NZ616346B2 - Thermoplastic films with visually-distinct stretched regions and methods for making the same - Google Patents
Thermoplastic films with visually-distinct stretched regions and methods for making the same Download PDFInfo
- Publication number
- NZ616346B2 NZ616346B2 NZ616346A NZ61634612A NZ616346B2 NZ 616346 B2 NZ616346 B2 NZ 616346B2 NZ 616346 A NZ616346 A NZ 616346A NZ 61634612 A NZ61634612 A NZ 61634612A NZ 616346 B2 NZ616346 B2 NZ 616346B2
- Authority
- NZ
- New Zealand
- Prior art keywords
- film
- stretched regions
- stretched
- visually
- regions
- Prior art date
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- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 76
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 76
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 40
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229960003563 Calcium Carbonate Drugs 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 5
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 13
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 13
- 239000010432 diamond Substances 0.000 claims description 6
- 229910003460 diamond Inorganic materials 0.000 claims description 5
- 235000013305 food Nutrition 0.000 abstract description 13
- 239000010813 municipal solid waste Substances 0.000 abstract description 11
- 238000003860 storage Methods 0.000 abstract description 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 7
- AYJRCSIUFZENHW-UHFFFAOYSA-L Barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 abstract description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L mgso4 Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K Aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 abstract description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L Magnesium hydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 abstract description 3
- 229920002472 Starch Polymers 0.000 abstract description 3
- 239000000292 calcium oxide Substances 0.000 abstract description 3
- 239000004927 clay Substances 0.000 abstract description 3
- 229910052570 clay Inorganic materials 0.000 abstract description 3
- 239000011521 glass Substances 0.000 abstract description 3
- 239000001095 magnesium carbonate Substances 0.000 abstract description 3
- 239000011776 magnesium carbonate Substances 0.000 abstract description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 abstract description 3
- 239000000347 magnesium hydroxide Substances 0.000 abstract description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract description 3
- 239000000395 magnesium oxide Substances 0.000 abstract description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract description 3
- 235000019341 magnesium sulphate Nutrition 0.000 abstract description 3
- 239000010445 mica Substances 0.000 abstract description 3
- 229910052618 mica group Inorganic materials 0.000 abstract description 3
- 239000000843 powder Substances 0.000 abstract description 3
- 239000000377 silicon dioxide Substances 0.000 abstract description 3
- 239000008107 starch Substances 0.000 abstract description 3
- 235000019698 starch Nutrition 0.000 abstract description 3
- 239000000454 talc Substances 0.000 abstract description 3
- 229910052623 talc Inorganic materials 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001929 titanium oxide Inorganic materials 0.000 abstract description 3
- 239000011787 zinc oxide Substances 0.000 abstract description 3
- 238000005096 rolling process Methods 0.000 description 36
- 238000000034 method Methods 0.000 description 20
- -1 polyethylene Polymers 0.000 description 16
- 239000011295 pitch Substances 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 9
- 239000000049 pigment Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 230000001131 transforming Effects 0.000 description 6
- 210000001138 Tears Anatomy 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000005043 ethylene-methyl acrylate Substances 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 241001270131 Agaricus moelleri Species 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 206010021639 Incontinence Diseases 0.000 description 2
- 239000004698 Polyethylene (PE) Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004708 Very-low-density polyethylene Substances 0.000 description 2
- 230000001058 adult Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000003247 decreasing Effects 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- 229920001866 very low density polyethylene Polymers 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-Hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-Octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000000996 additive Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 244000052616 bacterial pathogens Species 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atoms Chemical group C* 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- HGVPOWOAHALJHA-UHFFFAOYSA-N ethene;methyl prop-2-enoate Chemical compound C=C.COC(=O)C=C HGVPOWOAHALJHA-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000001815 facial Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 239000002365 multiple layer Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/04—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
- B29C55/06—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique parallel with the direction of feed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/04—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
- B29C55/08—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique transverse to the direction of feed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/18—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets by squeezing between surfaces, e.g. rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/002—Joining methods not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2623/00—Use of polyalkenes or derivatives thereof for preformed parts, e.g. for inserts
- B29K2623/04—Polymers of ethylene
- B29K2623/06—PE, i.e. polyethylene
- B29K2623/0608—PE, i.e. polyethylene characterised by its density
- B29K2623/0633—LDPE, i.e. low density polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
- B29L2031/7128—Bags, sacks, sachets
- B29L2031/7129—Bags, sacks, sachets open
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D31/00—Bags or like containers made of paper and having structural provision for thickness of contents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D33/00—Details of, or accessories for, sacks or bags
- B65D33/01—Ventilation or drainage of bags
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/006—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers in stretch films
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
- Y10T428/2457—Parallel ribs and/or grooves
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
Abstract
Disclosed are single-layered thermoplastic films that have been intermittently stretched to give regions that are visually distinct from un-stretched regions. The stretched regions can be white, opaque, and non-porous, and made further visually distinct from un-stretched regions by the use of a voiding agent selected from the group consisting of calcium carbonate, magnesium carbonate, barium carbonate, calcium sulfate, magnesium sulfate, barium sulfate, calcium oxide, magnesium oxide, titanium oxide, zinc oxide, aluminum hydroxide, magnesium hydroxide, talc, clay, silica, alumina, mica, glass powder, and starch. The single-layered thermoplastic films with visually-distinct stretched regions can be formed into bags for use as trash can liners or food storage. Additionally, methods of stretching thermoplastic films to create visually distinct stretched regions include incrementally stretching a plurality of film layers, at least one of which includes a thermoplastic material and a voiding agent. ing agent selected from the group consisting of calcium carbonate, magnesium carbonate, barium carbonate, calcium sulfate, magnesium sulfate, barium sulfate, calcium oxide, magnesium oxide, titanium oxide, zinc oxide, aluminum hydroxide, magnesium hydroxide, talc, clay, silica, alumina, mica, glass powder, and starch. The single-layered thermoplastic films with visually-distinct stretched regions can be formed into bags for use as trash can liners or food storage. Additionally, methods of stretching thermoplastic films to create visually distinct stretched regions include incrementally stretching a plurality of film layers, at least one of which includes a thermoplastic material and a voiding agent.
Description
THERMOPLASTIC FILMS WITH VISUALLY-DISTINCT STRETCHED
REGIONS AND METHODS FOR MAKING THE SAME
INVENTORS: Robert T. Dorsey and Michael G. Borchardt
CROSS-REFERENCE TO RELATED APPLICATIONS
This application claims the benefit of U.S. Provisional Application No.
61/478,639, filed April 25, 201 1, which is hereby incorporated by reference in its
entirety.
BACKGROUND OF THE INVENTION
1. The Field of the Invention
The present invention relates generally to thermoplastic films.
Specifically, the invention relates to stretched thermoplastic films with visual effects
created by voiding agents.
2. Background and Relevant Art
Thermoplastic films are a common component in various commercial
and consumer products. For example, grocery bags, trash bags, sacks, and packaging
materials are products that are commonly made from thermoplastic films.
Additionally, feminine hygiene products, baby diapers, adult incontinence products,
and many other products include thermoplastic films to one extent or another.
Thermoplastic films have a variety of different strength parameters that
manufacturers of products incorporating a thermoplastic film component may attempt
to manipulate to ensure that the film is suitable for use its intended use. For example,
manufacturers may attempt to increase or otherwise control the tensile strength, tear
resistance, impact resistance, and breathability of a thermoplastic film. One way
manufacturers may attempt to control or change the material properties of a
thermoplastic film is by stretching the film. Common directions of stretching include
"machine direction" and "transverse direction" stretching. As used herein, the term
"machine direction" or "MD" refers to the direction along the length of the film, or in
other words, the direction of the film as the film is formed during extrusion and/or
coating. As used herein, the term "transverse direction" or "TD" refers to the
direction across the film or perpendicular to the machine direction.
Common ways of stretching film in the machine direction include
machine direction orientation ("MDO") and incremental stretching. MDO involves
stretching the film between two pairs of smooth rollers. Commonly MDO involves
running a film through the nips of sequential pairs of smooth rollers. The first pair of
rollers rotates at a speed less than that of the second pair of rollers. The difference in
speed of rotation of the pairs of rollers can cause the film between the pairs of rollers
to stretch. The ratio of the roller speeds will roughly determine the amount that the
film is stretched. For example, if the first pair of rollers is rotating at 100 feet per
minute ("fpm") and the second pair of rollers is rotating at 500 fpm, the rollers will
stretch the film to roughly five times its original length. MDO stretches the film
continuously in the machine direction and is often used to create an oriented film.
