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Anexos 5 Hojas MSDS Aditivos

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HOJA DE DATOS DE SEGURIDAD

(MSDS / MATERIAL SAFETY DATA SHEET)


DRILLING PAPER

Última actualización: Noviembre de 2012 – Depto. HSE – JCPDS

1. IDENTIFICACION DEL PRODUCTO Y DE LA COMPAÑIA

NOMBRE DEL PRODUCTO : DRILLING PAPER


CLASIFICACION QUIMICA : Papel rayado
APLICACIONES : Aditivo para fluido de perforación.
NUMEROS TELEFONICOS DE EMERGENCIA : 057(5818055) – 057 (3202741417)
PROVEEDOR : JC PORTAL DRILLING SUPPLIES
SAC
Número Tel: (51) 01-2551210
Cel. 952049641
RPM # 0008761
AV CAMINO DEL INCA MZ. V LT. 7
URB. HUERTOS DE VILLA CHORRILLOS
TELEF. 5112551210

Salud: 0 Inflamabilidad: 0 Peligro Físico: 0

2. COMPOSICION / INFORMACION SOBRE LOS COMPONENTES

CAS # Componentes (Nombre Químico) Concentración


Partícula sin otra
Clasificación (PNOC) - 100%

3. IDENTIFICACION DE PELIGROS

INFORMACION GENERAL DE EMERGENCIAS: CUIDADO! PUEDE CAUSAR LA IRRITACION DE LOS OJOS,


LA PIEL Y LAS VIAS RESPIRATORIAS. Evitar el contacto con los ojos, la piel y la ropa. Evitar la respiración de
producto en el aire. Procurar una ventilación adecuada. Lavarse completamente después de manejar el producto.
Resbaladizo cuando está húmedo.

POTENCIALES EFECTOS EN LA SALUD:

Inhalación : El producto pueden irritar las membranas mucosas de la nariz, garganta, bronquios y pulmones
Ingestión : Si es ingerido, este material puede causar trastornos gástricos, nauseas y vómitos.
Ojos : Este producto puede causar irritación leve transitoria, los síntomas incluyen lagrimeo y
enrojecimiento.
Piel : Este producto puede causar irritación de piel leve, transitoria, en períodos cortos de exposición

EFECTOS CRONICOS

Ver la sección 11 – Información Toxicológica


Vía de Ingreso : Inhalación, contacto con la piel y/o los ojos.
Órganos señalados : sistema respiratorio, pulmones, piel y ojos.

4. PRIMEROS AUXILIOS

GENERAL: Las personas que requieren atención médica deberían llevar una copia de esta hoja MSDS con ellas.

WEB SITE: www.jcportaldrillingsupplies.com


MEXICO: (5233) 38106099 / (5233) 15616618
PERÚ: (511) 255 – 1210 / (511) 662 – 7779
COLOMBIA: (574) 5818055
1
HOJA DE DATOS DE SEGURIDAD
(MSDS / MATERIAL SAFETY DATA SHEET)
DRILLING PAPER

Última actualización: Noviembre de 2012 – Depto. HSE – JCPDS

INHALACIÓN: Mover la víctima al aire fresco inmediatamente. Proveer la respiración artificial si la respiración ha
parado. Conseguir atención médica.
INGESTIÓN: Tomar un par de vasos de leche o agua. NO se debe inducir el vómito a menos que lo ordene un
médico. Nunca se debe administrar nada por la boca a una persona inconsciente. Conseguir atención médica.
PIEL: Lavar la piel a fondo con jabón y agua. Quitar la ropa contaminada. Conseguir atención medica si continúa
cualquier malestar.
OJOS: Lavar inmediatamente los ojos con mucha agua manteniendo abiertos los parpados. Continuar lavando
durante al menos 15 minutos. Conseguir atención médica si persiste cualquier malestar.

5. MEDIDAS DE LUCHA CONTRA INCENDIOS

TEMP. DE AUTO-IGNICIÓN (°C) : N/D


LÍMITE DE INFLAMABILIDAD inferior % : N/D
LÍMITE DE INFLAMABILIDAD superior % : N/D
MEDIDAS DE EXTINCIÓN: Este material no es combustible. Utilizar medios de extinción adecuados para contener
el incendio de los materiales próximos.
PROCEDIMIENTOS ESPECIALES PARA COMBATIR INCENDIOS: Ningún procedimiento específico de contra-
incendios registrado.
RIESGOS INSOLITOS DE INCENDIO Y DE EXPLOSION: Ningún riesgo excepcional de incendio o de explosión
Señalado.
PRODUCTOS DE DESCOMPOSICIÓN PELIGROSOS: No relevante

6. MEDIDAS A TOMAR EN CASO DE VERTIDO ACCIDENTAL

PRECAUCIONES PERSONALES: Llevar equipos de protección personal adecuados

MÉTODOS DE LIMPIEZA DE DERRAME: Contener en recipientes secos. Tapar y quitar los recipientes. Chorrear
el área con agua. No contamine el drenaje o las vías acuáticas. Re empaquetar o reciclar, si es posible.

