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ATE488294T1 - GENERATOR FOR ELECTRICALLY CONDUCTIVE ELUENTS AND ASSOCIATED METHOD OF USE - Google Patents

GENERATOR FOR ELECTRICALLY CONDUCTIVE ELUENTS AND ASSOCIATED METHOD OF USE

Info

Publication number
ATE488294T1
ATE488294T1 AT07017726T AT07017726T ATE488294T1 AT E488294 T1 ATE488294 T1 AT E488294T1 AT 07017726 T AT07017726 T AT 07017726T AT 07017726 T AT07017726 T AT 07017726T AT E488294 T1 ATE488294 T1 AT E488294T1
Authority
AT
Austria
Prior art keywords
ions
zone
barrier portion
source
eluents
Prior art date
Application number
AT07017726T
Other languages
German (de)
Inventor
Yan Liu
Nebojsa Avdalovic
Original Assignee
Dionex Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dionex Corp filed Critical Dionex Corp
Application granted granted Critical
Publication of ATE488294T1 publication Critical patent/ATE488294T1/en

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02Column chromatography
    • G01N30/26Conditioning of the fluid carrier; Flow patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44Ion-selective electrodialysis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44Ion-selective electrodialysis
    • B01D61/46Apparatus therefor
    • B01D61/48Apparatus therefor having one or more compartments filled with ion-exchange material, e.g. electrodeionisation
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02Column chromatography
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02Column chromatography
    • G01N30/26Conditioning of the fluid carrier; Flow patterns
    • G01N30/28Control of physical parameters of the fluid carrier
    • G01N30/34Control of physical parameters of the fluid carrier of fluid composition, e.g. gradient
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/96Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation using ion-exchange
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08Selective adsorption, e.g. chromatography
    • B01D15/10Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/16Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to the conditioning of the fluid carrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08Selective adsorption, e.g. chromatography
    • B01D15/10Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/16Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to the conditioning of the fluid carrier
    • B01D15/166Fluid composition conditioning, e.g. gradient
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/96Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation using ion-exchange
    • G01N2030/965Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation using ion-exchange suppressor columns
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T436/00Chemistry: analytical and immunological testing
    • Y10T436/25Chemistry: analytical and immunological testing including sample preparation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Urology & Nephrology (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Control Of El Displays (AREA)
  • Electroluminescent Light Sources (AREA)
  • Control Of Indicators Other Than Cathode Ray Tubes (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)

Abstract

Apparatus comprising: (a) a source of first ions in a substantially non-flowing solution (302) adjacent an aqueous liquid in a first acid or base generation zone, said first ion source and first zone being separated by a first barrier portion (306a) substantially preventing liquid flow through the first barrier portion and transporting ions only of the same charge as said first ions, (b) a source of second ions of opposite charge to said first ions in a substantially non-flowing solution (302) adjacent an aqueous liquid in a second acid or base generation zone, said second ion source and second zone being separated by a second barrier portion (306b) substantially preventing liquid flow through the second barrier portion and transporting ions only of the same charge as said second ions, said second barrier portion being of opposite charge to said first barrier portion, to form a salt-containing solution therein suitable for use as an eluent for liquid chromatography, and (c) a first electrode (312) in electrical communication with said first zone and a second electrode (314) in electrical communication with said second zone, said first and second electrodes being disposed so that, when attached to a power source, current passes between said first and second electrodes through said first and second zones.
AT07017726T 2002-09-11 2003-09-09 GENERATOR FOR ELECTRICALLY CONDUCTIVE ELUENTS AND ASSOCIATED METHOD OF USE ATE488294T1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/241,361 US7402283B2 (en) 2002-09-11 2002-09-11 Electrolytic eluent generator and method of use

Publications (1)

Publication Number Publication Date
ATE488294T1 true ATE488294T1 (en) 2010-12-15

Family

ID=31991181

Family Applications (2)

Application Number Title Priority Date Filing Date
AT07017726T ATE488294T1 (en) 2002-09-11 2003-09-09 GENERATOR FOR ELECTRICALLY CONDUCTIVE ELUENTS AND ASSOCIATED METHOD OF USE
AT03752251T ATE382419T1 (en) 2002-09-11 2003-09-09 ELECTROLYTIC GENERATOR FOR PRODUCING ELUTING AGENT AND USE THEREOF

Family Applications After (1)

Application Number Title Priority Date Filing Date
AT03752251T ATE382419T1 (en) 2002-09-11 2003-09-09 ELECTROLYTIC GENERATOR FOR PRODUCING ELUTING AGENT AND USE THEREOF

Country Status (11)

