source

cond
emiss
feed
process
 B C
1 Source Description
2
3 Phase II ID No. 855
4 EPA ID No. LAD057117434
5 Facility Name Georgia Gulf Chemicals and Vinyls, LLC
6 Facility Location
7 City Plaquemine
8 State LA
9 Unit ID Name/No. IN-662 (Industrial Furnace for VCM and EDC production units)
10 Other Sister Facilities None
11 Number of Sister Facilities 0
12 Combustor Class HCl Production Furnace
13 Combustor Type
14 Combustor Characteristics Liquid injection, horizontal fired T-Thermal, 70 MM Btu/hr
15 Capacity (MMBtu/hr) 70
16 Soot Blowing
17 APCS Detailed Acronym WHB/4STGHClABS/CWS
18 APCS General Class WHB, LEWS
APCS Characteristics Waste heat boiler, 4-stage HCl absorber, caustic scrubber. Waste heat boiler
(single pass horizontal firetube, 240 psig steam, 450°F exit gas), 4 stage HCl
19 absorbers, caustic wet scrubber (packed bed with demister)

20 Hazardous Wastes Liq

2, source, 402837253.xls
 B C
1 Cond Description
2
3 855C10
4
Report Name/Date Georgia Gulf, Industrial Furnace DRE Trial Burn Report Volume I, June 1998, EMI
5
Proj No. 98-8045
6 Report Prepar Environmental Methods, Inc.
7 Testing Firm Environmental Methods, Inc.
8 Testing Dates June 19-20, 1998
9 Cond Dates June-98
10 Cond Description DRE trial burn testing only
11 Content DRE, CO
12
13 855C11
14
15 Report Name/Date Compliance Test Report, Georgia Gulf, April 25-26 and July 10, 1995
16 Report Prepar Environmental Science and Engineering, Inc.
17 Testing Firm Environmental Science and Engineering
18 Testing Dates April 25-26 1995
19 Cond Dates Apr-95
20 Cond. Description Louisiana Air Permit Compliance Testing
21 Content PM, HCl/Cl2, CO (no feedrate info)
22
23 855C12
24
Report Name/Date Confirmation of Trial Burn Test Report for Georgia Gulf Industrial Acid Furnace,
25
March 12-14, 1990
26 Report Prepar Environmental Science and Engineering
27 Testing Firm Environmental Science and Engineering
28 Testing Dates March 12-13, 1990
29 Cond Dates Mar-90
30 Cond Description Trial burn -- Heavy liquid and wet/dry vent streams
31 Content PM, HCl/Cl2, DRE, CO, complete waste feed analysis
32
33 855C13
34
Report Name/Date Confirmation of Trial Burn Test Report for Georgia Gulf Industrial Acid Furnace,
35
March 12-14, 1990
36 Report Prepar Environmental Science and Engineering
37 Testing Firm Environmental Science and Engineering
38 Testing Dates March 13, 23, 1990
39 Cond Dates Mar-90
40 Cond Description Trial burn -- Heavy liquid and wet/dry vent streams
41 Content PM, HCl/Cl2, DRE, CO, complete waste feed analysis