7. MANIPULACION Y ALMACENAMIENTO

PRECAUCIONES DE USO:
Usar el equipo de protección personal adecuado. Evitar el contacto con la piel y los ojos. Evitar la respiración de vapores o
neblinas. Utilizar solo un sitio bien ventilado. Lavarse minuciosamente después de manejar el producto.

PRECAUCIONES DE ALMACENAJE:
Almacenar en un lugar seco y bien ventilado. Mantener el recipiente cerrado. Almacenar lejos de productos incompatibles.
Observar prácticas seguras de almacenamiento.

WEB SITE: www.jcportaldrillingsupplies.com


MEXICO: (5233) 38106099 / (5233) 15616618
PERÚ: (511) 255 – 1210 / (511) 662 – 7779
COLOMBIA: (574) 5818055
2
HOJA DE DATOS DE SEGURIDAD
(MSDS / MATERIAL SAFETY DATA SHEET)
DRILLING PAPER

Última actualización: Noviembre de 2012 – Depto. HSE – JCPDS

8. CONTROLES DE EXPOSICION / PROTECCION PERSONAL

EQUIPO DE PROTECCIÓN:

CONDICIONES DE PROCESO:
Usar medios de control de ingeniería adecuados, tales como la ventilación de evacuación y recintos para el proceso, para reducir
la contaminación del aire y mantener la exposición de los trabajadores por debajo de los límites aplicables.

VENTILACIÓN:
Suministrar ventilación natural o mecánica adecuada para evacuar el producto presente en el aire y mantener los niveles de
exposición por debajo de los límites aplicables.

RESPIRADORES:
Usar como mínimo un respirador desechable o reutilizable N95 de media mascara para partículas Aprobado por NIOSH. En
ambientes de trabajo que contienen neblina/aerosol de aceite, usar como mínimo un respirador desechable o reutilizable P95 de
media mascara para partículas aprobado por NIOSH. Para las exposiciones que exceden 10 x PEL, usar un Respirador para
Partículas N100 aprobado por NIOSH.

GUANTES PROTECTORES:
Usar guantes protectores apropiados si hay riesgo de contacto con la piel.

PROTECCIÓN DEL OJO:


Usar lentes de seguridad, resistentes al polvo.

OTRA PROTECCIÓN:
Usar ropa apropiada para prevenir contacto prolongado o repetido con la piel.

TRABAJO HIGIENICO DE RUTINA:


Lavarse rápidamente con jabón y agua si la piel ha sido contaminada. Cambiarse diariamente la ropa de trabajo si hay cualquier
posibilidad de contaminación.

9. PROPIEDADES FISICAS Y QUIMICAS

ASPECTO : Polvillo - rasgado


COLOR : gris claro
PERFUME/SABOR : No oloroso o sin olor característico.
DESCRIPCIÓN DE SOLUBILIDAD : No Soluble en agua.
PESO ESPECÍFICO : 1.4 TEMPERATURA (°C): 20
DENSIDAD DE VAPOR (aire=1) : N/A
PRESIÓN DE VAPOR : N/A TEMPERATURA (°C):
WEB SITE: www.jcportaldrillingsupplies.com
MEXICO: (5233) 38106099 / (5233) 15616618
PERÚ: (511) 255 – 1210 / (511) 662 – 7779
COLOMBIA: (574) 5818055
3
HOJA DE DATOS DE SEGURIDAD
(MSDS / MATERIAL SAFETY DATA SHEET)
DRILLING PAPER

Última actualización: Noviembre de 2012 – Depto. HSE – JCPDS

10. ESTABILIDAD Y REACTIVIDAD

ESTABILIDAD : Normalmente estable.


CONDICIONES PARA EVITAR : N/D.
POLIMERIZACIÓN PELIGROSA : No polimeriza.
MATERIAL INCOMPATIBLE : N/D.
MATERIALES PARA EVITAR : N/D
PRODUCTOS DE DESCOMPOSICIÓN PELIGROSOS: Para productos de la combustión, ver la Sección 5.

11. INFORMACIÓN TOXICOLOGICA:

No hay datos de toxicología disponibles para este producto.

12. INFORMACIÓN ECOLÓGICA

Biodegradación : ND
Bio-acumulacion : ND
Coeficiente de Partición Octanol/Agua : ND

13. CONSIDERACIONES SOBRE LA ELIMINACION

Recuperar y reclamar o recircular, si es práctico. Si este producto se convierte en desecho, eliminarlo en un


vertedero industrial autorizado.
Tener en cuenta todos los reglamentos estatales y las regulaciones ambientales locales. Deséchese como un
residuo industrial no peligroso. Puede ser confinado o incinerado, en cumplimiento con las normas locales

14. INFORMACION RELATIVA AL TRANSPORTE

RQ – PRODUCTO : N/A
US DOT:
CLASSE DOT USA : No regulado.
TRANSPORTE CANADENSE:
CLASSE TDGR : No regulado.
TRANSPORTE MARINO:
CLASE IMDG : No regulado.
TRANSPORTE AEREO:
CLASE ICAO : No regulado.

