AU655184B2 - A sealed cartridge for the preparation of a beverage and a process and apparatus for its production - Google Patents
A sealed cartridge for the preparation of a beverage and a process and apparatus for its production Download PDFInfo
- Publication number
- AU655184B2 AU655184B2 AU80328/91A AU8032891A AU655184B2 AU 655184 B2 AU655184 B2 AU 655184B2 AU 80328/91 A AU80328/91 A AU 80328/91A AU 8032891 A AU8032891 A AU 8032891A AU 655184 B2 AU655184 B2 AU 655184B2
- Authority
- AU
- Australia
- Prior art keywords
- cup
- filter
- lower face
- cartridge
- welded
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B7/00—Closing containers or receptacles after filling
- B65B7/16—Closing semi-rigid or rigid containers or receptacles not deformed by, or not taking-up shape of, contents, e.g. boxes or cartons
- B65B7/28—Closing semi-rigid or rigid containers or receptacles not deformed by, or not taking-up shape of, contents, e.g. boxes or cartons by applying separate preformed closures, e.g. lids, covers
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J31/00—Apparatus for making beverages
- A47J31/06—Filters or strainers for coffee or tea makers ; Holders therefor
- A47J31/0657—Filters or strainers for coffee or tea makers ; Holders therefor for brewing coffee under pressure, e.g. for espresso machines
- A47J31/0668—Filters or strainers for coffee or tea makers ; Holders therefor for brewing coffee under pressure, e.g. for espresso machines specially adapted for cartridges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B29/00—Packaging of materials presenting special problems
- B65B29/02—Packaging of substances, e.g. tea, which are intended to be infused in the package
- B65B29/022—Packaging of substances, e.g. tea, which are intended to be infused in the package packaging infusion material into capsules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B61/00—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages
- B65B61/20—Auxiliary devices, not otherwise provided for, for operating on sheets, blanks, webs, binding material, containers or packages for adding cards, coupons or other inserts to package contents
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Apparatus For Making Beverages (AREA)
- Devices For Dispensing Beverages (AREA)
- Auxiliary Devices For And Details Of Packaging Control (AREA)
- Cartons (AREA)
- Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
- Closures For Containers (AREA)
- Photographic Developing Apparatuses (AREA)
- Packages (AREA)
- Glass Compositions (AREA)
- Medicinal Preparation (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Saccharide Compounds (AREA)
- Beverage Vending Machines With Cups, And Gas Or Electricity Vending Machines (AREA)
Abstract
The invention relates to a closed cartridge (1), provided in order to be extracted under pressure, containing ground roasted coffee (5), comprising a dish (2) with a lateral wall having substantially the shape of a frustum of a cone, an upper face with a diameter greater than the lower face (7), and, on the said lower face (7), a filter (4), the said lower face being detached from the said filter and the upper face comprising an edge (6) with an annular bead on which a cover (3) is welded.
Description
i:.
1 655184
AUSTRALIA
PATENTS ACT 1990 COWMPT.ETE RPFCIFTCATTON FOR A STANDARD PATENT oo 0 o0 0 00 0 00 0 00 0 0 0 0 0 00 0 0 o 00 o o
ORIGINAL
Name of Applicant: a o Actual Inventors: 0 00 00 0 0' Address for Service: 0 ooo 0 00o 0 0 00n00 0 nvention Title: SOCIETE DES PRODUITS NESTLE S.A.
Olivier Fond and Petr Masek SHELSTON WATERS Clarence Street SYDNEY NSW 2000 "A SEALED CARTRIDGE FOR THE PREPARATION OF A BEVERAGE AND A PROCE$SS AND APPARATUS FOR ITS
PRODUCTION"
The following statement is a full description of this invention, including the best method of performing it known to us:- R- I rC I la A sealed cartridge for the preparation of a beverage and a process and apparatus for its production This invention relates to a sealed cartridge which is designed to be extracted under pressure and which contains a substance for the preparation of a beverage, comprising a cup with a lateral wall substantially frustoconical in shape and an upper face larger in diameter than the lower face.