3, cond, 402837253.xls
 B C D E F G H I J K L M
1 Stack Gas Emissions
2
3 Comments Units 7% O2
4
5
6 855C10 R1 R2 R3 Cond Avg
7
8 CO (RA) E1 ppmv y 34.4 25.14 32.83 30.8
9
10 Sampling Train VOST E1
11 Stack Gas Flowrate dscfm 15079 15526 14352 14986
12 O2 % 10.3 12.1 11.4 11.3
13 Moisture % 7.9 7.5 8.9 8.1
14 Temperature °F 105 105 103.5 104.5
15
16 POHC DRE Monochlorobenzene
17 POHC Feedrate lb/hr 104.2 107.7 105.85
18 Emmision Rate
19 DRE E1 % 99.999976 99.999985 99.99999
20
21
22 855C11 R1 R2 R3 Cond Avg
23
24 PM E1 gr/dscf y 0.01613 0.01246 0.00973 0.0128
25 CO (RA) ppmv n 0.21 0 0.96
26 HCl lb/hr 0.056 0.061 0.09
27 Cl2 lb/hr 0.933 0.689 0.745
28
29 Sampling Train PM, HCl/ClE1
30 Stack Gas Flowrate dscfm 11328 11938 12085 11783.7
31 O2 % 9.2 9.1 9.1 9.1
32 Moisture % 9.7 6.8 7.04 7.8
33 Temperature °F 90 90 90 90.0
34
35 CO (RA) E1 ppmv y 0.2 0.0 1.1 0.5
36 HCl E1 ppmv y 1.0 1.1 1.6 1.2
37 Cl2 E1 ppmv y 9.0 6.2 6.7 7.3
38 Total Chlorine E1 ppmv y 19.0 13.5 14.9 15.8
39
40
41 855C12 R1 R2 R3 Cond Avg
42
43 PM E1 gr/dscf y 0.0208 0.0087 0.0091 0.0129
44 CO (RA) E1 ppmv y 7.27 32.68 17.55 19.2
45 HCl lb/hr 4.7 0.207 1.684
46 Cl2 lb/hr 2 0.98 1.186
47
48 Sampling Train PM, HCl/ClE1
49 Stack Gas Flowrate dscfm 10969 11579 11402.8 11316.9
50 O2 % 8.08 10.47 10.35 9.6
51
52 HCl E1 ppmv y 82.9 4.2 34.7 40.6
53 Cl2 E1 ppmv y 18.1 10.3 12.6 13.7
54 Total Chlorine E1 ppmv y 119.2 24.9 59.8 68.0
55
56 POHC DRE 1,1,2-trichloroethane
57 POHC Feedrate g/min 22000 22000 22000
58 Emission Rate
59 DRE E1 % > 99.9999 > 99.9999 > 99.9999
60
61 POHC DRE Tetrachloroethylene
62 POHC Feedrate g/min 1000 1000 1000
63 Emisssion Rate
64 DRE E1 % 99.9996 99.9985 99.9988
65
66 POHC DRE Hexachloroethane
67 POHC Feedrate g/min 20 20 20
68 Emmision Rate
69 DRE E1 % 99.9906 99.992 99.9926

4, emiss, 402837253.xls
 B C D E F G H I J K L M
70
71
72 855C13 R1 R2 R3 Cond Avg
73
74 PM E1 gr/dscf y 0.0131 0.0136 0.0155 0.0141
75 CO (RA) E1 ppmv y 27.56 28.15 23.98 26.6
76 HCl lb/hr 5.662 3.345 5.482
77 Cl2 lb/hr 0.737 0.657 0.626
78
79 Sampling Train PM, HCl/ClE1
80 Stack Gas Flowrate dscfm 10175 9679 9999 9951
81 O2 % 7.74 7.67 7.66 7.7
82
83 HCl E1 ppmv y 104.9 64.8 102.7 90.8
84 Cl2 E1 ppmv y 7.0 6.5 6.0 6.5
85 Total Chlorine E1 ppmv y 118.9 77.9 114.8 103.9
86
87
88 POHC DRE 1,1,2-trichloroethane
89 POHC Feedrate g/min 21000 21000 21000
90 Emissions rate
91 DRE E1 % > 99.9999 > 99.9999 > 99.9999
92
93 POHC DRE Tetrachloroethylene
94 POHC Feedrate g/min 1000 1000 1000
95 Emissions rate
96 DRE E1 % 99.9973 99.9977 99.9971
97
98 POHC DRE Hexachloroethane
99 POHC Feedrate g/min 20 20 20
100 Emissions Rate
101 DRE E1 % 99.9939 99.9918 99.9911