15. INFORMACION REGLAMENTARIA

WEB SITE: www.jcportaldrillingsupplies.com


MEXICO: (5233) 38106099 / (5233) 15616618
PERÚ: (511) 255 – 1210 / (511) 662 – 7779
COLOMBIA: (574) 5818055
4
HOJA DE DATOS DE SEGURIDAD
(MSDS / MATERIAL SAFETY DATA SHEET)
DRILLING PAPER

Última actualización: Noviembre de 2012 – Depto. HSE – JCPDS

Este producto no contiene componentes químicos.

CLAUSULA DE EXENCION DE RESPONSABILIDAD

La información proporcionada en esta Ficha de Datos de Seguridad es la más correcta de que disponemos a la
fecha de su publicación. La información suministrada está concebida solamente como una guía para la seguridad
en el manejo, uso, procesado, almacenamiento, transporte, eliminación y descarga. Y no debe ser considerada
como una garantía o especificación de calidad. El fabricante, no realiza expresamente ninguna aseveración ni
garantía, ni garantiza su precisión, fiabilidad o integridad, ni asume ninguna responsabilidad derivada de su uso.
Es responsabilidad del usuario verificar la adecuación y prolijidad de la información para cada uso particular.

WEB SITE: www.jcportaldrillingsupplies.com


MEXICO: (5233) 38106099 / (5233) 15616618
PERÚ: (511) 255 – 1210 / (511) 662 – 7779
COLOMBIA: (574) 5818055
5
EZ-MUD® PLUS
Polymer Emulsion

Description EZ-MUD® PLUS liquid polymer emulsion contains partially hydrolyzed


polyacrylamide/polyacrylate (PHPA) copolymer and is used primarily as a
viscosifier and borehole stabilizer to prevent reactive shales and clays
from swelling and sloughing. EZ-MUD PLUS is also added to low-solids
drilling fluids to increase lubricity and to improve the carrying capacity of
air/foam injection fluids.EZ-MUD PLUS polymer emulsion is a high
molecular weight version of EZ-MUD polymer emulsion with improved
properties.

Applications/Functions The use of EZ-MUD PLUS polymer assists or promotes the following:

 Stabilize reactive shale and clay formations


 Improve borehole and excavation stability
 Enhance slurry rheological properties
 Alleviate mud rings, bit balling and booting-off in clay formations
 Reduce drill pipe torque and pumping pressure
 Minimize rod chatter in diamond core drilling
 Create "stiff-foam" and maintain foam integrity
 Flocculate non-reactive solids in reserve pit at low concentrations

Advantages  Liquid form – mixes easily with minimum shear in fresh water
 Efficient shale/clay stabilizer and viscosifier
 Non-fermenting
 Cost-effective - small amounts produce desired results
 Breaks down chemically with bleach (sodium hypochlorite)
 NSF/ANSI Standard 60 Certified

Typical Properties  Appearance Thick, opaque white liquid


3
 Density 8.33 lbs/gal (1.00 g/cm )
 Flash point, PMCC °F, C >200 (>93.3)
 Thermal stability, °F, C 250 (121)

Recommended Approximate Amounts of EZ-MUD® PLUS High Molecular Weight Polymer


Treatment Emulsion Added to Water Based Fluids
3
Pints/bbl* Quarts/100 gal Liters/m

0.5 – 1.8 0.6 – 2.0 1.5 – 5.0


*1 bbl = 42 U.S. gallons

 It is recommended that Soda Ash (sodium carbonate) be added to the make-up water prior to
the addition of EZ-MUD PLUS high molecular weight liquid polymer emulsion for reduction of
excess calcium and pH adjustment.

 The above are generalized concentrations of EZ-MUD PLUS high molecular weight liquid
polymer emulsion to be added to water-based drilling fluids. The ultimate usage concentration
will be based on local geology, application and mixing efficiency. In the event that further
information is needed, please refer to the Product Data Sheet or contact your local Baroid IDP
representative.
Packaging EZ-MUD PLUS polymer emulsion is packaged in 5-gal (19-liter) plastic
pail weighing 42-lbs (19-kg) and a 25-kg (55-lb) plastic pail.

Availability EZ-MUD PLUS polymer emulsion can be purchased through any Baroid
Industrial Drilling Products Retailer. To locate the Baroid IDP retailer
nearest you contact the Customer Service Department in Houston or your
area IDP Sales Representative.
Baroid Industrial Drilling Products
Product Service Line, Halliburton
3000 N. Sam Houston Pkwy E.
Houston, TX 77032

Customer Service (800) 735-6075 Toll Free (281) 871-4612


Technical Service (877) 379-7412 Toll Free (281) 871-4613

© Copyright 2014 Halliburton Rev. 02/06/2014


EZ-MUD and QUIK-GEL are registered trademarks of Halliburton

Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or impli ed and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product will be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use. The
statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
HOLEPLUG®
Graded Sodium Bentonite
Gg

