corynespora cassiicola).

[092] Doenças fúngicas na base das raízes e do caule provocadas, por exemplo, por podridão negra de raízes (Calonectria crotalariae), podridão carvão (Macrophomina phaseolina), podridão das vagens e colar, podridão das raízes e degradação e murchidão por fusarium (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), podridão das raízes por mycoleptodiscus (Mycoleptodiscus terrestris), neocosmospora (Neocosmospora vasinfecta), murchidão do caule e das vagens (Diaporthe phaseolorum), cancro do caule (Diaporthe phaseolorum var. caulivora), podridão por phytophthora (Phytophthora megasperma), podridão castanha do caule (Phialophora gregata), podridão por pythium (Pythium aphanidermatum, Pythium irregulare, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), desumedecimento, degradação do caule e podridão da raiz por rhizoctonia (Rhizoctonia solani), degradação do caule por sclerotinia (Sclerotinia sclerotiorum), murchidão southern por sclerotinia (Sclerotinia rolfsii), podridão da raiz por thielaviopsis (Thielaviopsis basicola).[092] Fungal diseases at the base of the roots and stem caused, for example, by black root rot (Calonectria crotalariae), coal rot (Macrophomina phaseolina), pod and collar rot, root rot and fusarium degradation and wilting ( Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), root rot by mycoleptodiscus (Mycoleptodiscus terrestris), neocosmospora (Neocosmospora vasinfecta), wilting of the stem and pods (Diaporthe phaseolorum), stem cancer (Diaporthe phaseolor) stem cell (Diaporthe phaseolor). , phytophthora rot (Phytophthora megasperma), brown stem rot (Phialophora gregata), pythium rot (Pythium aphanidermatum, Pythium irregulare, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), dehumidation, Rhizoctonia solani), stem degradation by sclerotinia (Sclerotinia sclerotiorum), southern wilting by sclerotinia (Sclerot inia rolfsii), root rot by thielaviopsis (Thielaviopsis basicola).

[093] As composições fungicidas da invenção podem ser utilizadas para um controle curativo ou protectivo/preventivo de fungos fitopatogénicos. Assim sendo, a invenção também diz respeito a métodos curativos e protectivos para o controle de fungos fitopatogénicos por meio da utilização dos ingredientes ativos ou composições da invenção, os quais são aplicados às sementes, às plantas ou a partes da planta, ao fruto ou ao solo no qual as plantas crescem.[093] The fungicidal compositions of the invention can be used for curative or protective / preventive control of phytopathogenic fungi. Therefore, the invention also concerns curative and protective methods for the control of phytopathogenic fungi through the use of the active ingredients or compositions of the invention, which are applied to the seeds, plants or parts of the plant, the fruit or the soil on which plants grow.

[094] O fato dos ingredientes ativos serem bem tolerados pelas plantas nas concentrações necessárias para o controle de doenças de plantas permite o tratamento de partes aéreas de plantas, de enxertos e sementes de propagação e do solo.[094] The fact that the active ingredients are well tolerated by plants in the concentrations necessary for the control of plant diseases allows the treatment of aerial parts of plants, grafts and propagating seeds and soil.

[095] De acordo com a invenção, é possível tratar todas as plantas e partes de plantas. O termo “plantas” designa todas as plantas e populações de plantas, tais como plantas selvagens, cultivares e variedades de plantas desejadas e indesejadas (estejam ou não protegidas por direitos de variedades de plantas ou direitos de obtenção vegetal). Como cultivares e variedades de plantas é possível referir as plantas que podem ser obtidas por métodos convencionais de cultura e propagação os quais podem ser assistidos ou suplementados por um ou vários métodos biotecnológicos, tais como através da utilização de haploides duplos, fusão de protoplastos, mutagénese aleatória ou dirigida, marcadores moleculares ou genéticos ou por métodos de bioengenharia ou de engenharia genética. O termo “partes de plantas” pretende designar todas as partes e órgãos aéreos e subterrâneos das plantas, tais como rebentos, folhas, flores e raízes, sendo possível referir como exemplos as folhas, agulhas, caules, troncos, flores, carpóforos, frutos e sementes e ainda raízes, tubérculos e rizomas. As partes de plantas também compreendem o material de colheita e o material de propagação vegetativo e generativo, por exemplo, estacas, tubérculos, rizomas, estilhas enraizadas e sementes.[095] According to the invention, it is possible to treat all plants and parts of plants. The term "plants" means all plants and plant populations, such as wild plants, cultivars and desired and unwanted plant varieties (whether or not they are protected by plant variety rights or plant breeding rights). As cultivars and varieties of plants it is possible to mention the plants that can be obtained by conventional methods of culture and propagation which can be assisted or supplemented by one or several biotechnological methods, such as through the use of double haploids, protoplast fusion, mutagenesis random or targeted, molecular or genetic markers or by bioengineering or genetic engineering methods. The term “plant parts” is intended to refer to all aerial and underground parts and organs of plants, such as shoots, leaves, flowers and roots, and it is possible to mention as examples the leaves, needles, stems, trunks, flowers, carpophores, fruits and seeds and also roots, tubers and rhizomes. The plant parts also comprise the harvest material and the vegetative and generative propagation material, for example, cuttings, tubers, rhizomes, rooted chips and seeds.

[096] As composições activas da invenção, quando são bem toleradas pelas plantas, quando apresentam uma toxicidade homeotérmica favorável e quando são bem toleradas pelo ambiente, são adequadas para a protecção de plantas e de órgãos das plantas, para aumentar os rendimentos da colheita, para melhorar a qualidade do material colhido. De preferência, podem ser utilizadas como composições para a protecção de culturas. São activas contra espécies normalmente sensíveis e resistentes e contra todas ou algumas etapas de desenvolvimento.[096] The active compositions of the invention, when they are well tolerated by plants, when they have a favorable homeothermic toxicity and when they are well tolerated by the environment, are suitable for the protection of plants and plant organs, to increase the yields of the harvest, to improve the quality of the harvested material. Preferably, they can be used as compositions for the protection of cultures. They are active against normally sensitive and resistant species and against all or some stages of development.

[097] Como plantas que é possível tratar de acordo com a invenção refere-se as seguintes plantas de cultura principais: milho, soja, luzerna, algodão, girassol, sementes de óleo de Brassica, tais como Brassica napus (v.g., canola, colza), Brassica rapa, B. juncea (v.g., mostarda (campo)) e Brassica carinata, Arecaceae sp. (v.g., óleo de palma, coco), arroz, trigo, beterraba sacarina, cana-de-açúcar, aveia, centeio, cevada, milho-miúdo e sorgo, triticale, linho, frutos secos, uvas e vinha e diversos frutos e vegetais de várias classes botânicas, v.g., Rosaceae sp. (v.g., frutos de pevides, tais como maçãs e peras, mas também frutos de caroço, tais como alperces, cerejas, ameixas e pêssegos, e frutos de bagas, tais como morangos, framboesas, groselhas pretas e vermelhas e groselha verde), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp. (v.g., oliveira), Actinidaceae sp., Lauraceae sp. (v.g., abacate, canela, cânfora), Musaceae sp. (v.g., bananeiras e plantações de bananeiras), Rubiaceae sp. (v.g., café), Theaceae sp. (v.g., chá), Sterculiceae sp., Rutaceae sp. (v.g., limões, laranjas, tangerinas e toranjas); Solanaceae sp. (v.g., tomates, batatas, pimentos, pimentão, beringela, tabaco), Liliaceae sp., Compositae sp. (v.g., alface, alcachofra e chicória - incluindo raiz de chicória, endívia ou chicória comum), Umbelliferae sp. (v.g., cenoura, salsa, aipo e aipo- rábano), Cucurbitaceae sp. (v.g., pepinos - incluindo pepinos de conserva, abóboras, melancias, calabaças e melões), Alliaceae sp. (v.g., alho francês e cebolas), Cruciferae sp. (v.g., couve branca, couve vermelha, brócolo, couve-flor, couve de Bruxelas, pak choi, couve- rábano, rabanete, rábano silvestre e couve chinesa), Leguminosae sp. (v.g., amendoins, ervilhas, lentilhas e feijões - v.g., feijão comum e feijões largos), Chenopodiaceae sp. (v.g., couve suíça, beterraba forrageira, espinafres, beterraba), Linaceae sp. (v.g., cânhamo), Cannabeacea sp. (v.g., canábis), Malvaceae sp. (v.g., quiabo, cacau), Papaveraceae (v.g., papoila), Asparagaceae (v.g., espargos); plantas úteis e plantas ornamentais em jardins e florestas, incluindo turfa, relvado, relva e Stevia rebaudiana; e, em cada caso, tipos geneticamente modificados destas plantas.[097] As plants that can be treated according to the invention are the following main crop plants: corn, soy, lucerne, cotton, sunflower, Brassica oil seeds, such as Brassica napus (eg, canola, rapeseed) ), Brassica rapa, B. juncea (eg, mustard (field)) and Brassica carinata, Arecaceae sp. (eg, palm oil, coconut), rice, wheat, sugar beet, sugar cane, oats, rye, barley, millet and sorghum, triticale, flax, nuts, grapes and vines and various fruits and vegetables from various botanical classes, eg, Rosaceae sp. (eg, pevid fruits, such as apples and pears, but also stone fruits, such as apricots, cherries, plums and peaches, and berry fruits, such as strawberries, raspberries, black and red currants and green currant), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp. (e.g., olive), Actinidaceae sp., Lauraceae sp. (e.g., avocado, cinnamon, camphor), Musaceae sp. (e.g., banana and banana plantations), Rubiaceae sp. (e.g., coffee), Theaceae sp. (e.g. tea), Sterculiceae sp., Rutaceae sp. (e.g., lemons, oranges, tangerines and grapefruits); Solanaceae sp. (e.g., tomatoes, potatoes, peppers, peppers, eggplants, tobacco), Liliaceae sp., Compositae sp. (e.g., lettuce, artichoke and chicory - including chicory root, endive or common chicory), Umbelliferae sp. (e.g., carrot, parsley, celery and celeriac), Cucurbitaceae sp. (e.g., cucumbers - including pickled cucumbers, pumpkins, watermelons, dumplings and melons), Alliaceae sp. (e.g., leek and onions), Cruciferae sp. (e.g., white cabbage, red cabbage, broccoli, cauliflower, Brussels sprouts, pak choi, kohlrabi, radish, horseradish and Chinese cabbage), Leguminosae sp. (e.g., peanuts, peas, lentils and beans - e.g., common beans and broad beans), Chenopodiaceae sp. (e.g., Swiss cabbage, fodder beet, spinach, beet), Linaceae sp. (e.g., hemp), Cannabeacea sp. (e.g., cannabis), Malvaceae sp. (e.g., okra, cocoa), Papaveraceae (e.g., poppy), Asparagaceae (e.g., asparagus); useful plants and ornamental plants in gardens and forests, including peat, lawn, turf and Stevia rebaudiana; and, in each case, genetically modified types of these plants.

[098] Em particular, as misturas e composições de acordo com a invenção são adequadas para o controle das seguintes doenças de plantas:[098] In particular, the mixtures and compositions according to the invention are suitable for the control of the following plant diseases:

[099] Albugo spp. (ferrugem branca) em plantas ornamentais, culturas de vegetais (v.g., A. candida) e girassóis (v.g., A. tragopogonis); Alternaria spp. (doença de manchas pretas, manchas pretas) em vegetais, colza (v.g., A. brassicola ou A. brassicae), beterraba sacarina (v.g., A. tenuis), frutos, arroz, soja e também em batatas (v.g., A. solani ou A. alternata) e tomates (v.g., A. solani ou A. alternata) e Alternaria spp. (cabeças pretas) em trigo; Aphanomyces spp. em beterraba sacarina e vegetais; Ascochyta spp. em cereais e vegetais, v.g., A. tritici (queimadura das folhas por Ascochyta) em trigo e A. hordei em cevada; Bipolaris e Drechslera spp. (teleomorfo: Cochliobolus spp.), v.g., doenças de manchas nas folhas (D. maydis e B. zeicola) em milho, v.g., manchas de gluma (B. sorokiniana) em cereais e v.g., B. oryzae em arroz e em relvados; Blumeria (nome antigo: Erysiphe) graminis (míldio) em cereais (v.g., trigo ou cevada); Botryosphaeria spp. (‘Doença de Ramos Mortos’) em vinhas (v.g., B. obtusa); Botrytis cinerea (teleomorfo: Botryotinia fuckeliana: bolor cinzento, podridão cinzenta) em frutas moles e frutas de pomáceas (por exemplo, morangos), vegetais (por exemplo, alface, cenouras, aipo-rábano e couve), colza, flores, vinhas, culturas para florestas e trigo (bolor das espigas); Bremia lactucae(míldio) em alface; Ceratocystis (syn. Ophiostoma) spp. (fungo de manchas azuis) em árvores de folhas caducas e árvores resinosas, v.g., C. ulmi(doença de olmo holandês) em olmos; Cercospora spp. (manchas das folhas por Cereospora) em milho (v.g., C. zeae-maydis), arroz, beterraba sacarina (v.g., C. beticola),cana-de-açúcar, vegetais, café, soja (v.g., C. sojina ou C. kikuchil) e arroz; Cladosporium spp. em tomate (v.g., C. fulvum: bolor das folhas do tomate) e cereais, v.g., C. herbarum(podridão da espiga) em trigo; Claviceps purpurea (cravagem) em cereais; Cochliobolus (anamorfo: Helminthosporium ou Bipolaris) spp. (manchas das folhas) em milho (v.g., C. carbonum), cereais (v.g., C. sativus, anamorfo: B. sorokiniana: manchas na gluma) e arroz (por exemplo, C. miyabeanus, anamorfo: H. oryzae); Colletotrichum (teleomorfo: Glomerella) spp. (antracnose) em algodão (v.g., C. gossypii), milho (v.g., C. graminicola:podridão do caule e antracnose), frutos moles, batatas (v.g., C. coccodes:doença do emurchecimento), feijões (v.g., C. lindemuthianum) e soja (v.g., C. truncatum); Corticium spp., v.g., C. sasakii(degradação das folhas) em arroz; Corynespora cassiicola (manchas nas folhas) em soja e plantas ornamentais; Cycloconium spp., v.g., C. oleaginum em azeitonas; Cylindrocarpon spp. (v.g., cancro das árvores de frutos ou doença de raízes pretas de vinhas, teleomorfo: Nectria ou Neonectria spp.) em árvores de frutos, vinhas (v.g., C. liriodendn; teleomorfo: Neonectria liriodendri,doenças dos pés pretos) e muitas árvores ornamentais; Dematophora (teleomorfo: Rosellinia) necatrix(podridão da raiz/caule) em soja; Diaporthe spp. v.g., D. phaseolorum(doença do tronco) em soja; Drechslera (syn. Helminthosporium, teleomorfo: Pyrenophora) spp. em milho, cereais, tais como cevada (v.g., D. teres, manchas) e em trigo (v.g., D. tritici-repentis: manchas nas folhas por DTR), arroz e relvados; doença Esca(doença viral da vinha, apoplexia) em vinhas, provocada por Formitiporia (syn. Phellinus) punctata, F. mediterrânea, Phaeomoniella chlamydospora (nome antigo Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum e/ou Botryosphaeria obtusa; Elsinoe spp. em frutos de pevides (E. pyri) e frutos moles (E. veneta: antracnose) e também vinhas E. ampelina: antracnose); Entyloma oryzae (fuligem das folhas) em arroz; Epicoccum spp. (cabeças pretas) em trigo; Erysiphe spp. (míldio) em beterraba sacarina (E. betae), vegetais (v.g., E. pisi), tais como espécies de pepino (v.g., E. cichoracearum) e espécies de couve, tais como colza (v.g., E. cruciferarum); Eutypa fata (cancro ou doença viral por Eutypa, anamorfo: Cytosporina lata, syn. Libertella blepharis) em árvores de frutos, vinhas e muitas plantas ornamentais; Exserohilum (syn. Helminthosporium) spp. em milho (v.g., E. turcicum); Fusarium (teleomorfo: Gibberella) spp. (doença de míldio, podridão de raiz e do caule) em várias plantas, tais como, v.g., F. graminearum ou F. culmorum(podridão da raiz e topo prateado) em cereais (v.g., trigo ou cevada), F. oxysporum em tomates, F. solani em soja e F. verticillioides em milho; Gaeumannomyces graminis (takeall) em cereais (v.g., trigo ou cevada) e milho; Gibberella spp. em cereais (v.g., G. zeae) e arroz (v.g., G. fujikuroi: doença bakanae); Glomerella cingulata em vinhas, frutos pomáceos e outras plantas e G. gossypii em algodão; complexo de manchas no grão em arroz; Guignardia bidwellii(podridão preta) em vinhas; Gymnosporangium spp. em Rosaceae e zimbro, v.g., G. sabinae (ferrugem de peras) em peras; Helminthosporium spp. (syn. Drechslera, teleomorfo: Cochliobolus) em milho, cereais e arroz; Hemileia spp., v.g., H. vastatrix (ferrugem das folhas de café) em café; Isariopsis clavispora (syn. Cladosporium vitis) em vinhas; Macrophomina phaseolina (syn. phaseoli) (podridão da raiz/caule) em soja e algodão; Microdochium (syn. Fusarium) nivale (bolor branco rosado) em cereais (v.g., trigo ou cevada); Microsphaera diffusa(míldio) em soja; Monilinia spp., v.g., M. laxa. M. fructicola e M. fructigena (manchas nas flores e galhos) em frutas de caroço e outras Rosaceae; Mycosphaerella spp. em cereais, bananas, frutos moles e amendoins, tais como, v.g., M. graminicola (anamorfo: Septoria tritici, manchas nas folhas por Septoria) em trigo ou M. fijiensis(doença de Sigatoka) em bananas; Peronospora spp. (míldio) em couve (v.g., P. brassicae), colza (v.g., P. parasitica), plantas de bolbos (v.g., P. destructor), tabaco (P. tabacina) e soja (v.g., P. manshurica); Phakopsora pachyrhizi e P. meibomiae (ferrugem da soja) em soja; Phialophora spp. v.g., em vinhas (v.g., P. tracheiphila e P. tetraspora) e soja (v.g., P. gregata: doença do caule); Phoma lingam(podridão da raiz e do caule) em colza e couve e P. betae (manchas nas folhas) em beterraba sacarina; Phomopsis spp. em girassóis, vinhas (v.g., P. viticola:doença do ramo morto) e soja (v.g., cancro do caule/machas no caule: P. phaseoli, teleomorfo: Diaporthe phaseolorum); Physoderma maydis (manchas castanhas) em milho; Phytophthora spp. (doença do emurchecimento, podridão da raiz, folha, caule e fruto) em várias plantas, tais como em espécies de pimentos e de pepinos (v.g., P. capsici), soja (v.g., P. megasperma, syn. P. sojae), batatas e tomates (v.g., P. infestans. manchas tardias e podridão castanha) e árvores de folhas caducas (v.g., morte súbita do carvalho por P. ramorum); Plasmodiophora brassicae(hérnia) em couve, colza, rábano e outras plantas; Plasmopara spp., v.g., P. viticola (peronospora de vinhas, míldio) em vinhas e P. halstedii em girassóis; Podosphaera spp. (míldio) em Rosaceae, lúpulo, frutos de pevides e frutos moles, v.g., P. leucotricha em maçãs; Polymyxa spp., v.g., em cereais, tais como cevada e trigo (P. graminis) e beterraba sacarina (P. betae) e as doenças virais transmitidas por estes; Pseudocercosporella herpotrichoides (manchas/quebra de troncos, teleomorfo: Tapesia yallundae) em cereais. v.g., trigo ou cevada; Pseudoperonospora(míldio) em várias plantas, v.g., P. cubensis em espécies de pepinos ou P. humili em lúpulo; Pseudopezicula tracheiphila (queimadura angular de folhas, anamorfo: Phialophora) em vinhas; Puccinia spp. (doença da ferrugem) em várias plantas, v.g., P. triticina (ferrugem castanha do trigo), P. striiformis (ferrugem amarela). P. hordei (ferrugem de folhas anãs), P. graminis (ferrugem preta) ou P. recondita (ferrugem castanha de centeio) em cereais, tais como, v.g., trigo, cevada ou centeio, P. kuehnii em cana-de-açúcar e, v.g., em espargos (v.g., P. asparagi); Pyrenophora (anamorfo: Drechslera) tritici- repentis (manchas das folhas) em trigo ou P. teres (manchas) em cevada; Pyricularia spp., v.g., P. oryzae (teleomorfo: Magnaporthe grisea, murchidão do arroz) em arroz e P. grisea em relvados e cereais; Pythium spp. (doença dos cachos secos) em relvado, arroz, milho, trigo, algodão, colza, girassóis, beterraba sacarina, vegetais e outras plantas (v.g., P. ultimum ou P. aphanidermatum); Ramularia spp., v.g., R. collo-cygni (manchas na relva e nas folhas por Ramularia/manchas nas folhas fisiológicas) em cevada e R. beticola em beterraba sacarina; Rhizoctonia spp. em algodão, arroz, batatas, relvado, milho, colza, batatas, beterraba sacarina, vegetais e diversas outras plantas, por exemplo, R. solani(podridão da raiz e do caule) em soja, R. solani (manchas das folhas) em arroz ou R. cerealis (acamamento agudo) em trigo ou cevada; Rhizopus stolonifer(podridão mole) em morangos, cenouras, couve, vinhas e tomate; Rhynchosporium secalis (manchas nas folhas) em cevada, centeio e triticale; Sarocladium oryzae e S. attenuatum(podridão de folhas) em arroz; Sclerotinia spp. (podridão do caule ou branca) em vegetais e culturas de campo, tais como colza, sirassóis (v.g., Sclerotinia sclerotiorum) e soja (v.g., S. rolfsii), Septoria spp. em várias plantas, v.g., S. glycines (manchas nas folhas) em soja, S. tritici (manchas nas folhas por Septoria) em trigo e S. (syn. Stagonospora) nodorum (manchas nas folhas e manchas na gluma) em cereais; Uncinula (syn. Erysiphe) necator(míldio, anamorfo: Oidium tuckeri) em vinhas; Setospaeria spp. (manchas nas folhas) em milho (v.g., S. turcicum, syn. Helminthosporium turcicum) e relvado; Sphacelotheca spp. (fuligem da cabeça) em milho, (v.g., S. reiliana: fuligem do núcleo), milho-miúdo e cana-de-açúcar; Sphaerotheca fuliginea(míldio) em espécies de pepinos; Spongospora subterranea (sarna) em batatas e as doenças virais transmitidas por esta; Stagonospora spp. em cereais, v.g., S. nodorum (manchas nas folhas e manchas na gluma, teleomorfo: Leptosphaeria [syn. Phaeosphaeria] nodorum) em trigo; Synchytrium endobioticum em batatas (doença de intumescência de batata); Taphrina spp., v.g., T. deformans (doença das folhas encaracoladas) em pêssegos e T. pruni (doença de lepra da ameixa) em ameixas; Thielaviopsis spp. (podridão preta da raiz) em tabaco, frutos de pevides, culturas de vegetais, soja e algodão, v.g., T. basicola (sin. Chalara elegans); Tilletia spp. (cárie ou fuligem mal cheirosa) em cereais, tais como, v.g., T. tritici (syn. T. caries,cárie do trigo) e T. controversa(cárie anã) em trigo; Typhula incarnata (bolor branco acinzentado) em cevada ou trigo; Urocystis spp., v.g., U. occulta (fuligem de bandeira) em centeio; Uromyces spp. (ferrugem) em plantas vegetais, tais como feijões (v.g., U. appendiculatus, syn. U. phaseolI) e beterraba sacarina (v.g., U. betae); Ustilago spp. (alforra) em cereais (v.g., U. nuda e U. avaenae), milho (v.g., U. maydis: alforra do milho) e cana-de-açúcar; Venturia spp. (sarna) em maçãs (v.g., V. inaequalis) e peras e Verticillium spp. (murchidão das folhas e dos rebentos) em várias plantas, tais como árvores de frutos e árvores ornamentais, vinhas, frutos moles, culturas de vegetais e de campo, tais como v.g., V. dahliae em morangos, colza, batatas e tomates.[099] Albugo spp. (white rust) in ornamental plants, vegetable crops (e.g., A. candida) and sunflowers (e.g., A. tragopogonis); Alternaria spp. (black spot disease, black spot) on vegetables, rapeseed (eg, A. brassicola or A. brassicae), sugar beet (eg, A. tenuis), fruits, rice, soy and also potatoes (eg, A. solani or A. alternata) and tomatoes (eg, A. solani or A. alternata) and Alternaria spp. (black heads) in wheat; Aphanomyces spp. in sugar beet and vegetables; Ascochyta spp. in cereals and vegetables, e.g., A. tritici (Ascochyta leaf burn) in wheat and A. hordei in barley; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.), eg, leaf spot diseases (D. maydis and B. zeicola) on corn, eg, gluma spots (B. sorokiniana) on cereals and eg, B. oryzae on rice and lawns ; Blumeria (old name: Erysiphe) graminis (downy mildew) on cereals (e.g., wheat or barley); Botryosphaeria spp. (‘Dead Branches Disease’) in vines (e.g., B. obtusa); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: gray mold, gray rot) in soft fruits and pomegranate fruits (eg strawberries), vegetables (eg lettuce, carrots, celeriac and cabbage), rapeseed, flowers, vines, crops for forests and wheat (ear mold); Bremia lactucae (downy mildew) on lettuce; Ceratocystis (syn. Ophiostoma) spp. (blue-spotted fungus) on deciduous and resinous trees, e.g., C. ulmi (Dutch elm disease) in elm trees; Cercospora spp. (leaf spots by Cereospora) on corn (eg, C. zeae-maydis), rice, sugar beet (eg, C. beticola), sugar cane, vegetables, coffee, soy (eg, C. sojina or C kikuchil) and rice; Cladosporium spp. in tomatoes (e.g., C. fulvum: mold of tomato leaves) and cereals, e.g., C. herbarum (ear rot) in wheat; Claviceps purpurea (ergot) in cereals; Cochliobolus (anamorph: Helminthosporium or Bipolaris) spp. (leaf spots) on corn (e.g., C. carbonum), cereals (e.g., C. sativus, anamorph: B. sorokiniana: glume spots) and rice (for example, C. miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) in cotton (eg, C. gossypii), corn (eg, C. graminicola: stem rot and anthracnose), soft fruits, potatoes (eg, coccodes: wilting disease), beans (eg, C. lindemuthianum) and soy (eg, C. truncatum); Corticium spp., E.g., C. sasakii (leaf breakdown) in rice; Corynespora cassiicola (leaf spots) in soybeans and ornamental plants; Cycloconium spp., E.g., C. oleaginum in olives; Cylindrocarpon spp. (eg, cancer of fruit trees or disease of black roots in vines, teleomorph: Nectria or Neonectria spp.) in fruit trees, vines (eg, C. liriodendn; teleomorph: Neonectria liriodendri, diseases of the black feet) and many trees ornamental; Dematophora (teleomorph: Rosellinia) necatrix (root / stem rot) in soybean; Diaporthe spp. v. D. phaseolorum (stem disease) in soybean; Drechslera (syn. Helminthosporium, teleomorph: Pyrenophora) spp. in corn, cereals, such as barley (e.g., D. teres, patches) and in wheat (e.g., D. tritici-repentis: leaf spots by DTR), rice and lawns; Esca disease (viral disease of the vine, apoplexy) in vines, caused by Formitiporia (syn. Phellinus) punctata, F. mediterranea, Phaeomoniella chlamydospora (old name Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and / or Botryosphaeria obtusa; Elsinoe spp. in fruits of pevides (E. pyri) and soft fruits (E. veneta: anthracnose) and also E. ampelina vines: anthracnose); Entyloma oryzae (leaf soot) in rice; Epicoccum spp. (black heads) in wheat; Erysiphe spp. (downy mildew) on sugar beet (E. betae), vegetables (e.g., E. pisi), such as cucumber species (e.g., E. cichoracearum) and cabbage species, such as rapeseed (e.g., E. cruciferarum); Eutypa fata (cancer or viral disease caused by Eutypa, anamorph: Cytosporina lata, syn. Libertella blepharis) in fruit trees, vines and many ornamental plants; Exserohilum (syn. Helminthosporium) spp. in corn (e.g., E. turcicum); Fusarium (teleomorph: Gibberella) spp. (downy mildew, root and stem rot) in various plants, such as, eg, F. graminearum or F. culmorum (root rot and silver top) in cereals (eg, wheat or barley), F. oxysporum in tomatoes, F. solani in soy and F. verticillioides in corn; Gaeumannomyces graminis (takeall) in cereals (e.g., wheat or barley) and corn; Gibberella spp. in cereals (e.g., G. zeae) and rice (e.g., G. fujikuroi: bakanae disease); Glomerella cingulata in vines, pomegranate fruits and other plants and G. gossypii in cotton; grain stain complex in rice; Guignardia bidwellii (black rot) in vines; Gymnosporangium spp. in Rosaceae and juniper, e.g., G. sabinae (pear rust) in pears; Helminthosporium spp. (syn. Drechslera, teleomorph: Cochliobolus) in corn, cereals and rice; Hemileia spp., E.g., H. vastatrix (coffee leaf rust) in coffee; Isariopsis clavispora (syn. Cladosporium vitis) in vineyards; Macrophomina phaseolina (syn. Phaseoli) (root / stem rot) in soybeans and cotton; Microdochium (syn. Fusarium) nivale (pinkish-white mold) in cereals (e.g., wheat or barley); Microsphaera diffusa (downy mildew) in soybean; Monilinia spp., E.g., M. laxa. M. fructicola and M. fructigena (spots on flowers and branches) in stone fruits and other Rosaceae; Mycosphaerella spp. in cereals, bananas, soft fruits and peanuts, such as, e.g., M. graminicola (anamorph: Septoria tritici, Septoria leaf spots) in wheat or M. fijiensis (Sigatoka disease) in bananas; Peronospora spp. (downy mildew) on cabbage (e.g., P. brassicae), rapeseed (e.g., P. parasitica), bulb plants (e.g., P. destructor), tobacco (P. tabacina) and soy (e.g., P. manshurica); Phakopsora pachyrhizi and P. meibomiae (soybean rust) in soybean; Phialophora spp. v., in vines (v., P. tracheiphila and P. tetraspora) and soy (v., P. gregata: stem disease); Phoma lingam (root and stem rot) in rapeseed and cabbage and P. betae (leaf spots) in sugar beet; Phomopsis spp. in sunflowers, vines (e.g., P. viticola: dead branch disease) and soybeans (e.g., cancer of the stem / stems in the stem: P. phaseoli, teleomorph: Diaporthe phaseolorum); Physoderma maydis (brown spots) in corn; Phytophthora spp. (wilting disease, root rot, leaf, stem and fruit) in various plants, such as in pepper and cucumber species (eg, P. capsici), soybeans (eg, P. megasperma, syn. P. soye) , potatoes and tomatoes (eg, P. infestans. late spots and brown rot) and deciduous trees (eg, sudden death of the oak by P. ramorum); Plasmodiophora brassicae (hernia) in cabbage, rapeseed, horseradish and other plants; Plasmopara spp., E.g., P. viticola (vine peronospora, downy mildew) in vines and P. halstedii in sunflowers; Podosphaera spp. (downy mildew) in Rosaceae, hops, pevid fruits and soft fruits, e.g., P. leucotricha in apples; Polymyxa spp., E.g., in cereals, such as barley and wheat (P. graminis) and sugar beet (P. betae) and the viral diseases transmitted by them; Pseudocercosporella herpotrichoides (spots / trunk break, teleomorph: Tapesia yallundae) in cereals. e.g., wheat or barley; Pseudoperonospora (downy mildew) in various plants, e.g., P. cubensis in cucumber species or P. humili in hops; Pseudopezicula tracheiphila (angular leaf burn, anamorph: Phialophora) in vines; Puccinia spp. (rust disease) in various plants, e.g., P. triticina (brown rust of wheat), P. striiformis (yellow rust). P. hordei (dwarf leaf rust), P. graminis (black rust) or P. recondita (brown rye rust) in cereals, such as, eg, wheat, barley or rye, P. kuehnii in sugar cane and, eg, asparagus (eg, P. asparagi); Pyrenophora (anamorph: Drechslera) tritici-repentis (leaf spots) in wheat or P. teres (spots) in barley; Pyricularia spp., E.g., P. oryzae (teleomorph: Magnaporthe grisea, rice wilting) in rice and P. grisea in lawns and cereals; Pythium spp. (dry bunches disease) in lawns, rice, corn, wheat, cotton, rapeseed, sunflowers, sugar beet, vegetables and other plants (e.g., P. ultimum or P. aphanidermatum); Ramularia spp., E.g., R. collo-cygni (stains on grass and leaves by Ramularia / stains on physiological leaves) in barley and R. beticola in sugar beet; Rhizoctonia spp. in cotton, rice, potatoes, turf, corn, rapeseed, potatoes, sugar beet, vegetables and several other plants, for example, R. solani (root and stem rot) in soy, R. solani (leaf spots) in rice or R. cerealis (acute lodging) in wheat or barley; Rhizopus stolonifer (soft rot) in strawberries, carrots, cabbage, vines and tomatoes; Rhynchosporium secalis (leaf spots) in barley, rye and triticale; Sarocladium oryzae and S. attenuatum (leaf rot) in rice; Sclerotinia spp. (stem or white rot) in vegetables and field crops, such as rapeseed, sunflower (e.g., Sclerotinia sclerotiorum) and soy (e.g., S. rolfsii), Septoria spp. on various plants, e.g., S. glycines (leaf spots) on soy, S. tritici (leaf spots by Septoria) on wheat and S. (syn. Stagonospora) nodorum (leaf spots and glume spots) on cereals; Uncinula (syn. Erysiphe) necator (downy, anamorphic: Oidium tuckeri) in vines; Setospaeria spp. (leaf spots) on corn (e.g., S. turcicum, syn. Helminthosporium turcicum) and turf; Sphacelotheca spp. (soot from the head) in maize, (e.g., S. reiliana: soot from the nucleus), millet and sugar cane; Sphaerotheca fuliginea (downy mildew) in cucumber species; Spongospora subterranea (scabies) in potatoes and the viral diseases transmitted by it; Stagonospora spp. in cereals, e.g., S. nodorum (leaf spots and glume spots, teleomorph: Leptosphaeria [syn. Phaeosphaeria] nodorum) in wheat; Synchytrium endobioticum in potatoes (potato swelling disease); Taphrina spp., E.g., T. deformans (curly leaf disease) in peaches and T. pruni (plum leprosy disease) in plums; Thielaviopsis spp. (black root rot) in tobacco, fruit pods, vegetable crops, soybeans and cotton, e.g., T. basicola (sin. Chalara elegans); Tilletia spp. (caries or smelly soot) in cereals, such as, e.g., T. tritici (syn. T. caries, wheat caries) and T. controversa (dwarf caries) in wheat; Typhula incarnata (grayish white mold) in barley or wheat; Urocystis spp., E.g., U. occulta (flag soot) in rye; Uromyces spp. (rust) in vegetable plants, such as beans (e.g., U. appendiculatus, syn. U. phaseolI) and sugar beet (e.g., U. betae); Ustilago spp. (saddle) in cereals (e.g., U. nuda and U. avaenae), corn (e.g., U. maydis: corn saddle) and sugar cane; Venturia spp. (scabies) in apples (e.g., V. inaequalis) and pears and Verticillium spp. (wilting of leaves and shoots) in various plants, such as fruit trees and ornamental trees, vines, soft fruits, vegetable and field crops, such as, e.g., V. dahliae in strawberries, rapeseed, potatoes and tomatoes.