Incremental stretching of thermoplastic film, on the other hand,
typically involves running the film between grooved or toothed rollers. The grooves
or teeth on the rollers intermesh and stretch the film as the film passes between the
rollers. Incremental stretching can stretch a film in many small increments that are
spaced across the film. The depth at which the intermeshing teeth engage can control
the degree of stretching. Often, incremental stretching of films is referred to as ring
rolling.
In connection with stretching a film, manufacturers may add a voiding
agent to the film. Upon stretching, the voiding agent can create voids in the film;
thereby, producing a breathable film. Manufacturers commonly use relatively large
amounts of filler (50% by weight) and/or heat the film to an elevated temperature
during stretching when creating breathable or porous films.
In addition to allowing for the modification or tailoring of the strength
and the breathability of a film, stretching of a film can also reduce the thickness of the
film. Stretched films of reduced thickness can allow manufacturers to use less
thermoplastic material to form a product of a given surface area or size. Reducing the
gauge of a film; however, can make the film more transparent or translucent.
Consumers commonly associate thinner films and/or transparent films with weakness;
and thus, may be dissuaded to purchase stretched films. Manufacturers may add
pigments, such as Ti0 , to add either color or opacity to thinner films. Unfortunately,
additives, such as Ti0 can be expensive and often negatively impact the film strength
properties, especially as the additive concentration is increased. Furthermore, even
pigmented films commonly become less opaque upon stretching. .
One common use of thermoplastic films is as bags for liners in trash or
refuse receptacles. It is often undesirable to use porous or breathable films in trash
bags as the voids in porous films may allow odor and/or liquids to escape from the
bag. Additionally, many consumers may prefer opaque and non-transparent trash
bags that prevent others (i.e., neighbors) from viewing the contents in the trash bag.
Another common use of thermoplastic films is as flexible plastic bags
for storing food items. Similar to trash bags, in some instances it may be undesirable
to use porous or breathable films in food storage bags because the voids in porous
films can allow air and/or germs to reach and spoil the food within food storage bag.
In other instances, however, a breathable food storage bag may be desirable. For
example, a breathable food storage bag may be desirable when storing fruit and/or
vegetables.
Accordingly, there are a number of considerations to be made in
thermoplastic films and manufacturing methods.
BRIEF SUMMARY OF THE INVENTION
Implementations of the present invention solve one or more problems
in the art with apparatus and methods for creating films with visually-distinct
stretched regions. In particular, one or more implementations of the present invention
include incrementally stretching films formed from a thermoplastic material and a
voiding agent. Upon stretching, the voiding agent can cause the stretched regions of
the film to become more opaque than un-stretched regions of the film. Additionally,
one or more implementations of the present invention include methods of
incrementally-stretching films to create visually-distinct stretched regions.
For example, one implementation of a thermoplastic film can include a
first plurality of un-stretched regions. The film can also include a second plurality of
stretched regions intermittently dispersed about the first plurality of un-stretched
regions. The stretched regions can be non-porous and more opaque than the un-
stretched regions.
Additionally, one or more implementations of the present invention
include a thermoplastic bag that includes first and second sidewalls. The first and
second sidewalls can be joined along three edges. The thermoplastic bag can include
a plurality of un-stretched regions formed in one or more of the first sidewall or the
second sidewall. The un-stretched regions can have a first average thickness. The
thermoplastic bag can also include a plurality of stretched regions intermittently
dispersed about the un-stretched regions. The stretched regions can have a second
average thickness that is smaller than the first average thickness. Additionally, the
stretched regions can be more opaque then un-stretched regions.
In addition to the forgoing, a method for incrementally stretching a
film to create visually distinct regions can involve providing a thermoplastic film.
The thermoplastic film can comprise between about 65 and about 99 percent by
weight of a thermoplastic material and between about 1 and about 35 percent by
weight of a voiding agent. The method can also involve cold stretching the film to
create non-porous stretched regions intermittingly dispersed among un-stretched
regions. The stretched regions can be more opaque than the un-stretched regions of
the film.
Additional features and advantages of exemplary embodiments of the
present invention will be set forth in the description which follows, and in part will be
obvious from the description, or may be learned by the practice of such exemplary
embodiments. The features and advantages of such embodiments may be realized and
obtained by means of the instruments and combinations particularly pointed out in the
appended claims. These and other features will become more fully apparent from the
following description and appended claims, or may be learned by the practice of such
exemplary embodiments as set forth hereinafter.
BRIEF DESCRIPTION OF THE DRAWINGS
In order to describe the manner in which the above-recited and other
advantages and features of the invention can be obtained, a more particular
description of the invention briefly described above will be rendered by reference to
specific embodiments thereof which are illustrated in the appended drawings. It
should be noted that the figures are not drawn to scale, and that elements of similar
structure or function are generally represented by like reference numerals for
illustrative purposes throughout the figures. Understanding that these drawings depict
only typical embodiments of the invention and are not therefore to be considered to be
limiting of its scope, the invention will be described and explained with additional
specificity and detail through the use of the accompanying drawings in which:
Fig. 1A illustrates a schematic diagram of a thermoplastic film being
incrementally stretched by MD intermeshing rollers in accordance with one or more
implementations of the present invention;
Fig. IB illustrates an enlarged view of a portion of the thermoplastic
film passing through the intermeshing rollers of Fig. 1A taken along the circle IB of
Fig. 1;
Fig. 2 illustrates a view of a thermoplastic film including visually-
distinct stretched regions created by the intermeshing rollers of Fig. 1;
Fig. 3 illustrates a schematic diagram of a thermoplastic film being
incrementally stretched by TD intermeshing rollers in accordance with one or more
implementations of the present invention;
Fig. 4 illustrates a view of a thermoplastic film including visually-
distinct stretched regions created by the intermeshing rollers of Fig. 3;
Fig. 5 illustrates a view of a thermoplastic film including visually-
distinct stretched regions created by the intermeshing rollers of both Fig. 1 and Fig. 3;
Fig. 6 illustrates a view of thermoplastic film including visually-
distinct stretched regions created by diagonal direction intermeshing rollers in
accordance with one or more implementations of the present invention;
Fig. 7 illustrates a schematic diagram of a set of intermeshing rollers
used to impart strainable networks into a film in accordance with one or more
implementations of the present invention;
Fig. 8 illustrates a view of a thermoplastic film including visually-
distinct stretched regions created by the intermeshing rollers of Fig. 7;
Fig. 9 illustrates a view of a thermoplastic film including strainable
networks having visually-distinct stretched regions in accordance with one or more
implementations of the present invention;
Fig. 10 illustrates a bag incorporating the film of Fig. 2;
Fig. 11 illustrates a bag incorporating a film having visually-distinct
stretched regions in accordance with one or more implementations of the present
invention;
Fig. 12 illustrates a bag incorporating a middle section having visually-
distinct stretched regions in accordance with one or more implementations of the
present invention;
Fig. 13 illustrates a bag incorporating sections of different patterns of
visually-distinct stretched regions in accordance with one or more implementations of
the present invention;
Fig. 14 illustrates another bag incorporating sections of different
patterns of visually-distinct stretched regions in accordance with one or more
implementations of the present invention;
Fig. 15 illustrates a schematic diagram of a bag manufacturing process
in accordance with one or more implementations of the present invention;
Fig. 16 illustrates a schematic diagram of another bag manufacturing
process in accordance with one or more implementations of the present invention; and
Fig. 17 illustrates a schematic diagram of yet another bag
manufacturing process in accordance with one or more implementations of the present
invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
One or more implementations of the present invention include
apparatus and methods for creating films with visually-distinct stretched regions. In
particular, one or more implementations of the present invention include
incrementally stretching films formed from a thermoplastic material and a voiding
agent. Upon stretching, the voiding agent can cause the stretched regions of the film
to become more opaque than un-stretched regions of the film. Additionally, one or
more implementations of the present invention include methods of incrementally-
stretching films to create visually-distinct stretched regions.