®
Description HOLEPLUG naturally occurring Wyoming sodium bentonite clay is a sized and
graded chip material used to seal and plug earthen boreholes.
HOLEPLUG bentonite is available in two particle size grades:
®
 HOLEPLUG 3/4" bentonite (100% of particles pass through 3/4" screen; all
particles retained on 3/8" screen)
®
 HOLEPLUG 3/8" bentonite (100% of particles pass through 3/8" screen; all
particles retained on 1/4" screen)

Applications/Functions The use of HOLEPLUG sodium bentonite assists or promotes the following:

 Grouting annulus in all types of wells, particularly environmental monitoring


well applications
 Sealing above gravel packs
 Plugging decommissioned boreholes
 Stemming shotholes
 Sealing around conductor pipe
 Sealing lost circulation zones
 Shutting off artesian flow

Advantages  Helps prevent entry of surface water into boreholes


 High swelling potential
 In situ swelling to provide a superior seal with excellent casing stabilization
 Easier to apply than pellets
 Cost effective
 Simple to apply, mixing not required
 Helps prevent vertical movement of fluids in the hole between porous zones
 Helps form a permanent, flexible downhole seal
 Helps allow hole re-entry
 Rehydratable
 NSF/ANSI Standard 60 certified

Typical Properties Volume of 50-lb (22.7 kg) sack


3 3 3
HOLEPLUG 3/4" bentonite 0.73 ft or 0.027 yd or 0.021 m
3 3 3
HOLEPLUG 3/8" bentonite 0.70 ft or 0.026 yd or 0.020 m
-9
Permeability 1.5 x 10 cm/sec (in fresh water)
Appearance Beige to tan chips

© Copyright 2012 Halliburton


HOLEPLUG is a registered trademark of Halliburton Rev. 11/29/2012

Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or implied and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product will be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use.
The statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
Recommended Plugging and Stemming Drill Holes
Treatment
Due to shipping and handling, a small amount of fine bentonite particles may be
®
present. For optimum results, HOLEPLUG should be poured over a mesh or
screen with ¼" (6.4 mm) openings to "sift out" the smaller particles. The screen
2 2
should be large enough (approx.1 yd or 1m ) to be folded into a "V" shape to
allow sifting while the product is being poured into the hole. Also, HOLEPLUG
bentonite should be poured slowly. Allow approximately two minutes to pour a
50-lb (22.7 kg) bag.

1. Position the screen with the lower end placed over the borehole
2. Slowly pour HOLEPLUG bentonite down the "V" so that fine particles
fall through the screen before the larger particles fall into the borehole
3. Fill hole as required (above static water level or to ground level)
4. Observe all regulatory specifications

Stopping loss of circulation and stabilizing unconsolidated formations

1. Pull drill pipe out of hole


2. Pour HOLEPLUG bentonite into hole to fill above problem zone
3. Drill ahead slowly with reduced pump pressure

Plugging flowing wells

Pour HOLEPLUG bentonite into hole until water flow subsides or hole is filled to
surface.

Treatment • Adequate annular space should be present to allow for the placement of
Considerations HOLEPLUG bentonite into the area of concern without bridging. It is
recommended that a minimum annular space of two inches on either side of
the outside dimension of the casing be present. This will facilitate the
placement of tremie lines and reduce the potential of the HOLEPLUG
bentonite bridging during pouring operations. The use of this product should
always correspond with applicable federal, state and local well construction
guidelines.

