Nothing Special   »   [go: up one dir, main page]

AU2001236985A1 - Treatment of molecular sieves with silicon containing compounds - Google Patents

Treatment of molecular sieves with silicon containing compounds

Info

Publication number
AU2001236985A1
AU2001236985A1 AU2001236985A AU3698501A AU2001236985A1 AU 2001236985 A1 AU2001236985 A1 AU 2001236985A1 AU 2001236985 A AU2001236985 A AU 2001236985A AU 3698501 A AU3698501 A AU 3698501A AU 2001236985 A1 AU2001236985 A1 AU 2001236985A1
Authority
AU
Australia
Prior art keywords
treatment
containing compounds
molecular sieves
silicon containing
silicon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001236985A
Inventor
Jar-Lin Kao
John D. Y. Ou
Hsiang-Ning Sun
Stephen N. Vaughn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of AU2001236985A1 publication Critical patent/AU2001236985A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B01J2229/123—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation in order to deactivate outer surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AU2001236985A 2000-02-16 2001-02-13 Treatment of molecular sieves with silicon containing compounds Abandoned AU2001236985A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US50548300A 2000-02-16 2000-02-16
US09505483 2000-02-16
PCT/US2001/004668 WO2001060746A1 (en) 2000-02-16 2001-02-13 Treatment of molecular sieves with silicon containing compounds

Publications (1)

Publication Number Publication Date
AU2001236985A1 true AU2001236985A1 (en) 2001-08-27

Family

ID=24010489

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2001236985A Abandoned AU2001236985A1 (en) 2000-02-16 2001-02-13 Treatment of molecular sieves with silicon containing compounds

Country Status (3)

Country Link
US (2) US6841510B2 (en)
AU (1) AU2001236985A1 (en)
WO (1) WO2001060746A1 (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6759360B2 (en) * 2002-03-29 2004-07-06 Exxonmobil Chemical Patent Inc. Interior surface modifications of molecular sieves with organometallic reagents and the use thereof for the conversion of oxygenates to olefins
WO2004102162A2 (en) * 2003-03-21 2004-11-25 The Regents Of The University Of California Inorganic oxides comprising multiple surface-bound functional groups
US7015174B2 (en) 2003-06-20 2006-03-21 Exxonmobil Chemical Patents Inc. Maintaining molecular sieve catalytic activity under water vapor conditions
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
US20060231461A1 (en) * 2004-08-10 2006-10-19 Weijian Mo Method and apparatus for making a middle distillate product and lower olefins from a hydrocarbon feedstock
WO2007006584A2 (en) * 2005-07-14 2007-01-18 Elsper Ruediger Inorganic solid state cation conductor and method for producing the same
EP1792886A1 (en) * 2005-11-29 2007-06-06 BP Chemicals Limited Process for producing propylene
CA2684223A1 (en) * 2007-04-13 2008-10-23 Shell International Research Maatschappij B.V. Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock
CA2685541A1 (en) * 2007-04-30 2008-11-06 Shell Oil Company Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock
US20100324232A1 (en) * 2007-10-10 2010-12-23 Weijian Mo Systems and methods for making a middle distillate product and lower olefins from a hydrocarbon feedstock
US8715392B2 (en) * 2009-05-21 2014-05-06 Battelle Memorial Institute Catalyzed CO2-transport membrane on high surface area inorganic support
US8673067B2 (en) * 2009-05-21 2014-03-18 Battelle Memorial Institute Immobilized fluid membranes for gas separation
US8481187B2 (en) 2009-09-10 2013-07-09 Battelle Memorial Institute High-energy metal air batteries
US9834727B2 (en) * 2010-04-23 2017-12-05 Organic Fuel Technology A/S Process for the production of biofuel
RU2505356C2 (en) * 2011-12-27 2014-01-27 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Method of obtaining catalyst and method of synthesis of c2-c4 olefins in presence of catalyst obtained thereof
US9790139B2 (en) 2013-12-20 2017-10-17 Exxonmobil Chemical Patents Inc. Process for converting oxygenates to aromatic hydrocarbons
TWI659778B (en) 2014-04-09 2019-05-21 美商Ｗ Ｒ 康格雷氏公司 Improved zeolite particles for adsorption and / or desorption of gases and liquids, and application and manufacturing method thereof
US9783463B2 (en) 2014-09-30 2017-10-10 Exxonmobil Chemical Patents Inc. Conversion of acetylene and methanol to aromatics
CN107428628B (en) 2015-03-31 2021-03-02 埃克森美孚化学专利公司 Zoned process for oxygenated hydrocarbon conversion
CN106608634B (en) * 2015-10-22 2018-07-17 中国石油化工股份有限公司 The preparation method of cocrystallization molecular sieve integral material
WO2018071897A1 (en) 2016-10-14 2018-04-19 International Flavors & Fragrances Inc. High performing, high impact bloom accord
EP3544730A1 (en) 2016-11-28 2019-10-02 Basf Se Catalyst composite comprising an alkaline earth metal containing cha zeolite and use thereof in a process for the conversion of oxygenates to olefins
CN108609631B (en) * 2018-06-15 2022-03-25 山西大同大学 Method for synthesizing SAPO-20 molecular sieve
CN114031092B (en) * 2021-12-16 2023-03-24 中节能万润股份有限公司 Preparation method of SAPO-20 molecular sieve

