OA16299A - Water-based pesticidal suspension. - Google Patents
Water-based pesticidal suspension. Download PDFInfo
- Publication number
- OA16299A OA16299A OA1201300012 OA16299A OA 16299 A OA16299 A OA 16299A OA 1201300012 OA1201300012 OA 1201300012 OA 16299 A OA16299 A OA 16299A
- Authority
- OA
- OAPI
- Prior art keywords
- water
- weight
- tradename
- suspension
- based pesticidal
- Prior art date
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- 239000000725 suspension Substances 0.000 title claims abstract description 136
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 230000000361 pesticidal Effects 0.000 title claims abstract description 72
- 239000004094 surface-active agent Substances 0.000 claims abstract description 36
- 239000003905 agrochemical Substances 0.000 claims abstract description 34
- 239000002245 particle Substances 0.000 claims abstract description 30
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims abstract description 20
- 229920005646 polycarboxylate Polymers 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims description 48
- -1 alkyl sulfosuccinate Chemical compound 0.000 claims description 36
- 239000002518 antifoaming agent Substances 0.000 claims description 32
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 claims description 23
- 239000005900 Flonicamid Substances 0.000 claims description 22
- 229920001732 Lignosulfonate Polymers 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 230000000749 insecticidal Effects 0.000 claims description 9
- 230000000855 fungicidal Effects 0.000 claims description 8
- 239000005923 Pirimicarb Substances 0.000 claims description 7
- YFGYUFNIOHWBOB-UHFFFAOYSA-N Pirimicarb Chemical compound CN(C)C(=O)OC1=NC(N(C)C)=NC(C)=C1C YFGYUFNIOHWBOB-UHFFFAOYSA-N 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- 230000000996 additive Effects 0.000 claims description 5
- GHNRTXCRBJQVGN-UHFFFAOYSA-N 4-dodecan-6-ylbenzenesulfonic acid Chemical compound CCCCCCC(CCCCC)C1=CC=C(S(O)(=O)=O)C=C1 GHNRTXCRBJQVGN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003002 pH adjusting agent Substances 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 230000000087 stabilizing Effects 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 38
- 238000001238 wet grinding Methods 0.000 description 19
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 17
- DMSMPAJRVJJAGA-UHFFFAOYSA-N Benzisothiazolinone Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 16
- 239000000126 substance Substances 0.000 description 13
- 239000011362 coarse particle Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- QBSJMKIUCUGGNG-UHFFFAOYSA-N isoprocarb Chemical compound CNC(=O)OC1=CC=CC=C1C(C)C QBSJMKIUCUGGNG-UHFFFAOYSA-N 0.000 description 11
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-Dichlorophenoxyacetic acid Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 9
- 239000005660 Abamectin Substances 0.000 description 7
- JARYYMUOCXVXNK-IMTORBKUSA-N Validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 229910052700 potassium Inorganic materials 0.000 description 7
- 229950008167 Abamectin Drugs 0.000 description 6
- DIRFUJHNVNOBMY-UHFFFAOYSA-N Fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N Maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 6
- 239000005941 Thiamethoxam Substances 0.000 description 6
- NWWZPOKUUAIXIW-FLIBITNWSA-N Thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 description 6
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 6
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 description 6
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2R)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- DVBUIBGJRQBEDP-UHFFFAOYSA-N Cyantraniliprole Chemical compound CNC(=O)C1=CC(C#N)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl DVBUIBGJRQBEDP-UHFFFAOYSA-N 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 229920005552 sodium lignosulfonate Polymers 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 101700000038 mpas Proteins 0.000 description 4
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 4
- COMKTHXSKXDSHR-UHFFFAOYSA-N 5-bromo-N-[4-chloro-2-(1-cyclopropylethylcarbamoyl)-6-methylphenyl]-2-(3-chloropyridin-2-yl)pyrazole-3-carboxamide Chemical compound C1CC1C(C)NC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl COMKTHXSKXDSHR-UHFFFAOYSA-N 0.000 description 3
- NRTLIYOWLVMQBO-UHFFFAOYSA-N 5-chloro-1,3-dimethyl-N-(1,1,3-trimethyl-1,3-dihydro-2-benzofuran-4-yl)pyrazole-4-carboxamide Chemical compound C=12C(C)OC(C)(C)C2=CC=CC=1NC(=O)C=1C(C)=NN(C)C=1Cl NRTLIYOWLVMQBO-UHFFFAOYSA-N 0.000 description 3
- YASYVMFAVPKPKE-UHFFFAOYSA-N Acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 3
- 239000005875 Acetamiprid Substances 0.000 description 3
- WCXDHFDTOYPNIE-RIYZIHGNSA-N Acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 3
- 229940064005 Antibiotic throat preparations Drugs 0.000 description 3
- 229940083879 Antibiotics FOR TREATMENT OF HEMORRHOIDS AND ANAL FISSURES FOR TOPICAL USE Drugs 0.000 description 3
- 229940042052 Antibiotics for systemic use Drugs 0.000 description 3
- 229940042786 Antitubercular Antibiotics Drugs 0.000 description 3
- 239000005886 Chlorantraniliprole Substances 0.000 description 3
- SBPBAQFWLVIOKP-UHFFFAOYSA-N Chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 3
- 239000005944 Chlorpyrifos Substances 0.000 description 3
- 239000005888 Clothianidin Substances 0.000 description 3
- PGOOBECODWQEAB-UHFFFAOYSA-N Clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 description 3
- KAATUXNTWXVJKI-UHFFFAOYSA-N Cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 3
- OWZREIFADZCYQD-NSHGMRRFSA-N Deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 3
- CXEGAUYXQAKHKJ-FYOMLGFFSA-N Emamectin Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@H](C)[C@@H](NC)[C@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-FYOMLGFFSA-N 0.000 description 3
- YREQHYQNNWYQCJ-UHFFFAOYSA-N Etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 3
- 239000005786 Flutolanil Substances 0.000 description 3
- 229940093922 Gynecological Antibiotics Drugs 0.000 description 3
- 239000005906 Imidacloprid Substances 0.000 description 3
- YWTYJOPNNQFBPC-UHFFFAOYSA-N Imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 3
- 239000005914 Metaflumizone Substances 0.000 description 3
- MIFOMMKAVSCNKQ-HWIUFGAZSA-N Metaflumizone Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)N\N=C(C=1C=C(C=CC=1)C(F)(F)F)\CC1=CC=C(C#N)C=C1 MIFOMMKAVSCNKQ-HWIUFGAZSA-N 0.000 description 3
- 239000005917 Methoxyfenozide Substances 0.000 description 3
- KRTSDMXIXPKRQR-AATRIKPKSA-N Monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 3
- 239000005814 Pencycuron Substances 0.000 description 3
- OGYFATSSENRIKG-UHFFFAOYSA-N Pencycuron Chemical compound C1=CC(Cl)=CC=C1CN(C(=O)NC=1C=CC=CC=1)C1CCCC1 OGYFATSSENRIKG-UHFFFAOYSA-N 0.000 description 3
- HPYNBECUCCGGPA-UHFFFAOYSA-N Silafluofen Chemical compound C1=CC(OCC)=CC=C1[Si](C)(C)CCCC1=CC=C(F)C(OC=2C=CC=CC=2)=C1 HPYNBECUCCGGPA-UHFFFAOYSA-N 0.000 description 3
- 239000005929 Spinetoram Substances 0.000 description 3
- GOENIMGKWNZVDA-OAMCMWGQSA-N Spinetoram Chemical compound CO[C@@H]1[C@H](OCC)[C@@H](OC)[C@H](C)O[C@H]1OC1C[C@H]2[C@@H]3C=C4C(=O)[C@H](C)[C@@H](O[C@@H]5O[C@H](C)[C@H](CC5)N(C)C)CCC[C@H](CC)OC(=O)CC4[C@@H]3CC[C@@H]2C1 GOENIMGKWNZVDA-OAMCMWGQSA-N 0.000 description 3
- 239000005930 Spinosad Substances 0.000 description 3
- 229940024982 Topical Antifungal Antibiotics Drugs 0.000 description 3
- DQJCHOQLCLEDLL-UHFFFAOYSA-O Tricyclazole Chemical compound CC1=CC=CC2=C1N1C=N[NH+]=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-O 0.000 description 3
- JFLRKDZMHNBDQS-GQHNJWLYSA-N XPA88EAP6V Chemical compound C([C@@H](OC(=O)C[C@H]1[C@@H]2C=C[C@@H]3C[C@H](C[C@H]3[C@@H]2C=C1C(=O)[C@@H]1C)O[C@H]2[C@@H]([C@H](OC)[C@@H](OC)[C@H](C)O2)OC)CC)CCC1O[C@H]1CC[C@H](N(C)C)[C@@H](C)O1.C([C@@H](OC(=O)C[C@H]1[C@@H]2C=C(C)[C@@H]3C[C@H](C[C@H]3[C@@H]2C=C1C(=O)[C@@H]1C)O[C@H]2[C@@H]([C@H](OC)[C@@H](OC)[C@H](C)O2)OC)CC)CCC1O[C@H]1CC[C@H](N(C)C)[C@@H](C)O1 JFLRKDZMHNBDQS-GQHNJWLYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- FYZBOYWSHKHDMT-UHFFFAOYSA-N benfuracarb Chemical compound CCOC(=O)CCN(C(C)C)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 FYZBOYWSHKHDMT-UHFFFAOYSA-N 0.000 description 3
- 230000003115 biocidal Effects 0.000 description 3
- 229920005551 calcium lignosulfonate Polymers 0.000 description 3
- 229960002483 decamethrin Drugs 0.000 description 3
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 3
- 229940056881 imidacloprid Drugs 0.000 description 3
- 229940079866 intestinal antibiotics Drugs 0.000 description 3
- WLPCAERCXQSYLQ-UHFFFAOYSA-N isotianil Chemical compound ClC1=NSC(C(=O)NC=2C(=CC=CC=2)C#N)=C1Cl WLPCAERCXQSYLQ-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical compound COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 description 3