Country Link
US (3) US7402283B2 (en)
EP (3) EP1867384B1 (en)
JP (1) JP4446350B2 (en)
KR (1) KR101127317B1 (en)
CN (1) CN1703269A (en)
AT (2) ATE488294T1 (en)
AU (1) AU2003270551B2 (en)
CA (1) CA2498217C (en)
DE (2) DE60335051D1 (en)
HK (2) HK1108402A1 (en)
WO (1) WO2004024302A1 (en)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7288176B2 (en) * 2003-04-23 2007-10-30 Dionex Corporation Method and apparatus for generating high purity eluant
US8216515B2 (en) 2004-09-16 2012-07-10 Dionex Corporation Capillary ion chromatography
US7329346B2 (en) * 2005-02-23 2008-02-12 Dionex Corporation Ion chromatography system using catalytic gas elimination
US7473354B2 (en) * 2005-09-16 2009-01-06 Dionex Corporation Recycled suppressor regenerants
US7618826B2 (en) 2006-09-19 2009-11-17 Dionex Corporation Membrane suppressor with an outlet substantially non-retentive for ionic species
HUP0700669A2 (en) * 2007-10-12 2010-04-28 Ivan Dr Raisz Process for preparation of drinking water by an electrochemical method using ionselective membrane, without using any chemical
US7632404B2 (en) * 2007-11-15 2009-12-15 Dionex Corporation Barrier with a seated ion exchange bead and method
US8475639B2 (en) 2007-12-06 2013-07-02 Dionex Corporation Titration device and method
US8808931B2 (en) * 2008-01-09 2014-08-19 Dow Global Technologies Llc Ion exchange filter for fuel cell system
US8597571B2 (en) 2008-01-28 2013-12-03 Dionex Corporation Electrolytic eluent recycle device, apparatus and method of use
US8133373B2 (en) 2008-08-15 2012-03-13 Dionex Corporation Electrochemically driven pump
JP4968812B2 (en) * 2010-04-21 2012-07-04 日理工業株式会社 High purity electrolyte solution generator
JP5019663B2 (en) * 2010-09-22 2012-09-05 日理工業株式会社 Impurity ion remover
JP5576774B2 (en) * 2010-11-13 2014-08-20 日理工業株式会社 Ion chromatograph
EP2814597A4 (en) * 2012-02-15 2015-10-28 Bio Rad Laboratories Electronic control of ph and ionic strength
US9486799B2 (en) 2012-09-11 2016-11-08 Dionex Corporation Glycidol functionalized anion exchange stationary phases
US9086426B2 (en) * 2012-09-12 2015-07-21 Dionex Corporation Multi-component eluent generating system and method
US9309601B2 (en) 2012-10-16 2016-04-12 GenEon Technologies LLC Electrochemical activation of water
US10048233B2 (en) * 2012-11-12 2018-08-14 Dionex Corporation Suppressor device
EP2745904B1 (en) 2012-12-21 2015-12-16 Dionex Corporation HILIC/Anion-Exchange/Cation-Exchange Multimodal Media
US9310344B2 (en) 2013-06-14 2016-04-12 Dionex Corporation HILIC/anion-exchange/cation-exchange multimodal media
US9169331B2 (en) 2012-12-21 2015-10-27 Dionex Corporation Separation of glycans by mixed-mode liquid chromatography
US9216403B2 (en) 2013-03-15 2015-12-22 Dionex Corporation Epoxy chemistry derived materials as reversed-phase and hydrophobic interaction chromatography media, method for their synthesis and use
US9329158B2 (en) 2013-03-15 2016-05-03 Dionex Corporation Epoxy chemistry derived materials as mixed mode chromatography media, method for their synthesis and use
US9625430B2 (en) 2013-10-18 2017-04-18 Dionex Corporation Multielectrode electrolytic device and method
US11090606B2 (en) 2013-12-05 2021-08-17 Dionex Corporation Gas-less electrolytic device and method
US9931585B2 (en) 2014-04-23 2018-04-03 Dionex Corporation Electrolytic device for contaminant removal and method
WO2016028336A1 (en) * 2014-08-21 2016-02-25 Riviello John M Chambered ion reflux system for ion chromatography, apparatus and method of use
US11287403B2 (en) * 2016-01-07 2022-03-29 Board Of Regents, The University Of Texas System Ion chromatography system and methods utilizing a weak acid or weak base extraction device
US10228355B2 (en) 2016-05-06 2019-03-12 Board Of Regents, The University Of Texas System Volatile eluent preparation
CN106248863A (en) * 2016-10-31 2016-12-21 青岛鲁海光电科技有限公司 A kind of leacheate generating means in ion chromatography system
US10948466B2 (en) * 2017-03-03 2021-03-16 Dionex Corporation Flow control in an electrolytic reagent concentrator for ion chromatography
US11105782B2 (en) 2017-10-10 2021-08-31 Dionex Corporation Fast startup ion chromatography system and methods
CN109763136B (en) * 2019-02-02 2024-07-26 北京历元仪器有限公司 Acid-base generating device without degassing
KR102121732B1 (en) * 2019-10-11 2020-06-12 (주) 에이스엔 (Electrolytic eluent modification device for suppressed ion chromatography and ion chromatography system with the same
CN111549354A (en) * 2020-02-14 2020-08-18 北京历元仪器有限公司 Acid-base generating device without degassing
US11598014B2 (en) * 2020-10-02 2023-03-07 Dionex Corporation Electrolytic remote ion source and ion recycle (ISIR) module
CN112782334A (en) * 2020-12-24 2021-05-11 苏州明昊色谱技术有限公司 Ion chromatography carbonate leacheate concentration ratio adjusting device and method
CN115436559A (en) * 2022-09-28 2022-12-06 中国核动力研究设计院 Electrolytic anti-blocking leacheate generating device
CN115808496A (en) * 2022-12-28 2023-03-17 浙江西热利华智能传感技术有限公司 Eluent generation system and method based on anion chromatographic analysis