5, emiss, 402837253.xls
 B C D E F G H I J K L M N O P Q R S
1 Feedstreams
2
3 855C12 R1 R2 R3 Cond Avg R1 R2 R3
4
5 Feedstream Number F1 F1 F1 F1 F2 F2 F2
6 Feed Class Liq HW Liq HW Liq HW Liq HW Total Total Total
7 Feed Class 2 HW HW HW HW Total Total Total
8 Feedstream Description Liquid waste feed Liquid waste feed Liquid waste feed Liquid waste feed Total Total Total
9 Feed Rate gal/min 10.03 9.99 9.98 10
10 Feed Rate g/min 49800.6 49999.0 49975.4 49583.5
11 Feed Rate L/min 38.0 37.8 37.8 37.85
12 Density g/ml 1.3118 1.3223 1.323 1.31
13 Heat Content Btu/lb 6500 6500 6500 6500
14 Viscosity cst 5.02 5.03 5.03 5
15 Ash % wt 0.049 0.06 0.062 0.055
16 Chlorine % wt 67.98 68.69 67.93 68
17 Arsenic mg/L nd 0.08 nd 0.08 nd 0.08 0.08
18 Barium mg/L 0.2 0.2 0.2 0.2
19 Cadmium mg/L nd 0.2 nd 0.3 nd 0.3 0.25
20 Chromium mg/L 1 0.9 0.8 0.9
21 Lead mg/L nd 0.07 nd 0.05 nd 0.05 0.05
22 Mercury mg/L nd 0.06 nd 0.07 nd 0.07 0.06
23 Selenium mg/L nd 0.1 nd 0.1 nd 0.1 0.1
24 Silver mg/L nd 0.5 nd 0.5 nd 0.5 0.5
25
26 Gas Flowrate dscfm 10969 11579 11402.8 11316.9
27 Oxygen % 8.08 10.47 10.35 9.6
28
29 Thermal Feedrate MMBtu/hr 42.8 43.0 42.9 42.6 42.8 43.0 42.9
30 Estimated Firing Rate MMBtu/hr 45.0 38.7 38.6
31
32
33 Feedrate MTEC Calculations
34 Ash mg/dscm 85.2 121.7 126.2 111.0 85.2 121.7 126.2
35 Chlorine ug/dscm 118175556 139346820 138292418 131938264 118175556 139346820 138292418
36 Arsenic ug/dscm 100 10.6 100 12.3 100 12.3 100 11.7 100 5.3 100 6.1 100 6.2 100
37 Barium ug/dscm 26.5 30.7 30.8 29.3 26.5 30.7 30.8
38 Cadmium ug/dscm 100 26.5 100 46.0 100 46.2 100 39.6 100 13.3 100 23.0 100 23.1 100
39 Chromium ug/dscm 132.5 138.1 123.1 131.2 132.5 138.1 123.1
40 Lead ug/dscm 100 9.3 100 7.7 100 7.7 100 8.2 100 4.6 100 3.8 100 3.8 100
41 Mercury ug/dscm 100 8.0 100 10.7 100 10.8 100 9.8 100 4.0 100 5.4 100 5.4 100
42 Selenium ug/dscm 100 13.3 100 15.3 100 15.4 100 14.7 100 6.6 100 7.7 100 7.7 100
43 Silver ug/dscm 100 66.3 100 76.7 100 76.9 100 73.3 100 33.1 100 38.4 100 38.5 100
44
45 SVM ug/dscm 100 35.8 100 53.7 100 53.9 100 47.8 100 17.9 100 26.8 100 26.9 100
46 LVM ug/dscm 7 143.1 8 150.3 9 135.4 7 143.0 8 137.8 9 144.2 7 129.3 8
47
48
49
50 855C13 R1 R2 R3 Cond Avg R1 R2 R3
51
52 Feedstream Number F1 F1 F1 F1 F2 F2 F2
53 Feed Class Liq HW Liq HW Liq HW Liq HW Total Total Total
54 Feed Class 2 HW HW HW HW Total Total Total
55 Feedstream Description Liquid waste feed Liquid waste feed Liquid waste feed Liquid waste feed Total Total Total
56 Feed Rate gal/min 9.97 9.99 10.02 10
57 Feed Rate g/min 49589.5 49915.8 49690.3 49583.5
58 Feed Rate L/min 37.7 37.8 37.9 37.9
59 Density g/ml 1.3141 1.3201 1.3102 1.31

6, feed, 402837253.xls
 B T
1 Feedstreams
2
3 855C12 Cond Avg
4
5 Feedstream Number F2
6 Feed Class Total
7 Feed Class 2 Total
8 Feedstream Description Total
9 Feed Rate
10 Feed Rate
11 Feed Rate
12 Density
13 Heat Content
14 Viscosity
15 Ash
16 Chlorine
17 Arsenic
18 Barium
19 Cadmium
20 Chromium
21 Lead
22 Mercury
23 Selenium
24 Silver
25
26 Gas Flowrate
27 Oxygen
28
29 Thermal Feedrate 42.6
30 Estimated Firing Rate 40.8
31
32
33 Feedrate MTEC Calculations
34 Ash 111.0
35 Chlorine 131938264
36 Arsenic 11.7
37 Barium 29.3
38 Cadmium 39.6
39 Chromium 131.2
40 Lead 8.2
41 Mercury 9.8
42 Selenium 14.7
43 Silver 73.3
44
45 SVM 47.8
46 LVM 143.0
47
48
49
50 855C13 Cond Avg
51
52 Feedstream Number F2
53 Feed Class Total
54 Feed Class 2 Total
55 Feedstream Description Total
56 Feed Rate
57 Feed Rate
58 Feed Rate
59 Density

7, feed, 402837253.xls
 B C D E F G H I J K L M N O P Q R S
60 Heat Content Btu/lb 6500 6500 6500 6500
61 Viscosity cst 5.04 5.04 5.03 5
62 Ash % wt 0.058 0.054 0.068 0.06
63 Chlorine % wt 64.37 60.06 56.93 60.45
64 Arsenic mg/L nd 0.08 nd 0.08 nd 0.08 0.08
65 Barium mg/L 0.2 0.2 0.2 0.2
66 Cadmium mg/L nd 0.3 nd 0.2 nd 0.2 0.25
67 Chromium mg/L 0.8 0.7 0.7 0.8
68 Lead mg/L nd 0.05 nd 0.05 nd 0.05 0.05
69 Mercury mg/L nd 0.06 nd 0.06 nd 0.06 0.06
70 Selenium mg/L nd 0.1 nd 0.1 nd 0.1 0.1
71 Silver mg/L nd 0.5 nd 0.5 nd 0.5 0.5
72
73 Gas Flowrate dscfm 10175 9679 9999 9951
74 Oxygen % 7.74 7.67 7.66 7.69
75
76 Thermal Feedrate MMBtu/hr 42.6 42.9 42.7 42.6 42.6 42.9 42.7
77 Estimated Firing Rate MMBtu/hr 42.8 41.0 42.3 42.0 42.8 41.0 42.3
78
79
80 Feedrate MTEC Calculations
81 Ash mg/dscm 100.8 109.5 138.4 116.3 0 100.8 109.5 138.4
82 Chlorine ug/dscm 111899978 121839715 115898533 116546075 111899978 121839715 115898533
83 Arsenic ug/dscm 100 10.6 100 12.3 100 12.3 100 11.7 100 10.6 100 12.3 100 12.3 100
84 Barium ug/dscm 26.5 30.7 30.8 29.3 26.5 30.7 30.8
85 Cadmium ug/dscm 100 39.8 100 30.7 100 30.8 100 33.7 100 39.8 100 30.7 100 30.8 100
86 Chromium ug/dscm 106.0 107.4 107.7 107.0 106.0 107.4 107.7
87 Lead ug/dscm 100 6.6 100 7.7 100 7.7 100 7.3 100 6.6 100 7.7 100 7.7 100
88 Mercury ug/dscm 100 8.0 100 9.2 100 9.2 100 8.8 100 8.0 100 9.2 100 9.2 100
89 Selenium ug/dscm 100 13.3 100 15.3 100 15.4 100 14.7 100 13.3 100 15.3 100 15.4 100
90 Silver ug/dscm 100 66.3 100 76.7 100 76.9 100 73.3 100 66.3 100 76.7 100 76.9 100
91
92 SVM ug/dscm 100 46.4 100 38.4 100 38.5 100 41.1 100 46.4 100 38.4 100 38.5 100
93 LVM ug/dscm 9 116.6 10 119.7 10 120.0 10 118.8 9 116.6 10 119.7 10 120.0 10

8, feed, 402837253.xls
 B T
60 Heat Content
61 Viscosity
62 Ash
63 Chlorine
64 Arsenic
65 Barium
66 Cadmium
67 Chromium
68 Lead
69 Mercury
70 Selenium
71 Silver
72
73 Gas Flowrate
74 Oxygen
75
76 Thermal Feedrate 42.6
77 Estimated Firing Rate 42.0
78
79
80 Feedrate MTEC Calculations
81 Ash 116.3
82 Chlorine 116546075
83 Arsenic 11.7
84 Barium 29.3
85 Cadmium 33.7
86 Chromium 107.0
87 Lead 7.3
88 Mercury 8.8
89 Selenium 14.7
90 Silver 73.3
91
92 SVM 41.1
93 LVM 118.8

9, feed, 402837253.xls
 A B C
1 Process Information
2
3 Units Cond Avg
4
5 855C12
6
7 Steam production lb/hr 36200
8 Liquid waste feed gal/min 10
9 Natural gas feed scfh 2773
10 Boiler exit temperature °F 590
11 Fume Scrubber
12 Liquor pH pH 8.7
13 Water feed gal/min 10.7
14 Liquor feed gal/min 335
15 Pressure drop in H2O 1.31
16
17 855C13
18
19 Steam production lb/hr 37447
20 Liquid waste feed gal/min 10
21 Natural gas feed scfh 2.85
22 Boiler exit temperature °F 595
23 Fume Scrubber
24 Liquor pH pH 8.7
25 Water feed gal/min 12
26 Liquor feed gal/min 350
27 Pressure drop in H2O 1.43

10, process, 402837253.xls