Anexos 5 Hojas MSDS Aditivos
Anexos 5 Hojas MSDS Aditivos
Anexos 5 Hojas MSDS Aditivos
3. IDENTIFICACION DE PELIGROS
Inhalación : El producto pueden irritar las membranas mucosas de la nariz, garganta, bronquios y pulmones
Ingestión : Si es ingerido, este material puede causar trastornos gástricos, nauseas y vómitos.
Ojos : Este producto puede causar irritación leve transitoria, los síntomas incluyen lagrimeo y
enrojecimiento.
Piel : Este producto puede causar irritación de piel leve, transitoria, en períodos cortos de exposición
EFECTOS CRONICOS
4. PRIMEROS AUXILIOS
GENERAL: Las personas que requieren atención médica deberían llevar una copia de esta hoja MSDS con ellas.
INHALACIÓN: Mover la víctima al aire fresco inmediatamente. Proveer la respiración artificial si la respiración ha
parado. Conseguir atención médica.
INGESTIÓN: Tomar un par de vasos de leche o agua. NO se debe inducir el vómito a menos que lo ordene un
médico. Nunca se debe administrar nada por la boca a una persona inconsciente. Conseguir atención médica.
PIEL: Lavar la piel a fondo con jabón y agua. Quitar la ropa contaminada. Conseguir atención medica si continúa
cualquier malestar.
OJOS: Lavar inmediatamente los ojos con mucha agua manteniendo abiertos los parpados. Continuar lavando
durante al menos 15 minutos. Conseguir atención médica si persiste cualquier malestar.
MÉTODOS DE LIMPIEZA DE DERRAME: Contener en recipientes secos. Tapar y quitar los recipientes. Chorrear
el área con agua. No contamine el drenaje o las vías acuáticas. Re empaquetar o reciclar, si es posible.
7. MANIPULACION Y ALMACENAMIENTO
PRECAUCIONES DE USO:
Usar el equipo de protección personal adecuado. Evitar el contacto con la piel y los ojos. Evitar la respiración de vapores o
neblinas. Utilizar solo un sitio bien ventilado. Lavarse minuciosamente después de manejar el producto.
PRECAUCIONES DE ALMACENAJE:
Almacenar en un lugar seco y bien ventilado. Mantener el recipiente cerrado. Almacenar lejos de productos incompatibles.
Observar prácticas seguras de almacenamiento.
EQUIPO DE PROTECCIÓN:
CONDICIONES DE PROCESO:
Usar medios de control de ingeniería adecuados, tales como la ventilación de evacuación y recintos para el proceso, para reducir
la contaminación del aire y mantener la exposición de los trabajadores por debajo de los límites aplicables.
VENTILACIÓN:
Suministrar ventilación natural o mecánica adecuada para evacuar el producto presente en el aire y mantener los niveles de
exposición por debajo de los límites aplicables.
RESPIRADORES:
Usar como mínimo un respirador desechable o reutilizable N95 de media mascara para partículas Aprobado por NIOSH. En
ambientes de trabajo que contienen neblina/aerosol de aceite, usar como mínimo un respirador desechable o reutilizable P95 de
media mascara para partículas aprobado por NIOSH. Para las exposiciones que exceden 10 x PEL, usar un Respirador para
Partículas N100 aprobado por NIOSH.
GUANTES PROTECTORES:
Usar guantes protectores apropiados si hay riesgo de contacto con la piel.
OTRA PROTECCIÓN:
Usar ropa apropiada para prevenir contacto prolongado o repetido con la piel.
Biodegradación : ND
Bio-acumulacion : ND
Coeficiente de Partición Octanol/Agua : ND
RQ – PRODUCTO : N/A
US DOT:
CLASSE DOT USA : No regulado.
TRANSPORTE CANADENSE:
CLASSE TDGR : No regulado.
TRANSPORTE MARINO:
CLASE IMDG : No regulado.
TRANSPORTE AEREO:
CLASE ICAO : No regulado.