Indeed, one or more implementations of the present invention can
provide thermoplastic films, and products made there from, with visually-distinct
stretched regions. As used herein, the term "visually distinct" refers to a feature that
is more opaque and potentially a different color from another feature in a manner that
is visible to the naked eye. In one or more implementations, the visually-distinct
stretched regions can be white and opaque. The opacity of the visually-distinct
stretched regions can make the stretched regions appear thick and can connote
strength to a consumer.
In addition to the foregoing, one or more implementations provide
stretched thermoplastic films with visually distinct regions that consumers can
associate with improved properties created by stretching the film. For example, the
visually distinct regions can indicate that those regions have undergone a
transformation to impart a desirable characteristic to that region (e.g., increased
strength or elasticity). Thus, the visually distinct regions can serve to notify a
consumer that the thermoplastic film has been processed to improve the film.
Furthermore, different areas of a film can include different types of
stretching; and thus, different strength characteristics. The different visually-distinct
stretched regions created by the different types of stretching can serve to notify the
consumer that the different areas or zones of the film have been tailored with different
characteristics. For example, one or more implementations of the present invention
includes using MD ring rolling, TD ring rolling, diagonal direction ("DD") ring
rolling, and the formation of strainable networks, and combinations thereof to create
different stress-whitened patterns in a film. As used herein, "stress-whitening" or
"stress-whitened" refers to a film becoming more opaque and/or whiter upon
stretching. In addition to different types of stretching, intermeshing rollers with
different tooth pitches and/or layouts can allow for the creation of visually-distinct
stress-whitened patterns in a film. Also, the film can include one or more pigments of
a color other than white. Thus upon stretching, the whitened stretched regions can
contrast with the colored un-stretched regions.
Additionally, consumers may associate thinner films with decreased
strength. Indeed, such consumers may feel that they are receiving less value for their
money when purchasing thermoplastic film products with thinner gauges. One will
appreciate in light of the disclosure herein that a consumer may not readily detect that
one or more incrementally-stretched films of the present invention have a reduced
gauge. In particular, by imparting an alternating pattern of visually distinct regions,
the consumer may perceive the more opaque regions as being thicker and/or having
increased strength.
As explained in greater detail below, the use of a voiding agent to
create visually-distinct stretched regions can allow a manufacturer to use less
pigments, such as Ti0 , to color or add opacity to a film. The reduction in pigments
can lead to significant cost savings. Furthermore, pigments can become less effective
as a film is stretched; thus, one or more implementations of the implementations of
the present invention can be more effective in adding opacity to stretched films than
pigments alone.
As alluded to previously, voiding agents are commonly added to films
so as to create porous or breathable films upon stretching. One or more
implementations include adding relatively small amounts of a voiding agent(s) and/or
stretching the film under ambient or cold (non-heated) conditions to allow for the
creation of stress-whitened regions without creating a porous film. This differs
significantly from most conventional processes that stretch films including voiding
agents. In particular, most conventional processes that stretch films including voiding
agents stretch the films under heated conditions and include relatively large amounts
of the voiding agent. Stretching under ambient or cold conditions in accordance with
one or more implementations can constrain the molecules in the film so they are not
as easily oriented as under heated conditions, so as to help prevent the creation of a
porous film.
Film Materials
As an initial matter, in one or more implementations the films (e.g., 10-
lOe of Figs. 1A-9) can comprise a thermoplastic material and a voiding agent. In
alterative implementations, the films (e.g., 10-lOe of Figs. 1A-9) may comprise a
thermoplastic material(s) that stress whitens without a voiding agent. The
thermoplastic material of the films of one or more implementations can include, but
are not limited to, thermoplastic polyolefms, including polyethylene and copolymers
thereof and polypropylene and copolymers thereof. The olefin based polymers can
include the most common ethylene or propylene based polymers such as
polyethylene, polypropylene, and copolymers such as ethylene vinylacetate (EVA),
ethylene methyl acrylate (EMA) and ethylene acrylic acid (EAA), or blends of such
polyolefms.
Other examples of polymers suitable for use as films in accordance
with the present invention include elastomeric polymers. Suitable elastomeric
polymers may also be biodegradable or environmentally degradable. Suitable
elastomeric polymers for the film include poly(ethylene-butene), poly(ethylene-
hexene), poly(ethylene-octene), poly(ethylene-propylene), poly(styrene-butadiene-
styrene), poly(styrene-isoprene-styrene), poly(styrene-ethylene-butylene-styrene),
poly(ester-ether), poly(ether-amide), poly(ethylene-vinylacetate), poly(ethylene-
methylacrylate), poly(ethylene-acrylic acid), poly(ethylene butylacrylate),
polyurethane, poly(ethylene-propylene-diene), ethylene-propylene rubber.
In at least one implementation of the present invention, the film can
include linear low density polyethylene. The term "linear low density polyethylene"
(LLDPE) as used herein is defined to mean a copolymer of ethylene and a minor
amount of an olefin containing 4 to 10 carbon atoms, having a density of from about
0.910 to about 0.926, and a melt index (MI) of from about 0.5 to about 10. For
example, some implementations of the present invention can use an octene
comonomer, solution phase LLDPE (MI=1.1; p=0.920). Additionally, other
implementations of the present invention can use a gas phase LLDPE, which is a
hexene gas phase LLDPE formulated with slip/AB (MI=1.0; p=0.920). One will
appreciate that the present invention is not limited to LLDPE, and can include "high
density polyethylene" (HDPE), "low density polyethylene" (LDPE), and "very low
density polyethylene" (VLDPE). Indeed films made from any of the previously
mentioned thermoplastic materials or combinations thereof can be suitable for use
with the present invention.
LLDPE will typically not stress whiten without a voiding agent. Thus,
films of one or more implementations of the present invention including LLDPE may
also include a voiding agent. Furthermore, LLDPE is typically not a candidate
material for conventional film orientations methods because its relatively high
crystallinity can result in a relatively sharp melting point. The relatively sharp
melting point can make LLDPE difficult to process. As such, stretching LLDPE by
conventional means with voiding agents to create breathable films can be difficult.
Indeed, implementations of the present invention can include any
flexible or pliable thermoplastic material which may be formed or drawn into a web
or film. Furthermore, the thermoplastic materials may include a single layer or
multiple layers. The thermoplastic material may be opaque, transparent, translucent,
or tinted. Furthermore, the thermoplastic material may be gas permeable or
impermeable.
As used herein, the term "flexible" refers to materials that are capable
of being flexed or bent, especially repeatedly, such that they are pliant and yieldable
in response to externally applied forces. Accordingly, "flexible" is substantially
opposite in meaning to the terms inflexible, rigid, or unyielding. Materials and
structures that are flexible, therefore, may be altered in shape and structure to
accommodate external forces and to conform to the shape of objects brought into
contact with them without losing their integrity. In accordance with further prior art
materials, web materials are provided which exhibit an "elastic-like" behavior in the
direction of applied strain without the use of added traditional elastic. As used herein,
the term "elastic-like" describes the behavior of web materials which when subjected
to an applied strain, the web materials extend in the direction of applied strain, and
when the applied strain is released the web materials return, to a degree, to their pre-
strained condition.
In addition to a thermoplastic material, the films of one or more
implementations of the present invention can also include a voiding agent. Some
examples of voiding agents suitable for use in the present invention include calcium
carbonate, magnesium carbonate, barium carbonate, calcium sulfate, magnesium
sulfate, barium sulfate, calcium oxide, magnesium oxide, titanium oxide, zinc oxide,
aluminum hydroxide, magnesium hydroxide, talc, clay, silica, alumina, mica, glass
powder, starch, etc. One will appreciate in light of the disclosure herein that the
foregoing list of voiding agents are examples of some of the voiding agents that may
be suitable for use with the present invention.
Films of one or more implementations of the present invention may
include other voiding agents, or combinations of any of the previously mentioned
voiding agents. Indeed, in one or more implementations, the voiding agent any be
any inorganic or organic material with a relatively lower elasticity than the
thermoplastic material of the film. In one or more implementations, calcium
carbonate may be particularly suitable for its whiteness, inert characteristic, low cost,
and availability.
In addition to a thermoplastic material and a voiding agent, films of
one or more implementations of the present invention can also include one or more
additives. For examples, the films can include pigments, slip agents, anti-block
agents, or tackifiers. The pigments can include Ti0 , or other pigments, that can
impart a color and/or opacity to the film.