There are several reasons for the use of coffee capsules, above all in the field of espresso type coffees which are extracted under pressure, namely: hygiene, optimal storage of the coffee, ease of use, better control of the quality of the coffee obtained and good reproducibility of the extraction conditions. Among the number of capsules available, o 00 0. 0only sealed capsules which open under the pressure of O 15 the water injected respond more completely to the eo ao arguments listed above. These capsules are So distinguished by their opening system.
0 0 :The capsules according to CH 605 293 comprise weakened zones which tear preferentially under the o: 20 effect of pressure. This solution has the disadvantage of increasing the complexity and price 4 of the capsule because the materials used have to be 0 treated very precisely to ensure that the capsules 0o0 open correctly and reproducibly.
04 4 0 o 25 The cartridge according to the present 0 0 invention is much lower in price and much easier to produce, but can still be used as a cartridge for the preparation of an espresso coffee, i.e. in which coffee is extracted under a pressure of 2 to 20 bar.
The present invention relates to a sealed cartridge which contains a substance to be extracted under pressure for the preparation of a beverage, comprising a cup with a lateral wall substantially frustoconical in shape with a lower face with a periphery and with an upper face larger in diameter than the lower face, a filter disposed on the periphery of the lower face and separate from said i
L,;
i I' I i 1L ri: i 0 00 00 0 6 a 0 0 a 0 0 0000 5 a Q oQ 0600 0 00 0 04 02 Q 0 «0 a 01 ao o, o o ao 0 00 O" 5 0 )00 a a 2 lower face and a lid welded on the upper face of the cup, characterised in that the upper face of the cup comprises an annular bead which is turned downwards, in that the filter is welded on the periphery of the lower face of the cup and in that the lower face is flat and of even thickness.
By separate is meant that the filter and the lower face are not in contact and are separated by a distance of the order of 1 mm. This separation allows the formation during extraction of the cartridge of a collecting compartment which increases in volume during the increase in pressure in the capsule, providing for effective removal of the coffee extract and thus promoting good extraction. The filter and the lower face are only in contact at the edge of the filter and the lower face.
Frustoconical in the context of the invention means both frustoconical in the strict sense and also 20 frustoellipsoidal, frustospherical or even cylindrical.
The iartridge according to the invention may be extracted by the process and with the device according to the applicants' European Patent 25 Application filed on the same date as the present application under the title "A process and a device for the extraction of sealed cartridges" (EP 90114401.4).
The annular rim folded upwards or downwards provides for high imperviousness by compression between a cartridge holder and an extraction device during the extraction process.
The cartridge is filled with a substance for the preparation of a beverage. This substance is preferably roasted and ground coffee, but may also be tea, instant coffee, a mixture of ground coffee and instant coffee or a chocolate-flavoured product.
The cartridge according to the invention is made of aluminium or of a plastic compatible with foods. t-S N
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r: i 4 4I 1 4 1 4 4(14 3 aluminium is used, the wall thickness of the cup is between 50 and 120 nm and preferably between 70 and 80 im.
Where plastic is used, the wall thickness of the cup is between 300 and 500 lim.
Since the filter has to be capable of withstanding considerable variations in pressure, it should have a greater thickness than the cup, namely of the order of 100 to 300 lim and preferably of the order of 200 4m where it is made of aluminium and in the range from 300 to 1,000 -4m where it is made of plastic. The filter according to EP 309 708, for example, may be used.
The cartridge according to the invention may vary in size according to the volume of coffee to be prepared.
The dose of coffee contained in the cartridge may vary from 5 to 20 g, the diameter of the cartridge is from to 6 cm and the thickness of the layer of coffee between 10 and 25 mm.
