MXPA04000123A - Procedimiento de preparacion de hidrocarburos liquidos. - Google Patents
Procedimiento de preparacion de hidrocarburos liquidos.Info
- Publication number
- MXPA04000123A MXPA04000123A MXPA04000123A MXPA04000123A MXPA04000123A MX PA04000123 A MXPA04000123 A MX PA04000123A MX PA04000123 A MXPA04000123 A MX PA04000123A MX PA04000123 A MXPA04000123 A MX PA04000123A MX PA04000123 A MXPA04000123 A MX PA04000123A
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst particles
- slurry
- synthesis gas
- solid catalyst
- filtration medium
- Prior art date
Links
- 239000007788 liquid Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 5
- 229930195733 hydrocarbon Natural products 0.000 title abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 3
- 238000001914 filtration Methods 0.000 abstract 5
- 239000002245 particle Substances 0.000 abstract 5
- 239000002002 slurry Substances 0.000 abstract 4
- 230000015572 biosynthetic process Effects 0.000 abstract 3
- 239000011949 solid catalyst Substances 0.000 abstract 3
- 238000003786 synthesis reaction Methods 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000011344 liquid material Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invencion se refiere a un proceso de preparacion de hidrocarburos liquidos que comprende el contacto del gas de sintesis con un escurrido de particulas de catalizador solidas y un liquido en un recipiente del reactor mediante la introduccion del gas de sintesis en un nivel bajo en el escurrido, en condiciones adecuadas para la conversion del gas de sintesis en hidrocarburos liquidos, las particulas de catalizador solidas comprenden un metal cataliticamente activo seleccionado de cobalto o hierro sobre un transportador oxido refractario poroso, preferiblemente seleccionado de silice, aluminio, titania, zirconia o mezclas de los mismos, el catalizador se encuentra presente en una cantidad entre 10 y 40 por ciento en volumen basado en el volumen total de liquidos y solidos del escurrido, y separando el material liquido. de las particulas de catalizador solidas utilizando un sistema de filtracion que comprende un medio de filtracion asimetrico (el lado selectivo en el lado de escurrido), en donde el sistema de filtracion tiene una presion diferencial promedio sobre el medio de filtracion de al menos 0.1 bares, proceso en el cual la distribucion de tamano de particula es tal que al menos cierta cantidad de las particulas de catalizador es menor que el tamano promedio del poro de la lamina selectiva del medio de filtracion. La invencion tambien comprende un aparato para llevar a cabo el proceso anteriormente descrito.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30294701P | 2001-07-03 | 2001-07-03 | |
| PCT/EP2002/007534 WO2003004582A2 (en) | 2001-07-03 | 2002-07-03 | Process for the production of liquid hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA04000123A true MXPA04000123A (es) | 2004-05-21 |
Family
ID=23169930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA04000123A MXPA04000123A (es) | 2001-07-03 | 2002-07-03 | Procedimiento de preparacion de hidrocarburos liquidos. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7067559B2 (es) |
| EP (1) | EP1419216B1 (es) |
| CN (1) | CN1292045C (es) |
| AR (1) | AR034670A1 (es) |
| AU (1) | AU2002328852B2 (es) |
| CA (1) | CA2451746A1 (es) |
| DE (1) | DE60225148T2 (es) |
| EA (1) | EA005795B1 (es) |
| MX (1) | MXPA04000123A (es) |
| NO (1) | NO20040006L (es) |
| WO (1) | WO2003004582A2 (es) |
| ZA (1) | ZA200309943B (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003230924A1 (en) | 2002-04-16 | 2003-11-03 | Conocophillips Company | Solid/liquid separation system for multiphase converters |
| ITMI20030969A1 (it) * | 2003-05-15 | 2004-11-16 | Enitecnologie Spa | Procedimento per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida. |
| ITMI20031029A1 (it) | 2003-05-22 | 2004-11-23 | Enitecnologie Spa | Procedimenti per la produzione in continuo di idrocarburi da gas di sintesi. |
| ITMI20031288A1 (it) | 2003-06-25 | 2004-12-26 | Enitecnologie Spa | Processo per la produzione in continuo di idrocarburi da gas di sintesi in reattori a sospensione e per la separazione della fase liquida prodotta dalla fase solida. |
| US7378452B2 (en) * | 2005-12-28 | 2008-05-27 | Exxonmobil Research And Engineering Company | Filtration system for slurry hydrocarbon synthesis process using both small and large pore filter elements |