One will appreciate in light of the disclosure herein that manufacturers
may form the films or webs to be used with the present invention using a wide variety
of techniques. For example, a manufacturer can form precursor mix of the
thermoplastic material, a voiding agent, and one or more additives. The manufacturer
can then form the film(s) from the precursor mix using conventional flat or cast
extrusion or coextrusion to produce monolayer, bilayer, or multilayer films.
Alternatively, a manufacturer can form the films using suitable processes, such as, a
blown film process to produce monolayer, bilayer, or multilayer films. If desired for
a given end use, the manufacturer can orient the films by trapped bubble, tenterframe,
or other suitable process. Additionally, the manufacturer can optionally anneal the
films thereafter.
In one or more implementations, the films of the present invention are
blown film, or cast film. Blown film and cast film is formed by extrusion. The
extruder used can be a conventional one using a die, which will provide the desired
gauge. Some useful extruders are described in U.S. Pat. Nos. 4,814,135; 4,857,600;
,076,988; 5,153,382; each of which are incorporated herein by reference in their
entirety. Examples of various extruders, which can be used in producing the films to
be used with the present invention, can be a single screw type modified with a blown
film die, an air ring, and continuous take off equipment.
In a blown film process, the die can be an upright cylinder with a
circular opening. Rollers can pull molten plastic upward away from the die. An air-
ring can cool the film as the film travels upwards. An air outlet can force compressed
air into the center of the extruded circular profile, creating a bubble. The air can
expand the extruded circular cross section by a multiple of the die diameter. This
ratio is called the "blow-up ratio." When using a blown film process, the
manufacturer can collapse the film to double the plies of the film. Alternatively, the
manufacturer can cut and fold the film, or cut and leave the film unfolded.
As used herein, the term "starting gauge" or "initial gauge" refers to
the average distance between the major surfaces of a film before it is incrementally
stretched. The films of one or more implementations of the present invention can
have a starting gauge between about 0.1 mils to about 20 mils, suitably from about 0.2
mils to about 4 mils, suitably in the range of about 0.3 mils to about 2 mils, suitably
from about 0.6 mils to about 1.25 mils, suitably from about 0.9 mils to about 1.1 mils,
suitably from about 0.3 mils to about 0.7 mils, and suitably from about 0.4 mils and
about 0.6 mils. Additionally, the starting gauge of films of one or more
implementations of the present invention may not be uniform. Thus, the starting
gauge of films of one or more implementations of the present invention may vary
along the length and/or width of the film.
In one or more implementations of the present invention, the
incrementally-stretched films with visually-distinct stretched regions are non porous
or non breathable. As used herein, the terms "non porous" and "non breathable" refer
to a films that are liquid impermeable and at least substantially gas/vapor
impermeable. Thus, a non-porous or non-breathable film may not allow liquids or
gases to pass there through. Because the incrementally-stretched films with visually-
distinct stretched regions of one or more implementations are non porous or non
breathable, they may be particularly suited for use in trash liners or food storage bags.
In one or more additional implementations, the incrementally-stretched films with
visually-distinct stretched regions may be liquid impermeable, yet gas/vapor
permeable. Such incrementally-stretched films with visually-distinct stretched
regions of one or more implementations may be particularly suited for use in food
storage bags.
It should be noted that the non-porous or non-breathable films of the
present invention can include voids. The voids can create the stress-whitened and/or
opaque appearance in the stretched regions. One will appreciate, however, that the
size, number, and/or depth of the voids may prevent liquid from passing through the
film. Furthermore, in some implementations, the size, number, and/or depth of the
voids may substantially prevent gases and vapors from passing through the film. In
still further implementations, the size, number, and/or depth of the voids may
completely prevent gases and vapors from passing through the film.
The size, number, and/or depth of the voids can be controlled to ensure
a non-porous film by controlling one or more of the amount of the voiding agent in
the film, the degree or amount of stretching, and the temperature of the film upon
stretching. For example, in one or more implementations the percent weight of the
voiding agent in the film can be suitably between about 1% and about 35%, suitably
between about 1% and about 30%>, suitably between about 5% and about 25%,
suitably between about 5% and about 20%, and suitably between about 10% and
about 15%.
Additionally, one or more implementations include incrementally
stretching the film under ambient or cold (non-heated) conditions. Furthermore, one
or more implementations include stretching the film at ratios less than about 1:3. In
other words, one or more implementations include stretching the film less than about
3 times its original dimension (e.g., length, width). Suitably one or more
implementations include stretching the film less than about 1.5 times its original
dimension (e.g., length, width).
Referring now to the Figures, Figs. 1A and IB illustrate one exemplary
process of incrementally stretching a thermoplastic film to create visually-distinct
stretched regions in accordance with an implementation of the present invention. In
particular, Figs. 1A and IB illustrate an MD ring rolling process that incrementally
stretches a thermoplastic film 10 by passing the film 10 through a pair of MD
intermeshing rollers 12, 14. The MD ring rolling processes of the present invention
can stretch the film 10 in the machine direction.
As shown by the Figs. 1A and IB, the first roller 12 and the second
roller 14 can each have a generally cylindrical shape. The rollers 12, 14 may be made
of cast and/or machined metal, such as, steel, aluminum, or any other suitable
material. The rollers 12, 14 can rotate in opposite direction about parallel axes of
rotation. For example, Fig. 1A illustrates that the first roller 12 can rotate about a first
axis 16 of rotation in a counterclockwise direction 18. Fig. 1A also illustrates that the
second roller 14 can rotate about a second axis 20 of rotation in a clockwise direction
22. The axes of rotation 16, 20 can be parallel to the transverse direction and
perpendicular to the machine direction.
The intermeshing rollers 12, 14 can closely resemble fine pitch spur
gears. In particular, the rollers 12, 14 can include a plurality of protruding ridges 24,
26. The ridges 24, 26 can extend along the rollers 12, 14 in a direction generally
parallel to axes of rotation 16, 20. Furthermore, the ridges 24, 26 can extend
generally radially outward from the axes of rotation 16, 20. The tips of ridges 24, 26
can have a variety of different shapes and configurations. For example, the tips of the
ridges 24, 26 can have a rounded shape as shown in Fig. IB. In alternative
implementations, the tips of the ridges 24, 26 can have sharp angled corners. Figs. 1A
and IB also illustrate that grooves 28, 30 can separate adjacent ridges 24, 26.
The ridges 24 on the first roller 12 can be offset or staggered with
respect to the ridges 26 on the second roller 14. Thus, the grooves 28 of the first
roller 12 can receive the ridges 26 of the second roller 14, as the rollers 12, 14
intermesh. Similarly, the grooves 30 of the second roller 14 can receive the ridges 24
of the first roller 12. In one or more implementations, the ridges 24, 26 will not
contact each other or transmit rotational torque during an intermeshing stretching
operation.
One will appreciate in light of the disclosure herein that the
configuration of the ridges 24, 26 and grooves 28, 30 can prevent contact between
ridges 24, 26 during intermeshing. Additionally, the configuration of the ridges 24,
26 and grooves 28, 30 can dictate the amount stretching a film passing through the
MD intermeshing rollers 12, 14 undergoes.
Referring specifically to Fig. IB, various features of the ridges 24, 26
and grooves 28, 30 are shown in greater detail. The pitch and depth of engagement of
the ridges 24, 26 can determine, at least in part, the amount of incremental stretching
created by the intermeshing rollers 12, 14. As shown by Fig. IB, the pitch 32 is the
distance between the tips of two adjacent ridges on the same roller. The "depth of
engagement" (DOE) 34 is the amount of overlap between ridges 24, 26 of the
different rollers 12, 14 during intermeshing. The ratio of DOE 34 to pitch 32 can
determine, at least in part, the amount of stretch imparted by a pair of intermeshing
rollers 12, 14.
As shown by Fig. 1A, the direction of travel of the film 10 through the
intermeshing rollers 12, 14 is parallel to the machine direction and perpendicular to
the transverse direction. As the thermoplastic film 10 passes between the
intermeshing rollers 12, 14, the ridges 24, 26 can incrementally stretch the film 10 in
the machine direction. In some implementations, stretching the film 10 in the
machine direction can reduce the gauge of the film and increase the length of the film
. In other implementations, the film 10 may rebound after stretched such that the
gauge of the film 10 is not decreased. Furthermore, in some implementations,
stretching the film 10 in the machine direction can reduce the width of the film 10.
