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Nikonov et al., 1997 - Google Patents

The carbenoid nature of halophosphines. Carbene-like insertion mechanism in the reaction of chlorophosphines with Cp2NbH3

Nikonov et al., 1997

Document ID
11166780704213876755
Author
Nikonov G
Grishin Y
Lemenovskii D
Kazennova N
Kuzmina L
Howard J
Publication year
Publication venue
Journal of organometallic chemistry

External Links

Snippet

We have studied the reactivity of Cp2NbH3 (1) with different chlorophosphines and showed that all the reactions occur at the niobium-hydride bond and proceed by two competitive routes, via the direct insertion of a chlorophosphine into the Nb H bond and electron or/and …
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
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