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BG70207A - Метод за получаване на сребърни катализатори - Google Patents

Метод за получаване на сребърни катализатори

Info

Publication number
BG70207A
BG70207A BG070207A BG7020785A BG70207A BG 70207 A BG70207 A BG 70207A BG 070207 A BG070207 A BG 070207A BG 7020785 A BG7020785 A BG 7020785A BG 70207 A BG70207 A BG 70207A
Authority
BG
Bulgaria
Prior art keywords
catalysts
silver catalysts
obtaining silver
ethylene
acids
Prior art date
Application number
BG070207A
Other languages
English (en)
Other versions
BG60611B1 (bg
Inventor
William Armstrong
Original Assignee
Scientific Design Company, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scientific Design Company, Inc. filed Critical Scientific Design Company, Inc.
Publication of BG70207A publication Critical patent/BG70207A/bg
Publication of BG60611B1 publication Critical patent/BG60611B1/bg

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/50Silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

Катализаторите се използват при окисляване на етилен в парова фаза с молекулен кислород до етиленов окис. По метода се импрегнира носител с въглеводороден разтвор на сребърна сол на неокиселини, представляващи триалкилни оцетни киселини. Носителят е избран от групата на алуминиев окис, силициев двуокис, алумосилициев окис или техни смеси. Катализаторите могат в даден случай да бъдат промотирани с цезий, калий или рубидий. 16 претенции
BG70207A 1984-05-14 1985-05-13 Метод за получаване на сребърни катализатори BG60611B1 (bg)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/610,229 US4555501A (en) 1984-05-14 1984-05-14 Process for preparing silver catalysts

Publications (2)

Publication Number Publication Date
BG70207A true BG70207A (bg) 1993-12-24
BG60611B1 BG60611B1 (bg) 1995-10-31

Family

ID=24444215

Family Applications (1)

Application Number Title Priority Date Filing Date
BG70207A BG60611B1 (bg) 1984-05-14 1985-05-13 Метод за получаване на сребърни катализатори

Country Status (18)

Country Link
US (1) US4555501A (bg)
EP (1) EP0161930B1 (bg)
JP (1) JPH0611398B2 (bg)
KR (1) KR920005083B1 (bg)
AR (1) AR240661A1 (bg)
AU (1) AU570113B2 (bg)
BG (1) BG60611B1 (bg)
BR (1) BR8502254A (bg)
CA (1) CA1250277A (bg)
DD (1) DD233310A5 (bg)
DE (1) DE3570664D1 (bg)
ES (1) ES8606016A1 (bg)
IN (1) IN169852B (bg)
MX (2) MX167584B (bg)
RO (1) RO92423B (bg)
SU (1) SU1598856A3 (bg)
YU (2) YU45717B (bg)
ZA (1) ZA853653B (bg)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
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GB8613818D0 (en) * 1986-06-06 1986-07-09 Ici Plc Catalysts
DE3528313A1 (de) * 1985-08-07 1987-02-12 Basf Ag Silberkatalysator, seine herstellung und verwendung
US4663303A (en) * 1986-02-24 1987-05-05 The Halcon Sd Group, Inc. Process for preparing silver catalysts
US4897376A (en) * 1988-06-27 1990-01-30 Scientific Design Company, Inc. Process for preparing a catalyst for oxidation of ethylene to ethylene oxide
US5008413A (en) * 1989-10-23 1991-04-16 Scientific Design Company, Inc. Catalyst for oxidation of ethylene to ethylene oxide
US6184175B1 (en) 1993-03-01 2001-02-06 Scientic Design Company, Inc. Process for preparing silver catalyst
US5525740A (en) * 1993-03-01 1996-06-11 Scientific Design Company, Inc. Process for preparing silver catalyst and process of using same to produce ethylene oxide
WO1996004989A1 (en) * 1994-08-09 1996-02-22 Scientific Design Company, Inc. Process for preparing silver catalyst
US5602070A (en) * 1995-01-09 1997-02-11 Scientific Design Company, Inc. Process for preparing silver catalyst
US6455713B1 (en) 1998-09-14 2002-09-24 Eastman Chemical Company Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene
EP1029591B1 (en) * 1999-02-19 2005-11-02 Nippon Shokubai Co., Ltd. Method for the production of acrylic acid and method for the preparation of the catalyst
ATE291962T1 (de) 2000-10-25 2005-04-15 Mitsubishi Chem Corp Verfahren zur oxidation von olefinen unter verwendung eines silber und alkalimetall(e) enthaltenden katalysator
BR0312244B1 (pt) * 2002-06-28 2013-06-25 mÉtodo para melhorar a seletividade de um catalisador e um processo para a epoxidaÇço de uma olefina
US8148555B2 (en) * 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
KR20080102155A (ko) * 2006-02-03 2008-11-24 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 촉매의 처리 방법, 처리된 촉매, 및 이 촉매의 용도
CN103599798B (zh) 2007-05-09 2015-11-18 国际壳牌研究有限公司 环氧化催化剂及其制备方法和生产环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺的方法
US20090148600A1 (en) * 2007-12-05 2009-06-11 Xerox Corporation Metal Nanoparticles Stabilized With a Carboxylic Acid-Organoamine Complex
KR101629037B1 (ko) * 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
CN102066348B (zh) * 2008-05-07 2013-09-25 国际壳牌研究有限公司 环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或链烷醇胺的制备方法
CN110035998B (zh) 2016-12-02 2024-02-20 国际壳牌研究有限公司 调节乙烯环氧化催化剂的方法和生产环氧乙烷的相关方法

