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Looker et al., 1957 - Google Patents

Reduction of Methyl Benzoyldiazoacetate. A New Synthesis of Allophenylserine1

Looker et al., 1957

Document ID
1682784141645000234
Author
Looker J
THATCHER D
Publication year
Publication venue
The Journal of Organic Chemistry

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Snippet

The reaction of methyl diazoacetate (I) with benzoyl bromide (II) to give methyl benzoyldiazo- acetate (III) has long been known. 3 The present paper reports the results of an investigation which had as its principal objective the reductionof III to give either a phenylalanine or a ß …
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
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    • C07C45/41—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenolysis or reduction of carboxylic groups or functional derivatives thereof
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
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