For example, as the film 10 is lengthened in the machine direction, the film's length
can be reduced in the transverse direction.
In particular, as the film 10 proceeds between the intermeshing rollers
12, 14, the ridges 24 of the first roller 12 can push the film 10 into the grooves 30 of
the second roller 14 and vice versa. The pulling of the film 10 by the ridges 24, 26
can stretch the film 10. The rollers 12, 14 may not stretch the film 10 evenly along its
length. Specifically, the rollers 12, 14 can stretch the portions of the film 10 that
contact the ridges 24, 26 more than the portions of the film 10 that do not contact the
ridges 24, 26. Thus, the rollers 12, 14 can impart or form a striped pattern 36 into the
film 10. As used herein, the terms "impart" and "form" refer to the creation of a
desired structure or geometry in a film upon stretching the film that will at least
partially retain the desired structure or geometry when the film is no longer subject to
any strains or externally applied forces.
As shown in Figs. 1A and IB, the striped pattern 36 formed by the MD
ring rolling process can be visually perceivable. As used herein, the term "visually
perceivable" refers to features that are readily discernible to the normal naked eye. In
particular, visually perceivable features can be readily discernible to the normal naked
eye when a film 10 including the features is subjected to normal use.
In one or more implementations, prior to passing through the
intermeshing rollers 12, 14, the film 10 may not include a visually perceivable striped
pattern. For example, Figs. 1A and IB illustrate that the pre-stretched film 10a (i.e.,
the film that is yet to pass through the intermeshing rollers 12, 14) can have a
substantially flat top surface 38 and substantially flat bottom surface 40. The pre-
stretched film 10a can have an initial thickness or starting gauge 42 extending
between its major surfaces (i.e., the top surface 38 and the bottom surface 40). In at
least one implementation, the starting gauge 42 can be substantially uniform along the
length of the pre-stretched film 10a.
For purposes of the present invention, the pre-stretched film 10a need
not have an entirely flat top surface 38. Indeed, the top surface 38 can be rough or
uneven. Similarly, bottom surface 40 of the pre-stretched film 10a can also be rough
or uneven. Further, the starting gauge 42 need not be consistent or uniform
throughout the entirety of pre-stretched film 10a. Thus, the starting gauge 42 can vary
due to product design, manufacturing defects, tolerances, or other processing issues.
In any event, Figs. 1A and IB illustrate the intermeshing rollers 12, 14
can process the pre-stretched film 10a into an MD incrementally-stretched film 10b
with visually-distinct stretched regions. As previously mentioned, the MD
incrementally-stretched film 10b can include a striped pattern 36. The striped pattern
36 can include alternating series of "un-stretched" regions 44 and stretched regions
46. In one or more implementations, the "un-stretched" regions of the incrementally-
stretched films may be stretched to a small degree. In any event, the "un-stretched"
regions are stretched significantly less compared to the stretched regions.
The un-stretched regions 44 can have a first average thickness or gauge
48. The first average gauge 48 can be approximately equal to the starting gauge 42.
In one or more implementations, the first average gauge 48 can be less than the
starting gauge 42. The stretched regions 46 can have a second average thickness or
gauge 50. In one or more implementations, the second average gauge 50 can be less
than both the starting gauge 42 and the first average gauge 48.
One will appreciate in light of the disclosure herein that the striped
pattern 36 may vary depending on the method used to incrementally stretch the film
. To the extent that MD ring rolling is used to incrementally stretch the film 10, the
striped pattern 36 on the film 10 can depend on the pitch 32 of the ridges 24, 26, the
DOE 34, and other factors. In some implementations, the molecular structure of the
thermoplastic material of the film 10 may be rearranged to provide this shape
memory.
Fig. 2 illustrates a top view of the MD incrementally-stretched film
10b with visually-distinct stretched regions. As shown by Fig. 2, the stretched regions
46 can be white and opaque. The localized stretching of the film 10 in the stretched
regions 46 can create voids that provide the stretched regions 46 with whiteness and
opacity. In other words, the stretched regions can be stress-whitened. In one or more
implementations, the stretched regions 46 are non porous, despite the presence of
voids, as previously described herein above.
Additionally, in one or more implementations, despite having a
reduced gauge, the stretched regions 46 can be white and opaque. The opacity of the
stretched regions 46 can result in a pleasing appearance and connote strength to a
consumer. Furthermore, the whiteness and opacity of the stretched regions 46 can
signify that the film 10b has undergone a transformation to modify one or more
characteristics of the film 10b. For example, MD ring rolling the film 10 can increase
or otherwise modify one or more of the tensile strength, tear resistance, impact
resistance, or elasticity of the film 10b. The visually-distinct stretched regions 46 can
signify the transformation to a consumer.
Furthermore, the stretched regions 46 can include stripes that extend
across the film 10b in a direction transverse (i.e., transverse direction) to a direction in
which the film was extruded (i.e., machine direction). As shown by Fig. 2, the stripes
or stretched regions 46 can extend across the entire length of the film 10b. The pitch
32 and the DOE 34 of the ridges 24, 26 of the intermeshing rollers 12, 14 can
determine the width and spacing of the stripes or stretched regions 46. Thus, as
explained in greater detail below, by varying the pitch 32 and/or DOE 34, the width
and/or spacing of the stretched regions 46 can be varied.
Fig. 2 further illustrates that the stretched regions 46 can be
intermittently dispersed about un-stretched regions 44. In particular, each stretched
region 46 can reside between adjacent un-stretched regions 44. Additionally, the
stretched regions 46 can be visually distinct from the un-stretched regions 44. For
example, the stretched regions 46 can differ from the un-stretched regions 44 in one
or more of color or transparency.
Thus, the un-stretched regions 44 can be a color other than white
and/or transparent or translucent. For instance, the un-stretched regions 44 can be
black, blue, red, another color, or any shade there between. Thus, in one or more
implementations, the stretched regions 46 can be a lighter shade with increased
opacity and the un-stretched regions 44 can be either (i) white and transparent or
translucent, (ii) a color other than white and transparent or translucent, or (ii) a color
other than white and opaque.
Furthermore, the opacity and color of the visually-distinct stretched
regions 46 can vary based on the degree of stretching. For instance, when the un-
stretched regions 44 are red, the stretched regions 46 can be a lighter shade of red,
pink, or even white, along the spectrum of stretch. When the un-stretched regions 44
are black, the stretched regions 46 can be a lighter shade of black, grey, and even
white, depending on the degree of stretch. Similar to the shade or color, the opacity
of the stretched regions 46 can vary based on the degree of stretching.
As mentioned previously, MD ring rolling is one exemplary method of
incrementally stretching a thermoplastic film to create visually-distinct stretched
regions in accordance with an implementation of the present invention. TD ring
rolling is another suitable method of incrementally stretching a film to create visually-
distinct stretched regions. For example, Fig. 3 illustrates a TD ring rolling process
that incrementally stretches a thermoplastic film 10 by passing the film 10 through a
pair of TD intermeshing rollers 52, 54. A TD ring rolling processes (and associated
TD intermeshing rollers 52, 54) can be similar to the MD ring rolling process (and
associated MD intermeshing rollers 12, 14) described herein above, albeit that the
ridges 56, 58 and grooves 60, 62 of the TD intermeshing rollers 52, 54 can extend
generally orthogonally to the axes of rotation 16, 20.
Thus, as shown by Fig. 3, as the thermoplastic film 10 passes between
the intermeshing rollers 52, 54, the ridges 56, 58 can incrementally stretch the film 10
in the transverse direction. In particular, as the film 10 proceeds between the
intermeshing rollers 52, 54, the ridges 56, 58 can impart or form a striped pattern 36a
into the film 10 to form a TD incrementally-stretched film 10c with visually-distinct
stretched regions.
Fig. 4 illustrates a view of the TD incrementally-stretched film 10c
with visually-distinct stretched regions. The striped pattern 36a can include
alternating series of un-stretched regions 44a and stretched regions 46a. As shown by
Fig. 4, the stretched regions 46a can be white and opaque. The localized stretching of
the film 10 in the stretched regions 46a can create voids that provide the stretched
regions 46a with whiteness and opacity. In one or more implementations, the
stretched regions 46a are non porous, despite the presence of voids, as previously
described herein above.