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US424235A (en) * 1890-03-25 Gearing for spring vehicles
US2391842A (en) * 1942-10-16 1945-12-25 Cities Service Oil Co Lubricating greases
US2807553A (en) * 1955-07-18 1957-09-24 Heyden Newport Chemical Corp Stabilized metal soap compositions
US2955949A (en) * 1958-09-17 1960-10-11 Exxon Research Engineering Co Paint driers
US3255222A (en) * 1961-10-23 1966-06-07 Yardney International Corp Silver salt complexes of fatty acids and method of making same
US3255223A (en) * 1962-10-29 1966-06-07 Yardney International Corp Method of preparing stable silvercontaining compositions
US3702259A (en) * 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4012425A (en) * 1972-01-07 1977-03-15 Shell Oil Company Ethylene oxide process
US4065442A (en) * 1974-10-31 1977-12-27 Standard Oil Company Pyrolysis compositions from silver salts of polycarboxylic acids
US4005049A (en) * 1975-05-23 1977-01-25 Standard Oil Company (Indiana) Silver catalysts
US4102820A (en) * 1975-12-29 1978-07-25 Texaco Development Corp. Silver catalyst for ethylene epoxidation
US4066575A (en) * 1976-07-26 1978-01-03 Halcon International, Inc. Process for the preparation of a supported silver catalyst
US4097414A (en) * 1976-08-30 1978-06-27 Texaco Development Corp. Modified ethylene oxide catalyst and a process for its preparation
FR2412538A1 (fr) * 1977-12-22 1979-07-20 Ugine Kuhlmann Catalyseurs a base d'argent pour la production d'oxyde d'ethylene
JPS54125603A (en) * 1978-03-16 1979-09-29 Kao Corp Preparation of aliphatic amine
US4262040A (en) * 1978-08-30 1981-04-14 Engelhard Minerals & Chemicals Corporation Decoration for ceramics having the appearance of gold
DE2904919A1 (de) * 1979-02-09 1980-08-21 Basf Ag Verfahren zur herstellung und regenerierung von traegerkatalysatoren sowie deren verwendung fuer die herstellung von aethylenoxid
CA1162181A (en) * 1979-03-20 1984-02-14 Paul C. Ellgen Catalyst composition and process for oxidation of ethylene to ethylene oxide
US4342667A (en) * 1979-03-26 1982-08-03 The Halcon Sd Group, Inc. Process for preparing a silver catalyst
DE2925625C2 (de) * 1979-06-26 1981-10-01 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Steigerung der Aktivität und zur Verlängerung der Standzeit bei hoher Selektivität von Silber-Träger-Katalysatoren für den Einsatz zur Ethylenoxid-Synthese
DE3014091A1 (de) * 1980-04-12 1981-10-15 EC Erdölchemie GmbH, 5000 Köln Silberhaltige traegerkatalysatoren und katalysator-zwischenprodukte, verfahren zu ihrer herstellung und ihre verwendung
FR2495958A1 (fr) * 1980-12-12 1982-06-18 Gau Georges Catalyseurs a l'argent pour la synthese de l'oxyde d'ethylene et de l'oxyde de propylene par un procede regeneratif
US4368144A (en) * 1980-12-22 1983-01-11 Nippon Shokubai Kagaku Kogyo Co., Ltd. Silver catalyst for production of ethylene oxide
JPS57107240A (en) * 1980-12-26 1982-07-03 Nippon Shokubai Kagaku Kogyo Co Ltd Production of silver catalyst for producing ethylene oxide
US4419276A (en) * 1981-09-30 1983-12-06 Union Carbide Corporation Silver catalyst for the manufacture of ethylene oxide and a process for preparing the catalyst

Also Published As

Publication number Publication date
BG60611B1 (bg) 1995-10-31
EP0161930A2 (en) 1985-11-21
DE3570664D1 (en) 1989-07-06
RO92423A (ro) 1987-09-30
YU47370B (sh) 1995-01-31
JPH0611398B2 (ja) 1994-02-16
YU79485A (en) 1987-10-31
AU570113B2 (en) 1988-03-03
EP0161930A3 (en) 1986-04-16
AR240661A1 (es) 1990-08-31
DD233310A5 (de) 1986-02-26
YU45717B (sh) 1992-07-20
ES543098A0 (es) 1986-04-01
ZA853653B (en) 1986-12-30
BR8502254A (pt) 1986-01-14
MX9207577A (es) 1994-06-30
RO92423B (ro) 1987-10-01
MX167584B (es) 1993-03-30
ES8606016A1 (es) 1986-04-01
AU4228285A (en) 1985-11-21
KR850008630A (ko) 1985-12-21
CA1250277A (en) 1989-02-21
YU158990A (sh) 1992-12-21
KR920005083B1 (ko) 1992-06-26
US4555501A (en) 1985-11-26
SU1598856A3 (ru) 1990-10-07
JPS60244338A (ja) 1985-12-04
IN169852B (bg) 1992-01-04
EP0161930B1 (en) 1989-05-31

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