- 229940005935 ophthalmologic Antibiotics Drugs 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 description 3
- 150000003222 pyridines Chemical class 0.000 description 3
- XRJLAOUDSILTFT-UHFFFAOYSA-N pyroquilon Chemical compound O=C1CCC2=CC=CC3=C2N1CC3 XRJLAOUDSILTFT-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 229940014213 spinosad Drugs 0.000 description 3
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N γ-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 3
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 2
- RLLPVAHGXHCWKJ-HKUYNNGSSA-N (3-phenoxyphenyl)methyl (1R,3R)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-HKUYNNGSSA-N 0.000 description 2
- OXLXSOPFNVKUMU-UHFFFAOYSA-N 1,4-dioctoxy-1,4-dioxobutane-2-sulfonic acid Chemical compound CCCCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCCCC OXLXSOPFNVKUMU-UHFFFAOYSA-N 0.000 description 2
- XTDZGXBTXBEZDN-UHFFFAOYSA-N 3-(difluoromethyl)-N-(9-isopropyl-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl)-1-methylpyrazole-4-carboxamide Chemical compound CC(C)C1C2CCC1C1=C2C=CC=C1NC(=O)C1=CN(C)N=C1C(F)F XTDZGXBTXBEZDN-UHFFFAOYSA-N 0.000 description 2
- NMWKWBPNKPGATC-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2-benzofuran-1(3H)-one Chemical compound ClC1=C(Cl)C(Cl)=C2COC(=O)C2=C1Cl NMWKWBPNKPGATC-UHFFFAOYSA-N 0.000 description 2
- RAMUASXTSSXCMB-UHFFFAOYSA-N 5-bromo-N-[2-bromo-4-chloro-6-(1-cyclopropylethylcarbamoyl)phenyl]-2-(3-chloropyridin-2-yl)pyrazole-3-carboxamide Chemical compound C1CC1C(C)NC(=O)C1=CC(Cl)=CC(Br)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl RAMUASXTSSXCMB-UHFFFAOYSA-N 0.000 description 2
- VSLAFHRCBUGOBV-UHFFFAOYSA-N 5-bromo-N-[2-bromo-4-chloro-6-(cyclopropylmethylcarbamoyl)phenyl]-2-(3-chloropyridin-2-yl)pyrazole-3-carboxamide Chemical compound C1CC1CNC(=O)C1=CC(Cl)=CC(Br)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl VSLAFHRCBUGOBV-UHFFFAOYSA-N 0.000 description 2
- 239000005730 Azoxystrobin Substances 0.000 description 2
- WFDXOXNFNRHQEC-GHRIWEEISA-N Azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 description 2
- 239000005740 Boscalid Substances 0.000 description 2
- DUEPRVBVGDRKAG-UHFFFAOYSA-N Carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 2
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N Carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 2
- 239000005887 Chromafenozide Substances 0.000 description 2
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper(II) hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 2
- 239000005889 Cyantraniliprole Substances 0.000 description 2
- 239000005946 Cypermethrin Substances 0.000 description 2
- QAYICIQNSGETAS-UHFFFAOYSA-N Dazomet Chemical compound CN1CSC(=S)N(C)C1 QAYICIQNSGETAS-UHFFFAOYSA-N 0.000 description 2
- 239000005644 Dazomet Substances 0.000 description 2
- 239000005892 Deltamethrin Substances 0.000 description 2
- YKBZOVFACRVRJN-UHFFFAOYSA-N Dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 description 2
- HEZNVIYQEUHLNI-UHFFFAOYSA-N Ethiofencarb Chemical compound CCSCC1=CC=CC=C1OC(=O)NC HEZNVIYQEUHLNI-UHFFFAOYSA-N 0.000 description 2
- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 description 2
- 239000005899 Fipronil Substances 0.000 description 2
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N Fipronil Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 2
- 239000005901 Flubendiamide Substances 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
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- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical compound CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000005936 tau-Fluvalinate Substances 0.000 description 1
- LWLJEQHTPVPKSJ-UHFFFAOYSA-N tebufloquin Chemical compound C1=C(C(C)(C)C)C=C2C(OC(=O)C)=C(C)C(C)=NC2=C1F LWLJEQHTPVPKSJ-UHFFFAOYSA-N 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- SWLVFNYSXGMGBS-JBISRTOLSA-N tetradeuterioazanium;bromide Chemical compound [Br-].[2H][N+]([2H])([2H])[2H] SWLVFNYSXGMGBS-JBISRTOLSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- 239000004308 thiabendazole Substances 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- 150000003548 thiazolidines Chemical class 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- OPASCBHCTNRLRM-UHFFFAOYSA-N thiometon Chemical compound CCSCCSP(=S)(OC)OC OPASCBHCTNRLRM-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical compound COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- 238000004642 transportation engineering Methods 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- NKNFWVNSBIXGLL-UHFFFAOYSA-N triazamate Chemical compound CCOC(=O)CSC1=NC(C(C)(C)C)=NN1C(=O)N(C)C NKNFWVNSBIXGLL-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 description 1
- LESVOLZBIFDZGS-UHFFFAOYSA-N vamidothion Chemical compound CNC(=O)C(C)SCCSP(=O)(OC)OC LESVOLZBIFDZGS-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
- 239000005943 zeta-Cypermethrin Substances 0.000 description 1
- CHNQZRKUZPNOOH-UHFFFAOYSA-J zinc;manganese(2+);N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Zn+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S CHNQZRKUZPNOOH-UHFFFAOYSA-J 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N κ-bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- INISTDXBRIBGOC-XMMISQBUSA-N τ-fluvalinate Chemical compound N([C@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-XMMISQBUSA-N 0.000 description 1
Abstract
There has been a problem such that if a water-based pesticidal suspension containing, as an active ingredient, an agricultural chemical having a high aqueous solubility, particularly an agricultural chemical having an aqueous solubility exceeding 500 mg/L at 20°C, is stored for a long period of time, the active ingredient particles tend to grow and become coarse, whereby a stabilized suspension is hardly obtainable. To solve such a problem, the present invention provides a water-based pesticidal suspension comprising (a) an agricultural chemical or its salt having an aqueous solubility of from 500 mg/L to 6,000 mg/L at 20°C, (b) a polycarboxylate type surfactant, (c) a sulfonate type surfactant, and (d) water.
Description
DESCRIPTION
TITLE OF INVENTION: WATER-BASED PESTICIDAL SUSPENSION
TECHNICAL FIELD
The présent invention relates to a water-based pesticidal suspension containing, as an active ingrédient, an agricultural chemical having a high aqueous solubility, particularly an agricultural chemical having an aqueous solubility of from 500 mg/L to 6,000 mg/L at 20°C.
BACKGROUNDART
A compound having a high aqueous solubility, generally a compound having an aqueous solubility exceeding 100 mg/L at 20°C, is considered to be hardly formulated into a water-based suspension. Especially when a compound having an aqueous solubility exceeding 500 mg/L at 20°C is employed, a problem is likely to be resuit with respect to the physicochemical aspect of the formulation in many cases. For example, N-cyanomethyl-4-(trifluoromethyl)nicotinamide (common name: flonîcamid) is a compound disclosed as Compound No. 1 in Patent Document 1, and its aqueous solubility at 20°C is 5,200 mg/L, but in Patent Document 1, no Example is given to formulate flonîcamid into a water-based suspension formulation.
Patent Document 2 discloses a pesticidal composition comprising a pyridine type compound and another pesticide, and in its Formulation Example 5, a water-based suspension containing flonîcamid is disclosed. However, a water-based pesticidal suspension which employs spécifie surfactants as in the présent invention and which exhibits an excellent physicochemical performance, is not disclosed.
PRIOR ART DOCUMENTS
PATENT DOCUMENTS
Patent Document 1: EP-580374 B
Patent Document 2: W02002/034050
DISCLOSURE OF INVENTION
TECHNICAL PROBLEM
If a water-based pesticidal suspension containing, as an active ingrédient, an agrîcultural chemical having a high aqueous solubility is stored for a long period of time, the dissolved active ingrédient undergoes crystallization with suspended particles serving as nuclei, whereby the particles will grow and become coarse, and a stably suspended composition is hardly obtaînable. From such a problem in e.g. stability, it is not proper to select water as a dispersant at the time of formulating an agrîcultural chemical having a high aqueous solubility into a formulation. Further, the growth and coarsening of the active ingrédient particles are also influential over détérioration of the pesticidal effects. However, a pesticide formulation using water as a dispersant is very advantageous as it is less susceptible to restrictions in the production, transportation, storage or use from the viewpoint of e.g. the flame point, in handling, as compared with one using an organic solvent as a dispersant. Accordingly, a waterbased pesticidal suspension has been desired whereby the growth and coarsening of the active ingrédient particles are suppressed while using water as a dispersant.