Regulação do crescimento de plantasPlant growth regulation

[100] Em alguns casos, as composições da invenção também podem ser utilizadas, para concentrações ou taxas de aplicação particulares, como herbicidas, agentes fitoprotectores, reguladores do crescimento ou agentes para melhorar as propriedades das plantas, ou como microbicidas, por exemplo, como fungicidas, antimicóticos, bactericidas, viricidas (incluindo composições contra viróides) ou como composições contra MLO (organismos do tipo micoplasma) e RLO (organismos do tipo Rickettsia). Se adequado, também podem ser utilizados como intermediários ou precursores para a síntese de outros ingredientes ativos.[100] In some cases, the compositions of the invention can also be used, for particular concentrations or rates of application, as herbicides, phytoprotective agents, growth regulators or agents to improve plant properties, or as microbicides, for example, as fungicides, antimycotics, bactericides, viricides (including compositions against viroids) or as compositions against MLO (mycoplasma-like organisms) and RLO (Rickettsia-like organisms). If appropriate, they can also be used as intermediates or precursors for the synthesis of other active ingredients.

[101] As combinações activas da invenção intervêm no metabolismo das plantas, podendo assim ser utilizadas como reguladores do crescimento.[101] The active combinations of the invention intervene in the metabolism of plants and can therefore be used as growth regulators.

[102] Os reguladores do crescimento de plantas podem exercer diversos efeitos sobre as plantas. O efeito das substâncias depende essencialmente do momento da aplicação em relação à etapa de desenvolvimento da planta e também das quantidades de ingrediente ativo aplicadas sobre as plantas ou sobre o seu meio ambiente e do tipo de aplicação. Em cada um dos casos, os reguladores do crescimento deverão apresentar um efeito particular desejado sobre as plantas de cultura.[102] Plant growth regulators can have a variety of effects on plants. The effect of the substances depends essentially on the moment of application in relation to the stage of development of the plant and also on the amounts of active ingredient applied on the plants or on their environment and the type of application. In each case, growth regulators should have a particular desired effect on crop plants.

[103] Os compostos de regulação do crescimento de plantas podem ser utilizados, por exemplo, para inibir o crescimento vegetativo das plantas. Tal inibição de crescimento é interessante sob o ponto de vista económico, por exemplo, no caso de relvas, visto que é assim possível reduzir a frequência do corte da relva em jardins ornamentais, parques e instalações desportivas, nas bermas das estradas, em aeroportos ou em culturas de frutos. É também importante a inibição do crescimento de plantas herbáceas e plantas de madeiras nas bermas das estradas e na vizinhança de condutas ou de linhas aéreas ou, de um modo geral, em áreas em que o crescimento vigoroso de plantas é indesejado.[103] Plant growth regulating compounds can be used, for example, to inhibit plant growth. Such growth inhibition is interesting from an economic point of view, for example, in the case of grass, since it is thus possible to reduce the frequency of mowing in ornamental gardens, parks and sports facilities, on the side of roads, in airports or in fruit crops. It is also important to inhibit the growth of herbaceous plants and wood plants on the side of roads and in the vicinity of ducts or overhead lines or, in general, in areas where vigorous plant growth is undesirable.

[104] É também importante a utilização de reguladores de crescimento para a inibição do crescimento longitudinal de cereais. Tal reduz ou elimina completamente o risco de acamamento das plantas antes da colheita. Além do mais, no caso dos cereais, os reguladores de crescimento podem fortificar o colmo, o que também evita o acamamento. A utilização de reguladores do crescimento para a diminuição e fortificação de colmos permite a utilização de volumes superiores de fertilizantes para aumentar o rendimento, sem qualquer risco de acamamento da cultura de cereais.[104] It is also important to use growth regulators to inhibit the longitudinal growth of cereals. This reduces or completely eliminates the risk of lodging the plants before harvest. Furthermore, in the case of cereals, growth regulators can fortify the stalk, which also prevents lodging. The use of growth regulators to reduce and fortify stalks allows the use of higher volumes of fertilizers to increase yield, without any risk of lodging the cereal crop.

[105] Em muitas plantas de cultura, a inibição do crescimento vegetativo permite uma plantação mais densa, tornando assim possível a obtenção de rendimentos superiores com base na superfície do solo. Uma outra vantagem das plantas mais pequenas obtidas desta forma consiste no fato de ser mais fácil cultivar e colher a cultura.[105] In many crop plants, inhibition of vegetative growth allows for denser planting, thus making it possible to obtain higher yields based on the soil surface. Another advantage of the smaller plants obtained in this way is that it is easier to cultivate and harvest the crop.

[106] A inibição do crescimento vegetativo da planta também pode proporcionar rendimentos aumentados uma vez que os nutrientes e assimilados são mais benéficos para a formação de flores e frutos do que para as partes vegetativas das plantas.[106] Inhibiting the plant's vegetative growth can also provide increased yields since nutrients and assimilates are more beneficial to the formation of flowers and fruits than to the vegetative parts of plants.

[107] Frequentemente, os reguladores de crescimento também podem ser utilizados para promover o crescimento vegetativo. Tal é bastante benéfico durante a colheita das partes vegetativas das plantas. No entanto, a promoção do crescimento vegetativo também pode promover o crescimento generativo pelo fato de serem formados mais assimilados, proporcionando mais frutos ou frutos maiores.[107] Often, growth regulators can also be used to promote vegetative growth. This is quite beneficial when harvesting the vegetative parts of the plants. However, the promotion of vegetative growth can also promote generative growth because they are more assimilated, providing more fruits or bigger fruits.

[108] Em alguns casos, é possível alcançar um aumento de rendimento por manipulação do metabolismo da planta, sem quaisquer alterações detectáveis no crescimento vegetativo. Além disso, os reguladores de crescimento podem ser utilizados para alterar a composição das plantas, o que por sua vez pode proporcionar um aumento na qualidade dos produtos colhidos. Por exemplo, é possível aumentar o teor em açúcar na beterraba sacarina, cana-de-açúcar, ananases e em citrinos, ou aumentar o teor em proteínas na soja ou em cereais. Por exemplo, também é possível utilizar os reguladores de crescimento para inibir a degradação de ingredientes desejáveis, por exemplo, açúcar em beterraba sacarina ou cana-de-açúcar, antes ou depois da colheita. Também é possível influenciar positivamente a produção ou a eliminação de ingredientes secundários da planta. Um exemplo é a estimulação do fluxo de látex em borracheiras.[108] In some cases, it is possible to achieve an increase in yield by manipulating the plant's metabolism without any detectable changes in vegetative growth. In addition, growth regulators can be used to change the composition of plants, which in turn can provide an increase in the quality of harvested products. For example, it is possible to increase the sugar content in sugar beet, sugar cane, pineapples and citrus fruits, or to increase the protein content in soy or cereals. For example, it is also possible to use growth regulators to inhibit the breakdown of desirable ingredients, for example sugar in sugar beet or sugar cane, before or after harvest. It is also possible to positively influence the production or elimination of secondary plant ingredients. An example is the stimulation of latex flow in rubber plants.

[109] Sob a influência de reguladores de crescimento, é possível formar frutos partenocárpicos. Além disso, também é possível influenciar o sexo de flores. Também é possível produzir pólen estéril, que é bastante importante no cultivo e produção de sementes híbridas.[109] Under the influence of growth regulators, it is possible to form parthenocarpic fruits. In addition, it is also possible to influence the sex of flowers. It is also possible to produce sterile pollen, which is very important in the cultivation and production of hybrid seeds.

[110] A utilização de reguladores de crescimento pode controlar a ramificação das plantas. por um lado, através da quebra da dominância apical, é possível promover o desenvolvimento de rebentos laterais, o que pode ser particularmente desejado no cultivo de plantas ornamentais, em conjunto com uma inibição do crescimento. No entanto, por outro lado, também é possível inibir o crescimento de rebentos laterais. Este efeito é particularmente interessante, por exemplo, no cultivo de tabaco ou no cultivo de tomates.[110] The use of growth regulators can control the branching of plants. on the one hand, by breaking the apical dominance, it is possible to promote the development of lateral shoots, which may be particularly desired in the cultivation of ornamental plants, together with a growth inhibition. However, on the other hand, it is also possible to inhibit the growth of lateral shoots. This effect is particularly interesting, for example, in growing tobacco or growing tomatoes.

[111] Sob a influência de reguladores de crescimento, é possível controlar a quantidade de folhas nas plantas de um modo tal que a desfolhação das plantas seja alcançada no tempo desejado. Tal desfolhação desempenha um papel principal na colheita mecânica do algodão, embora também seja interessante para facilitar a colheita de outras culturas, por exemplo, em vinicultura. A desfolhação das plantas também pode ser efectuado para diminuir a transpiração das plantas antes destas serem transplantadas.[111] Under the influence of growth regulators, it is possible to control the amount of leaves on the plants in such a way that the defoliation of the plants is achieved in the desired time. Such defoliation plays a major role in the mechanical harvesting of cotton, although it is also interesting to facilitate the harvesting of other crops, for example, in winemaking. Defoliation of plants can also be done to decrease plant transpiration before they are transplanted.

[112] De igual modo, os reguladores de crescimento podem ser utilizados para regular a deiscência dos frutos. Por um lado, é possível prevenir a deiscência prematura de frutos. Por outro lado, também é possível promover a deiscência de frutos ou mesmo abortar a floração para se obter uma massa desejada (“desbaste”), para se eliminar a alternação. O termo “alternação” pretende designar a característica de algumas espécies de frutos, por razões endógenas, produzem rendimentos muito diferentes de ano para ano. Por último, é possível utilizar os reguladores de crescimento no momento da colheita para reduzir a força necessária para soltar os frutos, para assim permitir a colheita mecânica ou para facilitar a colheita manual.[112] Similarly, growth regulators can be used to regulate fruit dehiscence. On the one hand, it is possible to prevent premature dehiscence of fruits. On the other hand, it is also possible to promote dehiscence of fruits or even abort flowering to obtain a desired mass ("thinning"), to eliminate alternation. The term “alternation” is intended to designate the characteristic of some species of fruit, for endogenous reasons, produce very different yields from year to year. Finally, it is possible to use growth regulators at the time of harvest to reduce the force required to loosen the fruit, to allow mechanical harvesting or to facilitate manual harvesting.

[113] Os reguladores de crescimento também podem ser utilizados para se alcançar uma maturação mais rápida ou então retardada do material colhido, antes ou depois da colheita. Tal é particularmente vantajoso visto que permite um ajustamento ópitmo aos requisitos do mercado. Além do mais, em alguns casos, os reguladores de crescimento podem ser utilizados para concentrar a maturação em um determinado período de tempo. Tal estabelece os pré- requisitos para a colheita mecânica ou manual completa em uma operação individual, por exemplo, no caso de tabaco, tomates ou café.[113] Growth regulators can also be used to achieve faster or delayed maturation of the harvested material, before or after harvest. This is particularly advantageous since it allows an optimal adjustment to market requirements. In addition, in some cases, growth regulators can be used to concentrate maturation over a certain period of time. This establishes the prerequisites for complete mechanical or manual harvesting in an individual operation, for example, in the case of tobacco, tomatoes or coffee.

[114] Através da utilização de reguladores de crescimento, é ainda possível influenciar o repouso de sementes ou botões de plantas, de um modo tal que as plantas, tais como os ananases ou plantas ornamentais em viveiros, por exemplo, germinem, rebentem ou floresçam em um momento para o qual não estejam normalmente inclinados para o fazer. Em áreas em que existe o risco de geada, poderá ser desejável retardar a formação de botões ou a germinação de sementes com o auxílio de reguladores de crescimento, para evitar os danos provocados por geadas tardias.[114] Through the use of growth regulators, it is also possible to influence the rest of plant seeds or buds, in such a way that plants, such as pineapples or ornamental plants in nurseries, for example, germinate, burst or flower at a time when they are not normally inclined to do so. In areas where there is a risk of frost, it may be desirable to delay the formation of buds or the germination of seeds with the aid of growth regulators, to avoid the damage caused by late frosts.

[115] Por último, os reguladores de crescimento podem induzir a resistência das plantas à geada, à seca ou à elevada salinidade do solo. Tal permite o cultivo de plantas em regiões que são normalmente inadequadas para tal propósito.[115] Finally, growth regulators can induce plant resistance to frost, drought or high soil salinity. This allows for the cultivation of plants in regions that are normally unsuitable for this purpose.

Indução de resistência/saúde da planta e outros efeitosInduction of resistance / plant health and other effects

[116] As combinações activas de acordo com a invenção também podem exibir um potente efeito fortificador nas plantas. Assim sendo, estas podem ser utilizadas para mobilizar as defesas da planta contra ataques por microrganismos indesejados.[116] The active combinations according to the invention can also exhibit a potent strengthening effect on plants. Therefore, they can be used to mobilize the plant's defenses against attacks by unwanted microorganisms.

[117] No presente contexto, como substâncias fortificadoras de plantas (indutoras de resistência) pretende-se designar aquelas substâncias que são capazes de estimular o sistema de defesa das plantas de um modo tal que as plantas tratadas, quando subsequentemente inoculadas com microrganismos indesejados, desenvolvem um elevado grau de resistência contra esses microrganismos.[117] In the present context, as plant-fortifying substances (resistance inducers) it is intended to designate those substances that are capable of stimulating the defense system of plants in such a way that the treated plants, when subsequently inoculated with unwanted microorganisms, develop a high degree of resistance against these microorganisms.

[118] As combinações activas de acordo com a invenção também são adequadas para aumentar o rendimento de culturas. Além disso, apresentam uma toxicidade reduzida e são bem toleradas pelas plantas.[118] The active combinations according to the invention are also suitable for increasing the yield of cultures. In addition, they have reduced toxicity and are well tolerated by plants.

[119] Além disso, no contexto da presente invenção, os efeitos na fisiologia das plantas compreendem os seguintes:[119] In addition, in the context of the present invention, the effects on plant physiology comprise the following:

[120] tolerância a fatores de stress abiótico, os quais compreendem tolerância a temperatura, tolerância a seca e recuperação após stress por seca, eficácia na utilização de água (correlacionada com um consumo reduzido de água), tolerância a inundação, stress provocado por ozono e tolerância a UV, tolerância a químicos, tais como metais pesados, sais, pesticidas (agentes fitoprotectores), etc.;[120] tolerance to abiotic stress factors, which include temperature tolerance, drought tolerance and recovery after drought stress, water use effectiveness (correlated with reduced water consumption), flood tolerance, ozone stress and UV tolerance, tolerance to chemicals, such as heavy metals, salts, pesticides (phytoprotective agents), etc .;

[121] tolerância a fatores de stress biótico, os quais compreendem resistência aumentada a fungos e resistência aumentada contra nematodes, vírus e bactérias. No contexto da presente invenção, a tolerância a fatores de stress biótico compreende, de preferência, resistência aumentada a fungos e resistência aumentada contra nematodes;[121] tolerance to biotic stress factors, which comprise increased resistance to fungi and increased resistance against nematodes, viruses and bacteria. In the context of the present invention, tolerance to biotic stress factors preferably comprises increased resistance to fungi and increased resistance against nematodes;

[122] vigor aumentado da planta, que compreende a saúde da planta/qualidade da planta e o vigor das sementes, deficiência em povoamento reduzida, aparência melhorada, recuperação aumentada, efeito de enverdecimento aumentado e eficácia fotossintética melhorada;[122] increased plant vigor, which comprises plant health / plant quality and seed vigor, reduced stand deficiency, improved appearance, increased recovery, increased greening effect and improved photosynthetic efficacy;

[123] efeitos nas hormonas e/ou enzimas funcionais das plantas;[123] effects on plant hormones and / or functional enzymes;

[124] efeitos sobre os reguladores de crescimento (promotores), que compreendem a germinação rápida, emergência superior, sistema de raízes mais desenvolvido e/ou crescimento de raízes melhorado, aptidão aumentada para afilhamento, rebentos mais produtivos, floração mais rápida, altura e/ou biomassa da planta aumentadas, encurtamento de caules, melhorias no crescimento de ramos, número de núcleos/espiga, número de espigas/m2, número de estolhos e/ou número de flores, índice de colheita aumentado, folhas maiores, menor número de folhas basais mortas, filotaxia melhorada, maturação mais rápida/amadurecimento do fruto mais rápido, dilaceração homogénea, duração do enchimento do grão aumentada, melhor amadurecimento do fruto, maiores frutos/tamanho dos vegetais, resistência a germinação e acamamento reduzido.[124] effects on growth regulators (promoters), which include rapid germination, superior emergence, more developed root system and / or improved root growth, increased tillering capacity, more productive shoots, faster flowering, height and / or increased plant biomass, shortening of stems, improvements in branch growth, number of cores / ear, number of ears / m2, number of stolons and / or number of flowers, increased harvest index, larger leaves, lesser number of dead basal leaves, improved phyllotaxis, faster ripening / faster fruit ripening, homogeneous tearing, increased grain filling duration, better fruit ripening, larger fruits / vegetable sizes, germination resistance and reduced lodging.

