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Jiménez Tenorio et al., 2000 - Google Patents

Alkyne Coupling Reactions Mediated by Tris (pyrazolyl) borate Ruthenium Vinylidene Complexes: X-Ray Crystal Structures of [TpRu C CHPh (PEt3) 2][BPh4] and …

Jiménez Tenorio et al., 2000

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Document ID
14884254637571339573
Author
Jiménez Tenorio M
Tenorio M
Puerta M
Valerga P
Publication year
Publication venue
Organometallics

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A series of cationic vinylidene complexes of the type [TpRu C CHR (PR3) 2][BPh4](Tp= hydrotris (pyrazolyl) borate; PR3= PEt3, PMeiPr2; R= Ph, But, COOMe) have been prepared. The reaction of [TpRu C CHCOOMe (PEt3) 2][BPh4] with a further HC⋮ CCOOMe molecule …
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • C07F17/02Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds

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