La información proporcionada en esta Ficha de Datos de Seguridad es la más correcta de que disponemos a la
fecha de su publicación. La información suministrada está concebida solamente como una guía para la seguridad
en el manejo, uso, procesado, almacenamiento, transporte, eliminación y descarga. Y no debe ser considerada
como una garantía o especificación de calidad. El fabricante, no realiza expresamente ninguna aseveración ni
garantía, ni garantiza su precisión, fiabilidad o integridad, ni asume ninguna responsabilidad derivada de su uso.
Es responsabilidad del usuario verificar la adecuación y prolijidad de la información para cada uso particular.
Applications/Functions The use of EZ-MUD PLUS polymer assists or promotes the following:
Advantages Liquid form – mixes easily with minimum shear in fresh water
Efficient shale/clay stabilizer and viscosifier
Non-fermenting
Cost-effective - small amounts produce desired results
Breaks down chemically with bleach (sodium hypochlorite)
NSF/ANSI Standard 60 Certified
It is recommended that Soda Ash (sodium carbonate) be added to the make-up water prior to
the addition of EZ-MUD PLUS high molecular weight liquid polymer emulsion for reduction of
excess calcium and pH adjustment.
The above are generalized concentrations of EZ-MUD PLUS high molecular weight liquid
polymer emulsion to be added to water-based drilling fluids. The ultimate usage concentration
will be based on local geology, application and mixing efficiency. In the event that further
information is needed, please refer to the Product Data Sheet or contact your local Baroid IDP
representative.
Packaging EZ-MUD PLUS polymer emulsion is packaged in 5-gal (19-liter) plastic
pail weighing 42-lbs (19-kg) and a 25-kg (55-lb) plastic pail.
Availability EZ-MUD PLUS polymer emulsion can be purchased through any Baroid
Industrial Drilling Products Retailer. To locate the Baroid IDP retailer
nearest you contact the Customer Service Department in Houston or your
area IDP Sales Representative.
Baroid Industrial Drilling Products
Product Service Line, Halliburton
3000 N. Sam Houston Pkwy E.
Houston, TX 77032
Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or impli ed and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product will be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use. The
statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
HOLEPLUG®
Graded Sodium Bentonite
Gg
®
Description HOLEPLUG naturally occurring Wyoming sodium bentonite clay is a sized and
graded chip material used to seal and plug earthen boreholes.
HOLEPLUG bentonite is available in two particle size grades:
®
HOLEPLUG 3/4" bentonite (100% of particles pass through 3/4" screen; all
particles retained on 3/8" screen)
®
HOLEPLUG 3/8" bentonite (100% of particles pass through 3/8" screen; all
particles retained on 1/4" screen)
Applications/Functions The use of HOLEPLUG sodium bentonite assists or promotes the following:
Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or implied and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product will be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use.
The statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
Recommended Plugging and Stemming Drill Holes
Treatment
Due to shipping and handling, a small amount of fine bentonite particles may be
®
present. For optimum results, HOLEPLUG should be poured over a mesh or
screen with ¼" (6.4 mm) openings to "sift out" the smaller particles. The screen
2 2
should be large enough (approx.1 yd or 1m ) to be folded into a "V" shape to
allow sifting while the product is being poured into the hole. Also, HOLEPLUG
bentonite should be poured slowly. Allow approximately two minutes to pour a
50-lb (22.7 kg) bag.
1. Position the screen with the lower end placed over the borehole
2. Slowly pour HOLEPLUG bentonite down the "V" so that fine particles
fall through the screen before the larger particles fall into the borehole
3. Fill hole as required (above static water level or to ground level)
4. Observe all regulatory specifications
Pour HOLEPLUG bentonite into hole until water flow subsides or hole is filled to
surface.
Treatment • Adequate annular space should be present to allow for the placement of
Considerations HOLEPLUG bentonite into the area of concern without bridging. It is
recommended that a minimum annular space of two inches on either side of
the outside dimension of the casing be present. This will facilitate the
placement of tremie lines and reduce the potential of the HOLEPLUG
bentonite bridging during pouring operations. The use of this product should
always correspond with applicable federal, state and local well construction
guidelines.