In one embodiment of the cartridge according to the invention, the filter is welded to the lower face, particularly in the case of a cartridge made entirely of aluminium. Welding is carried out by heat sealing, the parts to be welded comprising a heat sealing lacquer on their opposite faces. The weld seam is between 1 and mm wide, irrespective of the diameter of the cartridge,so that the cartridge obtained is well capable of withstanding pressures of up to 20 bar. The lower face is separate from the filter to avoid welding of the filter over its entire surface. In a second embodiment of the cartridge according to the invention, the lower face is welded to the filter, particularly in the case of a plastic cartridge. In this case, welding is carried out by heat sealing or by ultrasonic welding.
Where aluminium is used, the cup is formed by stamping whereas, in the case of plastic, it is formed by injection moulding or thermoforming. To facilitate opening of the cartridge during extraction, a weakened zone may
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ii E: r 4 *t 0*4 o 0 1 0 0 6 0 00 also be provided in the central zone of the lower face or an opening to which a closure is welded may be provided in this central zone.
The invention thus provides a cartridge which is resistant to high pressures during extraction and which thus enables a coffee with all characteristics of an espresso to be obtained.
The invention also relates to a process for the production of these capsules (or cartridges). Starting out with a preformed cup of aluminium or plastic, the filter is placed on and welded to the lower face, the cup is filled with roasted and ground coffee and, after tamping, the lid is welded to the upper flange of the cup.
Welding of the filter is carried out by heat sealing where the cartridge is made of aluminium and by heat sealing or ultrasonic welding where the cartridge is made of plastic. After the cup has been filled, its upper flange may also be subjected to a cleaning step before the lid is applied. The capsules pass from one stage to the other by a step-by-step feed system in a linear or circular movement, depending on the construction of the machine. The filters placed in the bottom of the cup are prepared on a parallel or perpendicular line. They are prepared by piercing holes in a moving strip of aluminium or plastic and then cutting out the filter from the strip. The cup is filled with the coffee in an inert gas atmosphere, for example or nitrogen, co 2 The process according to the invention may be carried out in a single step on a production line or even in two steps, namely: preparation of the cup with the filter and then filling with coffee and fitting of the lid.
Finally, the invention also relates to a device for carrying out the process. This device comprises a 4060 000~c A4 L. i L i- piercing tool and a tool for cutting out the filter from a strip of aluminium, the cutting tool also being used for applying and welding the filter to the inner wall of the cup passing directly below the cutting tool, a dosing and tamping station for the roasted and ground coffee and a station for welding the lid to the upper face of the cup.
The machines performing these operations may be constructed with stations arranged either in the line or around a rotary lugle.
4 As mentioned above, the cup is moved from one station to the next by a step-by-step feed system.
4t fill Upstream of the tool for welding the filter, the device further comprises a system for folding the annular bead around the upper flange of the cup and, downstream of the coffee dosing and tamping station, a system for cleaning the upper flange of the cup. Cleaning is advan- I tageously carried out by suction or sweeping.
The invention is described in more detail in the following with reference to the accompanying drawings, wherein: SFigure 1 diagrammatically illustrates the cartridge according to the invention.
Figure 2 diagrammatically illustrates a second embodiment.
Figure 3 diagrammatically illustrates a third embodiment. Figures 4 and 5 diagrammatically illustrate the device for making the capsules according to the invention.
I 6 i
'I
I 15 I t i I 30 The cartridge comprises a cup with a frustoconical wall in which a filter is welded. The roasted and ground coffee to be extracted is placed on the filter. The cartridge is closed by a lid which forms the upper face. The upper flange of the cup comprises an annular bead which is turned downwards to enable the cartridge to be firmly held in the extraction system. The lower face is not in direct contact with the filter and forms a collecting compartment (8) ensuring good extraction of the coffee. The filter (4) is welded to the lower face around the periphery (9) of the face The shoulder (10) effectively separates the filter from the face Figure 2 shows a cartridge (11) comprising a cup (12) of which the wall is frustoellipsoidal in shape and contains ground roasted coffee The upper flange (13) comprises an annular bead (14) turned downwards which establishes imperviousness during extraction of the cartridge. A curved lid (15) is welded to the flange (13).
A filter (19) is welded to the periphery (18) of the similarly curved lower face (17) of the cartridge, forming a collecting compartment (20) of which the function was explained in the foregoing.