[125] O rendimento aumentado, referindo-se a biomassa total por hectare, rendimento por hectare, peso do núcleo/fruto, tamanho da semente e/ou peso do hectolitro, bem como qualidade de produto aumentada, compreende:[125] The increased yield, referring to total biomass per hectare, yield per hectare, core / fruit weight, seed size and / or hectoliter weight, as well as increased product quality, comprises:

[126] processabilidade melhorada no que diz respeito à distribuição de tamanho (núcleo, fruto, etc.), dilaceração homogénea, humidade do grão, melhor moagem, melhor vinificação, melhor fabricação de cerveja, rendimento em sumo aumentado, capacidade de colheita, capacidade de digestão, valor de sedimentação, número de entalhe, estabilidade da vagem, estabilidade ao armazenamento, comprimento/força/uniformidade de fibra melhorada, aumento da qualidade de leite e/ou de carne de animais alimentados por produtos ensilados, adaptabilidade para cozinha e fritura;[126] improved processability with regard to size distribution (core, fruit, etc.), homogeneous tearing, grain moisture, better grinding, better vinification, better brewing, increased juice yield, harvesting capacity, capacity digestion rate, sedimentation value, notch number, pod stability, storage stability, improved fiber length / strength / uniformity, increased quality of milk and / or meat from animals fed by silage products, adaptability for cooking and frying ;

[127] compreende ainda uma comercialização melhorada no que diz respeito a qualidade melhorada de fruto/grão, distribuição de tamanho (núcleo, fruto, etc.), capacidade de armazenamento/período de semi-vida aumentados, firmeza/macieza, paladar (aroma, textura, etc.), classificação (tamanho, forma, número de bagas, etc.), número de bagas/frutos por cacho, friabilidade, frescura, cobertura com cera, frequência de distúrbios fisiológicos, coloração, etc.;[127] further comprises improved marketing with regard to improved fruit / grain quality, size distribution (core, fruit, etc.), increased storage capacity / half-life, firmness / softness, taste (aroma , texture, etc.), classification (size, shape, number of berries, etc.), number of berries / fruits per bunch, friability, freshness, covering with wax, frequency of physiological disorders, coloring, etc .;

[128] compreende ainda o aumento em ingredientes desejados, tais como, v.g., teor em proteínas, ácidos gordos, teor em óleo, qualidade de óleo, composição de aminoácidos, teor em açúcar, teor em ácido (pH), proporção açúcar/ácido (Brix), polifenóis, teor em amido, qualidade nutricional, teor/índice de glúten, teor em energia, paladar, etc.;[128] further comprises the increase in desired ingredients, such as, eg, protein content, fatty acids, oil content, oil quality, amino acid composition, sugar content, acid content (pH), sugar / acid ratio (Brix), polyphenols, starch content, nutritional quality, gluten content / index, energy content, taste, etc .;

[129] e compreende ainda a diminuição em ingredientes desejados, tais como, v.g., menos micotoxinas, menos aflatoxinas, nível de geosmina, aromas fenólicos, lacase, polifenol oxidases e peroxidases, teor em nitrato, etc..[129] and further comprises the decrease in desired ingredients, such as, e.g., less mycotoxins, less aflatoxins, geosmin level, phenolic flavors, laccase, polyphenol oxidases and peroxidases, nitrate content, etc.

[130] A agricultura sustentável compreende a eficácia na utilização de nutrientes, em particular, eficácia na utilização de azoto (N), eficácia na utilização de fósforo (P), eficácia na utilização de água, transpiração melhorada, taxa de respiração e/ou assimilação de CO2, melhor nodulação, metabolismo de Ca melhorado, etc..[130] Sustainable agriculture comprises efficiency in the use of nutrients, in particular, efficiency in the use of nitrogen (N), efficiency in the use of phosphorus (P), efficiency in the use of water, improved sweating, respiration rate and / or CO2 assimilation, better nodulation, improved Ca metabolism, etc.

[131] A senescência retardada compreende a melhoria da fisiologia da planta, a qual é manifestada, por exemplo, em uma fase de enchimento de grão mais longa, que proporciona um rendimento superior, uma duração mais longa da coloração verde em folhas da planta e, assim, compreende a coloração (enverdecimento), teor em água, secura, etc.. assim sendo, no contexto da presente invenção, concluiu-se que a aplicação específica da invenção da combinação de composto ativo torna possível prolongar a duração da área verde da folha, que retarda a maturação (senescência) da planta. A vantagem principal para o agricultor é uma fase de enchimento do grão mais longa que proporciona um rendimento superior. Existe ainda uma vantagem para o agricultor baseada em uma flexibilidade superior no momento da colheita.[131] Delayed senescence comprises the improvement of the plant's physiology, which is manifested, for example, in a longer grain filling phase, which provides a higher yield, a longer duration of green coloration in the leaves of the plant and , thus, it includes the coloring (greening), water content, dryness, etc. Therefore, in the context of the present invention, it was concluded that the specific application of the invention of the active compound combination makes it possible to prolong the duration of the green area of the leaf, which slows down the maturation (senescence) of the plant. The main advantage for the farmer is a longer grain filling phase that provides superior yield. There is also an advantage for the farmer based on superior flexibility at the time of harvest.

[132] Aqui, o “valor de sedimentação” consiste em uma medida para a qualidade de proteína e é descrito de acordo com Zeleny (valor de Zeleny), o grau de sedimentação de farinha suspensa em uma solução de ácido láctico durante um intervalo de tempo padrão. Tal é considerado uma medida da qualidade de cozedura. O inchamento da fração de glúten da farinha na solução de ácido láctico afecta a taxa de sedimentação da suspensão de farinha. Tanto um teor superior em glúten como uma melhor qualidade em glúten proporciona uma sedimentação mais lenta e valores de teste de Zeleny mais elevados. O valor de sedimentação da farinha dependente da composição de proteína do trigo e está, principalmente, correlacionado com o teor em proteína, a dureza do milho e o volume do tacho e forno do pão. Uma correlação forte entre o volume de pão e o volume de sedimentação de Zeleny em comparação com o volume de sedimentação SDS poderá ser devida ao teor em proteína que influencia tanto o volume como o valor de Zeleny (Czech J. Food Sci. Vol. 21, No. 3: 91-96, 2000).[132] Here, the “sedimentation value” is a measure of protein quality and is described according to Zeleny (Zeleny value), the degree of sedimentation of flour suspended in a lactic acid solution during an interval of standard time. This is considered a measure of cooking quality. The swelling of the gluten fraction of the flour in the lactic acid solution affects the sedimentation rate of the flour suspension. Both a higher gluten content and better gluten quality provide slower sedimentation and higher Zeleny test values. The sedimentation value of the flour depends on the protein composition of the wheat and is mainly correlated with the protein content, the corn hardness and the volume of the bread pan and oven. A strong correlation between bread volume and Zeleny sedimentation volume compared to SDS sedimentation volume may be due to the protein content that influences both Zeleny volume and value (Czech J. Food Sci. Vol. 21 , No. 3: 91-96, 2000).

[133] Além disso, o “número de entalhe”, tal como aqui mencionado, constitui uma medida para a qualidade de cozedura de cereais e, em particular, de trigo. O teste de número de entalhe indica que danos nos rebentos podem ter ocorrido. Significa que alterações das propriedades físicas da porção de amido no núcleo de trigo já tiveram lugar. Aqui, o instrumento do número de entalhe analisa a viscosidade através da medição de resistência de uma farinha e pasta aquosa a uma punção de entalhe. O tempo (em segundos) para que tal aconteça é conhecido como o número de entalhe. Os resultados de número de entalhe são registados como um índice de atividade de enzima em uma amostra de trigo ou farinha e os resultados são expressos como tempo em segundos. Um número de entalhe elevado (por exemplo, superior a 300 segundos) indica uma atividade enzimática mínima e uma qualidade são de trigo ou farinha. Um número de entalhe baixo (por exemplo, inferior a 250 segundos) indica uma atividade enzimática substancial e trigo ou farinha danificado nos rebentos.[133] Furthermore, the "notch number", as mentioned here, is a measure of the cooking quality of cereals and, in particular, of wheat. The notch number test indicates that damage to the shoots may have occurred. It means that changes in the physical properties of the starch portion in the wheat kernel have already taken place. Here, the notch number instrument analyzes viscosity by measuring the resistance of an aqueous flour and paste to a notch punch. The time (in seconds) for this to happen is known as the notch number. Notch number results are recorded as an index of enzyme activity in a wheat or flour sample and the results are expressed as time in seconds. A high notch number (for example, greater than 300 seconds) indicates minimal enzymatic activity and a healthy quality of wheat or flour. A low notch number (for example, less than 250 seconds) indicates substantial enzymatic activity and damaged wheat or flour in the sprouts.

[134] A expressão “sistema de raízes mais desenvolvido” / “crescimento de raízes melhorado” designa um sistema de raízes mais longo, um crescimento de raízes mais profundo, um crescimento de raízes mais rápido, um peso superior de raiz seca/fresca, um volume mais elevado de raiz, uma área superficial de raiz mais larga, um maior diâmetro de raiz, uma estabilidade superior da raiz, maior ramificação da raiz, um número mais elevado de pelos da raiz e/ou mais pontas de raiz, e pode ser medido por meio da análise da arquitectura da raiz com metodologias adequados e programas de análise de imagem (v.g., WinRhizo).[134] The term “more developed root system” / “improved root growth” means a longer root system, deeper root growth, faster root growth, higher dry / fresh root weight, a higher root volume, a wider root surface area, a larger root diameter, greater root stability, greater root branching, a higher number of root hairs and / or more root tips, and may be measured by analyzing the root architecture with appropriate methodologies and image analysis programs (eg WinRhizo).

[135] A expressão “eficácia na utilização de água na cultura” designa, tecnicamente, a massa de agricultura produzida por unidade de água consumida e, economicamente, ao valor do(s) produto(s) produzido(s) por unidade de volume de água consumida e pode, v.g., ser medida em termos de rendimento por ha, biomassa das plantas, massa de mil núcleos e números de espigas por m2.[135] The term “efficacy in the use of water in culture” means, technically, the mass of agriculture produced per unit of water consumed and, economically, to the value of the product (s) produced per unit of volume of water consumed and can, for example, be measured in terms of yield per ha, plant biomass, mass of a thousand cores and numbers of ears per m2.

[136] A expressão “eficácia na utilização de azoto” designa, tecnicamente, a massa de agricultura produzida por unidade de azoto consumida e, economicamente, ao valor do(s) produto(s) produzido(s) por unidade de azoto consumida, reflectindo a eficácia de absorção e utilização.[136] The term "efficiency in using nitrogen" technically means the agricultural mass produced per unit of nitrogen consumed and, economically, the value of the product (s) produced per unit of nitrogen consumed, reflecting absorption and utilization efficiency.

[137] A melhoria no enverdecimento/coloração melhorada e eficácia fotossintética melhorada, bem como o retardamento de senescência, podem ser medidos através de técnicas bem conhecidas, tais como o sistema HandyPea (Hansatech). A razão Fv/Fm constitui um parâmetro amplamente utilizado para indicar a eficácia máxima em termos de quantidade do fotossistema II (PSII). Este parâmetro é amplamente considerado como indicação selectiva do desempenho fotossintético da planta, com amostras saudáveis tipicamente alcançando um valor máximo de Fv/Fm de aproximadamente 0,85. Irão observar-se valores inferiores a este caso a amostra tenha sido exposta a algum tipo de fator de stress biótico ou abiótico, o qual tenha reduzido a capacidade de extinção fotoquímica de energia no PSII. A razão Fv/Fm é apresentada como uma razão entre a fluorescência variável (Fv) e o valor máximo de fluorescência (Fm). O índice de desempenho constitui, essencialmente, um indicador da vitalidade da amostra. (Ver, v.g., Advanced Techniques in Soil Microbiology, 2007, 11, 319-341; Applied Soil Ecology, 2000, 15, 169-182).[137] The improvement in greening / coloration and improved photosynthetic efficacy, as well as the delay in senescence, can be measured using well-known techniques, such as the HandyPea system (Hansatech). The Fv / Fm ratio is a parameter widely used to indicate the maximum effectiveness in terms of quantity of photosystem II (PSII). This parameter is widely considered as a selective indication of the photosynthetic performance of the plant, with healthy samples typically reaching a maximum Fv / Fm value of approximately 0.85. Values lower than this will be observed if the sample has been exposed to some type of biotic or abiotic stress factor, which has reduced the photochemical energy extinction capacity in the PSII. The Fv / Fm ratio is presented as a ratio between the variable fluorescence (Fv) and the maximum fluorescence value (Fm). The performance index is essentially an indicator of the sample's vitality. (See, e.g., Advanced Techniques in Soil Microbiology, 2007, 11, 319-341; Applied Soil Ecology, 2000, 15, 169-182).

[138] A melhoria no enverdecimento/coloração melhorada e eficácia fotossintética melhorada, bem como o retardamento de senescência, também pode ser avaliada por medição da taxa fotossintética líquida (Pn), medição do teor em clorofila, v.g., pelo método de extração de pigmento de Ziegler e Ehle, medição da eficácia fotoquímica (razão Fv/Fm), determinação do crescimento de ramos e biomassa final da raiz e/ou cúpula, determinação da densidade do rebento, bem como da mortalidade da raiz.[138] The improvement in greening / coloration and improved photosynthetic efficacy, as well as senescence delay, can also be assessed by measuring the liquid photosynthetic rate (Pn), measuring the chlorophyll content, eg, by the pigment extraction method Ziegler and Ehle, measurement of photochemical efficacy (ratio Fv / Fm), determination of branch growth and final root and / or dome biomass, determination of shoot density, as well as root mortality.

[139] No contexto da presente invenção, é preferida a melhoria dos efeitos da fisiologia da planta, os quais são seecionados entre o conjunto constituído por: crescimento aumentado da raiz/sistema de raízes mais desenvolvido, enverdecimento melhorado, eficácia melhorada na utilização de água (correlacionado com um consumo reduzido de água), eficácia melhorada na utilização de nutrientes, que compreende, em particular, a eficácia melhorada na utilização de azoto (N), senescência retardada e rendimento aumentado.[139] In the context of the present invention, it is preferred to improve the effects of plant physiology, which are divided into the group consisting of: increased root growth / more developed root system, improved greening, improved water use efficiency (correlated with reduced water consumption), improved efficiency in the use of nutrients, which includes, in particular, improved efficiency in the use of nitrogen (N), delayed senescence and increased yield.

[140] Para o aumento de rendimento, é preferida uma melhoria no valor de sedimentação e do número de entalhe, bem como uma melhoria do teor em proteína e açúcar, em particular, em plantas seleccionadas entre o conjunto constituído por cereais (de preferência, trigo).[140] For the increase in yield, an improvement in the sedimentation value and the number of notches is preferred, as well as an improvement in the protein and sugar content, in particular, in plants selected from the group consisting of cereals (preferably, wheat).

[141] De preferência, a nova utilização das composições fungicidas da presente invenção diz respeito a uma utilização combinada de a) um controle preventivo e/ou curativo de fungos fitopatogénicos e/ou nematodes, com ou sem gestão de resistência, e b) pelo menos um dos efeitos entre crescimento aumentado da raiz, enverdecimento melhorado, eficácia melhorada na utilização de água, senescência retardada e rendimento aumentado. Do conjunto b), é particularmente preferido o aumento do sistema de raízes, da eficácia na utilização de água e da eficácia na utilização de N.[141] Preferably, the new use of the fungicidal compositions of the present invention concerns a combined use of a) a preventive and / or curative control of phytopathogenic and / or nematode fungi, with or without resistance management, and b) at least one of the effects between increased root growth, improved greening, improved water use efficiency, delayed senescence and increased yield. From set b), it is particularly preferred to increase the root system, the efficiency in the use of water and the efficiency in the use of N.

Tratamento de sementesSeed treatment

[142] A invenção compreende ainda um método para o tratamento de sementes.[142] The invention further comprises a method for treating seeds.

[143] A invenção diz ainda respeito a sementes que foram tratadas por um dos métodos descritos no parágrafo anterior. As sementes da invenção são utilizadas em métodos para a protecção de sementes contra microrganismos indesejados. Nestes métodos, são utilizadas sementes tratadas com pelo menos um ingrediente ativo da invenção.[143] The invention also relates to seeds that have been treated by one of the methods described in the previous paragraph. The seeds of the invention are used in methods for protecting seeds against unwanted microorganisms. In these methods, seeds treated with at least one active ingredient of the invention are used.

[144] As composições da invenção também são adequadas para o tratamento de sementes. Uma grande parte dos danos sobre plantas de cultura provocados por organismos prejudiciais é desencadeada pela infecção da semente durante o armazenamento ou após o cultivo, bem como durante e após a germinação da planta. Esta fase é particularmente crítica uma vez que as raízes e os rebentos da planta em crescimento são particularmente sensíveis, e mesmo danos pequenos podem provocar a morte da planta. Assim sendo, existe um grande interesse em proteger a semente e a planta em germinação por meio da utilização de composições adequadas.[144] The compositions of the invention are also suitable for seed treatment. A large part of the damage to crop plants caused by harmful organisms is triggered by infection of the seed during storage or after cultivation, as well as during and after plant germination. This stage is particularly critical since the roots and shoots of the growing plant are particularly sensitive, and even minor damage can cause the plant to die. Therefore, there is a great interest in protecting the seed and the germinating plant through the use of suitable compositions.

[145] O controle de fungos fitopatogénicos por meio do tratamento de sementes de plantas é já conhecido há algum tempo e é submetido a melhorias contínuas. No entanto, o tratamento de sementes apresenta um conjunto de problemas que nem sempre pode ser resolvido de um modo satisfatório. Assim, é desejável o desenvolvimento de métodos para a proteção de sementes e de plantas em germinação que dispense a aplicação suplementar de agentes para a protecção de culturas após o semeio ou após a emergência das plantas ou que pelo menos reduza consideravelmente a aplicação suplementar. Além do mais, é desejável optimizar a quantidade de ingrediente ativo utilizada deste modo, proporcionando uma protecção máxima da semente e da planta em germinação contra o ataque por fungos fitopatogénicos, mas não danificando a própria planta pelo ingrediente ativo utilizado. Em particular, os métodos para o tratamento de sementes também deverão ter em consideração as propriedades fungicidas intrínsecas de plantas transgénicas para se alcançar uma protecção óptima das sementes e da planta em germinação utilizando uma quantidade mínima das composições para a protecção de culturas.[145] The control of phytopathogenic fungi by treating plant seeds has been known for some time and has undergone continuous improvement. However, seed treatment presents a set of problems that cannot always be satisfactorily solved. Thus, it is desirable to develop methods for the protection of seeds and germinating plants that dispense with the supplemental application of crop protection agents after sowing or after the emergence of the plants or that at least considerably reduce the supplementary application. Furthermore, it is desirable to optimize the amount of active ingredient used in this way, providing maximum protection of the germinating seed and plant against attack by phytopathogenic fungi, but not damaging the plant itself by the active ingredient used. In particular, seed treatment methods should also take into account the intrinsic fungicidal properties of transgenic plants to achieve optimum protection of the seeds and the germinating plant using a minimal amount of the crop protection compositions.

[146] Assim sendo, a presente invenção também diz respeito a um método para a protecção de sementes e de plantas em germinação contra ataques por fungos fitopatogénicos, através do tratamento de sementes com uma composição de acordo com a invenção. A invenção também diz respeito à utilização das composições de acordo com a invenção para o tratamento de sementes para a protecção das sementes e de plantas em germinação contra fungos fitopatogénicos. Além disso, a invenção diz respeito às sementes tratadas com uma composição de acordo com a invenção para a protecção contra fungos fitopatogénicos.[146] Therefore, the present invention also concerns a method for protecting seeds and germinating plants against attacks by phytopathogenic fungi, by treating seeds with a composition according to the invention. The invention also relates to the use of the compositions according to the invention for the treatment of seeds for the protection of seeds and germinating plants against phytopathogenic fungi. In addition, the invention relates to seeds treated with a composition according to the invention for protection against phytopathogenic fungi.

[147] O controle de fungos fitopatogénicos que danificam as plantas pós-emergência é efectuado principalmente pelo tratamento do solo e pelas partes aéreas das plantas com composições para a protecção de culturas. Devido às preocupações no que diz respeito a uma possível influência das composições para a protecção de culturas sobre o meio ambiente e sobre a saúde de seres humanos e de animais, têm vindo a ser feitos esforços para reduzir a quantidade de ingredientes ativos aplicados.[147] The control of phytopathogenic fungi that damage post-emergence plants is mainly carried out by treating the soil and aerial parts of plants with crop protection compositions. Due to concerns about the possible influence of compositions for the protection of cultures on the environment and on the health of humans and animals, efforts have been made to reduce the amount of active ingredients applied.

[148] Uma das vantagens da presente invenção consiste no fato de, devido às propriedades sistémicas particulares dos ingredientes ativos e das composições de acordo com a invenção, o tratamento das sementes com tais ingredientes ativos e composições não protege apenas as próprias sementes, mas também as plantas resultantes após germinação, contra fungos fitopatogénicos. Deste modo, o tratamento imediato da cultura durante o período de semeio ou em um período curto após este pode ser dispensado.[148] One of the advantages of the present invention is that, due to the particular systemic properties of the active ingredients and the compositions according to the invention, the treatment of seeds with such active ingredients and compositions not only protects the seeds themselves, but also the resulting plants after germination, against phytopathogenic fungi. In this way, immediate treatment of the crop during the sowing period or in a short period after it can be dispensed with.

[149] Também é considerada uma vantagem o fato das composições de acordo com a invenção poderem também ser utilizadas, em particular, em sementes transgénicas, caso esse em que a planta em desenvolvimento a partir de tal semente é capaz de expressar uma proteína que actua contra as pragas. Devido ao tratamento de tal semente com os ingredientes ativos ou composições de acordo com a invenção, apenas por meio da expressão da proteína, por exemplo, uma proteína insecticida, é possível controlar determinadas pragas. De um modo surpreendente, neste caso é possível observar um outro efeito sinergístico, o qual aumenta adicionalmente a eficácia da protecção contra ataques por pragas.[149] It is also considered an advantage that the compositions according to the invention can also be used, in particular, in transgenic seeds, in which case the plant developing from such seed is capable of expressing a protein that acts against pests. Due to the treatment of such seed with the active ingredients or compositions according to the invention, it is only through expression of the protein, for example, an insecticidal protein, that certain pests can be controlled. Surprisingly, in this case it is possible to observe another synergistic effect, which further increases the effectiveness of protection against attacks by pests.

[150] As composições de acordo com a invenção são adequadas para a protecção de sementes de qualquer variedade de planta utilizadas em agricultura, em estufas, em florestas ou em horticultura e viticultura. Em particular, tal é o caso de sementes de cereais (tais como trigo, cevada, centeio, triticale, sorgo/milho-miúdo e aveia), milho, algodão, soja, arroz, batata, girassol, feijões, café, beterraba (v.g., beterraba sacarina e beterraba forrageira), amendoim, colza, papoila, azeitona, coco, cacau, cana-de-açúcar, tabaco, vegetais (tais como tomate, pepino, cebola e alface), relvados e plantas ornamentais (ver infra). O tratamento de sementes de cereais (tais como trigo, cevada, centeio, triticale e aveia), milho e arroz é particularmente importante.[150] The compositions according to the invention are suitable for the protection of seeds of any variety of plants used in agriculture, greenhouses, forests or horticulture and viticulture. In particular, this is the case for cereal seeds (such as wheat, barley, rye, triticale, sorghum / millet and oats), maize, cotton, soybeans, rice, potatoes, sunflowers, beans, coffee, beets (eg , sugar beet and fodder beet), peanuts, rapeseed, poppy, olive, coconut, cocoa, sugar cane, tobacco, vegetables (such as tomatoes, cucumbers, onions and lettuce), lawns and ornamental plants (see below). The treatment of cereal seeds (such as wheat, barley, rye, triticale and oats), corn and rice is particularly important.

[151] Tal como a seguir também descrito, o tratamento de sementes transgénicas com os ingredientes ativos ou composições da invenção é particularmente importante. Tal diz respeito às sementes de plantas que contêm pelo menos um gene heterólogo que permite a expressão de um polipéptido ou de uma proteína que possui propriedades insecticidas. O gene heterólogo nas sementes transgénicas pode ser proveniente, por exemplo, de microrganismos das espécies Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus ou Gliocladium. De preferência, este gene heterólogo é proveniente de Bacillus sp., caso esse em que o produto génico é eficaz contra pírale do milho europeu e/ou crisomelídeo do sistema radicular do milho Western. Mais preferencialmente, o gene heterólogo é proveniente de Bacillus thuringiensis.[151] As also described below, the treatment of transgenic seeds with the active ingredients or compositions of the invention is particularly important. This concerns plant seeds that contain at least one heterologous gene that allows the expression of a polypeptide or a protein that has insecticidal properties. The heterologous gene in transgenic seeds may come, for example, from microorganisms of the species Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium. Preferably, this heterologous gene comes from Bacillus sp., In which case the gene product is effective against European corn pyrale and / or chrysomelid from the Western corn root system. Most preferably, the heterologous gene comes from Bacillus thuringiensis.