*The above calculations and resultant volumes of material required assume a gauge bore hole and are based on the use
of HOLEPLUG 3/8" sodium bentonite where the average bulk density per bag is 0.020 m 3/22.7-kg bag. Required material
volumes for HOLEPLUG 3/4" will differ slightly for the same size bore hole.In the event that questions arise or further
information is needed, please contact your local Baroid IDP Representative for assistance.
Applications/Functions N-SEAL lost circulation material can be used as an additive for loss of
3
circulation in concentrations up to 70 lb/100 gallons (86 kg/m ).
Recommended N-SEAL lost circulation material can be added directly through the hopper.
Treatment For normal treatment to the active system, add 5-20 lb/100 gallons
3
drilling fluid (6-24 kg/m )
3
As a pill, add 20-70 lb/100 gallons of drilling fluid (24-86 kg/m )
Packaging N-SEAL lost circulation material is packaged in 30-lb (14 kg) multiwall
paper bags.
Availability N-SEAL lost circulation material can be purchased through any Baroid
Industrial Drilling Productgs Retailer. To locate the Baroid IDP retailer
nearest you contact the Customer Service Department in Houston or your
area IDP Sales Representative.
Baroid Industrial Drilling Products
Product Service Line, Halliburton
3000 N. Sam Houston Pkwy E.
Houston, TX 77032
Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or implied and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product wi ll be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use.
The statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
PENETROL®
Wetting Agent
Alternate application
Dilute 3.8 liters of PENETROL wetting agent with 38 liters of water and
inject 3.8 liters of mixture per minute into the pump suction
Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or implied and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product will be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use.
The statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
Packaging PENETROL® wetting agent is packaged in 5-gal (19-liter) plastic containers.
Availability PENETROL wetting agent can be purchased through any Baroid Industrial
Drilling Products Retailer. To locate the Baroid IDP retailer nearest you
contact the Customer Service Department in Houston or your area IDP
Sales Representative.
Baroid Industrial Drilling Products
Product Service Line, Halliburton
3000 N. Sam Houston Pkwy. E.
Houston, TX 77032
Because the conditions of use of this product are beyond the seller's control, the product is sold without warranty either express or implied and upon condition that
purchaser make its own test to determine the suitability for purchaser’s application. Purchaser assumes all risk of use and handling of this product. This product will be
replaced if defective in manufacture or packaging or if damaged. Except for such replacement, seller is not liable for any damages caused by this product or its use.
The statements and recommendations made herein are believed to be accurate. No guarantee of their accuracy is made, however.
MATERIAL SAFETY DATA SHEET
Product Trade Name: QUIK-GEL GOLD®
Revision Date: 07-Feb-2014
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Dangerous Goods according to
the criteria of ADG. Hazardous according to the criteria of NOHSC,
Non-Dangerous Goods according to the criteria of ADG.
2. HAZARDS IDENTIFICATION
Statement of Hazardous Nature Hazardous according to the criteria of NOHSC, Dangerous Goods according to
the criteria of ADG. Hazardous according to the criteria of NOHSC,
Non-Dangerous Goods according to the criteria of ADG.
QUIK-GEL GOLD®
Page 1 of 7
Hazard Overview CAUTION! - ACUTE HEALTH HAZARD
May cause eye and respiratory irritation.
This product contains quartz, cristobalite, and/or tridymite which may become
airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty
conditions. Use only with adequate ventilation to keep exposures below
recommended exposure limits. Wear a NIOSH certified, European Standard EN
149, or equivalent respirator when using this product. Review the Material Safety
Data Sheet (MSDS) for this product, which has been provided to your employer.
Classification T - Toxic.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT (w/w) Australia NOHSCNew Zealand ACGIH TLV-TWA
WES
Bentonite 1302-78-9 60 - 100% Not applicable Not applicable TWA: 1 mg/m3
Crystalline silica, quartz 14808-60-7 1 - 5% TWA: 0.1 mg/m3 TWA: 0.2 mg/m3 TWA: 0.025 mg/m3
Crystalline silica, 14464-46-1 0 - 1% TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3
cristobalite
Crystalline silica, tridymite 15468-32-3 0 - 1% TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 0.05 mg/m3
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Skin Wash with soap and water. Get medical attention if irritation persists.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
QUIK-GEL GOLD®
Page 2 of 7
Suitable Extinguishing Media
All standard fire fighting media
Personal Precautionary Use appropriate protective equipment. Avoid creating and breathing dust.