The cartridge shown in Figs. 1 and 2 are made of aluminium or plastic. The cartridge shown in Fig. 3 is made of plastic. The cartridge (21) comprises a cup (22) having a frustoconical wall. The cup comprises an upper flange (23) to which a lid (24) is welded. The roasted and ground coffee (25) rests on a filter (26) which forms an integral part of the cup The lower face (27) is welded to the periphery (28) of the filter. The collecting compartment (29) provides for good extraction of the cartridge and the separation (30) at the upper 7 flange (23) guarantees high imperviousness during extraction of the cartridge.
Figures 4 and 5 show the device for making the cartridges. The production of the filters (32) at the station (31) comprising a roll of aluminium foil or plastic film (33) arranged on a drum (35) will be described first. The aluminium foil (36) passes between a piercing head (37) and a matrix (38) and a cutting tool (39) and a matrix The rest of the aluminium foil is wound onto the shaft (41) in the form of a roll (34) after 4i passing around the return roller The station for fitting the filter (32) comprises a feeder (44) for the cups (43) which deposits the cups onto a step-by-step S 15 feed system (45) (not shown), a folding press (46) with '44' its supporting matrix(47), the cutting tool (39) which t I may also be used as a system for fitting and welding the filter (32) with its supporting matrix (48) and, finally, a feeder (49) for containers (43) plus filters comprising a piston The machine operates as follows: The feeder (44) deposits the cups (43) one after the other onto the step-by-step feed system The cup arrives in the supporting matrix (47) which ascends in the direction of the arrow (51) while the folding press (46) descends in the direction of the arrow (52) to fold the annular bead (53) onto the cup. The cup is released i by the return of the folding press (46) and the descent of the supporting matrix The cup is moved towards the tool (39) for fitting and welding the filter. It will be considered before production of the filter (32).
The drum (35) delivers the aluminium foil (36) in the i1 direction of the arrow The piercing head (37) with the needles (55) ascends in the direction of the arrow (56) while the matrix (38) with bores (57) descends in the direction of the arrow (58) to pierce the foil (36).
i- 15 41*2 S I 14 -8- The filter thus formed from the foil advances to the cutting tool The precision with which the holes pierced are centred in relation to the cutting tool (39) is guaranteed by a feed system comprising a detection system known per se, for example based on a photoelectric cell (not shown). The filter is cut out by descent of the tool (39) in the direction of the arrow (59) as far as the fixed matrix The cutting tool (39) causes the filter to descend, places it in the cup and comprises an annular heating system enabling the filter to be welded in the bottom of the cup. After the filter has been cut out, the remainder of the aluminium foil is wound onto the shaft The cup with its filter is introduced into the feeder (49) by ascent of the piston (50) in the direction of the arrow The system (61) for dosing the coffee (Fig. 5) comprises a passage (62) for the arrival of the roasted and ground coffee, a tamping system (63) and a support The station (65) for fixing the lid comprises a welding head (66) and a support (67).
The system operates as follows:
I
The feeder (49) deposits the cups (43) with their filters (32) onto the step-by-step feed system The support (64) ascends while the coffee dosing system (61) descends and surrounds the cup The coffee (69) is dosed through the passage (62) and the tamping system (63) descends so that the coffee is flush with the level of the upper flange of the cup. The filled capsule is released and arrives at the lid fixing station where it is held between the welding head (66) and the support (67. The lid (71) is welded to the upper flange of the capsule by means of the annular heating system (70) of the welding head The cartridge is then released and is taken to the packing station for wrapping.
Will""
Claims (12)
1. A sealed cartridge which contains a substance to be extracted under pressure for the preparation of a beverage, comprising a cup with a lateral wall substantially frustoconical in shape with a lower face with a peax-phery and with an upper face larger in diameter than the lower face, a filter disposed on h periphery of the lower face and separate from said lower face and a lid welded on the upper face of the cup, characterised in that the upper face of the cup comprises an annular bead which is turned downwards, in that the filter is welded on the periphery of the lower face of the cup and in that the lower face is flat and of even thickness.