[152] No contexto da presente invenção, a composição de acordo com a invenção é aplicada à semente por si só ou em uma formulação adequada. De preferência, a semente é tratada em um estado suficientemente estável de modo que o tratamento não cause qualquer dano. De um modo geral, a semente pode ser tratada em qualquer momento deste a colheita até ao semeio. De um modo habitual, a semente utilizada é separada da planta e liberta de espigas, cascas, caules, pelos ou carne dos frutos. Assim, é possível utilizar, por exemplo, sementes que foram colhidas, limpas e secas até um teor em humidade inferior a 15% em peso. Em alternativa, também é possível utilizar sementes que, após secagem, tenham sido tratadas, por exemplo, com água e depois novamente secas.[152] In the context of the present invention, the composition according to the invention is applied to the seed alone or in a suitable formulation. Preferably, the seed is treated in a sufficiently stable state so that the treatment does not cause any harm. In general, the seed can be treated at any time from harvest to sowing. In the usual way, the seed used is separated from the plant and freed from ears, barks, stems, hair or meat from the fruits. Thus, it is possible to use, for example, seeds that have been harvested, cleaned and dried to a moisture content of less than 15% by weight. Alternatively, it is also possible to use seeds that, after drying, have been treated, for example, with water and then dried again.

[153] Durante o tratamento das sementes, deverá ser normalmente garantido que a quantidade da composição de acordo com a invenção e/ou a quantidade de outros aditivos aplicada às sementes, é seleccionada de um modo tal que a germinação da semente não seja prejudicada ou que a planta resultante não seja danificada. Tal deverá ser particularmente garantido no caso de ingredientes ativos que exibam efeitos fitotóxicos para determinadas taxas de aplicação.[153] During seed treatment, it should normally be ensured that the amount of the composition according to the invention and / or the amount of other additives applied to the seeds, is selected in such a way that the germination of the seed is not impaired or that the resulting plant is not damaged. This should be particularly guaranteed in the case of active ingredients that exhibit phytotoxic effects for certain application rates.

[154] As composições de acordo com a invenção podem ser aplicadas directamente, isto é, na ausência de quaisquer outros componentes e sem ser necessário serem diluídas. De um modo geral, é preferível aplicar as composições às sementes sob a forma de uma formulação adequada. As formulações e os métodos adequados para o tratamento de sementes são conhecidos pelos especialistas na matéria e encontram-se descritos, por exemplo, nos documentos seguintes: US 4 272 417, US 4 245 432, US 4 808 430, US 5 876 739, US 2003/0176428 A1, WO 2002/080675, WO 2002/028186.[154] The compositions according to the invention can be applied directly, that is, in the absence of any other components and without having to be diluted. In general, it is preferable to apply the compositions to the seeds in the form of a suitable formulation. Suitable formulations and methods for treating seeds are known to those skilled in the art and are described, for example, in the following documents: US 4 272 417, US 4 245 432, US 4 808 430, US 5 876 739, US 2003/0176428 A1, WO 2002/080675, WO 2002/028186.

[155] Os ingredientes ativos utilizáveis de acordo com a invenção podem ser convertidos nas formulações convencionais de revestimento de sementes, tais como soluções, emulsões, suspensões, pós, espumas, pastas ou outras composições de revestimento para sementes, bem como formulações ULV.[155] The active ingredients usable according to the invention can be converted into conventional seed coating formulations, such as solutions, emulsions, suspensions, powders, foams, pastes or other seed coating compositions, as well as ULV formulations.

[156] Estas formulações são preparadas de um modo conhecidos, por mistura dos ingredientes ativos com aditivos convencionais, por exemplo, cargas convencionais e também solventes ou diluentes, corantes, agentes humectantes, agentes de dispersão, emulsificantes, anti- espumantes, conservantes, espessantes secundários, adesivos, giberelinas e também água.[156] These formulations are prepared in a known manner by mixing the active ingredients with conventional additives, for example, conventional fillers and also solvents or diluents, dyes, wetting agents, dispersing agents, emulsifiers, defoamers, preservatives, thickeners secondary, adhesives, gibberellins and also water.

[157] Como corantes úteis que podem estar presentes nas formulações de revestimento das sementes utilizáveis de acordo com a invenção refere-se todos os corantes convencionalmente utilizados para tais propósitos. É possível utilizar pigmentos, os quais são fracamente solúveis em água, ou corantes, os quais são solúveis em água. Como exemplos refere-se os corantes conhecidos pelos nomes 'Rhodamine B', 'C.I. Pigment Red 112' e 'C.I. Solvent Red 1'.[157] As useful dyes that may be present in seed coating formulations usable in accordance with the invention are all dyes conventionally used for such purposes. It is possible to use pigments, which are poorly soluble in water, or dyes, which are soluble in water. Examples include dyes known by the names' Rhodamine B ',' C.I. Pigment Red 112 'and' C.I. Solvent Red 1 '.

[158] Como agentes humectantes que podem estar presentes nas formulações de revestimento de sementes utilizáveis de acordo com a invenção refere-se todas as substâncias que promovem a humectação e que são convencionalmente utilizadas para a formulação de ingredientes agroquímicos ativos. De preferência, utiliza-se alquilnaftaleno- sulfonatos, tais como diisopropil- ou diisobutil-naftaleno- sulfonatos.[158] As wetting agents that can be present in seed coating formulations usable according to the invention are all substances that promote wetting and that are conventionally used for the formulation of active agrochemical ingredients. Preferably, alkylnaphthalene sulfonates, such as diisopropyl- or diisobutyl-naphthalene sulfonates, are used.

[159] Como dispersantes e/ou emulsificantes úteis que podem estar presentes nas formulações de revestimento de sementes utilizáveis de acordo com a invenção refere-se todos os dispersantes não iónicos, aniónicos e catiónicos convencionalmente utilizados para a formulação de ingredientes agroquímicos ativos. De preferência, utiliza- se dispersantes não iónicos ou aniónicos ou misturas de dispersantes não iónicos ou aniónicos. Em particular, como dispersantes não iónicos adequados refere-se polímeros de blocos de óxido de etileno/óxido de propileno, éteres poliglicólicos de alquilfenol e éter poliglicólico de tristririlfenol, e os seus derivados fosfatados ou sulfatados. Em particular, como dispersantes aniónicos adequados refere-se ligno-sulfonatos, sais de ácido poliacrílico e condensados de arilsulfonato/formaldeído.[159] Useful dispersants and / or emulsifiers that may be present in seed coating formulations usable according to the invention include all nonionic, anionic and cationic dispersants conventionally used for the formulation of active agrochemical ingredients. Preferably, nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants are used. In particular, suitable non-ionic dispersants include block polymers of ethylene oxide / propylene oxide, polyglycolic alkylphenol ethers and polyglycolic tristryrylphenol ether, and their phosphate or sulfate derivatives. In particular, suitable anionic dispersants include lignosulphonates, polyacrylic acid salts and aryl sulphonate / formaldehyde condensates.

[160] Como anti-espumantes que podem estar presentes nas formulações de revestimento de sementes utilizáveis de acordo com a invenção refere-se todas as substâncias inibidoras de espuma convencionalmente utilizadas para a formulação de ingredientes agroquímicos ativos. De preferência, utiliza-se anti-espumantes de silicone e estearato de magnésio.[160] As defoamers that can be present in seed coating formulations usable according to the invention, all foam-inhibiting substances conventionally used for the formulation of active agrochemical ingredients are referred to. Preferably, silicone defoamers and magnesium stearate are used.

[161] Como conservantes que podem estar presentes nas formulações de revestimento de sementes utilizáveis de acordo com a invenção refere-se todas as substâncias utilizáveis para tais propósitos em composições agroquímicas. Como exemplos refere-se diclorofeno e hemiformal do álcool benzílico.[161] As preservatives that may be present in seed coating formulations usable according to the invention, all substances that can be used for such purposes in agrochemical compositions include. Examples include dichlorophene and hemiformal benzyl alcohol.

[162] Como espessantes secundários que podem estar presentes nas formulações de revestimento de sementes utilizáveis de acordo com a invenção refere-se todas as substâncias utilizáveis para tais propósitos em composições agroquímicas. Como exemplos preferidos refere-se derivados de celulose, derivados de ácido acrílico, xantano, argilas modificadas e sílica finamente dividida.[162] As secondary thickeners that may be present in seed coating formulations usable in accordance with the invention are all substances usable for such purposes in agrochemical compositions. Preferred examples include cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and finely divided silica.

[163] Como adesivos que podem estar presentes nas formulações de revestimento de sementes utilizáveis de acordo com a invenção refere-se todos os aglutinantes convencionais utilizáveis em produtos de revestimento de sementes. Como exemplos preferidos refere-se polivinilpirrolidona, acetato de polivinila, álcool polivinílico e tilose.[163] As adhesives that may be present in seed coating formulations usable according to the invention are all conventional binders usable in seed coating products. Preferred examples include polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and tylose.

[164] De preferência, as giberelinas que podem estar presentes nas formulações de revestimento de sementes utilizáveis de acordo com a invenção podem ser giberelinas A1, A3 (= ácido giberélico), A4 e A7; é particularmente preferida a utilização de ácido giberélico. As giberelinas são conhecidas (cf. R. Wegler "Chemie der Pflanzenschutz- und Schãdlingsbekãmpfungsmittel"[Chemistry of Crop Protection Compositions and Pesticides], vol. 2, Springer Verlag, 1970, págs. 401-412).[164] Preferably, the gibberellins which may be present in the seed coating formulations usable according to the invention may be gibberellins A1, A3 (= gibberellic acid), A4 and A7; the use of gibberellic acid is particularly preferred. Gibberellins are known (cf. R. Wegler "Chemie der Pflanzenschutz- und Schãdlingsbekãmpfungsmittel" [Chemistry of Crop Protection Compositions and Pesticides], vol. 2, Springer Verlag, 1970, pp. 401-412).

[165] As formulações de revestimento de sementes utilizáveis de acordo com a invenção podem ser utilizadas, quer directamente quer após diluição prévia com água, para tratar diversos tipos diferentes de sementes, incluindo as sementes de plantas transgénicas. Neste caso, pode ocorrer um efeito sinergístico adicional na interação com as substâncias formadas por expressão.[165] Seed coating formulations usable according to the invention can be used, either directly or after previous dilution with water, to treat several different types of seeds, including seeds from transgenic plants. In this case, an additional synergistic effect may occur in the interaction with the substances formed by expression.

[166] Para o tratamento de sementes com as formulações de revestimento de sementes utilizáveis de acordo com a invenção, ou com as preparações preparadas a partir destas por adição de água, todas as unidades de mistura convencionalmente utilizadas para o revestimento de sementes são úteis. Em particular, o procedimento para o revestimento de sementes consiste em colocar as sementes em uma misturadora, adicionar a quantidade particular desejada de formulações de revestimento de sementes, tal qual ou após diluição prévia com água, e misturar tudo até a formulação se encontrar distribuída homogeneamente sobre as sementes. Se adequado, após estes passos, segue-se um processo de secagem.[166] For the treatment of seeds with the seed coating formulations usable according to the invention, or with the preparations prepared therefrom by adding water, all mixing units conventionally used for seed coating are useful. In particular, the seed coating procedure consists of placing the seeds in a mixer, adding the particular desired amount of seed coating formulations, as such or after previous dilution with water, and mixing everything until the formulation is evenly distributed about the seeds. If appropriate, after these steps, a drying process is followed.

MicotoxinasMycotoxins

[167] Além do mais, o tratamento de acordo com a invenção pode reduzir o teor em micotoxinas no material colhido e nos alimentos e rações preparados a partir deste. Em particular, as micotoxinas compreendem, mas não exclusivamente, as seguintes: desoxinivalenol (DON), nivalenol, 15-Ac-DON, 3-Ac-DON, toxina T2 e HT2, fumonisinas, zearalenona, moniliformina, fusarina, diaceotoxiscirpenol (DAS), beauvericina, enniatina, fusaroproliferina, fusarenol, ocratoxinas, patulina, alcaloides ergot e aflatoxinas, as quais podem ser produzidas, por exemplo, pelos seguintes fungos: Fusarium spec., tais como F. acuminatum, F. asiaticum, F. avenaceum, F. crookwellense, F. culmorum, F. graminearum (Gibberella zeae), F. equiseti, F. fujikoroi, F. musarum, F. oxysporum, F. proliferatum, F. poae, F. pseudograminearum, F. sam- bucinum, F. scirpi, F. semitectum, F. solani, F. sporotrichoides, F. langsethiae, F. subglutinans, F. tricinctum, F. verticillioides, etc., e também por Aspergillus spec., tais como A. flavus, A. parasiticus, A. nomius, A. ochraceus, A. clavatus, A. terreus, A versicolor, Penicillium spec., tais como P. verrucosum, P viridicatum, P. citrinum, P. expansum, P. claviforme, P roqueforti, Claviceps spec., tais como C. purpurea, C fusiformis, C. paspali, C. africana, Stachybotrys spec. e outros.[167] Furthermore, the treatment according to the invention can reduce the mycotoxin content in the harvested material and in the food and feed prepared from it. In particular, mycotoxins include, but are not limited to, the following: deoxynivalenol (DON), nivalenol, 15-Ac-DON, 3-Ac-DON, T2 and HT2 toxin, fumonisins, zearalenone, moniliformine, fusarin, diaceotoxiscirpenol (DAS) , beauvericin, enniatin, fusaroproliferin, fusarenol, ochratoxins, patulin, ergot alkaloids and aflatoxins, which can be produced, for example, by the following fungi: Fusarium spec., such as F. acuminatum, F. asiaticum, F. avenaceum, F crookwellense, F. culmorum, F. graminearum (Gibberella zeae), F. equiseti, F. fujikoroi, F. musarum, F. oxysporum, F. proliferatum, F. poae, F. pseudograminearum, F. sam- bucinum, F scirpi, F. semitectum, F. solani, F. sporotrichoides, F. langsethiae, F. subglutinans, F. tricinctum, F. verticillioides, etc., and also by Aspergillus spec., such as A. flavus, A. parasiticus , A. nomius, A. ochraceus, A. clavatus, A. terreus, A versicolor, Penicillium spec., Such as P. verrucosum, P viridicatum, P. citrinum, P. expansum, P. claviforme, P roqueforti, Claviceps spec., such as C. purpurea, C fusiformis, C. paspali, C. africana, Stachybotrys spec. and others.

Protecção de materialMaterial protection

[168] As composições de acordo com a invenção também podem ser utilizadas na protecção de materiais, para a protecção de materiais industriais contra ataques e destruição por microrganismos indesejados, por exemplo, fungos e insectos.[168] The compositions according to the invention can also be used in the protection of materials, for the protection of industrial materials against attack and destruction by unwanted microorganisms, for example, fungi and insects.

[169] Além disso, as combinações da invenção podem ser utilizadas como composições anti-incrustamento, por si sós ou em combinação com outros ingredientes ativos.[169] In addition, the combinations of the invention can be used as antifouling compositions, either alone or in combination with other active ingredients.

[170] No presente contexto, a expressão “materiais industriais” pretende designar materiais inanimados que tenham sido preparados para utilização industrial. Por exemplo, como materiais industriais que se pretende proteger com os ingredientes ativos de acordo com a invenção contra a modificação ou destruição microbiana é possível referir adesivos, colas, papel, papel de parede e cartão, têxteis, carpetes, couro, madeira, fibras e tecidos, tintas e artigos de plástico, lubrificantes de arrefecimento e outros materiais que possam ser infectados ou destruídos por microrganismos. Entre os materiais que se pretende proteger também é possível referir as partes de instalações fabris e edifícios, por exemplo, circuitos de arrefecimento a água, sistemas de arrefecimento e aquecimento e sistemas de ventilação e de condicionamento de ar, os quais podem ser danificados pela proliferação de microrganismos. No âmbito da presente invenção, como materiais industriais refere-se, de preferência, adesivos, colas, papel e cartão, couro, madeira, tintas, lubrificantes de arrefecimento e fluidos de transferência de calor e, mais preferencialmente, madeira.[170] In the present context, the term "industrial materials" is intended to mean inanimate materials that have been prepared for industrial use. For example, as industrial materials that are intended to be protected with the active ingredients according to the invention against microbial modification or destruction, it is possible to refer to adhesives, glues, paper, wallpaper and cardboard, textiles, carpets, leather, wood, fibers and fabrics, paints and plastic articles, cooling lubricants and other materials that can be infected or destroyed by microorganisms. Among the materials to be protected, it is also possible to mention parts of factory facilities and buildings, for example, water cooling circuits, cooling and heating systems and ventilation and air conditioning systems, which can be damaged by proliferation. of microorganisms. Within the scope of the present invention, industrial materials preferably include adhesives, glues, paper and cardboard, leather, wood, paints, cooling lubricants and heat transfer fluids and, more preferably, wood.

[171] As combinações activas da invenção podem prevenir efeitos adversos, tais como podridão, degradação, descoloração ou formação de bolor.[171] The active combinations of the invention can prevent adverse effects, such as rot, degradation, discoloration or mold formation.

[172] No caso do tratamento de madeira, as composições de acordo com a invenção também podem ser utilizadas contra doença fúngicas capazes de crescer sobre madeira ou dentro de madeira. O termo “madeira” designa todos os tipos de espécies de madeira e todos os tipos de processamento desta madeira utilizados para construção, por exemplo, madeira sólida, madeira de elevada densidade, madeira laminada e contraplacado. O método para o tratamento de madeira de acordo com a invenção consiste principalmente em fazê-la contactar com um ou mais compostos de acordo com a invenção ou uma composição de acordo com a invenção; tal compreende, por exemplo, aplicação directa, pulverização, imersão, injecção ou qualquer outro meio adequado.[172] In the case of wood treatment, the compositions according to the invention can also be used against fungal diseases capable of growing on wood or inside wood. The term “wood” refers to all types of wood species and all types of wood processing used for construction, for example, solid wood, high density wood, laminated and plywood. The method for treating wood according to the invention consists mainly of making it contact with one or more compounds according to the invention or a composition according to the invention; this includes, for example, direct application, spraying, immersion, injection or any other suitable means.

[173] Além disso, os compostos da invenção podem ser utilizados para proteger objectos que entrem em contacto com água salgada e água salobra, em particular cascos, crivos, redes, edifícios, amarras e sistemas de sinalização, contra incrustações.[173] In addition, the compounds of the invention can be used to protect objects that come into contact with salt water and brackish water, in particular hulls, screens, nets, buildings, moorings and signaling systems, against fouling.

[174] O método de acordo com a invenção para o controle de fungos indesejados também pode ser utilizado para a protecção de bens armazenados. Como bens armazenados pretende designar-se substâncias naturais de origem animal ou vegetal ou seus produtos processados que sejam de origem natural, e para os quais seja desejada uma protecção de longo prazo. Os bens armazenados de origem vegetal, por exemplo, plantas ou partes de plantas, tais como caules, folhas, tubérculos, sementes, frutos, grãos, podem ser protegidos momentos após a colheita ou após processamento por (pré-)secagem, humectação, fragmentação, moagem, compressão ou torrefação. Os bens armazenados também compreendem madeira, quer seja não processada, tal como madeira para construção, postes de electricidade e barreiras, ou sob a forma de produtos acabados, tais como mobília. Como bens armazenados de origem animal refere-se, por exemplo, couros, peles e pelos. Os ingredientes ativos da invenção podem prevenir efeitos adversos, tais como podridão, degradação, descoloração ou formação de bolor.[174] The method according to the invention for controlling unwanted fungi can also be used to protect stored goods. Stored goods are intended to be designated natural substances of animal or vegetable origin or their processed products that are of natural origin, and for which long-term protection is desired. Stored goods of plant origin, for example, plants or parts of plants, such as stems, leaves, tubers, seeds, fruits, grains, can be protected moments after harvest or after processing by (pre-) drying, wetting, fragmentation , grinding, compression or roasting. Stored goods also comprise wood, whether unprocessed, such as construction timber, electricity poles and barriers, or in the form of finished products, such as furniture. Stored goods of animal origin include, for example, hides, skins and hair. The active ingredients of the invention can prevent adverse effects, such as rot, degradation, discoloration or mold formation.

[175] Como microrganismos capazes de degradar ou alterar os materiais industriais refere-se, por exemplo, bactérias, fungos, leveduras, algas e organismos mucilaginosos. De preferência, os ingredientes ativos da invenção actuam contra fungos, em particular bolores, fungos descoloradores da madeira e fungos destruidores da madeira (Ascomycetes, Basidiomycetes, Deuteromycetes e Zygomycetes), bem como contra organismos mucilaginosos e algas. Como exemplos é possível referir os microrganismos dos géneros seguintes: Alternaria, tais como Alternaria tenuis; Aspergillus, tais como Aspergillus niger; Chaetomium, tais como Chaetomium globosum; Coniophora, tais como Coniophora puetana; Lentinus, tais como Lentinus tigrinus; Penicillium, tais como Penicillium glaucum; Polyporus, tais como Polyporus versicolor; Aureobasidium, tais como Aureobasidium pullulans; Sclerophoma, tais como Sclerophoma pityophila; Trichoderma, tais como Trichoderma viride; Ophiostoma spp., Ceratocystis spp., Humicola spp., Petriella spp., Trichurus spp., Coriolus spp., Gloeophyllum spp., Pleurotus spp., Poria spp., Serpula spp. e Tyromyces spp., Cladosporium spp., Paecilomyces spp., Mucor spp., Escherichia, tais como Escherichia coli; Pseudomonas, tais como Pseudomonas aeruginosa; Staphylococcus, tais como Staphylococcus aureus, Candida spp. e Saccharomyces spp., tais como Saccharomyces cerevisae.[175] Microorganisms capable of degrading or altering industrial materials include, for example, bacteria, fungi, yeasts, algae and mucilaginous organisms. Preferably, the active ingredients of the invention act against fungi, in particular molds, wood decolorizing fungi and wood destroying fungi (Ascomycetes, Basidiomycetes, Deuteromycetes and Zygomycetes), as well as against mucilaginous organisms and algae. As examples it is possible to mention the microorganisms of the following genera: Alternaria, such as Alternaria tenuis; Aspergillus, such as Aspergillus niger; Chaetomium, such as Chaetomium globosum; Coniophora, such as Coniophora puetana; Lentinus, such as Lentinus tigrinus; Penicillium, such as Penicillium glaucum; Polyporus, such as Polyporus versicolor; Aureobasidium, such as Aureobasidium pullulans; Sclerophoma, such as Sclerophoma pityophila; Trichoderma, such as Trichoderma viride; Ophiostoma spp., Ceratocystis spp., Humicola spp., Petriella spp., Trichurus spp., Coriolus spp., Gloeophyllum spp., Pleurotus spp., Poria spp., Serpula spp. and Tyromyces spp., Cladosporium spp., Paecilomyces spp., Mucor spp., Escherichia, such as Escherichia coli; Pseudomonas, such as Pseudomonas aeruginosa; Staphylococcus, such as Staphylococcus aureus, Candida spp. and Saccharomyces spp., such as Saccharomyces cerevisae.

Atividade antimicóticaAntimycotic activity

[176] Além do mais, as combinações da invenção também apresentam uma atividade antimicótica muito boa. Apresentam um espectro de atividade antimicótica muito alargado, em particular contra dermatófitos e leveduras, bolores e fungos difásicos (por exemplo, contra a espécie Candida, tal como C. albicans, C. glabrata) e Epidermophyton floccosum, espécie Aspergillus, tal como A. niger e A. fumigatus, espécie Trichophyton, tal como T. mentagrophytes, espécie Microsporon, tal como M. canis e M. audouinii. A listagem destes fungos não constitui de um modo qualquer uma restrição ao espectro micótico coberto e possui apenas um carácter ilustrativo.[176] Furthermore, the combinations of the invention also have very good antimycotic activity. They have a very broad spectrum of antimycotic activity, in particular against dermatophytes and yeasts, molds and diphasic fungi (for example, against the Candida species, such as C. albicans, C. glabrata) and Epidermophyton floccosum, Aspergillus species, such as A. niger and A. fumigatus, Trichophyton species, such as T. mentagrophytes, Microsporon species, such as M. canis and M. audouinii. The listing of these fungi does not in any way constitute a restriction on the covered mycotic spectrum and is for illustrative purposes only.

[177] Assim sendo, as combinações da invenção podem ser utilizadas em aplicações médicas e em aplicações não médicas.[177] Therefore, the combinations of the invention can be used in medical and non-medical applications.

GMOGMO

[178] Tal como aqui referido antes, é possível tratar todas as plantas e suas partes de acordo com a invenção. De acordo com uma variante preferida, efectua-se o tratamento de espécies e variedades de plantas e de partes de plantas selvagens ou obtidas por métodos de cultura biológica convencional, tais como cruzamento ou fusão de protoplastos. De acordo com uma variante mais preferida, efectua-se o tratamento de plantas, variedades de plantas e partes de plantas transgénicas obtidas por métodos de engenharia genética, facultativamente em combinação com métodos convencionais (Organismos Geneticamente Modificados). O termo "partes" ou "partes de plantas" foi explicado antes. De um modo particularmente preferido, as plantas que são tratadas de acordo com a invenção são as plantas das variedades que se encontram comercialmente disponíveis ou em utilização. A expressão "variedades de plantas" pretende designar as plantas que possuem novas propriedades ("traços") e que foram obtidas por cultura convencional, por mutagénese ou por técnicas de ADN recombinante. Podem ser cultivares, variedades, biótipos ou genótipos.[178] As mentioned above, it is possible to treat all plants and their parts according to the invention. According to a preferred variant, the treatment of species and varieties of plants and parts of wild plants is carried out or obtained by conventional biological culture methods, such as crossing or fusion of protoplasts. According to a more preferred variant, the treatment of plants, plant varieties and parts of transgenic plants obtained by genetic engineering methods is carried out, optionally in combination with conventional methods (Genetically Modified Organisms). The term "parts" or "parts of plants" has been explained before. Particularly preferably, the plants that are treated according to the invention are plants of the varieties that are commercially available or in use. The term "plant varieties" is intended to mean plants that have new properties ("traits") and that have been obtained by conventional culture, mutagenesis or by recombinant DNA techniques. They can be cultivars, varieties, biotypes or genotypes.