Measures
Procedure for Cleaning / Collect using dustless method and hold for appropriate disposal. Consider
Absorption possible toxic or fire hazards associated with contaminating substances and use
appropriate methods for collection, storage and disposal.
Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become
airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty
conditions. Use only with adequate ventilation to keep exposure below
recommended exposure limits. Wear a NIOSH certified, European Standard En
149, or equivalent respirator when using this product. Material is slippery when
wet.
Storage Information Do not reuse empty container. Use good housekeeping in storage and work areas
to prevent accumulation of dust. Close container when not in use. Keep from
excessive heat. Product has a shelf life of 24 months.
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain
exposures below applicable exposure limits.
Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Dust/mist respirator. (N95, P2/P3)
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be
laundered before reuse. Use precautionary measures to avoid creating dust when
removing or laundering clothing.
QUIK-GEL GOLD®
Page 3 of 7
Other Precautions None known.
Color: Tan
Odor: Mild earthy
pH: 8.5-9.5 (3%)
Specific Gravity @ 20 C (Water=1): 2.5 - 2.6
Density @ 20 C (kg/l): Not Determined
Bulk Density @ 20 C (kg/M3): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (C): Not Determined
Pour Point/Range (C): Not Determined
Flash Point/Range (C): Not Determined
Flash Point Method: Not Determined
Autoignition Temperature (C): Not Determined
Flammability Limits in Air - Lower (g/m 3): Not Determined
Flammability Limits in Air - Lower (%): Not Determined
Flammability Limits in Air - Upper (g/m3): Not Determined
Flammability Limits in Air - Upper (%): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air=1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1): Not Determined
Solubility in Water (g/100ml): Slightly soluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (g/l): Not Determined
Viscosity, Dynamic @ 20 C (centipoise): Not Determined
Viscosity, Kinematic @ 20 C (centistokes): Not Determined
Partition Coefficient/n-Octanol/Water: Not Determined
Molecular Weight (g/mole): Not Determined
Decomposition Temperature (C): Not Determined
Hazardous Decomposition Amorphous silica may transform at elevated temperatures to tridymite (870 C) or
Products cristobalite (1470 C).
QUIK-GEL GOLD®
Page 4 of 7
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is
carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimental
animals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.
Breathing silica dust may not cause noticeable injury or illness even though permanent lung
damage may be occurring. Inhalation of dust may also have serious chronic health effects
(See "Chronic Effects/Carcinogenicity" subsection below).
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive,
disabling, and sometimes-fatal lung disease called silicosis. Symptoms include cough,
shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function.
This disease is exacerbated by smoking. Individuals with silicosis are predisposed to
develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) has determined
that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources
can cause lung cancer in humans (Group 1 - carcinogenic to humans) and has determined
that there is sufficient evidence in experimental animals for the carcinogenicity of tridymite
(Group 2A - possible carcinogen to humans). Refer to IARC Monograph 68, Silica, Some
Silicates and Organic Fibres (June 1997) in conjunction with the use of these minerals. The
National Toxicology Program classifies respirable crystalline silica as "Known to be a
human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American
Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica,
quartz, as a suspected human carcinogen (A2).
There is some evidence that breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints such as
scleroderma (an immune system disorder manifested by scarring of the lungs, skin, and
other internal organs) and kidney disease.
