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ATE526080T1 - METHOD FOR PRODUCING DEFORMED ZEOLITES AND METHOD FOR REMOVING IMPURITIES FROM A GAS STREAM - Google Patents

METHOD FOR PRODUCING DEFORMED ZEOLITES AND METHOD FOR REMOVING IMPURITIES FROM A GAS STREAM

Info

Publication number
ATE526080T1
ATE526080T1 AT03008047T AT03008047T ATE526080T1 AT E526080 T1 ATE526080 T1 AT E526080T1 AT 03008047 T AT03008047 T AT 03008047T AT 03008047 T AT03008047 T AT 03008047T AT E526080 T1 ATE526080 T1 AT E526080T1
Authority
AT
Austria
Prior art keywords
binder
gas stream
zeolite
removing impurities
zeolites
Prior art date
Application number
AT03008047T
Other languages
German (de)
Inventor
Armin Pfenninger
Sonja Odolo-Hitz
Original Assignee
Zeochem Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zeochem Ag filed Critical Zeochem Ag
Application granted granted Critical
Publication of ATE526080T1 publication Critical patent/ATE526080T1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/22—Type X
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/402—Dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/404—Nitrogen oxides other than dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

In the production of shaped zeolites (I) by mixing faujasite family zeolite crystals having a silica to alumina ratio of 3.0 or less (preferably type LSX zeolite, optionally together with type 13X zeolite), a highly dispersed attapulgite binder (II) (optionally mixed with other clay binder(s)) and water, forming shaped articles from the mixture, drying and calcining to give an active adsorbent, the binder (II) has a bulk density of more than 550 g/l (measured according to EN ISO 787:1995D). An independent claim is included for zeolitic adsorbents obtained by the process.
AT03008047T 2003-04-14 2003-04-14 METHOD FOR PRODUCING DEFORMED ZEOLITES AND METHOD FOR REMOVING IMPURITIES FROM A GAS STREAM ATE526080T1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP03008047A EP1468731B1 (en) 2003-04-14 2003-04-14 Method for preparing shaped zeolites and method for removing impurities from a gas stream

Publications (1)

Publication Number Publication Date
ATE526080T1 true ATE526080T1 (en) 2011-10-15

Family

ID=32892863

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03008047T ATE526080T1 (en) 2003-04-14 2003-04-14 METHOD FOR PRODUCING DEFORMED ZEOLITES AND METHOD FOR REMOVING IMPURITIES FROM A GAS STREAM

Country Status (7)

Country Link
US (1) US20070062369A1 (en)
EP (1) EP1468731B1 (en)
JP (1) JP2006522730A (en)
KR (1) KR101005396B1 (en)
AT (1) ATE526080T1 (en)
CA (1) CA2522135A1 (en)
WO (1) WO2004089536A1 (en)

Families Citing this family (14)

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FR2863909B1 (en) * 2003-12-22 2006-05-26 Ceca Sa PROCESS FOR PURIFYING GASEOUS STREAMS CONTAMINATED BY CO2 AND HYDROCARBON (S) AND / OR NITROGEN OXIDE (S) BY AGGLOMERIC ZEOLITIC ADSORBENT
US7413595B2 (en) 2005-04-08 2008-08-19 Air Products And Chemicals, Inc. Control scheme for hybrid PSA/TSA systems
US7713334B1 (en) * 2006-10-27 2010-05-11 The United States Of America As Represented By The Secretary Of The Army Process for removing epoxides
KR100879312B1 (en) * 2007-05-25 2009-01-19 주식회사 애니텍 A Manufacturing Method of the CO2 Gas Absorbent
US7875106B2 (en) * 2008-05-30 2011-01-25 Battelle Memorial Institute Adsorbent and adsorbent bed for materials capture and separation processes
WO2010113173A2 (en) * 2009-03-31 2010-10-07 Council Of Scientific & Industrial Research A barium and potassium exchanged zeolite-x adsorbents for co2 removal from a gas mixture and preparation thereof
DE102011104006A1 (en) 2010-12-10 2012-06-14 Süd-Chemie AG Granulated zeolites with high adsorption capacity for the adsorption of organic molecules
CN102502693A (en) * 2011-10-27 2012-06-20 江苏奥石科技有限公司 Method for synthesizing large-grain and highly-dispersed 4A zeolite
KR20150112988A (en) 2013-01-31 2015-10-07 바스프 에스이 Metal-organic framework extrudates with high packing density and tunable pore volume
WO2014118054A1 (en) 2013-01-31 2014-08-07 Basf Se Stable spherical, porous metal-organic framework shaped bodies for gas storage and gas separation
US20140323289A1 (en) * 2013-04-24 2014-10-30 Uop Llc Zeolitic adsorbents for use in adsorptive separation processes and methods for manufacturing the same
EP2985075A1 (en) 2014-08-15 2016-02-17 Basf Se Shaped body made of a porous material
KR102248115B1 (en) * 2019-07-01 2021-05-03 한국화학연구원 Catalysts for Fischer―Tropsch Synthesis Reaction and Preparing Method Thereof
KR20210093181A (en) 2020-01-17 2021-07-27 주식회사 보야스에너지 Air cleaner filter containing hydrophobic zeolite and reduction of volatile organic compounds using the same

Family Cites Families (16)

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US2882244A (en) * 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
DE1040005B (en) * 1955-07-01 1958-10-02 Union Carbide Corp Process for making bound molecular sieves
DE1055515B (en) * 1956-11-05 1959-04-23 Union Carbide Corp Process for making bound molecular sieves
US3078639A (en) * 1960-01-06 1963-02-26 Union Carbide Corp Carbon dioxide removal from vapor mixtures
DE2642777A1 (en) * 1976-09-23 1978-03-30 Camag Chemie DEVICE FOR APPLYING LIQUID SAMPLES TO SURFACES
US4818508A (en) * 1985-08-20 1989-04-04 Uop Process for preparing molecular sieve bodies
US5493821A (en) * 1994-05-04 1996-02-27 Uop Adsorbent for use in double glazed windows
US5531808A (en) * 1994-12-23 1996-07-02 The Boc Group, Inc. Removal of carbon dioxide from gas streams
US6171370B1 (en) * 1998-03-04 2001-01-09 Tosoh Corporation Adsorbent for separating gases
JPH11246282A (en) * 1998-03-04 1999-09-14 Tosoh Corp X-zeolite bead compact and its production
US6183539B1 (en) * 1998-07-01 2001-02-06 Zeochem Co. Molecular sieve adsorbent for gas purification and preparation thereof
US6106593A (en) * 1998-10-08 2000-08-22 Air Products And Chemicals, Inc. Purification of air
JP2000210557A (en) * 1998-11-16 2000-08-02 Tosoh Corp Molded product containing x-type zeolite, manufacture and use application thereof
JP2000211915A (en) * 1998-11-16 2000-08-02 Tosoh Corp Formed compact containing low-silica x type zeolite, its production and use thereof
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Also Published As

Publication number Publication date
JP2006522730A (en) 2006-10-05
EP1468731B1 (en) 2011-09-28
EP1468731A1 (en) 2004-10-20
KR20060007019A (en) 2006-01-23
CA2522135A1 (en) 2004-10-21
US20070062369A1 (en) 2007-03-22
KR101005396B1 (en) 2010-12-30
WO2004089536A1 (en) 2004-10-21

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