SOLUTION TO PROBLEM
The présent inventors hâve conducted a research to solve the above problem and as a resuit, hâve found that by dispersing an agrîcultural chemical having a high aqueous solubility, particularly agrîcultural chemical particles having an aqueous solubility of at least 500 mg/L at 20°C, in an aqueous medium containing a polycarboxylate type surfactant and a sulfonate type surfactant, a stable water-based pesticidal suspension free from the growth and coarsening ofthe active ingrédient particles, can be obtained. The présent invention has been accomplished on the basis of this discovery. That is, the présent invention relates to a water-based pesticidal suspension comprising an agrîcultural chemical having a high aqueous solubility, particularly an agrîcultural chemical having an aqueous solubility of at least 500 mg/L at 20°C, a polycarboxylate type surfactant, a sulfonate type surfactant and water. Particularly, the présent invention relates to a water-based pesticidal suspension comprising (a) an agrîcultural chemical or its sait having an aqueous solubility of from 500 mg/L to 6,000 mg/L at 20°C, (b) a polycarboxylate type surfactant, (c) a sulfonate type surfactant, and (d) water.
ADVANTAGEOUS EFFECT OF INVENTION
According to the présent invention, it is possible to prevent the growth and coarsening ofthe active ingrédient particles in the water-based pesticidal suspension during its storage. Accordingly, the water-based pesticidal suspension ofthe présent invention is expected to provide an excellent physicochemical performance and a high pesticidal effect which is stable over a long period of time.
DESCRIPTION OF EMBODIMENTS
In the water-based pesticidal suspension ofthe présent invention (hereinafter referred to simply as the suspension ofthe présent invention), as the agricultural chemical, an agricultural chemical having a high aqueous solubility, particularly an agricultural chemical having an aqueous solubility of from 500 mg/L to 6,000 mg/L at 20°C, is employed, and more preferably, an agricultural chemical having an aqueous solubility of from 3,000 mg/L to 6,000 mg/L at 20°C is employed. Its spécifie examples include azamethiphos (aqueous solubility: 1100 mg/L (20°C)), dazomet (aqueous solubility: 3500 mg/L (20°C)), pyroquilon (aqueous solubility: 4000 mg/L (20°C))t pirimicarb (aqueous solubility: 3100 mg/L (20°C)), thiamethoxam (aqueous solubility: 4100 mg/L (25°C)), flonicamid (aqueous solubility: 5200 mg/L (20°C)), etc. Among them, preferred are pirimicarb, thiamethoxam and flonicamid, and more preferred is flonicamid.
The agricultural chemical in the suspension of the présent invention may form a sait together with an acidic substance or basic substance. As a sait with an acidic substance, an inorgantc acid sait such as a hydrochlorate, a hydrobromate, a phosphate, a sulfate or a nitrate may be mentioned, and as a sait with a basic substance, an inorganic or organic base sait such as a sodium sait, a potassium sait, a calcium sait, an ammonium sait or a dimethylamine sait may be mentioned.
The content of the agricultural chemical in the suspension of the présent invention is usually from 0.1 to 90 wt%, preferably from 1 to 60 wt%, more preferably from 5 to 45 wt%.
The polycarboxylate type surfactant may, for example, be polyacrylic acid, polymethacrylic acid, polymaleic acid, polymaleic anhydride, a copolymer of maleic acid or maleic anhydride with an olefin (such as isobutylene or diisobutylene), a copolymer of acrylic acid and îtaconic acid, a copolymer of methacrylic acid and itaconic acid, a copolymer of maleic acid or maleic anhydride with styrene, a copolymer of acrylic acid and methacrylic acid, a copolymer of acrylic acid and methyl acrylate, a il copolymer of acrylic acid and vinyl acetate, a copolymer of maleic acid or maleic anhydride with acrylic acid, an N-methyl-fatty acid (e.g. C0_i0) sarcosinate, a carboxylic acid such as a resin acid or a fatty acid (e.g. C8-ia), or a sait of such a carboxylic acid. Such a sait may, for example, be an alkali métal (such as sodium or potassium), an aîkaline earth métal (such as calcium or magnésium), ammonium or various amines (such as an alkylamine, a cycloalkylamine and an alkanolamîne). Further, a commercially available polycarboxylate may be used as it is, and for example, Geropon T/36 (sodium sait of maleic acid/olefin copolymer, tradename of Rhodia) may be mentioned.
The content of the polycarboxylate type surfactant in the suspension of the présent invention may be optionally changed depending upon the amount of the active ingrédient compound to be added. However, it is usually from 0.1 to 20 wt%, preferably from 0.1 to 10 wt%. The weight ratio in content of the active ingrédient to the polycarboxylate type surfactant is usually from 1:0,001 to 1:10, preferably from 1:0.005 to 1:2.
The sulfonate type surfactant may, for example, be a lignosulfonate, an alkyl sulfosuccinate, a Ca-i0 alkylbenzene sulfonate or a C0.10 alkyl diphenyl ether disulfonate. As such a sulfonate type surfactant, it is preferred to use a lignosulfonate, and it is particularly preferred to use a lignosulfonate and an alkyl sulfosuccinate.
The lignosulfonate may, for example, be calcium lignosulfonate, sodium lignosulfonate, potassium lignosulfonate, magnésium lignosulfonate or ammonium lignosulfonate. For example, New Kargen WG-4 (sodium lignosulfonate, manufactured by TAKEMOTO OIL & FAT Co., LTD.), New Kargen RX-B (sodium lignosulfonate, manufactured by TAKEMOTO OIL & FAT Co., LTD ), SANX P-252 (sodium lignosulfonate, manufactured by NIPPON PAPER CHEMICALS Co., LTD.), SANX C (calcium lignosulfonate, manufactured by NIPPON PAPER CHEMICALS Co., LTD.), SANX P201 (calcium lignosulfonate, manufactured by NIPPON PAPER CHEMICALS Co., LTD ), VANILLEX N (partially desulfonated sodium lignosulfonate, manufactured by NIPPON PAPER CHEMICALS Co., LTD.), or PEARLLEX NP (high molecular weight sodium lignosulfonate, manufactured by NIPPON PAPER CHEMICALS Co., LTD.), may, for example, be mentioned.
The alkyl sulfosuccinate may, for example, be a compound represented by the formula (I):
CH2COOR’
O3S---CHCOOR (D [wherein each of R’ and R” which are independent of each other, is a linear or branched C1.12 alkyl group; M is Na, Ca or K; when M is Na or K, p is 1; and when M is Ca, p is 2.] Among them, sodium dioctyl sulfosuccinate is preferred. Spécifie examples of the sodium dioctyl sulfosuccinate include AGNIQUE EHS70WE (manufactured by Cognis), LANKROPOL4500 (manufactured by LION AKZO Co., Ltd), New Kargen EP-70G (manufactured byTAKEMOTO OIL & FAT Co., LTD.), New Kargen EX-70 (manufactured byTAKEMOTO OIL & FAT Co., LTD.), etc.
The content of the sulfonate type surfactant in the suspension of the présent invention may suitably be changed depending upon the amount of the active ingrédient compound to be added, but it is usually from 0.1 to 30 wt%, preferably from 0.1 to 20 wt%. The weight ratio in content of the active ingrédient to the sulfonate type surfactant is usually from 1:0.001 to 1:20, preferably from 1:0.005 to 1:4. The weight ratio in content of the polycarboxylate type surfactant to the sulfonate type surfactant is usually from 1:0.01 to 1:200, preferably from 1:0.01 to 1:40.
In the suspension of the présent invention, water is employed as a dispersant.
In the suspension of the présent invention, water may be incorporated as the rest of the above-mentioned (a), (b), (c) and the after-mentioned other components to adjust so that the entirety becomes 100 wt%. The content of the water in the suspension of the présent invention is usually from 9.8 to 99.7 wt%, preferably from 20 to 98.8 wt%.
To the suspension of the présent invention, as other optional components, additives such as an antîfreezîng agent, a thickener, an antifoaming agent, an antiseptie agent, a dispersant, a wetting agent, a pH modifier, a stabilizer, etc. may suitably be added, as the case requires. As such additives, an antifreezing agent, a ?
thickener, an antifoaming agent, an antiseptie agent, etc. are preferred.
As the antifreezing agent, various ones may be mentioned, but a dihydric alcohol which is effective also as a viscosity lowering agent, is preferred. As the dihydric alcohol, an alkylene glycol such as ethylene glycol or propylene glycol may be mentioned, and it is particularly preferred to employ propylene glycol among them. The amount of the antifreezing agent to be used in the suspension of the présent invention is usually from 2 to 30 wt%, preferably from 5 to 10 wt%.
The thickener may, for example, be a natural polysaccharide such as xanthan gum, rhamsan gum, locust bean gum, carrageenan or welan gum; a synthetic polymer such as sodium polyacrylate; a semisynthetic polysaccharide such as carboxy methyl cellulose; a minerai fine powder such as aluminum magnésium silicate, smectite, bentonite, hectorite or fumed silica, or alumina sol. The amount of the thickener to be used in the suspension of the présent invention is usually from 0.01 to 5.0 wt%, preferably from 0.05 to 1.0 wt%.
As the antiseptie, various ones may be mentioned, but for example, Proxel GXL (tradename, Zeneca AG) may be used. The amount of the antiseptie to be used in the suspension of the présent invention is usually from 0.01 to 1.0 wt%, preferably from 0.05 to 0.2 wt%.