• The subsurface environment that the respective bentonite sealing material


or grout is to be placed into should always be taken into consideration when
selecting the appropriate material to compose the well seal. If the formation
water chemistry has a total hardness of greater than or equal to 500 parts
per million and/or a chloride content of greater than or equal to 1500 parts
per million the use of a bentonite material may not be appropriate for this
environment. In the event that questions regarding subsurface
environments arise it is always best to consult your local Baroid IDP
representative to determine if the Baroid product of choice is appropriate for
the given conditions.
®
Application Amounts of HOLEPLUG * Graded Sodium Bentonite Required for
Amounts Plugging Applications
Pounds Bags
Hole Feet Filled by
Hole Diameter HOLEPLUG HOLEPLUG
Volume One Bag
bentonite bentonite
(inches) HOLEPLUG
3
(ft /ft) Needed to Fill Needed to Fill
bentonite
One Foot 100 ft
2 0.022 1.6 32.6 3.2
2.5 0.034 2.4 20.5 5.0
3 0.049 3.5 14.3 7.0
3.5 0.067 4.8 10.4 9.6
4 0.087 6.3 7.9 12.6
4.5 0.110 7.9 6.3 15.8
5 0.136 9.8 5.1 19.6
5.5 0.165 11.9 4.2 23.8
6 0.196 14.1 3.5 28.2
6.5 0.230 16.6 3.0 33.2
7 0.267 19.2 2.6 38.4
7.5 0.307 22.1 2.3 44.2
8 0.349 25.1 2.0 50.2
8.5 0.394 28.4 1.8 56.8
9 0.442 31.8 1.6 63.6
9.5 0.492 35.4 1.4 70.8
10 0.545 39.2 1.3 78.4
11 0.660 47.5 1.1 95.0
12 0.785 56.5 0.89 113.0
15 1.227 88.3 0.57 176.6
18 1.767 127.2 0.39 254.4
20 2.182 157.1 0.32 314.2
25 3.409 245.4 0.20 490.8
30 4.909 353.4 0.14 706.8
*The above calculations and resultant volumes of material required assume a gauge bore hole and are based on the use
of HOLEPLUG 3/8" sodium bentonite where the average bulk density per bag is 0.7 ft 3/50-lb bag. Required material
volumes for HOLEPLUG 3/4" will differ slightly for the same size bore hole. In the event that questions arise or further
information is needed, please contact your local Baroid IDP Representative for assistance
®
Application Amounts of HOLEPLUG * Graded Sodium Bentonite Required for
Amounts Plugging Applications
(metric equivalents) Kilograms Bags
Hole Meters Filled
Hole Diameter HOLEPLUG HOLEPLUG
Volume by One Bag
bentonite bentonite
(mm) HOLEPLUG
3
(m /m) Needed to Fill Needed to Fill
bentonite
One Meter 10 meters
51 0.002 2.3 9.87 1.0
64 0.003 3.6 6.31 1.6
76 0.005 5.2 4.38 2.3
89 0.006 7.0 3.22 3.1
102 0.008 9.2 2.47 4.1
114 0.010 11.6 1.95 5.1
127 0.013 14.4 1.58 6.3
140 0.015 17.4 1.30 7.7
152 0.018 20.7 1.10 9.1
165 0.021 24.3 0.93 10.7
178 0.025 28.2 0.81 12.4
191 0.029 32.4 0.70 14.3
203 0.032 36.8 0.62 16.2
216 0.037 41.6 0.55 18.2
229 0.041 46.6 0.49 20.5
241 0.046 51.9 0.44 22.9
254 0.051 57.5 0.39 25.3
279 0.061 69.6 0.33 30.7
305 0.073 82.8 0.27 36.5
381 0.114 129.4 0.18 57.0
457 0.164 186.4 0.12 82.1
508 0.203 230.1 0.10 101.4
635 0.317 359.5 0.06 158.4
762 0.456 517.7 0.04 228.1

*The above calculations and resultant volumes of material required assume a gauge bore hole and are based on the use
of HOLEPLUG 3/8" sodium bentonite where the average bulk density per bag is 0.020 m 3/22.7-kg bag. Required material
volumes for HOLEPLUG 3/4" will differ slightly for the same size bore hole.In the event that questions arise or further
information is needed, please contact your local Baroid IDP Representative for assistance.

Packaging HOLEPLUG graded bentonite is packaged in 50-lb (22.7 kg) multiwall


paper bags.

Availability HOLEPLUG graded sodium bentonite can be purchased through any


Baroid Industrial Drilling Products Retailer. To locate the Baroid IDP
retailer nearest you contact the Customer Service Department in Houston
or your area IDP Sales Representative.

Baroid Industrial Drilling Products


Product Service Line, Halliburton
3000 N. Sam Houston Pkwy E.
Houston, TX 77032
Customer Service (800) 735-6075 Toll Free (281) 871-4612

Technical Service (877) 379-7412 Toll Free (281) 871-4613


N-SEAL™
Lost Circulation Material

Description N-SEAL™ acid soluble lost circulation material is specially formulated,


extrusion-spun mineral fiber. Due to its solubility in weak acids, N-SEAL
lost circulation material is easily removed from production zones.

Applications/Functions N-SEAL lost circulation material can be used as an additive for loss of
3
circulation in concentrations up to 70 lb/100 gallons (86 kg/m ).

Advantages  NSF/ANSI Standard 60 certified


 Acid soluble
 Can be easily wetted
 Inorganic and non-fermenting

Typical Properties  Appearance Gray to white fiber


 Specific gravity 2.6

Recommended N-SEAL lost circulation material can be added directly through the hopper.
Treatment  For normal treatment to the active system, add 5-20 lb/100 gallons
3
drilling fluid (6-24 kg/m )
3
 As a pill, add 20-70 lb/100 gallons of drilling fluid (24-86 kg/m )

N-SEAL lost circulation material is 95% acid soluble. To dissolve 1 lb of


N-SEAL lost circulation material treat with either:
®
 1-2 lb AQUA-CLEAR MGA modified granular acid (1-2 kg/kg)
or
 0.5-1 gal of 10% HCl/5% Acetic acid blend (1-2 liters/kg)

Packaging N-SEAL lost circulation material is packaged in 30-lb (14 kg) multiwall
paper bags.

Availability N-SEAL lost circulation material can be purchased through any Baroid
Industrial Drilling Productgs Retailer. To locate the Baroid IDP retailer
nearest you contact the Customer Service Department in Houston or your
area IDP Sales Representative.
Baroid Industrial Drilling Products
Product Service Line, Halliburton
3000 N. Sam Houston Pkwy E.
Houston, TX 77032

Customer Service (800) 735-6075 Toll Free (281) 871-4612


Technical Service (877) 379-7412 Toll Free (281) 871-4613

© Copyright 2012 Halliburton


AQUA-CLEAR is a registered trademark of Halliburton Rev. 10/10/2012
N-SEAL is a trademark of Halliburton

Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or implied and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product wi ll be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use.
The statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
PENETROL®
Wetting Agent

Description PENETROL wetting agent is a water miscible, non-ionic surfactant designed


to counteract the sticking tendencies of clay.

