Torres et al., 1999 - Google Patents
Retention of optical activity during conversion of Λ-[Ru (1, 10-phenanthroline) 3] 2+ to Λ-[Ru (1, 10-phenanthroline-5, 6-dione) 3] 2+ and Λ-[Ru (dipyrido [a: 3, 2-h: 2 …Torres et al., 1999
- Document ID
- 11536156443881904936
- Author
- Torres A
- Maloney D
- Tate D
- Saad Y
- MacDonnell F
- Publication year
- Publication venue
- Inorganica chimica acta
External Links
Snippet
Complete retention of stereochemistry about the metal center is observed during the oxidation of Λ-[Ru (phen) 3] 2+ in sulfuric acid–nitric acid–bromide mixture to Λ-[Ru (phendione) 3] 2+(Λ-1) and subsequent conversion to Λ-[Ru (dppz) 3] 2+(Λ-2)(where dppz …
- 230000003287 optical 0 title abstract description 26
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
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