[179] O método de tratamento de acordo com a invenção pode ser utilizado para o tratamento de organismos geneticamente modificados (GMO), v.g., plantas ou sementes. As plantas geneticamente modificadas (ou plantas transgénicas) são plantas nas quais foi integrado estavelmente um gene heterólogo no genoma. A expressão "gene heterólogo"designa essencialmente um gene que é proveniente ou que é montado no exterior da planta e que quando é introduzido no genoma nuclear, cloroplástico ou mitocondrial proporciona à planta transformada novas ou melhoradas propriedades agronómicas ou outras através da expressão de uma proteína ou polipéptido relevante ou por desregulação ou silenciamento de outro(s) gene(s) que estejam presentes na planta (utilizando, por exemplo, tecnologia anti-sentido, tecnologia de co-supressão ou tecnologia de interferência de ARN - RNAi ou tecnologia de microARN - miRNA). Um gene heterólogo que esteja localizado no genoma é também designado por um transgene. Um transgene que é definido pela sua localização particular no genoma da planta é designado uma transformação ou evento transgénico.[179] The treatment method according to the invention can be used for the treatment of genetically modified organisms (GMO), e.g., plants or seeds. Genetically modified plants (or transgenic plants) are plants in which a heterologous gene has been stably integrated into the genome. The term "heterologous gene" essentially refers to a gene that is derived from or that is assembled outside the plant and that when introduced into the nuclear, chloroplastic or mitochondrial genome provides the transformed plant with new or improved agronomic or other properties through the expression of a protein or relevant polypeptide or by deregulation or silencing of other gene (s) that are present in the plant (using, for example, antisense technology, co-suppression technology or RNA interference technology - RNAi or microRNA technology - miRNA). A heterologous gene that is located in the genome is also called a transgene. A transgene that is defined by its particular location in the plant's genome is called a transgenic transformation or event.

[180] Dependendo da espécie da planta ou das variedades da planta, da sua localização e das condições de crescimento (solos, clima, período de vegetação, dieta), o tratamento de acordo com a invenção também pode proporcionar efeitos sobreaditivos (“sinergísticos"). Assim, por exemplo, é possível conseguir uma redução das taxas de aplicação e/ou um alargamento do espectro de atividade e/ou um aumento da atividade dos compostos ativos e composições utilizáveis de acordo com a invenção, um melhor crescimento da planta, uma maior tolerância a temperaturas elevadas ou reduzidas, uma maior tolerância à seca ou a água ou ao teor em sais no solo, um maior desempenho de floração, uma maior facilidade de colheita, uma maturação acelerada, maiores rendimentos de colheita, frutos maiores, maior altura das plantas, coloração mais verde das folhas, floração mais rápida, uma melhor qualidade e/ou um valor nutricional superior dos produtos colhidos, uma concentração superior em açúcar nos frutos, uma maior estabilidade ao armazenamento e/ou uma maior facilidade de processamento dos produtos colhidos, efeitos estes que excedem os efeitos que se poderia prever na realidade.[180] Depending on the species of the plant or the varieties of the plant, its location and growing conditions (soils, climate, vegetation period, diet), the treatment according to the invention can also provide over-additive effects ("synergistic" Thus, for example, it is possible to achieve a reduction in application rates and / or a broadening of the activity spectrum and / or an increase in the activity of the active compounds and compositions usable according to the invention, better plant growth, greater tolerance to elevated or reduced temperatures, greater tolerance to drought or water or to the content of salts in the soil, greater flowering performance, greater ease of harvest, accelerated ripening, greater yields, larger fruits, greater plant height, greener leaf color, faster flowering, better quality and / or a higher nutritional value of the harvested products, a higher concentration of sugar in the fruits, a greater storage stability and / or easier processing of harvested products, effects that exceed the effects that could be predicted in reality.

[181] Para determinadas taxas de aplicação, as combinações de acordo com a invenção também podem apresentar um efeito fortificador nas plantas. Assim sendo, são adequadas para mobilizar o sistema de defesa da planta contra ataques por microrganismos indesejados. Se adequado, tal pode constituir uma das razões para a atividade aumentada das combinações de acordo com a invenção, por exemplo, contra fungos. Como substâncias fortificadoras de plantas (indutoras de resistência) pretende-se designar, no presente contexto, aquelas substâncias ou combinações de substâncias que são capazes de estimular o sistema de defesa das plantas de um modo tal que as plantas tratadas, quando subsequentemente inoculadas com microrganismos indesejados, desenvolvem um elevado grau de resistência contra esses microrganismos. No presente caso, como microrganismos indesejados pretende-se designar fungos fitopatogénicos, bactérias e vírus. Assim, as substâncias de acordo com a invenção podem ser utilizadas para proteger plantas contra ataques pelos patogénios supramencionados decorrido um determinado intervalo de tempo após o tratamento. O período de tempo durante o qual a protecção é conferida está normalmente compreendido entre 1 e 10 dias e de preferência entre 1 e 7 dias, após o tratamento das plantas com os compostos ativos.[181] For certain application rates, the combinations according to the invention can also have a strengthening effect on plants. Therefore, they are suitable for mobilizing the plant's defense system against attacks by unwanted microorganisms. If appropriate, this may be one of the reasons for the increased activity of the combinations according to the invention, for example, against fungi. As plant-fortifying substances (resistance inducers) we intend to designate, in the present context, those substances or combinations of substances that are capable of stimulating the defense system of plants in such a way that the treated plants, when subsequently inoculated with microorganisms unwanted, develop a high degree of resistance against these microorganisms. In the present case, unwanted microorganisms are intended to refer to phytopathogenic fungi, bacteria and viruses. Thus, the substances according to the invention can be used to protect plants against attack by the aforementioned pathogens after a certain period of time after treatment. The period of time during which protection is conferred is normally between 1 and 10 days and preferably between 1 and 7 days, after the treatment of the plants with the active compounds.

[182] As plantas e variedades de plantas que são preferencialmente tratadas de acordo com a invenção compreendem todas as plantas que possuem material genético que confira características úteis e particularmente vantajosas a essas plantas (sejam estas obtidas por meios de cultura e/ou meios biotecnológicos).[182] The plants and varieties of plants that are preferably treated according to the invention include all plants that have genetic material that gives useful and particularly advantageous characteristics to these plants (whether obtained by means of culture and / or biotechnological means) .

[183] As plantas e as variedades de plantas que também são preferencialmente tratadas de acordo com as combinações são resistentes contra um ou mais stresses bióticos, isto é, as referidas plantas apresentam uma melhor defesa contra pragas animais e microbianas, tais como contra nematodes, insectos, ácaros, fungos fitopatogénicos, bactérias, vírus e/ou viróides.[183] Plants and plant varieties that are also preferably treated according to the combinations are resistant to one or more biotic stresses, that is, the said plants have a better defense against animal and microbial pests, such as against nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and / or viroids.

[184] Como exemplos de plantas resistentes a nematodes ou insectos refere-se as descritas, v.g., nos pedidos de patente de invenção norte-americanos nos. 11/765 491, 11/765 494, 10/926 819, 10/782 020, 12/032 479, 10/783 417, 10/782 096, 11/657 964, 12/192 904, 11/396 808, 12/166 253, 12/166 239, 12/166 124, 12/166 209, 11/762 886, 12/364 335, 11/763 947, 12/252 453, 12/209 354, 12/491 396, 12/497 221, 12/644 632, 12/646 004, 12/701 058, 12/718 059, 12/721 595, 12/638 591.[184] Examples of plants resistant to nematodes or insects include those described, e.g., in US patent applications nos. 11/765 491, 11/765 494, 10/926 819, 10/782 020, 12/032 479, 10/783 417, 10/782 096, 11/657 964, 12/192 904, 11/396 808, 12/166 253, 12/166 239, 12/166 124, 12/166 209, 11/762 886, 12/364 335, 11/763 947, 12/252 453, 12/209 354, 12/491 396, 12/497 221, 12/644 632, 12/646 004, 12/701 058, 12/718 059, 12/721 595, 12/638 591.

[185] As plantas e variedades de plantas que também podem ser tratadas de acordo com a invenção são aquelas plantas que são resistentes a um ou mais stresses abióticos. As condições de stress abiótico podem compreender, por exemplo, seca, exposição a temperaturas frias, exposição a calor, stress osmótico, inundação, aumento da salinidade do solo, aumento à exposição a minerais, exposição a ozono, exposição elevada a luz, disponibilidade limitada de nutrientes de azoto, disponibilidade limitada de nutrientes de fósforo, ausência de sombra.[185] The plants and varieties of plants that can also be treated according to the invention are those plants that are resistant to one or more abiotic stresses. Abiotic stress conditions may include, for example, drought, exposure to cold temperatures, exposure to heat, osmotic stress, flooding, increased soil salinity, increased exposure to minerals, exposure to ozone, high exposure to light, limited availability nitrogen nutrients, limited availability of phosphorus nutrients, no shade.

[186] As plantas e variedades de plantas que também podem ser tratadas de acordo com a invenção são aquelas plantas caracterizadas por características aumentadas de rendimento. O rendimento aumentado nas referidas plantas pode ser o resultado, por exemplo, de uma melhoria na fisiologia, crescimento e desenvolvimento da planta, tal como eficácia na utilização de água, eficácia na retenção de água, utilização de azoto melhorada, assimilação de carbono melhorada, fotossíntese melhorada, eficácia de germinação aumentada e maturação acelerada. Além disso, o rendimento pode ser afectado por uma arquitectura melhorada da planta (sob condições de stress e na ausência de stress), incluindo, mas sem que isso constitua qualquer limitação. Floração mais rápida, controle da floração para a produção de sementes híbridas, vigor dos rebentos, tamanho da planta, número e distância internodal, crescimento das raízes, tamanho das sementes, tamanho dos frutos, tamanho das vagens, número de vagens e espigas, número de sementes por vagem ou espiga, massa da semente, enchimento aumentado da semente, dispersão reduzida da semente, deiscência reduzida da vagem e resistência ao acamamento. Outras características do rendimento compreendem a composição da semente, tal como o teor em hidratos de carbono, teor em proteínas, teor e composição em óleo, valor nutricional, redução nos compostos anti- nutricionais, processabilidade melhorada e melhor estabilidade ao armazenamento.[186] The plants and varieties of plants that can also be treated according to the invention are those plants characterized by increased yield characteristics. The increased yield in said plants may be the result, for example, of an improvement in the physiology, growth and development of the plant, such as efficiency in water use, efficiency in water retention, improved nitrogen utilization, improved carbon assimilation, improved photosynthesis, increased germination efficiency and accelerated maturation. In addition, performance can be affected by improved plant architecture (under stress conditions and in the absence of stress), including, but not limited to, this. Faster flowering, flowering control for hybrid seed production, shoot vigor, plant size, internodal number and distance, root growth, seed size, fruit size, pod size, number of pods and ears, number of seeds per pod or ear, seed mass, increased seed filling, reduced seed dispersion, reduced pod dehiscence and lodging resistance. Other yield characteristics include seed composition, such as carbohydrate content, protein content, oil content and composition, nutritional value, reduction in anti-nutritional compounds, improved processability and better storage stability.

[187] As plantas que podem ser tratadas de acordo com a invenção são plantas híbridas que já expressam as características de heterose ou vigor híbrido que proporciona normalmente um melhor rendimento, vigor, saúde e resistência face a stresses bióticos e abióticos. Tipicamente, tais plantas são preparadas por cruzamento de uma linhagem progenitora estéril macho consanguínea (progenitor fêmea) com outra linhagem progenitora fértil macho consanguínea (progenitor macho). Tipicamente, as sementes híbridas são colhidas a partir das plantas estéreis macho e vendidas a produtores. As plantas estéreis macho podem, por vezes (v.g., no milho), ser produzidas por corte da panícula, isto é, remoção mecânica dos órgãos reprodutores masculinos (ou flores macho), embora, mais tipicamente, a esterilidade masculina seja resultado de determinantes genéticos no genoma da planta. Neste caso, e particularmente quando a semente constitui o produto desejado que se pretende colher a partir das plantas híbridas, é tipicamente útil garantir que a fertilidade masculina nas plantas híbridas seja totalmente restaurada. Tal pode ser efectuado garantindo que as progenitoras masculinas possuem os genes restauradores de fertilidade adequados, os quais são capazes de restaurar a fertilidade masculina nas plantas híbridas que contêm os determinantes genéticos responsáveis pela esterilidade masculina. Os determinantes genéticos para a esterilidade masculina podem estar localizados no citoplasma. Exemplos de esterilidade masculina citoplásmica (CMS) foram descritos, por exemplo, para a espécie Brassica (WO 92/05251, WO 95/09910, WO 98/27806, WO 05/002324, WO 06/021972 e US 6 229 072). No entanto, os determinantes genéticos para a esterilidade masculina também podem estar localizados no genoma nuclear. As plantas com esterilidade masculina também podem ser obtidas por métodos biotecnológicos de plantas, tais como engenharia genética. Um meio particularmente útil para se obter plantas com esterilidade masculina encontra-se descrito no documento WO 89/10396, no qual, por exemplo, uma ribonuclease, tal como barnase, é selectivamente expressa em células tapetum nos estames. A fertilidade pode então ser restaurada por expressão nas células tapetum de um inibidor de ribonuclease, tal como barstar, (v.g., WO 91/02069).[187] The plants that can be treated according to the invention are hybrid plants that already express the characteristics of heterosis or hybrid vigor that normally provides better performance, vigor, health and resistance to biotic and abiotic stresses. Typically, such plants are prepared by crossing a sterile inbred male parent line (female parent) with another inbred male fertile parent line (male parent). Typically, hybrid seeds are harvested from sterile male plants and sold to producers. Sterile male plants can sometimes (eg, in corn) be produced by cutting the panicle, that is, mechanical removal of the male reproductive organs (or male flowers), although, more typically, male sterility is the result of genetic determinants in the plant genome. In this case, and particularly when the seed is the desired product to be harvested from hybrid plants, it is typically useful to ensure that male fertility in hybrid plants is fully restored. This can be done by ensuring that male parents have the appropriate fertility restoring genes, which are capable of restoring male fertility in hybrid plants that contain the genetic determinants responsible for male sterility. The genetic determinants for male sterility may be located in the cytoplasm. Examples of cytoplasmic male sterility (CMS) have been described, for example, for the species Brassica (WO 92/05251, WO 95/09910, WO 98/27806, WO 05/002324, WO 06/021972 and US 6 229 072). However, the genetic determinants for male sterility can also be located in the nuclear genome. Plants with male sterility can also be obtained by plant biotechnological methods, such as genetic engineering. A particularly useful means of obtaining plants with male sterility is described in WO 89/10396, in which, for example, a ribonuclease, such as barnase, is selectively expressed in tapetum cells in the stamens. Fertility can then be restored by expression in tapetum cells of a ribonuclease inhibitor, such as barstar, (e.g., WO 91/02069).

[188] As plantas ou variedades de plantas (obtidas por métodos de biotecnologia de plantas, tais como engenharia genética) que podem ser tratadas de acordo com a invenção são plantas tolerantes a herbicidas, isto é, plantas tornadas tolerantes a um ou mais herbicidas específicos. Tais plantas podem ser obtidas por transformação genética ou por meio de selecção de plantas que contêm uma mutação que lhes confira tal tolerância ao herbicida.[188] The plants or plant varieties (obtained by plant biotechnology methods, such as genetic engineering) that can be treated according to the invention are herbicide tolerant plants, that is, plants made tolerant to one or more specific herbicides . Such plants can be obtained by genetic transformation or by selecting plants that contain a mutation that gives them such tolerance to the herbicide.

[189] As plantas tolerantes a herbicidas são, por exemplo, plantas tolerantes a glifosato, isto é, plantas tornadas tolerantes ao herbicida glifosato ou aos seus sais. As plantas podem ser tornadas tolerantes a glifosato de diferentes modos. Por exemplo, plantas tolerantes a glifosato podem ser obtidas por meio da transformação da planta com um gene que codifica a enzima 5- enolpiruvilshiquimato-3-fosfato sintase (EPSPS). Como exemplos de tais genes EPSPS refere-se o gene AroA (mutante CT7) da bactéria Salmonella typhimurium (Science 1983, 221, 370-371), o gene CP4 da bactéria Agrobacterium sp. (Curr. Topics Plant Physiol. 1992, 7, 139-145), os genes que codificam uma EPSPS de petúnia (Science 1986, 233, 478- 481), uma EPSPS de tomate (J. Biol. Chem. 1988, 263, 4280- 4289) ou uma EPSPS de eleusina (documento WO 01/66704). Também podem ser uma EPSPS mutada, conforme descrito, por exemplo, nos documentos EP 0837944, WO 00/66746, WO 00/66747 ou WO 02/26995. As plantas tolerantes a glifosato também podem ser obtidas por meio da expressão de um gene que codifica uma enzima glifosato oxidoreductase, tal como descrito nos documentos US 5 776 760 e US 5 463 175. As plantas tolerantes a glifosato também podem ser obtidas por meio da expressão de um gene que codifica uma enzima glifosato acetil-transferase, tal como descrito, por exemplo, nos documentos WO 02/036782, WO 03/092360, WO 2005/012515 e WO 2007/024782. As plantas tolerantes a glifosato também podem ser obtidas por meio da selecção de plantas que contêm mutações que ocorrem naturalmente dos genes supramencionados, tal como descrito, por exemplo, nos documentos WO 01/024615 ou WO 03/013226. As plantas que expressam genes EPSPS que conferem tolerância a glifosato encontram-se descritas, v.g., nos pedidos de patente de invenção norte-americana nos. 11/517 991, 10/739 610, 12/139 408, 12/352 532, 11/312 866, 11/315 678, 12/421 292, 11/400 598, 11/651 752, 11/681 285, 11/605 824, 12/468 205, 11/760 570, 11/762 526, 11/769 327, 11/769 255, 11/943 801 ou 12/362 774. As plantas que compreendem outros genes que conferem tolerância a glifosato, tais como genes descarboxilase, encontram-se descritas, v.g., nos pedidos de patente de invenção norte-americana nos. 11/588 811, 11/185 342, 12/364 724, 11/185 560 ou 12/423 926.[189] Herbicide-tolerant plants are, for example, glyphosate-tolerant plants, that is, plants made tolerant to the glyphosate herbicide or its salts. Plants can be made tolerant to glyphosate in different ways. For example, glyphosate-tolerant plants can be obtained by transforming the plant with a gene that encodes the enzyme 5-enolpyruvylshiquimato-3-phosphate synthase (EPSPS). Examples of such EPSPS genes include the AroA gene (CT7 mutant) of the bacterium Salmonella typhimurium (Science 1983, 221, 370-371), the CP4 gene of the bacterium Agrobacterium sp. (Curr. Topics Plant Physiol. 1992, 7, 139-145), the genes encoding a petunia EPSPS (Science 1986, 233, 478- 481), a tomato EPSPS (J. Biol. Chem. 1988, 263, 4280- 4289) or an EPSPS of eleusina (WO 01/66704). They can also be a mutated EPSPS, as described, for example, in EP 0837944, WO 00/66746, WO 00/66747 or WO 02/26995. Glyphosate-tolerant plants can also be obtained by expressing a gene encoding a glyphosate oxidoreductase enzyme, as described in US 5 776 760 and US 5 463 175. Glyphosate-tolerant plants can also be obtained by using expression of a gene encoding a glyphosate acetyl transferase enzyme, as described, for example, in WO 02/036782, WO 03/092360, WO 2005/012515 and WO 2007/024782. Glyphosate-tolerant plants can also be obtained by selecting plants that contain naturally occurring mutations of the aforementioned genes, as described, for example, in WO 01/024615 or WO 03/013226. Plants that express EPSPS genes that confer glyphosate tolerance are described, e.g., in U.S. patent applications nos. 11/517 991, 10/739 610, 12/139 408, 12/352 532, 11/312 866, 11/315 678, 12/421 292, 11/400 598, 11/651 752, 11/681 285, 11/605 824, 12/468 205, 11/760 570, 11/762 526, 11/769 327, 11/769 255, 11/943 801 or 12/362 774. Plants that comprise other genes that confer tolerance to glyphosate, such as decarboxylase genes, are described, e.g., in U.S. patent applications nos. 11/588 811, 11/185 342, 12/364 724, 11/185 560 or 12/423 926.

[190] Como outras plantas resistentes a herbicidas refere-se, por exemplo, plantas que são tornadas tolerantes a herbicidas que inibem a enzima glutamina sintase, tais como bialafos, fosfinotricina ou glufosinato. Tais plantas podem ser obtidas por meio de expressão de uma enzima desintoxicante do herbicida ou uma enzima glutamina sintase mutante que seja resistente a inibição, v.g., descrita no pedido de patente de invenção norte-americana n° . 11/760 602. Uma tal enzima desintoxicante eficaz é uma enzima que codifica um fosfinotricina acetil-transferase (tal como a proteína bar ou pat proveniente da espécie Streptomyces). As plantas que expressam uma fosfinotricina acetil- transferase exógena encontram-se descritas nas patentes de invenção norte-americanas nos. 5 561 236; 5 648 477; 5 646 024; 5 273 894; 5 637 489; 5 276 268; 5 739 082; 5 908 810 e 7 112 665.[190] Other herbicide-resistant plants include, for example, plants that are made tolerant to herbicides that inhibit the enzyme glutamine synthase, such as bialafos, phosphinothricin or glufosinate. Such plants can be obtained by expression of a herbicide detoxifying enzyme or a mutant glutamine synthase enzyme that is resistant to inhibition, e.g., described in U.S. Patent Application No. 11/760 602. Such an effective detoxifying enzyme is an enzyme that encodes a phosphinothricin acetyl transferase (such as the bar or pat protein from the species Streptomyces). Plants that express an exogenous phosphinothricin acetyl transferase are described in U.S. Patent Nos. 5,561,236; 5,648,477; 5 646 024; 5,273,894; 5 637 489; 5,276,268; 5,739,082; 5,908,810 and 7,112,665.

[191] Além disso, outras plantas tolerantes a herbicidas são também plantas que são tornadas tolerantes a herbicidas que inibem a enzima hidroxifenilpiruvato-dioxigenase (HPPD). A HPPD é uma enzima que catalisa a reação pela qual para-hidroxifenilpiruvato (HPP) é transformado em homogentisato. As plantas tolerantes a inibidores de HPPD podem ser transformadas com um gene que codifica uma enzima HPPD resistente que ocorra naturalmente ou um gene que codifica uma enzima HPPD mutada ou quimérica, tal como descrito nos documentos WO 96/38567, WO 99/24585, WO 99/24586, WO 09/144079, WO 02/046387 ou US 6 768 044. A tolerância a inibidores de HPPD também pode ser obtida por meio da transformação de plantas com genes que codificam determinadas enzimas que permitem a formação de homogentisato apesar da inibição da enzima HPPD nativa pelo inibidor de HPPD. Tais plantas e genes encontram-se descritos nos documentos WO 99/34008 e WO 02/36787. A tolerância das plantas a inibidores de HPPD também pode ser melhorada por meio da transformação de plantas com um gene que codifica uma enzima que possui atividade de prefenato desidrogenase (PDH) para além de um gene que codifica uma enzima tolerante a HPPD, conforme descrito no documento WO 04/024928. Além disso, as plantas podem ser tornadas tolerantes a herbicidas inibidores de HPPD por adição ao seu genoma de um gene que codifica uma enzima capaz de metabolizar ou de degradar os inibidores de HPPD, tais como as enzimas CYP450 descritas nos documentos WO 2007/103567 e WO 2008/150473.[191] In addition, other herbicide-tolerant plants are also plants that are made tolerant to herbicides that inhibit the enzyme hydroxyphenylpyruvate-dioxigenase (HPPD). HPPD is an enzyme that catalyzes the reaction by which parahydroxyphenylpyruvate (HPP) is transformed into homogentisate. Plants tolerant to HPPD inhibitors can be transformed with a gene encoding a naturally occurring resistant HPPD enzyme or a gene encoding a mutated or chimeric HPPD enzyme, as described in WO 96/38567, WO 99/24585, WO 99/24586, WO 09/144079, WO 02/046387 or US 6 768 044. Tolerance to HPPD inhibitors can also be obtained by transforming plants with genes that encode certain enzymes that allow the formation of homogentisate despite inhibition of the native HPPD enzyme by the HPPD inhibitor. Such plants and genes are described in WO 99/34008 and WO 02/36787. Plant tolerance to HPPD inhibitors can also be improved by transforming plants with a gene that encodes an enzyme that has prefenate dehydrogenase (PDH) activity in addition to a gene that encodes an HPPD-tolerant enzyme, as described in WO 04/024928. In addition, plants can be made tolerant to HPPD-inhibiting herbicides by adding to their genome a gene encoding an enzyme capable of metabolizing or degrading HPPD-inhibitors, such as the CYP450 enzymes described in WO 2007/103567 and WO 2008/150473.