The antifoaming agent is added for the purpose of suppressing formation of bubbles at the time of producing ordiluting with waterthe suspension ofthe présent invention thereby to avoid a trouble during the production or préparation of a diluted suspension. As such an antifoaming agent, a silicone type antifoaming agent contaîning polydimethylsiloxane as an active ingrédient, may be mentioned. For example, Rhodorsil Antifoam 416 (tradename, Rhodia Nicca Ltd.), Rhodorsil Antifoam 481 (tradename, Rhodia Nîcca Ltd.), Rhodorsil Antifoam 432 tradename, Rhodia Nîcca Ltd.), KM 72 (tradename, Shin-Etsu Chemical Co., Ltd.), KM 75 (tradename, Shin-Etsu Chemical Co., Ltd.), or Anti-mousse (tradename, BELCHIM CROP PROTECTION) may be mentioned. Here, the silicone type antifoaming agent includes an antifoaming agent contaîning silica. The amount ofthe antifoaming agent to be used in the suspension of the présent invention is usually from 0.01 to 10 wt%, preferably from 0.1 to 1.0 wt%.
The suspension of the présent invention can be produced by a usual method for producing a water-based pesticidal suspension. For example, after mixing blend components, wet grinding is carried out to make active ingrédient particles fine. The slurry particles thereby obtainable are preferably fine, and the average particle sîze(volume) of the agricultural chemical of the above (a) is made to be a particle size of from 0.5 to 10 pm, more preferably from 1 to 3 pm, from the viewpoint of the suspension stability in a case where the finally obtainable water-based pesticidal suspension is formulated as a water diluted suspension. Here, the average particle size is one measured by a particle size analyzer Microtrac H RA (manufactured by NIKKISO Co., Ltd.).
At the time of formulating the suspension of the présent invention, as the method of wet grinding, bead mill or sand mill may, for example, be mentioned. As bead mill, DYNO-MILL may, for example, be mentioned.
The viscosity of the suspension of the présent invention is preferably from 100 to 1000 mPa-S, more preferably from 200 to 500 mPa-S. Here, the viscosity is one measured by a B type viscometer (rotational speed of rotor: 60 rpm (20°C)).
A method for application of the suspension of the présent invention is not particularly limited. However, usually, the suspension of the présent invention is prepared as described above, and then a water-dïluted liquid suitable for e.g. application by spraying is prepared, and it can be applied to soil, plants, etc. The method for preparing the water-diluted liquid is not particularly limited, and the suspension of the présent invention may be added to water in a suitable amount as a diluting liquid, followed by mixing by means of a suitable means. The degree of dilution is not particularly limited, and it is possible to détermine the concentration of the water-diluted liquid so that the pesticidal component will be in contact with soil, plants, etc. at a suitable concentration after the application.
The concentration of the suspension of the présent invention to be used cannot generally be defined, since it varies depending upon conditions such as the crop plants, the method of use, the type of the formulation, the amount to be applied, etc. However, in the case of foliar treatment, the concentration of the active ingrédient is usually from 1 to 50,000 ppm; in the case of water surface application, the concentration of the active ingrédient is usually from 50 to 50,000 ppm; and in the case of soil treatment, the concentration of the active ingrédient is usually from 1 to 1,000 ppm.
The suspension of the présent invention may be used as mixed with or in combination with other agricultural chemicals other than the agricultural chemical of the above (a), as the case requires, for example, an insecticide, a miticide, a nematicide, a soil pesticide, a fungicide, an antivirus agent, an attractant, a herbicide, a plant growth-regulating agent, etc. In such a case, a further superior effect may sometimes be obtainable. In such a case, at the time of preparing the suspension of the présent invention, the above (a), (b), (c) and (d), and such other agricultural chemicals may be mixed and formulated together, or they may be separately formulated so that they may be mixed for use at the time of application.
The active ingrédient compounds ofthe insecticide, the miticide, the nematicide or the soil insect pesticide, i.e. insecticidal compounds, in the above-mentioned other agricultural chemicals, include, for example, (by common names, some of them are still in an application stage, or test codes of Japan Plant Protection Association): organic phosphate compounds, such as profenofos, dichlorvos, fenamiphos, fenitrothion, EPN, diazinon, chlorpyrifos, chlorpyrifos-methyl, acephate, prothiofos, fosthiazate, cadusafos, disulfoton, isoxathion, isofenphos, ethion, etrimfos, quinalphos, dimethylvinphos, dimethoate, sulprofos, thiometon, vamidothion, pyraclofos, pyridaphenthion, pirimiphos-methyl, propaphos, phosalone, formothion, malathion, tetrachlorvinphos, chlorfenvinphos, cyanophos, trichlorfon, methidathion, phenthoate, ESP, azinphos-methyl, fenthion, heptenophos, methoxychlor, parathion, phosphocarb, demeton-S-methyl, monocrotophos, methamidôphos, imicyafos, parathion-methyl, terbufos, phosphamidon, phosmet, phorate, phoxim and triazophos;
carbamate compounds, such as carbaryl, propoxur, aldicarb, carbofuran, thiodicarb, methomyl, oxamyl, ethiofencarb, pirimicarb, fenobucarb, carbosulfan, benfuracarb, bendiocarb, furathiocarb, isoprocarb, metolcarb, xylylcarb, XMC and fenothiocarb;
nereistoxin dérivatives, such as cartap, thiocyclam, bensultap, thiosultap-sodium thiosultap-disodium, monosultap, bisultap and thiocyclam hydrogen oxalate;
organic chlorine compounds, such as dicofol, tetradifon, endosulfan, dienochlor and dieldrin;
organic métal compounds, such as fenbutatin oxide and cyhexatin;
pyrethroid compounds, such as fenvaierate, permethrin, cypermethrin, deltamethrin, cyhalothrin, tefluthrin, ethofenprox, flufenprox, cyfluthrin, fenpropathrin, flucythrinate, fluvalinate, cycloprothrin, lambda-cyhalothrin, pyrethrins, esfenvalerate, tetramethrin, resmethrin, protrifenbute, bifenthrîn, zeta-cypermethrin, acrinathrin, alpha-cypermethrin, allethrin, gamma-cyhalothrin, theta-cypermethrin, tau-fluvalinate, tralomethrin, profluthrin, beta-cypermethrin, beta-cyfluthrin, metofluthrin, phenothrin, flumethrin and decamethrin;
benzoylurea compounds, such as diflubenzuron, chlorfluazuron, teflubenzuron, flufenoxuron, lufenuron, novaluron, triflumuron, hexaflumuron, bistrifluron, noviflumuron and fluazuron;
juvénile hormone-like compounds, such as methoprene, pyriproxyfen, fenoxycarb and diofenolan;
pyridazinone compounds, such as pridaben;
pyrazole compounds, such as fenpyroxîmate, fîpronil, tebufenpyrad, ethiprole, tolfenpyrad, acetoprole, pyrafluprole and pyrtprole;
neonicotinoids, such as imidacloprid, nitenpyram, acetamiprid, thiacloprid, thiamethoxam, clothianidin, nidinotefuran, dînotefuran and nithiazine;
hydrazine compounds, such as tebufenozide, methoxyfenozide, chromafenozide and halofenozide;
pyridine compounds, such as pyridalyl and flonîcamid;
cyclic keto-enol compounds, such as spirodiclofen; spiromesifen and spirotetramat;
strobilurin compounds, such as fluacrypyrim;
pyrîmidinamine compounds, such as flufenerim;
dinitro compounds; organic sulfur compounds; urea compounds; triazine compounds; hydrazone compounds;
other compounds, such as buprofezîn, hexythiazox, amitraz, chlordimeform, silafluofen, triazamate, pymetrozîne, pyrimidifen, chlorfenapyr, indoxacarb, acequinocyl, etoxazole, cyromazine, 1,3-dichloropropene, diafenthiuron, benclothiaz, bifenazate, propargite, clofentezine, metaflumizone, flubendiamide, cyflumetofen, chlorantraniliprole, cyantraniliprole, cyenopyrafen, pyrifluquinazon, fenazaquin, amidoflumet, sulfluramid, hydramethylnon, metaldehyde, HGW-86, ryanodine, verbutin, 3-bromo-N-(2-bromo-4-chloro-6-(1-cyclopropylethylcarbamoyl)phenyl)-1-(3chloropyridin-2-yl)-1H-pyrazol-5-carboxamide, 3-bromo-N-(4-chloro-2-(1cyclopropylethylcarbamoyl)-6-methylphenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazol-5carboxamide, 3-bromo-N-(2-bromo-4-chloro-6-(cyclopropylmethylcarbamoyl)phenyl)-1(3-chloropyridin-2-yl)-1 H-pyrazol-5-carboxamide, 3-bromo-N-(4-chloro-2-methyl-6(methylcarbamoyl)phenyl)-1 -(3-chloropyridin-2-yl)-1 H-pyrazol-5-carboxamide and 3bromo-1-(3-chloropyridin-2-yl)-N-(4-cyano-2-methyl-6-(methylcarbamoyl)phenyl)-1Hpyrazol-5-carboxamide; and the like. Further, it may be used in combination with or together with microbial agricultural chemicals, such as insecticidal crystal proteins produced by Bacillus thuringiensis aizawai, Bacillus thuringiensis kurstaki, Bacillus thuringiensis israelensis, Bacillus thuringiensis japonensis, Bacillus thuringiensis tenebrionis or Bacillus thuringiensis, insect viruses, etomopathogenic fungi, and nematophagous fungi; antibiotics or semisynthetic antibiotics, such as avermectin, emamectin benzoate, milbemectin, milbemycin, spinosad, ivermectin, lepimectin, DE175, abamectin, emamectin and spinetoram; natural products, such as azadirachtin and rotenone; and repellents, such as deet.