| DE102007056170A1 (de) * | 2006-12-28 | 2008-11-06 | Dominik Peus | Semikontinuierliches Verfahren zur Herstellung von Brennstoff aus Biomasse |
| US20080260631A1 (en) | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| WO2008146239A2 (en) * | 2007-05-28 | 2008-12-04 | The Petroleum Oil And Gas Corporation Of South Africa (Pty) Ltd | Removal of fine particles from a fischer tropsch stream |
| US9018128B2 (en) | 2007-09-14 | 2015-04-28 | Res Usa Llc | Promoted, attrition resistant, silica supported precipitated iron catalyst |
| US20100084350A1 (en) * | 2008-10-06 | 2010-04-08 | Jing Liu | Systems and Methods for Continuous Multiphase Reaction and Separation |
| US8022109B2 (en) * | 2008-12-23 | 2011-09-20 | Exxonmobil Research And Engineering Company | Product filtration system for slurry reactors |
| US9149781B2 (en) | 2009-12-28 | 2015-10-06 | Shell Oil Company | Reactor with gas distribution system in bottom |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3245318C3 (de) | 1982-12-08 | 1996-06-20 | Bayer Ag | Verfahren zur Durchführung von Druckreaktionen mit suspendierten Katalysatoren |
| US5324335A (en) | 1986-05-08 | 1994-06-28 | Rentech, Inc. | Process for the production of hydrocarbons |
| CA2038772C (en) | 1990-04-04 | 2001-12-25 | Eric Herbolzheimer | Catalyst fluidization improvements |
| GB9203958D0 (en) | 1992-02-25 | 1992-04-08 | Norske Stats Oljeselskap | Catalytic multi-phase reactor |
| CA2105940C (en) | 1992-10-05 | 2001-12-25 | Robert M. Koros | Bubble column, tube side slurry process and apparatus |
| NZ250750A (en) * | 1993-01-27 | 1995-02-24 | Sasol Chem Ind Pty | Reacting gases in a slurry bed which contains a filtration zone to separate liquid product |
| GB9301723D0 (en) | 1993-01-28 | 1993-03-17 | Norske Stats Oljeselskap | Solid/liquid treatment apparatus and catalytic multi-phase reactor |
| GB2281224B (en) | 1993-08-24 | 1998-02-11 | Norske Stats Oljeselskap | Solid/liquid slurry treatment apparatus and catalytic multi-phase reactor |
| NO953797L (no) * | 1995-09-25 | 1997-03-26 | Norske Stats Oljeselskap | Fremgangsmåte og anlegg for behandling av en brönnström som produseres fra et oljefelt til havs |
| US5600700A (en) | 1995-09-25 | 1997-02-04 | Vivid Technologies, Inc. | Detecting explosives or other contraband by employing transmitted and scattered X-rays |
| US5770629A (en) | 1997-05-16 | 1998-06-23 | Exxon Research & Engineering Company | Slurry hydrocarbon synthesis with external product filtration |
| US6344490B1 (en) * | 1999-01-22 | 2002-02-05 | Exxon Research And Engineering Company | Removable filter for slurry hydrocarbon synthesis process |
| EG22489A (en) | 1999-02-05 | 2003-02-26 | Sasol Technology | Process for producing liquid and optionally gaseous products from gaseous reactants |
-
2002
- 2002-07-01 AR ARP020102469A patent/AR034670A1/es not_active Application Discontinuation
- 2002-07-03 US US10/482,724 patent/US7067559B2/en not_active Expired - Fee Related
- 2002-07-03 CN CN02813434.6A patent/CN1292045C/zh not_active Expired - Fee Related
- 2002-07-03 EA EA200400136A patent/EA005795B1/ru not_active IP Right Cessation
- 2002-07-03 AU AU2002328852A patent/AU2002328852B2/en not_active Ceased
- 2002-07-03 MX MXPA04000123A patent/MXPA04000123A/es not_active Application Discontinuation
- 2002-07-03 WO PCT/EP2002/007534 patent/WO2003004582A2/en active IP Right Grant
- 2002-07-03 DE DE60225148T patent/DE60225148T2/de not_active Expired - Lifetime
- 2002-07-03 CA CA002451746A patent/CA2451746A1/en not_active Abandoned
- 2002-07-03 EP EP02764641A patent/EP1419216B1/en not_active Expired - Lifetime
-
2003
- 2003-12-23 ZA ZA200309943A patent/ZA200309943B/xx unknown
-
2004
- 2004-01-02 NO NO20040006A patent/NO20040006L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA200309943B (en) | 2004-05-24 |
| CN1292045C (zh) | 2006-12-27 |
| WO2003004582A2 (en) | 2003-01-16 |
| EA200400136A1 (ru) | 2004-06-24 |
| EP1419216A2 (en) | 2004-05-19 |
| US7067559B2 (en) | 2006-06-27 |
| EP1419216B1 (en) | 2008-02-20 |
| DE60225148D1 (de) | 2008-04-03 |
| CA2451746A1 (en) | 2003-01-16 |
| NO20040006L (no) | 2004-01-02 |
| EA005795B1 (ru) | 2005-06-30 |
| US20040235966A1 (en) | 2004-11-25 |
| CN1529744A (zh) | 2004-09-15 |
| WO2003004582A3 (en) | 2003-11-20 |
| AR034670A1 (es) | 2004-03-03 |
| AU2002328852B2 (en) | 2007-06-07 |
| DE60225148T2 (de) | 2009-03-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |