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BRILL et al., 1961 - Google Patents

Metal-Salt—Catalyzed Oxidation of Methacrolein

BRILL et al., 1961

Document ID
11305736686839507160
Author
BRILL W
LISTER F
Publication year
Publication venue
The Journal of Organic Chemistry

External Links

Snippet

The kinetics and products of the metal-salt-catalyzed oxidation of methacrolein and other unsaturated aldehydes in acetic acid were investigated. Methacrolein goes to peroxide, methacrylic acid, and, on extended oxidation, solublepoly-mer. At high aldehyde …
Continue reading at pubs.acs.org (other versions)

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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
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    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
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    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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