Family Cites Families (72)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4076698A (en) 1956-03-01 1978-02-28 E. I. Du Pont De Nemours And Company Hydrocarbon interpolymer compositions
NZ126521A (en) 1959-06-06
US3305538A (en) 1961-11-22 1967-02-21 Montedison Spa Polymerization process
US3364190A (en) 1964-04-27 1968-01-16 Standard Oil Co Process for polymerizing propylene to syndiotactic polypropylene
CA849081A (en) 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
CA1086426A (en) 1975-10-13 1980-09-23 Shunji Minami Analog voltage memory device
US4090981A (en) 1976-09-23 1978-05-23 Mobile Oil Corporation Catalyst for selective production of para dialkyl substituted benzenes
US4100219A (en) 1976-03-31 1978-07-11 Mobil Oil Corporation Silica-modified zeolite catalyst and conversion therewith
US4060568A (en) 1976-03-31 1977-11-29 Mobil Oil Corporation Silica-modified zeolite catalyst and conversion therewith
US4079096A (en) 1976-11-04 1978-03-14 Mobil Oil Corporation Manufacture of light olefins
US4086186A (en) 1976-11-04 1978-04-25 Mobil Oil Corporation Crystalline zeolite ZSM-34 and method of preparing the same
US4079095A (en) 1976-11-04 1978-03-14 Mobil Oil Corporation Manufacture of light olefins
US4145315A (en) 1976-12-23 1979-03-20 Mobil Oil Corporation Silica-modified zeolite catalyst
US4302565A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
US4243691A (en) 1979-05-18 1981-01-06 The Procter & Gamble Company Sodium-free salt substitute
DE3008146A1 (en) 1980-03-04 1981-09-17 Hoechst Ag METHOD FOR PRODUCING AN ALUMINUM SILICATE CATALYST FOR CONVERTING WATER-BASED METHANOL AND / OR WATER-BASED DIMETHYL ETHER IN LOWER OLEFINS
US4402867A (en) * 1981-12-22 1983-09-06 Mobil Oil Corporation Silica-modified zeolite catalysts
US4440871A (en) 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4452909A (en) * 1982-09-13 1984-06-05 E. I. Du Pont De Nemours And Company Process for coating crystalline silica polymorphs
US4677242A (en) 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins
US4499327A (en) 1982-10-04 1985-02-12 Union Carbide Corporation Production of light olefins
US4677243A (en) 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
US4477583A (en) * 1983-06-09 1984-10-16 Mobil Oil Corporation Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes
US4594332A (en) 1983-10-20 1986-06-10 Basf Aktiengesellschaft Preparation of hard, fracture-resistant catalysts from zeolite powder
US4683334A (en) * 1985-04-30 1987-07-28 E. I. Du Pont De Nemours & Company Modified 8-ring zeolites as catalysts for conversion of methanol and ammonia to dimethylamine
US4659685A (en) 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
US4752651A (en) 1986-06-16 1988-06-21 Union Carbide Corporation Production of light olefins
US4849386A (en) 1987-04-08 1989-07-18 Taiwan Styrene Monomer Corporation Novel silicon-modified catalyst Si/HZSM-5 preparation
US4861938A (en) 1987-07-07 1989-08-29 Uop Chemical conversion process
US4861743A (en) 1987-11-25 1989-08-29 Uop Process for the production of molecular sieves
US4943424A (en) 1988-02-12 1990-07-24 Chevron Research Company Synthesis of a crystalline silicoaluminophosphate
FR2645141B1 (en) 1989-03-31 1992-05-29 Elf France PROCESS FOR THE SYNTHESIS OF PRECURSORS OF MOLECULAR SIEVES OF THE SILICOALUMINOPHOSPHATE TYPE, PRECURSORS OBTAINED AND THEIR APPLICATION FOR OBTAINING SAID MOLECULAR SIEVES
US5279810A (en) 1990-12-20 1994-01-18 Mobil Oil Corporation Method of preparing silicoaluminophosphate compositions using a reagent containing both phosphorus and silicon reactive sites in the same molecule
US5095163A (en) 1991-02-28 1992-03-10 Uop Methanol conversion process using SAPO catalysts
US5233117A (en) 1991-02-28 1993-08-03 Uop Methanol conversion processes using syocatalysts
DE4131268A1 (en) 1991-09-20 1993-03-25 Basf Ag METHOD FOR PRODUCING ALUMO AND SILICOALUMOPHOSPHATES WITH AEL STRUCTURE USING 1,2-BIS (4-PYRIDYL) ETHANE
US5126308A (en) 1991-11-13 1992-06-30 Uop Metal aluminophosphate catalyst for converting methanol to light olefins
US5191141A (en) 1991-11-13 1993-03-02 Uop Process for converting methanol to olefins using an improved metal aluminophosphate catalyst
NO174341B1 (en) 1991-12-23 1994-04-21 Polymers Holding As Prepare foremost crystalline microporosis SiAl phosphates with controlled Si content, crystalline microporosis SiAl phosphates with improved stability against deactivation and use thereof in the preparation of olefins from methanol