The active ingrédient compounds of the fungicide, i.e. the fungicidal compounds, in the above-mentioned other agricultural chemicals include, for example, (by common names, some of them are still in an application stage, or test codes of Japan Plant Protection Association):
anilinopyrimidine compounds, such as mepanipyrim, pyrimethanil, cyprodinil and ferimzone;
triazoropyrimidine compounds, such as 5-chloro-7-(4-methylpiperidin-1-yl)-6(2,4,6-trifluorophenyl)[1,2,4]triazolo[1,5-a]pyrimidine; pyridinamine compounds, such as fluazinam;
azote compounds, such as triadimefon, bitertanol, triflumizole, etaconazole, propiconazole, penconazole, flusilazole, myclobutanil, cyproconazole, tebuconazole, hexaconazole, furconazole-cis, prochloraz, metconazole, epoxiconazole, tetraconazole, oxpoconazole fumarate, sipconazole, prothîoconazole, triadimenol, flutriafol, difenoconazole, fluquinconazole, fenbuconazole, bromuconazole, diniconazole, tricyclazole, probenazole, simeconazole, pefurazoate, ipconazole and imibenconazole;
quinoxaline compounds, such as quinomethionate;
dithiocarbamate compounds, such as maneb, zineb, mancozeb, polycarbamate, metiram, propineb and thiram;
organic chlorine compounds, such as fthalide, chlorothalonil and quintozene;
imidazole compounds, such as benomyl, cyazofamid, thiophanate-methyl, carbendazîm, thiabendazole and fuberiazole;
cyanoacetamide compounds, such as cymoxanil;
anilide compounds, such as metalaxyl, metalaxyl-M, mefenoxam, oxadixyl, ofurace, benalaxyl, benalaxyl-M (another name: kiralaxyl, chiralaxyl), furalaxyl, cyprofuram, carboxin, oxycarboxin, thifluzamide, boscalid, bîxafen, isotianil, tiadinil and sedaxane;
sulfamide compounds, such as dichlofluanid;
copper compounds, such as cupric hydroxide and oxine copper;
isoxazole compounds, such as hymexazol;
organophosphorus compounds, such as fosetyl-AI, tolclofos-methyl, S-benzyl 0,0-dîisopropylphosphorothioate, O-ethyl S,S-diphenylphosphorodithioate, aluminum ethylhydrogen phosphonate, edifenphos, and iprobenfos;
phthalimide compounds, such as captan, captafol and folpet;
dicarboximide compounds, such as procymidone, iprodione and vinclozolin; benzanilide compounds, such as flutolanil and mepronil;
amide compounds, such as penthiopyrad, mixture of 3-(difluoromethyl)-1-methylN [( 1 RS,4SR,9SR)-1,2,3,4-tetrahydro-9-isopropyl-1,4-methanonaphthalen-5yl]pyrazole-4-carboxamide and 3-(difluoromethyl)-1-methyl-N-[(1RS,4SR,9SR)-1,2,3,4tetrahydro-9-isopropyl-1,4-methanonaphthalen-5-yl]pyrazole-4-carboxamide (isopyrazam), silthiopham, fenoxanil and furametpyr;
benzamide compounds, such as fluopyram and zoxamide;
piperazine compounds, such as triforine;
pyridine compounds, such as pyrifenox;
carbinol compounds, such as fenarîmol;
piperidine compounds, such as fenpropidin;
morpholine compounds, such as fenpropimorph and tridemorph;
organotin compounds, such as fentin hydroxide and fentin acetate;
urea compounds, such as pencycuron;
cinnamic acid compounds, such as dimethomorph and flumorph; phenylcarbamate compounds, such as diethofencarb;
cyanopyrrole compounds, such as fludioxonil and fenpîclonil;
strobilurin compounds, such as azoxystrobin, kresoxim-methyl, metominostrobin, trifloxystrobîn, picoxystrobin, oryzastrobin, dimoxystrobin, pyraclostrobin, and fluoxastrobin;
oxazolidinone compounds, such as famoxadone;
thiazolecarboxamide compounds, such as ethaboxam;
valinamide compounds, such as iprovalicarb and benthiavalicarb-isopropyl;
acylamino acid compounds, such as methyl N-(isopropoxycarbonyl)-L-valyl(3RS)-3-(4-chlorophenyl)-p-alaninate (valiphenalate);
imidazolinone compounds, such as fenamidone; hydroxyanilide compounds, such as fenhexamid; benzenesulfonamide compounds, such as flusulfamide;
oxime ether compounds, such as cyflufenamid;
anthraquinone compounds;
crotonic compounds;
antibiotics, such as validamycin, kasugamycin and polyoxins;
guanidine compounds, such as iminoctadine and dodine;
quinoline compounds, such as 6-tert-butyl-8-fluoro-2,3-dimethylquino1in-
4-yl acetate (tebufloquin);
thiazolidine compounds, such as (z)-2-(2-fluoro-5-(trifluromethyl)phenylthio)-2-(3(2-methoxyphenyl)thiazolidin-2-yliden)acetonitrile (flutianil);
and other compounds, such as pyribencarb, isoprothîolane, pyroquilon, diclomezine, quinoxyfen, propamocarb hydrochloride, chloropicrin, dazomet, metamsodium, nicobifen, metrafenone, UBF-307, diclocymet, proquinazid, amisulbrom (another name: amibromdole), pyriofenone, mandipropamid, fluopicolide, carpropamid, meptyldinocap, N-[(3',4’-dichloro-1,1-dimethyl)phenacyl]-3-tnfluoromethy-2-pyndine carboxamide, N-[(3’,4’-dichloro-1r1-dimethyl)phenacyl]-3-methyl-2-thiophene carboxamide, N-[(3’,4'-dichloro-1,1-dimethyl)phenacyl]-1-methyl-3-trifluoromethy-4pyrazole carboxamide, N-[[2'-methyl-4’-(2-propyloxy)-1,1-dimethyl]phenacyl]-316299 trifluoromethy-2-pyridine carboxamide, N-[[2’-methyl-4'-(2-propyloxy)-1,1dimethyl]phenacyl]-3-methyl-2-thiophene carboxamide, N-[[2'-methyl-4'-(2-propyloxy)-
1,1-dimethyi]phenacyl]-1-methyl-3-trifluoromethy-4-pyrazole carboxamide, N-[[4'-(2propyloxy)-! ,1-dimethyl]phenacyl]-3-trifluoromethy-2-pyridine carboxamide, N-[(4’-(2 propyloxy)-1,1-dimethyl]phenacyl]’3-methyl-2-thiophene carboxamide, N-[[4'-(2propyloxy)-1,1-dimethyl]phenacyl]-1-methyl-3-trifluoromethy-4-pyrazole carboxamide, N-[[2’-methyl-4'-(2-pentyloxy)-1,1-dimethyl]phenacyl]-3-trifiuoromethy-2-pyridine carboxamide, N-[[4'-(2-pentyloxy)-1,1 -dimethyl]phenacyl]-3-trifluoromethy-2-pyridine carboxamide, spiroxamine, S-2188 (fenpyrazamine), S-2200, ZF-9646, BCF-051, BCM-061 and BCM-062.
Among these, preferred as active ingrédient compounds to be further incorporated to the suspension ofthe présent invention are the following compounds. These insecticidal compounds orfungicidal compounds are referred to as compounds of group X”.
That is, as the compounds of group X, abamectin, fenobucarb, isoprocarb, chlorfluazuron, chlorpyrifos, fipronil, clothianidin, spinetoram, spinosad, dinotefuran, methoxyfenozide, ethofenprox, ethiprole, acephate, benfuracarb, monocrotophos, silafluofen, imidacloprid, acetamiprid, thiamethoxam, chlorantraniliprole, cyantraniliprole, bensultap, cyhalothrin, cypermethrin, permethrin, deltamethrin, bifenthrin, lambda-cyhalothrin, thiacloprid, nitenpyram, buprofezin, pymetrozine, profenofos, chromafenozide, tebufenozide, thiocyclam, cartap, lepimectin, emamectin benzoate, pirimicarb, indoxacarb, carbofuran, carbosulfan, flufenoxuron, pyriproxyfen, flubendiamide, spirotetramat, novaluron, thiosultap-disodium, metaflumizone, 3-bromoN-(2-bromo-4-chloro-6-(1-cyclopropylethylcarbamoyl)phenyl)-1-(3-chloropyridin-2-yl)1 H-pyrazol-5-carboxamide, 3-bromo-N-(4-chloro-2-(1-cyclopropylethylcarbamoyl)-6methylphenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazol-5-carboxamide, 3-bromo-N-(2bromo-4-chloro-6-(cyclopropylmethylcarbamoÿl)phenyl)’1-(3-chloropyridin-2-y1)-1Hpyrazol-5-carboxamide, 3-bromo-N-(4-chloro-2-methyl-6-(methylcarbamoyl)phenyl)-1(3-chloropyridin-2-yl)-1H-pyrazol-5-carboxamide and 3-bromo-1-(3-chloropyridin-2-yl)N-(4-cyano-2-methyl-6-(methylcarbamoyl)phenyl)-1H-pyrazol-5-carboxamîde, validamycin, oryzastrobin, tricyclazole, isotianil, tiadinil, probenazole, flutolanil, pencycuron, isoprothiolane, thifluzamide, azoxystrobin, metominostrobin, ferimzone, fthalide, mepronil, diclomezine, pyroquilon and furametpyr may be mentioned.
