Chen et al., 2024 - Google Patents
The crystallization behavior of poly (d-lactic acid)/poly (l-lactic acid) asymmetric blends: effect of morphology of stereocomplex crystals on the formation of homochiral …Chen et al., 2024
- Document ID
- 9984911208787512001
- Author
- Chen W
- Zhong C
- Li S
- Wen D
- Zhou D
- Shao J
- Chen S
- Hou H
- Xiang S
- Publication year
- Publication venue
- Journal of Polymers and the Environment
External Links
Snippet
The blends of poly (D-lactic acid) and poly (L-lactic acid)(PDLA/PLLA) produce the stereocomplex crystals (SC) with a melting temperature of~ 250° C, which exhibits higher crystallization rate and mechanical strength than PDLA or PLLA. The SC was also reported …
- 238000002425 crystallisation 0 title abstract description 83
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/912—Polymers modified by chemical after-treatment derived from hydroxycarboxylic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR ARTIFICIAL THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR ARTIFICIAL THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/88—Post-polymerisation treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- D—TEXTILES; PAPER
- D01—NATURAL OR ARTIFICIAL THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Shi et al. | Influence of PLA stereocomplex crystals and thermal treatment temperature on the rheology and crystallization behavior of asymmetric poly (L-Lactide)/poly (D-lactide) blends | |
Zhang et al. | Enhanced heat deflection resistance via shear flow-induced stereocomplex crystallization of polylactide systems | |
Shao et al. | Modified PLA homochiral crystallites facilitated by the confinement of PLA stereocomplexes | |
Bai et al. | Low-temperature sintering of stereocomplex-type polylactide nascent powder: effect of crystallinity | |
Liu et al. | Suppression of phase separation for exclusive stereocomplex crystallization of a high-molecular-weight racemic poly (l-lactide)/poly (d-lactide) blend from the glassy state | |
Liao et al. | Electrospinning fabrication of partially crystalline bisphenol A polycarbonate nanofibers: Effects on conformation, crystallinity, and mechanical properties | |
He et al. | A promising strategy for fabricating high-performance stereocomplex-type polylactide products via carbon nanotubes-assisted low-temperature sintering | |
Feng et al. | The crystallization behavior of poly (L-lactic acid)/poly (D-lactic acid) electrospun fibers: effect of distance of isomeric polymers | |
Li et al. | Non-isothermal crystallization of p (3hb-co-4hb)/pla blends: Crystallization kinetic, melting behavior and crystal morphology | |
Maleki et al. | Improvement of physical and mechanical properties of electrospun poly (lactic acid) nanofibrous structures | |
Xing et al. | Tailoring crystallization behavior of poly (L-lactide) with a low molecular weight aliphatic amide | |
Jing et al. | Rheology and crystallization behavior of asymmetric PLLA/PDLA blends based on linear PLLA and PDLA with different structures | |
Bai et al. | Low-temperature sintering of stereocomplex-type polylactide nascent powder: the role of poly (methyl methacrylate) in tailoring the interfacial crystallization between powder particles | |
Jing et al. | Investigation of poly (lactide) stereocomplexation between linear poly (l‐lactide) and PDLA‐PEG‐PDLA tri‐block copolymer | |
Chen et al. | The crystallization behavior of poly (d-lactic acid)/poly (l-lactic acid) asymmetric blends: effect of morphology of stereocomplex crystals on the formation of homochiral crystals | |
Chen et al. | Unusual Radiating-Stripe Morphology in Nonequimolar Mixtures of Poly (l-lactic acid) with Poly (d-lactic acid) | |
Wang et al. | A well-defined biodegradable 1, 2, 3-triazolium-functionalized PEG-b-PCL block copolymer: facile synthesis and its compatibilization for PLA/PCL blends | |
Huang et al. | Fabrication of melt-spun fibers from irradiation modified biocompatible PLA/PCL blends | |
Su et al. | High performance polylactic acid/thermoplastic polyurethane blends with in‐situ fibrillated morphology | |
Uehara et al. | Stereo-complex crystallization of poly (lactic acid) s in block-copolymer phase separation | |
Li et al. | Enabling electrospinning of medium-chain length polyhydroxyalkanoates (PHAs) by blending with short-chain length PHAs | |
Zhang et al. | Exclusive formation of poly (lactide) stereocomplexes with enhanced melt stability via regenerated cellulose assisted Pickering emulsion approach | |
Zhao et al. | Enhanced stereocomplex crystalline polylactic acids in melt processed enantiomeric bicomponent fiber configurations | |
Wu et al. | Banded spherulites of electrospun poly (trimethylene terephthalate)/carbon nanotube composite mats | |
Yan et al. | Biodegradable blends of poly (butylene succinate-co-terephthalate) and stereocomplex polylactide with enhanced rheological, mechanical properties, heat resistance and hydrolytic degradation |