2. A cartridge as claimed in claim 1, characterized 15 in that it is made of F'uminium or plastic.
3. A cartridge as claimed in claim 1 or 2, characterized in that the cup has a thickness of 50 to 120 j.tm when it is made of aluminium and a thickness of 300 to 500 lim when it is made of plastic.
4. A cartridge as claimed in any one of claims 1 to 3, characterized in that it has a diameter of 2.5 to 6 cm and a thickness of 10 to 25 mm.
A process for the production of the cartridge claimed in any one of claims 1 to 4, characterized in 25 that the filter is deposited and welded to the lower face of the cup, the cup is filled with roasted and ground coffee and, after tamping, the lid is welded to the upper flange of the cup.
6. A process as claimed in claim 5, characterized in 30 that the filter is prepared by piercing holes in a moving strip of aluminium or plastic after which the filter is cut out from the strip.
7. A process as claimed in claim 5 or 6, characterized in that the cup is filled with coffee in an atmosphere of nitrogen or CO 2
8. A device for carrying out the process claimed in any one of claims 5 to 7, characterized in that it rC~rl iii _1 II rl) C-i ~1 f; i, LA 1-: "I 10 comprises a piercing tool and a tool for cutting out the filter from a strip of aluminium, the cutting tool also being used for fitting and welding the filter to the lower wall of the cup passing directly beneath the cutting tool, a dosing and tamping station for the roasted and ground coffee and a welding station for welding the lid to the upper face of the cup.
9. A device as claimed in claim 8, characterized in that the cup is moved by a step-by-step system.
10. A device as claimed in claim 8 or 9, characterized in that, upstream of the tool for welding the filter, it comprises a system for folding the annular bead around the upper flange of the cup.
11. A sealed cartridge substantially as herein described with reference to any one of Figures 1 or 2 of the accompanying drawings.
12. A device for carrying out the production of a sealed cartridge substantially as herein described with reference to Figures 4 and 5 of the accompanying drawings. DATED this 27th day of July 1994 SOCIETE DES PRODUITS NESTLE S.A. Attorney: RUTH M. CLARKSON Fellow Institute of Patent Attorneys of Australia of SHELSTON WATERS ro a. ar a a ar a. Ga a a a at a a a.R a 04 at a at' I I Sa I jqj-' 'a To: The Commissioner of Patents WODEN ACT 26Q06 SFee $25 .00 Fee: $256.00 L. g e I i:: L 4 Abstract A sealed cartridge for the preparation of a beverage and a process and apparatus for its production O rr# ~r10 "110 GI I a O'Oa a 14 15 P 15 The invention relates to a sealed cartridge which is designed to be extracted under pressure and which con- tains a substance for the preparation of a beverage comprising a cup with a lateral wall substantially frustoconical in shape, an upper face larger in diameter than the lower face and, on the lower face a filter the lower face being separate from the filter, flat and of even thickness and the upper face comprising a flange with an annular rim to which a lid is welded. Fig. 1 t L
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP90114404 | 1990-07-27 | ||
EP90114404A EP0468079B1 (en) | 1990-07-27 | 1990-07-27 | Closed cartridge for making a beverage, process and device for manufacturing such a cartridge |
Publications (2)
Publication Number | Publication Date |
---|---|
AU8032891A AU8032891A (en) | 1992-01-30 |
AU655184B2 true AU655184B2 (en) | 1994-12-08 |
Family