The opacity of the stretched regions 46a can result in a pleasing
appearance and connote strength to a consumer. Furthermore, the whiteness and
opacity of the stretched regions 46a can signify that the film 10c has undergone a
transformation to modify one or more characteristics of the film 10c. For example,
TD ring rolling the film 10 can increase or otherwise modify one or more of the
tensile strength, tear resistance, impact resistance, or elasticity of the film 10c. The
visually-distinct stretched regions 46a can signify the transformation to a consumer.
Fig. 4 illustrates that the stretched regions 46a can include stripes that
extend across the film 10c in the machine direction. As shown by Fig. 4, the stripes
or stretched regions 46a can extend across the entire width of the film 10c. In
alternative implementations, stretched regions 46a can extend across only a portion of
the film 10c. Similar to MD ring rolling, the pitch and the DOE of the ridges 56, 58
of the intermeshing rollers 52, 54 can determine the width and spacing of the stripes
or stretched regions 46a.
In still further implementations, a film 10 can undergo both an MD
ring rolling process and a TD ring rolling process to create visually-distinct stretched
regions. For example, Fig. 5 illustrates a top view of an incrementally-stretched film
lOd with visually-distinct stretched regions created by MD and TD ring rolling. The
incrementally-stretched film lOd can have a checker board pattern 36b. The checker
board pattern 36b can include alternating series of un-stretched regions 44b and
stretched regions 46b, 46c. As shown by Fig. 5, stretched regions 46b, 46c can be
visually distinct from the un-stretched regions 44b. In particular, stretched regions
46b, 46c can be white and opaque. The stretched regions 46b, 46c can include stripes
46b that extend along the film 10c in the machine direction, and stripes 46c that
extend along the film in the transverse direction. As shown by Fig. 5, in one or more
implementations, the aspect ratio of the rows and columns of the stretched regions
46b, 46c can be approximately 1 to 1. In alternative implementations, the aspect ratio
of the rows and columns of the rows and columns of the stretched regions 46b, 46c
can be greater or less than 1 to 1, as explained in greater detail in relation to Fig. 11.
The incrementally-stretched film lOd with visually-distinct stretched
regions created by MD and TD ring rolling can allow for even greater material
savings by further increasing the surface area of a given portion of film. Additionally,
MD and TD ring rolling can provide properties or advantages not obtained by MD or
TD ring rolling alone. Thus, checker board pattern 36b created by the stretched
regions 46b, 46c can signify these transformations to a consumer.
In yet further implementations, a manufacturer can use DD ring rolling
to incrementally stretch a thermoplastic film to create visually-distinct stretched
regions. A DD ring rolling processes (and associated DD intermeshing rollers) can be
similar to the MD ring rolling process (and associated MD intermeshing rollers 12,
14) described herein above, albeit that the ridges and grooves of the DD intermeshing
rollers can extend at an angle relative to the axes of rotation. For example, Fig. 6
illustrates a view of an incrementally-stretched film lOe with visually-distinct
stretched regions created by DD ring rolling. The incrementally-stretched film lOe
can have a diamond pattern 36c. The diamond pattern 36c can include alternating
series of diamond-shaped un-stretched regions 44c and stretched regions 46d. As
shown by Fig. 6, stretched regions 46d can be visually distinct. The stretched regions
can include stripes 46d oriented at an angle relative to the transverse direction such
that the stripes 46d are neither parallel to the transverse or machine direction.
One will appreciate in light of the disclosure herein that one or more
implementations can include stretched regions arranged in other patterns/shapes.
Such additional patterns include, but are not limited to, intermeshing circles, squares,
diamonds, hexagons, or other polygons and shapes. Additionally, one or more
implementations can include stretched regions arranged in patterns that are
combinations of the illustrated and described patterns/shapes.
In accordance with another implementation, a structural elastic like
film (SELF) process may be used to create a thermoplastic film with strainable
networks. As explained in greater detail below, the strainable networks can include
visually-distinct stretched regions. U.S. Patent No. 5,518,801, U.S. Patent No.
6,139,185; U.S. Patent No. 6,150,647; U.S. Patent No. 6,394,651; U.S. Patent No.
6,394,652; U.S. Patent No. 6,513,975; U.S. Patent No. 6,695,476; U.S. Patent
Application Publication No. 2004/0134923; and U.S. Patent Application Publication
No. 2006/0093766 each disclose processes to form strainable networks or patterns of
strainable networks suitable for use with implementations of the present invention.
The contents of each of the aforementioned patents and patent application
publications are incorporated in their entirety by reference herein.
Fig. 7 illustrates a pair of SELF'ing intermeshing rollers 72, 74 for
creating strainable networks with visually-distinct stretched regions in a film. The
first SELF'ing intermeshing roller 72 can include a plurality of ridges 76 and grooves
78 extending generally radially outward in a direction orthogonal to an axis of
rotation 16. Thus, the first SELF'ing intermeshing roller 72 can be similar to a TD
intermeshing roller 52, 54. The second SELF'ing intermeshing roller 74 can include
also include a plurality of ridges 80 and grooves 82 extending generally radially
outward in a direction orthogonal to an axis of rotation 20. As shown by Fig. 7;
however, the ridges 80 of the second SELF'ing intermeshing roller 74 can include a
plurality of notches 84 that define a plurality of spaced teeth 86.
Referring now to Fig. 8, an incrementally-stretched film lOf with
visually-distinct stretched regions created using the SELF'ing intermeshing rollers 72,
74 is shown. In particular, as the film passes through the SELF'ing intermeshing
rollers 72, 74, the teeth 86 can press a portion of the web out of plane to cause
permanent, deformation of a portion of the film in the Z-direction. On the other hand
the portions of the film that pass between the notched regions 84 and the teeth 86 will
be substantially unformed in the Z-direction, resulting in a plurality of deformed,
raised, rib-like elements 88.
As shown by Fig. 8, the strainable network of the incrementally-
stretched film lOf with visually-distinct stretched regions can include first un-
stretched regions 44d, second un-stretched regions 44e, and stretched transitional
regions 46e connecting the first and second un-stretched regions 44d, 44e. The
second un-stretched regions 44e and the stretched regions 46e can form the raised rib
like elements 88 of the strainable network.
Fig. 8 illustrates that the stretched regions 46e can be visually distinct
from the un-stretched regions 44d, 44e. In particular, stretched regions 46e can be
white and opaque. The stretched regions 46e can be discontinuous or be separated as
they extend across the film lOf in both transverse and machine directions. This is in
contrast to stripes that extend continuously across a film in one of the machine and
transverse directions.
The rib-like elements 88 can allow the film lOf to undergo a
substantially "geometric deformation" prior to a "molecular-level deformation." As
used herein, the term "molecular-level deformation" refers to deformation which
occurs on a molecular level and is not discernible to the normal naked eye. That is,
even though one may be able to discern the effect of molecular-level deformation,
e.g., elongation of the film, one is not able to discern the deformation which allows or
causes it to happen. This is in contrast to the term "geometric deformation." As used
herein, the term "geometric deformation" refers to deformations of the film lOf which
are generally discernible to the normal naked eye when the film lOf or articles
embodying the film lOf are subjected to an applied strain. Types of geometric
deformation include, but are not limited to bending, unfolding, and rotating.
Thus, upon an applied strain, the rib-like elements 88 can undergo
geometric deformation before either the rib-like elements 88 or the flat regions
undergo molecular-level deformation. For example, an applied strain can pull the rib
like elements 88 back into plane with the flat regions prior to any molecular-level
deformation of the film lOf. Geometric deformation can result in significantly less
resistive forces to an applied strain than that exhibited by molecular-level
deformation.
Thus, the strainable network of the film lOf may provide improved
properties to the film lOf, such as elasticity, improved tear, and improved impact
properties. The visually-distinct stretched regions 46e can provide notice to a
consumer that the film lOf includes the improved properties provided by the
strainable network. Additionally, the opacity of the visually-distinct stretched regions
46e can provide a look or feel of increased thickness and strength.
