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Evariste et al., 2020 - Google Patents

Luminescent vapochromic single crystal to single crystal transition in one-dimensional coordination polymer featuring the first Cu (I) dimer bridged by an aqua ligand

Evariste et al., 2020

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Document ID
11099908581925552750
Author
Evariste S
Khalil A
Kerneis S
Xu C
Calvez G
Costuas K
Lescop C
Publication year
Publication venue
Inorganic Chemistry Frontiers

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Snippet

The reaction of the pre-assembled bimetallic Cu (I)[Cu2 (μ2-dppm) 2] 2+ fragment with the ligand 1, 4-dicyanobenzene B0 in non-distilled CH2Cl2 allowed the characterisation of an unexpected one-dimensional coordination polymer D, while no reaction occurred when dry …
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    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1044—Heterocyclic compounds characterised by ligands containing two nitrogen atoms as heteroatoms
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    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0033—Iridium compounds
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    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/18—Metal complexes
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    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
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    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
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    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds
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    • H01L51/0032—Selection of organic semiconducting materials, e.g. organic light sensitive or organic light emitting materials
    • H01L51/0077—Coordination compounds, e.g. porphyrin
    • H01L51/0084—Transition metal complexes, e.g. Ru(II)polypyridine complexes
    • H01L51/0085—Transition metal complexes, e.g. Ru(II)polypyridine complexes comprising Iridium
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    • H01L51/5012—Electroluminescent [EL] layer
    • H01L51/5016—Triplet emission

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