Among the compounds of group X, further preferred are the following ones.
The insecticîdal compounds include abamectin, fenobucarb, isoprocarb, chlorfluazuron, chlorantraniliprole, cyantran il i proie, chlorpyrifos, fipronil, clothianidin, spinetoram, spinosad, dinotefuran, methoxyfenozide, ethofenprox, ethîprole, acephate, benfuracarb, monocrotophos, silafluofen, imidacloprid, acetamiprid, thiamethoxam, thiosultap-disodium, metaflumizone, 3-bromo-N-(2-bromo-4-chloro-6-(1cyclopropylethylcarbamoy[)phenyl)-1-(3-ch!oropyridin-2-yl)-1H-pyrazol-5-carboxamide,
3-bromo-N-(4-chloro-2-(1-cyclopropylethylcarbamoyl)-6-methylphenyl)-1-(3chloropyridin-2-yl)-1H-pyrazol-5-carboxamide, 3-bromo-N-(2-bromo-4-chloro-6(cyclopropylmethylcarbamoyl)phenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazol-5carboxamide, 3-bromo-N-(4-chloro-2-methyl-6-(methylcarbamoyl)phenyl)-1-(3chloropyridin-2-yl)-1H-pyrazol-5-carboxamîde and 3-bromo-1-(3-chloropyridin-2-yl)-N(4-cyano-2-methyl-6-(methylcarbamoyl)phenyl)-1H-pyrazol-5-carboxamide.
The fungicidal compounds include oryzastrobin, tricyclazole, isotianil, tiadinil, probenazole, flutolanil, pencycuron, furametpyr and validamycin.
Among them, particularly preferred are chlorfluazuron, abamectin, fenobucarb, isoprocarb and validamycin.
The amount of the active ingrédient compounds other than the agricultural compound of the above (a) to be used in the suspension of the présent invention is usually from 0.1 to 60 wt%, preferably from 1 to 60 wt%.
Now, some preferred embodiments ofthe suspension ofthe présent invention will be exemplified, but it should be understood that the présent invention is by no means thereby restricted.
(1) A water-based pesticidal suspension comprising (a) an agricultural chemical or its sait having an aqueous solubility of from 500 mg/L to 6,000 mg/L at 20°C, (b) a polycarboxylate type surfactant, (c) a sulfonate type surfactant, and (d) water.
(2) The water-based pesticidal suspension according to (1), wherein the agricultural chemical (a) is an agricultural chemical having an aqueous solubility of from 3,000 mg/L to 6,000 mg/L at 20°C.
(3) The water-based pesticidal suspension according to (1) or (2), wherein the agricultural chemical (a) is at Ieast one member selected from the group consisting of pirimicarb, thîamethoxam and flonicamid.
(4) The water-based pesticidal suspension according to (3), wherein the agricultural chemical (a) is flonicamid.
(5) The water-based pesticidal suspension according to (1), wherein the agricultural chemical (a) has an average particle size(volume) of from 0.5 pm to 10 pm.
(6) The water-based pesticidal suspension according to (1), wherein the polycarboxylate type surfactant (b) is a polycarboxylate.
(7) The water-based pesticidal suspension according to (1), wherein the sulfonate type surfactant (c) is at least one member selected from the group consisting of an alkyl sulfosuccinate, a lignosulfonate, a C8.18 alkyl benzene sulfonate and a Ce-w alkyl diphenyl ether disulfonate.
(8) The water-based pesticidal suspension according to (7), wherein the sulfonate type surfactant (c) is a lignosulfonate.
(9) The water-based pesticidal suspension according to (7), wherein the sulfonate type surfactant (c) is a lignosulfonate and an alkyl sulfosuccinate.
(10) The water-based pesticidal suspension according to (1), which contains an additive in addition to (a), (b), (c) and (d).
(11) The water-based pesticidal suspension according to (10), wherein the additive is at least one member selected from the group consisting of an antîfreezîng agent, a thickener, an antifoaming agent, an antiseptie agent, a pH modifier and a stabilizer.
(12) The water-based pesticidal suspension according to (10), wherein the additive is an antîfreezîng agent, a thickener and/or an antifoaming agent.
(13) The water-based pesticidal suspension according to (1), which further contains at least one agricultural chemical selected from the group consisting of an insecticidal compound and a fungicidal compound.
(14) The water-based pesticidal suspension according to (13), wherein said at least one member selected from the group consisting of an insecticidal compound and a fungicidal compound is the above-mentioned compounds of group X.
(15) The water-based pesticidal suspension according to (14), wherein said at least one compound selected from the group consisting of an insecticidal compound and a fungicidal compound is chlorfluazuron, abamectin, fenobucarb, isoprocarb and validamycin (16) A method which comprises stabilizing the suspension state of an agricultural chemical or its sait having an aqueous solubility of from 500 mg/L to 6,000 mg/L at 20“C in a water-based pesticidal suspension by means of (b) a polycarboxylate type surfactant and (c) a sulfonate type surfactant.
(17) A method which comprises stabilizing the suspension state of an agricultural chemical or its sait having an aqueous solubility of from 3,000 mg/L to 6,000 mg/L at 20°C in a water-based pesticidal suspension by means of (b) a polycarboxylate type surfactant and (c) a sulfonate type surfactant.
EXAMPLES
Now, Examples of the présent invention will be described, but it should be understood that the présent invention is by no means thereby restricted.
EXAMPLE 1 (1) (a) Flonicamid (purity: 97.5%) 41.0 parts by weight (2) (b) Polycarboxylate (tradename: Geropon T/36, manufactured by Rhodia) 3.0 parts by weight (3) (c) Lignosulfonate (tradename: SANX C, manufactured by NIPPON PAPER CHEMICALS Co:, LTD.) 5.0 parts by weight (4) (c) Alkyl sulfosuccinate (tradename: New Kargen EP-70G, manufactured by TAKEMOTO OIL & FAT Co., LTD.) 1.0 part by weight (5) Propylene glycol 7.0 parts by weight (6) Aluminum magnésium silicate (tradename: Veegum R, manufactured by Sanyo Chemical Industries, Ltd.) 0.2 part by weight (7) Silicone type antifoaming agent (tradename: Rhodorsil
Antifoam 432, manufactured by Rhodia Nicca Ltd.) 0.5 part by weight (8) (d) Water 42.3 parts by weight
The above (1) and (2) to (8) were mixed, followed by wet grinding by DYNO-MILL (manufactured by SHINMARU ENTERPRISES CORPORATION) to obtain a waterbased pesticidal suspension.
EXAMPLE 2 (1) (a) Flonicamid (purity: 97.5%) 27.4 parts by weight
(2) (b) | Geropon T/36 (tradename) | 1.8 parts by weight |
(3) (c) | SANX C (tradename) | 4.4 parts by weight |
(4) (c) | New Kargen EP-70G (tradename) | 0.9 part by weight |
(5) | Propylene glycol | 6.2 parts by weight |
(6) | Veegum R (tradename) | 0.4 part by weight |
(7) | Xanthan gum (tradename: Rhodopol 23, | |
manufactured by Rhodia) | 0.1 part by weight | |
¢8) | Rhodorsil Antifoam 432 (tradename) | 0.4 part by weight |
(9) | Proxel GXL (tradename, manufactured by |
Zeneca AG)
0.1 part by weight (10) (d) Water
58.3 parts by weight
The above (1) and (2) to (10) were mixed, followed by wet grinding by DYNOMILL (the same above) to obtain a water-based pesticidal suspension.
EXAMPLE 3
(1) (a) | Flonicamid (purity: 97.5%) | 19.0 parts by weight |
¢2) (b) | Geropon T/36 (tradename) | 1.8 parts by weight |
(3) (c) | SANX C (tradename) | 4.6 parts by weight |
(4) (c) | New Kargen EP-70G (tradename) | 0.9 part by weight |
(5) | Propylene glycol | 6.4 parts by weight |
(6) | Veegum R (tradename) | 0.5 part by weight |
(7) | Rhodopol 23 (tradename) | 0.1 part by weight |
(8) | Rhodorsil Antifoam 432 (tradename) | 0.5 part by weight |
(9) | Proxel GXL (tradename) | 0.1 part by weight |
(10) (d) | Water | 66.1 parts by weight |
The above (1) and (2) to (10) were mixed, followed by stirrîng and wet grinding by
DYNO-MILL (the same above) to obtain a water-based pesticidal suspension.
EXAMPLE 4 (1) (a) (2) (b) (3) (c) (4) (5)
Flonicamid (purity: 97.5%) Geropon T/36 (tradename) SANX C (tradename) Propylene glycol Veegum R (tradename)
27.4 parts by weight
1.8 parts by weight
4.4 parts by weight
6.2 parts by weight
0.4 part by weight
(6) | Rhodopol 23 (tradename) | 0.1 part by weight |
(7) | Rhodorsil Antifoam 432 (tradename) | 0.4 part by weight |
(8) | Proxel GXL (tradename) | 0.1 part by weight |
(9) (d) | Water | 59.2 parts by weight |
The above (1) and (2) to (9) were mixed, followed by wet grinding by DYNO-MILL (the same above) to obtain a water-based pesticidal suspension.
