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MX2007009504A - Catalizador para la primera etapa de hidrodesmetalizacion en un sistema de hidro procesamiento con reactores multiples para el mejoramiento de crudos pesados y extra-pesados. - Google Patents

Catalizador para la primera etapa de hidrodesmetalizacion en un sistema de hidro procesamiento con reactores multiples para el mejoramiento de crudos pesados y extra-pesados.

Info

Publication number
MX2007009504A
MX2007009504A MX2007009504A MX2007009504A MX2007009504A MX 2007009504 A MX2007009504 A MX 2007009504A MX 2007009504 A MX2007009504 A MX 2007009504A MX 2007009504 A MX2007009504 A MX 2007009504A MX 2007009504 A MX2007009504 A MX 2007009504A
Authority
MX
Mexico
Prior art keywords
hydro
catalyst
demetallization
heavy
heavy crudes
Prior art date
Application number
MX2007009504A
Other languages
English (en)
Inventor
Patricia Rayo Mayoral
Jorge Ancheyta Juarez
Samir Kumar Maity
Mohan Singh
Original Assignee
Mexicano Inst Petrol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexicano Inst Petrol filed Critical Mexicano Inst Petrol
Priority to MX2007009504A priority Critical patent/MX2007009504A/es
Priority to US12/733,054 priority patent/US9133401B2/en
Priority to PCT/MX2008/000064 priority patent/WO2009022890A1/es
Publication of MX2007009504A publication Critical patent/MX2007009504A/es
Priority to US14/806,375 priority patent/US9901908B2/en

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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
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    • B01J23/85—Chromium, molybdenum or tungsten
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/85—Chromium, molybdenum or tungsten
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    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
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    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Nanotechnology (AREA)

Abstract

En el presente trabajo se discute sobre un catalizador mejorado para la hidrodesmetalización de crudos pesados y residuos. El catalizador se usa en unidades de hidroprocesamiento de lecho fijo. El catalizador se caracteriza por tener un diámetro de poro grande para la hidrodesmetalización de crudo pesado y residuo en el primer reactor de un procedo multi-reactores. El catalizador posee actividad alta en la desmetalización y alta capacidad de deposición de metales, lo que resulta en buena estabilidad respecto al tiempo de corrida (TOS). El catalizador de hidrorrefinación se obtiene amasando un material poroso en polvo compuesto principalmente de gamma-alúmina, esta pasta se extruye, los extrusados se secan y calcinan, las propiedades de estos extrusados son: un volumen de poro de 0.3-0.6 mL/g mayor y diámetro de poro medio de 10 a 26 nm, posteriormente se agregan componentes metálicos activos de elementos que pertenecen a los grupos VIIIB y VIB de la tabla periódica.
MX2007009504A 2007-08-07 2007-08-07 Catalizador para la primera etapa de hidrodesmetalizacion en un sistema de hidro procesamiento con reactores multiples para el mejoramiento de crudos pesados y extra-pesados. MX2007009504A (es)

Priority Applications (4)

Application Number Priority Date Filing Date Title
MX2007009504A MX2007009504A (es) 2007-08-07 2007-08-07 Catalizador para la primera etapa de hidrodesmetalizacion en un sistema de hidro procesamiento con reactores multiples para el mejoramiento de crudos pesados y extra-pesados.
US12/733,054 US9133401B2 (en) 2007-08-07 2008-05-26 Catalyst for the first hydrodemetalization step in a hydroprocessing system with multiple reactors for the improvement of heavy and extra heavy crudes
PCT/MX2008/000064 WO2009022890A1 (es) 2007-08-07 2008-05-26 Catalizador para la primera etapa de hidrodesmetalización en un sistema de hidroprocesamiento con reactores múltiples para el mejoramiento de crudos pesados y extra-pesados
US14/806,375 US9901908B2 (en) 2007-08-07 2015-07-22 Catalyst for the first hydrodemetalization step in a hydroprocessing system with multiple reactors for the improvement of heavy and extra heavy crudes

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US20100304963A1 (en) 2010-12-02
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WO2009022890A1 (es) 2009-02-19

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