[192] Outras plantas resistentes a herbicidas são plantas que são tornadas tolerantes a inibidores de acetolactato sintase (ALS). Como inibidores de ALS conhecidos refere-se, por exemplo, os herbicidas sulfonilureia, imidazolinona, triazolopirimidinas, pirimidiniloxi(tio)-benzoatos e/ou sulfonilaminocarbonil-triazolinona. São conhecidas diferentes mutações na enzima ALS (também conhecida como aceto-hidroxi-ácido sintase, AHAS) que conferem tolerância a herbicidas e grupos de herbicidas diferentes, tal como descrito, por exemplo, por Tranel e Wright (Weed Science 2002, 50, 700-712), mas também nas patentes de invenção norte-americanas nos. 5 605 011, 5 378 824, 5 141 870 e 5 013 659. A produção de plantas tolerantes a sulfonil-ureia e a imidazolinona encontra-se descrita nas patentes de invenção norte-americanas nos. 5 605 011; 5 013 659; 5 141 870; 5 767 361; 5 731 180; 5 304 732; 4 761 373; 5 331 107; 5 928 937 e 5 378 824; e no documento WO 96/33270. Outras plantas tolerantes a imidazolinona também se encontram descritas, por exemplo, nos documentos WO 2004/040012, WO 2004/106529, WO 2005/020673, WO 2005/093093, WO 2006/007373, WO 2006/015376, WO 2006/024351 e WO 2006/060634. Ainda outras plantas tolerantes a sulfonil- ureia e a imidazolinona também se encontram descritas, por exemplo, no documento WO 2007/024782 e no pedido de patente de invenção norte-americana n°. 61/288958.[192] Other herbicide-resistant plants are plants that are made tolerant to acetolactate synthase (ALS) inhibitors. Known ALS inhibitors include, for example, the herbicides sulfonylurea, imidazolinone, triazolopyrimidines, pyrimidinyloxy (thio) -benzoates and / or sulfonylaminocarbonyl-triazolinone. Different mutations in the ALS enzyme (also known as acetohydroxy acid synthase, AHAS) are known to confer tolerance to different herbicides and groups of herbicides, as described, for example, by Tranel and Wright (Weed Science 2002, 50, 700 -712), but also in US Patent Nos. 5,605,011, 5,378,824, 5,141,870 and 5,013,659. The production of plants tolerant to sulfonylurea and imidazolinone is described in U.S. Pat. 5,605,011; 5,013,659; 5,141,870; 5,767,361; 5,731,180; 5,304,732; 4,761,373; 5,331,107; 5,928,937 and 5,378,824; and WO 96/33270. Other imidazolinone tolerant plants are also described, for example, in WO 2004/040012, WO 2004/106529, WO 2005/020673, WO 2005/093093, WO 2006/007373, WO 2006/015376, WO 2006/024351 and WO 2006/060634. Still other plants tolerant to sulfonylurea and imidazolinone are also described, for example, in WO 2007/024782 and in U.S. Patent Application No. 61/288958.

[193] Outras plantas tolerantes a imidazolinona e/ou sulfonil-ureia podem ser obtidas por mutagénese induzida, selecção em culturas de células na presença do herbicida ou criação da mutação, tal como descrito, por exemplo, para soja na patente de invenção norte-americana n°. 5 084 082, para arroz no documento WO 97/41218, para beterraba sacarina na patente de invenção norte-americana n°. 5 773 702 e no documento WO 99/057965, para alface na patente de invenção norte-americana n°. 5 198 599 ou para girassol no documento WO 01/065922.[193] Other imidazolinone and / or sulfonyl urea tolerant plants can be obtained by induced mutagenesis, selection in cell cultures in the presence of the herbicide or creation of the mutation, as described, for example, for soybeans in the US patent. American No. 5,084,082, for rice in WO 97/41218, for sugar beet in U.S. Patent No. 5,773,702 and WO 99/057965, for lettuce in U.S. Patent No. 5 198 599 or for sunflower in WO 01/065922.

[194] As plantas ou variedades de plantas (obtidas por métodos biotecnológicos de plantas, tais como engenharia genética) que também podem ser tratadas de acordo com a invenção são plantas transgénicas resistentes a insectos, isto é, plantas tornadas resistentes ao ataque por determinados insectos alvo. Tais plantas podem ser obtidas por transformação genética ou por meio da selecção de plantas que contêm uma mutação que confere tal resistência a insectos.[194] The plants or plant varieties (obtained by biotechnological methods of plants, such as genetic engineering) that can also be treated according to the invention are transgenic plants resistant to insects, that is, plants made resistant to attack by certain insects target. Such plants can be obtained by genetic transformation or by selecting plants that contain a mutation that confers such resistance to insects.

[195] Uma "planta transgénica resistente a insectos", tal como aqui utilizada, inclui qualquer planta que contenha pelo menos um transgene que compreenda uma sequência de codificação que codifique: 1) uma proteína cristal insecticida proveniente de Bacillus thuringiensis ou uma sua porção insecticida, tal como as proteínas cristais insecticidas descritas por Crickmore et al. (1998, Microbiology and Molecular Biology Reviews, 62: 807-813), actualizado por Crickmore et al. (2005) na nomenclatura da toxina Bacillus thuringiensis, disponível em:[195] A "insect resistant transgenic plant" as used herein includes any plant that contains at least one transgene that comprises a coding sequence that encodes: 1) an insecticidal crystal protein from Bacillus thuringiensis or an insecticidal portion thereof , such as the crystalline insecticidal proteins described by Crickmore et al. (1998, Microbiology and Molecular Biology Reviews, 62: 807-813), updated by Crickmore et al. (2005) in the nomenclature of the toxin Bacillus thuringiensis, available at:

[196] http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/ Bt/,[196] http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/ Bt /,

[197] ou suas porções insecticidas, v.g., proteínas das classes de proteínas Cry, Cry1Ab, Cry1Ac, Cry1B, Cry1C, Cry1D, Cry1F, Cry2Ab, Cry3Aa ou Cry3Bb ou suas porções insecticidas (v.g., documentos EP 1999141 e WO 2007/107302), ou tais proteínas codificadas pelos genes sintéticos, v.g., tal como descrito no pedido de patente de invenção norte-americana n°. 12/249 016; ou[197] or their insecticidal moieties, eg proteins of the Cry, Cry1Ab, Cry1Ac, Cry1B, Cry1C, Cry1D, Cry1F, Cry2Ab, Cry3Aa or Cry3Bb protein classes or their insecticidal moieties (eg, EP 1999141 and WO 2007/107302) , or such proteins encoded by the synthetic genes, eg, as described in U.S. Patent Application No. 12/249 016; or

[198] 2) uma proteína cristal proveniente de Bacillus thuringiensis ou uma sua porção que seja insecticida na presença de uma segunda proteína cristal diferente proveniente de Bacillus thuringiensis ou uma sua porção, tal como a toxina binária constituída pelas proteínas cristal Cry34 e Cry35 (Nat. Biotechnol. 2001, 19: 668-72; Applied Environm. Microbiol. 2006, 71, 1765-1774) ou a toxina binária constituída pelas proteínas Cry1A ou Cry1F e as proteínas Cry2Aa ou Cry2Ab ou Cry2Ae (pedido de patente de invenção norte-americana n°. 12/214 022 e documento EP-A 2 300 618); ou[198] 2) a crystal protein from Bacillus thuringiensis or a portion thereof that is insecticidal in the presence of a second different crystal protein from Bacillus thuringiensis or a portion thereof, such as the binary toxin consisting of the crystal proteins Cry34 and Cry35 (Nat Biotechnol. 2001, 19: 668-72; Applied Environm. Microbiol. 2006, 71, 1765-1774) or the binary toxin made up of the Cry1A or Cry1F proteins and the Cry2Aa or Cry2Ab or Cry2Ae proteins (US patent application) American No. 12/214 022 and EP-A 2 300 618); or

[199] 3) uma proteína insecticida híbrida que compreende partes de diferentes proteínas cristal insecticidas provenientes de Bacillus thuringiensis, tal como um híbrido das proteínas da alínea 1) anterior ou um híbrido das proteínas da alínea 2) anterior, v.g., a proteína Cry1A.105 produzida pelo evento no milho MON89034 (WO 2007/027777) ou[199] 3) a hybrid insecticidal protein comprising parts of different crystal insecticidal proteins from Bacillus thuringiensis, such as a hybrid of the proteins in the previous paragraph 1) or a hybrid of the proteins in the previous paragraph 2), eg, the Cry1A protein. 105 produced by the event on MON89034 corn (WO 2007/027777) or

[200] 4) uma proteína de qualquer uma das alíneas 1) a 3) anteriores, em que alguns, em particular, 1 a 10, aminoácidos foram substituídos por outros aminoácidos para se obter uma atividade insecticida superior para uma espécie de insecto alvo e/ou para expandir o alcance das espécies de insecto alvo afectadas e/ou devido às alterações introduzidas no ADN de codificação durante a clonagem ou transformação, tal como a proteína Cry3Bb1 nos eventos no milho MON863 ou MON88017 ou a proteína Cry3A no evento no milho MIR 604; ou[200] 4) a protein of any one of the points 1) to 3) above, in which some, in particular, 1 to 10, amino acids have been replaced by other amino acids to obtain superior insecticidal activity for a target insect species and / or to expand the range of the target insect species affected and / or due to changes introduced in the coding DNA during cloning or transformation, such as the Cry3Bb1 protein in the events in MON863 or MON88017 corn or the Cry3A protein in the event in MIR corn 604; or

[201] 5) uma proteína segregada insecticida proveniente de Bacillus thuringiensis ou Bacillus cereus, ou uma sua porção insecticida, tal como as proteínas insecticidas vegetativas (VIP) listadas em:[201] 5) a secreted insecticidal protein from Bacillus thuringiensis or Bacillus cereus, or an insecticidal portion thereof, such as the vegetative insecticidal (VIP) proteins listed under:

[202] http://www.lifesci.sussex.ac.uk//Home/Neil_Crickmor e/Bt/vip.html,[202] http://www.lifesci.sussex.ac.uk//Home/Neil_Crickmor e / Bt / vip.html,

[203] v.g., proteínas da classe de proteínas VIP3Aa ou[203] e.g., proteins of the VIP3Aa or

[204] 6) uma proteína segregada proveniente de Bacillus thuringiensis ou Bacillus cereus que é insecticida na presença de uma segunda proteína segregada proveniente de Bacillus thuringiensis ou B. cereus, tal como a toxina binária constituída pelas proteínas VIP1A e VIP2A (documento WO 94/21795) ou[204] 6) a secreted protein from Bacillus thuringiensis or Bacillus cereus that is insecticidal in the presence of a second secreted protein from Bacillus thuringiensis or B. cereus, such as the binary toxin consisting of the VIP1A and VIP2A proteins (WO 94 / 21795) or

[205] 7) uma proteína insecticida híbrida que compreende partes de proteínas segregadas diferentes provenientes de Bacillus thuringiensis ou Bacillus cereus, tal como um híbrido das proteínas na alínea 1) anterior ou um híbrido das proteínas na alínea 2) anterior ou[205] 7) a hybrid insecticidal protein comprising parts of different secreted proteins from Bacillus thuringiensis or Bacillus cereus, such as a hybrid of the proteins in paragraph 1) above or a hybrid of the proteins in paragraph 2) above or

[206] 8) uma proteína de qualquer uma das alíneas 5) a 7) anteriores, em que alguns, em particular, 1 a 10, aminoácidos foram substituídos por outros aminoácidos para se obter uma atividade insecticida superior para uma espécie de insecto alvo e/ou para expandir o alcance das espécies de insecto alvo afectadas e/ou devido às alterações introduzidas no ADN de codificação durante a clonagem ou transformação (embora codifiquem ainda uma proteína insecticida), tal como a proteína VIP3Aa no evento do algodão COT 102 ou[206] 8) a protein of any one of paragraphs 5) to 7) above, in which some, in particular, 1 to 10, amino acids have been replaced by other amino acids to obtain superior insecticidal activity for a target insect species and / or to expand the range of the target insect species affected and / or due to changes introduced in the coding DNA during cloning or transformation (although they still encode an insecticidal protein), such as the VIP3Aa protein in the COT 102 cotton event or

[207] 9) uma proteína segregada proveniente de Bacillus thuringiensis ou Bacillus cereus que é insecticida na presença de uma proteína cristal proveniente de Bacillus thuringiensis, tal como a toxina binária constituída por VIP3 e Cry1A ou Cry1F (pedidos de patente de invenção norte-americana nos. 61/126083 e 61/195019), ou a toxina binária constituída pela proteína VIP3 e pelas proteínas Cry2Aa ou Cry2Ab ou Cry2Ae (pedido de patente de invenção norte-americana n°. 12/214 022 e documento EP-A 2 300 618);[207] 9) a secreted protein from Bacillus thuringiensis or Bacillus cereus that is insecticidal in the presence of a crystal protein from Bacillus thuringiensis, such as the binary toxin consisting of VIP3 and Cry1A or Cry1F (US patent applications) Nos. 61/126083 and 61/195019), or the binary toxin consisting of the VIP3 protein and the Cry2Aa or Cry2Ab or Cry2Ae proteins (U.S. Patent Application No. 12/214 022 and EP-A 2 300 618);

[208] 10) uma proteína da alínea 9) anterior, em que alguns, em particular, 1 a 10, aminoácidos foram substituídos por outros aminoácidos para se obter uma atividade insecticida superior para uma espécie de insecto alvo e/ou para expandir o alcance das espécies de insecto alvo afectadas e/ou devido às alterações introduzidas no ADN de codificação durante a clonagem ou transformação (embora codifiquem ainda uma proteína insecticida).[208] 10) a protein of paragraph 9) above, in which some, in particular 1 to 10, amino acids have been replaced by other amino acids to obtain superior insecticidal activity for a target insect species and / or to expand the range the target insect species affected and / or due to changes made to the coding DNA during cloning or transformation (although they still encode an insecticidal protein).

[209] Como é evidente, uma planta transgénica resistente a insectos, tal como aqui utilizada, inclui também qualquer planta que compreenda uma combinação de genes que codifiquem as proteínas de qualquer uma das classes 1 a 10 anteriores. De acordo com uma variante, uma planta resistente a insectos contém mais do que um transgene que codifica uma proteína de qualquer uma das classes 1 a 10 anteriores, para expandir o alcance de espécies de insectos alvo afectadas quando se utilizam diferentes proteínas dirigidas a diferentes espécies de insecto alvo ou para retardar o desenvolvimento de resistência dos insectos às plantas, utilizando diferentes proteínas insecticidas para a mesma espécie de insectos alvo, embora apresentando um modo de ação diferente, tal como ligação a diferentes locais de ligação ao receptor no insecto.[209] As is evident, a transgenic insect-resistant plant, as used herein, also includes any plant that comprises a combination of genes that encode the proteins of any of the previous classes 1 to 10. According to one variant, an insect-resistant plant contains more than one transgene that encodes a protein from any of the previous classes 1 to 10, to expand the range of affected target insect species when using different proteins targeting different species of target insect or to delay the development of insect resistance to plants, using different insecticidal proteins for the same species of target insects, although presenting a different mode of action, such as binding to different receptor binding sites on the insect.

[210] Uma “planta transgénica resistente a insectos”, tal como aqui utilizada, inclui ainda qualquer planta que contenha pelo menos um transgene que compreende uma sequência que produz, por expressão, um ARN de cadeia dupla que durante a ingestão pela praga de insectos da planta inibe o crescimento de tal praga de insectos, tal como descrito, v.g., nos documentos WO 2007/080126, WO 2006/129204, WO 2007/074405, WO 2007/080127 e WO 2007/035650.[210] A "insect resistant transgenic plant" as used herein, further includes any plant that contains at least one transgene that comprises a sequence that produces, by expression, a double-stranded RNA that during ingestion by the insect pest of the plant inhibits the growth of such an insect pest, as described, e.g., in WO 2007/080126, WO 2006/129204, WO 2007/074405, WO 2007/080127 and WO 2007/035650.

[211] As plantas e variedades de plantas (obtidas por métodos biotecnológicos de plantas, tais como engenharia genética) que também podem ser tratadas de acordo com a invenção são tolerantes a stresses abióticos. Tais plantas podem ser obtidas por transformação genética ou por meio da selecção de plantas que contêm uma mutação que lhes confere tal resistência ao stress. Como plantas tolerantes ao stress particularmente úteis refere-se: 1) plantas que contêm um transgene capaz de reduzir a expressão e/ou a atividade do gene poli(ADP-ribose) polimerase (PARP) nas células de plantas ou nas plantas, tal como descrito nos documentos WO 00/04173, WO 2006/045633, EP-A 1 807 519 ou EP-A 2 018 431; 2) plantas que contêm um transgene que potencia a tolerância ao stress capaz de reduzir a expressão e/ou a atividade dos genes codificadores de PARG de plantas ou de células de plantas, tal como descrito, v.g., no documento WO 2004/090140; 3) plantas que contêm um transgene que potencia a tolerância ao stress que codifica uma enzima funcional da planta da via de biossíntese do salvamento de nicotinamida adenina dinucleótidos, incluindo nicotinamidase, nicotinato fosforibosiltransferase, ácido nicotínico de monocucléotidos de adeniltransferase, nicotinamida adenina dinucleótido sintetase ou nicotinamida fosforibosil- transferase, tal como descrito, v.g., nos documentos EP-A 1 794 306, WO 2006/ /133827, WO 2007/107326, EP-A 1 999 263 ou WO 2007/107326.[211] Plants and plant varieties (obtained by plant biotechnological methods, such as genetic engineering) that can also be treated according to the invention are tolerant to abiotic stresses. Such plants can be obtained by genetic transformation or by selecting plants that contain a mutation that gives them such resistance to stress. Particularly useful stress-tolerant plants include: 1) plants that contain a transgene capable of reducing the expression and / or activity of the poly (ADP-ribose) polymerase (PARP) gene in plant cells or plants, such as described in WO 00/04173, WO 2006/045633, EP-A 1 807 519 or EP-A 2 018 431; 2) plants that contain a transgene that enhances stress tolerance capable of reducing the expression and / or activity of the genes encoding PARG of plants or plant cells, as described, e.g., in WO 2004/090140; 3) plants containing a transgene that potentiates stress tolerance encoding a functional plant enzyme from the nicotinamide salvage pathway adenine dinucleotides, including nicotinamidase, nicotinate phosphoribosyltransferase, nicotinic acid, adenyltransinamide, nicotinamide, dinotinotide, nicotinamide phosphoribosyl transferase, as described, e.g., in EP-A 1 794 306, WO 2006 / / 133827, WO 2007/107326, EP-A 1 999 263 or WO 2007/107326.

[212] As plantas e variedades de plantas (obtidas por métodos biotecnológicos de plantas, tais como engenharia genética) que também podem ser tratadas de acordo com a invenção apresentam uma quantidade, qualidade e/ou estabilidade ao armazenamento alteradas do produto colhido e/ou propriedades alteradas de ingredientes específicos do produto colhido, tais como: 1) plantas transgénicas que sintetizam um amido modificado, o qual nas suas características físico- químicas, em particular no teor em amilose ou na proporção amilose/amilopectina, no grau de ramificação, no comprimento de cadeia médio, da distribuição da cadeia lateral, no comportamento de viscosidade, na força de gelificação, no tamanho de grão de amido e/ou na morfologia do grão de amido, está alterado em comparação com o amido sintetizado nas células de plantas ou nas plantas de tipo selvagem, de modo que este amido modificado seja melhor adequado para aplicações especiais. As referidas plantas transgénicas que sintetizam um amido modificado encontram- se descritas, por exemplo, nos documentos EP-A 0 571 427, WO 95/04826, EP-A 0 719 338, WO 96/15248, WO 96/19581, WO 96/27674, WO 97/11188, WO 97/26362, WO 97/32985, WO 97/42328, WO 97/44472, WO 97/45545, WO 98/27212, WO 98/40503, WO 99/58688, WO 99/58690, WO 99/58654, WO 00/08184, WO 00/08185, WO 00/08175, WO 00/28052, WO 00/77229, WO 01/12782, WO 01/12826, WO 02/101059, WO 03/071860, WO 04/056999, WO 05/030942, WO 2005/030941, WO 2005/095632, WO 2005/095617, WO 2005/095619, WO 2005/095618, WO 2005/123927, WO 2006/018319, WO 2006/103107, WO 2006/108702, WO 2007/009823, WO 00/22140, WO 2006/063862, WO 2006/072603, WO 02/034923, WO 2008/017518, WO 2008/080630, WO 2008/080631, EP 07090007.1, WO 2008/090008, WO 01/14569, WO 02/79410, WO 03/33540, WO 2004/078983, WO 01/19975, WO 95/26407, WO 96/34968, WO 98/20145, WO 99/12950, WO 99/66050, WO 99/53072, US 6 734 341, WO 00/11192, WO 98/22604, WO 98/32326, WO 01/98509, WO 01/98509, WO 2005/002359, US 5 824 790, US 6 013 861, WO 94/04693, WO 94/09144, WO 94/11520, WO 95/35026, WO 97/20936, WO 2010/012796, WO 2010/003701; 2) plantas transgénicas que sintetizam polímeros de hidratos de carbono diferentes de amido ou que sintetizam polímeros de hidratos de carbono diferentes de amido com propriedades alteradas em comparação com plantas de tipo selvagem sem modificação genética. Como exemplos refere-se as plantas que produzem polifructose, em particular do tipo inulina e levano, tal como descrito nos documentos EP-A 0 663 956, WO 96/01904, WO 96/21023, WO 98/39460 e WO 99/24593, plantas que produzem alfa-1,4-glucanos, tal como descrito nos documentos WO 95/31553, US 2002031826, US 6 284 479, US 5 712 107, WO 97/47806, WO 97/47807, WO 97/47808 e WO 00/14249, plantas que produzem alfa-1,4- glucanos ramificados alfa-1,6, tal como descrito no documento WO 00/73422, plantas que produzem alternano, tal como descrito, v.g., nos documentos WO 00/47727, WO 00/73422, EP 06077301.7, US 5 908 975 e EP-A 0 728 213; 3) plantas transgénicas que produzem hialuronano, tais como, por exemplo, as descritas no documento WO 2006/032538, WO 2007/039314, WO 2007/039315, WO 2007/039316, JP-A 2006-304779 e WO 2005/012529; 4) plantas transgénicas ou plantas híbridas, tais como cebolas, com características tais como ‘teor em sólidos bastante solúveis’, ‘pungência reduzida’ (LP) e/ou ‘armazenamento prolongado’ (LS), tal como descrito nos pedidos de patente de invenção norte-americana nos. 12/020 360 e 61/054 026.[212] Plants and plant varieties (obtained by biotechnological plant methods, such as genetic engineering) that can also be treated according to the invention have an altered quantity, quality and / or storage stability of the harvested product and / or altered properties of specific ingredients of the harvested product, such as: 1) transgenic plants that synthesize a modified starch, which in its physico-chemical characteristics, in particular in the amylose content or in the amylose / amylopectin ratio, in the degree of branching, average chain length, side chain distribution, viscosity behavior, gelling force, starch grain size and / or starch grain morphology, is altered compared to starch synthesized in plant cells or in wild type plants, so that this modified starch is better suited for special applications. Said transgenic plants that synthesize a modified starch are described, for example, in EP-A 0 571 427, WO 95/04826, EP-A 0 719 338, WO 96/15248, WO 96/19581, WO 96 / 27674, WO 97/11188, WO 97/26362, WO 97/32985, WO 97/42328, WO 97/44472, WO 97/45545, WO 98/27212, WO 98/40503, WO 99/58688, WO 99 / 58690, WO 99/58654, WO 00/08184, WO 00/08185, WO 00/08175, WO 00/28052, WO 00/77229, WO 01/12782, WO 01/12826, WO 02/101059, WO 03 / 071860, WO 04/056999, WO 05/030942, WO 2005/030941, WO 2005/095632, WO 2005/095617, WO 2005/095619, WO 2005/095618, WO 2005/123927, WO 2006/018319, WO 2006 / 103107, WO 2006/108702, WO 2007/009823, WO 00/22140, WO 2006/063862, WO 2006/072603, WO 02/034923, WO 2008/017518, WO 2008/080630, WO 2008/080631, EP 07090007.1 , WO 2008/090008, WO 01/14569, WO 02/79410, WO 03/33540, WO 2004/078983, WO 01/19975, WO 95/26407, WO 96/34968, WO 98/20145, WO 99/12950 , WO 99/66050, WO 99/53072, US 6 734 341, WO 00/11192, WO 98/22604, WO 98/32326, WO 01/9 8509, WO 01/98509, WO 2005/002359, US 5 824 790, US 6 013 861, WO 94/04693, WO 94/09144, WO 94/11520, WO 95/35026, WO 97/20936, WO 2010 / 012796, WO 2010/003701; 2) transgenic plants that synthesize polymers of carbohydrates other than starch or that synthesize polymers of carbohydrates other than starch with altered properties compared to wild type plants without genetic modification. Examples include plants producing polyfructose, in particular of the inulin and levano type, as described in EP-A 0 663 956, WO 96/01904, WO 96/21023, WO 98/39460 and WO 99/24593 , plants that produce alpha-1,4-glucans, as described in WO 95/31553, US 2002031826, US 6,284,479, US 5,712,107, WO 97/47806, WO 97/47807, WO 97/47808 and WO 00/14249, plants that produce alpha-1,4-branched alpha-1,6 glucans, as described in WO 00/73422, plants that produce alternan, as described, eg, in WO 00/47727, WO 00/73422, EP 06077301.7, US 5 908 975 and EP-A 0 728 213; 3) transgenic plants that produce hyaluronan, such as, for example, those described in WO 2006/032538, WO 2007/039314, WO 2007/039315, WO 2007/039316, JP-A 2006-304779 and WO 2005/012529; 4) transgenic plants or hybrid plants, such as onions, with characteristics such as 'very soluble solids content', 'reduced pungency' (LP) and / or 'prolonged storage' (LS), as described in the patent applications for American invention us. 12/020 360 and 61/054 026.

[213] As plantas e variedades de plantas (obtidas por métodos biotecnológicos de plantas, tais como engenharia genética) que também podem ser tratadas de acordo com a invenção são plantas, tais como plantas de algodão, com características de fibras alteradas. Tais plantas podem ser obtidas por transformação genética ou por meio da selecção de plantas que contêm uma mutação que lhes confere tais características de fibras alteradas, e compreendem:a) plantas, tais como plantas de algodão, que contêm uma forma alterada de genes de celulose sintase, tal como descrito no documento WO 98/00549; b) plantas, tais como plantas de algodão, que contêm uma forma alterada dos ácidos nucleicos homólogos rsw2 ou rsw3, tal como descrito no documento WO 2004/053219; c) plantas, tais como plantas de algodão, com expressão aumentada de sacarose fosfato sintase, tal como descrito no documento WO 01/17333; d) plantas, tais como plantas de algodão, com expressão aumentada de sacarose sintase, tal como descrito no documento WO 02/45485; e) plantas, tais como plantas de algodão, em que o momento de activação plasmodesmatal na base da célula de fibra é alterado, v.g., por desregulação de β-1,3-glucanase selectiva para fibras, tal como descrito no documento WO 2005/017157 ou tal como descrito no documento WO 2009/143995; f) plantas, tais como plantas de algodão, que possuem fibras com reatividade alterada, v.g., através da expressão do gene N-acetilglucosamina-transferase, incluindo os genes nodC e quitina sintase, tal como descrito no documento WO 2006/136351.[213] Plants and plant varieties (obtained by biotechnological plant methods, such as genetic engineering) that can also be treated according to the invention are plants, such as cotton plants, with altered fiber characteristics. Such plants can be obtained by genetic transformation or by selecting plants that contain a mutation that gives them such altered fiber characteristics, and comprise: a) plants, such as cotton plants, that contain an altered form of cellulose genes synthase, as described in WO 98/00549; b) plants, such as cotton plants, which contain an altered form of homologous nucleic acids rsw2 or rsw3, as described in WO 2004/053219; c) plants, such as cotton plants, with increased expression of sucrose phosphate synthase, as described in WO 01/17333; d) plants, such as cotton plants, with increased expression of sucrose synthase, as described in WO 02/45485; e) plants, such as cotton plants, in which the moment of plasmodesmatal activation at the base of the fiber cell is altered, eg, by deregulation of fiber-selective β-1,3-glucanase, as described in WO 2005 / 017157 or as described in WO 2009/143995; f) plants, such as cotton plants, that have fibers with altered reactivity, e.g., through expression of the N-acetylglucosamine transferase gene, including the nodC and chitin synthase genes, as described in WO 2006/136351.

[214] As plantas e variedades de plantas (obtidas por métodos biotecnológicos de plantas, tais como engenharia genética) que também podem ser tratadas de acordo com a invenção são plantas, tais como plantas de colza ou plantas associadas a Brassica, com características alteradas do perfil de óleo. Tais plantas podem ser obtidas por transformação genética ou por meio da selecção de plantas que contêm uma mutação que lhes confere tais características alteradas de óleo, e compreendem: a) plantas, tais como plantas de colza, que produzem óleo com um teor elevado em ácido oleico, tal como descrito, v.g., nos documentos US 5 969 169, US 5 840 946 ou US 6 323 392 ou US 6 063 947; b) plantas, tais como plantas de colza, que produzem óleo com um teor reduzido em ácido linolénico, tal como descrito nos documentos US 6 270 828, US 6 169 190 ou US 5 965 755; c) plantas, tais como plantas de colza, que produzem óleo com um nível reduzido de ácidos gordos saturados, tal como descrito, v.g., no documento US 5 434 283 ou no pedido de patente de invenção norte-americana n°. 12/668303.[214] The plants and plant varieties (obtained by biotechnological plant methods, such as genetic engineering) that can also be treated according to the invention are plants, such as rapeseed plants or plants associated with Brassica, with altered characteristics of the oil profile. Such plants can be obtained by genetic transformation or by selecting plants that contain a mutation that gives them such altered oil characteristics, and comprise: a) plants, such as rapeseed plants, which produce oil with a high acid content oleic, as described, e.g., in US 5,969,169, US 5,840,946 or US 6,323,392 or US 6,063,947; b) plants, such as rapeseed plants, which produce oil with a reduced content of linolenic acid, as described in US 6,270,828, US 6,169,190 or US 5,965,755; c) plants, such as rapeseed plants, that produce oil with a low level of saturated fatty acids, as described, e.g., in US 5,434,283 or in U.S. Patent Application No. 12/668303.

[215] As plantas e variedades de plantas (obtidas por métodos biotecnológicos de plantas, tais como engenharia genética) que também podem ser tratadas de acordo com a invenção são plantas, tais como colza ou plantas associadas a Brassica, com características de estilhaçamento de semente alteradas. Tais plantas podem ser obtidas por transformação genética ou por selecção de plantas que contêm uma mutação que confere às plantas tais características de estilhaçamento alteradas e compreende plantas, tais como plantas de colza, com estilhaçamento de semente retardada ou reduzida, tal como descrito no pedido de patente de invenção norte-americana n°. 61/135 230, e nos documentos WO 2009/068313 e WO 2010/006732.[215] The plants and plant varieties (obtained by plant biotechnological methods, such as genetic engineering) that can also be treated according to the invention are plants, such as rapeseed or plants associated with Brassica, with seed shattering characteristics changed. Such plants can be obtained by genetic transformation or by selecting plants that contain a mutation that gives plants such altered shattering characteristics and comprises plants, such as rapeseed plants, with delayed or reduced seed shattering, as described in the application. US patent no. 61/135 230, and in WO 2009/068313 and WO 2010/006732.

[216] As plantas e variedades de plantas (obtidas por métodos biotecnológicos de plantas, tais como engenharia genética) que também podem ser tratadas de acordo com a invenção são plantas, tais como plantas de tabaco, com padrões de modificação de proteínas pós-translacionais alteradas, por exemplo, tal como descrito nos documentos WO 2010/121818 e WO 2010/145846.[216] The plants and plant varieties (obtained by biotechnological plant methods, such as genetic engineering) that can also be treated according to the invention are plants, such as tobacco plants, with post-translational protein modification patterns amended, for example, as described in WO 2010/121818 and WO 2010/145846.

[217] Como plantas transgénicas particularmente úteis que é possível tratar de acordo com a invenção refere-se plantas que contêm eventos de transformação ou combinações de eventos de transformação que sejam o assunto de petições concedidas ou pendentes para um estatuto não regulado nos Estados Unidos da América no ‘Animal and Plant Health Inspection Service’ (APHIS) do ‘United States Department of Agriculture’ (USDA). Informação respeitante a estes encontra-se disponível em qualquer momento a partir do APHIS (4700 River Road Riverdale, MD 20737, USA), por exemplo, através da sua página morada na internet (URL: http://www.aphis.usda.gov/brs/not_reg.html). Na data de entrega do presente pedido de patente de invenção, as petições para um estatuto não regulado que estavam pendentes com APHIS ou que foram atribuídas pelo APHIS, foram aquelas que contêm a seguinte informação:[217] As particularly useful transgenic plants that can be treated according to the invention are plants that contain transformation events or combinations of transformation events that are the subject of petitions granted or pending for unregulated status in the United States of America. America at the 'Animal and Plant Health Inspection Service' (APHIS) of the 'United States Department of Agriculture' (USDA). Information regarding these is available at any time from APHIS (4700 River Road Riverdale, MD 20737, USA), for example, through its home page (URL: http: //www.aphis.usda. gov / brs / not_reg.html). On the date of delivery of the present application for an invention patent, petitions for unregulated status that were pending with APHIS or that were assigned by APHIS, were those that contain the following information:

[218] Petição: número de identificação da petição. A descrição técnica do evento de transformação pode ser encontrada nos documentos de petição individuais disponibilizados pelo APHIS, por exemplo, através do website da APHIS, através do número de petição. Estas descrições são aqui incorporadas por referência. - Extensão de uma petição: referência a uma petição anterior para a qual é requerida uma extensão. - Instituição: nome da entidade que submete a petição. - Artigo regulamentado: a espécie da planta em questão.- Fenótipo transgénico: o traço conferido à planta pelo evento de transformação. - Evento ou linha de transformação: o nome do evento ou dos eventos (por vezes também referido como linha ou linhas) para os quais o estatuto de não regulamentado é requerido. - Documentos APHIS: diversos documentos publicados pelo APHIS no que diz respeito à petição e que podem ser requeridos ao APHIS.[218] Petition: identification number of the petition. The technical description of the transformation event can be found in the individual petition documents made available by APHIS, for example, through the APHIS website, through the petition number. These descriptions are hereby incorporated by reference. - Extension of a petition: reference to a previous petition for which an extension is required. - Institution: name of the entity submitting the petition. - Regulated article: the species of the plant in question.- Transgenic phenotype: the trait conferred to the plant by the transformation event. - Event or transformation line: the name of the event or events (sometimes also referred to as line or lines) for which non-regulated status is required. - APHIS documents: several documents published by APHIS regarding the petition and which can be requested from APHIS.

[219] Além disso, plantas particularmente úteis que contêm eventos de transformação individuais ou combinações de eventos de transformação encontram-se agrupadas, por exemplo, em bases de dados de diversas agentes reguladoras nacionais ou regionais (ver, por exemplo, http://gmoinfo.jrc.it/gmp_browse.aspx e http://www.agbios.com/dbase.php).[219] In addition, particularly useful plants that contain individual transformation events or combinations of transformation events are grouped, for example, in databases of various national or regional regulatory agents (see, for example, http: // gmoinfo.jrc.it/gmp_browse.aspx and http://www.agbios.com/dbase.php).

[220] Como plantas transgénicas particularmente úteis que é possível tratar de acordo com a invenção refere-se plantas que contêm eventos de transformação, ou uma combinação de eventos de transformação, e que se encontram listadas, por exemplo, em bases de dados de diversas agências reguladoras nacionais ou regionais, incluindo o evento 1143-14A (algodão, controle de insectos, não depositado, descrito no documento WO 2006/128569); evento 1143-51B (algodão, controle de insectos, não depositado, descrito no documento WO 2006/128570); evento 1445 (algodão, tolerância a herbicida, não depositado, descrito nos documentos US 2002-120964 ou WO 02/034946); evento 17053 (arroz, tolerância a herbicida, depositado como PTA- 9843, descrito no documento WO 2010/117737); evento 17314 (arroz, tolerância a herbicida, depositado como PTA-9844, descrito no documento WO 2010/117735); evento 281-24-236 (algodão, controle de insectos - tolerância a herbicida, depositado como PTA-6233, descrito nos documentos WO 2005/103266 ou US-A 2005-216969); evento 3006-210-23 (algodão, controle de insectos - tolerância a herbicida, depositado como PTA-6233, descrito nos documentos US-A 2007-143876 ou WO 2005/103266); evento 3272 (milho, traço de qualidade, depositado como PTA-9972, descrito nos documentos WO 2006098952 ou US-A 2006-230473); evento 40416 (milho, controle de insectos - tolerância a herbicida, depositado como ATCC PTA-11508, descrito no documento WO 2011/075593); evento 43A47 (milho, controle de insectos - tolerância a herbicida, depositado como ATCC PTA-11509, descrito no documento WO 2011/075595); evento 5307 (milho, controle de insectos, depositado como ATCC PTA-9561, descrito no documento WO 2010/077816); evento ASR-368 (agróstide, tolerância a herbicida, depositado como ATCC PTA-4816, descrito nos documentos US-A 2006-162007 ou WO 2004/053062); evento B16 (milho, tolerância a herbicida, não depositado, descrito no documento US-A 2003-126634); evento BPS-CV127-9 (soja, tolerância a herbicida, depositado como NCIMB No. 41603, descrito no documento WO 2010/080829); evento CE43-67B (algodão, controle de insectos, depositado como DSM ACC2724, descrito nos documentos US-A 2009-217423 ou WO 2006/128573); evento CE44-69D (algodão, controle de insectos, não depositado, descrito no documento US-A 2010-0024077); evento CE44-69D (algodão, controle de insectos, não depositado, descrito no documento WO 2006/128571); evento CE46-02A (algodão, controle de insectos, não depositado, descrito no documento WO 2006/128572); evento COT102 (algodão, controle de insectos, não depositado, descrito nos documentos US-A 2006-130175 ou WO 2004/039986); evento COT202 (algodão, controle de insectos, não depositado, descrito nos documentos US-A 2007-067868 ou WO 2005/054479); evento COT203 (algodão, controle de insectos, não depositado, descrito no documento WO 2005/054480); evento DAS40278 (milho, tolerância a herbicida, depositado como ATCC PTA- 10244, descrito no documento WO 2011/022469); evento DAS- 59122-7 (milho, controle de insectos - tolerância a herbicida, depositado como ATCC PTA 11384, descrito no documento US-A 2006-070139); evento DAS-59132 (milho, controle de insectos - tolerância a herbicida, não depositado, descrito no documento WO 2009/100188); evento DAS68416 (soja, tolerância a herbicida, depositado como ATCC PTA-10442, descrito nos documentos WO 2011/066384 ou WO 2011/066360); evento DP-098140-6 (milho, tolerância a herbicida, depositado como ATCC PTA-8296, descrito nos documentos US-A 2009-137395 ou WO 2008/112019); evento DP- 305423-1 (soja, traço de qualidade, não depositado, descrito nos documentos US-A 2008-312082 ou WO 2008/054747); evento DP-32138-1 (milho, sistema de hibridação, depositado como ATCC PTA-9158, descrito nos documentos US-A 2009-0210970 ou WO 2009/103049); evento DP- 356043-5 (soja, tolerância a herbicida, depositado como ATCC PTA-8287, descrito nos documentos US-A 2010-0184079 ou WO 2008/002872); evento EE-1 (beringela, controle de insectos, não depositado, descrito no documento WO 2007/091277); evento FI117 (milho, tolerância a herbicida, depositado como ATCC 209031, descrito nos documentos US-A 2006-059581 ou WO 1998/044140); evento GA21 (milho, tolerância a herbicida, depositado como ATCC 209033, descrito nos documentos US-A 2005-086719 ou WO 1998/044140); evento GG25 (milho, tolerância a herbicida, depositado como ATCC 209032, descrito nos documentos US-A 2005-188434 ou WO 1998/044140); evento GHB119 (algodão, controle de insectos - tolerância a herbicida, depositado como ATCC PTA-8398, descrito no documento WO 2008/151780); evento GHB614 (algodão, tolerância a herbicida, depositado como ATCC PTA-6878, descrito nos documentos US-A 2010- 050282 ou WO 2007/017186); evento GJ11 (milho, tolerância a herbicida, depositado como ATCC 209030, descrito nos documentos US-A 2005-188434 ou WO 1998/044140); evento GM RZ13 (beterraba sacarina, resistência contra vírus, depositado como NCIMB-41601, descrito no documento WO 2010/076212); evento H7-1 (beterraba sacarina, tolerância a herbicida, depositado como NCIMB 41158 ou NCIMB 41159, descrito no documento US-A 2004-172669 ou WO 2004/074492); evento JOPLIN1 (trigo, tolerância a doença, não depositado, descrito no documento US-A 2008-064032); evento LL27 (soja, tolerância a herbicida, depositado como NCIMB41658, descrito nos documentos WO 2006/108674 ou US-A 2008- 320616); evento LL55 (soja, tolerância a herbicida, depositado como NCIMB 41660, descrito nos documentos WO 2006/108675 ou US-A 2008-196127); evento LLcotton25 (algodão, tolerância a herbicida, depositado como ATCC PTA- 3343, descrito nos documentos WO 03/013224 ou US-A 2003- 097687); evento LLRICE06 (arroz, tolerância a herbicida, depositado como ATCC-23352, descrito nos documentos US 6 468 747 ou WO 00/026345); evento LLRICE601 (arroz, tolerância a herbicida, depositado como ATCC PTA-2600, descrito nos documentos US-A 2008-2289060 ou WO 00/026356); evento LY038 (milho, traço de qualidade, depositado como ATCC PTA-5623, descrito nos documentos US-A 2007-028322 ou WO 2005/061720); evento MIR162 (milho, controle de insectos, depositado como PTA-8166, descrito nos documentos US-A 2009-300784 ou WO 2007/142840); evento MIR604 (milho, controle de insectos, não depositado, descrito nos documentos US-A 2008-167456 ou WO 2005/ /103301); evento MON15985 (algodão, controle de insectos, depositado como ATCC PTA-2516, descrito nos documentos US-A 2004-250317 ou WO 02/100163); evento MON810 (milho, controle de insectos, não depositado, descrito no documento US-A 2002-102582); evento MON863 (milho, controle de insectos, depositado como ATCC PTA-2605, descrito nos documentos WO 2004/011601 ou US-A 2006-095986); evento MON87427 (milho, controle de polinização, depositado como ATCC PTA-7899, descrito no documento WO 2011/062904); evento MON87460 (milho, tolerância a stress, depositado como ATCC PTA-8910, descrito nos documentos WO 2009/111263 ou US-A 2011- 0138504); evento MON87701 (soja, controle de insectos, depositado como ATCC PTA-8194, descrito nos documentos US-A 2009-130071 ou WO 2009/064652); evento MON87705 (soja, traço de qualidade - tolerância a herbicida, depositado como ATCC PTA-9241, descrito nos documentos US-A 2010- 0080887 ou WO 2010/037016); evento MON87708 (soja, tolerância a herbicida, depositado como ATCC PTA-9670, descrito no documento WO 2011/034704); evento MON87754 (soja, traço de qualidade, depositado como ATCC PTA-9385, descrito no documento WO 2010/024976); evento MON87769 (soja, traço de qualidade, depositado como ATCC PTA-8911, descrito nos documentos US-A 2011-0067141 ou WO 2009/102873); evento MON88017 (milho, controle de insectos - tolerância a herbicida, depositado como ATCC PTA-5582, descrito nos documentos US-A 2008-028482 ou WO 2005/059103); evento MON88913 (algodão, tolerância a herbicida, depositado como ATCC PTA-4854, descrito nos documentos WO 2004/072235 ou US-A 2006-059590); evento MON89034 (milho, controle de insectos, depositado como ATCC PTA-7455, descrito nos documentos WO 2007/140256 ou US-A 2008-260932); evento MON89788 (soja, tolerância a herbicida, depositado como ATCC PTA-6708, descrito nos documentos US-A 2006-282915 ou WO 2006/130436); evento MS11 (colza, controle de polinização - tolerância a herbicida, depositado como ATCC PTA-850 ou PTA-2485, descrito no documento WO 01/031042); evento MS8 (colza, controle de polinização - tolerância a herbicida, depositado como ATCC PTA-730, descrito nos documentos WO 01/041558 ou US-A 2003- 188347); evento NK603 (milho, tolerância a herbicida, depositado como ATCC PTA-2478, descrito no documento US-A 2007-292854); evento PE-7 (arroz, controle de insectos, não depositado, descrito no documento WO 2008/114282); evento RF3 (colza, controle de polinização - tolerância a herbicida, depositado como ATCC PTA-730, descrito nos documentos WO 01/041558 ou US-A 2003-188347); evento RT73 (colza, tolerância a herbicida, não depositado, descrito nos documentos WO 02/036831 ou US-A 2008-070260); evento T227-1 (beterraba sacarina, tolerância a herbicida, não depositado, descrito nos documentos WO 02/44407 ou US-A 2009-265817); evento T25 (milho, tolerância a herbicida, não depositado, descrito nos documentos US-A 2001-029014 ou WO 01/051654); evento T304-40 (algodão, controle de insectos - tolerância a herbicida, depositado como ATCC PTA-8171, descrito nos documentos US-A 2010-077501 ou WO 2008/122406); evento T342-142 (algodão, controle de insectos, não depositado, descrito no documento WO 2006/128568); evento TC1507 (milho, controle de insectos - tolerância a herbicida, não depositado, descrito nos documentos US-A 2005-039226 ou WO 2004/099447); evento VIP1034 (milho, controle de insectos - tolerância a herbicida, depositado como ATCC PTA-3925, descrito no documento WO 03/052073), evento 32316 (milho, controle de insectos - tolerância a herbicida, depositado como PTA- 11507, descrito no documento WO 2011/084632), evento 4114 (milho, controle de insectos - tolerância a herbicida, depositado como PTA-11506, descrito no documento WO 2011/084621).[220] As particularly useful transgenic plants that can be treated according to the invention are plants that contain transformation events, or a combination of transformation events, and which are listed, for example, in databases of different national or regional regulatory agencies, including event 1143-14A (cotton, insect control, not deposited, described in WO 2006/128569); event 1143-51B (cotton, insect control, not deposited, described in WO 2006/128570); event 1445 (cotton, herbicide tolerance, not deposited, described in US 2002-120964 or WO 02/034946); event 17053 (rice, herbicide tolerance, deposited as PTA-9843, described in WO 2010/117737); event 17314 (rice, herbicide tolerance, deposited as PTA-9844, described in WO 2010/117735); event 281-24-236 (cotton, insect control - herbicide tolerance, deposited as PTA-6233, described in WO 2005/103266 or US-A 2005-216969); event 3006-210-23 (cotton, insect control - herbicide tolerance, deposited as PTA-6233, described in documents US-A 2007-143876 or WO 2005/103266); event 3272 (corn, quality trait, deposited as PTA-9972, described in WO 2006098952 or US-A 2006-230473); event 40416 (maize, insect control - herbicide tolerance, deposited as ATCC PTA-11508, described in WO 2011/075593); event 43A47 (corn, insect control - herbicide tolerance, deposited as ATCC PTA-11509, described in WO 2011/075595); event 5307 (corn, insect control, deposited as ATCC PTA-9561, described in WO 2010/077816); event ASR-368 (agrostide, herbicide tolerance, deposited as ATCC PTA-4816, described in documents US-A 2006-162007 or WO 2004/053062); event B16 (maize, herbicide tolerance, not deposited, described in US-A 2003-126634); event BPS-CV127-9 (soybean, herbicide tolerance, deposited as NCIMB No. 41603, described in WO 2010/080829); event CE43-67B (cotton, insect control, deposited as DSM ACC2724, described in documents US-A 2009-217423 or WO 2006/128573); event CE44-69D (cotton, insect control, not deposited, described in document US-A 2010-0024077); event CE44-69D (cotton, insect control, not deposited, described in WO 2006/128571); event CE46-02A (cotton, insect control, not deposited, described in WO 2006/128572); event COT102 (cotton, insect control, not deposited, described in US-A 2006-130175 or WO 2004/039986); event COT202 (cotton, insect control, not deposited, described in documents US-A 2007-067868 or WO 2005/054479); event COT203 (cotton, insect control, not deposited, described in WO 2005/054480); event DAS40278 (corn, herbicide tolerance, deposited as ATCC PTA-10244, described in WO 2011/022469); event DAS- 59122-7 (maize, insect control - herbicide tolerance, deposited as ATCC PTA 11384, described in document US-A 2006-070139); event DAS-59132 (maize, insect control - herbicide tolerance, not deposited, described in document WO 2009/100188); event DAS68416 (soybean, herbicide tolerance, deposited as ATCC PTA-10442, described in WO 2011/066384 or WO 2011/066360); event DP-098140-6 (corn, herbicide tolerance, deposited as ATCC PTA-8296, described in documents US-A 2009-137395 or WO 2008/112019); event DP-305423-1 (soybean, quality trace, not deposited, described in documents US-A 2008-312082 or WO 2008/054747); event DP-32138-1 (corn, hybridization system, deposited as ATCC PTA-9158, described in documents US-A 2009-0210970 or WO 2009/103049); event DP-356043-5 (soybean, herbicide tolerance, deposited as ATCC PTA-8287, described in US-A 2010-0184079 or WO 2008/002872); event EE-1 (eggplant, insect control, not deposited, described in WO 2007/091277); event FI117 (corn, herbicide tolerance, deposited as ATCC 209031, described in US-A 2006-059581 or WO 1998/044140); event GA21 (maize, herbicide tolerance, deposited as ATCC 209033, described in US-A 2005-086719 or WO 1998/044140); event GG25 (maize, herbicide tolerance, deposited as ATCC 209032, described in US-A 2005-188434 or WO 1998/044140); event GHB119 (cotton, insect control - herbicide tolerance, deposited as ATCC PTA-8398, described in WO 2008/151780); event GHB614 (cotton, herbicide tolerance, deposited as ATCC PTA-6878, described in documents US-A 2010-050282 or WO 2007/017186); event GJ11 (corn, herbicide tolerance, deposited as ATCC 209030, described in US-A 2005-188434 or WO 1998/044140); event GM RZ13 (sugar beet, virus resistance, deposited as NCIMB-41601, described in WO 2010/076212); event H7-1 (sugar beet, herbicide tolerance, deposited as NCIMB 41158 or NCIMB 41159, described in US-A 2004-172669 or WO 2004/074492); event JOPLIN1 (wheat, disease tolerance, not deposited, described in document US-A 2008-064032); event LL27 (soybean, herbicide tolerance, deposited as NCIMB41658, described in WO 2006/108674 or US-A 2008- 320616); event LL55 (soybean, herbicide tolerance, deposited as NCIMB 41660, described in WO 2006/108675 or US-A 2008-196127); event LLcotton25 (cotton, herbicide tolerance, deposited as ATCC PTA-3343, described in WO 03/013224 or US-A 2003-2007687); event LLRICE06 (rice, herbicide tolerance, deposited as ATCC-23352, described in documents US 6 468 747 or WO 00/026345); event LLRICE601 (rice, herbicide tolerance, deposited as ATCC PTA-2600, described in documents US-A 2008-2289060 or WO 00/026356); event LY038 (corn, quality trait, deposited as ATCC PTA-5623, described in documents US-A 2007-028322 or WO 2005/061720); event MIR162 (corn, insect control, deposited as PTA-8166, described in documents US-A 2009-300784 or WO 2007/142840); event MIR604 (corn, insect control, not deposited, described in documents US-A 2008-167456 or WO 2005 / / 103301); event MON15985 (cotton, insect control, deposited as ATCC PTA-2516, described in documents US-A 2004-250317 or WO 02/100163); event MON810 (maize, insect control, not deposited, described in document US-A 2002-102582); event MON863 (maize, insect control, deposited as ATCC PTA-2605, described in WO 2004/011601 or US-A 2006-095986); event MON87427 (corn, pollination control, deposited as ATCC PTA-7899, described in WO 2011/062904); event MON87460 (maize, stress tolerance, deposited as ATCC PTA-8910, described in WO 2009/111263 or US-A 2011-0138504); event MON87701 (soybean, insect control, deposited as ATCC PTA-8194, described in US-A 2009-130071 or WO 2009/064652); event MON87705 (soybean, trait of quality - herbicide tolerance, deposited as ATCC PTA-9241, described in documents US-A 2010- 0080887 or WO 2010/037016); event MON87708 (soybean, herbicide tolerance, deposited as ATCC PTA-9670, described in WO 2011/034704); event MON87754 (soybean, quality trait, deposited as ATCC PTA-9385, described in WO 2010/024976); event MON87769 (soybean, quality trait, deposited as ATCC PTA-8911, described in documents US-A 2011-0067141 or WO 2009/102873); event MON88017 (maize, insect control - herbicide tolerance, deposited as ATCC PTA-5582, described in documents US-A 2008-028482 or WO 2005/059103); event MON88913 (cotton, herbicide tolerance, deposited as ATCC PTA-4854, described in WO 2004/072235 or US-A 2006-059590); event MON89034 (maize, insect control, deposited as ATCC PTA-7455, described in WO 2007/140256 or US-A 2008-260932); event MON89788 (soybean, herbicide tolerance, deposited as ATCC PTA-6708, described in documents US-A 2006-282915 or WO 2006/130436); event MS11 (rapeseed, pollination control - herbicide tolerance, deposited as ATCC PTA-850 or PTA-2485, described in WO 01/031042); event MS8 (rapeseed, pollination control - herbicide tolerance, deposited as ATCC PTA-730, described in WO 01/041558 or US-A 2003- 188347); event NK603 (corn, herbicide tolerance, deposited as ATCC PTA-2478, described in US-A 2007-292854); event PE-7 (rice, insect control, not deposited, described in WO 2008/114282); event RF3 (rapeseed, pollination control - herbicide tolerance, deposited as ATCC PTA-730, described in WO 01/041558 or US-A 2003-188347); event RT73 (rapeseed, herbicide tolerance, not deposited, described in WO 02/036831 or US-A 2008-070260); event T227-1 (sugar beet, herbicide tolerance, not deposited, described in WO 02/44407 or US-A 2009-265817); event T25 (maize, herbicide tolerance, not deposited, described in US-A 2001-029014 or WO 01/051654); event T304-40 (cotton, insect control - herbicide tolerance, deposited as ATCC PTA-8171, described in US-A 2010-077501 or WO 2008/122406); event T342-142 (cotton, insect control, not deposited, described in WO 2006/128568); event TC1507 (maize, insect control - herbicide tolerance, not deposited, described in documents US-A 2005-039226 or WO 2004/099447); event VIP1034 (corn, insect control - herbicide tolerance, deposited as ATCC PTA-3925, described in WO 03/052073), event 32316 (corn, insect control - herbicide tolerance, deposited as PTA-11507, described in WO 2011/084632), event 4114 (maize, insect control - herbicide tolerance, deposited as PTA-11506, described in WO 2011/084621).