EXAMPLE 5
(D (a) | Flonicamid (purity: 97.5%) | 1.0 part by weight |
(2) (b) | Geropon T/36 (tradename) | 0.5 part by weight |
(3) (c) | SANX C (tradename) | 20.0 parts by weight |
(4) | Propylene glycol | 6.2 parts by weight |
(5) | Veegum R (tradename) | 0.4 partby weight |
(6) | Rhodopol 23 (tradename) | 0.1 part by weight |
(7) | Rhodorsil Antifoam 432 (tradename) | 0.4 part by weight |
(8) | Proxel GXL (tradename) | 0.1 part by weight |
(9) (d) | Water | 71.3 parts by weight |
The above (1) and (2) to (9) are mixed, followed by wet grinding by DYNO-MILL (the same above) to obtain a water-based pesticidal suspension.
EXAMPLE 6
(1) (a) | Flonicamid (purity: 97.5%) | 60.0 parts by weight |
(2) (b) | Geropon T/36 (tradename) | 10.0 parts by weight |
(3) (c) | SANX C (tradename) | 1.0 parts by weight |
(4) | Propylene glycol | 1.2 parts by weight |
(5) | Veegum R (tradename) | 0.4 part by weight |
(6) | Rhodopol 23 (tradename) | 0.1 part by weight |
(7) | Rhodorsil Antifoam 432 (tradename) | 0.4 part by weight |
(8) | Proxel GXL (tradename) | 0.1 part by weight |
(9) (d) | Water | 26.8 parts by weight |
The above (1) and (2) to (9) are mixed, followed by wet grinding by DYNO-MILL (the same above) to obtain a water-based pesticidal suspension.
COMPARATIVE EXAMPLE 1 (1) (a) Flonicamid (purity: 97.5%) 41.0 parts by weight
(2) | Potassium sait of polyoxyethylenetristyryl phenyl ether phosphoric acid ester (tradename: Soprophor FLK/70, manufactured by Rhodia Nicca Ltd.) | 5.0 parts by weight |
(3) | Propylene glycol | 7.0 parts by weight |
(4) | Veegum R (tradename) | 0.5 part by weight |
(5) | Rhodopol 23 (tradename) | 0.03 part by weight |
(6) | Rhodorsii Antifoam 432 (tradename) | 0.5 part by weight |
(7) | Proxel GXL (tradename) | 0.03 part by weight |
(8) (d) | Water | 45.94 parts by weight |
The above (1) and (2) to (8) were mixed, followed by wet grinding by DYNO-MILL (the same above) to obtain a water-based pesticidal suspension.
COMPARATIVE EXAMPLE 2 (1) (a) Flonicamid (purity: 97.5%) (2) Potassium sait of polyoxyethylenetristyryl phenyl ether phosphoric acid ester (tradename: Soprophor
FLK/70, manufactured by Rhodia Nicca Ltd.) (3) (c) New Kargen EP-70G (tradename) (4) Propylene glycol
41.0 parts by weight
3.0 parts by weight
0.3 part by weight
7.0 parts by weight (5) Veegum R (tradename)
0.5 part by weight (6) Rhodopol 23 (tradename)
0.03 part by weight (7) Rhodorsii Antifoam 432 (tradename)
0.5 partby weight (8) Proxel GXL (tradename)
0.03 part by weight (9) (d) Water
47.64 parts by weight
The above (1) and (2) to (9) were mixed, followed by wet grinding by DYNO-MILL (the same above) to obtain a water-based pesticidal suspension.
COMPARATIVE EXAMPLE 3
(D (a) | Flonicamid (purity: 97.5%) |
(2) (b) | Geropon T/36 (tradename) |
(3) | Propylene glycol |
¢4) | Veegum R (tradename) |
(5) | Rhodorsii Antifoam 432 (tradename) |
(6) (d) | Water |
41.0 parts by weight
5.0 parts by weight
7.0 parts by weight
0.2 part by weight
0.5 part by weight
46.3 parts by weight
The above (1) and (2) to (6) were mixed, followed by wet grinding by DYNO-MILL (the same above) to obtain a water-based pesticidal suspension.
EXAMPLE 7 (1) (a) Pirimicarb
27.0 parts by weight (2) (b) Geropon T/36 (tradename) (3) (c) SANX C (tradename) (4) (c) New Kargen EP-70G (tradename) (5) Propylene glycol (6) Veegum R (tradename) (7) Rhodopol 23 (tradename) (8) Rhodorsil Antifoam 432 (tradename) (9) Proxel GXL (tradename) (10) (d) Water
1.8 parts by weight
4.5 parts by weight
0.9 part by weight
6.3 parts by weight
0.4 part by weight
0.1 part by weight
0.4 part by weight
0.1 part by weight
58.5 parts by weight
The above (1) and (2) to (10) were mixed, followed by wet grinding by DYNOMILL (the same above) to obtain a water-based pesticidal suspension.
EXAMPLE 8
(1) (a) | Thiamethoxam | 27.0 parts by weight |
¢2) (b) | Geropon T/36 (tradename) | 1.8 parts by weight |
(3) (c) | SANX C (tradename) | 4.5 parts by weight |
(4) (c) | New Kargen EP-70G (tradename) | 0.9 part by weight |
(5) | Propylene glycol | 6.3 parts by weight |
(6) | Veegum R (tradename) | 0.4 part by weight |
(7) | Rhodopol 23 (tradename) | 0.1 part by weight |
(8) | Rhodorsil Antifoam 432 (tradename) | 0.4 part by weight |
(9) | Proxel GXL (tradename) | 0.1 part by weight |
(10) (d) | Water | 58.5 parts by weight |
The above (1) and (2) to (10) were mixed, followed by wet grinding by DYNOMILL (the same above) to obtain a water-based pesticidal suspension.
EXAMPLE 9 (1) (a) Flonicamid (purity: 97.5%)
18.2 parts by weight (2) Chlorfluazuron
4.4 parts by weight (3) (b) Geropon T/36 (tradename)
1.8 parts by weight
(4) (c) | SANX C (tradename) | 4.6 parts by weight |
(5) (c) | New Kargen EP-70G (tradename) | 0.9 part by weight |
(6) | Propylene glycol | 6.4 parts by weight |
(7) | Veegum R (tradename) | 0.5 part by weight |
(8) | Rhodopol 23 (tradename) | 0.1 part by weight |
(9) | Rhodorsil Antifoam 432 (tradename) | 0.5 partby weight |
(W) | Proxel GXL (tradename) | 0.1 part by weight |
(11)(d) | Water | 62.5 parts by weight |
The above (1) and (2) to (11) were mixed, followed by wet grinding by DYNOMILL (the same above) to obtain a water-based pesticidal suspension.
According to the présent invention, as shown below, even if the agricultural chemical (a) is blended with another active ingrédient, it is possible to obtain a stable water-based suspension.
EXAMPLE 10
(1) (a) | Flonicamid (purity: 97.5%) | 27.2 parts by weight |
(2) | Abamectin | 2.7 parts by weight |
(3) (b) | Geropon T/36 (tradename) | 1.8 parts by weight |
(4) (c) | SANX C (tradename) | 4.6 parts by weight |
(5) (c) | New Kargen EP-70G (tradename) | 0.9 part by weight |
(6) | Propylene glycol | 6.4 parts by weight |
(7) | Veegum R (tradename) | 0.5 part by weight |
(8) | Rhodopol 23 (tradename) | 0.1 part by weight |
(9) | Rhodorsil Antifoam 432 (tradename) | 0.5 part by weight |
(10) | Proxel GXL (tradename) | 0.1 partby weight |
(11)(d) | Water | 55.2 parts by weight |
The above (1) and (2) to (11) are mixed, followed by wet grinding to obtain a water-based pesticidal suspension of the présent invention.
EXAMPLE 11 (1) (a) Flonicamid (purity: 97.5%) (2) Isoprocarb (3) (b) Geropon T/36 (tradename) (4) (c) SANX C (tradename)
4.5 parts by weight
22.1 parts by weight
1.8 parts by weight
4.6 parts by weight
¢5) (c) | New Kargen EP-70G (tradename) | 0.9 part by weight |
(6) | Propylene glycol | 6.4 parts by weight |
(7) | Veegum R (tradename) | 0.5 part by weight |
(8) | Rhodopol 23 (tradename) | 0.1 part by weight |
(9) | Rhodorsil Antifoam 432 (tradename) | 0.5 part by weight |
(10) | Proxel GXL (tradename) | 0.1 part by weight |
(11)(d) | Water | 58.5 parts by weight |
The above (1) and (2) to (11) are mixed, followed by wet grinding to obtain a water-based pesticidal suspension ofthe présent invention.