US5321183A (en) 1992-03-12 1994-06-14 Mobil Oil Corp. Process for the regioselective conversion of aromatics to para-disubstituted benzenes
US5278345A (en) 1992-05-27 1994-01-11 Exxon Chemical Patents Inc. Use of ECR-1, mazmorite and ECR-18 in the conversion of oxygenates to hydrocarbons
CA2136625C (en) 1992-05-27 1999-05-04 Marcel J. G. Janssen Use of acid extracted molecular sieve catalysts in oxygenate conversion
US5365003A (en) * 1993-02-25 1994-11-15 Mobil Oil Corp. Shape selective conversion of hydrocarbons over extrusion-modified molecular sieve
US5349113A (en) 1993-02-25 1994-09-20 Mobil Oil Corp. Shape selective hydrocarbon conversion over pre-selectivated, activated catalyst
US5349114A (en) 1993-04-05 1994-09-20 Mobil Oil Corp. Shape selective hydrocarbon conversions over modified catalyst
US5476823A (en) 1993-05-28 1995-12-19 Mobil Oil Corp. Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof
US5714662A (en) 1995-08-10 1998-02-03 Uop Process for producing light olefins from crude methanol
TW325461B (en) * 1995-09-11 1998-01-21 Air Prod & Chem Ammoxidation of alkanes and alkenes
US5962762A (en) 1995-12-13 1999-10-05 Sun; Hsian-Ning Use of transition metal containing small pore molecular sieve catalysts in oxygenate conversion
US5714663A (en) 1996-02-23 1998-02-03 Exxon Research And Engineering Company Process for obtaining significant olefin yields from residua feedstocks
US6040264A (en) 1996-04-04 2000-03-21 Exxon Chemical Patents Inc. Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion
EP0912473B1 (en) * 1996-05-29 2003-04-16 ExxonMobil Chemical Patents Inc. Methylation of toluene to para-xylene
KR20000016111A (en) 1996-05-29 2000-03-25 엑손 케미칼 패턴츠 인코포레이티드 Hydrocarbon conversion catalyst and use thereof
US5904880A (en) 1996-12-31 1999-05-18 Exxon Chemical Patents Inc. One step conversion of methanol to hydrogen and carbon dioxide
US5952538A (en) 1996-12-31 1999-09-14 Exxon Chemical Patents Inc. Use of short contact time in oxygenate conversion
US5925586A (en) 1996-12-31 1999-07-20 Exxon Chemical Patents, Inc. Phosphorus modified small pore molecular sieve catalysts, and their use in the production of light olefins
US5960643A (en) 1996-12-31 1999-10-05 Exxon Chemical Patents Inc. Production of ethylene using high temperature demethanization
US5925800A (en) 1996-12-31 1999-07-20 Exxon Chemical Patents Inc. Conversion of oxygenates to hydrocarbons with monolith supported non-zeolitic molecular sieve catalysts
US5907076A (en) 1996-12-31 1999-05-25 Exxon Chemical Patents Inc. Process for selectively separating hydrogen, or both hydrogen and carbon monoxide from olefinic hydrocarbons
US6051746A (en) 1997-06-18 2000-04-18 Exxon Chemical Patents Inc. Oxygenate conversions using modified small pore molecular sieve catalysts
US6023005A (en) 1997-07-03 2000-02-08 Exxon Chemicals Patents Inc. Process for converting oxygenates to olefins using molecular sieve catalysts comprising desirable carbonaceous deposits
TWI234556B (en) * 1997-07-23 2005-06-21 Mitsubishi Gas Chemical Co Catalysts for methanol conversion reactions
US5927063A (en) 1997-08-19 1999-07-27 Exxon Chemical Patents Inc. High efficiency reformed methanol gas turbine power plants
US5932512A (en) 1997-08-19 1999-08-03 Exxon Chemical Patents, Inc. Fluorination of synthesized molecular sieve catalysts for increased selectivity to ethylene during conversion of oxygenates to olefins
US5892079A (en) 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use
US6040257A (en) 1997-11-07 2000-03-21 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
US6005155A (en) 1997-12-03 1999-12-21 Exxon Chemicals Patents Inc. Modification of molecular sieve catalyst for reduced methane production during conversion of oxygenates to olefins
US5912393A (en) 1997-12-09 1999-06-15 Uop Llc Metallo aluminophosphate molecular sieve with novel crystal morphology and methanol to olefin process using the sieve
US6046373A (en) 1998-04-29 2000-04-04 Exxon Chemical Patents Inc. Catalytic conversion of oxygenates to olefins
US6034020A (en) 1998-12-29 2000-03-07 Phillips Petroleum Company Zeolite-based catalyst material, the preparation thereof and the use thereof
US6051745A (en) 1999-03-04 2000-04-18 Phillips Petroleum Company Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins
US6046371A (en) * 1999-05-05 2000-04-04 Phillips Petroleum Company Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins

Also Published As

Publication number Publication date
US7102051B2 (en) 2006-09-05
WO2001060746A1 (en) 2001-08-23
US20050003957A1 (en) 2005-01-06
US20030027712A1 (en) 2003-02-06
US6841510B2 (en) 2005-01-11

Similar Documents

Publication Publication Date Title
AU2001236985A1 (en) Treatment of molecular sieves with silicon containing compounds
AU2001272849A1 (en) Composition for the treatment of osteoarthritis
AU2002257936A1 (en) Methods of well treatment
AU2002223827A1 (en) Well treatment
AU2002211686A1 (en) Bandage using molecular sieves
AU2001233081A1 (en) Composition for treatment of stress
AU2000276362A1 (en) Composition for the treatment of diabetes
AU2002342310A1 (en) Modification of drawn film
AU2002361149A1 (en) Set of teeth
AU2001269704A1 (en) Oxazinoquinolones useful for the treatment of viral infections
AU2002231206A1 (en) Treatment of depression
AU2001237992A1 (en) Purification of oligonucleotides
AU2002322481A1 (en) Use of r-nsaid compounds for anti-hiv treatment
AU2002353739A1 (en) Therapeutic compounds
EP1394166A3 (en) Organosilicon Compounds
AU2001276919A1 (en) Haplotypes of the mmp13 gene
AU2002243497A1 (en) Ozone irrigator
AU2001293818A1 (en) Polycondensation of organic silicon compounds
AU2001282277A1 (en) Treatment of mycobacterial infection
AU2001253560A1 (en) Methods of treatment
AU2000272704A1 (en) Use of compounds for the treatment of obesity
AU2002341485A1 (en) Treatment of polyaluminium compounds
AU2002321877A1 (en) Oral treatment of hemophilia
AUPR282601A0 (en) Treatment of combustible liquids
AU2002303272A1 (en) Functional treatment of textile materials