ID=8204270
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU80328/91A Ceased AU655184B2 (en) | 1990-07-27 | 1991-07-10 | A sealed cartridge for the preparation of a beverage and a process and apparatus for its production |
Country Status (16)
Country | Link |
---|---|
EP (1) | EP0468079B1 (en) |
JP (1) | JP2784282B2 (en) |
AT (1) | ATE142974T1 (en) |
AU (1) | AU655184B2 (en) |
BR (1) | BR9102993A (en) |
CA (1) | CA2046558A1 (en) |
DE (1) | DE69028628T2 (en) |
DK (1) | DK0468079T3 (en) |
ES (1) | ES2091780T3 (en) |
FI (1) | FI96738C (en) |
GR (1) | GR3021816T3 (en) |
MX (1) | MX9100373A (en) |
NO (1) | NO303170B1 (en) |
NZ (1) | NZ238935A (en) |
PT (1) | PT98458B (en) |
ZA (1) | ZA915420B (en) |
Cited By (3)
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EP1900653A1 (en) * | 2006-09-18 | 2008-03-19 | Nicoletta Francovicchio | Sealed capsule for making a beverage |
CN102741135A (en) * | 2009-10-23 | 2012-10-17 | K-Fee系统有限责任公司 | Portion capsule and method for producing a portion capsule |
CN102933471A (en) * | 2009-12-16 | 2013-02-13 | K-Fee系统有限责任公司 | Portion capsule and use of portion capsule |
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US6662955B1 (en) * | 1998-08-11 | 2003-12-16 | Food Equipment Technologies Company Inc. | Beverage ingredient filter and assembly |
DE20015903U1 (en) | 2000-09-14 | 2000-12-07 | Eugster/Frismag Ag, Romanshorn | Magazine for espresso coffee capsules |
DE20100166U1 (en) | 2001-01-05 | 2001-03-29 | Melitta Haushaltsprodukte GmbH & Co. KG, 32427 Minden | Portion pack for the production of a brewed beverage |
CA2421128C (en) | 2002-03-14 | 2008-05-20 | Robert Hale | Beverage cartridge and filter assembly |
ITMI20021087A1 (en) * | 2002-05-21 | 2003-11-21 | Sergio Tonon | CARTRIDGE FOR COFFEE AND SOLUBLE PRODUCTS APPARATUS FOR THE EXTRACTION OF BEVERAGES FROM THE CARTRIDGE AND RELATED METHOD OF PRODUCTION OF A DRINK |
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ITTV20030058A1 (en) * | 2003-04-02 | 2004-10-03 | Hausbrandt Trieste 1892 S P A | SINGLE-DOSE PLASTIC CAPSULES FOR POWDER COFFEE AND SIMILAR. |
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- 1990-07-27 AT AT90114404T patent/ATE142974T1/en not_active IP Right Cessation
- 1990-07-27 DK DK90114404.8T patent/DK0468079T3/da active
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EP1900653A1 (en) * | 2006-09-18 | 2008-03-19 | Nicoletta Francovicchio | Sealed capsule for making a beverage |
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CN102933471B (en) * | 2009-12-16 | 2015-07-29 | K-Fee系统有限责任公司 | The application of distributor disk and distributor disk |
Also Published As
Publication number | Publication date |
---|---|
FI96738C (en) | 1996-08-26 |
PT98458A (en) | 1993-09-30 |
ATE142974T1 (en) | 1996-10-15 |
PT98458B (en) | 1999-01-29 |
EP0468079A1 (en) | 1992-01-29 |
NO912910L (en) | 1992-01-28 |
MX9100373A (en) | 1992-02-28 |
FI96738B (en) | 1996-05-15 |
JPH04236920A (en) | 1992-08-25 |
FI913270A (en) | 1992-01-28 |
JP2784282B2 (en) | 1998-08-06 |
DK0468079T3 (en) | 1997-03-03 |
DE69028628T2 (en) | 1997-01-30 |
CA2046558A1 (en) | 1992-01-28 |
DE69028628D1 (en) | 1996-10-24 |
ES2091780T3 (en) | 1996-11-16 |
NZ238935A (en) | 1994-06-27 |
ZA915420B (en) | 1992-04-29 |
FI913270A0 (en) | 1991-07-05 |
BR9102993A (en) | 1992-02-18 |
GR3021816T3 (en) | 1997-02-28 |
NO303170B1 (en) | 1998-06-08 |
NO912910D0 (en) | 1991-07-25 |
EP0468079B1 (en) | 1996-09-18 |
AU8032891A (en) | 1992-01-30 |
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