Applications/Functions The use of PENETROL wetting agent aids the following:

 Reduce or eliminate bit balling


 Reduce surface tension of drilling fluid, which allows faster chip removal
without continuously grinding the hard shale formations
 Improve drilling efficiency by preferentially coating the bottom-hole
assembly and drill string
 Minimize differential sticking
 Increase bit life and reduce drill pipe and bottom-hole assembly wear

Advantages  Easy to mix


 Effective in low concentrations
 Compatible with other Baroid drilling fluid additives
 Biodegradable

Typical Properties  Appearance forest green liquid


 Specific gravity 0.98
 pH (1%) solution 9.5
 Flash point, TOC, F, C >300, (149)

Recommended Added uniformly through entire circulation system


Treatment
 1 to 4 quarts of PENETROL wetting agent per 100 gallons of drilling fluid
 2.5 to 10 liters of PENETROL wetting agent per m3 of drilling fluid

As a slug down drill rods to counteract the sticking tendencies of clay

 1 to 2 quarts of PENETROL wetting agent per drill rod


 1 to 2 liters of PENETROL wetting agent per drill rod

Alternate application

 Dilute 1 gallon of PENETROL wetting agent with 10 gallons of water and


inject one gallon of mixture per minute into the pump suction

 Dilute 3.8 liters of PENETROL wetting agent with 38 liters of water and
inject 3.8 liters of mixture per minute into the pump suction

© Copyright 2011 Halliburton


PENETROL is a registered trademark of Halliburton Rev. 03/2011 · IDP 050

Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or implied and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product will be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use.
The statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
Packaging PENETROL® wetting agent is packaged in 5-gal (19-liter) plastic containers.

Availability PENETROL wetting agent can be purchased through any Baroid Industrial
Drilling Products Retailer. To locate the Baroid IDP retailer nearest you
contact the Customer Service Department in Houston or your area IDP
Sales Representative.
Baroid Industrial Drilling Products
Product Service Line, Halliburton
3000 N. Sam Houston Pkwy. E.
Houston, TX 77032

Customer Service (800) 735-6075 Toll Free (281) 871-4612


Technical Service (877) 379-7412 Toll Free (281) 871-4613

© Copyright 2011 Halliburton


PENETROL is a registered trademark of Halliburton Rev. 03/2011 · IDP 050

Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or implied and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product will be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use.
The statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
MATERIAL SAFETY DATA SHEET
Product Trade Name: QUIK-GEL GOLD®
Revision Date: 07-Feb-2014

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE


COMPANY/UNDERTAKING

Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Dangerous Goods according to
the criteria of ADG. Hazardous according to the criteria of NOHSC,
Non-Dangerous Goods according to the criteria of ADG.

Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd.


15 Marriott Road
Jandakot
WA 6164
Australia

ACN Number: 009 000 775


Telephone Number: 61 (08) 9455 8300
Fax Number: 61 (08) 9455 5300

Product Emergency Telephone


Australia: 08-64244950
Papua New Guinea: 05 1 281 575 5000
New Zealand: 06-7559274

Fire, Police & Ambulance - Emergency Telephone


Australia: 000
Papua New Guinea: 000
New Zealand: 111

Identification of Substances or Preparation

Product Trade Name: QUIK-GEL GOLD®


Synonyms: None
Chemical Family: Mineral
UN Number: None
Dangerous Goods Class: None
Subsidiary Risk: None
Hazchem Code: None Allocated
Poisons Schedule: None Allocated
Application: Viscosifier

Prepared By Chemical Compliance


Telephone: 1-580-251-4335
e-mail: fdunexchem@halliburton.com

2. HAZARDS IDENTIFICATION

Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Dangerous Goods according to
the criteria of ADG. Hazardous according to the criteria of NOHSC,
Non-Dangerous Goods according to the criteria of ADG.

QUIK-GEL GOLD®
Page 1 of 7
Hazard Overview CAUTION! - ACUTE HEALTH HAZARD
May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD


Breathing crystalline silica can cause lung disease, including silicosis and lung
cancer. Crystalline silica has also been associated with scleroderma and kidney
disease.

This product contains quartz, cristobalite, and/or tridymite which may become
airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty
conditions. Use only with adequate ventilation to keep exposures below
recommended exposure limits. Wear a NIOSH certified, European Standard EN
149, or equivalent respirator when using this product. Review the Material Safety
Data Sheet (MSDS) for this product, which has been provided to your employer.

Classification T - Toxic.

Risk Phrases R49 May cause cancer by inhalation.


R48/20 Harmful: danger of serious damage to health by prolonged exposure
through inhalation.

Safety Phrases S22 Do not breathe dust.

HSNO Classification 6.7A Known or presumed human carcinogens


6.9A Toxic to human target organs or systems

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances CAS Number PERCENT (w/w) Australia NOHSCNew Zealand ACGIH TLV-TWA
WES
Bentonite 1302-78-9 60 - 100% Not applicable Not applicable TWA: 1 mg/m3
Crystalline silica, quartz 14808-60-7 1 - 5% TWA: 0.1 mg/m3 TWA: 0.2 mg/m3 TWA: 0.025 mg/m3
Crystalline silica, 14464-46-1 0 - 1% TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3
cristobalite
Crystalline silica, tridymite 15468-32-3 0 - 1% TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 0.05 mg/m3

Non-Hazardous Substance to Total of 100%

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Treat symptomatically.

5. FIRE FIGHTING MEASURES

QUIK-GEL GOLD®
Page 2 of 7
Suitable Extinguishing Media
All standard fire fighting media

Extinguishing media which must not be used for safety reasons


None known.

Special Exposure Hazards Not applicable.

Special Protective Equipment Not applicable.


for Fire-Fighters

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary Use appropriate protective equipment. Avoid creating and breathing dust.
Measures

Environmental Precautionary None known.


Measures

Procedure for Cleaning / Collect using dustless method and hold for appropriate disposal. Consider
Absorption possible toxic or fire hazards associated with contaminating substances and use
appropriate methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become
airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty
conditions. Use only with adequate ventilation to keep exposure below
recommended exposure limits. Wear a NIOSH certified, European Standard En
149, or equivalent respirator when using this product. Material is slippery when
wet.

Storage Information Do not reuse empty container. Use good housekeeping in storage and work areas
to prevent accumulation of dust. Close container when not in use. Keep from
excessive heat. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain
exposures below applicable exposure limits.

Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Dust/mist respirator. (N95, P2/P3)

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be
laundered before reuse. Use precautionary measures to avoid creating dust when
removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

QUIK-GEL GOLD®
Page 3 of 7
Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: Tan
Odor: Mild earthy
pH: 8.5-9.5 (3%)
Specific Gravity @ 20 C (Water=1): 2.5 - 2.6
Density @ 20 C (kg/l): Not Determined
Bulk Density @ 20 C (kg/M3): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m 3): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m3): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Slightly soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): Not Determined
Decomposition Temperature (C): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to Hydrofluoric acid.


Avoid)

Hazardous Decomposition Amorphous silica may transform at elevated temperatures to tridymite (870 C) or
Products cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION


Principle Route of Exposure Eye or skin contact, inhalation.

Sympotoms related to exposure


Acute Toxicity

QUIK-GEL GOLD®
Page 4 of 7
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is
carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimental
animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.
Breathing silica dust may not cause noticeable injury or illness even though permanent lung
damage may be occurring. Inhalation of dust may also have serious chronic health effects
(See "Chronic Effects/Carcinogenicity" subsection below).

Eye Contact May cause eye irritation.


Skin Contact May cause mechanical skin irritation.
Ingestion None known

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive,
disabling, and sometimes-fatal lung disease called silicosis. Symptoms include cough,
shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function.
This disease is exacerbated by smoking. Individuals with silicosis are predisposed to
develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has determined
that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources
can cause lung cancer in humans (Group 1 - carcinogenic to humans) and has determined
that there is sufficient evidence in experimental animals for the carcinogenicity of tridymite
(Group 2A - possible carcinogen to humans). Refer to IARC Monograph 68, Silica, Some
Silicates and Organic Fibres (June 1997) in conjunction with the use of these minerals. The
National Toxicology Program classifies respirable crystalline silica as "Known to be a
human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American
Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica,
quartz, as a suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints such as
scleroderma (an immune system disorder manifested by scarring of the lungs, skin, and
other internal organs) and kidney disease.

Toxicology data for the components


Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Bentonite 1302-78-9 5000 mg/kg ( Rat ) No data available No data available
Crystalline silica, quartz 14808-60-7 500 mg/kg ( Rat ) No data available No data available
Crystalline silica, 14464-46-1 No data available No data available No data available
cristobalite
Crystalline silica, 15468-32-3 No data available No data available No data available
tridymite

12. ECOLOGICAL INFORMATION

Ecotoxicological Information

Ecotoxicity Product
Acute Fish Toxicity: TLM96: 10000 ppm (Oncorhynchus mykiss)
Acute Crustaceans Toxicity: Not determined
Acute Algae Toxicity: Not determined

Ecotoxicity Substance
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water
Microorganisms Flea)
Bentonite 1302-78-9 No information available TLM96: 10000 ppm No information available No information available
(Oncorhynchus mykiss)

QUIK-GEL GOLD®
Page 5 of 7
Crystalline silica, 14808-60-7 No information available No information available No information available No information available
quartz
Crystalline silica, 14464-46-1 No information available No information available No information available No information available
cristobalite
Crystalline silica, 15468-32-3 No information available No information available No information available No information available
tridymite

12.2 Persistence and degradability


No information available

12.3 Bioaccumulative potential


No information available

12.4 Mobility in soil


No information available

12.5 Results of PBT and vPvB assessment


No information available.

12.6 Other adverse effects

13. DISPOSAL CONSIDERATIONS

Disposal Method If practical, recover and reclaim, recycle, or reuse by the guidelines of an
approved local reuse program. Should contaminated product become a waste,
dispose of in a licensed industrial landfill according to federal, state, and local
regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation
ADR
Not restricted

Air Transportation
ICAO/IATA
Not restricted

Sea Transportation
IMDG
Not restricted

Other Transportation Information


Labels: None

15. REGULATORY INFORMATION

Chemical Inventories

Australian AICS Inventory All components listed on inventory or are exempt.


New Zealand Inventory of All components listed on inventory or are exempt.
Chemicals
US TSCA Inventory All components listed on inventory or are exempt.
QUIK-GEL GOLD®
Page 6 of 7
EINECS Inventory This product, and all its components, complies with EINECS

Classification T - Toxic.

Risk Phrases R49 May cause cancer by inhalation.


R48/20 Harmful: danger of serious damage to health by prolonged exposure
through inhalation.

Safety Phrases S22 Do not breathe dust.

16. OTHER INFORMATION

The following sections have been revised since the last issue of this SDS
Not applicable

Contact

Australian Poisons Information Centre


24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100

New Zealand National Poisons Centre


0800 764 766

Additional Information For additional information on the use of this product, contact your local Halliburton
representative.

For questions about the Safety Data Sheet for this or other Halliburton products,
contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to


accuracy or completeness. The information is obtained from various sources
including the manufacturer and other third party sources. The information may not
be valid under all conditions nor if this material is used in combination with other
materials or in any process. Final determination of suitability of any material is the
sole responsibility of the user.

***END OF MSDS***

QUIK-GEL GOLD®
Page 7 of 7
QUIK-TROL® GOLD LV
Highly Dispersible Low Viscosity Filtration Control Additive

®
Description QUIK-TROL GOLD LV highly dispersible, low viscosity grade, polyanionic cellulosic (PAC)
polymer provides enhanced filtration control in most water-based drilling fluids. QUIK-TROL
GOLD LV low viscosity PAC polymer, when added to a bentonite based drilling fluid, yields a
low filtrate drilling fluid system with manageable viscosity suitable for drilling in water
sensitive and unstable formations.
Applications/Functions The use of QUIK-TROL GOLD LV low viscosity filtration control additive promotes:
 Filtration control in fresh or brackish water-based drilling fluids
 Borehole stability in water sensitive formations
 Encapsulation of shale to prevent swelling and disintegration
 Minimized rod chatter, rotational torque and circulating pressure
 Improved hole cleaning and core recovery
 Enhanced foam properties to improve cuttings transport in air/foam drilling
Advantages  Disperses readily at low shear rates
 Effective in fresh, salt and brackish water-based drilling fluids
 Tolerant of harsh environments and contaminants
 Non-fermenting
 Compatible with other Baroid drilling fluid additives
 NSF/ANSI Standard 60 certified
Typical Properties  Appearance Off-white powder
 pH ( 1% aqueous solution) 6.0 – 8.0
Recommended  Using a Venturi Mixer, or into vortex of a high-speed stirrer, add slowly and uniformly to
Treatment the entire circulating system. See treatment chart below or contact your local Baroid IDP
Field Representative for dosing assistance.
Approximate Amounts of QUIK-TROL® GOLD LV Filtration Control
Polymer Added to Water-Based Fluids
3
lbs/bbl lbs/100 gallons kg/m
0.1 – 2.0 0.25 – 5.0 0.3 – 6.0
Note:
 The above are generalized concentration ranges of QUIK-TROL GOLD LV
filtration control additive to be added to water-based drilling fluids. The ultimate
usage concentration will be based on local geology, application and mixing
efficiency. For further information or assistance please contact your local
Baroid IDP representative.
 Very salty water may require twice as much QUIK-TROL GOLD LV additive as
fresh water. Preferably, QUIK-TROL GOLD LV filtration control additive should
be mixed in fresh water before it is added to very salty water.
®
Packaging QUIK-TROL GOLD LV highly dispersible low viscosity filtration control additive is packaged
in 40-lb (18.2-kg) plastic pails and in 20-lb (9.1-kg) plastic pails containing 10 airtight sealed
plastic bags. Each bag contains 2-lb (0.91- kg).
Availability QUIK-TROL GOLD LV highly dispersible low viscosity filtration control additive can be
purchased through any Baroid Industrial Drilling Products Retailer. To locate the Baroid IDP
retailer nearest you contact the Customer Service Department in Houston or your area IDP
Sales Representative.
Baroid Industrial Drilling Products
Product Service Line, Halliburton
3000 N. Sam Houston Pkwy. E.
Houston, TX 77032
Customer Service (800) 735-6075 Toll Free (281) 871-4612
Technical Service (877) 379-7412 Toll Free (281) 871-4613

© Copyright 2017 Halliburton


Rev. 06/278/2017
QUIK-TROL is a registered trademark of Halliburton
Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or implied and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product will be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use.
The statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.

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