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Howson et al., 2011 - Google Patents

Origins of stereoselectivity in optically pure phenylethaniminopyridine tris-chelates M (NN′) 3 n+ (M= Mn, Fe, Co, Ni and Zn)

Howson et al., 2011

Document ID
10118115071853596960
Author
Howson S
Allan L
Chmel N
Clarkson G
Deeth R
Faulkner A
Simpson D
Scott P
Publication year
Publication venue
Dalton Transactions

External Links

Snippet

One-pot reactions of 2-pyridinecarboxaldehyde, chiral phenylethanamines and Fe (II) give single diastereomer facdiimine complexes at thermodynamic equilibrium so that no chiral separations are required (dr> 200: 1). The origins of this stereoselectivity are partly steric …
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    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
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    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/04—Nickel compounds
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