Taxas de aplicação e momentoApplication rates and timing

[221] Quando se utilizam as combinações da invenção como fungicidas, as taxas de aplicação podem variar em um intervalo relativamente amplo, dependendo do tipo de aplicação. A taxa de aplicação dos ingredientes ativos da invenção está compreendida • no caso do tratamento de partes de plantas, por exemplo, de folhas: entre 0,1 e 10 000 g/ha, de preferência, entre 10 e 1000 g/ha, mais preferencialmente, entre 10 e 800 g/ha e, ainda mais preferencialmente, entre 50 e 300 g/ha (no caso de aplicação por enxaguamento ou gotejamento, é mesmo possível reduzir a taxa de aplicação, em particular quando se utilizam substratos inertes, tais como lã de rocha ou perlite); • no caso do tratamento de sementes: entre 2 e 200 g por 100 kg de semente, de preferência, entre 3 e 150 g por 100 kg de semente, mais preferencialmente, entre 2,5 e 25 g por 100 kg de semente e, ainda mais preferencialmente, entre 2,5 e 12,5 g por 100 kg de semente; • no caso do tratamento do solo: entre 0,1 e 10 000 g/ha e, de preferência, entre 1 e 5000 g/ha.[221] When the combinations of the invention are used as fungicides, application rates can vary over a relatively wide range, depending on the type of application. The application rate of the active ingredients of the invention is included • in the case of the treatment of parts of plants, for example, leaves: between 0.1 and 10,000 g / ha, preferably between 10 and 1000 g / ha, more preferably between 10 and 800 g / ha and, even more preferably, between 50 and 300 g / ha (in the case of rinsing or dripping application, it is even possible to reduce the application rate, particularly when using inert substrates, such as rock wool or perlite); • in the case of seed treatment: between 2 and 200 g per 100 kg of seed, preferably between 3 and 150 g per 100 kg of seed, more preferably between 2.5 and 25 g per 100 kg of seed and, even more preferably, between 2.5 and 12.5 g per 100 kg of seed; • in the case of soil treatment: between 0.1 and 10,000 g / ha and preferably between 1 and 5000 g / ha.

[222] Estas taxas de aplicação são meramente exemplificativas e não são limitativas para o propósito da invenção.[222] These application rates are merely exemplary and are not limiting for the purpose of the invention.

[223] As composições da invenção podem assim ser utilizadas para proteger as plantas contra ataques pelos patogénicos mencionados durante um determinado período de tempo após o tratamento. De um modo geral, o período para o qual a protecção é conferida está compreendido entre 1 e 28 dias, de preferência, entre 1 e 14 dias, mais preferencialmente, entre 1 e 10 dias e, ainda mais preferencialmente, entre 1 e 7 dias, após o tratamento das plantas com os ingredientes ativos, ou até 200 dias após o tratamento de sementes.[223] The compositions of the invention can thus be used to protect plants against attack by the mentioned pathogens for a certain period of time after treatment. In general, the period for which protection is conferred is between 1 and 28 days, preferably between 1 and 14 days, more preferably between 1 and 10 days and, even more preferably, between 1 and 7 days , after treating the plants with the active ingredients, or up to 200 days after treating the seeds.

[224] O método de tratamento de acordo com a invenção também proporciona a utilização ou aplicação dos compostos (A) e (B) e/ou (C) em simultâneo, em separado ou de um modo sequencial. Caso os ingredientes ativos individuais sejam aplicados de um modo sequencial, isto é, em momentos diferentes, então são aplicados um a seguir ao outro em um período de tempo razoavelmente curto, tal como algumas horas ou dias. De preferência, a ordem de aplicação dos compostos (A) e (B) e/ou (C) não é essencialmente para a realização da presente invenção.[224] The treatment method according to the invention also provides for the use or application of compounds (A) and (B) and / or (C) simultaneously, separately or sequentially. If the individual active ingredients are applied sequentially, that is, at different times, then they are applied one after the other in a reasonably short period of time, such as a few hours or days. Preferably, the order of application of compounds (A) and (B) and / or (C) is not essentially for carrying out the present invention.

[225] De um modo particularmente vantajoso, as plantas listadas podem ser tratadas de acordo com a invenção com os compostos de fórmula estrutural (I) e com as composições da invenção. Os intervalos preferidos referidos antes para os ingredientes ativos ou composições também se aplicam ao tratamento destas plantas. É particularmente importante o tratamento de plantas com os compostos ou composições mencionados especificamente no presente texto.[225] In a particularly advantageous way, the listed plants can be treated according to the invention with the compounds of formula (I) and with the compositions of the invention. The preferred ranges mentioned above for the active ingredients or compositions also apply to the treatment of these plants. It is particularly important to treat plants with the compounds or compositions mentioned specifically in this text.

[226] A atividade fungicida avançada das combinações de compostos ativos de acordo com a invenção é evidente a partir do exemplo a seguir apresentado. Embora os compostos ativos individuais exibam fraqueza no que diz respeito à atividade fungicida, as combinações possuem uma atividade que excede uma simples adição de atividades.[226] The advanced fungicidal activity of the combinations of active compounds according to the invention is evident from the example below. Although the individual active compounds exhibit weakness with respect to fungicidal activity, the combinations have an activity that exceeds a simple addition of activities.

[227] Está sempre presente um efeito sinergístico de fungicidas quando a atividade fungicida das combinações de compostos ativos excede o total das atividades dos compostos ativos quando estes são aplicados individualmente. a atividade esperada para uma determinada combinação de dois compostos ativos podem ser calculada do modo seguinte (ver, Colby, S.R., "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1967, 15, 20-22): se o símbolo X representa a eficácia quando o composto ativo A é aplicado a uma taxa de aplicação de m p.p.m. (ou g/ha), o símbolo Y representa a eficácia quando o composto ativo B é aplicado a uma taxa de aplicação de n p.p.m. (oug/ha), o símbolo E representa a eficácia quando os compostos ativos A e B são aplicados a taxas de aplicação de m e n p.p.m. (ou g/ha), respectivamente,

Figure img0002
[227] A synergistic effect of fungicides is always present when the fungicidal activity of the combinations of active compounds exceeds the total activities of the active compounds when they are applied individually. the expected activity for a given combination of two active compounds can be calculated as follows (see, Colby, SR, "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1967, 15, 20-22): if the symbol X represents the effectiveness when active compound A is applied at an application rate of m ppm (or g / ha), the symbol Y represents the effectiveness when active compound B is applied at an application rate of n ppm (oug / ha) , the symbol E represents the effectiveness when the active compounds A and B are applied at application rates of men ppm (or g / ha), respectively,
Figure img0002

[228] O grau de eficácia, expresso em percentagem (%), é determinado. Um valor de 0% designa uma eficácia que corresponde à do controle, ao passo que uma eficácia de 100% designa que não foi observada doença.[228] The degree of effectiveness, expressed as a percentage (%), is determined. A value of 0% designates an efficacy that corresponds to that of the control, whereas a 100% efficacy designates that no disease was observed.

[229] Caso a atividade fungicida actual exceda o valor calculado, então a atividade da combinação é sobre-aditiva, isto é, existe um efeito sinergístico. Neste caso, a eficácia actualmente observada deverá ser superior ao valor para a eficácia esperada (E) calculado a partir da fórmula supramencionada.[229] If the current fungicidal activity exceeds the calculated value, then the activity of the combination is over-additive, that is, there is a synergistic effect. In this case, the effectiveness currently observed should be greater than the value for the expected effectiveness (E) calculated from the aforementioned formula.

[230] Uma outra forma de demonstrar um efeito sinergístico consiste no método de Tammes (ver “Isoboles, a graphic representation of synergism in pesticides” em Neth. J. Plant Path., 1964, 70, 73-80).[230] Another way to demonstrate a synergistic effect is the Tammes method (see "Isoboles, the graphic representation of synergism in pesticides" in Neth. J. Plant Path., 1964, 70, 73-80).

[231] A invenção é ilustrada pelos exemplos seguintes. No entanto, a invenção não é limitada aos exemplos.[231] The invention is illustrated by the following examples. However, the invention is not limited to the examples.

Exemplo 1Example 1 Teste de Alternaria (tomates) / preventivoAlternaria test (tomatoes) / preventive

[232] Solvente: 24,5 partes em peso de acetone 24,5 partes em peso de dimetilacetamida[232] Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide

[233] Emulsificante: 1 parte em peso de éter alquilaril-poliglicólico[233] Emulsifier: 1 part by weight of alkylaryl-polyglycolic ether

[234] Para se produzir uma preparação adequada de composto ativo, mistura-se 1 parte em peso de composto ativo com as quantidades especificadas de solvente e emulsificante e dilui-se o concentrado com água até á concentração desejada.[234] To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the specified amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.

[235] Para se testar quanto à atividade preventiva, pulveriza-se plantas jovens com a preparação de composto ativo à taxa de aplicação especificada. Após secagem do revestimento pulverizado, inocula-se as plantas com uma suspensão aquosa de esporos de Alternaria solani. Coloca-se então as plantas em uma câmara de incubação a aproximadamente 20°C e uma humidade atmosférica relativa de 100%.[235] To test for preventive activity, spray young plants with the preparation of active compound at the specified application rate. After drying the spray coating, the plants are inoculated with an aqueous spore suspension of Alternaria solani. The plants are then placed in an incubation chamber at approximately 20 ° C and a relative atmospheric humidity of 100%.

[236] O teste é avaliado 3 dias após a inoculação. Um valor de 0% designa uma eficácia que corresponde à do controle não tratado, ao passo que uma eficácia de 100% designa que não foi observada doença.[236] The test is evaluated 3 days after inoculation. A value of 0% designates an efficacy that corresponds to that of the untreated control, whereas a 100% efficacy designates that no disease was observed.

[237] O quadro seguinte mostra claramente que a atividade observada da combinação de composto ativo de acordo com a invenção é superior à atividade calculada, isto é, está presente um efeito sinergístico. Quadro 1 Teste de Alternaria (tomates) / preventive

Figure img0003
Figure img0004
Figure img0005
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby Quadro 2 Teste de Alternaria (tomates) / preventive
Figure img0006
Figure img0007
Figure img0008
Figure img0009
* encontrada = atividade encontrada ** calculada = atividade calculada utilizando a fórmula de Colby[237] The following table clearly shows that the observed activity of the active compound combination according to the invention is greater than the calculated activity, that is, a synergistic effect is present. Chart 1 Alternaria test (tomatoes) / preventive
Figure img0003
Figure img0004
Figure img0005
1 found = activity found 2 * calculated = activity calculated using Colby's formula Chart 2 Alternaria test (tomatoes) / preventive
Figure img0006
Figure img0007
Figure img0008
Figure img0009
* found = activity found ** calculated = activity calculated using Colby's formula

Exemplo 2Example 2 Teste de Phytophthora (tomates) / preventivoPhytophthora test (tomatoes) / preventive

[238] Solvente: 24,5 partes em peso de acetona[238] Solvent: 24.5 parts by weight of acetone

[239] 24,5 partes em peso de dimetilacetamida[239] 24.5 parts by weight of dimethylacetamide

[240] Emulsificante: 1 parte em peso de éter alquilaril-poliglicólico[240] Emulsifier: 1 part by weight of alkylaryl-polyglycolic ether

[241] Para se produzir uma preparação adequada de composto ativo, mistura-se 1 parte em peso de composto ativo com as quantidades especificadas de solvente e emulsificante e dilui-se o concentrado com água até á concentração desejada.[241] To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the specified amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.

[242] Para se testar quanto à atividade preventiva, pulveriza-se plantas jovens com a preparação de composto ativo à taxa de aplicação especificada. Após secagem do revestimento pulverizado, inocula-se as plantas com uma suspensão aquosa de esporos de Phytophthora infestans. Coloca-se então as plantas em uma câmara de incubação a aproximadamente 20°C e uma humidade atmosférica relativa de 100%.[242] To test for preventive activity, spray young plants with the preparation of active compound at the specified application rate. After the spray coating has dried, the plants are inoculated with an aqueous spore suspension of Phytophthora infestans. The plants are then placed in an incubation chamber at approximately 20 ° C and a relative atmospheric humidity of 100%.

[243] O teste é avaliado 3 dias após a inoculação. Um valor de 0% designa uma eficácia que corresponde à do controle não tratado, ao passo que uma eficácia de 100% designa que não foi observada doença.[243] The test is evaluated 3 days after inoculation. A value of 0% designates an efficacy that corresponds to that of the untreated control, whereas a 100% efficacy designates that no disease was observed.

[244] O quadro seguinte mostra claramente que a atividade observada da combinação de composto ativo de acordo com a invenção é superior à atividade calculada, isto é, está presente um efeito sinergístico. Quadro 3 Teste de Phytophthora (tomates) / protective

Figure img0010
Figure img0011
Figure img0012
Figure img0013
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby Quadro 4 Teste de Phytophthora (tomates) / protective
Figure img0014
Figure img0015
Figure img0016
Figure img0017
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby Quadro 5 Teste de Phytophthora (tomates) / protective
Figure img0018
Figure img0019
Figure img0020
Figure img0021
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby Quadro 6 Teste de Phytophthora (tomates) / protective
Figure img0022
Figure img0023
Figure img0024
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby[244] The following table clearly shows that the observed activity of the active compound combination according to the invention is greater than the calculated activity, that is, a synergistic effect is present. Table 3 Phytophthora (tomatoes) / protective test
Figure img0010
Figure img0011
Figure img0012
Figure img0013
1 found = activity found 2 * calculated = activity calculated using Colby's formula Chart 4 Phytophthora test (tomatoes) / protective
Figure img0014
Figure img0015
Figure img0016
Figure img0017
1 found = activity found 2 * calculated = activity calculated using Colby's formula Chart 5 Phytophthora test (tomatoes) / protective
Figure img0018
Figure img0019
Figure img0020
Figure img0021
1 found = activity found 2 * calculated = activity calculated using Colby's formula Table 6 Phytophthora test (tomatoes) / protective
Figure img0022
Figure img0023
Figure img0024
1 found = activity found 2 * calculated = activity calculated using Colby's formula

Exemplo 3Example 3 Teste de Sphaerotheca (pepinos) / preventivoSphaerotheca test (cucumbers) / preventive

[245] Solvente: 24,5 partes em peso de acetone 24,5 partes em peso de dimetilacetamida[245] Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide

[246] Emulsificante: 1 parte em peso de éter alquilaril-poliglicólico[246] Emulsifier: 1 part by weight of alkylaryl-polyglycolic ether

[247] Para se produzir uma preparação adequada de composto ativo, mistura-se 1 parte em peso de composto ativo com as quantidades especificadas de solvente e emulsificante e dilui-se o concentrado com água até á concentração desejada.[247] To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the specified amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.

[248] Para se testar quanto à atividade preventiva, pulveriza-se plantas jovens com a preparação de composto ativo à taxa de aplicação especificada. Após secagem do revestimento pulverizado, inocula-se as plantas com uma suspensão aquosa de esporos de Sphaerotheca fuliginea. Coloca-se então as plantas em uma estufa a aproximadamente 23°C e uma humidade atmosférica relativa de aproximadamente 70%.[248] To test for preventive activity, spray young plants with the preparation of active compound at the specified application rate. After drying the spray coating, the plants are inoculated with an aqueous spore suspension of Sphaerotheca fuliginea. The plants are then placed in a greenhouse at approximately 23 ° C and a relative atmospheric humidity of approximately 70%.

[249] O teste é avaliado 7 dias após a inoculação. Um valor de 0% designa uma eficácia que corresponde à do controle não tratado, ao passo que uma eficácia de 100% designa que não foi observada doença.[249] The test is evaluated 7 days after inoculation. A value of 0% designates an efficacy that corresponds to that of the untreated control, whereas a 100% efficacy designates that no disease was observed.

[250] O quadro seguinte mostra claramente que a atividade observada da combinação de composto ativo de acordo com a invenção é superior à atividade calculada, isto é, está presente um efeito sinergístico. Quadro 7 Teste de Sphaerotheca (pepinos) / preventive

Figure img0025
Figure img0026
Figure img0027
Figure img0028
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby Quadro 8 Teste de Sphaerotheca (pepinos) / preventivo
Figure img0029
Figure img0030
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby Quadro 9 Teste de Sphaerotheca (pepinos) / preventive
Figure img0031
Figure img0032
Figure img0033
* encontrada = atividade encontrada ** calculada = atividade calculada utilizando a fórmula de Colby[250] The following table clearly shows that the observed activity of the active compound combination according to the invention is greater than the calculated activity, that is, a synergistic effect is present. Table 7 Sphaerotheca test (cucumbers) / preventive
Figure img0025
Figure img0026
Figure img0027
Figure img0028
1 found = activity found 2 * calculated = activity calculated using Colby's formula Chart 8 Sphaerotheca test (cucumbers) / preventive
Figure img0029
Figure img0030
1 found = activity found 2 * calculated = activity calculated using Colby's formula Chart 9 Sphaerotheca test (cucumbers) / preventive
Figure img0031
Figure img0032
Figure img0033
* found = activity found ** calculated = activity calculated using Colby's formula

Exemplo 4Example 4 Teste de Venturia(maçãs) / preventivoVenturia test (apples) / preventive

[251] Solvente: 24,5 partes em peso de acetone 24,5 partes em peso de dimetilacetamida[251] Solvent: 24.5 parts by weight of acetone 24.5 parts by weight of dimethylacetamide

[252] Emulsificante: 1 parte em peso de éter alquilaril-poliglicólico[252] Emulsifier: 1 part by weight of alkylaryl-polyglycolic ether

[253] Para se produzir uma preparação adequada de composto ativo, mistura-se 1 parte em peso de composto ativo com as quantidades especificadas de solvente e emulsificante e dilui-se o concentrado com água até á concentração desejada.[253] To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the specified amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.

[254] Para se testar quanto à atividade preventiva, pulveriza-se plantas jovens com a preparação de composto ativo à taxa de aplicação especificada. Após secagem do revestimento pulverizado, inocula-se as plantas com uma suspensão aquosa de conídeos do agente causador de sarna das maçãs (Venturia inaequalis) e depois mantém-se durante 1 dia em uma câmara de incubação a aproximadamente 20°C e uma humidade atmosférica relativa de 100%.[254] To test for preventive activity, spray young plants with the preparation of active compound at the specified application rate. After the spray coating has dried, the plants are inoculated with an aqueous conidia suspension of the apple scab causing agent (Venturia inaequalis) and then maintained for 1 day in an incubation chamber at approximately 20 ° C and atmospheric humidity. relative 100%.

[255] Coloca-se então as plantas em uma estufa a aproximadamente 21°C e a uma humidade atmosférica relativa de aproximadamente 90%.[255] The plants are then placed in a greenhouse at approximately 21 ° C and a relative atmospheric humidity of approximately 90%.

[256] O teste é avaliado 10 dias após a inoculação. Um valor de 0% designa uma eficácia que corresponde à do controle não tratado, ao passo que uma eficácia de 100% designa que não foi observada doença.[256] The test is evaluated 10 days after inoculation. A value of 0% designates an efficacy that corresponds to that of the untreated control, whereas a 100% efficacy designates that no disease was observed.

[257] O quadro seguinte mostra claramente que a atividade observada da combinação de composto ativo de acordo com a invenção é superior à atividade calculada, isto é, está presente um efeito sinergístico. Quadro 10Teste de Venturia(maças) / preventive

Figure img0034
Figure img0035
Figure img0036
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby Quadro 11 Teste de Venturia (maças) / preventive
Figure img0037
Figure img0038
Figure img0039
Figure img0040
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby Quadro 12 Teste de Venturia (maças) / preventive
Figure img0041
Figure img0042
Figure img0043
1 encontrada = atividade encontrada 2 * calculada = atividade calculada utilizando a fórmula de Colby Quadro 13 Teste de Venturia (maças) / preventive
Figure img0044
Figure img0045
Figure img0046
Figure img0047
* encontrada = atividade encontrada ** calculada = atividade calculada utilizando a fórmula de Colby[257] The following table clearly shows that the observed activity of the active compound combination according to the invention is greater than the calculated activity, that is, a synergistic effect is present. Table 10 Venturia test (apples) / preventive
Figure img0034
Figure img0035
Figure img0036
1 found = activity found 2 * calculated = activity calculated using Colby's formula Chart 11 Venturia test (apples) / preventive
Figure img0037
Figure img0038
Figure img0039
Figure img0040
1 found = activity found 2 * calculated = activity calculated using Colby's formula Chart 12 Venturia test (apples) / preventive
Figure img0041
Figure img0042
Figure img0043
1 found = activity found 2 * calculated = activity calculated using Colby's formula Table 13 Venturia test (apples) / preventive
Figure img0044
Figure img0045
Figure img0046
Figure img0047
* found = activity found ** calculated = activity calculated using Colby's formula

Claims (7)

1. Combinação, caracterizada por compreender, como ingredientes ativos: (A) uma tiazolilisoxazolina selecionada de (I-1) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-fenila, e (I-3) metano-sulfonato de 2-{3-[2-(1-{[3,5-bis- (difluorometil)-1H-pirazol-1-il]-acetil}-piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-3- clorofenila ou um sal agroquimicamente aceitável do mesmo, e (B) (2.6) fluopirame; em que os compostos (A) e (B) estão presentes em uma razão por peso A:B de 25:1.1. Combination, characterized by comprising, as active ingredients: (A) a thiazolylisoxazoline selected from (I-1) methanesulfonate of 2- {3- [2- (1 - {[3,5-bis- (difluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} - phenyl, and 2- {3- [2- (1 - {[3,5-bis- (difluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4-methanesulfonate -il) - 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl or an agrochemically acceptable salt thereof, and (B) ( 2.6) fluopirame; wherein compounds (A) and (B) are present in an A: B weight ratio of 25: 1. 2. Combinação, de acordo com a reivindicação 1, caracterizada pelo composto (A) ser: (I-3) metano-sulfonato de 2-{3-[2-(1-{[3,5- bis(difluorometil)-1H-pirazol-1-il]acetil}piperidina-4-il)- 1,3-tiazol-4-il]-4,5-di-hidro-1,2-oxazol-5-il}-3- clorofenila ou um sal agroquimicamente aceitável do mesmo,Combination according to claim 1, characterized in that compound (A) is: (I-3) 2- {3- [2- (1 - {[3,5-bis (difluoromethyl) - methanesulfonate - 1H-pyrazol-1-yl] acetyl} piperidine-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl or an agrochemically acceptable salt thereof, 3. Método para controle de fungos fitopatogênicos prejudiciais, caracterizado pelo fato de que a combinação, como definida na reivindicação 1 ou 2, é aplicada aos fungos fitopatogênicos prejudiciais e/ou ao seu habitat.3. Method for controlling harmful phytopathogenic fungi, characterized by the fact that the combination, as defined in claim 1 or 2, is applied to harmful phytopathogenic fungi and / or their habitat. 4. Uso da combinação, como definida na reivindicação 1 ou 2, caracterizado por ser para o controle de fungos fitopatogênicos prejudiciais.4. Use of the combination, as defined in claim 1 or 2, characterized by being for the control of harmful phytopathogenic fungi. 5. Uso da combinação, como definida na reivindicação 1 ou 2, caracterizado por ser como reguladores do crescimento de plantas.5. Use of the combination, as defined in claim 1 or 2, characterized as being plant growth regulators. 6. Uso da combinação, como definida na reivindicação 1 ou 2, caracterizado por ser para o tratamento de plantas transgênicas.6. Use of the combination, as defined in claim 1 or 2, characterized by being for the treatment of transgenic plants. 7. Uso da combinação, como definida na reivindicação 1 ou 2, caracterizado por ser para o tratamento de sementes e de sementes de plantas transgênicas.7. Use of the combination, as defined in claim 1 or 2, characterized by being for the treatment of seeds and seeds of transgenic plants.
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US12102087B2 (en) 2024-10-01
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BR112014020898B1 (en) 2020-08-11
ES2650764T3 (en) 2018-01-22
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AP2014007876A0 (en) 2014-08-31
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US10375961B2 (en) 2019-08-13
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JP2015511579A (en) 2015-04-20
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