One will appreciate in light of the disclosure herein that the pattern of
the strainable network of Fig. 8 is only one pattern suitable for use with the present
invention. For example, Fig. 9 illustrates another strainable network pattern that can
include visually-distinct stretched regions. In particular, Fig. 9 illustrates an
incrementally-stretched film lOg with a strainable network of rib-like elements 88a
arranged in diamond patterns. The strainable network of the incrementally-stretched
film lOg with visually-distinct stretched regions can include first un-stretched regions
44d, second un-stretched regions 44e, and stretched transitional regions 46e
connecting the first and second un-stretched regions 44d, 44e. The stretched regions
46e can be visually distinct from the un-stretched regions 44d, 44e. In particular,
stretched regions 46e can be white and opaque.
One or more implementations of the present invention can include
strainable network patterns other than those shown by Figs. 8 and 9, or combinations
of various patterns. It should be understood that the term "pattern" is intended to
include continuous or discontinuous sections of patterns, such as may result, for
example, from the intersection of first and second patterns with each other.
Furthermore, the patterns can be aligned in columns and rows aligned in the machine
direction, the transverse direction, or neither the machine or transverse directions.
One will appreciate in light of the disclosure herein that the
incrementally-stretched films with visually-distinct stretched regions can form part of
any type of product made from, or incorporating, thermoplastic films. For instance,
grocery bags, trash bags, sacks, packaging materials, feminine hygiene products, baby
diapers, adult incontinence products, sanitary napkins, bandages, food storage bags,
food storage containers, thermal heat wraps, facial masks, wipes, hard surface
cleaners, and many other products can include incrementally-stretched with visually-
distinct stretched regions to one extent or another. Trash bags and food storage bags
may be particularly benefited by the films of the present invention.
Referring to Fig. 10, in a particular implementation of the present
invention, the incrementally-stretched film 10b illustrated in Fig. 2 may be
incorporated in a bag construction, such as a flexible draw tape bag. The bag 90 can
include a bag body 92 formed from a piece of incrementally-stretched film 10b folded
upon itself along a bag bottom 94. Side seams 96 and 98 can bond the sides of the
bag body 92 together to form a semi-enclosed container having an opening 100 along
an upper edge 102. The bag 90 also optionally includes closure means 104 located
adjacent to the upper edge 102 for sealing the top of the bag 90 to form a fully-
enclosed container or vessel. The bag 90 is suitable for containing and protecting a
wide variety of materials and/or objects. The closure means 104 can comprise flaps,
adhesive tapes, a tuck and fold closure, an interlocking closure, a slider closure, a
zipper closure or other closure structures known to those skilled in the art for closing
a bag.
As shown, the sides of the bag body 92 can include un-stretched
regions 44 and stretched regions 46 in the form of stripes. The stretched regions 46
can be visually distinct from the un-stretched regions 44. In particular, the stretched
regions 46 can be white and opaque. The stripes can extend across the bag 90 in the
TD direction, or in other words, from the bag bottom 94 to the upper edge 102. The
bag 90 can require less material to form than an identical bag formed with an un-
stretched film 10a of the same thermoplastic material. Additionally, despite requiring
less material, the bag 90 can include improved properties imparted by MD ring
rolling. The visually-distinct stretched regions 46 can serve to notify a consumer of
the improved properties. Furthermore, while the bag body 92 can include opaque
regions created by voiding agents, the bag body 92 can be non porous. Thus, the bag
body 92 can prevent liquids, and at least substantially prevent gases, from passing
there through.
Fig. 11 illustrates a tie bag 106 incorporating an incrementally-
stretched film with visually-distinct stretched regions in accordance with an
implementation of the present invention. As shown the sides of the tie bag 106 can
include a pattern of un-stretched regions 44f and stretched regions 46f, 46g created by
MD and TD ring rolling. The stretched regions 46f, 46g can be visually distinct from
the un-stretched regions 44f. In particular, stretched regions 46f, 46g can be white
and opaque.
The visually-distinct stretched regions can include stripes 46f that
extend across the bag 106 in the machine direction. Additionally, visually-distinct
stretched regions can include stripes 46g that extend across the bag 106 in the
transverse direction, or in other words from the bag bottom 108 to flaps 110 of an
upper edge 112 of the bag 106.
In comparison with the film lOd of Fig. 5, the spacing between the MD
extending stripes 46f is greater in the bag 106. This effect is created by using MD
ring rolls having a greater pitch between ridges. Similarly, the spacing of the TD
extending stripes 46g is greater in the bag 106 than the film lOd. This effect is
created by using TD ring rolls having a greater pitch between ridges. Furthermore,
the relative spacing between the MD extending stripes and the TD extending stripes
differs in the bag 106, while relative spacing is the same in the film lOd. This effect
is created by using TD ring rolls having a greater pitch between ridges compared to
the pitch between ridges of the MD ring rolls. One will appreciate in light of the
disclosure herein that the use of intermeshing rollers with greater or varied ridge pitch
can provide the different spacing and thicknesses of the stripes. Thus, one will
appreciate in light of the disclosure herein that a manufacturer can vary the ridge pitch
of the intermeshing rollers to vary the pattern of the visually-distinct stretched
regions, and thus, the aesthetic and/or properties of the bag or film.
In addition to the varying the pattern of visually-distinct stretched
regions in a bag or film, one or more implementations also include providing visually-
distinct stretched regions in certain sections of a bag or film, and only un-stretched
regions in other sections of the bag or film. For example, Fig. 1 illustrates a bag 114
having an upper section 116 adjacent a top edge 118 that is devoid of visually-distinct
stretched regions. Similarly, the bag 114 includes a bottom section 120 adjacent a
bottom fold or edge 122 devoid of visually-distinct stretched regions. In other words,
both the top section 116 and bottom section 120 of the bag 114 can each comprise un-
stretched regions.
A middle section 124 of the bag 114 between the upper and lower
sections 116, 120 on the other hand can include visually-distinct stretched regions. In
particular, Fig. 12 illustrates that the middle section can include a strainable network
of rib-like elements arranged in diamond patterns similar to the film lOe of Fig. 9.
Thus, the middle section 124 of the bag 114 can include improved properties, such as
elasticity and impact resistance, created by the strainable network. Furthermore, the
white and opaque stretched regions (i.e., the stretched transitional regions of the rib
like elements) can serve to notify a consumer of that the middle section 124 includes
improved properties.
In one or more additional implementations, the present invention
includes providing different visually-distinct stretched regions in different sections of
a bag or film. For example, Fig. 13 illustrates a bag 114a similar to the bag 114 of
Fig. 12, albeit that the bottom section 120a includes alternating series of un-stretched
regions 44a and stretched regions 46a created by TD ring rolling. Thus, the middle
section 124 of the bag 114 can include one set of improved properties created by the
strainable network, and the bottom section 120a can include another set of improved
properties created by TD ring rolling. Furthermore, the white and opaque stretched
regions can serve to notify a consumer of the different properties of the middle section
124 and the bottom section 120a.
Fig. 14 illustrates yet another bag 126 including having an upper
section 116a adjacent a top edge 118 that includes alternating series of un-stretched
regions 44b and visually-distinct stretched regions 46b, 46c created by MD and TD
ring rolling similar to the film lOd of Fig. 5. Furthermore, the middle section 124a of
the bag 126 can include un-stretched regions 44 and stretched regions 46 in the form
of stripes created by MD ring rolling. The stretched regions 46 can be visually
distinct from the un-stretched regions 44. In particular, stretched regions 46 can be
white and opaque.
Thus, one will appreciate in light of the disclosure herein that a
manufacturer can tailor specific sections or zones of a bag or film with desirable
properties by MD, TD, or DD ring rolling, SELF'ing, or a combination thereof.
Furthermore, the different visually-distinct stretched regions can serve to notify a
consumer of the properties of the different sections. One will appreciate in light of
the disclosure herein that the visually-distinct stretched regions can be more visually
discernable than any geometric deformation alone.
Fig. 15 illustrates an exemplary embodiment of a high-speed
manufacturing process 128 for incrementally stretching a thermoplastic film to
produce visually-distinct stretched regions and produce a plastic bag there from.
According to the process 128, an un-stretched thermoplastic film 10 including a
thermoplastic material and a voiding agent is unwound from a roll 130 and directed
along a machine direction.