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US5045204A (en) * 1990-02-13 1991-09-03 Dionex Corporation Method and apparatus for generating a high purity chromatography eluent
US5350360A (en) 1990-03-01 1994-09-27 Michigan Transtech Corporation Implantable access devices
US5132094A (en) * 1990-03-02 1992-07-21 Sievers Instruments, Inc. Method and apparatus for the determination of dissolved carbon in water
US5248426A (en) * 1992-02-10 1993-09-28 Dionex Corporation Ion chromatography system using electrochemical suppression and detector effluent recycle
GB2274409A (en) 1993-01-22 1994-07-27 Aligena Ag Thin film mosaic composite membranes
US5567293A (en) * 1994-12-22 1996-10-22 Pulp And Paper Research Institute Of Canada Electromembrane processes for the treatment of kraft mill electrostatic precipitator catch
US6036921A (en) * 1997-01-15 2000-03-14 Dionex Corporation Acid or base generator with chromatograph
US6294066B1 (en) * 1997-01-23 2001-09-25 Archer Daniels Midland Company Apparatus and process for electrodialysis of salts
US5961796A (en) * 1997-06-03 1999-10-05 Lynntech, Inc. Bipolar membranes with fluid distribution passages
US6027643A (en) * 1997-09-04 2000-02-22 Dionex Corporation Ion chromatographic method and apparatus using a combined suppressor and eluent generator
US6225129B1 (en) * 1998-02-02 2001-05-01 Dionex Corporation Large capacity acid or base generation apparatus and method of use
JP3453067B2 (en) 1998-02-25 2003-10-06 大日精化工業株式会社 Charged mosaic film, method of using charged mosaic film, and apparatus provided with charged mosaic film
US6325976B1 (en) * 1998-02-26 2001-12-04 Dionex Corporation Continuous electrolytically regenerated packed bed suppressor for ion chromatography
US6720190B1 (en) * 1998-03-27 2004-04-13 Ole Hindsgaul Methods for screening compound libraries
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Also Published As

Publication number Publication date
US20040048389A1 (en) 2004-03-11
US8647576B2 (en) 2014-02-11
WO2004024302A1 (en) 2004-03-25
ATE382419T1 (en) 2008-01-15
AU2003270551B2 (en) 2009-02-05
DE60318455D1 (en) 2008-02-14
US7767462B2 (en) 2010-08-03
HK1076267A1 (en) 2006-01-13
JP2005538382A (en) 2005-12-15
EP2286899B1 (en) 2014-03-05
WO2004024302A8 (en) 2004-07-08
CA2498217A1 (en) 2004-03-25
EP1536879B1 (en) 2008-01-02
JP4446350B2 (en) 2010-04-07
US20060211125A1 (en) 2006-09-21
US7402283B2 (en) 2008-07-22
KR20050042815A (en) 2005-05-10
HK1108402A1 (en) 2008-05-09
DE60335051D1 (en) 2010-12-30
CA2498217C (en) 2013-11-05
AU2003270551A1 (en) 2004-04-30
US20100307919A1 (en) 2010-12-09
DE60318455T2 (en) 2008-12-18
EP1536879A1 (en) 2005-06-08
KR101127317B1 (en) 2012-03-30
CN1703269A (en) 2005-11-30
EP1867384A1 (en) 2007-12-19
EP1867384B1 (en) 2010-11-17
EP2286899A1 (en) 2011-02-23

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Legal Events

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