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Rosenfield et al., 1986 - Google Patents

Convenient synthesis and properties of (R4N) 2 [Ni (SAr) 4](Ar= C6H5, p-C6H4Cl, p-C6H4CH3, and m-C6H4Cl) and the structure of tetraethylammonium tetrakis (p …

Rosenfield et al., 1986

Document ID
5623629754871081322
Author
Rosenfield S
Armstrong W
Mascharak P
Publication year
Publication venue
Inorganic Chemistry

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Snippet

Reaction of (Et4N) 2NiCl4 and (R4N)(SAr)(Ar= C6H5, p-C6H4Cl, m-C6H4Cl, p-C6H4CH3) in acetonitrile affords (R4N) 2-[Ni (SAr) 4] in high yield. Syntheses of soluble nickel thiolates are not possible in protic solvents, where only insoluble polymeric materials are …
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    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/04Nickel compounds
    • C07F15/045Nickel compounds without a metal-carbon linkage
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    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
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