The un-stretched film 10 can pass between first and second cylindrical
intermeshing rollers 134, 136 to incrementally stretch the un-stretched film 10 to
create un-stretched regions and visually-distinct stretched regions in at least one
section of the film. The intermeshing rollers 134, 136 can have a construction similar
to that of intermeshing rollers 12, 14 of Figs. 1A-1B, or any of the other intermeshing
rollers shown or described herein. The rollers 134, 136 may be arranged so that their
longitudinal axes are perpendicular to the machine direction. Additionally, the rollers
134, 136 may rotate about their longitudinal axes in opposite rotational directions. In
various embodiments, motors may be provided that power rotation of the rollers 134,
136 in a controlled manner. As the un-stretched film 10 passes between the first and
second rollers 134, 136, the ridges and/or teeth of the intermeshing rollers 134, 136
can form an incrementally-stretched film 138 with visually-distinct stretched regions.
During the manufacturing process 128, the incrementally-stretched
film 138 can also pass through a pair of pinch rollers 140, 142. The pinch rollers 140,
142 can be appropriately arranged to grasp the incrementally-stretched film 138 with
visually-distinct stretched regions. The pinch rollers 140, 142 may facilitate and
accommodate the incrementally-stretched film 138 with visually-distinct stretched
regions.
A folding operation 144 can fold the incrementally-stretched film 138
with visually-distinct stretched regions to produce the sidewalls of the finished bag.
The folding operation 144 can fold the incrementally-stretched film 138 with visually-
distinct stretched regions in half along the transverse direction. In particular, the
folding operation 144 can move a first edge 148 adjacent to the second edge 150,
thereby creating a folded edge 152. The folding operation 144 thereby provides a first
film half 154 and an adjacent second web half 156. The overall width 158 of the
second film half 156 can be half the width 158 of the pre-folded incrementally-
stretched film 138 with visually-distinct stretched regions.
To produce the finished bag, the processing equipment may further
process the folded incrementally-stretched film 138 with visually-distinct stretched
regions. In particular, a draw tape operation 160 can insert a draw tape 162 into the
incrementally- stretched film 138 with visually-distinct stretched regions.
Furthermore, a sealing operation 164 can form the parallel side edges of the finished
bag by forming heat seals 166 between adjacent portions of the folded incrementally-
stretched film 138 with visually-distinct stretched regions. The heat seals 166 may be
spaced apart along the folded incrementally- stretched film 138 with visually-distinct
stretched regions. The sealing operation 164 can form the heat seals 166 using a
heating device, such as, a heated knife.
A perforating operation 168 may form a perforation 170 in the heat
seals 166 using a perforating device, such as, a perforating knife. The perforations
170 in conjunction with the folded outer edge 152 can define individual bags 172 that
may be separated from the incrementally- stretched film 138. A roll 174 can wind the
incrementally-stretched film 138 with visually-distinct stretched regions embodying
the finished bags 172 for packaging and distribution. For example, the roll 174 may
be placed into a box or bag for sale to a customer.
In still further implementations, the folded incrementally-stretched film
138 may be cut into individual bags along the heat seals 166 by a cutting operation.
In another implementation, the folded incrementally-stretched film 138 with visually-
distinct stretched regions may be folded one or more times prior to the cutting
operation. In yet another implementation, the side sealing operation 164 may be
combined with the cutting and/or perforation operations 168.
One will appreciate in light of the disclosure herein that the process
128 described in relation to Fig. 15 can be modified to omit or expanded acts, or vary
the order of the various acts as desired. For example, Fig. 16 illustrates another
manufacturing process 176 for producing a plastic bag having visually-distinct
stretched regions imparted therein. The process 176 can be similar to process 128 of
Fig. 15, except that the un-stretched film 10 is stretched by intermeshing rollers 134,
136 after the folding operation 144 has folded the un-stretched film 10 in half.
Fig. 17 illustrates yet another manufacturing process 178 for producing
a plastic bag having visually-distinct stretched regions imparted therein. The process
178 can be similar to process 128 of Fig. 15, except that the un-stretched film 10 is
folded prior to winding it on the roll 130a. Thus, in such implementations, the un-
stretched film 10 unwound from the roll 130a is already folded. Additionally, the
manufacturing process 178 illustrates that after passing through intermeshing rollers
134, 136, the film can pass through another set of intermeshing rollers 180, 182 to
impart a second pattern of visually-distinct stretched regions to one or more sections
of the film. The intermeshing rollers 180, 182 can have a construction similar to that
of intermeshing rollers 52, 54 of Fig. 3, or any of the other intermeshing rollers shown
or described herein.
Implementations of the present invention can also include methods of
incrementally stretching a film of thermoplastic material to produce visually-distinct
stretched regions. The following describes at least one implementation of a method
with reference to the components and diagrams of Figs. 1A through 17. Of course, as
a preliminary matter, one of ordinary skill in the art will recognize that the methods
explained in detail herein can be modified to install a wide variety of configurations
using one or more components of the present invention. For example, various acts of
the method described can be omitted or expanded, and the order of the various acts of
the method described can be altered as desired.
For example, one method in accordance with one or more
implementations of the present invention can include providing a film. For example,
the method can involve providing a film comprising between about 65 and about 99
percent by weight of a thermoplastic material, and between about 1 and about 35
percent by weight of a voiding agent. In particular, the method can involve extruding
a film 10 and directing the film 10 into a high speed manufacturing system.
The method can also include cold stretching the film 10 incrementally
to create stretched regions that are white, opaque, and non-porous. In one or more
implementations this can involve imparting a pattern 36 of un-stretched regions 44
and stretched regions 46 that are visually distinct from un-stretched regions 44. For
example, the method can involve MD ring rolling the film, TD ring rolling the film,
DD ring rolling the film, SELF'ing the film, or a combination thereof. More
specifically, the method can involve passing the film 10 through intermeshing rollers.
As the film 10 passes through the intermeshing rollers, ridges can impart the pattern
36 into the film and incrementally stretch the film 10.
The present invention may be embodied in other specific forms
without departing from its spirit or essential characteristics. The described
embodiments are to be considered in all respects only as illustrative and not
restrictive. The scope of the invention is, therefore, indicated by the appended claims
rather than by the foregoing description. All changes that come within the meaning
and range of equivalency of the claims are to be embraced within their scope.
Claims (9)
1. An incrementally-stretched film with visually-distinct stretched regions, comprising: thermoplastic material comprising linear low density polyethylene and a voiding agent, the voiding agent being between 5 and 25 percent by weight of the film; a first plurality of un-stretched regions; and a second plurality of cold-stretched regions intermittently dispersed about the first plurality of un-stretched regions; wherein the cold-stretched regions are: non-porous, and more opaque than the un-stretched regions.
2. The film as recited in claim 1, wherein the film comprises between 65 and 99 percent by weight of the thermoplastic material, and between 5 and 20 percent by weight of the voiding agent.
3. The film as recited in claim 2, wherein the voiding agent comprises calcium carbonate.
4. The film as recited in claim 2, wherein the voiding agent comprises 15 percent by weight of the film.
5. The film as recited in claim 1, wherein a color of the cold-stretched regions differs from a color of the un-stretched regions.
6. The film as recited in claim 1, wherein an average thickness of the cold-stretched regions is less than an average thickness of the un-stretched regions.
7. The film as recited in claim 1, wherein the cold-stretched regions comprise one or more 206441NZ_ claims_20150716_PLH stripes extending along the film in a direction transverse to a direction in which the film was extruded; stripes extending along the film in a direction in which the film was extruded; or discontinuous strainable networks extending in a direction transverse to direction in which the film was extruded.
8. The film as recited in claim 7, wherein the cold-stretched regions comprise: stripes extending along the film in a direction in which the film was extruded; and stripes extending along the film in a direction transverse to a direction in which the film was extruded.
9. The film as recited in claim 1, wherein the cold-stretched regions comprise discontinuous strainable networks arranged in diamond patterns. 206441NZ_ claims_20150716_PLH
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161478639P | 2011-04-25 | 2011-04-25 | |
US61/478,639 | 2011-04-25 | ||
PCT/US2012/034817 WO2012148916A1 (en) | 2011-04-25 | 2012-04-24 | Thermoplastic films with visually-distinct stretched regions and methods for making the same |
US13/454,412 US9381697B2 (en) | 2011-04-25 | 2012-04-24 | Thermoplastic films with visually-distinct stretched regions and methods for making the same |
US13/454,412 | 2012-04-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
NZ616346A NZ616346A (en) | 2015-08-28 |
NZ616346B2 true NZ616346B2 (en) | 2015-12-01 |
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