Ecotoxicological Information
Ecotoxicity Product
Acute Fish Toxicity: TLM96: 10000 ppm (Oncorhynchus mykiss)
Acute Crustaceans Toxicity: Not determined
Acute Algae Toxicity: Not determined
Ecotoxicity Substance
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water
Microorganisms Flea)
Bentonite 1302-78-9 No information available TLM96: 10000 ppm No information available No information available
(Oncorhynchus mykiss)
QUIK-GEL GOLD®
Page 5 of 7
Crystalline silica, 14808-60-7 No information available No information available No information available No information available
quartz
Crystalline silica, 14464-46-1 No information available No information available No information available No information available
cristobalite
Crystalline silica, 15468-32-3 No information available No information available No information available No information available
tridymite
Disposal Method If practical, recover and reclaim, recycle, or reuse by the guidelines of an
approved local reuse program. Should contaminated product become a waste,
dispose of in a licensed industrial landfill according to federal, state, and local
regulations.
Land Transportation
ADR
Not restricted
Air Transportation
ICAO/IATA
Not restricted
Sea Transportation
IMDG
Not restricted
Chemical Inventories
Classification T - Toxic.
The following sections have been revised since the last issue of this SDS
Not applicable
Contact
Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Safety Data Sheet for this or other Halliburton products,
contact Chemical Compliance at 1-580-251-4335.
***END OF MSDS***
QUIK-GEL GOLD®
Page 7 of 7
QUIK-TROL® GOLD LV
Highly Dispersible Low Viscosity Filtration Control Additive
®
Description QUIK-TROL GOLD LV highly dispersible, low viscosity grade, polyanionic cellulosic (PAC)
polymer provides enhanced filtration control in most water-based drilling fluids. QUIK-TROL
GOLD LV low viscosity PAC polymer, when added to a bentonite based drilling fluid, yields a
low filtrate drilling fluid system with manageable viscosity suitable for drilling in water
sensitive and unstable formations.
Applications/Functions The use of QUIK-TROL GOLD LV low viscosity filtration control additive promotes:
Filtration control in fresh or brackish water-based drilling fluids
Borehole stability in water sensitive formations
Encapsulation of shale to prevent swelling and disintegration
Minimized rod chatter, rotational torque and circulating pressure
Improved hole cleaning and core recovery
Enhanced foam properties to improve cuttings transport in air/foam drilling
Advantages Disperses readily at low shear rates
Effective in fresh, salt and brackish water-based drilling fluids
Tolerant of harsh environments and contaminants
Non-fermenting
Compatible with other Baroid drilling fluid additives
NSF/ANSI Standard 60 certified
Typical Properties Appearance Off-white powder
pH ( 1% aqueous solution) 6.0 – 8.0
Recommended Using a Venturi Mixer, or into vortex of a high-speed stirrer, add slowly and uniformly to
Treatment the entire circulating system. See treatment chart below or contact your local Baroid IDP
Field Representative for dosing assistance.
Approximate Amounts of QUIK-TROL® GOLD LV Filtration Control
Polymer Added to Water-Based Fluids
3
lbs/bbl lbs/100 gallons kg/m
0.1 – 2.0 0.25 – 5.0 0.3 – 6.0
Note:
The above are generalized concentration ranges of QUIK-TROL GOLD LV
filtration control additive to be added to water-based drilling fluids. The ultimate
usage concentration will be based on local geology, application and mixing
efficiency. For further information or assistance please contact your local
Baroid IDP representative.
Very salty water may require twice as much QUIK-TROL GOLD LV additive as
fresh water. Preferably, QUIK-TROL GOLD LV filtration control additive should
be mixed in fresh water before it is added to very salty water.
®
Packaging QUIK-TROL GOLD LV highly dispersible low viscosity filtration control additive is packaged
in 40-lb (18.2-kg) plastic pails and in 20-lb (9.1-kg) plastic pails containing 10 airtight sealed
plastic bags. Each bag contains 2-lb (0.91- kg).
Availability QUIK-TROL GOLD LV highly dispersible low viscosity filtration control additive can be
purchased through any Baroid Industrial Drilling Products Retailer. To locate the Baroid IDP
retailer nearest you contact the Customer Service Department in Houston or your area IDP
Sales Representative.
Baroid Industrial Drilling Products
Product Service Line, Halliburton
3000 N. Sam Houston Pkwy. E.
Houston, TX 77032
Customer Service (800) 735-6075 Toll Free (281) 871-4612
Technical Service (877) 379-7412 Toll Free (281) 871-4613