Dettenrieder et al., 2014 - Google Patents
Half-sandwich rare-earth-metal alkylaluminate complexes bearing peripheral boryl ligandsDettenrieder et al., 2014
- Document ID
- 7436865678047884165
- Author
- Dettenrieder N
- Hollfelder C
- Jende L
- Maichle-Mossmer C
- Anwander R
- Publication year
- Publication venue
- Organometallics
External Links
Snippet
[(C5Me5) LnMe2] 3 (Ln= Y, Lu) dissolve readily in an-hexane/toluene mixture upon addition of 3 equiv of the organoaluminum boryl compound [Me2Al {B (NDippCH) 2}] 2 (Dipp= C6H3 i Pr2-2, 6). The half-sandwich complexes (C5Me5) Ln [(AlMe3){B (NDippCH) 2}] 2 thus …
- 239000003446 ligand 0 title description 146
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/02—Boron compounds
- C07F5/025—Boronic and borinic acid compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
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