EXAMPLE 12
(1) (a) | Flonicamid (purity: 97.5%) | 4.5 parts by weight |
(2) | Fenobucarb | 22.1 parts by weight |
(3) (b) | Geropon T/36 (tradename) | 1.8 parts by weight |
(4) (c) | SANX C (tradename) | 4.6 parts by weight |
(5) (c) | New Kargen EP-70G (tradename) | 0.9 part by weight |
(6) | Propylene glycol | 6.4 parts by weight |
(7) | Veegum R (tradename) | 0.5 part by weight |
(8) | Rhodopol 23 (tradename) | 0.1 part by weight |
(9) | Rhodorsil Antifoam 432 (tradename) | 0.5 part by weight |
(10) | Proxel GXL (tradename) | 0.1 part by weight |
(11)(d) | Water | 58.5 parts by weight |
The above (1) and (2) to (11) are mixed, followed by wet grinding to obtain a | ||
water-based pesticidal suspension ofthe présent invention. | ||
EXAMPLE 13 | ||
(1) (a) | Flonicamid (purity: 97.5%) | 11.6 parts by weight |
(2) | Validamycin | 17.7 parts by weight |
(3) (b) | Geropon T/36 (tradename) | 1.8 parts by weight |
(4) (c) | SANX C (tradename) | 4.6 parts by weight |
(5) (c) | New Kargen EP-70G (tradename) | 0.9 part by weight |
(6) | Propylene glycol | 6.4 parts by weight |
(7) | Veegum R (tradename) | 0.5 part by weight |
(8) | Rhodopol 23 (tradename) | 0.1 part by weight |
(9) Rhodorsil Antifoam 432 (tradename) (10) Proxel GXL (tradename)
0.5 partby weight
0.1 part by weight (11) (d) Water
55.8 parts by weight
The above (1) and (2) to (11) are mixed, followed by wet grinding to obtain a water-based pesticidal suspension of the présent invention.
EXAMPLE 14
(1) (a) | Flonicamid (purity: 97.5%) | 10.3 parts by weight |
(2) | At least one member selected from the | |
above-mentioned Group X | 10.0 parts by weight | |
(3) (b) | Geropon T/36 (tradename) | 1.8 parts by weight |
(4) (c) | SANX C (tradename) | 4.6 parts by weight |
(5) (c) | New Kargen EP-70G (tradename) | 0.9 part by weight |
(6) | Propylene glycol | 6.4 parts by weight |
(7) | Veegum R (tradename) | 0.5 part by weight |
(8) | Rhodopol 23 (tradename) | 0.1 part by weight |
(9) | Rhodorsil Antifoam 432 (tradename) | 0.5 part by weight |
(10) | Proxel GXL (tradename) | 0.1 partby weight |
(11)(d) | Water | 64.8 parts by weight |
The above (1) and (2) to (11) are mixed, followed by wet grinding to obtain a water-based pesticidal suspension of the présent invention.
TEST EXAMPLE 1 (Initial physical property tests)
The water-based pesticidal suspension obtained in each of Examples 1 to 4, 7 and 9 and Comparative Examples 1 to 3 was filled in a 30 mL glass bottle, which was capped and then immersed in a constant température water tank at 20°C. 30 Minutes later, the glass bottle was taken out, and the viscosity of the water-based pesticidal suspension was measured by means of a B type viscosimeter (rotor: No. 2, rotational speed of rotor: 60 rpm). Further, the average particle size(volume) was measured by a particle size analyzer Microtrac HRA (manufactured by NIKKISO Co., Ltd ). The results are shown in Tables 1,2 and 3.
TEST EXAMPLE 2 (Suspension stability test after heating (54°C for 2 weeks))
The water-based pesticidal suspension was filled in a 30 mL glass bottle, which was capped and then stored in an incubator at 54°C for 2 weeks, whereupon the glass
bottle was taken out from the constant température machine, and Visual observation of the suspension state, and the viscosity measurement and particle size measurement in the same manner as in Test Example 1 were carried out. The Visual observation was assessed by means of eye observation or optical microscopie observation (600 magnification, OLYMPUS CORPORATION, BH-2), Here, presence or absence of coarse particles was assessed by determining the existence of crystals by means of eye observation ,or by determining the existence of crystals of 50 pm or more exist, by means of optical microscopie observation. The results are also shown in Tables 1,2 and 3.
TEST EXAMPLE 3 (Suspension stability test after storage at room température (room température for 2 years))
The water-based pesticidal suspension was filled in a 30 mL glass bottle, which was capped and then stored in a laboratory for 2 years, whereupon Visual observation of the suspension state, and the viscosity measurement and the particle size measurement in the same manner as in Test Example 1, were carried out. The results are also shown in Table 1.
It is évident that the water-based pesticidal suspension of the présent invention was excellent in suspension stability, and the physical properties in the formulation were stable such that the suspension state was stabilized, no coarse particles were precipitated, and the average particle size of the active ingrédient particles and the viscosity of the suspension undergo no change even under severe conditions such as storage by heating condition or storage for a long period of time.
On the other hand, in the suspension stability test after heating and the suspension stability ordinary température évaluation test, in Comparative Examples 1 and 2, the entire suspension underwent gélation, and in Comparative Example 3, the suspension underwent phase séparation to a supernatant layer and a suspension layer, and in the vicinity of the interface, needle coarse particles were precipitated, and the form of the desired suspension was not maintained, and thus, it is évident that in case component (b) and component (c) are not contained at the same time, it is not possible to obtain a water-based pesticidal suspension having a storage stability for a long period of time.
ΙΟ OJ
TABLE 1
Comp. Ex. 3 | 8.3 | 400 | Coarse needle-form particles precipitated in the vicinity of the interface between the suspension layer and the supernatant layer. | 1 | l | 1 | 1 | |
Comp. Ex 2 | o IO | 380 | Entire suspension gelled. | I | 1 | I Entire suspension gelled. I I___________________________„_______________________________ | 1 | 1 |
Comp. Ex. 1 | O) M- | 360 | Entire suspension gelled. | 1 | 1 | Entire suspension gelled. | 1 | 1 |
Ex. 4 | 1.6 | 240 | No coarse particles were observed in suspension. | σ> | 220 | 1 | 1 | 1 |
co X LLl | - | 240 | No coarse particles were observed in suspension. | up | 210 | i | 1 | 1 |
cxl X LLl | 240 | No coarse particles were observed in suspension. | 2.0 | 220 | No coarse particles were observed in suspension. | CD t” | 220 | |
Ex. 1 | 2.9 | 420 | No coarse particles were observed în suspension. ; | 3.2 | 400 | No coarse particles were observed in suspension. | CM | 480 |
Average particle size (um) | Viscosity (mPas) | Appearance ' | Average particle size (um) | Viscosity (mPas) | Appearance | Average particle size (um) | Viscosity (mPas) | |
Test Example 1 Initial physical properties | Test Example 2 Suspension stability (heating test) | Test Example 3 Suspension stability (ordinary température test) |
TABLE 2
Ex. 7 | Ex. 8 | ||
Test Example 1 Initial physical properties | Average particle size (pm) | 2.9 | 8.4 |
Viscosity (mPas) | 112 | 122 | |
Test Example 2 Suspension stability (heating test) | App ea rance | No coarse particles were observed in suspension. | No coarse particles were observed in suspension. |
Average particle size (pm) | 2.6 | 7.5 | |
Viscosity (mPa-s) | 213 | 132 |
TABLE 3
Ex. 9 | ||
Test Example 1 Initial physical properties | Average particle size (pm) | 1.4 |
Viscosity (mPa-s) | 200 | |
Test Example 2 Suspension stability (heating test) | Appearance | No coarse particles were observed in suspension. |
Average particle size (pm) | 1.6 | |
Viscosity (mPa s) | 180 |
The entire dîsclosure of Japanese Patent Application No. 2010-157295 filed on
July 9, 2010 including spécification, claims and summary is incorporated herein by reference in its entirety.
Claims (12)
- CLAIMS:1. A water-based pesticidal suspension comprising (a) an agricultural chemical or its sait having an aqueous solubility of from 500 mg/L to 6,000 mg/L at 20°C, (b) a polycarboxylate type surfactant, (c) a sulfonate type surfactant, and (d) water.
- 2. The water-based pesticidal suspension according to Claim 1, wherein the agricultural chemical (a) is at least one member selected from the group consisting of pirimicarb, thîamethoxam and flonicamid.
- 3. The water-based pesticidal suspension according to Claim 2, wherein the agricultural chemical (a) is flonicamid.
- 4. The water-based pesticidal suspension according to Claim 1, wherein the agricultural chemical (a) has an average particle size(volume) of from 0.5 pm to 10 pm.
- 5. The water-based pesticidal suspension according to Claim 1, wherein the polycarboxylate type surfactant (b) is a polycarboxylate.
- 6. The water-based pesticidal suspension according to Claim 1, wherein the sulfonate type surfactant (c) is at least one member selected from the group consisting of an alkyl sulfosuccinate, a lignosulfonate, a Cs-ie alkyl benzene sulfonate and a C8_i8 alkyl diphenyl ether disulfonate.
- 7. The water-based pesticidal suspension according to Claim 6, wherein the sulfonate type surfactant (c) is a lignosulfonate.
- 8. The water-based pesticidal suspension according to Claim 6, wherein the sulfonate type surfactant (c) is a lignosulfonate and an alkyl sulfosuccinate.
- 9. The water-based pesticidal suspension according to Claim 1, which contains an additive in addition to (a), (b), (c) and (d).
- 10. The water-based pesticidal suspension according to Claim 9, wherein the additive is at least one member selected from the group consisting of an antifreezing agent, a thickener, an antifoaming agent, an antiseptie agent, a pH modifier and a stabilizer.
- 11. The water-based pesticidal suspension according to Claim 1, which further contains at least one agricultural chemical selected from the group consisting of an insecticidal compound and a fungicidal compound.
- 12. A method which comprises stabilizing the suspension state of (a) an agricultural chemical or its sait having an aqueous solubility of from 500 mg/Lto 6,000 mg/L at20°C in a water-based pesticidal suspension by means of (b) a polycarboxylate type surfactant and (c) a sulfonate type surfactant.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010-157295 | 2010-07-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
OA16299A true OA16299A (en) | 2015-04-24 |
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