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Konsep Mol

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KONSEP MOL

RENY ROSALINA, M.SI


Micro World Macro World
atoms & molecules grams

Atomic mass is the mass of an atom in atomic


mass units (amu)
By definition:
1 atom 12C “weighs” 12 amu

On this scale
1
H = 1.008 amu
16
O = 16.00 amu
3.1
Natural lithium is:
7.42% 6Li (6.015 amu)
92.58% 7Li (7.016 amu)

Average atomic mass of lithium:

7.42 x 6.015 + 92.58 x 7.016


= 6.941 amu
100

3.1
Average atomic mass (6.941)
The mole (mol) is the amount of a substance that
contains as many elementary entities

1 mol = 12.00 g of 12C


1 mol = NA = 6.0221367 x 1023
Avogadro’s number (NA)
Molar mass is the mass of 1 mole of atoms in grams

1 mole 12C atoms = 6.022 x 1023 atoms = 12.00 g


1 12C atom = 12.00 amu

1 mole 12C atoms = 12.00 g 12C


1 mole lithium atoms = 6.941 g of Li

For any element


atomic mass (amu) = molar mass (grams)
mass (gr) mass
( gr )
mol = ----------------- or mol =
----------------
Ar Mr

M = molar mass in g/mol


NA = Avogadro’s number
3.2
Do You Understand Molar Mass?
How many atoms are in 0.551 g of potassium (K) ?

1 mol K = 39.10 g K
1 mol K = 6.022 x 1023 atoms K

1 mol K 6.022 x 1023 atoms K


0.551 g K x x =
39.10 g K 1 mol K

8.49 x 1021 atoms K


Zinc (Zn) is a silvery metal that is used in making brass (with copper) and in plating iron to prevent
corrosion. How many moles of Zn are there in 45.9 g of Zn?atomic mass of Zn 65.39 amu

1 mol K
45.9 g Zn x = 0.702 mol
65.39 g K
Molecular mass (or molecular weight) is the sum of
the atomic masses (in amu) in a molecule.

1S 32.07 amu
2O + 2 x 16.00 amu
SO2 SO2 64.07 amu

For any molecule


molecular mass (amu) = molar mass (grams)

1 molecule SO2 = 64.07 amu


1 mole SO2 = 64.07 g SO2
Calculate the molecular masses (in amu) of the following compounds: (a) Urea
((NH2)2CO) and (b) caffeine (C8H10N4O2).

molecular mass of (NH2)2CO = 2(14.01 amu) + 4(1.008 amu) + 12.01 amu + 16.00 amu
= 60.06 amu

molecular mass of C8H10N4O2 = 8(12.01 amu) + 10(1.008 amu) + 4(14.01 amu) + 2(16.00 amu)
= 194.20 amu

How many moles in 43.8 g of urea [(NH2)2CO], which is used as a fertilizer, in animal feed, and in the
manufacture of polymers?

1 mol urea
43.8 g Urea x = 0.729 mol
60.06 g K
Do You Understand Molecular Mass?
How many H atoms are in 72.5 g of C3H8O ?

1 mol C3H8O = (3 x 12) + (8 x 1) + 16 = 60 g C3H8O


1 mol C3H8O molecules = 8 mol H atoms
1 mol H = 6.022 x 1023 atoms H

1 mol C3H8O 8 mol H atoms 6.022 x 1023 H atoms


72.5 g C3H8O x x x =
60 g C3H8O 1 mol C3H8O 1 mol H atoms

5.82 x 1024 atoms H


Formula mass is the sum of the atomic masses
(in amu) in a formula unit of an ionic compound.

1Na 22.99 amu


NaCl 1Cl + 35.45 amu
NaCl 58.44 amu

For any ionic compound


formula mass (amu) = molar mass (grams)

1 formula unit NaCl = 58.44 amu


1 mole NaCl = 58.44 g NaCl
Do You Understand Formula Mass?
What is the formula mass of Ca3(PO4)2 ?

1 formula unit of Ca3(PO4)2


3 Ca 3 x 40.08
2P 2 x 30.97
8O + 8 x 16.00
310.18 amu

3.3

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