Nothing Special   »   [go: up one dir, main page]

Ibáñez et al., 2016 - Google Patents

Ferrocenyl-imidazolylidene ligand for redox-switchable gold-based catalysis. A detailed study on the redox-switching abilities of the ligand

Ibáñez et al., 2016

View PDF
Document ID
4801888730719994557
Author
Ibáñez S
Poyatos M
Dawe L
Gusev D
Peris E
Publication year
Publication venue
Organometallics

External Links

Snippet

An imidazolium salt with a fused benzoferrocenyl was synthesized. This compound was used as an N-heterocyclic carbene (NHC) precursor, and the related ferrocenyl- imidazolylidene complexes Fc-NHC-MLn (MLn= IrCl (COD), IrCl (CO) 2, AuCl) were …
Continue reading at www.researchgate.net (PDF) (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System

Similar Documents

Publication Publication Date Title
Ibáñez et al. Ferrocenyl-imidazolylidene ligand for redox-switchable gold-based catalysis. A detailed study on the redox-switching abilities of the ligand
Peris Smart N-heterocyclic carbene ligands in catalysis
Roy et al. Cyclic alkyl (amino) carbene stabilized complexes with low coordinate metals of enduring nature
McGuinness et al. Oxidative addition of the imidazolium cation to zerovalent Ni, Pd, and Pt: A combined density functional and experimental study
Dobereiner et al. Iridium-catalyzed hydrogenation of N-heterocyclic compounds under mild conditions by an outer-sphere pathway
Huynh et al. Palladium (II) Complexes of a Sterically Bulky, Benzannulated N-Heterocyclic Carbene with Unusual Intramolecular C− H⊙⊙⊙ Pd and Ccarbene⊙⊙⊙ Br Interactions and Their Catalytic Activities
Kaufhold et al. Metal template controlled formation of [11] ane-P2CNHC macrocycles
Türkmen et al. Annulated N-heterocyclic carbene ligands derived from 2-methylaminopiperidine: Their complexes and catalytic applications
Li et al. Cobalt POCOP Pincer Complexes via Ligand C–H Bond Activation with Co2 (CO) 8: Catalytic Activity for Hydrosilylation of Aldehydes in an Open vs a Closed System
Dash et al. Highly convenient regioselective intermolecular hydroamination of alkynes yielding ketimines catalyzed by gold (I) complexes of 1, 2, 4-triazole based N-heterocyclic carbenes
Teng et al. Determining the electron-donating properties of bidentate ligands by 13C NMR spectroscopy
Donnelly et al. Regioselective electrophilic C–H bond activation in triazolylidene metal complexes containing a N-bound phenyl substituent
Baron et al. Dinuclear N-Heterocyclic Dicarbene Gold Complexes in I–III and III–III Oxidation States: Synthesis and Structural Analysis
Cao et al. Hydroamination of unactivated alkenes catalyzed by novel platinum (II) N-heterocyclic carbene complexes
Mas-Marzá et al. Synthesis and Catalytic Properties of Two Trinuclear Complexes of Rhodium and Iridium with the N-Heterocyclic Tris-carbene Ligand TIMENiPr
Garcı́a-Álvarez et al. Ruthenium (II) arene complexes with asymmetrical guanidinate ligands: synthesis, characterization, and application in the base-free catalytic isomerization of allylic alcohols
Newman et al. Metal complexes of chiral NHCs containing a fused six-and seven-membered central ring
Gruver et al. Acceptor pincer chemistry of osmium: catalytic alkane dehydrogenation by (CF3PCP) Os (cod)(H)
Baron et al. Single-step synthesis of dinuclear neutral gold (I) complexes with bridging di (N-heterocyclic carbene) ligands and their catalytic performance in cross coupling reactions and alkyne hydroamination
Lapointe et al. Stable nickel (I) complexes with electron-rich, sterically-hindered, innocent PNP pincer ligands
Vivancos et al. Influence of the Linker Length and Coordination Mode of (Di) Triazolylidene Ligands on the Structure and Catalytic Transfer Hydrogenation Activity of Iridium (III) Centers
ACA Bayrakdar et al. Dinuclear gold (I) complexes bearing alkyl-bridged bis (N-heterocyclic carbene) ligands as catalysts for carboxylative cyclization of propargylamine: Synthesis, structure, and kinetic and mechanistic comparison to the mononuclear complex [Au (IPr) Cl]
Wan et al. Iridium and rhodium complexes containing enantiopure primary amine-tethered N-heterocyclic carbenes: synthesis, characterization, reactivity, and catalytic asymmetric hydrogenation of ketones
Flores-Jarillo et al. Synthesis and catalytic benefits of tetranuclear gold (I) complexes with a C 4-symmetric tetratriazol-5-ylidene
Fernandez et al. Picolyl–NHC Hydrotris (pyrazolyl) borate Ruthenium (II) Complexes: Synthesis, Characterization, and Reactivity with Small Molecules