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Chemistry of whiskey
Cont…
 Character and flavour of whiskey vary due to
varying chemical composition of
compounds.That influenced by:
 Type of malt
 Grain used
 Distillation process
 Wood used in barrels that is used in ageing
process
Compounds
 Compounds that impact whiskey flavour:
 Phenolic compounds
 Aldehydes
 Lactones
 Esters
 Other compounds
Whiskey lactones
Cont…
 Two compounds, just isomers of each
other, and chemically are named cis-
and trans-3-methyl-4-octanolide.
 Originate from the oak barrels in which
the whisky is aged,
 Offer a coconut flavour.
 cis isomer has a stronger, spicier
flavour.
Phenolic compounds
Cont…
 Phenol,
 Cresols,
 Xylenol,
 Guaiacol
Cont…
 Guaiacol is also somewhat responsible
for Smokey flavours.
 Meta-cresol, which has a medicinal
aroma, and was also traditionally used
in band-aids as an antiseptic.
 Eugenol responsible for spicy aroma.
Aldehydes
Cont…
 Syringaldehyde gives a spicy, smoky note,
with furfural providing an almond-like, grainy
flavour.
 Other aldehydes from the wood include
coniferaldehyde and sinapaldehyde.
 Hexanal contribute grassy note.
Esters
Cont…
 Produced during the fermentation process.
 isoamyl acetate,
an ester with a banana-like aroma.
 ethyl hexanoate,
which has an aroma as apple.
Other compounds
 beta- damascenone and phenylethyl
alcohol, contribute a floral note.
 Diacetyl, has a buttery aroma.
Whiskey
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Whiskey

  • 2. Cont…  Character and flavour of whiskey vary due to varying chemical composition of compounds.That influenced by:  Type of malt  Grain used  Distillation process  Wood used in barrels that is used in ageing process
  • 3. Compounds  Compounds that impact whiskey flavour:  Phenolic compounds  Aldehydes  Lactones  Esters  Other compounds
  • 5. Cont…  Two compounds, just isomers of each other, and chemically are named cis- and trans-3-methyl-4-octanolide.  Originate from the oak barrels in which the whisky is aged,  Offer a coconut flavour.  cis isomer has a stronger, spicier flavour.
  • 7. Cont…  Phenol,  Cresols,  Xylenol,  Guaiacol
  • 8. Cont…  Guaiacol is also somewhat responsible for Smokey flavours.  Meta-cresol, which has a medicinal aroma, and was also traditionally used in band-aids as an antiseptic.  Eugenol responsible for spicy aroma.
  • 10. Cont…  Syringaldehyde gives a spicy, smoky note, with furfural providing an almond-like, grainy flavour.  Other aldehydes from the wood include coniferaldehyde and sinapaldehyde.  Hexanal contribute grassy note.
  • 12. Cont…  Produced during the fermentation process.  isoamyl acetate, an ester with a banana-like aroma.  ethyl hexanoate, which has an aroma as apple.
  • 13. Other compounds  beta- damascenone and phenylethyl alcohol, contribute a floral note.  Diacetyl, has a buttery aroma.