Katayama et al., 2002 - Google Patents
Effect of Substituents on the Formation of Vinylideneruthenium (II) Complexes. X-ray Structures of RuCl2 {CC (Z) Ph}(dcpmp)(Z= H, SiMe3; dcpmp= C5H3N (CH2PCy2 …Katayama et al., 2002
- Document ID
- 7245179610055208647
- Author
- Katayama H
- Wada C
- Taniguchi K
- Ozawa F
- Publication year
- Publication venue
- Organometallics
External Links
Snippet
Kinetic studies have been carried out for the formation of vinylideneruthenium (II) complexes RuCl2 {CC (Z) R}(dcpmp)[Z= H, R= p-MeOC6H4 (2a), p-MeC6H4 (2b), Ph (2c), p-BrC6H4 (2d), t-Bu (2e), ferrocenyl (2f); Z= SiMe3, R= Ph (5a), SiMe3 (5b); dcpmp= 2, 6-bis …
- 230000015572 biosynthetic process 0 title abstract description 55
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Katayama et al. | Convenient Routes to Vinylideneruthenium Dichlorides with Basic and Bulky Tertiary Phosphine Ligands (PPr i 3 and PCy3) | |
Katayama et al. | Effect of Substituents on the Formation of Vinylideneruthenium (II) Complexes. X-ray Structures of RuCl2 {CC (Z) Ph}(dcpmp)(Z= H, SiMe3; dcpmp= C5H3N (CH2PCy2) 2) | |
Göttker-Schnetmann et al. | Synthesis and properties of iridium bis (phosphinite) pincer complexes (p-XPCP) IrH2,(p-XPCP) Ir (CO),(p-XPCP) Ir (H)(aryl), and {(p-XPCP) Ir} 2 {μ-N2} and their relevance in alkane transfer dehydrogenation | |
Hermann et al. | Synthesis, Structure, and Reactivity of New Rhodium and Iridium Complexes, Bearing a Highly Electron-Donating PNP System. Iridium-Mediated Vinylic C− H Bond Activation | |
Rybtchinski et al. | Unexpected isomerization of a cis-into a trans-dihydride complex. A neutral late transition metal complex as a hydride donor | |
Hung et al. | Osmabenzenes from the reactions of a dicationic osmabenzyne complex | |
Sangtrirutnugul et al. | Silyl derivatives of [bis (8-quinolyl) methylsilyl] iridium (III) complexes: catalytic redistribution of arylsilanes and dehydrogenative arene silylation | |
Sutter et al. | Versatile N, C, N Coordination Behavior of a Monoanionic Aryldiamine Ligand in Ruthenium (II) Complexes: Syntheses and Crystal Structures of [RuII {C6H3 (CH2NMe2) 2-2, 6} X (L)](L= Norbornadiene, X= Cl, SO3CF3; L= PPh3, X= I) and [RuII {C6H3 (CH2NMe2) 2-2, 6}(2, 2 ‘: 6 ‘, 2 ‘‘-terpyridine)] Cl | |
Rüba et al. | [RuCp (PR3)(CH3CN) 2] PF6 (R= Ph, Me, Cy). Convenient Precursors for Mixed Ruthenium (II) and Ruthenium (IV) Half-Sandwich Complexes | |
Amoroso et al. | Deactivation of ruthenium metathesis catalysts via facile formation of face-bridged dimers | |
Esteruelas et al. | The Dihydride− Osmium (IV) Complex [OsH2 (κ 2-O2CCH3)(H2O)(PiPr3) 2] BF4 as a Precursor for Carbon− Carbon Coupling Reactions | |
Szadkowska et al. | Latent thermo-switchable olefin metathesis initiators bearing a pyridyl-functionalized chelating carbene: Influence of the leaving group’s rigidity on the catalyst’s performance | |
Horak et al. | Tuning of Metal Complex Electronics and Reactivity by Remote Lewis Acid Binding to π-Coordinated Pyridine Diphosphine Ligands | |
Huang et al. | A 14-Electron Ruthenium (II) Hydride,[RuH (CO)(PtBu2Me) 2] BAr ‘4 (Ar ‘= 3, 5-(C6H3)(CF3) 2): Synthesis, Structure, and Reactivity toward Alkenes and Oxygen Ligands | |
Hu et al. | Constructing a catalytic cycle for C–F to C–X (X= O, S, N) bond transformation based on gold-mediated ligand nucleophilic attack | |
Tagge et al. | Synthesis, X-ray Structure Determination, and Reactions of (Pentamethylcyclopentadienyl)(nitrosyl) ruthenium η2-Arene Complexes | |
Fernandez et al. | Functionalized N-heterocyclic carbene nonspectator ligands upon internal alkyne activation reactions | |
Bennett et al. | Ligand-Induced ring slippage of η6-to η4-Naphthalene. Preparation and structural characterization of Ru (η4-C10H8)(η4-1, 5-C8H12)(L)[L= PMe3, PEt3, P (OMe) 3] and of derived binuclear complexes containing bridging naphthalene, Ru2 (μ-η6: η4-C10H8)(η4-1, 5-C8H12) 2 (L)[L= PEt3, P (OMe) 3] | |
Mauthner et al. | Synthesis and Reactivity of RuCp*(κ2 (P, N)-Ph2PCH2CH2NMe2) Cl. Chelate-Assisted Methyl C− H Activation and Formation of the Novel Complex [RuCp*(κ3 (P, N, C)-Ph2PCH2CH2N (CH2) Me) Cl] BPh4 | |
Nemeh et al. | Iridium Chemistry of 1, 6-Bis ((tert-butylphosphino) methyl)-1, 3, 5-cycloheptatriene | |
Matthes et al. | Ortho-metalated ruthenium hydrido dihydrogen complexes: Dynamics, exchange couplings, and reactivity | |
Palacios et al. | Synthesis of a square-planar rhodium alkylidene N-heterocyclic carbene complex and its reactivity toward alkenes | |
Hyder et al. | Nucleophilic Addition Reactions to Allenylidene Complexes of Ruthenium Bearing Hemilabile P, N Ligands: Isolation of the Vinylcarbene Complex [Cp* Ru CHCH CPh2 (iPr2PNHPy)][PF6] | |
Bott et al. | Acetylide Participation in Ligand Substitution and P− C Bond Cleavage in the Reaction between HRu3 (CO) 9 (μ3, η2, η2, η1-C⋮ CPh) and 4, 5-Bis (diphenylphosphino)-4-cyclopenten-1, 3-dione (bpcd). Syntheses and X-ray Structures of HRu3 (CO) 7 [μ3, η2, η2, η1, η1, η1-Ph2PC CC (O) CH2C (O) PPh2C CPh] and Ru3 (CO) 7 (μ, η2, η1-PhC CHPh)[μ2, η2, η1-PPhC CC (O) CH2C (O) PPh2] | |
Mai et al. | Half-Sandwich Silane σ-Complexes of Ruthenium Supported by NHC Carbene |